TITAN CHLORPYRIFOS 500 TERMITICIDE AND INSECTICIDE

Australia - English - APVMA (Australian Pesticides and Veterinary Medicines Authority)

Active ingredient:
CHLORPYRIFOS; HYDROCARBON LIQUID
Available from:
Titan Ag Pty Ltd
INN (International Name):
chlorpyrifos(500g/L)
Pharmaceutical form:
EMULSIFIABLE CONCENTRATE
Composition:
CHLORPYRIFOS ORGANOPHOSPHORUS Active 500.0 g/L; HYDROCARBON LIQUID SOLVENT Other 474.0 g/L
Units in package:
1000L; 110L; 1L; 200L; 20L; 5L
Class:
A - Agricultural
Manufactured by:
TITAN AG
Therapeutic group:
AGRICULTURAL AREA - GENERAL | ANNUAL PASTURE-IMPROVED | APPLE CROP = APPLE ORCHARD | ASPARAGUS | AVOCADO | BANANA | BARLEY | BEA
Therapeutic area:
INSECTICIDE
Therapeutic indications:
AFRICAN BLACK BEETLE | ANT | ARGENTINE ANT | AUSTRALIAN PLAGUE LOCUST | AVOCADO LEAFROLLER | BANANA SCAB MOTH | BANANA WEEVIL BORER | BLACK BEETLE | BLACKHEADED PASTURE COCKCHAFER | BLUE OAT OR PEA MITE | BLUEGREEN APHID | BROWN PASTURE LOOPER | BROWN PLANTHOPPER | CABBAGE APHID | CABBAGE CLUSTER CATERPILLAR | CABBAGE MOTH | CABBAGE WHITE BUTTERFLY | CALIFORNIA RED SCALE | CATERPILLAR | CLUSTER CATERPILLAR | COCKROACH | COMMON ARMYWORM - MYTHIMNA CONVECTA | COMMON MANGO SCALE | CORN APHID | CORN EARWORM | COTTON APHID | COTTON FLEA BEETLE | CURCULIO BEETLE | CUTWORM - AGROTIS SPP. | CUTWORM IN YOUNG PLANTS | EUROPEAN EARWIG | FALSE WIREWORM - CELIBE SPP. | FIELD CRICKET | FLEA | GRAPEVINE MOTH | GRAPEVINE SCALE | GREEN PEACH APHID | GREEN VEGETABLE BUG | HAIRY CATERPILLAR | HIDE OR SKIN BEETLE | IVY LEAFROLLER | LATANIA SCALE | LAWN ARMYWORM | LIGHT BROWN APPLE MOTH | LUCERNE FLEA | LUCERNE LEAFROLLER | MIGRATORY LOCUST | MOLE CRICKET - GRYLLOTALPA SPP. | MOSQUITO | MOSQUITO LARVA | NATIVE BUDWORM OR BOLLWORM
Product summary:
Poison schedule: 6; Withholding period: WHP: Do not graze or cut cereals, past ures or forage crops for stock food for 2 days after application. Cotton:Do no t harvest for 4 weeks after application . Do not graze or cut for stock food fo r 4 weeks after application Do not harv est the following crops until the numbe r of days stated below has elapsed aft er spraying: Mango: 21 days Asparagus Bananas Citrus Grapevines, Kiwifruit Pome Fruit Stone Fruit, Celery: 14 da ys Cereal Grain Crops: 10 days Avocado Sugar Cane: 7 days Cole Crops Cucurb its: 5 days Tomatoes: 3 days Sorghum G rain Crops: 2 days; Host/pest details: AGRICUL/FARM BUILDING UNDER CONSTRUCTION NOT PUBLICLY ACCESSIBLE: [ANT, ARGENTINE ANT, COCKROACH, FLEA, SILVERFISH, SPIDER]; AGRICULTURAL AREA THAT THE PUBLIC DO NOT HAVE ACCESS TO: [ARGENTINE ANT]; ANNUAL PASTURE-IMPROVED: [BLUE OAT OR PEA MITE, REDLEGGED EARTH MITE]; APPLE CROP = APPLE ORCHARD: [SAN JOSE' SCALE, WINGLESS GRASSHOPPER, WOOLLY APHID]; ASPARAGUS: [CUTWORM - AGROTIS SPP., FIELD CRICKET, MOLE CRICKET - GRYLLOTALPA SPP., VEGETABLE WEEVIL, WINGLESS GRASSHOPPER]; AVOCADO: [AVOCADO LEAFROLLER, HAIRY CATERPILLAR, IVY LEAFROLLER, LATANIA SCALE, LIGHT BROWN APPLE MOTH, REDSHOULDERED LEAF BEETLE]; BANANA: [BANANA SCAB MOTH, BANANA WEEVIL BORER, CATERPILLAR]; BARLEY: [BLUE OAT OR PEA MITE, REDLEGGED EARTH MITE]; BEAN: [CUTWORM - AGROTIS SPP., FIELD CRICKET, MOLE CRICKET - GRYLLOTALPA SPP., VEGETABLE WEEVIL, WINGLESS GRASSHOPPER]; BEETROOT: [CUTWORM - AGROTIS SPP., FIELD CRICKET, MOLE CRICKET - GRYLLOTALPA SPP., VEGETABLE WEEVIL, WINGLESS GRASSHOPPER]; BRASSICA SPP. OR COLE CROP: [BLUE OAT OR PEA MITE, CABBAGE APHID, CABBAGE CLUSTER CATERPILLAR, CABBAGE MOTH, CABBAGE WHITE BUTTERFLY, CLUSTER CATERPILLAR, CORN EARWORM, NATIVE BUDWORM OR BOLLWORM, REDLEGGED EARTH MITE, WINGLESS GRASSHOPPER]; BROAD BEAN: [BLUE OAT OR PEA MITE, REDLEGGED EARTH MITE]; BROCCOLI: [BLUE OAT OR PEA MITE, CABBAGE APHID, CABBAGE CLUSTER CATERPILLAR, CABBAGE MOTH, CABBAGE WHITE BUTTERFLY, CLUSTER CATERPILLAR, CORN EARWORM, CUTWORM - AGROTIS SPP., FIELD CRICKET, MOLE CRICKET - GRYLLOTALPA SPP., NATIVE BUDWORM OR BOLLWORM, REDLEGGED EARTH MITE, VEGETABLE WEEVIL, WINGLESS GRASSHOPPER]; BRUSSELS SPROUTS: [BLUE OAT OR PEA MITE, CABBAGE APHID, CABBAGE CLUSTER CATERPILLAR, CABBAGE MOTH, CABBAGE WHITE BUTTERFLY, CLUSTER CATERPILLAR, CORN EARWORM, CUTWORM - AGROTIS SPP., FIELD CRICKET, MOLE CRICKET - GRYLLOTALPA SPP., NATIVE BUDWORM OR BOLLWORM, REDLEGGED EARTH MITE, VEGETABLE WEEVIL, WINGLESS GRASSHOPPER]; BUILDINGS - AROUND: [SUBTERRANEAN TERMITE, SUBTERRANEAN TERMITE INCL. M.DARWINIENSI]; CABBAGE: [AFRICAN BLACK BEETLE, BLUE OAT OR PEA MITE, CABBAGE APHID, CABBAGE CLUSTER CATERPILLAR, CABBAGE MOTH, CABBAGE WHITE BUTTERFLY, CLUSTER CATERPILLAR, CORN EARWORM, CUTWORM - AGROTIS SPP., FIELD CRICKET, MOLE CRICKET - GRYLLOTALPA SPP., NATIVE BUDWORM OR BOLLWORM, REDLEGGED EARTH MITE, VEGETABLE WEEVIL, WINGLESS GRASSHOPPER]; CANOLA OILSEED CROP: [BLUE OAT OR PEA MITE, FALSE WIREWORM - CELIBE SPP., REDLEGGED EARTH MITE, WIREWORM]; CAPSICUM OR PEPPER: [CUTWORM - AGROTIS SPP., FIELD CRICKET, MOLE CRICKET - GRYLLOTALPA SPP., VEGETABLE WEEVIL, WINGLESS GRASSHOPPER]; CARROT: [CUTWORM - AGROTIS SPP., FIELD CRICKET, LIGHT BROWN APPLE MOTH, MOLE CRICKET - GRYLLOTALPA SPP., VEGETABLE WEEVIL, WINGLESS GRASSHOPPER]; CASSAVA: [CUTWORM - AGROTIS SPP.]; CAULIFLOWER: [AFRICAN BLACK BEETLE, BLUE OAT OR PEA MITE, CABBAGE APHID, CABBAGE CLUSTER CATERPILLAR, CABBAGE MOTH, CABBAGE WHITE BUTTERFLY, CLUSTER CATERPILLAR, CORN EARWORM, CUTWORM - AGROTIS SPP., FIELD CRICKET, MOLE CRICKET - GRYLLOTALPA SPP., NATIVE BUDWORM OR BOLLWORM, REDLEGGED EARTH MITE, VEGETABLE WEEVIL, WINGLESS GRASSHOPPER]; CELERY: [CUTWORM - AGROTIS SPP., FIELD CRICKET, MOLE CRICKET - GRYLLOTALPA SPP., VEGETABLE WEEVIL, WINGLESS GRASSHOPPER]; CEREAL CROP: [AUSTRALIAN PLAGUE LOCUST, BLUE OAT OR PEA MITE, COMMON ARMYWORM - MYTHIMNA CONVECTA, CURCULIO BEETLE, CUTWORM - AGROTIS SPP., LUCERNE FLEA, MIGRATORY LOCUST, PASTURE WEBWORM, REDLEGGED EARTH MITE, SOUTHERN OR BARLEY ARMYWORM, SPUR-THROATED LOCUST, WINGLESS GRASSHOPPER]; CHICKPEA: [BLUE OAT OR PEA MITE, REDLEGGED EARTH MITE]; CITRUS FRUIT ORCHARD: [CALIFORNIA RED SCALE, WINGLESS GRASSHOPPER]; CLOVER SEED CROP: [BLUE OAT OR PEA MITE, REDLEGGED EARTH MITE]; COMMERICAL / INDUSTRIAL AREAS (NOT IN RESIDENTIAL / HOME / PUBLIC/ COMMERICAL / SPACES): [ANT, ARGENTINE ANT, COCKROACH, FLEA, SILVERFISH, SPIDER]; COTTON: [COMMON ARMYWORM - MYTHIMNA CONVECTA, COTTON APHID, COTTON FLEA BEETLE, FALSE WIREWORM - CELIBE SPP., MIGRATORY LOCUST, PINK SPOTTED BOLLWORM MOTH, REDSHOULDERED LEAF BEETLE, SOUTHERN OR BARLEY ARMYWORM, SPRINGTAIL, SPUR-THROATED LOCUST, WINGLESS GRASSHOPPER, WIREWORM]; COTTON - YOUNG PLANTS: [CUTWORM - AGROTIS SPP.]; CUCURBIT: [WHITEFLY]; EGGPLANT: [CUTWORM - AGROTIS SPP., FIELD CRICKET, MOLE CRICKET - GRYLLOTALPA SPP., VEGETABLE WEEVIL, WINGLESS GRASSHOPPER]; FIELD PEA: [BLUE OAT OR PEA MITE, REDLEGGED EARTH MITE]; FORAGE CROP: [AUSTRALIAN PLAGUE LOCUST, BLUE OAT OR PEA MITE, BROWN PASTURE LOOPER, COMMON ARMYWORM - MYTHIMNA CONVECTA, LUCERNE FLEA, MIGRATORY LOCUST, PASTURE WEBWORM, REDLEGGED EARTH MITE, SOUTHERN OR BARLEY ARMYWORM, SPUR-THROATED LOCUST, UNDERGROUND GRASS GRUB]; FORAGE CROP (CONTAINING LUCERNE): [BLUEGREEN APHID, PEA APHID, SITONA WEEVIL, SPOTTED ALFALFA APHID]; FORAGE CROP (CONTAINING MEDIC): [BLUEGREEN APHID, PEA APHID, SITONA WEEVIL, SPOTTED ALFALFA APHID]; GINGER: [CUTWORM - AGROTIS SPP.]; GRAPEVINE: [GRAPEVINE MOTH, GRAPEVINE SCALE, LIGHT BROWN APPLE MOTH]; HEAVY VEGETATION: [MOSQUITO LARVA]; INSECTS INFESTING HIDES AND SKIN: [HIDE OR SKIN BEETLE]; KIWI FRUIT: [COMMON ARMYWORM - MYTHIMNA CONVECTA, LIGHT BROWN APPLE MOTH, SOUTHERN OR BARLEY ARMYWORM]; KIWIFRUIT - TRELLISED: [COMMON ARMYWORM - MYTHIMNA CONVECTA, LIGHT BROWN APPLE MOTH, SOUTHERN OR BARLEY ARMYWORM]; LIGHT TO MEDIUM VEGETATION (NOT IN RESIDENTIAL, HOME, PUBLIC OR COMMERCIAL SPACES): [MOSQUITO]; LIGHT VEGETATION (NOT IN RESIDENTIAL / HOME / PUBLIC/ COMMERICAL / SPACES): [MOSQUITO LARVA]; LINSEED CROP: [BLUE OAT OR PEA MITE, REDLEGGED EARTH MITE]; LUCERNE: [BLUE OAT OR PEA MITE, LUCERNE LEAFROLLER, REDLEGGED EARTH MITE, WEBSPINNER CATERPILLAR]; LUCERNE - YOUNG PLANTS: [CUTWORM - AGROTIS SPP., CUTWORM IN YOUNG PLANTS]; LUCERNE PASTURE - REFER TO LABEL: [BLUE OAT OR PEA MITE, CUTWORM - AGROTIS SPP., REDLEGGED EARTH MITE]; LUPIN: [BLUE OAT OR PEA MITE, REDLEGGED EARTH MITE]; MAIZE: [AFRICAN BLACK BEETLE, COCKROACH, FALSE WIREWORM - CELIBE SPP., FIELD CRICKET, WIREWORM]; MANGO: [COMMON MANGO SCALE]; MEDIUM TO HEAVY VEGETATION (NOT IN RESIDENTIAL / HOME / PUBLIC/ COMMERICAL / SPACES): [MOSQUITO]; MEDIUM VEGETATION (NOT IN RESIDENTIAL / HOME / PUBLIC/ COMMERICAL / SPACES): [MOSQUITO LARVA]; OATS: [BLUE OAT OR PEA MITE, REDLEGGED EARTH MITE]; OILSEED - YOUNG PLANTS: [CUTWORM - AGROTIS SPP.]; OILSEED CROP: [CUTWORM - AGROTIS SPP., WINGLESS GRASSHOPPER]; ONION: [CUTWORM - AGROTIS SPP., FIELD CRICKET, MOLE CRICKET - GRYLLOTALPA SPP., VEGETABLE WEEVIL, WINGLESS GRASSHOPPER]; PASTURE: [AUSTRALIAN PLAGUE LOCUST, BLACKHEADED PASTURE COCKCHAFER, BLUE OAT OR PEA MITE, BROWN PASTURE LOOPER, COMMON ARMYWORM - MYTHIMNA CONVECTA, CUTWORM - AGROTIS SPP., LAWN ARMYWORM, LUCERNE FLEA, MIGRATORY LOCUST, PASTURE WEBWORM, REDLEGGED EARTH MITE, SOD WEBWORM, SOUTHERN OR BARLEY ARMYWORM, SPUR-THROATED LOCUST, UNDERGROUND GRASS GRUB, WINGLESS GRASSHOPPER]; PASTURE (CONTAINING LUCERNE): [BLUEGREEN APHID, PEA APHID, SITONA WEEVIL, SPOTTED ALFALFA APHID]; PASTURE (CONTAINING MEDIC): [BLUEGREEN APHID, PEA APHID, SITONA WEEVIL, SPOTTED ALFALFA APHID]; PEA: [CUTWORM - AGROTIS SPP., FIELD CRICKET, MOLE CRICKET - GRYLLOTALPA SPP., VEGETABLE WEEVIL, WINGLESS GRASSHOPPER]; PEAR: [SAN JOSE' SCALE, WINGLESS GRASSHOPPER, WOOLLY APHID]; PERENNIAL PASTURES - ESTABLISHING: [BLUE OAT OR PEA MITE, REDLEGGED EARTH MITE]; PINEAPPLE: [ANT, PINEAPPLE MEALY BUG, WHITEGRUB]; POLLUTED WATER: [MOSQUITO, MOSQUITO LARVA]; POME FRUIT: [WINGLESS GRASSHOPPER]; POTATO: [AFRICAN BLACK BEETLE, CUTWORM - AGROTIS SPP., FIELD CRICKET, MOLE CRICKET - GRYLLOTALPA SPP., VEGETABLE WEEVIL, WHITE FRINGED WEEVIL, WINGLESS GRASSHOPPER, WIREWORM];
Authorization status:
Registered
Authorization number:
50387
Authorization date:
2019-07-01

TITAN CHLORPYRIFOS 500 TERMITICIDE AND INSECTICIDE

50387/121071

Product Name:

APVMA Approval No:

Label Name:

TITAN CHLORPYRIFOS 500 TERMITICIDE AND INSECTICIDE

Signal Headings:

POISON

KEEP OUT OF REACH OF CHILDREN

READ SAFETY DIRECTIONS BEFORE OPENING OR USING

Constituent

Statements:

500 g/L CHLORPYRIFOS

SOLVENT: 474 g/L HYDROCARBON LIQUID

Mode of Action:

GROUP

INSECTICIDE

Statement of Claims:

For the control of certain insect pests of fruit, vegetables, field crops and pasture and other

situations and for the post-construction management of subterranean termites in accord

with AS 3660.2 and other insect pests as per directions for use table

THIS PRODUCT IS TOO HAZARDOUS FOR USE BY HOUSEHOLDERS. DO NOT USE

THIS PRODUCT IN OR AROUND THE HOME

Net Contents:

1000L

110L

200L

Restraints:

Restraints: MANAGEMENT OF SUBTERRANEAN TERMITES (All States, except

Tasmania)

DO NOT apply to soils if excessively wet, immediately after heavy rain or if heavy rains are

expected within 48 hours to avoid run-off of chemical.

DO NOT use at less than indicated label rates.

DO NOT use in cavity walls, except for direct treatment of nest.

DO NOT use on alkaline soils in SA (use on neutral or acidic soils only) or on dolomite

based sub-slab bedding material.

RLP

APPROVED

DO NOT use Horizontal barriers around homes, in residential areas, public spaces or in

publicly accessible commercial areas

GENERAL PEST CONTROL Restraint:

DO NOT spray polycarbonate surfaces/roof sheeting or aged vinyl wall cladding as solvent

may cause etching.

DO NOT use in residential areas, public spaces or in publicly accessible commercial areas

Directions for Use:

This section contains file attachment.

Other Limitations:

Withholding Periods:

WITHHOLDING PERIOD

DO NOT GRAZE OR CUT CEREALS, PASTURES OR FORAGE CROPS FOR STOCK

FOOD FOR 2 DAYS AFTER APPLICATION.

COTTON: DO NOT HARVEST FOR 4 WEEKS AFTER APPLICATION. DO NOT GRAZE

OR CUT FOR STOCK FOOD FOR 4 WEEKS AFTER APPLICATION.

DO NOT HARVEST THE FOLLOWING CROPS UNTIL THE NUMBER OF DAYS STATED

BELOW HAS ELAPSED, AFTER SPRAYING:

Mango 21 days

Asparagus, Bananas, Citrus, Grapevines, Kiwifruit,

Pome Fruit, Stone Fruit, Celery 14 days

Cereal Grain Crops 10 days

Avocado, Sugar Cane 7 days

Cole Crops, Cucurbits 5 days

Tomatoes 3 days

Sorghum Grain Crops 2 days

Trade Advice:

General Instructions:

GENERAL INSTRUCTIONS – For use as a Termiticide

MIXING

Half fill the spray tank with water (or creosote where applicable) and add the required

amount of TITAN CHLORPYRIFOS 500, then add the remaining water (or creosote) with

an agitator running. If using a knapsack sprayer gently shake before using. Only mix

sufficient chemical for each specific application.

CLEANING SPRAY EQUIPMENT

After using TITAN CHLORPYRIFOS 500, empty the spray equipment completely and drain

the whole system. Thoroughly wash inside the tank using a pressure hose, and drain. To

wash the system, quarter fill the tank with clean water and circulate through the pump,

lines, hoses and nozzles (for knapsack sprayers spray to waste through the nozzle). Drain

and repeat the washing procedure twice. Dispose of rinsate/rinse water in accordance with

STORAGE AND DISPOSAL instructions below.

GENERAL INSTRUCTIONS: FOR USE AS AN INSECTICIDE

Thorough coverage is essential.

For application by aircraft apply in 10-50L of water/ha.

MIXING

Slowly add the required amount of product to the water in the spray tank under agitation.

Dilute Spraying

Use a sprayer designed to apply high volumes of water up to the point of run-off and

matched to the crop being sprayed.

Set up and operate the sprayer to achieve even coverage throughout the crop canopy.

Apply sufficient water to cover the crop to the point of run-off. Avoid excessive run-off.

The required water volume may be determined by applying different test volumes, using

different settings on the sprayer, from industry guidelines or expert advise.

Add the amount of product specified in the Directions for Use table for each 100L of

water. Spray to the point of run-off.

The required dilute spray volume will change and the sprayer set up and operation may

also need to be changed, as the crop grows.

Concentrate Spraying

Use a sprayer designed and set up for concentrate spraying (that is a sprayer which

applies water volumes less than those required to reach the point of run-off) and matched

to the crop being sprayed.

Set up and operate the sprayer to achieve even coverage throughout the crop canopy

using your chosen water volume.

Determine an appropriate dilute spray volume (see Dilute Spraying above) for the crop

canopy. This is needed to calculate the concentrate mixing rate.

The mixing rate for concentrate spraying can then be calculated in the following way:

EXAMPLE ONLY

1. Dilute spray volume as determined above: For example 1500L/ha

2. Your chosen concentrate spray volume: For example 500L/ha

3. The concentration factor in this example is: 3 X (i.e. 1500L ÷ 500L = 3)

4. If the dilute label rate is 10mL/100L, then the concentrate rate becomes 3 x 10, that is

30mL/100L of concentrate spray.

The chosen spray volume, amount of product per 100L of water, and the sprayer set up

and operation may need to be changed as the crop grows.

For further information on concentrate spraying, users are advised to consult relevant

industry guidelines, undertake appropriate competency training and follow industry Best

Practices.

SOIL APPLICATION

In-Furrow: Apply as a band spray to the open furrow at planting. Spray the entire furrow

tilth using a nozzle located directly behind the seed tube. Ensure all spray is directed into

the furrow contacting bottom, sides and all soil drawn in to the furrow at closure. Use a

minimum of 20L of water/ha. Use the higher rate under extreme population numbers.

BAIT APPLICATION

Bran bait: Mix 10mL/kg of bran using sufficient water to give a moist crumb structure. Allow

to stand for 2-3 hours before application. Gloves should be worn when preparing and

applying the bait.

Cracked wheat or cracked sorghum bait: Mix the required volume of TITAN

CHLORPYRIFOS 500 and sunflower oil together. Then, add to the wheat or sorghum,

mixing thoroughly. Gloves should be worn when preparing and applying the bait.

COMPATIBILITY

TITAN CHLORPYRIFOS 500 Termiticide and Insecticide is compatible with the following:

Herbicides

Atrazine, bromoxynil, chlorsulfuron, diclofop-methyl, diuron, flamprop-methyl, fluometuron,

glyphosate, paraquat, paraquat + diquat, pendimethalin, trifluralin.

Insecticides and Miticides

Acephate, azinphos-methyl, carbaryl, cypermethrin, deltamethrin, demeton-S-methyl,

diazinon, dichlorvos, dicofol, dimethoate, endosulfan, ethion, fenvalerate, maldison,

methidathion, methomyl, monocrotophos, oils, oxythioquinox, parathion, phosalone,

phosmet, tetradifon, trichlorfon.

Fungicides

Benomyl, chlorothalonil, thiram, triadimefon, zineb, ziram.

Fertilisers

Diammonium phosphate, limestone, miloreanite, monoammonium sulphate, potash,

sulphur coated urea, triple superphosphate, urea.

INCOMPATIBILITY

TITAN CHLORPYRIFOS 500 Termiticide and Insecticide is NOT compatible with the

following:

Herbicides

2,4-D, Dicamba, MCPA, Tordon* 75-D, Tordon*242.

Fungicides

Fixed coppers, liquid and organic coppers, wettable sulphur.

Fertilisers

Iron sulphate, manganese sulphate, zinc oxysulphate.

Resistance Warning:

INSECTICIDE RESISTANCE WARNING

For insecticide resistance management TITAN Chlorpyrifos 500 Termiticide & Insecticide

is a Group 1B insecticide. Some naturally occurring insect biotypes resistant to TITAN

Chlorpyrifos 500 Termiticide & Insecticide and other Group 1B insecticides may exist

through normal genetic variability in any insect population. The resistant individuals

can eventually dominate the insect population if TITAN Chlorpyrifos 500 Termiticide &

Insecticide or other Group 1B insecticides are used repeatedly. The effectiveness of TITAN

Chlorpyrifos 500 Termiticide & Insecticide on resistant individuals could be significantly

reduced. Since occurrence of resistant individuals is difficult to detect prior to use, TITAN

AG Pty Ltd accepts no liability for any losses that may result from the failure of TITAN

Chlorpyrifos 500 Termiticide & Insecticide to control resistant insects. TITAN Chlorpyrifos

500 Termiticide & Insecticide may be subject to specific resistance management strategies.

For further information contact your local supplier or TITAN AG representative.

Precautions:

PRECAUTIONS

DO NOT apply inside buildings except as a crack and crevice treatment. DO NOT apply to

surface areas such as interior floors or walls.

DO NOT permit re-occupancy of any premises until treated areas are completely dried

(normally 3-4 hours) and adequately ventilated

THIS PRODUCT IS TOO HAZARDOUS FOR USE BY HOUSEHOLDERS. DO NOT USE

THIS PRODUCT IN OR AROUND THE HOME

RE-ENTRY TO TREATED AREAS

Field crops, tree crops and vines: DO NOT allow entry into treated crops until spray

deposits have dried. If prior entry is required, limit duration of entry and wear cotton overalls

buttoned to the neck and wrist (or equivalent clothing) and chemical resistant gloves.

Clothing must be laundered after each day's use.

Cotton chippers: DO NOT allow entry into treated crops until spray deposits have dried.

After this time, wear shoes or boots, socks, long trousers, long sleeved shirt, gloves and

hat.

Protections:

PROTECTION OF WILDLIFE, FISH, CRUSTACEANS AND ENVIRONMENT

HIGHLY TOXIC TO BIRDS AND REPTILES. VERY HIGHLY TOXIC TO FISH AND

AQUATIC INVERTEBRATES. DO NOT re-apply to the same crop within 7 days (unless

specifically recommended in the Directions for Use). Spray drift may occur under adverse

meteorological conditions or from certain spray equipment. DO NOT allow spray to drift

onto sensitive areas including, but not limited to, natural streams, rivers or waterways

and human dwellings. A spray drift management strategy such as those in the "Best

Management Practices Manual for Cotton Growers" or the "Pilots and Operators Manual"

should be applied. Options for minimising drift to sensitive areas include not spraying within

a certain distance of sensitive areas when the wind is blowing towards them (see Table for

guidance) or ensuring that drifting spray will be intercepted by a catching surface such as a

row of shelter trees, an unsprayed row of orchard trees, or hail netting.

Situation Rate (L/ha) Recommended Buffer Distance (m)

Orchard

(dormant trees, citrus, large trees) <4 30

4-8 40

>8 50

Cotton (aerial application) – 300

Other crops (aerial application) – 100

DO NOT apply if heavy rains or storms that are likely to cause surface run-off are forecast

in the immediate area within two days of application.

DO NOT apply when irrigating, or to waterlogged soil, or while water remains on the

surface or in furrows, unless tail water is captured on farm.

DO NOT allow contaminated run-off water from treated paddocks to enter adjacent areas or

water bodies. Run-off contaminated by irrigation events (tail water) and a 25mm rainstorm

should be captured on farm for two days after application.

DO NOT contaminate streams, rivers or waterways with chemical or used container.

PROTECTION OF LIVESTOCK

DO NOT feed grass clippings to poultry or other animals. Dangerous to bees. DO NOT

spray any plants in flower while bees are foraging.

Storage and

Disposal:

SMALL SPILL MANAGEMENT

Wear appropriate clothing and protective equipment whilst cleaning up small spills (see

SAFETY DIRECTIONS). Apply absorbent material such as earth, sand, cat litter or clay

granules to the spill. Sweep up contaminated material and contain in a refuse vessel

for disposal. If spilled inside a building, wash contaminated surfaces to deactivate the

chlorpyrifos with a dilute solution of bleach (sodium hypochlorite), prepared according to

the bleach label instructions. Dispose of the contaminated material in accordance with

STORAGE AND DISPOSAL instructions below.

STORAGE AND DISPOSAL

Store in the closed, original container in a cool, well-ventilated area. Do not store for

prolonged periods in direct sunlight. Triple-rinse containers before disposal. Add rinsings

to spray tank. Do not dispose of undiluted chemicals on site. If recycling, replace cap and

return clean containers to recycler or designated collection point.

If not recycling, break, crush, or puncture and deliver empty packaging to an approved

waste management facility. If an approved waste management facility is not available,

bury the empty packaging 500 mm below the surface in a disposal pit specifically marked

and set up for this purpose, clear of waterways, desirable vegetation and tree roots, in

compliance with relevant local, state or territory government regulations. Do not burn empty

containers or product.

Refillable containers

Empty contents fully into application equipment. Close all valves and return to [point of

supply/designated collection point/other specific collection details] for refill or storage.

Safety Directions:

SAFETY DIRECTIONS

Product is poisonous if absorbed by skin contact, inhaled or swallowed. Repeated exposure

may cause allergic disorders. Repeated minor exposure may have a cumulative poisoning

effect. Will irritate the eyes and skin. Avoid contact with eyes and skin. DO NOT inhale

vapour or spray mist. When opening the container, preparing the spray and using the

prepared spray, wear chemical resistant clothing buttoned to the neck and wrist and

a washable hat, elbowlength PVC gloves, goggles, chemical resistant footwear and

a half facepiece respirator with combined dust and gas cartridge. If clothing becomes

contaminated with product, or wet with spray, remove clothing immediately. If product on

the skin, immediately wash the area with soap and water. If product is in the eyes, wash it

out immediately with water. After use and before eating, drinking, or smoking, wash hands,

arms and face thoroughly with soap and water. After each day’s use wash gloves, goggles,

respirator (and if rubber wash with detergent and warm water) and contaminated clothing.

First Aid Instructions:

FIRST AID

If swallowed, splashed on skin or in eyes, or inhaled, contact a Poisons Information Centre

(Phone Australia 13 11 26, New Zealand 0800 764 766) or a doctor at once. Remove any

contaminated clothing and wash skin thoroughly. If swallowed, activated charcoal may be

advised. Give atropine if instructed.

If in eyes, hold eyes open, flood with water for at least 15 minutes and see a doctor.

First Aid Warnings:

DIRECTIONS FOR USE AS A TERMITICIDE:

MANAGEMENT OF SUBTERRANEAN TERMITES (All States, except Tasmania)

RATES OF APPLICATION

IMPORTANT: TITAN CHLORPYRIFOS 500 Termiticide and Insecticide should be used as part of an overall termite management program as detailed

in Australian Standard Series AS 3660. A great deal of care is required to understand construction details of the building and to apply the product in a

manner which ensures a complete chemical soil barrier. Where necessary, the barrier may need to be re-applied under the building. Application

equipment

must be fitted with a flow meter and pressure regulator on the application device. The purpose of a chemical soil barrier is to impede and discourage

concealed termite entry into a structure. Barriers may still be bridged by termites, but their entry can then be more easily detected during routine

inspections. If a barrier is not complete or breached, then concealed termite entry may occur. It is often not possible to form a complete barrier around

existing structures in which case other termite management options and/or more frequent inspections will also need to be considered.

SITUATION

RATE

CRITICAL COMMENTS

Installing a chemical soil

barrier around and under

buildings

Horizontal Barriers:

100mL/m

Vertical Barriers:

2L/m

Horizontal Barriers: Use 100mL TITAN CHLORPYRIFOS 500 per 5L water and apply the

mixture (emulsion) at a rate of 5L/m

. Not to be used around homes, in residential areas, or in

public spaces or in publicly accessible commercial areas.

Vertical Barriers: Use 2L of TITAN CHLORPYRIFOS 500 per 100L of water and apply the

mixture at a rate of 100L/m

See APPLICATION VOLUME section in GENERAL INSTRUCTIONS for further information.

200mL/10L is equivalent to a 1% active ingredient emulsion.

See Service requirement in GENERAL INSTRUCTIONS for expected barrier life.

Installing a chemical soil

barrier around and under

buildings north of the

Tropic of Capricorn or

where Mastotermes

darwiniensis is a concern.

Horizontal Barriers:

200mL/m

Vertical Barriers:

4L/m

This is an optional high rate for use north of the Tropic of Capricorn, or where M darwiniensis is

a concern.

Horizontal Barriers: Not to be used around homes, in residential areas, or in public spaces or

in publicly accessible commercial areas. Use 200mL of TITAN CHLORPYRIFOS 500 per 5L of

water and apply the mixture (emulsion) at a rate of 5L/m

Vertical Barriers: Use 4L of TITAN CHLORPYRIFOS 500 per 100L of water and apply the

mixture at a rate of 100L/m

See APPLICATION VOLUME section in GENERAL INSTRUCTIONS for further information.

4L/100L is equivalent to a 2% active ingredient emulsion.

See Service requirement in GENERAL INSTRUCTIONS for expected barrier life.

Installing a chemical soil barrier

around new and

existing poles, e.g.

transmission and

building poles, fence

posts and palings.

200mL/10L of water

or creosote

Trench (preferred) or rod and puddle-treat backfill, ensuring a complete and continuous treated

soil barrier is provided around the pole or post, to a minimum depth of 300mm and minimum

width of 150mm. Use 100L of emulsion per m

of soil. In addition, infested poles may be drilled

near ground level and the cavity flooded with the emulsion. This allows seepage to form a

treated soil barrier.

Note: A 50mm gap between fence palings and soil will reduce termite attack and fungal decay.

Only soil in contact with palings should be treated.

Replenishment is recommended within 2 years north of the Tropic of Capricorn and 5 years in

other areas.

If the barrier is disturbed, or rain falls immediately after application, retreat to restore continuity

and completeness of the barrier.

Refer to Australian Standard Series AS 3660.

Treatment of termite nest or

colony

100mL/10L of water

.

Once the nest or colony has been located it should be broken open and flooded with emulsion.

This includes nests located in trees. When treating trees, addition of a wetting agent is

suggested.

Refer to Australian Standard Series AS 3660.

NOT TO BE USED FOR ANY PURPOSE, OR IN ANY MANNER, CONTRARY TO THIS LABEL UNLESS AUTHORISED UNDER

APPROPRIATE LEGISLATION

APPLICATION INSTRUCTIONS

APPLICATION EQUIPMENT

Hand Spraying

For hand spraying use a rose head shrouded nozzle operated at 170 kPa, with a flow meter and pressure regulator fitted to the hand-piece.

Treatment Beneath Concrete Slabs or Sealed Areas

Where it is not possible or practical to remove the slab to allow direct application to the soil, use a sub-slab injector fitted with multi-directional tip (eg.

a B&G or similar system) with a 5 degree upward angle (eg. 3 way or 4 way) operated at 170 kPa. Ensure a strong seal with the top of the drill hole to

avoid leakage. For the best distribution, the injector needs to be held vertically, at right angles to the slab, and rotated during the application through

90 degrees (if using a 4 way dispersion tip), or through 120 degrees (for a 3 way dispersion tip).

Injection into Soil

Where it is not possible or practicable to trench the soil; use a soil rod with a 3 or 4 way multi-directional tip (B&G, or similar) operated at 170 kPa. The

4 way tip needs to be rotated during the application through 90 degrees and the 3 way tip through 120 degrees.

APPLICATION VOLUME

To compensate for impervious soils such as heavy clay where application of 5L/m

would cause run-off, it may be necessary to apply a volume of

emulsion less than 5L/m

. When reducing the total volume of emulsion used, increase the concentration accordingly to match the label rate by mixing

the required amount of TITAN CHLORPYRIFOS 500 per m

in a lesser volume of water. DO NOT use emulsion volumes less than 2L for every square

metre to be treated.

Note: Use of emulsion volumes other than the recommended 5L/m

is only permitted when installing chemical barriers in exposed soil. It is not

permitted when injecting through the slab or into sealed areas.

Existing Structures

(a) Strategic Drilling Through Slab or Sealed Areas

For treatment of slabs when termites are entering the building through the slab, where reticulation systems do not exist, slab drilling and injection will

be required. In most cases, unless there is a known severe termite hazard, grid drilling of the slab is not required. Any such need is to be determined

by a licensed Pest Manager. Treatment needs to be made around the inside of all exterior walls to complete a termite barrier, along both sides of

interior wall partitions, around plumbing/electrical or piping entry points and along major cracks or expansion joints. When treating along major cracks

or expansion joints it is recommended that holes are drilled alternately on either side of the crack at the recommended drill hole spacings.

For a sand base or sandy soil, apply through a row of holes drilled no more than 300mm apart and 100-200mm out from the wall, crack or pipe. For a

clay base, apply through a row of holes drilled 150mm apart and 100mm from the wall, crack or pipe. Apply 10L of emulsion per linear metre and

ensure the holes are securely plugged after treatment.

(b) External Barriers

An external barrier should be installed around the perimeter of the building and should circumference all pipes and service facilities. External barriers

should be created by using either a vertical or horizontal barrier, as determined by the building construction type and adjoining ground level. An

external barrier is an essential part of the treatment when relying on a chemical soil barrier to provide the full termite management system

as per AS 3660.

An external horizontal barrier is only required when prevention of concealed vertical access by termites is necessary at the perimeter (eg, when

ground level is equal to the top of a slab, where the slab is also a barrier to concealed termite movement into the building). A vertical barrier is

required when prevention of concealed horizontal access is necessary (eg, where ground level is higher than building material vulnerable to

concealed horizontal entry by termites).

(i) Horizontal Barrier: Do not use horizontal barriers around homes or in residential areas, or in public spaces and publicly accessible

commercial areas. Use a rose head shower nozzle operated at 170 kPa to apply the required rate of 1.5L of the correctly diluted TITAN

CHLORPYRIFOS 500 per lineal metre (150mm wide) to soil loosened to a depth of approximately 80mm (see APPLICATION VOLUME section).

(ii) Vertical Barrier: The vertical barrier should be at least 150mm wide and should reach down to 50mm below the top of the footings. To achieve

this, trench to the top of the footings, and where this is not possible, a combination of trenching (preferably at least 300mm deep) and rodding into the

base of the trench may be necessary. Apply TITAN CHLORPYRIFOS 500 emulsion at 100L per cubic metre of backfill soil, this equates to 1.5L of

emulsion/linear metre of a trench 150mm wide and 100mm deep. Where the required vertical barrier is deeper than 100mm, ensure the same rate of

application for the extra volume of soil. Use a rose head shower nozzle operated at 170 kPa to flood the base of the open trench and also to treat the

backfill soil as it is replaced into the trench to ensure even distribution. Where rodding is necessary, rod before the trench is treated using the spacings

in the following table.

Rod Spacings:

HEAVY CLAY SANDS

CLAY LOAMS

SANDS

150mm

200mm

300mm

Insert the rod to the foundation foot as close as possible to the house wall ensuring the chemical is applied during insertion and withdrawal. (See

APPLICATION EQUIPMENT Section, Injection into Soil.)

(c) Suspended Floors

Install horizontal and vertical barriers as specified in Australian Standard Series AS 3660 to adjoin all substructure walls, stumps, piers, pipes and

wastes using the techniques described for external barriers around concrete slabs. (See Existing Structures section.)

DIRECTIONS FOR USE – AS AN INSECTICIDE

FRUIT AND VEGETABLES

CROPS

INSECT

STATE

RATE

WITHHOLDING

Period

CRITICAL COMMENTS

VOL/HA

VOL/100

L

WATER

Bananas

Banana Scab

Moth

Qld only

Aerial: 1 or

in a

minimum of

10L water

200mL.

Apply a

minimum

of 500L

water/ha

14 days

Apply from the first appearance of flower bell and

repeat as populations indicate until fingers are

exposed. Use high rate with onset of wet weather

and/or heavy insect pressure. Note: Burning

of young fruit may occur under poor drying

conditions

Banana Weevil

Borer

Qld, NSW,

ACT only

applicable

1 or 1.8 L

After removal of trash, apply 500-700mL of spray

depending on butt size, to the lower 30cm of the

butt and to the surrounding soil within a radius of

30cm, ensuring thorough coverage of butt

and suckers. Sub-tropical areas: Use high rate

for annual control of borers. Tropical areas: Use

high rate in September-November for initial spray

and a follow-up with low rate in February-April

should insect presence warrant a second

application.

Caterpillars

NSW, ACT

only

200 mL

Apply from the first appearance of flower bell and

repeat as populations indicate until fingers are

exposed. Use as ground application only, do not

apply by air

Carrots

Light Brown Apple

Moth

500 or 700

applicable

Not applicable

Apply when moths are first detected. Repeat at the

higher rate if there is a re-occurrence of infestation.

Cassava

Cutworm

Qld only

700 mL

Apply to seedlings and soil at base of seedlings,

when cutworm activity is observed.

Cole crops

including

cabbage,

cauliflower,

brussels

sprouts,

broccoli

Cabbage moth,

Cabbage white

butterfly,

Cabbage aphid,

Cluster caterpillar,

Cabbage cluster

caterpillar

NSW, ACT,

VIC,

TAS, SA,

ONLY

1.5 or 2L

150 or

200mL

5 days

Spray at 10 to 14 day intervals. Use high rate

under heavy pest

pressure.

Large plants: Use 1000L of spray/ha. To improve

spray coverage

add non-ionic wetting agents as recommended.

Corn earworm

Native budworm

Qld only

1.5 L

150 mL

Apply when pests first appear.

Large plants: Use 1000L of spray/ha.

Corn earworm

NSW, ACT,

VIC,

SA, WA

ONLY

1.5 or 2L

150 or

200mL

Apply at 10 to 14 day intervals. Use high rate

under heavy pest

pressure. Large plants: Use 1000L of spray/ha

Native budworm

NSW, ACT,

Vic, TAS,

SA, WA

only

Apply at 10 day intervals commencing when pests

first appear.

Apply at 7 day intervals under heavy pest

pressure.

Large plants: Use 1000L/ha

Wingless

Grasshopper

NSW, ACT,

Vic, TAS,

500 mL

50 mL

Spray areas of crop infested with grasshoppers.

Also apply as a

SA only

barrier across the line of advance, when

grasshoppers are

invading the crop.

Red-legged earth

mite, Blue oat mite

NSW, ACT

ONLY

140 or

300mL

applicable

Use higher rate for severe infestations. Headlands

and vegetation

surrounding the crop may also need to be sprayed

Cabbage,

Cauliflower

African Black

beetle

NSW, ACT

only

2 L (Boom

spray)

300 mL

(drench)

5 days

Boom spray: Apply in 500-1000L of water/ha at or

soon after planting as a 10-15cm band spray.

Drench: Apply 100mL of diluted spray to base of

each plant. Treat as soon as the first signs of

infestation are observed. Note: If attack is

prolonged, follow up boom spray or drench

treatment may be necessary.

Cucurbits

White flies

applicable

50 mL

Apply when pest is first detected. If required repeat

applications every 10-14 days

Ginger

Cutworm

Qld only

700-900 mL

applicable

Not applicable

Apply when pest population is evident from

damage to the primary shoot at or below ground,

or to the first leaf during growth.

Kiwifruit

Common

armyworm,

Southern

armyworm,

Light brown apple

moth

NSW, ACT,

VIC,

WA, SA,

TAS,

QLD ONLY

50 mL

14 days

Apply at green tip at least 10 days after dormant

lime sulphur application and pre-blossom. Do not

apply post-blossom.

Pineapples

Pineapple mealy

bug, ants

Qld only

applicable

50 or 100

Not applicable

Apply when pests are first seen and repeat at 90

day intervals or as necessary. Use a minimum of

3000L of spray/ha. Use higher rate under heavy

pest pressure

White grubs

applicable

Apply as a pre-plant spray to a freshly cultivated

soil surface. Incorporate immediately by rotary

hoeing to a depth of 10-20 cm

Potatoes

African black

beetle

NSW, ACT,

ONLY

3 or 6L

Apply the spray to the soil immediately prior to

planting, ensuring thorough immediate

incorporation to a depth of 15cm. Use higher

rate under heavy pest pressure.

900 mL

Apply as a second spray as bands on either side of

plants at final hilling-up. Ensure good incorporation

of the spray immediately into the soil in the hill.

Whitefringed

weevil

NSW, ACT,

VIC,

WA ONLY

Apply pre-plant and incorporate into the soil

immediately after application.

WA, NSW,

ACT only

Apply at hilling-up or 7 weeks after planting as a

follow-up to preplant incorporation

Wireworm

VIC only

Apply as a band spray to the soil surface

incorporating immediately. Use before planting in

areas where wireworms are a known problem

Silver Beet

Redlegged earth

mite,

Blue oat mite

NSW, ACT

ONLY

140 or

300mL

applicable

Not applicable

Use higher rate for severe infestations. Headlands

and vegetation surrounding the crop may also

need to be treated.

Strawberries

Field crickets,

Mole crickets

QLD ONLY

100mL/10kg

bran

bait/ha

Apply in recently ratooned strawberry patches or

newly planted runners when damage or pest

populations indicate. Broadcast, preferably in the

late afternoon, to base of plants and inter-row

space. See General Instructions on preparation

of bran baits

Tomatoes

Wingless

Grasshopper

NSW, ACT,

VIC, SA,

TAS ONLY

500mL

50mL

Spray areas of crop infested with grasshoppers.

Also apply as a barrier across the line of advance,

when grasshoppers are invading the crop.

Wireworm

False Wireworm

QLD ONLY

5L/ha

sprayed

applicable

Apply as a band at least 10cm wide into the open

furrow at planting. Spray the entire furrow width

using a nozzle directly behind the planting tine.

Use a minimum spray volume of 20L/ha.

See General Instructions on soil application.

African Black

Beetle

NSW, ACT

ONLY

2L (Boom

Spray)

300mL

(Drench)

Boom spray: Apply in 500-1000L of water/ha at or

soon after planting as a 10-15cm band spray.

Drench: Apply 100mL of diluted spray to base of

each plant. Treat as soon as first sign of infestation

is noticed. Note: If attack is prolonged, follow-up

boom spray or drench treatment may be

necessary.

Tomato grubs

QLD, NSW,

ACT, VIC,

ONLY

1.5 or 2L

150 or

200mL

3 days

Spray on 7 to 10 day schedule commencing at

flowering. Use high rate under heavy pest pressure

Native Budworm

TAS only

Green Vegetable

TAS, SA,

WA only

Spray at first sign of bug activity. Use higher rate

under heavy pest pressure.

Green Peach

Aphid

QLD, VIC,

TAS,

SA, WA

ONLY

100 mL

Spray when aphids are seen.

Large plants: Use 1000L/ha.

Vegetables

including

asparagus,

beans,

beetroot,

broccoli,

brussels

Wingless

Grasshopper

NSW, ACT,

VIC, TAS

only

500 mL

50 mL

Tomatoes

3 days

Cole crops

5 days

Asparagus,

celery

– 14 days

Spray areas of crop infested with grasshoppers.

Also apply as a barrier across the line of advance,

when grasshoppers are invading the crop.

Cutworm

STATES

700 mL

70 mL

Apply immediately infestation is observed.

Increase concentration to compensate if

application is below 1000L/ha. Spray should

cover soil out to at least 20cm on both sides of row

sprouts,

cabbage,

cauliflower,

capsicum,

carrot,

celery,

eggplant,

onion, peas,

potato,

radish,

rhubarb,

shallot,

sweet

potato,

tomato,

turnip

crop.

Field crickets,

Mole crickets

QLD ONLY

100mL/10kg

bran

bait/ha

applicable

Apply as pest populations indicate. See General

Instructions on preparation of bran baits

Vegetable weevil

NSW, ACT

ONLY

800mL

Apply immediately infestation is observed. Apply

as a band over the young plants and adjacent soil

along the row. One treatment should be sufficient if

plants are sprayed at the seedling stage or soon

afterwards

Apples,

Pears

San Jose scale

QLD, NSW,

ACT, SA,

ONLY

applicable

100 mL

miscible

winter oil

may be

added to

dormant

spray)

14 days

Dormant period: Apply as late as possible

ensuring thorough coverage of all branches.

Seasonal period: Apply to coincide with crawler

activity in mid-late November and later as

necessary. Ensure thorough coverage of all

branches, foliage and fruit.

Woolly aphid

Apply when infestation build-up is first noticed

ensuring thorough coverage.

Wingless

Grasshopper

NSW, ACT

ONLY

500 mL

50 mL

Apply to areas of crop infested with grasshoppers.

Also apply as a barrier across the line of advance,

when grasshoppers are invading the crop

Avocado

Avocado leafroller

QLD ONLY

1 or 2L

50 or

100mL

7 days

Use this rate in tank mix with 1L/ha (500mL/100L

of water) of dichlorvos (500g/L). For the low

volume spray equipment use L/ha rate. Apply at

first sign of pest activity before larvae move to

fruit. Use higher rate when populations are high

Ivy leafroller

NSW, ACT

ONLY

Apply at first sign of pest activity before larvae

move to fruit. Use higher rate when populations

are high. For low volume spray equipment use

L/ha rate

Latania scale,

Hairy caterpillars,

Light brown apple

moth,

Red shouldered

leaf

beetle

Apply when populations indicate treatment is

required. Spotspray affected trees only. Repeat as

necessary. Use higher rate when populations are

high.

Citrus

California red

Scale

NSW, ACT,

VIC,

WA, SA,

TAS only

applicable

100mL

alone or

50mL + 1L

miscible

summer

spraying oil

14 days

Apply during November-March period. Two sprays

may be required under conditions of heavy scale

infestation. Apply with high volume sprayer to point

of run-off.

Note: Do not use on citrus in areas where

integrated control programmes are in operation

Qld only

ONLY

100mL

alone or

100mL +

miscible

summer

spraying oil

Citrus,

Pome Fruits

Wingless

grasshopper

VIC,TAS,

SA only

500 mL

50 mL

Spray areas of crop infested with grasshoppers.

Also apply as a barrier across the line of advance,

when grasshoppers are invading the crop.

Grapevines

Light brown apple

moth

ALL States

500 mL

50 mL

Apply initial spray just after berry set (early

October). Later schedule sprays should be made

as required

Grapevine moth

Qld, NSW,

ACT, TAS,

SA, WA

only

Grapevine Scale

applicable

100mL

alone or

50mL + 1L

miscible

winter oil

Apply as a dormant spray, post-pruning (July).

Kiwifruit –

trellised

Common

armyworm,

Southern

armyworm,

Light brown apple

moth

NSW, ACT,

VIC,

WA, SA,

TAS,

QLD ONLY

50 mL

Apply at green tip at least 10 days after dormant

lime sulphur application and pre-blossom. Do not

apply post-blossom

Mango

Common mango

scale

QLD ONLY

applicable

100mL

21 days

Apply to coincide with crawler activity. Ensure

thorough coverage of all branches, foliage and fruit

Stonefruit

European earwig

NSW, ACT

ONLY

100 mL

14 days

Spray application: Apply in a minimum of

2000L/ha in spring. If lower volume used, increase

concentration to apply 2L of product/ha

200mL +

250mL

sunflower

oil/

5kg cracked

wheat

or cracked

Bait application: Apply 5kg of bait/ha in spring by

fertiliser spreader. See General Instructions on

preparation of cracked wheat or cracked sorghum

bait

sorghum

bait

San Jose Scale

QLD, WA,

NSW, ACT

ONLY

applicable

100mL (2%

miscible

winter oil

may be

added to

dormant

spray)

Dormant period: Apply as late as possible

ensuring thorough coverage of all branches.

Seasonal period: Apply to coincide with crawler

activity in mid-late November and later if

necessary.

Ensure thorough coverage of all branches, foliage

and fruit.

Note: Some fruit marking may occur if high volume

spraying is carried out under hot, dry conditions

Tomatoes –

trellised

Wingless

grasshopper

NSW, ACT,

VIC,

TAS, SA

ONLY

500mL

50mL

3 days

Spray areas of crop infested with grasshoppers.

Also apply as a barrier across the line of advance,

when grasshoppers are invading the crop

Wireworm,

False wireworm

QLD ONLY

5L/ha

sprayed

applicable

Not applicable

Apply as a band at least 10cm wide into the open

furrow at planting. Spray the entire furrow width

using a nozzle directly behind the planting tine.

Use a minimum spray volume of 20L/ha.

See General Instructions on soil application.

African black

Beetle

NSW, ACT

only

2 L (Boom

spray)

300 mL

(drench)

Boom spray: Apply in 500-1000L of water/ha at or

soon after planting as a 10-15cm band spray.

Drench: Apply 100mL of diluted spray to base of

each plant. Treat as soon as first sign of

infestation is noticed. Note: If attack is prolonged,

follow-up boom spray or drench treatment may be

necessary

Tomato grubs

NSW, ACT,

QLD, VIC,

WA ONLY

1.5 or 2 L

150 or 200

3 days

Spray on 7 to 10 day schedule commencing at

flowering. Use high rate under heavy pest pressure

Native budworm

TAS ONLY

Green vegetable

TAS, SA,

ONLY

Spray at first sign of bug activity. Use higher rate

under heavy pest pressure

Green peach

aphid

QLD, VIC,

TAS,

SA, WA

ONLY

100mL

Spray when aphids are seen.

Large plants: Use 1000L/ha.

FIELD CROPS AND PASTURE

CROPS

INSECT

STATE

VOL/HA

WITHHOLDING

PERIODS

CRITICAL COMMENTS

Canola

(rapeseed)

Wireworm,

False wireworm

QLD ONLY

1 or 1.5L/ha

Not applicable

Apply as a broadcast application. Use higher rate with

extreme population numbers.

See General Instructions on soil application

Cereals,

Pasture,

forage crops

Southern

armyworm,

Common

armyworm

STATES

700 or

900mL

Cereals - 10 days

Grazing - 2 days

Spray over total crop area when infestation is widespread.

When pests are moving as an “army”, treat a broad strip over

and in advance of the infestation. Late stage instar:

Use higher rate when larvae 3cm in length. Apply follow-up as

required.

Cereals

Pasture webworm

NSW,

ACT, VIC,

TAS,

SA ONLY

700 mL

Spray at first sign of damage. Apply with ground-rig boom or

mister or by air.

WA only

300 mL

Pre-plant: Apply with the label rate of an approved tillage

herbicide to foliage prior to

any cultivation.

Post-emergence: Apply at first sign of damage. Apply with

ground-rig boom or

mister or by air.

Cereals,

Pasture,

young

plants of oil

seeds

Cutworm

QLD, NSW,

ACT, TAS,

ONLY

900mL in a

minimum of

100L

water

Apply immediately infestation is observed. Apply follow-up

treatments as required.

VIC ONLY

700mL in a

minimum of

100L

water

Cereals,

pasture, oil

seeds

Cutworm (Agrotis

munda and A.

infusa)

SA ONLY

Cereals,

Cereal curculio

SA, WA

ONLY

120mL/

100kg seed

Not applicable

Apply as a seed dressing just prior to sowing through an

accurately calibrated

applicator. Note: A sowing rate of 95kg/ha (min.) is necessary

to ensure economic

responses are achieved.

Cereals,

pasture,

forage crops

Spur-throated

locust

Qld, NSW,

ACT, VIC,

WA ONLY

1.25 or 1.5 L

Cereals 10 days

Grazing – 2 days

Spray areas of crop or pasture infested with locusts. Apply

spray to trees or roosting sites to control swarming adult

locusts.

Late stage hoppers and adults: Use higher rate.

Australian Plague

Locust

VIC only

560 mL

Adults: Spray areas of crop or pasture infested with locusts.

350 mL

Hoppers: Spray a swath in advance of marching band and

then spray along the dense marching front. Continue spraying

until all hoppers have been contacted

SA only

560 mL

Adults: Spray areas of crop or pasture infested with locusts.

Hoppers: Spray a swath in advance of marching band and

then spray along the dense marching front. Continue spraying

Qld, NSW,

ACT, VIC,

350 mL

WA ONLY

until all hoppers have been contacted

Migratory locust

Qld only

Spray areas of crop, trees and roosting sites infested with

locusts

Blue oat mite

All states

140 mL

Spray when pests appear in large numbers, 3-6 weeks after

autumn rains.

Re-spray as necessary. Avoid spraying when pests are

sheltering. Spray when at least 2.5cm cover of pasture or crop

is present. DO NOT spray if rain is imminent

Red legged earth

mite

NSW, ACT,

VIC, WA,

TAS, SA

ONLY

Lucerne Flea

70 mL

Cereals,

pasture,

oilseeds

Wingless

grasshopper

NSW, ACT,

VIC,

TAS, SA

ONLY

500mL

Spray area of crop or pasture infested with grasshoppers.

Apply also as a barrier across the line of advance, when

grasshoppers are invading the crop

Field Peas,

broad beans,

chickpeas,

lupins,

lucerne,

lucerne

pastures

and clover

seed

crops,

rapeseed,

linseed,

safflower,

wheat, oats,

barley, rye,

triticale.

Improved

annual

pastures,

establishing

perennial

pastures.

Blue oat mite,

Redlegged earth

mite

NSW, ACT

ONLY

140-300 mL

Apply as a ground spray immediately prior to seedling

emergence using sufficient water to give good coverage. If

mite activity is severe, also spray headlands and

surrounding vegetation prior to seedling emergence.

Cotton (young

plants)

Cutworm

Qld, NSW,

ACT only

900mL in

a minimum

100L water

4 weeks (harvest)

4 weeks (grazing)

Apply immediately infestation is observed. Apply follow-up

treatments as required.

Cotton

Southern

armyworm,

Common

armyworm

700 mL or

900 mL

Spray over total crop area when infestation is widespread.

When pests are moving as an “army” treat broad strip over

and in advance of the infestation.

Late stage instar: Use higher rate when larvae 3cm in length.

Apply follow-up treatments as required.

Pink spotted

bollworm

moth

Qld only

Apply when 10-15 moths are trapped on two consecutive

nights. This prevents infestation of bolls by larvae.

Spur-throated

locusts

Qld, NSW,

ACT only

1.25 or 1.5 L

Spray areas of crop infested with locusts. Apply spray to trees

or roosting sites to control swarming adult locusts Late stage

instar: Use higher rate.

Wingless

Grasshopper

500 mL

Spray areas of crop infested with grasshoppers. Apply also as

a barrier across the line of advance when grasshoppers are

invading the crop.

Cotton aphid

300 or 400

Apply when pests first appear. Re-spray as indicated by field

inspection. Use higher rate for higher populations.

Cotton flea beetle,

Red shouldered

leaf

Beetle

900 mL or

1.5 L

Apply when pests are present. Use higher rate under heavy

pest pressure.

Springtails

300 mL

Spray when large numbers of pests occur and damage is

evident. Re-spray as

necessary.

Migratory locust

Qld only

350 mL

Spray areas of crop infested with locusts. Apply spray to trees

or roosting sites to

control swarming adult locusts

Wireworm,

False wireworm

Qld, NSW,

ACT only

In-furrow:

5 to

15mL/100m

row or

500mL to

1.5L/ha for

spacing of 1

metre

Use higher rate with extreme population numbers. See

General Instructions on soil

application.

Lucerne

(young plants)

Cutworm

QLD, NSW,

ACT, TAS,

WA ONLY

900mL in

a minimum

100L water

Grazing – 2 days

Apply immediately infestation is observed. Apply follow-up

treatments as required.

Vic only

700mL in

a minimum

100L water

Cutworm (Agrotis

munda and A.

infusa)

SA only

Lucerne

Webspinner

caterpillar

Qld, NSW,

ACT only

700 mL

Spray when pests appear

Lucerne leaf roller

300 or 400

Apply when pests first appear.

Late stage instar: Use higher rate when larvae 1.5cm in

length are present and/or under heavy pest pressure.

Lucerne and

medics in

pasture and

forage crops

Spotted alfalfa

aphid,

Bluegreen aphid

NSW, ACT

only

200 or 300

Spray when aphids first appear. Use the higher rate when

large numbers of aphids are invading the crop

QLD, VIC,

TAS,

Seeding lucerne, medics: Apply when 1-2 aphids/plant are

observed.

SA, WA

ONLY

Established lucerne, medics: Apply when 20-40

aphids/stem are observed.

Pea aphid

QLD, NSW,

ACT, VIC,

TAS,

SA ONLY

Sitona weevil

NSW, ACT,

VIC,

TAS, SA

ONLY

350 mL

Apply October to December, or in autumn when adults occur

in damaging numbers

Maize

African Black

Beetle

NSW, ACT

only

20mL/100m

of row

or 2L/ha for

spacing of 1

metre

Not applicable

Apply at sowing as a 15-20cm band spray. For best results

spray nozzles should be in front of press wheels on planter.

Press wheels assist in establishment

Maize,

soybeans,

sunflower

False wireworm,

Cockroaches,

Field crickets

Qld only

100mL +

125mL

sunflower

oil/

2.5kg

cracked

wheat or

cracked

sorghum

bait/ha

Apply at planting of crop.

See General Instructions on preparation of cracked wheat or

sorghum bait.

Maize,

Sunflower

Wireworm,

False wireworm

Qld, NSW,

ACT only

In-furrow: 5

15mL/100m

or 500mL to

1.5L/ha for

spacing of 1

metre

Use higher rate with extreme population numbers. See

General Instructions on soil

application

Pasture

Lawn armyworm

700 mL

Grazing-2 days

Spray over total crop area when infestation is widespread.

When pests are moving as an “army” treat a broad strip over

and in advance of the infestation. Apply follow-up treatments

as required.

Sod webworm

Qld only

Spray as early as possible once pests appear. Apply with

ground-rig boom or mister.

Re-spray as necessary

Blackheaded

pasture

cockchafer

NSW, ACT,

VIC,

TAS, SA,

ONLY

900 mL

Treat when larvae are actively foraging as indicated by

numerous piles of fresh soil, or casts on the surface. This

usually occurs after showers of rain following short dry

spells. Apply by ground-rig boom.

Pasture,

forage crops

Underground

Grass grub

NSW, ACT,

VIC,

SA, WA

ONLY

Apply when caterpillars are actively feeding. Spray before

noticeable damage has occurred. Graze pasture prior to

spraying to ensure penetration of spray into the

pasture sward.

Brown Pasture

Looper

NSW, ACT,

VIC,

TAS, SA,

ONLY

700 mL

Spray at first sign of pasture infestation

Pasture webworm

Spray at first sign of damage. Apply with ground-rig boom or

mister or by air.

Rice

Bloodworm

NSW,

ACT ONLY

60 to 150

10 days

Use higher rate when water more than 15cm or amount of

decaying plant material is high

Brown planthopper

QLD only

1.5 L

Apply when pest numbers reach 1-2 per tiller and repeat as

necessary.

Sorghum

Note: (DO

NOT

use on Sugar

Drip or Alpha

sorghum.

Check new

varieties

before

applying to

entire crop.)

Southern

armyworm,

Common

armyworm

QLD, NSW,

ACT ONLY

700 or

900mL

2 days

Spray over total crop area when infestation is widespread.

When pests are moving as an “army” treat a broad strip over

and in advance of the infestation. Late stage instar:

Use higher rate when larvae 3cm in length. Apply follow-up

treatments as required.

Cutworm

900mL in

a minimum

100L water

Apply immediately infestation is observed. Apply follow-up

treatments as required

Spur-throated

locust

1.25 or 1.5L

Spray areas of crop infested with locusts. Apply spray to trees

or roosting sites to control swarming adult locusts.

Late stage instar: Use higher rate.

Australian Plague

Locust

350 mL

Adults: Spray areas of crop infested with locusts. Hoppers:

Spray a swath in advance of marching band and the dense

marching front. Continue spraying until all hoppers have been

contacted.

Migratory locust

Qld only

Spray all areas of crop, trees and roosting sites infested with

locusts

Sorghum Midge

500 mL

Check regularly (preferably in the morning) and apply when 1-

2 midge per head are present from first emergence of boot to

pollen shedding. With repeated attack spray at intervals of 5

days or less.

Wireworm,

False wireworm

Qld, NSW,

ACT ONLY

In-furrow:

5 to

15mL/100 m

row or

500mL to

1.5L/ha for

spacing of 1

metre

Not applicable

Use high rate with extreme population numbers. See General

Instructions on soil application.

Corn aphid

500 mL

2 days

Apply when damaging populations of aphids occur.

False wireworm,

Cockroaches,

Field crickets

QLD ONLY

100mL +

125mL

sunflower

oil/

2.5kg

cracked

wheat or

cracked

sorghum

bait/ha

Grazing - 2 days

Apply at planting of crop.

See General Instructions on preparation of cracked wheat or

cracked sorghum bait.

Sugarcane

Southern

Armyworm

Common

Armyworm

700 or 900

7 days

Grazing - 2 days

Spray over total crop area when infestation is widespread.

When pests are moving as an “army” treat a broad strip over

and in advance of the infestation.

Late stage instar: Use higher rate when larvae 3cm in length.

Apply follow-up treatments as required.

Spur-throated

locust

1.25 or 1.5 L

7 days

Grazing - 2 days

Spray areas of crop infested with locusts. Apply spray to trees

or roosting sites to control swarming adult locusts. Late stage

hoppers and adults: Use higher rate.

Australian plague

locust,

Migratory locust

Qld only

350 mL

Adults: Spray areas of crop infested with locusts.

Hoppers: Spray a swath in advance of marching band and

then spray along the dense marching front. Continue spraying

until all hoppers have been contacted. Spray areas

of crop, trees and roosting sites infested with locusts.

Symphylids

Apply as a low pressure (less than 35 kPa) or gravity feed

spray onto the plant sett and adjacent to soil, at the point of

exit from the rear of the planting machine, immediately

prior to soil cover being brought in over the sett.

Sugarcane

wireworm

Qld, NSW,

ACT ONLY

1.5 L

African black

beetle,

Black beetle

NSW,

ACT ONLY

Apply at planting or ratooning. Apply as a low pressure (less

than 35 kPa) or gravity feed spray onto the plant sett and

adjacent soil through a nozzle placed above the planter

boards. Repeat treatment within 12 weeks of planting if black

beetles re-occur

Tobacco

Wireworm,

False wireworm,

Cutworm

VIC ONLY

3.0L

Not applicable

Apply as a pre-plant spray to cultivated soil surface.

Incorporate immediately by rotary

hoeing to a depth of 10cm.

GENERAL PEST CONTROL

RESTRAINTS

DO NOT spray polycarbonate surfaces/roof sheeting or aged vinyl wall cladding as solvent may cause etching.

Do not

use around homes or in residential areas, or in public spaces and publicly accessible commercial areas.

SITUATION

PEST

RATE

CRITICAL COMMENTS

Commercial and industrial areas not

accessible to the public.

Cockroaches (residual control and/or

heavy infestations)

95mL/10L of water

Apply as a coarse, low pressure

spray to the point of run-off, to

cracks, crevices, harbourages,

eaves, downpipes and other places

where pests may occur.

For optimum control of webbing

spiders, use a 2-part treatment. After

applying as a coarse, low pressure

spray to harbourages where the

spiders may occur, apply a light

spray over surfaces of the building

Spiders

Silverfish

50 mL/10L of water

Cockroaches (light infestations)

Ants including Argentine ants

95mL/10L of water.

Use at least 1L spray/

infested area

Locate ant nests and treat

appropriately. Spray ant tracks or

where ant activity is noticed. Apply to

paths in continuous 300mm bands.

Apply to base of buildings, walls,

fences, rock-works, trunks of shrubs

and trees, and other hard surfaces to

a height of 300mm.

Note: All occurrences of Argentine

Ants are to be reported to WA

Department of

Agriculture

Fleas (outdoor use only)

90mL/10L of water

Apply as a fine droplet spray.

Outdoors only. Treat areas where

animals frequent.

Remove animals during treatment

and until spray deposit is dry.

Do not treat pets with this product.

Pets should be treated with a

product registered

for application to animals.

Hides/skins

Hide beetles

200mL/100L of water.

Use at least 30mL of

spray/skin

Apply spray to flesh side of skins or

hides sufficient to moisten them.

Ensure coverage of ears and lugs.

To minimise the chance of later

infestations, storage area should be

sprayed regularly. Repeat application

every 3 months. Access through

bales should be maintained for

application of product.

Light vegetation not around homes or

in residential areas, or in public

spaces and publicly accessible

commercial areas.

Mosquito larvae

30mL/ha

Dilute with water and apply as a

spray to areas infested with

mosquitoes.

Medium vegetation not around

homes or in residential areas, or in

public spaces and publicly accessible

commercial areas.

60mL/ha

Heavy vegetation not around homes

or in residential areas, or in public

spaces and publicly accessible

commercial areas.

105mL/ha

Light to medium

Vegetation not around homes or in

residential areas, or in public spaces

and publicly accessible commercial

areas.

Mosquito adults

60mL/ha

Medium to heavy

Vegetation not around homes or in

residential areas, or in public spaces

and publicly accessible commercial

areas.

105mL/ha

Polluted water

impoundments

Mosquitoes (larvae and adults)

2mL/10,000L water or

20mL/100m

of water

NOT TO BE USED FOR ANY PURPOSE, OR IN ANY MANNER, CONTRARY TO THIS LABEL UNLESS AUTHORISED UNDER

APPROPRIATE LEGISLATION

Page 1/7

SAFETY DATA SHEET

According to Safe Work Australia

Printing date 01.11.2016

Revision: 01.11.2016

43.0

1

. IDENTIFICATION: PRODUCT IDENTIFIER AND CHEMICAL IDENTITY

Product Name: CHLORPYRIFOS 500 TERMITICIDE & INSECTICIDE by TITAN

Other Means of Identification:

Mixture

Recommended Use of the Chemical and Restriction on Use:

Agricultural insecticide

Details of Manufacturer or Importer:

Titan Ag Pty Ltd

15/16 Princes Street

Newport NSW 2106

Phone Number:

02 9999 6655

Emergency telephone number:

02 9999 6655

2

. HAZARDS IDENTIFICATION

Hazardous Nature:

Classified as Hazardous according to the Globally Harmonised System of Classification and Labelling of

Chemicals (GHS) and Safe Work Australia criteria.

Classified as Dangerous Goods according to the Australian Code for the Transport of Dangerous Goods by

Road and Rail (7th edition).

skull and crossbones

Acute Toxicity (Oral) 3

H301 Toxic if swallowed.

Acute Toxicity (Dermal) 3 H311 Toxic in contact with skin.

environment

Aquatic Acute 1

H400 Very toxic to aquatic life.

Aquatic Chronic 1

H410 Very toxic to aquatic life with long lasting effects.

Flammable Liquids 4

H227 Combustible liquid.

Signal Word

Danger

Hazard Statements

H227

Combustible liquid.

H301+H311 Toxic if swallowed or in contact with skin.

H410

Very toxic to aquatic life with long lasting effects.

Precautionary Statements

P210

Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

P280

Wear protective gloves/protective clothing/eye protection/face protection.

P273

Avoid release to the environment.

P264

Wash hands thoroughly after handling.

P270

Do not eat, drink or smoke when using this product.

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor.

P321

Specific treatment (see on this label).

P312

Call a POISON CENTER/doctor if you feel unwell.

P330

Rinse mouth.

P370+P378 In case of fire: Use for extinction: CO2, powder or water spray.

P302+P352 IF ON SKIN: Wash with plenty of water.

P391

Collect spillage.

P361+P364 Take off immediately all contaminated clothing and wash it before reuse.

(Contd. on page 2)

Page 2/7

SAFETY DATA SHEET

According to Safe Work Australia

Printing date 01.11.2016

Revision: 01.11.2016

Product Name: CHLORPYRIFOS 500 TERMITICIDE & INSECTICIDE by TITAN

(Contd. of page 1)

43.0

P405

Store locked up.

P403+P235 Store in a well-ventilated place. Keep cool.

P501

Dispose of contents/container in accordance with local/regional/national regulations.

3

. COMPOSITION AND INFORMATION ON INGREDIENTS

Chemical Characterization: Mixtures

Description:

Mixture of substances listed below with nonhazardous additions.

Hazardous Components:

2921-88-2 Chlorpyrifos (ISO)

Acute Toxicity (Oral) 3, H301;

Aquatic Acute 1, H400; Aquatic Chronic 1, H410

Additional information:

Liquid Hydrocarbon (A), CAS No. not supplied: 474 g/L

Liquid Hydrocarbon (B), CAS No. not supplied: 488 g/L

4

. FIRST AID MEASURES

Inhalation:

If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.

Seek medical attention if breathing problems develop.

Skin Contact:

In case of skin contact, immediately remove contaminated clothing and wash affected areas with water and

soap. Seek medical attention if symptoms occur.

Eye Contact:

In case of eye contact, hold eyelids open and rinse with water for at least 15 minutes. Seek medical attention

if symptoms occur.

Ingestion:

If swallowed, do not induce vomiting. Immediately rinse mouth with water. Give a glass of water. If vomiting

occurs spontaneously, keep head below hips to prevent aspiration. Do not give anything by mouth to an

unconscious person. Seek immediate medical attention.

Symptoms Caused by Exposure:

Inhalation: May cause symptoms similar to ingestion.

Skin Contact: May cause symptoms similar to ingestion.

Eye Contact: May cause eye irritation, stinging, reddening and watering.

Ingestion: Toxic if swallowed. May cause numbness, tingling sensations, incoordination, headache, dizziness,

nausea, abdominal cramps, excessive sweating and salivation, blurred vision, respiratory depression,

unconsciousness, incontinence, convulsions, fatigue, slowed heart rate, seizures and possible fatality.

5

. FIRE FIGHTING MEASURES

Suitable Extinguishing Media:

Use fire extinguishing methods suitable to surrounding conditions.

Specific Hazards Arising from the Chemical:

Hazardous combustion products include oxides of carbon, nitrogen, nitrogen oxides, other nitrogen

compounds, hydrogen cyanide, oxides of sulphur, other sulphur compounds, oxides of phosphorous, other

phosphorous compounds, hydrogen chloride, other chlorine compounds, smoke and water.

Product is combustible.

Closed containers may explode when exposed to extreme heat. Containers close to fire should be removed if

safe to do so. Use water spray to cool fire exposed containers.

Special Protective Equipment and Precautions for Fire Fighters:

When fighting a major fire wear self-contained breathing apparatus and protective equipment.

(Contd. on page 3)

Page 3/7

SAFETY DATA SHEET

According to Safe Work Australia

Printing date 01.11.2016

Revision: 01.11.2016

Product Name: CHLORPYRIFOS 500 TERMITICIDE & INSECTICIDE by TITAN

(Contd. of page 2)

43.0

6

. ACCIDENTAL RELEASE MEASURES

Personal Precautions, Protective Equipment and Emergency Procedures:

Wear approved respiratory protection, chemical resistant gloves, protective clothing and safety boots.

Evacuate all non-essential personnel from affected area. Do not breathe vapours. Ensure adequate

ventilation. Extinguish all sources of ignition. Avoid sparks and open flames. No smoking.

Environmental Precautions:

In the event of a major spill, prevent spillage from entering drains or water courses.

Methods and Materials for Containment and Cleaning Up:

Stop leak if safe to do so and absorb spill with sand, earth, vermiculite or some other absorbent material. If

absorbent material is not available or spill is too large, create a dike to stop spill from spreading. Collect the

spilled material and place into a suitable container for disposal.

7

. HANDLING AND STORAGE

Precautions for Safe Handling:

Use of safe work practices are recommended to avoid eye or skin contact and inhalation of vapours. Use only

outdoors or in a well-ventilated area. Food, beverages and tobacco products should not be stored or

consumed where this material is in use. Always wash hands before smoking, eating, drinking or using the

toilet. Wash contaminated clothing and other protective equipment before storage or re-use. Provide eyewash

fountains and safety showers in close proximity to points of potential exposure.

Conditions for Safe Storage:

Store in a cool, dry and well ventilated area. Keep in original container tightly closed when not in use. Protect

from heat, sparks, open flames and other sources of ignition. Keep away from strong oxidising agents, strong

acids and strong bases.

8

. EXPOSURE CONTROLS AND PERSONAL PROTECTION

Exposure Standards:

291-88-2 chlorpyrifos

NES TWA: 0.2 mg/m³

Engineering Controls:

Ensure adequate ventilation of the working area.

Respiratory Protection:

Use an approved vapour respirator under conditions where exposure to the substance is apparent (e.g.

generation of high concentrations of mist or vapour, inadequate ventilation, development of respiratory tract

irritation) and engineering controls are not feasible. See Australian Standards AS/NZS 1715 and 1716 for

more information.

Skin Protection:

PVC or rubber gloves. See Australian/New Zealand Standard AS/NZS 2161 for more information. When

selecting gloves for use against certain chemicals, the degradation resistance, permeation rate and

permeation breakthrough time should be considered.

Occupational protective clothing (depending on conditions in which it has to be used, in particular as regards

the period for which it is worn, which shall be determined on the basis of the seriousness of the risk, the

frequency of exposure to the risk, the characteristics of the workstation of each worker and the performance of

the protective clothing). See Australian/New Zealand Standard AS/NZS 4501 for more information.

Eye and Face Protection:

Eye and face protectors for protection against splashing materials or liquids. See Australian/New Zealand

Standard AS/NZS 1337 for more information.

(Contd. on page 4)

Page 4/7

SAFETY DATA SHEET

According to Safe Work Australia

Printing date 01.11.2016

Revision: 01.11.2016

Product Name: CHLORPYRIFOS 500 TERMITICIDE & INSECTICIDE by TITAN

(Contd. of page 3)

43.0

9

. PHYSICAL AND CHEMICAL PROPERTIES

Appearance:

Form:

Liquid

Colour:

Straw coloured

Odour:

Characteristic hydrocarbon

Odour Threshold:

No information available

pH-Value:

No information available

Melting point/Melting range:

No information available

Initial Boiling Point/Boiling Range:

>178 °C

Flash Point:

>63 °C

Flammability:

Combustible Liquid Class 1

Auto-ignition Temperature:

No information available

Decomposition Temperature:

No information available

Explosion Limits:

Lower:

No information available

Upper:

No information available

Vapour Pressure at 20 °C:

<0.074 kPa

Relative Density at 20 °C:

1.05-1.10

Vapour Density:

No information available

Evaporation Rate at 20 °C:

<0.06

Solubility in Water:

Emulsifies into water.

% Volatiles by Weight:

48 %

10 . STABILITY AND REACTIVITY

Possibility of Hazardous Reactions:

Hazardous polymerisation will not occur.

Chemical Stability:

Stable at ambient temperature and under normal conditions of use.

Conditions to Avoid:

Heat, sparks, open flames, hot surfaces and direct sunlight.

Incompatible Materials:

Strong oxidising agents, strong acids and strong bases.

Hazardous Decomposition Products:

Oxides of carbon, nitrogen, nitrogen oxides, other nitrogen compounds, hydrogen cyanide, oxides of sulphur,

other sulphur compounds, oxides of phosphorous, other phosphorous compounds, hydrogen chloride, other

chlorine compounds, smoke and water.

11 . TOXICOLOGICAL INFORMATION

Toxicity:

LD

₅₀

/LC

₅₀

Values Relevant for Classification:

2921-88-2 Chlorpyrifos (ISO)

Oral

₅₀

mg/kg (lepomis macrochirus)

1000 mg/kg (rabbit)

500-504 mg/kg (guinea pig)

60 mg/kg (mice)

Dermal

₅₀

1000-2000 mg/kg (rabbit)

>2000 mg/kg (rat)

Inhalation LC

₅₀

/4 h >0.2 mg/L (rat)

Acute Health Effects

Inhalation:

May cause symptoms similar to ingestion.

(Contd. on page 5)

Page 5/7

SAFETY DATA SHEET

According to Safe Work Australia

Printing date 01.11.2016

Revision: 01.11.2016

Product Name: CHLORPYRIFOS 500 TERMITICIDE & INSECTICIDE by TITAN

(Contd. of page 4)

43.0

Skin:

May cause symptoms similar to ingestion.

Eye:

May cause eye irritation, stinging, reddening and watering.

Ingestion:

Toxic if swallowed. May cause numbness, tingling sensations, incoordination, headache, dizziness, nausea,

abdominal cramps, excessive sweating and salivation, blurred vision, respiratory depression,

unconsciousness, incontinence, convulsions, fatigue, slowed heart rate, seizures and possible fatality.

Skin Corrosion / Irritation:

Based on classification principles, the classification criteria are not met.

Serious Eye Damage / Irritation:

Based on classification principles, the classification criteria are not met.

Respiratory or Skin Sensitisation:

Based on classification principles, the classification criteria are not met.

Germ Cell Mutagenicity:

Based on classification principles, the classification criteria are not met.

Carcinogenicity:

This product does NOT contain any IARC listed chemicals.

Reproductive Toxicity:

Based on classification principles, the classification criteria are not met.

Specific Target Organ Toxicity (STOT) - Single Exposure:

Based on classification principles, the classification criteria are not met.

Specific Target Organ Toxicity (STOT) - Repeated Exposure:

Based on classification principles, the classification criteria are not met.

Aspiration Hazard:

Based on classification principles, the classification criteria are not met.

Chronic Health Effects:

Repeated or prolonged exposure to organophosphates may result in the same effects as acute exposure

including the delayed symptoms. Other effects reported in workers repeatedly exposed include impaired

memory and concentration, disorientation, severe depressions, irritability, confusion, headache, speech

difficulties, delayed reaction times, nightmares, sleepwalking, and drowsiness or insomnia.

Existing Conditions Aggravated by Exposure:

No information available

Additional toxicological information:

The Australian Acceptable Daily Intake (ADI) for chlorpyrifos for a human is 0.003 mg/kg/day, set for the

public for daily, lifetime exposure. This is based on the NOEL of 0.03 mg/kg/day, the level determined to show

no effects during long term exposure for the most sensitive indicators and the most sensitive species. (Ref:

Comm. Dept. of Health and Ageing Office of Chemical Safety, 'ADI List', June 2014).

Chlorpyrifos primarily affects the nervous system through inhibition of cholinesterase, an enzyme required for

proper nerve functioning. Chlorpyrifos is readily absorbed into the bloodstream through the gastrointestinal

tract if it is ingested, through the lungs if it is inhaled, or through the skin if there is dermal exposure. In

humans, chlorpyrifos and its principal metabolites are eliminated rapidly.

12 . ECOLOGICAL INFORMATION

Ecotoxicity:

Serious hazard to wildlife and bees.

Aquatic toxicity:

Very Toxic to aquatic life with long lasting effects.

Persistence and Degradability:

Persistent in soils. Half-life in soil normally ranges from 60 to 120 days, though may be as long as a year,

depending on soil type.

Bioaccumulative Potential:

No information available

Mobility in Soil:

Due to relatively low solubility and strong potential to adsorb to soil, chlorpyrifos is immobile in soils.

Other adverse effects:

No information available

(Contd. on page 6)

Page 6/7

SAFETY DATA SHEET

According to Safe Work Australia

Printing date 01.11.2016

Revision: 01.11.2016

Product Name: CHLORPYRIFOS 500 TERMITICIDE & INSECTICIDE by TITAN

(Contd. of page 5)

43.0

13 . DISPOSAL CONSIDERATIONS

Disposal Methods and Containers:

Dispose according to applicable local and state government regulations.

Special Precautions for Landfill or Incineration:

Please consult your state Land Waste Management Authority for more information.

14 . TRANSPORT INFORMATION

UN Number

ADG, IMDG, IATA

UN3018

Proper Shipping Name

ADG

3018 ORGANOPHOSPHEROUS PESTICIDES, LIQUID

TOXIC, (chlopyrifos (ISO))

IMDG

ORGANOPHOSPHEROUS PESTICIDES, LIQUID

TOXIC, (chlopyrifos (ISO)), MARINE POLLUTANT

IATA

ORGANOPHOSPHEROUS PESTICIDES, LIQUID

TOXIC, (chlopyrifos (ISO))

Dangerous Goods Class

ADG Class:

6.1 Toxic substances.

Packing Group:

ADG, IMDG, IATA

Marine pollutant:

Symbol (fish and tree)

EMS Number:

F-A,S-A

Hazchem Code:

Special Provisions:

61, 223, 274

Limited Quantities:

Packagings & IBCs - Packing Instruction:

P001, IBC03, LP01

Packagings & IBCs - Special Packing Provisions:

No information available

Portable Tanks & Bulk Containers - Instructions:

Portable Tanks & Bulk Containers - Special

Provisions:

TP2, TP28

15 . REGULATORY INFORMATION

Australian Inventory of Chemical Substances:

2921-88-2 Chlorpyrifos (ISO)

Standard for the Uniform Scheduling of Drugs and Poisons (SUSMP) - Poison Schedule:

Poisons Schedule: 6

16 . OTHER INFORMATION

Date of Preparation or Last Revision:

01.11.2016

Prepared by:

MSDS.COM.AU Pty Ltd www.msds.com.au

Abbreviations and acronyms:

ADG: Australian Dangerous Goods

IMDG: International Maritime Code for Dangerous Goods

(Contd. on page 7)

Page 7/7

SAFETY DATA SHEET

According to Safe Work Australia

Printing date 01.11.2016

Revision: 01.11.2016

Product Name: CHLORPYRIFOS 500 TERMITICIDE & INSECTICIDE by TITAN

(Contd. of page 6)

43.0

IATA: International Air Transport Association

GHS: Globally Harmonised System of Classification and Labelling of Chemicals

CAS: Chemical Abstracts Service (division of the American Chemical Society)

₅₀

: Lethal concentration, 50 percent

₅₀

: Lethal dose, 50 percent

IARC: International Agency for Research on Cancer

STEL: Short Term Exposure Limit

TWA: Time Weighted Average

NES: National Exposure Standard (Safe Work Australia - Workplace Exposure Standards For Airborne Contaminants)

Flammable Liquids 4: Flammable liquids – Category 4

Acute Toxicity (Oral) 3: Acute toxicity – Category 3

Aquatic Acute 1: Hazardous to the aquatic environment, short-term (Acute). Category 1

Aquatic Chronic 1: Hazardous to the aquatic environment, long-term (Chronic). Category 1

Disclaimer

This SDS is prepared in accord with the Safe Work Australia document “Code of Practice for the Preparation

of Safety Data Sheets for Hazardous Chemicals - December 2011”

The information contained in this safety data sheet is provided in good faith and is believed to be accurate at

the date of issuance. Titan Ag Pty Ltd makes no representation of the accuracy or comprehensiveness of the

information and to the full extent allowed by law excludes all liability for any loss or damage related to the

supply or use of the information in this material safety data sheet. MSDS.COM.AU Pty Ltd is not in a position

to warrant the accuracy of the data herein. The user is cautioned to make their own determinations as to the

suitability of the information provided to the particular circumstances in which the product is used.

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