SUNRISE HEAVY DUTY MORNING ACID

Australia - English - APVMA (Australian Pesticides and Veterinary Medicines Authority)

Active ingredient:
NITRIC ACID; SULFAMIC ACID
Available from:
DASCO PROPRIETARY LIMITED
INN (International Name):
nitric acid(206g/L)+sulfamic acid(54g/L)
Pharmaceutical form:
AQUEOUS CONCENTRATE
Composition:
NITRIC ACID ACID-GENERAL Active 206.0 g/L; SULFAMIC ACID MINERAL-SULFUR-ACID Active 54.0 g/L
Units in package:
20L
Class:
A - Agricultural
Therapeutic group:
MILKING EQUIPMENT | MILKING MACHINE
Therapeutic area:
DAIRY CLEANSER
Therapeutic indications:
GENERAL DISINFECTION | ANTIVIRAL AGENT | AVIARIES | CATTERIES | DETERGENT | FEEDING UTENSILS | FLESH WOUNDS | FLOOR | GERMICIDAL DETERGENT | KENNEL | MASTITIS | MOULD GROWTH | POULTRY CAGES | PROTOZOANS | STABLES | TOILETS (NOT SEPTIC) | WALLS
Product summary:
Poison schedule: 6; Withholding period: WHP: N/A; Host/pest details: MILKING EQUIPMENT: [GENERAL DISINFECTION]; Poison schedule: 6; Withholding period: ; Host/pest details: MILKING EQUIPMENT: [GENERAL DISINFECTION]; Low foaming liquid acid detergent.
Authorization status:
Registered
Authorization number:
50906
Authorization date:
2019-07-01

N.R.A.

APPROVEDLABEL(TEXT)

Label No:

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Date:

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POISON

KEEP OUT OF REACH OF CHILDREN

READ SAFETY DIRECTIONS BEFORE OPENING OR USING

LOW FOAMING LIQUID ACID DETERGENT

Active Constituents

206 g/L Nitric Acid

54 g/L Sulphamic Acid

Net Contents: 20 L

Manufactured by :

Dasco

Pty Ltd, 24-26 Helen St, West Heidelberg,

Vic

3081

Phone: 03-9459-7004,

Fax:03-9459-9200

NRA Approval No. 50906/0798

DIRECTIONS FOR USE :

MORNING ACID CLEANING :

After milking rinse plant free of milk

ALKA RINSE as per label direc-

tions

,wrth

cold water (20 -30%) use 10

Lltres

per set of cups

Wash plant

wtth

SUNRISE

HEAVY

DUTY

M O R N I N G

ACID at the rate

of 20ml

per 10 Litces of hot water (85’C)

Use 5 litres per set of cups. When mixing

the cleaning solution, ADD the product to

the water, DO NOT ADD the water to the

product

Rinse plant

with

hot water (85’C). Use 5

tres per set of cups.

EVENING:

alkaline

wash Replace SUNRISE

HEAVY

DUTY MORNING ACID with SUNSET HEAVY

DUTY EVENING ALKALI, as per label direc-

tions

NOT TO BE USED FOR ANY PURPOSE, OR

IN ANY OTHER MANNER, CONTRARY TO

THIS LABEL UNLESS AUTHORISED UNDER

APPROPRIATE LEGISLATION.

SAFETY

DIRECTIONS

:

Corrosive

Attacks eyes and nose and throat

and skin Avoid contact

with

eyes and skin and

clothrng.

Do not

Inhale

vapour or spray mist.

When preparing solution wear cotton overalls

buttoned to the neck and wrist, and a washable

hat, and rubber apron, and elbow-length neo-

prene gloves, and chemical resistant foot ware,

and full face piece respirator with organic va-

pour/gas cartridge or canister. When using the

prepared solution wear elbow-length neoprene

gloves

face-shield.

clothing

becomes

contaminated with product, remove clothing im-

mediately. If product on skin, wash area with

soap and water. If product in eyes wash it out

Immediately with water. After use and before

eating, drinking, or smoking wash hands, arms

and face thoroughly with soap and water. After

each day’s use, wash gloves, contaminated

clothing and respirator and if rubber wash with

detergent and warm water.

FIRST AID :

IF POISONING OCCURS. CONTACT A DOC-

TOR OR POISONS INFORMATION CENTRE.

Phone

Australia

131126;

New Zealand 03 4747000.

IF SWALLOWED DO NOT INDUCE VOMIT-

ING. GIVE

GLASS

WATER.

SKIN

CONTACT

OCCURS,

REMOVE

CONTAMI-

NATED CLOTHING AND WASH SKIN THOR-

OUGHLY. IF IN EYES, HOLD EYES OPEN,

FLOOD

WITH

WATER

LEAST

MINUTES AND SEE A DOCTOR.

STORAGE AND DISPOSAL :

Store in closed original container,

a well ven-

tilated area, as cool as possible, out of direct

sunlight. Triple or (preferably) pressure rinse

containers before

disposal.

Add rinsings to pre-

pared

product.

dispose

undiluted

chemicals on site. Break, crush, puncture and

bury empty containers in a local authority land-

fill. If not available bury the containers below

500 mm in a disposal pit specifically marked

and set up for this purpose clear of waterways,

vegetation

roots.

Empty

containers

product should not be burnt.

PROTECTION OF WILDLIFE, FISH, CRUSTA-

CEA, AND ENVIRONMENT

Dangerous to fish. DO NOT contaminate

streams, rivers, or water ways with the chemical

or used containers.

UN 1760

CORROSIVE

LIQUID,

N.O.S.

In a Transport Emergency

Dial

Police or Fire Brigade

Or DASCO (03) 9459 7004

HAZCHEM

Date of Manufacture

Batch No. :

NRA Approval No.

50906/O

Product Name: Sunrise Heavy Duty Morning Acid

Other Names:

Nitric acid, sulphamic acid mixture.

Proper shipping name (ADG Code):

Corrosive liquid, n.o.s.

(Contains 13 % nitric acid, < 5 % sulphamic acid)

Recommended use:

As an acid detergent. Use as directed on the

product label.

Supplier: DASCO Pty. Ltd.,

ABN: 14 004 581 113

24 - 26 Helen Street,

HEIDELBERG HEIGHTS VIC 3081

Tel: (03) 9459 7004

(business hours)

Fax: (03) 9459 9200

Emergency Phone Numbers:

Transport/Fire Emergency:

000

(Emergency services)

Medical Emergency:

131126

(Poisons Information Centre)

Classified as hazardous according to criteria of Worksafe Australia.

Dangerous goods.

Risk Phrases:

R: 34 Causes burns.

Safety Phrases:

S:(1/2) Keep locked up and out of the reach of

children.

S: 23 Do not breathe vapour.

S: 26 In case of contact with eyes, rinse

immediately with plenty of water and seek

medical advice.

S: 36 Wear suitable protective clothing.

S: 45 In case of accident or if you feel unwell,

seek medical advice immediately (show the

label where possible).

Ingredients:

Nitric acid [7697-37-2] 10 - 30 %

Sulphamic acid [5329-14-6] < 10 %

Surfactant < 10 %

Other ingredients < 10 %

Water [7732-18-5] to 100 %

For advice, contact a Poisons Information Centre (Phone 131126)

or a doctor.

Dasco Hygiene Logo

Section 1: Identification of the Material and Supplier

Section 2: Hazards Identification

Section 3: Composition/Information on Ingredients

Section 4: First Aid Measures

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Swallowed: Do not induce vomiting.

Skin: If skin or hair contact occurs, Remove contaminated

clothing and flush skin and hair with running water.

Eyes: If in eyes, hold eyelids apart and flush the eye

continuously with running water. Continue flushing

until advised to stop by the Poisons Information

Centre or a doctor, or for at least 15 minutes.

Inhaled: Remove from exposure, rest and keep warm.

First Aid facilities:

Mandatory: Eye wash. Hand wash basin.

Recommended: Safety shower if handling industrial

quantities.

Advice to Doctor:

Product is an acid mixture containing up to 13 % nitric acid.

Causes burns. Risk of serious damage to eyes. Contact Poisons

Information Centre.

Aggravated medical conditions:

Pre-existing lung disorders or skin disorders.

HAZCHEM Code:

Extinguishant:

Water fog or fine water spray.

Risk of violent reaction or explosion:

Products of combustion:

Water vapour, oxides of nitrogen, oxides of

sulphur, oxides of phosphorus.

Protective Equipment:

Full protective clothing including breathing

apparatus and protective gloves.

Emergency Procedures:

Contain.

For large spills:

Contain spillage using sand or earth. Transfer both liquids and

solids to suitable container. Treat residues as for small

spillages.

For small spills:

Neutralise spills by covering liberally with soda ash or lime, if

available.

If local regulations permit, mop up with plenty of water and run

to waste, diluting greatly with running water. Otherwise absorb on

inert absorbent, transfer to suitable container and arrange

removal by disposals company.

Section 5: Fire Fighting Measures

Section 6: Accidental Release Measures

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Precautions for safe handling:

Avoid contact with skin and eyes.

Wear suitable protective clothing.

Conditions for safe storage:

Store in a cool, well ventilated place, out of reach of children.

Large quantities should be stored in a bunded dangerous goods

store. Store in original container. Keep container tightly closed.

Keep away from alkalis (including carbonates and bicarbonates),

oxidising agents, organic materials, combustible materials, active

metals, copper and its alloys.

Protect from physical damage. Clean up all spills and splashes

promptly; avoid secondary accidents.

Incompatibles:

Alkalis, oxidising agents, organic materials, combustible

materials, active metals, copper and alloys.

National Exposure Standards:

ES-TWA:

Nitric acid 2 ppm, 5.2 mg/m³

ES-STEL:

Nitric acid 4 ppm, 10 mg/m³

ES-PEAK:

None assigned.

Notations:

None.

Biological Limit Values:

No data found.

Engineering Controls:

Do not use active metals, such as aluminium, zinc, copper or its

alloys, or wood/paper products as materials of construction.

Ensure adequate ventilation (same as outdoors) when using.

If handling industrial quantities, or if vapour or aerosol risk

exists, consider local mechanical exhaust/extraction to keep

airborne contamination as low as possible, and at least below the

TLV.

Personal Protective Equipment:

Avoid contact with skin and eyes. Avoid breathing vapour or

spray/mist. Personal protection to be selected from those

recommended below, as appropriate to mode of use, quantity

handled and degree of hazard:-

Normal Use:

Eye/face protection

Gloves, rubber or plastic.

Industrial Quantities:

Face shield or safety glasses

Gloves, rubber or plastic

Plastic apron, sleeves and boots

Impervious overalls.

Appearance: Clear, slightly frothing liquid.

Section 7: Handling and Storage

Section 8: Exposure Controls/Personal Protection

Section 9: Physical and Chemical Properties

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Odour: Slight smell of surfactant and nitric acid.

pH: Very acid.

Vapour Pressure: No data.

Vapour Density: No data.

Boiling Point: > 100 °C

Melting Point: No data.

Volatiles: About 92 %

Volatile Organic Compounds (VOC): None.

Evaporation Rate: No data.

Solubilities: Miscible with water in all proportions.

Specific Gravity/Density: 1.1 g/mL

Flash Point: None.

Flammable Limits: None.

Dust Explosion: Not applicable.

Auto-ignition Temperature: No data.

Other Information:

Very acidic liquid. Will react vigorously or violently with

alkalis. Contact with carbonates or bicarbonates will generate

carbon dioxide, a simple asphyxiant. Contact with aluminium or

zinc may generate hydrogen, a flammable gas. Contact with copper

or its alloys may generate brown fumes of nitrogen dioxide, a

toxic and corrosive gas. Contact with combustible materials may

cause fire. Reaction with organic materials, including wood or

paper products, may produce products that are readily ignited or

even explosive. Slippery when spilled.

Chemical Stability:

Stable under normal conditions.

Conditions to Avoid:

Incompatible materials.

Incompatible Materials:

Copper and alloys, active metals, alkalis,

organic materials (including wood and paper),

other combustible materials.

Hazardous Decomposition Products:

Oxides of nitrogen, oxides of

sulphur, oxides of phosphorus.

Hazardous Reactions:

Will react vigorously or violently with

alkalis. Contact with carbonates or

bicarbonates will generate carbon dioxide, a

simple asphyxiant. Contact with aluminium or

zinc may generate hydrogen, a flammable gas.

Contact with copper or its alloys may generate

brown fumes of nitrogen dioxide, a toxic and

corrosive gas. Contact with combustible

materials may cause fire. Reaction with

organic materials, including wood or paper

products, may produce products that are

readily ignited or even explosive.

Health Effects:

No data available for the mixture. Information presented

relates to individual ingredients.

Acute: Swallowed:

Corrosive. May cause burns to the lips,

Section 10: Stability and Reactivity

Section 11: Toxicological Information

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mouth, throat and gastrointestinal tract.

Other symptoms may include increased

salivation, intense thirst, difficulty

swallowing, chills, pain and shock.

Large doses may be fatal.

Skin:

Corrosive. May cause yellowish skin

discoloration, pain, burns and possibly deep

ulceration. Milder exposures may cause skin

rash, cold and clammy skin with pale skin

colour or cyanosis (bluish colour of the

lips and skin).

Eyes:

Corrosive. May cause immediate pain,

redness, severe deep burns.

Vapours may also cause irritation and

permanent damage to the eyes, chemical

conjunctivitis and corneal damage.

Inhaled:

May cause irritation of the nose and throat,

a burning sensation in the nose, throat and

lungs, coughing, difficulty breathing,

choking.

May cause chemical pneumonitis and pulmonary

oedema (fluid build-up in the lungs), which

may be fatal. Onset of symptoms may be

delayed.

Chronic:

Long term, low level, exposure to vapours of nitric acid

may cause chronic bronchitis, erosion of the teeth and

possible lung damage.

LD50:

Nitric acid No data found.

Sulphamic acid 3,160 mg/kg oral, rat.

LC50:

Nitric acid 67 ppm/4 hours, rat.

LDLo:

Nitric acid 430 mg/kg oral, human.

110 mg/kg unknown route, man.

Ecotoxicity:

Toxic to aquatic organisms.

Persistance and degradability:

No data.

Mobility:

Soluble in water.

Environmental Fate:

No data.

Bioaccumulative potential:

No data.

Other adverse environmental effects:

No data.

The generator of any wastes from this product is responsible for

its proper classification, transport and disposal.

Section 12: Ecological Information

Section 13: Disposal Considerations

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Consult appropriate local and State regulations.

Disposal methods and containers:

Prevent disposal to sewer.

Special precautions for landfill or incineration:

Neutralise with soda ash or lime before disposal.

UN Number:

UN 1760

UN Proper shipping name:

Corrosive liquid, n.o.s.

(Contains 13 % nitric acid, < 5 % sulphamic acid)

Class and subsidiary risk:

8 Corrosive.

Packaging group:

Special precautions for user:

Segregate from alkalis, active

metals, combustibles, organic materials.

HAZCHEM Code:

Material for export:

Regulated.

Refer to

IMO/IMDG

IATA/ICAO

Poisons (SUSDP):

Schedule 6 (nitric acid > 10 %)

Dangerous Goods:

Yes. UN 1760 8/II 2 X.

Carcinogen: Australia IARC NTP RTECS

No. No. No. No.

Agricultural and Veterinary Chemicals Act:

No data.

This product is registered with the Australian Pesticides and

Veterinary Medicines Authority

(APVMA)

Australian Inventory of Chemical Substances (AICS):

Listed.

Other National/International Regulations:

No data.

Date of MSDS update:

March 2004

Complete review and re-write of all sections.

Abbreviations:

NOHSC - National Occupational Health and Safety Commission.

ACGIH - American Conference of Governmental Industrial Hygienists.

MAK - Maximum workplace concentration - Germany,

maximale Arbeitsplatzkonzentration

IARC - International Agency for Research on Cancer (France).

NTP - National Toxicology Program (USA).

RTECS - Registry of Toxic Effects of Chemical Substances.

Literature references:

Section 14: Transport Information

Section 15: Regulatory Information

Section 16: Other information

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Available Sources of Data:

National Code of Practice for the Preparation of Material Safety Data

Sheets 2nd Edition [2011(2003)] - NOHSC.

Australian Dangerous Goods Code.

Standard for the Uniform Scheduling of Drugs and Poisons - AHMAC.

Exposure Standards for Atmospheric Contaminants in the

Occupational Environment [1003]- NOHSC.

List of Designated Hazardous Substances [10005] - NOHSC.

Merck Index - Merck Inc.

Sax's Dangerous Properties of Industrial Materials - Lewis.

Handbook of Toxic and Hazardous Chemicals and Carcinogens - Sittig.

Handbook of Reactive Chemical Hazards - Bretherick.

Hawley's Condensed Chemical Dictionary - Wiley Interscience.

AUSREG's Chemical Data Package for PCs - AUSREG Consultancy.

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