RID AUSTRALIA MEDICATED RID INSECT REPELLENT TROPICAL STRENGTH + ANTISEPTIC ROLL-ON 6 HOURS MOSQUITO PROTECTION NEUTRAL SCENT PR

Australia - English - APVMA (Australian Pesticides and Veterinary Medicines Authority)

Active ingredient:
N-OCTYL BICYCLOHEPTENE DICARBOXIMIDE; DI-N-PROPYL ISOCINCHOMERONATE; DIETHYLTOLUAMIDE; TRICLOSAN
Available from:
Cavalieri Investing Pty Ltd
INN (International Name):
DEET(191g/L)+MGK264(40g/L)+DPIC(20g/L)+triclosan(1g/L)
Pharmaceutical form:
CREAM
Composition:
N-OCTYL BICYCLOHEPTENE DICARBOXIMIDE BICYCLO Active 40.0 g/L; DI-N-PROPYL ISOCINCHOMERONATE BENZENE Active 20.0 g/L; DIETHYLTOLUAMIDE INSECT REPELLENT Active 191.0 g/L; TRICLOSAN PHENOL Active 1.0 g/L
Units in package:
50-250mL
Class:
A - Agricultural
Manufactured by:
CAVALIERI INVESTING
Therapeutic group:
PEST CONTROL - PERSONAL USE
Therapeutic area:
HOUSEHOLD INSECTICIDE
Therapeutic indications:
BITING INSECT | FLEA | FLY | LEECH | MIDGES & SANDFLIES - CULICOIDES SPP. | MOSQUITO | TICK | ADULT MOSQUITOES | CTENOCEPHALIDES SPP. | GROUND FLEAS
Product summary:
Poison schedule: 0; Withholding period: WHP: N/A.; Host/pest details: PEST CONTROL - PERSONAL USE: [BITING INSECT, FLEA, FLY, LEECH, MIDGES & SANDFLIES - CULICOIDES SPP., MOSQUITO, TICK]; Provides long lasting protection against mosquitoes for 6 hours. Helps protect you and your family against the risk of bites from disease carrying insects including mosquitoes that may carry Ross River virus and dengue.For external use only. If rash or irritation occurs, discontinue use. See also RESTRAINTS and DEET WARNING on label.
Authorization status:
Registered
Authorization number:
53406
Authorization date:
2020-07-01

~--~--------------------------------------

FINAL

COPY

FOR

PRODUCT

LABEL:

53406

PRODUCT NAME:

AUSTRALIA MEDICATED RID®

INSECT

REPELLENT

TROPICAL

STRENGTH

ROLL-ON+

ANTISEPTIC

ROLL

ON 6

HOURS

MOSQUITO

PROTECTION

NEUTRAL

SCENT

PROTECTION

AGAINST MOSQUITOES THAT MAY

CARRY

ROSS

RIVER

VIRUS

DENGUE.

Front

label

9311037421005

Australia

Medicated

RID®

Insect Repellent

Tropical

Strength+

ANTISEPTIC Roll-on

Hours

Mosquito

Protection

Neutral

Scent

Approved

Protection

against

mosquitoes

that

carry

Ross River Virus

&

Dengue

ACTIVE CONSTITUENTS:

191g/l

N,N-DIETHYL-M-TDLUAMIDE

40g/l

N-DCTYL

BICYCLOHEPTENE

DICARBDXIMIDE,

20g/l

DI-N-PROPYLISDCINCHOMERDNATE,

TRICLDSAN

lOOm I

Roll-on

Milk

«RID

Australia's

logo

insect

repellent

logo

«Graphic

Mosquito

with

device

display

benefits.

«images

insects-

Mosquitoes, Flies,

Ticks, Fleas,

leeches, Sandflies,

Biting

Midge

Back

Label

Medicated

RID"'

Insect Repellent

insect

repellent

Logo

Tropical Strength +ANTISEPTIC

Independent laboratory tests prove

Medicated

Tropical

Strength+

Antiseptic

Insect Repellent provides long lasting protection against

mosquitoes

6 hours.

Especially formulated

repel insects in

toughest conditions .

Medicated Tropical Strength

+Antiseptic

Insect Repellent helps

protect you and

yourfamily

against the risk

bites from disease

carrying insects including mosquitoes

that

may carry

Ross

River Virus

&

Dengue.

DIRECTIONS

USE:

To repel insect pests, apply

all exposed skin.

Reapply

regular intervals.

apply near eyes

mouth.

apply

lips, broken skin

babies' hands.

USED

PURPOSE,

IN ANY MANNER,

CONTRARY

THIS

LABEL

UNLESS

AUTHORISED.

SAFETY

PRECAUTIONS:

For external

only.

rash

irritation occurs,

discontinue

use.

swallowed, seek medical advice.

RESTRAINTS:

apply near eyes

mouth.

apply

lips,

broken skin or babies' hands. Avoid contact

with

food and food utensils,

spectacle frames, soft plastics

synthetic fibres,

timber

fittings and

furniture.

DEETWARNING:

dangerous, particularly

children,

used in large

amounts on the skin, clothes,

bedding,

on large areas

the body,

especially

you keep using

a long

time.

FIRST

AID:

poisoning occurs, contact a

doctor

Poisons Information

Centre. Phone Australia 13 11

Zealand 0800 764 766.

STORAGE

DISPOSAL:

KEEP

REACH

FROM

CHILDREN.

Keep

upright position, in a cool

place. Store in closed original container.

Dispose

bottle

putting

in garbage.

Batch

number

and expiry located

bottom

container.

Redg

Trademark-

Authorised User

APVMA Approval No: 53406/62651

Australia

«Rid

Australia's

Logo

Levell,

Denham Street, Townsville

4810, www.rid.com.au

<<Barcode

Write

call +61 7 4772 1411

(vertical)

Australia's Owned & Made (flag device)

«Flag

Graphic-

Australia's Own

Flag

True Blue

Australian Owned

& Made

Other major brands are foreign owned.

RID (RID (Australia))

Chemwatch Hazard Alert Code: 1

RID 401100 Tropical Roll-On

Chemwatch: 36-6831

Version No: 7.1.1.1

Safety Data Sheet according to WHS and ADG requirements

Issue Date: 24/04/2015

Print Date: 27/04/2015

Initial Date: Not Available

S.GHS.AUS.EN

SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING

Product Identifier

Product name

RID 401100 Tropical Roll-On

Synonyms

401100 Tropical Roll-On 100ml APN 9311037421005, 401100HK Tropical Roll-On 100ml HK APN 9311037421005, 410100 Tropical Roll-On 100ml APN

9311037421005, 410100HK Tropical Roll-On 100ml HK APN 9311037421005

Other means of

identification

Not Available

Relevant identified uses of the substance or mixture and uses advised against

Relevant identified uses

Use according to manufacturer's directions.

Personal insecticide lotion applied to skin.

Details of the manufacturer/importer

Registered company name

RID (RID (Australia))

Address

79 Denham Street Townsville 4810 QLD Australia

Telephone

+61 7 4772 1411

Fax

+61 7 4721 3892

Website

Not Available

Email

Not Available

Emergency telephone number

Association / Organisation

Not Available

Emergency telephone

numbers

+61 7 4772 1411

Other emergency telephone

numbers

Not Available

SECTION 2 HAZARDS IDENTIFICATION

Classification of the substance or mixture

HAZARDOUS CHEMICAL. NON-DANGEROUS GOODS. According to the Model WHS Regulations and the ADG Code.

CHEMWATCH HAZARD RATINGS

Flammability

0

Toxicity

0

Body Contact

1

Reactivity

0

Chronic

0

0 = Minimum

1 = Low

2 = Moderate

3 = High

4 = Extreme

Poisons Schedule

Not Applicable

GHS Classification

Not Applicable

Label elements

GHS label elements

Not Applicable

SIGNAL WORD

NOT APPLICABLE

Hazard statement(s)

Not Applicable

Supplementary statement(s)

Not Applicable

Continued...

Precautionary statement(s) Prevention

Not Applicable

Precautionary statement(s) Response

Not Applicable

Precautionary statement(s) Storage

Not Applicable

Precautionary statement(s) Disposal

Not Applicable

SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS

Substances

See section below for composition of Mixtures

Mixtures

CAS No

%[weight]

Name

134-62-3

Not Available

<11

ingredients determined not to be hazardous [Mfr]

7732-18-5

balance

SECTION 4 FIRST AID MEASURES

Description of first aid measures

Eye Contact

If this product comes in contact with eyes:

Wash out immediately with water.

If irritation continues, seek medical attention.

Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.

Skin Contact

· Intended for application to skin.

· Remove with soap and water if irritation occurs.

· Seek medical advice if irritation persists.

Inhalation

If fumes, aerosols or combustion products are inhaled remove from contaminated area.

Other measures are usually unnecessary.

Ingestion

Immediately give a glass of water.

First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor.

Indication of any immediate medical attention and special treatment needed

Treat symptomatically.

SECTION 5 FIREFIGHTING MEASURES

Extinguishing media

There is no restriction on the type of extinguisher which may be used.

Use extinguishing media suitable for surrounding area.

Special hazards arising from the substrate or mixture

Fire Incompatibility

None known.

Advice for firefighters

Fire Fighting

Alert Fire Brigade and tell them location and nature of hazard.

Wear breathing apparatus plus protective gloves in the event of a fire.

Prevent, by any means available, spillage from entering drains or water courses.

Use fire fighting procedures suitable for surrounding area.

Fire/Explosion Hazard

Non combustible.

Not considered a significant fire risk, however containers may burn.

May emit poisonous fumes.

SECTION 6 ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Minor Spills

Clean up all spills immediately.

Avoid breathing vapours and contact with skin and eyes.

Control personal contact with the substance, by using protective equipment.

Contain and absorb spill with sand, earth, inert material or vermiculite.

Major Spills

Moderate hazard.

Clear area of personnel and move upwind.

Alert Fire Brigade and tell them location and nature of hazard.

Wear breathing apparatus plus protective gloves.

N,N-diethyl-m-toluamide

water

Chemwatch: 36-6831

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RID 401100 Tropical Roll-On

Issue Date: 24/04/2015

Print Date: 27/04/2015

Continued...

Personal Protective Equipment advice is contained in Section 8 of the MSDS.

SECTION 7 HANDLING AND STORAGE

Precautions for safe handling

Safe handling

Avoid all personal contact, including inhalation.

Wear protective clothing when risk of exposure occurs.

Use in a well-ventilated area.

Prevent concentration in hollows and sumps.

Other information

Store in original containers.

Keep containers securely sealed.

Store in a cool, dry, well-ventilated area.

Store away from incompatible materials and foodstuff containers.

Conditions for safe storage, including any incompatibilities

Suitable container

Polyethylene or polypropylene container.

Packing as recommended by manufacturer.

Check all containers are clearly labelled and free from leaks.

Storage incompatibility

Avoid reaction with oxidising agents

X

— Must not be stored together

0

— May be stored together with specific preventions

+

— May be stored together

PACKAGE MATERIAL INCOMPATIBILITIES

Not Available

SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION

Control parameters

OCCUPATIONAL EXPOSURE LIMITS (OEL)

INGREDIENT DATA

Not Available

EMERGENCY LIMITS

Ingredient

Material name

TEEL-1

TEEL-2

TEEL-3

RID 401100 Tropical Roll-On

Not Available

Not Available

Not Available

Not Available

Ingredient

Original IDLH

Revised IDLH

N,N-diethyl-m-toluamide

Not Available

Not Available

ingredients determined not to

be hazardous [Mfr]

Not Available

Not Available

water

Not Available

Not Available

Exposure controls

Appropriate engineering

controls

Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed engineering controls can be highly

effective in protecting workers and will typically be independent of worker interactions to provide this high level of protection.

The basic types of engineering controls are:

Process controls which involve changing the way a job activity or process is done to reduce the risk.

Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker and ventilation that strategically "adds" and

"removes" air in the work environment.

Personal protection

Eye and face protection

Safety glasses with side shields

Chemical goggles.

Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing the wearing of

lenses or restrictions on use, should be created for each workplace or task. This should include a review of lens absorption and adsorption for the class of

chemicals in use and an account of injury experience.

Skin protection

See Hand protection below

Hands/feet protection

The selection of suitable gloves does not only depend on the material, but also on further marks of quality which vary from manufacturer to manufacturer. Where

the chemical is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior

to the application.

The exact break through time for substances has to be obtained from the manufacturer of the protective gloves and.has to be observed when making a final

choice.

Suitability and durability of glove type is dependent on usage.

Chemwatch: 36-6831

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RID 401100 Tropical Roll-On

Issue Date: 24/04/2015

Print Date: 27/04/2015

Continued...

Body protection

See Other protection below

Other protection

Overalls.

P.V.C. apron.

Barrier cream.

Thermal hazards

Not Available

Recommended material(s)

GLOVE SELECTION INDEX

Glove selection is based on a modified presentation of the:

"

Forsberg Clothing Performance Index".

The effect(s) of the following substance(s) are taken into account in the

computer-

generated

selection:

RID 401100 Tropical Roll-On

Material

CPI

BUTYL

NATURAL RUBBER

NEOPRENE

VITON

* CPI - Chemwatch Performance Index

A: Best Selection

B: Satisfactory; may degrade after 4 hours continuous immersion

C: Poor to Dangerous Choice for other than short term immersion

NOTE: As a series of factors will influence the actual performance of the glove, a final

selection must be based on detailed observation. -

* Where the glove is to be used on a short term, casual or infrequent basis, factors such as

"feel" or convenience (e.g. disposability), may dictate a choice of gloves which might otherwise

be unsuitable following long-term or frequent use. A qualified practitioner should be consulted.

Respiratory protection

Type A-P Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI

Z88 or national equivalent)

Where the concentration of gas/particulates in the breathing zone, approaches or exceeds the

"Exposure Standard" (or ES), respiratory protection is required.

Degree of protection varies with both face-piece and Class of filter; the nature of protection

varies with Type of filter.

Required Minimum

Protection Factor

Half-Face

Respirator

Full-Face

Respirator

Powered Air

Respirator

up to 10 x ES

A-AUS P2

A-PAPR-AUS /

Class 1 P2

up to 50 x ES

A-AUS / Class 1

up to 100 x ES

A-2 P2

A-PAPR-2 P2 ^

^ - Full-face

A(All classes) = Organic vapours, B AUS or B1 = Acid gasses, B2 = Acid gas or hydrogen

cyanide(HCN), B3 = Acid gas or hydrogen cyanide(HCN), E = Sulfur dioxide(SO2), G =

Agricultural chemicals, K = Ammonia(NH3), Hg = Mercury, NO = Oxides of nitrogen, MB =

Methyl bromide, AX = Low boiling point organic compounds(below 65 degC)

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties

Appearance

White fragrant non-greasy cosmetic based lotion/liquid; miscible with water (200 g/l)

Physical state

Liquid

Relative density (Water = 1)

0.98

Odour

Not Available

Partition coefficient

n-octanol / water

Not Available

Odour threshold

Not Available

Auto-ignition temperature

(°C)

Not Available

pH (as supplied)

6.4-6.7

Decomposition

temperature

Not Available

Melting point / freezing

point (°C)

Not Available

Viscosity (cSt)

Not Available

Initial boiling point and

boiling range (°C)

85-100

Molecular weight (g/mol)

Not Applicable

Flash point (°C)

Not Applicable

Taste

Not Available

Evaporation rate

Not Available

Explosive properties

Not Available

Flammability

Not Applicable

Oxidising properties

Not Available

Upper Explosive Limit (%)

Not Applicable

Surface Tension (dyn/cm or

mN/m)

Not Available

Lower Explosive Limit (%)

Not Applicable

Volatile Component (%vol)

80-90

Vapour pressure (kPa)

Not Available

Gas group

Not Available

Solubility in water (g/L)

Miscible

pH as a solution (1%)

Not Available

Vapour density (Air = 1)

Not Available

VOC g/L

Not Available

SECTION 10 STABILITY AND REACTIVITY

Reactivity

See section 7

Chemical stability

Unstable in the presence of incompatible materials.

Product is considered stable.

Hazardous polymerisation will not occur.

Possibility of hazardous

reactions

See section 7

Conditions to avoid

See section 7

Incompatible materials

See section 7

Hazardous decomposition

products

See section 5

Chemwatch: 36-6831

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RID 401100 Tropical Roll-On

Issue Date: 24/04/2015

Print Date: 27/04/2015

Continued...

Legend:

– Data required to make classification available

– Data available but does not fill the criteria for classification

– Data Not Available to make classification

SECTION 11 TOXICOLOGICAL INFORMATION

Information on toxicological effects

Inhaled

The material is not thought to produce adverse health effects or irritation of the respiratory tract (as classified by EC Directives using animal models).

Nevertheless, good hygiene practice requires that exposure be kept to a minimum and that suitable control measures be used in an occupational setting.

Not normally a hazard due to non-volatile nature of product

Ingestion

The material has NOT been classified by EC Directives or other classification systems as "harmful by ingestion". This is because of the lack of corroborating

animal or human evidence.

Skin Contact

The material is not thought to produce adverse health effects or skin irritation following contact (as classified by EC Directives using animal models).

Nevertheless, good hygiene practice requires that exposure be kept to a minimum and that suitable gloves be used in an occupational setting.

Application of Deet to the skin produces no primary skin irritation or sensitisation in humans. In rabbits, redness and peeling of the skin have been observed as

well as intoxication, excitation, stiffness and loss of co-ordination.

Eye

The liquid may produce eye discomfort causing smarting, pain and redness.

Chronic

Based on experience with similar materials, there is a possibility that exposure to the material may reduce fertility in humans at levels which do not cause other

toxic effects.

Exposure to DEET is usually by inhaling mists or vapours, or through skin contact/absorption.

Repeated exposure to DEET can cause slight irritation and dryness of the face, sloughing around the nose and a tingling sensation. Some individuals have

shown nervous system symptoms (muscle cramp, urinary hesitation, difficulty sleeping, abnormal sweating, irritability, depression, paranoia, confusion and

aggressive behaviour) and brain disease.

RID 401100 Tropical Roll-On

TOXICITY

IRRITATION

Not Available

Not Available

N,N-diethyl-m-toluamide

TOXICITY

IRRITATION

dermal (rat) LD50: 5000 mg/kg

Eye (rabbit) : 10 mg - moderate

Oral (rat) LD50: 1800 mg/kg

Eye (rabbit): 100 mg

Skin (rabbit): 500 mg - moderate

water

TOXICITY

IRRITATION

Oral (rat) LD50: >90000 mg/kg

Not Available

Legend:

1. Value obtained from Europe ECHA Registered Substances - Acute toxicity 2.* Value obtained from manufacturer's msds. Unless otherwise specified data

extracted from RTECS - Register of Toxic Effect of chemical Substances

N,N-DIETHYL-

M-TOLUAMIDE

For N,N-diethyl-m-toluamide (Deet)

Acute toxicity: Different preparations of Deet with different proportions of the m-isomer produced different oral LD50s. Rats killed by dosages in the LD50

range showed lacrimation, chromodacryorrhea, depression, prostration, tremors, and asphyxial convulsions. Respiratory failure usually preceded cardiac

failure.

In rabbits, an intravenous dosage of 75 mg/kg was rapidly fatal, but 50 mg/kg was not.

Reproductive effector in rats

RID 401100 Tropical Roll-On

& WATER

No significant acute toxicological data identified in literature search.

Acute Toxicity

Carcinogenicity

Skin Irritation/Corrosion

Reproductivity

Serious Eye

Damage/Irritation

STOT - Single Exposure

Respiratory or Skin

sensitisation

STOT - Repeated Exposure

Mutagenicity

Aspiration Hazard

CMR STATUS

Not Applicable

SECTION 12 ECOLOGICAL INFORMATION

Toxicity

Environmental Fate:

Soil: N,N-diethly-m-toluamide (DEET), an active ingredient in insect repellant, is found to be moderately mobile in soil and is stable to hydrolysis at soil pH level typically found in the environment.

Studies show that DEET can be biodegraded by soil microorganism e.g. P. putida.

Water: DEET, practically insoluble in water, was detected in water as a result of urban wastewater contamination to stream-flow.

Persistence and degradability

Ingredient

Persistence: Water/Soil

Persistence: Air

N,N-diethyl-m-toluamide

HIGH

HIGH

water

Chemwatch: 36-6831

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RID 401100 Tropical Roll-On

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Continued...

Bioaccumulative potential

Ingredient

Bioaccumulation

N,N-diethyl-m-toluamide

LOW (BCF = 2.4)

water

LOW (LogKOW = -1.38)

Mobility in soil

Ingredient

Mobility

N,N-diethyl-m-toluamide

LOW (KOC = 536.6)

water

LOW (KOC = 14.3)

SECTION 13 DISPOSAL CONSIDERATIONS

Waste treatment methods

Product / Packaging

disposal

Legislation addressing waste disposal requirements may differ by country, state and/ or territory. Each user must refer to laws operating in their area. In some

areas, certain wastes must be tracked.

A Hierarchy of Controls seems to be common - the user should investigate:

Reduction

Reuse

Recycling

Disposal (if all else fails)

This material may be recycled if unused, or if it has not been contaminated so as to make it unsuitable for its intended use.

SECTION 14 TRANSPORT INFORMATION

Labels Required

Marine Pollutant

HAZCHEM

Not Applicable

Land transport (ADG): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS

Air transport (ICAO-IATA / DGR): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS

Sea transport (IMDG-Code / GGVSee): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS

SECTION 15 REGULATORY INFORMATION

Safety, health and environmental regulations / legislation specific for the substance or mixture

N,N-diethyl-

m-toluamide(134-62-3) is

found on the following

regulatory lists

"Australia Inventory of Chemical Substances (AICS)","Australia Hazardous Substances Information System - Consolidated Lists"

water(7732-18-5) is found

on the following regulatory

lists

"Australia Inventory of Chemical Substances (AICS)"

National Inventory

Status

Australia - AICS

Canada - DSL

China - IECSC

Europe - EINEC / ELINCS /

Japan - ENCS

N (water)

Korea - KECI

New Zealand - NZIoC

Philippines - PICCS

USA - TSCA

Legend:

Y = All ingredients are on the inventory N = Not determined or one or more ingredients are not on the inventory and are not exempt from listing(see specific

ingredients in brackets)

SECTION 16 OTHER INFORMATION

Other information

Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification committee using

available literature references.

A list of reference resources used to assist the committee may be found at:

www.chemwatch.net

The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace or other

settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or available engineering controls must be considered.

This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or criticism, as permitted under the Copyright Act, no part may be reproduced by any

Chemwatch: 36-6831

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RID 401100 Tropical Roll-On

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Continued...

process without written permission from CHEMWATCH. TEL (+61 3) 9572 4700.

Chemwatch: 36-6831

Version No: 7.1.1.1

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RID 401100 Tropical Roll-On

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Print Date: 27/04/2015

end of SDS

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