PANOCTINE LIQUID FUNGICIDE

Australia - English - APVMA (Australian Pesticides and Veterinary Medicines Authority)

Active ingredient:
GUAZATINE ACETATES
Available from:
Grochem Australia Pty Ltd
INN (International Name):
guazatine acetate(400g/L)
Pharmaceutical form:
LIQUID
Composition:
GUAZATINE ACETATES GUANIDINE Active 400.0 g/L
Units in package:
1L - 50L
Class:
A - Agricultural
Therapeutic group:
CITRUS | ROCKMELON OR CANTALOUP | TOMATO | CANTALOUPE | CANTELOUP | GRAPEFRUIT | LEMON | LIME | MANDARIN | MUSK MELON | ORANGE
Therapeutic area:
FUNGICIDE
Therapeutic indications:
ALTERNARIA ROT | BLUE MOULD ON CITRUS - P. ITALICUM | GREEN MOULD | GREY MOULD - BOTRYTIS CINEREA | SOUR OR YEASTY ROT | STEM END ROTS | BOTRYTIS BLIGHT | BOTRYTIS ROT | BUNCH ROT
Product summary:
Poison schedule: 6; Withholding period: WHP: NOT REQUIRED WHEN USED AS DIRECTED .; Host/pest details: CITRUS: [BLUE MOULD ON CITRUS - P. ITALICUM, GREEN MOULD, SOUR OR YEASTY ROT]; CUCURBIT: [SOUR OR YEASTY ROT]; ROCKMELON OR CANTALOUP: [SOUR OR YEASTY ROT]; TOMATO: [ALTERNARIA ROT, GREY MOULD - BOTRYTIS CINEREA, SOUR OR YEASTY ROT, STEM END ROTS]; For the control of post harvest diseases of citrus, tomatoes and rockmelons.
Authorization status:
Registered
Authorization number:
54002
Authorization date:
2019-07-01

For Official Use Only

Page 1 of 3

e-Label Application (DRAFT)

Company Name:

Product Name:

eLabel Application No:

APVMA Approval No:

CROP CARE AUSTRALASIA PTY LTD

PANOCTINE LIQUID FUNGICIDE

DCNV-30327423E68

54002/102521

Product ID:

54002

Version No:

Application Started:

2015-Apr-27 17:14:52

Version Created:

2015-May-26 15:08:49

Started By:

Rita Kulkarni

Printed:

2015-May-26 15:11:21

Label Name:

PANOCTINE LIQUID FUNGICIDE

Signal Headings:

POISON

KEEP OUT OF REACH OF CHILDREN

READ SAFETY DIRECTIONS BEFORE OPENING OR USING

Constituent

Statements:

400 g/L GUAZATINE ACETATES

Mode of Action:

GROUP

M7

FUNGICIDE

Statement of

Claims:

For the control of post-harvest diseases of Citrus, Tomatoes and Rockmelons as specified

in the Directions for Use table.

Net Contents:

Directions for Use:

This section contains file attachment.

File Name: DIRECTIONS FOR USES - Panoctine 060515.pdf

File Size: 172047 bytes

Withholidng

Periods:

WITHHOLDING PERIOD: NOT REQUIRED WHEN USED AS DIRECTED.

Trade Advice:

Note: As Panoctine is not registered in all countries overseas, please check with a Crop

Care Australasia Pty Ltd. representative before treating produce destined for export.

RLP

APPROVED

For Official Use Only

Page 2 of 3

General

Instructions:

The use of Panoctine as a post harvest dip is a subject to an AFRAC anti-resistance

strategy:

1. For the last pre-harvest spray, use a fungicide with a different mode of action to the

fungicide planned for use as a post-harvest dip.

2. Handle fruit carefully to minimise potential infection sites caused by injury.

3. Ensure diseased fruit is promptly removed from the field and packing house and

destroyed.

4. Dip fruit promptly after harvest.

5. Do not store fruit in the packing house - move it through the packing house quickly.

6. Dispose of mouldy fungicide-treated fruit harvested - do not bring it into the packing

house.

7. Resistant strains of fungi can develop within the packing house. Where alternatives are

available, rotate to use as many different modes of action as possible.

8. Remove mouldy fruit from storage - isolate from other fruit.

9. Do not move fruit between packing houses - especially mouldy fruit.

MIXING

Add the required amount of product/s to the water in the dip tank, ensuring thorough mixing

between addition of each product. Agitate the solution during the dipping process.

IMPORTANT

Dip ingredients MUST NOT be mixed together in concentrated form. Add separately to the

full volume of water in the dip tank. To restore the original volume in the dip tank, add the

required water and then the appropriate amounts of Chemwet 1000 and Panoctine. To

restore the original volume in the dip-tank, add the required volume of water and then the

appropriate amounts of products. Dip should be replaced when dirt begins to accumulate.

To ensure effective coating of the fruit, the temperature of the fruit and the dip solution must

be the same.

PREPARING SPRAY (TOMATOES ONLY - NON-RECIRCULATING SPRAY)

Water should be at ambient temperature when applying the spray solution. Apply as a very

fine spray using hollow cone nozzles. Apply sufficient spray to wet the entire surface of the

fruit without causing significant run-off.

Resistance

Warning:

FUNGICIDE RESISTANCE WARNING

GROUP M7 FUNGICIDE

For fungicide resistance management Panoctine Liquid Fungicide is a Group M7 fungicide.

Some naturally occurring individual fungi resistant to Panoctine Liquid Fungicide and other

Group M7 fungicides may exist through normal genetic variability in any fungal population.

The resistant individuals can eventually dominate the fungi population if these fungicides

are used repeatedly. These resistant fungi will not be controlled by Panoctine Liquid

Fungicide and other Group M7 fungicides, thus resulting in a reduction in efficacy and

possible yield loss. Since the occurrence of resistant fungi is difficult to detect prior to use,

Crop Care Australasia Pty Ltd. accepts no liability for any losses that may result from the

failure of Panoctine Liquid Fungicide to control resistant fungi.

Protections:

PROTECTION OF WILDLIFE, FISH, CRUSTACEANS AND ENVIRONMENT

Dangerous to fish. DO NOT contaminate streams, rivers or water ways with the chemical or

used containers. DO NOT discharge waste liquid into streams.

Storage and

Disposal:

STORAGE AND DISPOSAL

Store in the closed, original container in a cool, well-ventilated area. DO NOT store for

prolonged periods in direct sunlight. Triple rinse containers before disposal. Add rinsings

to spray tank or dip. DO NOT dispose of undiluted chemicals onsite. If recycling, replace

For Official Use Only

Page 3 of 3

cap and return clean containers to recycler or designated collection point. If not recycling,

break, crush or puncture and deliver empty packaging to an approved waste management

facility. If an approved waste management facility is not available bury the empty packaging

500mm below the surface in a disposal pit specifically marked and set up for this purpose

clear of waterways, desirable vegetation and tree roots in compliance with relevant Local,

State or Territory government regulations. DO NOT burn empty containers or product.

DIP DISPOSAL

Unused or spent dip should be disposed of carefully to avoid contamination of streams,

rivers and waterways. Dispose of dip by pouring into a limed disposal pit set aside for this

purpose and clearly marked. Alternatively, spray onto soil or grassed area where runoff to

waterways or grazing by animals will not occur.

Safety Directions:

SAFETY DIRECTIONS

Product is harmful if swallowed or poisonous if inhaled. Will damage eyes. Avoid contact

with eyes. When opening the container and preparing the spray or dip, wear face shield or

goggles. If product in eyes, wash it out immediately with water. After use and before eating,

drinking or smoking, wash hands, arms, and face thoroughly with soap and water. After

each day’s use wash face shield or goggles.

First Aid

Instructions:

FIRST AID

If poisoning occurs, contact a Doctor or Poisons Information Centre. Phone Australia 13 11

26. If in eyes, hold eyes open, flood with water for at least 15 minutes and see a doctor.

First Aid Warnings:

DIRECTIONS FOR USE

(Qld, NSW, Vic, SA, WA, and NT only)

CROP

DISEASE

RATE

CRITICAL COMMENTS

Citrus

Green Mould (Penicillium digitatum

Blue Mould (Penicillium italicum)

Sour Rot (Geotrichum candidum)

1.3L/1000L water

Apply as a bulk dip within 24 hours of harvest. For packing line,

flood fruit for 30 seconds within 24 hours of harvest. Re-charge

dip with solution of 1.3L/1000L water.

Tomatoes

Grey Mould (Botrytis cinerea)

Alternaria Rot (Alternaria alternata)

Yeasty Rot (Geotrichum candidum)

Transit Rot (Rhizopus stolonifer)

250mL PLUS 16mL

Chemwet 1000 /100L water

For Non-Recirculating Spray Only:

Post-harvest washing in chlorinated water (50ppm) is

recommended. Before spraying with Panoctine

the fruit should

be cooled to below 35°C and dry. Spray fruit for 30 seconds as

soon as possible and no later than 24 hours after harvest. Allow

fruit to drain thoroughly and dry before packing.

Note: The level of disease control may vary between tomato

varieties. Panoctine is most effective on cv. Flora-Dade and

Pirate.

Rockmelons

Sour Rot (Geotrichum candidum)

1.3L/1000L water

Dip fruit for 45 seconds within 24 hours of harvest.

NOT TO BE USED FOR ANY PURPOSE OR IN ANY MANNER CONTRARY TO THIS LABEL

UNLESS AUTHORISED UNDER APPROPRIATE LEGISLATION

CS: 1.7.2

Page:

Safety Data Sheet

Infosafe No™ 3NUUG

July 2015

ISSUED by CRPCARE

Issue Date :

PANOCTINE LIQUID FUNGICIDE

Product Name

Classified as hazardous

1. Identification

PANOCTINE LIQUID FUNGICIDE

GHS Product

Identifier

0898

Product Code

Group M7 Fungicide

Product Type

Crop Care Australasia Pty Ltd (ABN 53 061 362 347)

Company Name

Unit 17/16 Metroplex Avenue Murarrie

Queensland 4172 Australia

Address

Tel: +61 7 3909 2000

Fax: +61 7 3909 2010

Telephone/Fax

Number

1800 033 498 (24hr Australia)

Emergency phone

number

For the control of post-harvest diseases of citrus, tomatoes and rockmelons as

specified in the Directions for Use table on the label.

Recommended use of

the chemical and

restrictions on use

This Safety Data Sheet describes the properties of the concentrated product.

The physical properties and the assessments may not apply to the properties of

the product once it has been diluted for application.

Other Information

2. Hazard Identification

OT4 Acute Toxicity - Oral: Category 4

DT4 Acute Toxicity - Dermal: Category 4

Acute Toxicity - Inhalation: Category 2

SC-2 Skin Corrosion/Irritation: Category 2

ED1 Eye Damage/Irritation: Category 1

SE-3RES STOT Single Exposure Category 3 (respiratory tract irritation)

GHS classification of

the

substance/mixture

DANGER

Signal Word (s)

H302 Harmful if swallowed.

H312 Harmful in contact with skin.

H330 Fatal if inhaled.

H315 Causes skin irritation.

H318 Causes serious eye damage.

H335 May cause respiratory irritation.

Hazard Statement (s)

P101 If medical advice is needed, have product container or label at hand.

P102 Keep out of reach of children.

P103 Read label before use.

General

Precautionary

Statement (s)

Skull and crossbones, Corrosion,

The below pictograms are GHS Hazard symbols for workplace use only.

See SECTION 14 for Dangerous Goods information.

Pictogram (s)

P261 Avoid breathing spray.

P264 Wash hands and exposed skin thoroughly after handling.

P270 Do not eat, drink or smoke when using this product.

P280 Wear eye and face protection.

Precautionary

statement –

Prevention

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a

position comfortable for breathing.

P310 Immediately call a POISON CENTER or doctor/physician.

P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel

unwell.

P330 Rinse mouth.

P302+P352 IF ON SKIN: Wash with plenty of soap and water.

P312 Call a POISON CENTER or doctor/physician if you feel unwell.

P332+P313 If skin irritation occurs: Get medical advice/attention.

P362 Take off contaminated clothing and wash before reuse.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes.

Remove contact lenses, if present and easy to do. Continue rinsing.

Precautionary

statement –

Response

Print Date: 31/07/2015

CS: 1.7.2

CS: 1.7.2

Page:

Safety Data Sheet

Infosafe No™ 3NUUG

July 2015

ISSUED by CRPCARE

Issue Date :

PANOCTINE LIQUID FUNGICIDE

Product Name

Classified as hazardous

P310 Immediately call a POISON CENTER or doctor/physician.

Poisons Schedule S6

Other Information

3. Composition/information on ingredients

Liquid

Chemical

Characterization

Name

CAS

Proportion

Ingredients

Guazatine (as the

acetate salt)

115044-19-4

400 g/L

Water

to 100%

4. First-aid measures

Remove affected person to fresh air until recovered. Obtain medical advice.

Inhalation

If swallowed do NOT induce vomiting; seek medical advice immediately and show

this container or label or contact the Poisons Information Centre on 13 11 26

(Aust). Make every effort to prevent vomit from entering the lungs by careful

placement of the patient.

Ingestion

If skin contact occurs, remove contaminated clothing and wash skin thoroughly

with water.

Wash affected areas thoroughly with soap and water.

Skin

If in eyes, hold eyelids open and wash with copious amounts of water for at

least 15 minutes.

Seek medical advice.

Eye contact

Treat symptomatically.

Advice to Doctor

5. Fire-fighting measures

Water fog, foam, carbon dioxide or dry chemical.

If involved in a fire, the product will not burn. Choose extinguishing

media to suit the burning material.

Suitable

extinguishing media

Breathable air apparatus should be worn when fighting a fire in which

panoctine is involved.

Special Protective

Equipment for fire

fighters

Hazchem Code

STOP FIRE WATER FROM ENTERING DRAINS OR WATER BODIES.

Other Information

6. Accidental release measures

Contain spill and absorb with clay, sand, soil or proprietary absorbent (such

as vermiculite).

Collect spilled material and waste in sealable open-top type containers for

disposal.

On-site disposal of concentrate is not acceptable.

Spills & Disposal

Prevent from entering drains, waterways or sewers.

Environmental

Precautions

7. Handling and storage

Store in the closed, original container in a dry, well ventilated area out of

direct sunlight.

Conditions for safe

storage, including

any

incompatabilities

Always read the label and any attached leaflet before use.

Other Information

8. Exposure controls/personal protection

No exposure standard has been established for this product.

Occupational

exposure limit values

Handle in well ventilated areas, generally natural ventilation is adequate.

Appropriate

engineering controls

It is good practice to wear suitable personal protective equipment (PPE).

When opening the container,

preparing product for use and using the prepared

product, wear cotton overalls buttoned to the neck and wrist (or equivalent

Personal Protective

Equipment

Print Date: 31/07/2015

CS: 1.7.2

CS: 1.7.2

Page:

Safety Data Sheet

Infosafe No™ 3NUUG

July 2015

ISSUED by CRPCARE

Issue Date :

PANOCTINE LIQUID FUNGICIDE

Product Name

Classified as hazardous

clothing), a washable hat, elbow-length PVC gloves, goggles and a half face

piece respirator.

When handling large quantities associated with industrial processing, in

enclosed areas, wear elbow length gloves, protective clothing, full face

protection and respiratory protection.

After use and before eating, drinking or smoking, wash hands, arms and face

thoroughly with soap and water.

After each day's use, wash contaminated clothing and safety equipment.

Hygiene Measures

Check State or Territory regulations that require people who use pesticides in

their job or business to have training in the application of the materials.

Requirements

Concerning Special

Training

9. Physical and chemical properties

Liquid

Form

Clear yellow-orange liquid.

Appearance

Vinegar odour.

Odour

<0°C

Melting Point

100°C (water)

Boiling Point

Soluble in water.

Solubility in Water

1.061 at 20°C

Specific Gravity

pH

<10-2 mPa at 50°C for guazatine

Vapour Pressure

Volatile Component

Non Flammable

Flash Point

Non flammable.

Flammability

10. Stability and reactivity

Stable under normal conditions.

Chemical Stability

Excessive heat and fire.

Conditions to Avoid

Avoid contact with oxidising agents, acids and bases.

Incompatible

Materials

Hazardous polymerisation is not possible.

Hazardous

Polymerization

11. Toxicological Information

No harmful effects are expected if the precautions on the label and this MSDS

are followed.

Toxicology

Information

LD50 (rat) 308 mg/kg for guazatine acetates

Acute Toxicity - Oral

LD50 (rat, percutaneous) >1000 mg/kg for guazatine acetates

Acute Toxicity -

Dermal

LC50 (rat) (4hr) 0.163 mg/l

Acute Toxicity -

Inhalation

The concentrate is harmful if swallowed.

Ingestion

May cause irritation to mucous membranes.

Inhalation

May irritate the skin.

Skin

Prolonged contact with the concentrate may cause damage to the eye.

Eye

Data indicates no carcinogenic effects.

Carcinogenicity

Data indicates no teratogenic effects.

Reproductive

Toxicity

The product is a severe eye irritant.

Serious eye

damage/irritation

Print Date: 31/07/2015

CS: 1.7.2

CS: 1.7.2

Page:

Safety Data Sheet

Infosafe No™ 3NUUG

July 2015

ISSUED by CRPCARE

Issue Date :

PANOCTINE LIQUID FUNGICIDE

Product Name

Classified as hazardous

The Australian Acceptable Daily Intake (ADI) for guazatine for a human is

0.006 mg/kg/day, set for the public for daily, lifetime exposure. This is

based on the NOEL of 0.625 mg/kg/day, the level determined to show no effects

during long term exposure for the most sensitive indicators and the most

sensitive species. (Ref: Comm. Dept. of Health and Ageing, Office of Chemical

Safety, 'ADI List', June 2014).

Other Information

12. Ecological information

Do not contaminate dams, waterways or sewers with this product or the

containers which have held this product.

Other Precautions

LC50 (96hr) for bluegill sunfish is 0.42 mg/l for guazatine acetate

Acute Toxicity - Fish

LC50 (48hr) for daphnia is 0.15 mg/l for guazatine acetate.

Acute Toxicity -

Daphnia

EC50 (72hr) for Raphidocelis subcapitata 0.0135 mg/l for guazatine.

Acute Toxicity -

Algae

LD50 for pigeons (with emetic effect) is 82 mg/kg

Bees: Not toxic to bees. LD50 (contact) >200 µg/bee.

Acute Toxicity -

Other Organisms

13. Disposal considerations

On site disposal of the concentrated product is not acceptable.

Ideally, the product should be used for its intended purpose. If there is a

need to dispose of the product, approach local authorities who hold periodic

collections of unwanted chemicals (ChemClear®).

Unused or spent dip should be disposed of carefully to avoid contamination

of streams, rivers and waterways.

Dispose of dip by pouring into a limed disposal pit set aside for this

purpose and clearly marked.

Alternatively, spray onto soil or grassed area where runoff to waterways or

grazing by animals will not occur.

Product Disposal

Do not use this container for any other purpose.

Triple or preferably pressure rinse containers before disposal. Add

rinsings to the dip/spray tank. If recycling, replace cap and return clean

containers to recycler or designated collection point.

If not recycling, break, crush or puncture and deliver empty packaging for

appropriate disposal at an approved waste management facility.

If an approved waste management facility is not available, bury the empty

packaging 500mm below the surface in a disposal pit specifically marked and

set up for this purpose clear of waterways, desirable vegetation and tree

roots, in compliance with relevant local, state or territory government

regulations.

DO NOT burn empty containers or product. drumMUSTER is the national program

for the collection and recycling of empty, cleaned, non returnable crop

production and on-farm animal health chemical containers. If the label on your

container carries the drumMUSTER symbol, triple rinse the container, ring your

local Council, and offer the container for collection in the program.

Container Disposal

14. Transport information

2902

U.N. Number

PESTICIDE, LIQUID, TOXIC, N.O.S. - (contains guazatine)

UN proper shipping

name

Transport hazard

class(es)

Hazchem Code

3.8.6

Packaging Method

Packing Group

Considered dangerous for transport by the Australian Code for the Transport of

Dangerous Goods by Road and Rail.

Storage and

Transport

EPG Number

IERG Number

Print Date: 31/07/2015

CS: 1.7.2

CS: 1.7.2

Page:

Safety Data Sheet

Infosafe No™ 3NUUG

July 2015

ISSUED by CRPCARE

Issue Date :

PANOCTINE LIQUID FUNGICIDE

Product Name

Classified as hazardous

2902

UN Number (Sea

Transport)

Class 6.1; Packing Group II

IMO Class/Packing

Group

Marine Pollutant

IMO Marine

Pollutant

PESTICIDE, LIQUID, TOXIC, N.O.S.(contains guazatine)

IMO Proper

Shipping Name

15. Regulatory information

Poisons Schedule

POISON

KEEP OUT OF REACH OF CHILDREN

READ SAFETY DIRECTIONS BEFORE OPENING OR USING

Packaging &

Labelling

This product is registered with the Australian Pesticides and Veterinary

Medicines Authority (APVMA). APVMA product number: TBA.

Other Information

16. Other Information

28/07/2015

Date of preparation

or last revision of

SDS

Normal Hours: Mrs Kathleen Marsh Phone: +61 3 9282 1000

After Hours: Shift Supervisor Phone: 1800 033 498

Contact

Person/Point

First Issue

Revisions

Highlighted

...End Of MSDS...

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Print Date: 31/07/2015

CS: 1.7.2

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