OFF! SKINTASTIC FAMILYCARE INSECT REPELLENT SPRAY NON GREASY & SOFTLY SCENTED

Australia - English - APVMA (Australian Pesticides and Veterinary Medicines Authority)

Active ingredient:
PICARIDIN
Available from:
S.C. JOHNSON & SON PTY LTD
INN (International Name):
picaridin(95g/kg)
Pharmaceutical form:
AEROSOL
Composition:
PICARIDIN PIPERIDINE Active 95.0 g/kg
Units in package:
150g; 250g; 275g; 300g
Class:
A - Agricultural
Manufactured by:
S.C. JOHNSON & SON
Therapeutic group:
PEST CONTROL - PERSONAL USE
Therapeutic area:
HOUSEHOLD INSECTICIDE
Therapeutic indications:
BITING INSECT | FLY | MOSQUITO | SAND FLY (BITING MIDGE) | ADULT MOSQUITOES
Product summary:
Poison schedule: 0; Withholding period: WHP: N/A; Host/pest details: PEST CONTROL - PERSONAL USE: [BITING INSECT, FLY, MOSQUITO, SAND FLY (BITING MIDGE)]; Poison schedule: 0; Withholding period: ; Host/pest details: PEST CONTROL - PERSONAL USE: [BITING INSECT, FLY, MOSQUITO, SAND FLY (BITING MIDGE)]; Repels up to 4 hours, repels mosquitoes, flies, sandflies and other biting insects.WARNING: NOT TO BE APPLIED TO INFANTS UNDER 12 MONTHS OF AGE UNLESS ON DOCTOR'S ADVICE. AVOID CONTACT WITH THE EYES. WILL CAUSE EYE IRRITATION.
Authorization status:
Registered
Authorization number:
51712
Authorization date:
2017-07-01

SC Johnson

A Family Company

Main pane/label

OFF!

®

Skintas

tic®

Familycare

INSECT RE,PELLENT SPRAY

greasy

& softly scented

Appro

ACTIVE CONSTITUENT: 95.0 g/kg PICARIDIN

(Graphic)

SUITABLE FOR CHILDREN 12 MONTHS & OVER

REPELS UP

HOURS

repels mosquitoes, flies, sandflies and other biting insects

(150, 250g, 275g, 300g) NET

Off! Familycare Insect Repellent Aerosol150g, 250g, 275g, 300g Picadirin

Logo

OFF logo

Page 1

Version 2 - 23.08.

2011

Infopest

Verified

Ancillary panel 1 (Label back panel)

OFF! ® Skintastic® familycare

rM

Insect Repellent Spray

with Picadirin, is

highly effective, yet

e

to skin

a softly scented, non greasy formula. It is

specially formulated for the whole family*, including children

months and

over, with up to 4 hours repellency against mosquitoes, flies, sandflies, and

other biting insects.

HOW TO USE:

Hold can upright and lightly spray all exposed skin in a slow

sweeping motion from a distance

15-20

em. Do not spray towards eyes

mouth. To apply to face, firstly spray on hands and rub on. Reapply as

necessary in cases

exc~ssive

perspiration.

*WARNING:

NOT TO BE APPLIED TO INFANTS UNDER

MONTHS

UNLESS ON DOCTOR'S ADVICE. WILL IRRITATE EYES. AVOID

CONTACT

WITH EYES.

NOT TO

BE

USED FOR ANY PURPOSE, OR

IN

ANY MANNER,

CONTRARY TO THIS LABEL UNLESS AUTHORISED.

PRECAUTION:

KEEP

OF REACH CHILDREN.

rash or irritation occurs, discontinue

use.

NOT spray near food and food utensils.

EXTREMELY

FLAMMABLE.

DO NOT SPRAY ON A NAKED FLAME OR ANY

INCANDESCENT MATERIAL. KEEP

AWAY

FROM SOURCES OF

IGNITION-

NO SMOKING. DO NOT STORE OR USE NEAR FIRE OR

. FLAME.

BEWARE:

INTENTIONAL MISUSE BY DELIBERATELY

CONCENTRATING AND INHALING CONTENTS CAN BE HARMFUL OR

FATAL.

STORAGE AND DISPOSAL:

PRESSURISED DISPENSER. PROTECT

FROM SUNLIGHT AND

EXPOSE

TEMPERATURES

EXCEEDING

5oc.

DO NOT PIERCE OR BURN EVEN AFTER USE.

Recycle empty cans

a facility is available

place used can in household

rubbish.

FIRST AID:

poisoning occurs, contact a doctor or Poisons Information

Centre. Phone Australia

New Zealand

0800 764 766.

APVMA Approval

No:

51712/

5"q

ERMA Approval No: HSR002552

PROPELLANT:

Hydrocarbon

MADE

AUSTRALIA

2012

Registered Trademark

S.C. Johnson & Son Inc

All Rights

Reserved.

Authorised Users:

S.C. Johnson

&

Son Pty Ltd

Epping Road Lane Cove

2066

Australia

Johnson & Son Pty Ltd

21-23

Vestey Drive,

Wellington, Auckland, New Zealand

Consumer

Advice Line: Australia

1800

New Zealand

0800 656 534

.scjohnson.com.au www.scjohnson.co.nz

A family company since 1886. Fisk Johnson signature

Label code xxxxxx

Flammable gas

logo

Recyclable steel

logo

Barcode

Consumer advice

line logo

Fisk Johnson

signature logo

Off! Familycare Insect Repellent Aerosol150g , 250g, 275g, 300g Picadirin

Page 2

Version 2 - 23.08.2011

ProductName: Off!® Skintastic Familycare™ Insect RepellentSprayNon

Greasy& Soft Scented

Page: 1 of 5

This revision issued: July, 2007

Section 1 - Identification of Chemical Product and Company

S.C. Johnson & Son Pty.Ltd. S.C. Johnson & Son Pty.Ltd.

A.C.N. 000021 009 21-23 Vestey Drive

160 Epping Road, Lane Cove, N.S.W. 2066. Australia Mt. Wellington, Auckland

(Private Bag22, Lane Cove, NSW 2066 Australia) New Zealand

Telephone:(61)(02) 9428-9111 Telephone (64)(09)573-2850

Fax: (61)(02) 9428-9169 Fax: (64)(09) 573-2888

Poisons Information Centre: (61) 131126 National Poisons: (64) 0800 764 766

Substance: Picaridin based formulation in ethanol.Presented asan aerosol.

Trade Name: Off! ® Skintastic ®

FamilycareInsect Repellent SprayNon Greasy

& Soft Scented

Formula code:632000/1

APVMA Code:51712

Product Codes:861217 Off! ® Familycare™Insect Repellent Aerosol Spray 150g AU

Product Use: Household insect repellent.

Creation Date: July, 2007

Revision Date: July, 2007

Section 2 -Hazards Identification

Statement of Hazardous Nature

This productis classifiedas:F, Flammable. Not classified ashazardous according to the criteria of ASCC.

Dangerous according to the AustralianDangerous Goods (ADG)Code.

Risk Phrases:R10. Flammable.

SafetyPhrases:S16, S23, S25. Keep away fromsources of ignition - Nosmoking. Do not breathe spraymists.

Avoid contact with eyes.

SUSDP Classification:None allocated.

ADG Classification:Class 2.1, (AEROSOLS)

UN Number:1950

EmergencyOverview

Physical Description & Colour: Clear, colourless liquid.

Odour:Pleasant floral/alcohol fragrance.

Major Health Hazards:no significant risk factors have been found for this product.

Potential Health Effects

Inhalation:

Short TermExposure:Available data indicates that this product isnot harmful. In additionproduct is unlikely to

cause any discomfort or irritation. Intentional misuseby deliberately concentrating andinhaling contents ofaerosol

containers can be harmful or fatal.

Long Term Exposure:No data for health effectsassociatedwith long term inhalation.

Skin Contact:

Short TermExposure:Major healtheffectfrom thisproduct ismisuseof the aerosol function. If sprayed

continuously on skin or ineyes, it can cause frostbite.

Long Term Exposure:No data for health effectsassociatedwith long term skin exposure.

Eye Contact:

Short TermExposure:If sprayed directly in the eye, this product willirritate. If sprayingis prolonged, it may cause

damage through frostbite.

Long Term Exposure:No data for health effectsassociatedwith long term eye exposure.

Issued by: S.C. Johnson& Son Pty.Ltd. Phone: (02) 9428 9111

Poisons Information Centre: 131126 from anywhere in Australia, (0800 764766 in NewZealand)

ProductName: Off!® Skintastic Familycare™ Insect RepellentSprayNonGreasy& Soft Scented

Page: 2 of 5

This revision issued: July, 2007

Ingestion:

Short TermExposure:Significant oral exposure isconsideredto be unlikely. However, thisproduct may be mildly

irritating to mucous membranes but is unlikely to cause anything more thanmild transient discomfort.

Long Term Exposure:No data for health effectsassociatedwith long term ingestion.

Carcinogen Status:

ASCC:No significant ingredient isclassified ascarcinogenic by ASCC.

NTP:No significant ingredient is classified as carcinogenic by NTP.

IARC:No significant ingredient isclassified ascarcinogenic by IARC.

Section 3 - Composition/Information on Ingredients

Ingredients CAS No Conc,% TWA (mg/m 3 ) STEL (mg/m 3 )

Ethanol64-17-5 >80 1880 not set

Picaridin 119515-38-795g/L not set not set

Carbon dioxide 124-38-9 5 9000 54000

Other non hazardous ingredients secret to 100 not set not set

This isa commercial product whose exact ratio of components may vary slightly. Minor quantities of other non

hazardousingredients arealso possible.

The ASCCTWAexposurevalue is the averageairborne concentration of a particularsubstance whencalculated over a normal 8 hour workingday

for a 5 dayworkingweek. The STEL (ShortTermExposure Limit) isan exposure value thatmaybe equalled (but should not be exceeded) forno

longer than 15 minutes and should not be repeated more than4 times per day. There should be at least 60 minutes between successive exposures

at the STEL.Theterm "peak "is used when theTWA limit, becauseof the rapid action of the substance, should never be exceeded, even briefly.

Section 4 -First Aid Measures

General Information:

You should call The Poisons Information Centre if youfeel that you may have been poisoned, burned orirritated by

this product. The number is13 1126 fromanywhere in Australia (0800 764 766 in New Zealand) and is available at all

times.Have thisMSDS withyou when you call.

Inhalation:First aid isnot generally required. If in doubt, contact a Poisons Information Centre or a doctor.

Skin Contact:Irritation isunlikely. However, if irritation does occur, flushwith lukewarm, gently flowing water for 5

minutes oruntil product is removed.

Eye Contact:No effects expected. If irritation doesoccur, flushcontaminatedeye(s) with lukewarm, gently flowing

water for 5 minutes oruntil the product is removed. Obtainmedical advice if irritation becomespainful or lasts more

than a few minutes. Takespecial care ifexposed person is wearingcontact lenses.

Ingestion:If product isswallowed or gets in mouth, doNOT induce vomiting; wash mouth with water and give some

water to drink. If symptoms develop, or if in doubtcontact a Poisons InformationCentre or a doctor.

Section 5 -Fire FightingMeasures

Fire and Explosion Hazards: Thereis a moderaterisk of an explosion fromthis product ifcommercialquantities

are involved ina fire. Vapours from thisproduct are heavier than air and may accumulate in sumps, pitsand other

low-lying spaces, formingpotentially explosive mixtures. They mayalso flash backconsiderable distances.

Fire decomposition products from this product may be toxic if inhaled. Take appropriate protective measures.

Extinguishing Media:Preferred extinguishing media are carbondioxide, dry chemical, foam, water fog. Water fog

or fine spray isthe preferred medium forlarge fires. If practical, contain materialand prevent from enteringdrainsand

water courses.

Fire Fighting:Immediately evacuate the areaof unnecessary personnel.

Flash point: No specific data. Flammable liquid

Upper FlammabilityLimit:No data.

Lower FlammabilityLimit:No data.

Autoignitiontemperature:No data.

Flammability Class:Flammable.

Section 6 -Accidental Release Measures

Accidental release:In the event of a majorspill,prevent spillage fromentering drains or water courses. As a

minimum, wear overalls, gogglesand gloves. Suitable materials for protective clothing include rubber, PVC. Eye/face

protective equipment should comprise asa minimum,protective glasses and, preferably, goggles. If there isa

Issued by: S.C. Johnson& Son Pty.Ltd. Phone: (02) 9428 9111

Poisons Information Centre: 131126 from anywhere in Australia, (0800 764766 in NewZealand)

ProductName: Off!® Skintastic Familycare™ Insect RepellentSprayNonGreasy& Soft Scented

Page: 3 of 5

This revision issued: July, 2007

significant chance that vapours or mistsare likely to build up in thecleanup area,we recommend that you use a

respirator. It should befitted with a type Acartridge, suitable for organic vapours.

Stop leak if safe to do so, and containspill. Absorb onto sand, vermiculite orother suitable absorbent material. If spill

is too large or if absorbent material isnot available, try tocreate adike to stopmaterialspreading orgoinginto drains

or waterways. If containers are leaking, they may cause oxygen levels inimmediate areas to reach dangerously low

levels. Take suitable precautions. Sweepup andshovel orcollect recoverable product into labelledcontainers for

recycling orsalvage, and dispose of promptly. Recycle containerswhereverpossible aftercareful cleaning.After

spills, wash area preventing runoff fromentering drains. Ifa significant quantity of material enters drains, advise

emergency services. Thismaterial maybe suitable for approved landfill. Ensure legality of disposal by consulting

regulationsprior to disposal. Thoroughly launder protectiveclothing beforestorage or re-use. Advise laundryof nature

of contamination when sending contaminated clothingto laundry.

Section 7 -Handlingand Storage

Handling:Keep exposureto this product to a minimum, and minimise the quantities kept in work areas. Check

Section 8 of this MSDS for details of personal protectivemeasures,and make sure that those measures arefollowed.

The measuresdetailed below under "Storage" shouldbe followed during handling in order tominimise risks to

personsusing the productin the workplace. Also, avoidcontact or contamination of productwith incompatible

materials listed in Section 10.

Storage:Store in a cool, well ventilated area. Check containersand valves periodically for leaks. Check packaging -

there may befurtherstorage instructionson the label.

Section 8 - Exposure Controls and Personal Protection

The followingAustralian Standards will provide general advice regarding safety clothing and equipment:

Respiratory equipment:AS/NZS 1715, Protective Gloves:AS 2161, Industrial Clothing:AS2919, Industrial Eye

Protection:AS1336andAS/NZS 1337, Occupational ProtectiveFootwear:AS/NZS2210.

ASCCExposure Limits TWA (mg/m 3 ) STEL (mg/m 3 )

Ethanol1880 not set

Carbon dioxide 9000 54000

No special equipment is usually neededwhenoccasionallyhandlingsmall quantities. The following instructions are

for bulk handling or where regularexposure in an occupational setting occurswithout propercontainment systems.

Ventilation:This productshould only be used wherethere isventilation that is adequate to keep exposurebelow

the TWA levels. If necessary, use a fan.

Eye Protection:Eye protection isnot normally necessary whenthis product is beingused.However, if in doubt,

wearsuitableprotective glasses or goggles.

Skin Protection:The information at hand indicates that this product is not harmful and that normally no special skin

protection isnecessary. However, we suggest that you routinely avoid contactwith all chemical productsand that you

wearsuitablegloves (preferably elbow-length)whenskin contact islikely.

Protective Material Types:There is no specific recommendation for anyparticularprotective material type. Use

impermeable glovessuch asrubber.

Respirator:Usually, no respiratoris necessary whenusing this product. However, if you have any doubts consult

the AustralianStandard mentioned above.

Section 9 - Physical and Chemical Properties

Physical Description & colour:Clear, colourless liquid.

Odour: Pleasant floral/alcohol fragrance.

Boiling Point: Approx 78°Cat 100kPa(ethanol)

Freezing/Melting Point: No specific data. Liquid at normal temperatures.

Volatiles:>90%

Vapour Pressure:No data.

Vapour Density:No data.

Specific Gravity:Approx 0.80

Water Solubility:Soluble.

pH:No data.

Volatility:No data.

Odour Threshold:No data.

Evaporation Rate:No data.

Coeff Oil/water Distribution: No data

Autoignition temp:No data.

Issued by: S.C. Johnson& Son Pty.Ltd. Phone: (02) 9428 9111

Poisons Information Centre: 131126 from anywhere in Australia, (0800 764766 in NewZealand)

ProductName: Off!® Skintastic Familycare™ Insect RepellentSprayNonGreasy& Soft Scented

Page: 4 of 5

This revision issued: July, 2007

Section 10 -Stabilityand Reactivity

Reactivity:This product isunlikely to react ordecompose undernormal storage conditions. However, if you have

any doubts, contact the supplier for advice onshelf life properties.

Conditions to Avoid:This product should bekept in a cool place,preferably below30°C. Keep containers tightly

closed. Containers shouldbe kept dry.Keep containers and surroundingareaswell ventilated. Keep awayfrom

sources ofsparks orignition.

Incompatibilities:acids,strongoxidising agents.

Fire Decomposition:Carbondioxide,and if combustion isincomplete, carbonmonoxide and smoke. Nitrogen and

its compounds, and undersomecircumstances, oxides ofnitrogen. Occasionallyhydrogencyanide gas inreducing

atmospheres. Water. Carbon monoxide poisoning producesheadache, weakness, nausea, dizziness, confusion,

dimness of vision, disturbance of judgment,and unconsciousness followed by coma and death.

Polymerisation:This product will not undergo polymerisation reactions.

Section 11 -Toxicological Information

Local Effects:

Target Organs: There is no data to hand indicatingany particular target organs.

Classification of Hazardous Ingredients

IngredientRisk Phrases

Picaridin:LD

Oral, Rat 2236-4743mg/kg LD

Dermal, Rat =>2000mg/kg

Inhalation, Rat = >4.364mg/L/4hr

Shown to benon mutagenic, non carcinogenic, not a skin sensitiser.

Section 12 -Ecological Information

This product isbiodegradable. It will notaccumulate in the soil orwater orcause long term problems.

Fish:LC

rainbow trout: 173mg/L

Green algae:Scenedesmus subspicatus: The study was of 72 hourendurance and included 6nominal

concentrationsranging from5.6 mg/l to100 mg/l. Effectswere determined withinthe range of56 mg/l and 100 mg/l.

The NOEC and LOECwere determinedto be 56 mg/l.

Daphnia Magna: Picaridin was testedat five concentrationsranging from 10 mg/l to 100 mg/l at 24 and 48hours. No

effects were found at any concentration.

Avian Dietary: Non-toxic. Bobwhite quail: LC

>5000ppm a.i.-diet. Based on the results of this study, Picaridin can

be considered as non-toxic to birds.

Section 13 -Disposal Considerations

Disposal:There are manypiecesof legislation covering wastedisposal and theydiffer in each state and territory, so

each user must refer to laws operating intheir area. In someareas, certain wastesmust be tracked. TheHierarchy of

Controlsseems to be common - the usershould investigate: Reduce, Reuse, and Recycle and only if all else fails

should disposal be considered. Note thatproperties of a product may change in use, so that the followingsuggestions

may not always be appropriate. The following may help you inproperly addressing this matter for thisproduct. This

product maybe recycledif unused, or if it has not been contaminated so asto make it unsuitable for its intended use.

If it has been contaminated, it may be possible to reclaim the product by filtration, distillation or some other means. If

neither of these options issuitable, consider controlled incineration,or landfill.

Section 14 -Transport Information

ADG Code:1950, AEROSOLS

Hazchem Code:2[Y]E

Special Provisions:SP63, SP190, SP229, SP227

Dangerous Goods Class:Class 2.1,Flammable gases.

Packaging Group:Not set

Packaging Method:No packaging methods specified.

Class 2.1 Flammable gases shall not beloaded in thesamevehicleor packed in the same freight containerwith

Classes 1 (Explosives), 3 (Flammable Liquids) (where both flammable liquidsand flammablegasesare in bulk), 4.1

(FlammableSolids), 4.2 (Spontaneously Combustible Substances), 4.3 (DangerousWhenWet Substances), 5.1

(Oxidising Agents), 5.2 (Organic Peroxides), and 7 (Radioactive Substances). They may however be loadedin the

Issued by: S.C. Johnson& Son Pty.Ltd. Phone: (02) 9428 9111

Poisons Information Centre: 131126 from anywhere in Australia, (0800 764766 in NewZealand)

ProductName: Off!® Skintastic Familycare™ Insect RepellentSprayNonGreasy& Soft Scented

Page: 5 of 5

This revision issued: July, 2007

same vehicleor packed in the samefreight containerwith Classes 2.2 (Non-flammable Non-Toxic gases), 3

(Flammable liquidsexcept where both flammable liquids andflammable gasesare in bulk), 6 (Toxic Substances), 8

(Corrosive Substances) 9(Miscellaneous dangerous goods), Foodstuffs and foodstuff empties.

Section 15 -RegulatoryInformation

AICS:All of the significant ingredients inthis formulation arecompliant with NICNAS regulations.

Section16 -Other Information

This MSDS contains onlysafety-related information. For other data see product literature.

Acronyms:

ADG Code Australian Code for the Transport of Dangerous Goods by Road and Rail

AICS Australian Inventory of Chemical Substances

ASCC Office of the Australian Safety and CompensationCouncil

CAS Number Chemical Abstracts Service Registry Number

HazchemCode Emergency action code ofnumbers andletters that provide information to

emergency servicesespecially firefighters

IARC International Agency forResearch onCancer

NOS Not otherwisespecified

NTP National Toxicology Program (USA)

R-PhraseRisk Phrase

SUSDP Standard for the Uniform Scheduling ofDrugs & Poisons

UN NumberUnited Nations Number

THIS MSDS SUMMARISES OUR BEST KNOWLEDGEOFTHEHEALTHAND SAFETYHAZARD INFORMATIONOFTHE PRODUCT AND

HOW TOSAFELYHANDLE ANDUSE THE PRODUCT INTHE WORKPLACE.EACH USER MUSTREVIEW THIS MSDS IN THECONTEXTOF

HOW THE PRODUCT WILLBE HANDLEDANDUSED IN THE WORKPLACE.

IF CLARIFICATIONORFURTHER INFORMATION IS NEEDEDTOENSURETHATAN APPROPRIATE RISK ASSESSMENT CANBE MADE,

THE USER SHOULD CONTACTTHIS COMPANY SOWE CAN ATTEMPT TOOBTAIN ADDITIONAL INFORMATION FROMOUR SUPPLIERS

OURRESPONSIBILITYFOR PRODUCTS SOLDIS SUBJECT TO OURSTANDARD TERMS ANDCONDITIONS, ACOPYOFWHICH IS SENT

TOOUR CUSTOMERS AND IS ALSOAVAILABLEONREQUEST.

Please read all labels carefully before using product.

This MSDS isprepared in accord with the ASCCdocument “National Code of Practice for the Preparation

of Material Safety DataSheets” 2nd Edition [NOHSC:2011(2003)]

Issued by: S.C. Johnson& Son Pty.Ltd. Phone: (02) 9428 9111

Poisons Information Centre: 131126 from anywhere in Australia, (0800 764766 in NewZealand)

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