neodisher SB eco

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Read the complete document

Date revised: 23.05.2017

Print date: 26.05.17

2 / GB- 800142-014-01

Version: 2 / GB

Replaces Version: 1 /

Safety data sheet in accordance with regulation (EC) No

1907/2006

neodisher SB eco

Page 1(8)

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

neodisher SB eco

1.2. Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/preparation

Washing and cleaning products (including solvent based products)

1.3. Details of the supplier of the safety data sheet

Address:

Chemische Fabrik Dr. Weigert GmbH & Co. KG

Mühlenhagen 85

D-20539 Hamburg

Telephone no.

+49 40 789 60 0

Fax no.

+49 40 789 60 120

www.drweigert.com

E-mail address of person responsible for this SDS:

sida@drweigert.de

1.4. Emergency telephone number

GBK/ Infotrac: (USA domestic) 1 800 535 5053 or international +1 352 323 3500

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification (Regulation (EC) No. 1272/2008)

Classification (Regulation (EC) No. 1272/2008)

Eye Irrit. 2

H319

2.2. Label elements

Labelling according to regulation (EC) No 1272/2008

Hazard pictograms

Signal word

Warning

Hazard statements

H319

Causes serious eye irritation.

Precautionary statements

P280

Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact

lenses, if present and easy to do. Continue rinsing.

P337+P313

If eye irritation persists: Get medical advice/attention.

Dispose only when container is empty and closed. For disposal of product

residues, refer to Safety Data Sheet.

Date revised: 23.05.2017

Print date: 26.05.17

2 / GB- 800142-014-01

Version: 2 / GB

Replaces Version: 1 /

Safety data sheet in accordance with regulation (EC) No

1907/2006

neodisher SB eco

Page 2(8)

2.3. Other hazards

No special hazards have to be mentioned.

SECTION 3: Composition/information on ingredients

3.2. Mixtures

Hazardous ingredients

citric acid, anhydrous

CAS No.

77-92-9

EINECS no.

201-069-1

Registration no.

01-2119457026-42

Concentration

>=

<

Classification (Regulation (EC) No. 1272/2008)

Eye Irrit. 2

H319

SECTION 4: First aid measures

4.1. Description of first aid measures

General information

Remove contaminated, soaked clothing immediately and dispose of safely.

After inhalation

Ensure supply of fresh air. In the event of symptoms take medical treatment.

After skin contact

After contact with skin, wash immediately with plenty of water. Consult a doctor if skin irritation persists.

After eye contact

In case of contact with the eyes, rinse immediately for at least 15 minutes with plenty of water. In case of

irritation consult an oculist.

After ingestion

Rinse mouth thoroughly with water.

Adhere to personal protective measures when giving first aid

First aider: Pay attention to self-protection!

4.2. Most important symptoms and effects, both acute and delayed

Until now no symptoms known so far.

4.3. Indication of any immediate medical attention and special treatment needed

Hints for the physician / hazards

In the case of swallowing with subsequent vomiting, aspiration of the lungs can occur which can lead to

chemical pneumonia or asphyxiation.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media

Product itself is non-combustible; adapt fire extinguishing measures to surrounding areas.

Non suitable extinguishing media

Full water jet

5.2. Special hazards arising from the substance or mixture

In case of combustion evolution of dangerous gases possible.

Date revised: 23.05.2017

Print date: 26.05.17

2 / GB- 800142-014-01

Version: 2 / GB

Replaces Version: 1 /

Safety data sheet in accordance with regulation (EC) No

1907/2006

neodisher SB eco

Page 3(8)

5.3. Advice for firefighters

Special protective equipment for fire-fighting

Do not inhale explosion and/or combustion gases. In case of combustion use a suitable breathing

apparatus.

Other information

Collect contaminated fire-fighting water separately, must not be discharged into the drains. Fire residues

and contaminated fire-fighting water must be disposed of in accordance with the local regulations.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Avoid contact with skin, eyes and clothing. Refer to protective measures listed in Sections 7 and 8.

6.2. Environmental precautions

Do not discharge into the drains/surface waters/groundwater.

6.3. Methods and material for containment and cleaning up

Pick up with absorbent material. Dispose of absorbed material in accordance with the regulations.

6.4. Reference to other sections

Refer to protective measures listed in Sections 7 and 8.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Advice on safe handling

Avoid formation of aerosols. Observe the usual precautions for handling chemicals. Keep container

tightly closed.

Advice on protection against fire and explosion

The product is not combustible.

7.2. Conditions for safe storage, including any incompatibilities

Recommended storage temperature

Value

>

<

Requirements for storage rooms and vessels

Keep in original packaging, tightly closed. Storage rooms must be properly ventilated. Containers which

are opened must be carefully resealed and kept upright to prevent leakage.

Storage class according to TRGS 510

Storage class according to

TRGS 510

10-13

Other combustible and non-combustible substances

7.3. Specific end use(s)

no data

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Other information

There are not known any further control parameters.

8.2. Exposure controls

General protective and hygiene measures

Hold eye wash fountain available. Do not inhale gases/vapours/aerosols. Avoid contact with skin and

Date revised: 23.05.2017

Print date: 26.05.17

2 / GB- 800142-014-01

Version: 2 / GB

Replaces Version: 1 /

Safety data sheet in accordance with regulation (EC) No

1907/2006

neodisher SB eco

Page 4(8)

eyes. Do not eat, drink or smoke during work time. Wash hands before breaks and after work.

Respiratory protection

Not necessary, but do not inhale vapours. If workplace limits are exceeded, a respiratory protection

approved for this particular job must be worn.

Hand protection

Chemical resistant gloves (EN 374)

Permanent hand contact

Appropriate Material

neoprene

Material thickness

>=

0,65

Breakthrough time

>

Appropriate Material

nitrile

Material thickness

>=

Breakthrough time

>

Appropriate Material

butyl

Material thickness

>=

Breakthrough time

>

Short-term hand contact

Appropriate Material

nitrile

Material thickness

>=

0,11

Hand protection must comply with EN 374.

Eye protection

Safety glasses with side protection shield (EN 166)

Body protection

Clothing as usual in the chemical industry.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Form

liquid

Colour

colourless

Odour

characteristic

Odour threshold

Remarks

not determined

pH value

Value

appr.

Temperature

Melting point

Remarks

not determined

Freezing point

Remarks

not determined

Initial boiling point and boiling range

Remarks

not determined

Flash point

Remarks

Not applicable

Evaporation rate (ether = 1) :

Remarks

not determined

Flammability (solid, gas)

evaluation

not determined

Upper/lower flammability or explosive limits

Remarks

not determined

Date revised: 23.05.2017

Print date: 26.05.17

2 / GB- 800142-014-01

Version: 2 / GB

Replaces Version: 1 /

Safety data sheet in accordance with regulation (EC) No

1907/2006

neodisher SB eco

Page 5(8)

Vapour pressure

Remarks

not determined

Vapour density

Remarks

not determined

Density

Value

1,09

g/cm³

Temperature

Solubility in water

Remarks

miscible in all proportions

Solubility(ies)

Remarks

not determined

Partition coefficient: n-octanol/water

Remarks

not determined

Ignition temperature

Remarks

not determined

Decomposition temperature

Remarks

not determined

Viscosity

dynamic

Value

<

mPa.s

Temperature

Explosive properties

evaluation

not determined

Oxidising properties

evaluation

None known

9.2. Other information

Other information

None known

SECTION 10: Stability and reactivity

10.1. Reactivity

No hazardous reactions when stored and handled according to prescribed instructions.

10.2. Chemical stability

No hazardous reactions known.

10.3. Possibility of hazardous reactions

No hazardous reactions known.

10.4. Conditions to avoid

No hazardous reactions known.

Decomposition temperature

Remarks

not determined

10.5. Incompatible materials

Reactions with alkalies.

10.6. Hazardous decomposition products

Irritant gases/vapours

Date revised: 23.05.2017

Print date: 26.05.17

2 / GB- 800142-014-01

Version: 2 / GB

Replaces Version: 1 /

Safety data sheet in accordance with regulation (EC) No

1907/2006

neodisher SB eco

Page 6(8)

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute oral toxicity

Species

LD50

>

2000

mg/kg

Method

calculated value (Regulation (EC) No. 1272/2008)

Acute oral toxicity (Components)

citric acid, anhydrous

Species

LD50

11700

mg/kg

citric acid, anhydrous

Species

mouse

LD50

5040

mg/kg

Acute dermal toxicity

Remarks

Based on available data, the classification criteria are not met.

Acute inhalational toxicity

Remarks

Based on available data, the classification criteria are not met.

Skin corrosion/irritation

Remarks

Based on available data, the classification criteria are not met.

Serious eye damage/irritation

evaluation

irritant

Sensitization

Remarks

Based on available data, the classification criteria are not met.

Subacute, subchronic, chronic toxicity

Remarks

Based on available data, the classification criteria are not met.

Mutagenicity

Remarks

Based on available data, the classification criteria are not met.

Reproductive toxicity

Remarks

Based on available data, the classification criteria are not met.

Carcinogenicity

Remarks

Based on available data, the classification criteria are not met.

Specific Target Organ Toxicity (STOT)

Remarks

not determined

Aspiration hazard

No special hazards have to be mentioned.

Experience in practice

Inhalation may lead to irritation of the respiratory tract.

Other information

There is no data available on the product apart from the information given in this subsection.

SECTION 12: Ecological information

12.1. Toxicity

General information

not determined

Fish toxicity (Components)

Date revised: 23.05.2017

Print date: 26.05.17

2 / GB- 800142-014-01

Version: 2 / GB

Replaces Version: 1 /

Safety data sheet in accordance with regulation (EC) No

1907/2006

neodisher SB eco

Page 7(8)

citric acid, anhydrous

Species

golden orfe (Leuciscus idus)

LC50

mg/l

Duration of exposure

Daphnia toxicity (Components)

citric acid, anhydrous

Species

Daphnia magna

EC50

mg/l

Duration of exposure

12.2. Persistence and degradability

General information

not determined

12.3. Bioaccumulative potential

General information

not determined

Partition coefficient: n-octanol/water

Remarks

not determined

12.4. Mobility in soil

General information

not determined

12.5. Results of PBT and vPvB assessment

General information

not determined

Evaluation of persistance and bioaccumulation potential

The product contains no PBT or vPvB substances.

12.6. Other adverse effects

General information

not determined

General information / ecology

Do not allow to enter soil, waterways or waste water canal. Avoid release into the atmosphere.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Disposal recommendations for the product

Allocation of a waste code number, according to the European Waste Catalogue (EWC), should be

carried out in agreement with the regional waste disposal company.

Disposal recommendations for packaging

Packaging that cannot be cleaned should be disposed off in agreement with the regional waste disposal

company.

SECTION 14: Transport information

Land transport ADR/RID

Marine transport

IMDG/GGVSee

Air transport ICAO/IATA

14.1. UN number

Non-dangerous goods

The product does not constitute a

The product does not constitute a

Date revised: 23.05.2017

Print date: 26.05.17

2 / GB- 800142-014-01

Version: 2 / GB

Replaces Version: 1 /

Safety data sheet in accordance with regulation (EC) No

1907/2006

neodisher SB eco

Page 8(8)

hazardous substance in sea

transport.

hazardous substance in air

transport.

Information for all modes of transport

14.6. Special precautions for user

See Sections 6 to 8

Other information

14.7. Transport in bulk according to Annex II of Marpol and the IBC Code

Not applicable

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance

or mixture

Ingredients (Regulation (EC) No 648/2004)

less than 5 %:

polycarboxylates

Further ingredients

preservation agents: Potassium sorbate, A mixture of: 5-Chloro-2-methyl-2h-isothiazol-3-one [EC-no.

247-500-7] and 2-Methyl-2H-isothiazol-3-one [EC-no. 220-239-6] (3:1)

Water Hazard Class (Germany)

Water Hazard Class

(Germany)

WGK 1

Remarks

Classification according to Annex 4 VwVwS

VOC

VOC (EU)

Other information

The product does not contain substances of very high concern (SVHC).

15.2. Chemical safety assessment

For this preparation a chemical safety assessment has not been carried out.

SECTION 16: Other information

Hazard statements listed in Chapter 3

H319

Causes serious eye irritation.

CLP categories listed in Chapter 3

Eye Irrit. 2

Eye irritation, Category 2

Supplemental information

Relevant changes compared with the previous version of the safety data sheet are marked with: ***

This information is based on our present state of knowledge. However, it should not constitute a

guarantee for any specific product properties and shall not establish a legally valid relationship.

Read the complete document

www.drweigert.com

With the above information, which is appropriate to our current knowledge we describe our product regarding possible safety necessities, but we do not involve any quality description or

promise certain properties.

Chemische Fabrik Dr. Weigert GmbH & Co. KG

Tel.: +49-40-7 89 60-0

info@drweigert.de

Mühlenhagen 85 D-20539 Hamburg

Fax: +49-40-7 89 60-120

www.drweigert.com

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