MARK-IT

Australia - English - APVMA (Australian Pesticides and Veterinary Medicines Authority)

Active ingredient:
RHODAMINE B
Available from:
SST AUSTRALIA PTY. LTD.
INN (International Name):
rhodamine B(150g/L)
Pharmaceutical form:
LIQUID
Composition:
RHODAMINE B DYE-RED Active 150.0 g/L
Units in package:
0.25L; 0.5L; 110L; 1L; 200L; 20L; 5L
Class:
A - Agricultural
Manufactured by:
SST AUSTRALIA
Therapeutic group:
PESTICIDE ADDITIVE
Therapeutic area:
MARKER
Therapeutic indications:
DYE MARKER | FOAM MARKER
Product summary:
Poison schedule: 0; Withholding period: WHP: N/A; Host/pest details: PESTICIDE ADDITIVE: [DYE MARKER, FOAM MARKER]; Liquid marking dye and foam marker colouring agent - suitable for use with both liquid & powder products and can be used to help identify sprayed areas.
Authorization status:
Registered
Authorization number:
53962
Authorization date:
2019-07-01

READ SAFETY DIRECTIONS BEFORE OPENING

OR

USING

MARK-IT

Active Constituent: 150 g/L RHODAMINE B

Liquid marking Dye and Foam Marker

Colouring Agent

AUSTRALIA PTY L

97 Bayfield Road East,

Bayswater, Victoria 3153

Tel:: (03) 9720 6306

CONTENTS:

250m I

. 500ml

1 LITRE

5LLTRE

20 LITRE

110 LITRE

200 LITRE

Approved

DIRECTIONS FOR USE:

SPRAY

MARKING: Suitable for use with both liquid and powder products and can be used

help identify

sprayed areas.

FOAM MARKERS: Where a coloured foam is required for foam markers, add at the recommended rate

the dilute foam mixture

RATE

VOLUME

CRITICAL COMMENTS

5-10 ml

per 10 Litres

spray solution.

Use higher rate

more intense colour marking is required.

50-100 ml

per 100 Litres

spray solution.

20 - 30 ml

per 1 0 L of foam marker diluted

Will convert white foam

pink for easier identification in

solution.

specific situations.

TO BE USED FOR ANY PURPOSE OTHER THAN INDICATED ON THIS LABEL UNLESS AUTHORISED

UNDER APPROPRIATE LEGISLATION.

GENERAL INSTRUCTIONS

The concentrate and spray solution

Mark-It is dye

fast

on·

contact with most materials. Do not allow spray

drift to come into contact with the paint work of motor

vehicles.

Mark-It is suitable for use with both liquid

and powder formulations and can be used to visually

mark sprayed areas.

Suggested uses include:

Marking trial plots and strips.

Marking

help prevent farmers/contractors

over-

spraying.

Line marking of ovals and courts.

When used as a foam marker colouring agent, white

foam will become pink

colour

assist identification.

MIXING

Premix Mark-It with water and add

the spray tank

first. Agitate or mix thoroughly

the tank before

adding any other product.

Important:

When using with amine based products

such as Amicide 625 and MCPA 500, ensure that the

Mark-It is thoroughly mixed with the water before

adding the herbicide.

Wash out spray equipment thoroughly after use.

product residue is left

equipment colouration

subsequent sprays can

expected.

PROTECTION OF WILDLIFE, FISH, CRUSTACEANS

AND ENVIRONMENT ·

NOT contaminate streams, rivers

waterways

with the chemical

used containers.

APVMA Approval No.

53962/57163

Batch

Date

Manufacture

STORAGE AND DISPOSAL

Keep out of reach

children. Store in the closed,

original container in a cool, well-ventilated area. Do not

store for prolonged periods in direct sunlight. Triple or

preferably pressure rinse containers before disposal.

Add rinsing's

spray tank. Do not dispose

undiluted.

chemicals on-site.

recycling, replace cap and return

clean containers to

recycler

or designated collection

point.

not recycling, break, crush, or puncture and

deliver

empty

packaging

appropriate

disposal

approved

waste

management

facility.

approved

waste

management

facility

available

bury the

empty

packaging

below

surface

in a disposal pit specifically

marked

this

purpose

clear

wat~rways,

desirable

ve;Jetation and

tree roots, in

compliance

with

relevant

Local, State

Territory

government

regulations

burn

empty

containers

product.

SAFETY DIRECTIONS

not swallow. Avoid contact with eyes

skin

not inhale spray mist.

tf product

skin immediately wash area with soap

water.

FIRST AID

If poisoning occurs, contact a doctor or Poisons

Information Centre. Phone Australia

MATERIAL SAFETY DATA SHEET

For further information refer

the Material Safety Data

Sheet (MSDS), which

obtained

from

your supplier

SST Australia web site at

www.sstaustralia.com

CONDITIONS

SALE

The use of Mark-it Liquid Marking

being beyond

the control of the manufacturer,

warranty expressed

or implied

given

SST Australia PTY L

regarding

suitability, fitness

efficiency for

purpose for

which it

used

the buyer, whether

accordance

with directions

SST Australia PTY

accepts

responsibility for

consequences

whatsoever resulting

from

use of this product.

In

an

Emergency

Dial 000

Police or Fire Brigade

SST Australia PTY L

97 Bayfield Road East, Bayswater, Victoria 3153 Phone : (03) 9720 6306

MATERIALSAFETYDATASHEET–MARKITDYE1MAY2011

ProductName:MARKITDYE Page1of4

1.Identificationofthesubstance/preparationandofthecompany

ProductName: MARKITDYE

Supplier: SSTAustraliaPtyLtd

ACN: 052854833

Address: P.O.Box2032BayswaterVillage,BayswaterVic;3153Australia

Emergencyphone: +(0)418844861

TelephoneNumber:+61397206306

Facsimile:+61397206407

Recommendeduse: Liquidmarkingdyeforagriculturalspraysandmarkingfoams

2.Hazardsidentification

Hazard: HazardousaccordingtocriteriaofNOHSC.

Classification: HAZRADOUSSUBSTANCE.

NON-DANGEROUSGOODS.

DangerousgoodsclassificationaccordingtotheAustralianDangerousGoodsCode

RiskPhrases: Classifiedashazardous

Harmfulifswallowed

R41Riskofseriousdamagetoeyes

SafetyPhrases: S13Keepawayfromfood,drinkandanimalfeedingstuffs.

S2Keepoutofreachofchildren

S26Incaseofcontactwitheyes,rinseimmediatelywithplentyof

waterandseekmedicaladvice.

S46Ifswallowed,seekimmediatemedicaladviceandshowthis

MSDS,containerorlabel

PoisonsSchedule: Noneallocated.

3.Composition/informationoningredients

ChemicalCharacterization Liquid–mediumviscosity

Components CASNumber Proportion

RhodamineB 81-88-9 150g/L

Diethyleneglycol 111-46-6 60–90%

Othernonhazardouscomponents 0–30%

4.First-aidmeasures

Inhalation: Removeaffectedpersontofreshairuntilrecovered.

Ifsymptomsdeveloporpersist,seekmedicaladvice.

Ingestion: Rinsemouthandthendrinkplentyofwater.IfswalloweddoNOTinduce

vomiting;seekmedicaladviceimmediatelyandshowproductcontaineror

labelorcontactthePoisonsInformationCentreon131126(Aust).Make

everyefforttopreventvomitfromenteringthelungsbycarefulplacementof

thepatient.

Skin: Washaffectedareasthoroughlywithsoapandwater.Removecontaminated

clothingandlaunderbeforere-use.Ifirritationpersists,seekmedicaladvice.

Eye: Ifineyes,holdeyelidsopenandwashwithcopiousamountsofwaterforat

least15minutes.Seekmedicalattention.

MATERIALSAFETYDATASHEET–MARKITDYE1MAY2011

ProductName:MARKITDYE Page2of4

FirstAidFacilities:Ifpoisoningoccurs,contactadoctororPoisonsInformationCentreon

131126(Australia).

AdvicetoDoctor:Treatsymptomatically.

Gastriclavagewithmedicinalcharcoalinwaterisrecommended .

5.Fire-fightingmeasures

ExtinguishingMedia:Waterfog,foam,carbondioxideordrychemical.

Avoidusinglargevolumesofwaterwhichwouldspreadtheproduct.

HazardousCombustionProducts:Ifinvolvedinafire,itwillemitoxidesofcarbon,oxidesof

nitrogenandpossiblytracesofhydrogenchloride.

ProtectiveEquipment:Breathableairapparatusmayhavetobewornifmaterialisinvolvedin

firesespeciallyinconfinedspaces.

EmergencyActionincaseofFire:Ifexposedtofire,keepcontainercoolbysprayingwith

water.

6.Accidentalreleasemeasures

Spills&Disposal:Containspillandabsorbwithclay,sand,soilorproprietaryabsorbent(such

asvermiculite).Collectspilledmaterialandwasteinsealableopen-toptypecontainersfor

disposal.On-sitedisposalofconcentrateisnotacceptable.

PersonalProtection:Forappropriatepersonalprotectiveequipment(PPE),referSection8.

Clean-upMethods-LargeSpillages:Iflargeliquidspillsoccur,attempttorecoverasmuch

spiltmaterialfromsumpsandbundedareasbeforeabsorbingremainingmaterialinto

vermiculiteorotherabsorbent.

EnvironmentalPrecautions:Useearthenbundsorabsorbentbundingtopreventspreading

ofspillage.Preventfromenteringdrains,waterwaysorsewers.

7.Handlingandstorage

Handling:Spraymarkerdyeiscolouredandwillstronglystainskinandclothing.Ifskinhas

beenexposedtotheproduct,thoroughwashingwithsoapandwaterwillremoveanyexcess

product.Thecolourontheskinisnotdeepandwillnaturallydisappearoverafewdays.

Storage:Storeintheclosed,originalcontainerinacool,wellventilatedarea.Donotstorefor

prolongedperiodsindirectsunlight.Alwaysreadthelabelandtechnicaladvicebeforeuse.

8.Exposurecontrols/personalprotection

NationalExposureStandards:NOHSChassetthefollowingexposurestandardfor

diethyleneglycol:TLV(TWA)100mg/m3,STEL-.

EngineeringControls:Handleinwellventilatedareas,generallynaturalventilationis

adequate.

PersonalProtectiveEquipment:Itisgoodpracticetowearsuitablepersonalprotective

equipment(PPE).Whenopeningthecontainer,preparingsprayandusingthepreparedspray

wearcottonoverallsbuttonedtotheneckandwristandawashablehat,elbow-lengthPVC

glovesandgoggles.

HygieneMeasures:Afteruseandbeforeeating,drinkingorsmoking,washhands,armsand

facethoroughlywithsoapandwater.Aftereachday’susewascontaminatedclothingand

safetyequipment.

Aftereachday'suse,washcontaminatedclothingandsafetyequipment .

MATERIALSAFETYDATASHEET–MARKITDYE1MAY2011

ProductName:MARKITDYE Page3of4

9.Physicalandchemicalproperties

Physicalappearance: Clearredliquid

Solubility: Solubleinwater.

SpecificGravity@20°C: 1.13approx

FlashPoint(°C): >96

pH:(1%aqueoussolution) 6-8

FreezingPoint(°C): <0

Flammability: Combustible

10.Stabilityandreactivity

HazardousDecompositionProducts:Avoidcontactwithaluminium,aluminiumalloys,

copperrichalloysandneoprene.

HazardousReaction: Violentreactionsbetweenspraymarkerdyeandoxidisingagentsare

possible.

HazardousPolymerisation:Hazardouspolymerizationisnotpossible.

11.Toxicologicalinformation

Inhalation:Maycauseirritationtomucousmembranesandrespiratorytract.Thecomponents

oftheproductareoflowvolatilityandnoadverseeffectsareexpectedfromhandlingthe

concentrate.Breathingvapourcanresultinheadachesandnausea.

Ingestion:Possiblesymptomsofexposureinclude:nausea,vomitingandcentralnervous

systemdepression.

Skin:Prolongedcontactwiththeconcentratemaycauseirritation.Prolongedcontactwiththe

concentratecancausedefattingoftheskinandmayresultindermatitis.Thisproductwillstain

theskinwhichmaypersistforsometime.

Eye:Prolongedcontactwiththeconcentratemaycausedamagetotheeye.

Carcinogenicity:RhodamineBhasbeenassessedinanimalsandsomedataexiststhat

RhodamineBisasubstancewhichcausessomeconcernforhumansowingtopossible

carcinogeniceffectsfromlongtermexposure,butinrespectofwhichtheavailableinformation

isnotadequateformakingasatisfactoryassessment.

RhodamineBhasbeenincludedontheUSEPAlist4B.List4Bcontainssubstancesforwhich

theEPAhassufficientinformationtoreasonablyconcludethatthecurrentusepatternin

pesticideproductswillnotadverselyaffectpublichealthortheenvironment.

AcuteToxicity–Oral:LD50(rat)400-2000mg/kgforRhodamineB

EyeIrritation: Theproductisaneyeirritant.

SkinIrritation: Mildskinirritant.

12.Ecotoxicologicalinformation

Donotcontaminatedams,waterwaysorsewerswiththisproduct.

AcuteToxicity–Fish:LC50(96hr)forfishis10-100mg/lforRhodamineB

13.Disposalconsiderations

ProductDisposal:Onsitedisposaloftheconcentratedproductisnotacceptable.Ideally,the

productshouldbeusedforitsintendedpurpose.Ifthereisaneedtodisposeoftheproduct,

approachlocalauthoritieswhoholdperiodiccollectionsofunwantedchemicals(ChemClear®).

ContainerDisposal:Donotusethiscontainerforanyotherpurpose.Triplerinsecontainers,

addrinsatetothespraytank,thenofferthecontainerforrecycling/reconditioning,orpuncture

top,sidesandbottomanddisposeofinlandfillinaccordancewithlocalregulations.

drumMUSTERisthenationalprogramforthecollectionandrecyclingofempty,cleaned,non

returnablecropproductionandon-farmanimalhealthchemicalcontainers.Ifthelabelonyour

MATERIALSAFETYDATASHEET–MARKITDYE1MAY2011

ProductName:MARKITDYE Page4of4

containercarriesthedrumMustersymbol,triplerinsethecontainer,ringyourlocalCouncil,and

offerthecontainerforcollectionintheprogram.Ifnotrecycling,punctureorshredandbury

containersinlocalauthoritylandfill.Emptycontainersandproductshouldnotbeburnt.

14.Transportinformation

Itisgoodpracticetoseparatethisproductfromfood,foodrelatedmaterials,feedstuffs,seedor

fertilizersduringtransport.

RoadandRailTransport

NotclassifiedasDangerousGoodsbythecriteriaoftheAustralianDangerousGoodsCode

(ADGCode)fortransportbyRoadandRail.

MarineTransport

NotclassifiedasDangerousGoodsbythecriteriaoftheInternationalMaritimeDangerous

GoodsCode(IMDGCode)fortransportbysea.

AirTransport

NotclassifiedasDangerousGoodsbythecriteriaoftheInternationalAirTransportAssociation

(IATA)DangerousGoodsRegulationsfortransportbyair.

15.Regulatoryinformation

PoisonsSchedule:Noneallocated.

NationalRegulatoryInformation:RhodamineBhasbeenincludedontheUSEPAlist4B.

List4BcontainssubstancesforwhichtheEPAhassufficientinformationtoreasonably

concludethatthecurrentusepatterninpesticideproductswillnotadverselyaffectpublichealth

ortheenvironment.

Packaging&Labelling:READSAFETYDIRECTIONSBEFOREOPENINGORUSING

HazardCategory:Harmful,Irritant

AICS(Australia):AllofthecomponentsinthisproductarelistedontheAustralianInventoryof

ChemicalSubstances.

16.Otherinformation

Reason(s)forIssue:

CONTACTPOINT:JohnIllingworthPhone:+61397206306orMob:+61(0)418844861

Allinformationcontainedinthisdocumentisasaccurateaspossiblebasedontheinformation

submittedbyrawmaterialsuppliers.SSTAustraliaPtyLtdwillnotacceptanyresponsiblyforany

damagethatmayresultfromrelianceupontheinformationcontainedherein.

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