FARMOZ TRIAD 125 FUNGICIDE SPRAY

Australia - English - APVMA (Australian Pesticides and Veterinary Medicines Authority)

Active ingredient:
TRIADIMEFON; N-METHYL-2-PYRROLIDONE; HYDROCARBON LIQUID
Available from:
ADAMA Australia Pty Limited
INN (International Name):
triadimefon(125g/L)
Pharmaceutical form:
EMULSIFIABLE CONCENTRATE
Composition:
TRIADIMEFON TRIAZOLE Active 125.0 g/L; N-METHYL-2-PYRROLIDONE SOLVENT Other 50.0 g/L; HYDROCARBON LIQUID SOLVENT Other 618.0 g/L
Units in package:
1000L; 110L; 1L; 200L; 20L; 5L
Class:
A - Agricultural
Manufactured by:
ADAMA AUST
Therapeutic group:
AZALEA | BARLEY | CUCURBIT | GRAPEVINE | PEA | SUGAR CANE | WHEAT | CANTALOUPE | CHOKO | CUCUMBER | GHERKIN | HONEYDEW MELON | I
Therapeutic area:
FUNGICIDE
Therapeutic indications:
BARLEY LEAF SCALD | PETAL BLIGHT | PINEAPPLE DISEASE | POWDERY MILDEW | SPECKLED LEAF BLOTCH | STRIPE RUST | AZALEA | BARLEY SCALD | CERATOCYSTIS PARADOXA | YELLOW RUST
Product summary:
Poison schedule: 6; Withholding period: WHP: Cucurbits: do not harvest for 1 da y after application. Grapevines and pe as: do not harvest for 14 days after ap plication. Barley and wheat: do not har vest for 4 weeks after application.; Host/pest details: AZALEA: [PETAL BLIGHT]; BARLEY: [BARLEY LEAF SCALD, POWDERY MILDEW]; CUCURBIT: [POWDERY MILDEW]; GRAPEVINE: [POWDERY MILDEW]; PEA: [POWDERY MILDEW]; SUGAR CANE: [PINEAPPLE DISEASE]; WHEAT: [SPECKLED LEAF BLOTCH, STRIPE RUST]; Poison schedule: 6; Withholding period: ; Host/pest details: AZALEA: [PETAL BLIGHT]; BARLEY: [BARLEY LEAF SCALD, POWDERY MILDEW]; CUCURBIT: [POWDERY MILDEW]; GRAPEVINE: [POWDERY MILDEW]; PEA: [POWDERY MILDEW]; SUGAR CANE: [PINEAPPLE DISEASE]; WHEAT: [SPECKLED LEAF BLOTCH, STRIPE RUST]; For the control of powdery mildew on barley, peas, cucurbits and grapevines, petal blight of azaleas, pineapple disease of sugarcane, stripe rust on wheat and other cereal diseases.
Authorization status:
Registered
Authorization number:
50902
Authorization date:
2019-07-01

STORAGE AND DISPOSAL

Store in the closed, original container in a cool, well-ventilated

areas. DO NOT store for prolonged periods in direct sunlight.

Storage must be secure so that contents cannot be tampered with.

All locks and/or seals must be in order. If locks or seals are broken

prior to initial use then the integrity of this product cannot be

assured. If this occurs FARMOZ Pty. Ltd. should be advised

immediately. This minibulk/bulk container is reusable and remains

the property of FARMOZ Pty. Ltd. DO NOT rinse empty container.

Empty contents fully into application equipment. Close all valves and

return to the point of supply for refill or storage. No other liquid, solid

or pesticide product should be put into it. When empty return to

FARMOZ Pty. Ltd. for cleaning, relabelling and refilling.

SAFETY DIRECTIONS

Poisonous if swallowed. May irritate the eyes and skin. DO NOT

inhale spray mist. When preparing product for use wear elbow-

length PVC gloves. After use and before eating, drinking or smoking,

wash hands, arms and face thoroughly with soap and water. After

each day's use, wash gloves and contaminated clothing.

FIRST AID

If poisoning occurs, contact a doctor or Poisons Information Centre.

Phone Australia 131126. If swallowed, DO NOT induce vomiting. Give

a glass of water.

MSDS

Additional information is listed in the material safety data sheet

(MSDS). A material safety safety data sheet for TRIAD 125 is

available from FARMOZ on request. Call Customer Service on (02)

9431 7800.

CONDITIONS OF SALE: The use of FARMOZ TRIAD 125 Fungicide Spray being beyond

the control of the manufacturer, no warranty expressed or implied is given by

FARMOZ Pty. Ltd., regarding its suitability, fitness or efficiency for any purpose for

which it is used by the buyer, whether in accordance with the directions or not and

FARMOZ Pty. Ltd. accepts no responsibility for any consequence whatsoever from the

use of this product.

TRIAD 125 1000L METAL LABEL – SIZE: 325 MM WIDE X 480 MM DEEP (240 MM X 2 PANELS)

PLACE LEAFLET HERE

APVMA Approval No.: 50902/1000/0805

EXECUTIVE PRESS 08/05 – 0418 263 830

CONTENTS

1000 L

For control of powdery mildew on barley, peas, cucurbits

and grapevines, petal blight of azaleas, pineapple disease

of sugar cane, stripe rust on wheat and other cereal

diseases as specified in the Directions for Use table.

IMPORTANT: READ THE ATTACHED LEAFLET BEFORE OPENING OR USING

www.farmoz.com.au

ACTIVE CONSTITUENT: 125 g/L TRIADIMEFON

SOLVENTS: 618 g/L LIQUID HYDROCARBON

50 g/L N-METHYL-2-PYRROLIDONE

Triad

GROUP

FUNGICIDE

C

POISON

KEEP OUT OF REACH OF CHILDREN

READ SAFETY DIRECTIONS BEFORE OPENING OR USING

F U N G I C I D E S P R AY

Farmoz Pty. Ltd.

ABN 55 050 328 973

Suite 1, Level 4, Building B, 207 Pacific Highway

St Leonards NSW 2065 Australia

Tel: (02) 9431 7800 Fax: (02) 9431 7700

Batch No.

Date of

Manufacture

FOR SPECIALIST ADVICE IN

AN EMERGENCY ONLY

PHONE 1800 024 973

TOLL FREE – ALL HOURS – AUSTRALIA WIDE

Info

pest

Verified

TRIAD 125 8pp Leaflet - 174 mm wide x 234 mm deep

FOLDS to 87mm wide x 118mm

GENERAL INSTRUCTIONS

FARMOZ TRIAD 125 is a systemic fungicide with protective and curative

action. When applied the product is absorbed by the roots and leaves, with

ready

translocation

young

growing

tissues.

TRIAD

acts

ergosterol biosynthesis inhibitor.

MIXING

Half fill the spray tank with clean filtered water. Then add the required

amount of TRIAD 125 and top up the tank with water. Agitate thoroughly

prior to and during spraying. TRIAD 125 should be used in a full spray

programme on grapevines for prevention of heavy infections of powdery

mildew. TRIAD 125 may be applied by ground rig or aircraft.

Ground Rig Application:

Use a convenient amount of water e.g. 50 to 200

litres water per hectare.

Aircraft Application:

Apply not less than 10 L of spray mix per hectare.

Spraying should be carried out in a crosswind of not less than 5 knots. If it

is necessary to spray in calm conditions, increase spray volume up to 30

L/ha using larger droplets, reduce the swathe width and spray in the

morning. Aircraft fitted with booms or micronairs are equally satisfactory.

Micronairs should have blade setting of 30 to 50˚ and booms should be fitted

with fan nozzles set forward at 45˚ to the airstream. Use smoke generators

to measure direction, speed and variability of wind.

APPLICATION Grapevines

Dilute Spraying:

Use a sprayer designed to apply high volumes of water up to the point of

run-off and matched to the crop being sprayed. Set up and operate the

sprayer to achieve even coverage throughout the crop canopy. Apply

sufficient water to cover the crop to the point of run-off. Avoid excessive

run-off. The required water volume may be determined by applying different

test

volumes,

using

different

settings

sprayer,

from

industry

guidelines or expert advice. Add the amount of product specified in the

Directions For Use table for each 100 L of water. Spray to the point of run-

off. The required dilute spray volume will change and the sprayer set up and

operation may also need to be changed, as the crop grows.

Concentrate Spraying:

Use a sprayer designed and set up for the concentrate spraying (that is a

sprayer which applies water volumes less than those required to reach the

point of run-off) and matched to the crop being sprayed. Set up and operate

the sprayer to achieve even coverage throughout the crop canopy using

your chosen water volume. Determine an appropriate dilute spray volume

(See Dilute Spraying above) for the crop canopy. This is needed to calculate

the concentrate mixing rate. The mixing rate for concentrate can then be

calculated in the following way:

EXAMPLE ONLY

1. Dilute spray volume as determined above: For example 1500 L/ha.

2. Your chosen concentrate spray volume: For example 500 L/ha.

3. The concentration factor in this example is:

3x (ie 1500 L ÷ 500 L = 3).

APVMA Approval No.: 50902/0805

EXECUTIVE PRESS 08/05 – 0418 263 830

Triad

F U N G I C I D E S P R AY

For the control of powdery mildew on barley, peas,

cucurbits and grapevines, petal blight of azaleas,

pineapple disease of sugar cane, stripe rust on wheat

and other cereal diseases as specified in the Directions

for Use table.

ACTIVE CONSTITUENT: 125 g/L TRIADIMEFON

SOLVENTS: 618 g/L LIQUID HYDROCARBON

50 g/L N-METHYL-2-PYRROLIDONE

POISON

KEEP OUT OF REACH OF CHILDREN

READ SAFETY DIRECTIONS BEFORE OPENING OR USING

IMPORTANT: THIS LEAFLET IS PART OF THE LABEL ATTACHED TO

THE CONTAINER. READ THOROUGHLY BEFORE OPENING OR

USING THIS PRODUCT

Farmoz Pty. Ltd.

ABN 55 050 328 973

Suite 1, Level 4, Building B, 207 Pacific Highway

St Leonards NSW 2065 Australia

Tel: (02) 9431 7800 Fax: (02) 9431 7700

C

GROUP

FUNGICIDE

www.farmoz.com.au

4. If the dilute label rate is 10 mL/100 L, then the concentrate rate becomes

3 x10, that is 30 mL/100 L of concentrate spraying.

The chosen spray volume, amount of product per 100 L of water, and the

sprayer set up and operation may need to be changed as the crop grows.

For further information on concentrate spraying, users are advised to

consult relevant industry guidelines, undertake appropriate competency

training and follow industry Best Practices.

SPRAY TIMINGS FOR STRIPE RUST CONTROL

Read

advisory

literature

from

local

Department

Agriculture

classification of resistant and susceptible varieties then follow the spray

programme below;

SEEDLING INFECTIONS

When approx. 20 out of 100 leaves show first signs of infection during

tillering to jointing apply a spray within one week.

ADULT INFECTION

Susceptible Varieties: When approx. 10 out of 100 leaves show first signs of

infection apply a spray within one week. DO NOT delay.

Moderately Susceptible Varieties: When approx. 15 to 20 leaves out of 100

leaves show first sign of infection apply a spray within one week. DO NOT

delay.

Moderately Resistant and Resistant Varieties:

Monitor carefully. If rust

appears and spreads spray within one week.

FUNGICIDE RESISTANCE WARNING

TRIAD 125 Fungicide Spray is a member of the

group

fungicides.

fungicide

resistance management TRIAD 125 is a Group C fungicide. Some naturally

occurring

individual

fungi

resistant

TRIAD

other

Group

fungicides

exist

through

normal

genetic

variability

fungal

population. The resistant individuals can eventually dominate the fungi

population if these fungicides are used repeatedly. These resistant fungi

will not be controlled by TRIAD 125 and other Group C fungicides, thus

resulting in a reduction in efficacy and possible yield loss. Since the

occurrence of resistant fungi is difficult to detect prior to use, FARMOZ Pty.

Ltd. accepts no liability for any losses that may result from the failure of

TRIAD 125 to control resistant fungi. This product should not be used where

the user suspects that a tolerant or resistant strain is present.

Note on Azaleas: Some varieties are particularly sensitive to chemical

sprays and as this is often related to local conditions, it is advisable to treat

only a small number of plants first, in order to ascertain their reaction,

before treating the whole crop.

COMPATIBILITY

TRIAD 125 is compatible with most cereal herbicides. However, DO NOT use

it with herbicides known to cause damage when used together with a

wetting agent, because TRIAD 125 has some properties of a wetting agent.

TRIAD

compatible

with

most

commonly

used

fungicides.

compatibilities

given

based

world-wide

experience

considered correct. However, as changes in climatic conditions can alter

the sensitivity of plants to mixtures of sprays, we accept no responsibility

for the behaviour of such mixtures.

PROTECTION OF WILDLIFE, FISH, CRUSTACEANS AND ENVIRONMENT

Dangerous to fish. DO NOT contaminate streams, rivers or waterways with

the chemical or used container.

STORAGE AND DISPOSAL

Store in the closed, original container in a cool, well-ventilated area. DO

NOT store for prolonged periods in direct sunlight. Triple or preferably

pressure rinse containers before disposal. Add rinsings to spray tank. DO

NOT dispose of undiluted chemicals on-site. If recycling, replace cap and

return clean containers to recycler or designated collection point. If not

recycling, break, crush, or puncture and bury empty containers in a local

authority landfill. If no landfill is available, bury the containers below 500 mm

in a disposal pit specifically marked and set up for this purpose clear of

waterways, desirable vegetation and tree roots. Empty containers and

product should not be burnt.

For refillable containers,

empty contents fully into application equipment.

Close all valves and return to point of supply for refill or storage.

Envirodrum Micro Matic Valve (110 L): Store the original sealed Envirodrum

in a cool well-ventilated area. DO NOT store for prolonged periods in direct

sunlight. DO NOT tamper with the Micro Matic valve or the security seal. DO

NOT contaminate the Envirodrum with water or any foreign matter. After

each use of the product, please ensure that the Micro Matic coupler

delivery system and hoses are disconnected, triple rinsed with clean water

and drained accordingly. When the contents of the Envirodrum have been

used,

please

return

Envirodrum

point

purchase.

Envirodrum remains the property of FARMOZ Pty. Ltd.

C

GROUP

FUNGICIDE

CROP

Peas

DISEASE

Powdery Mildew

STATE

NSW, Vic,

Tas only

RATE

500 mL/ha

WHP

14 days

CRITICAL COMMENTS

Apply first spray at flowering . This is a preventive

spray and should be applied at very first sign of

disease or just before disease appears. Apply a

second spray 14 days later (about flat pod stage).

Cucurbits

Powdery Mildew

NSW,

WA only

40 mL/100 L or

400 mL/ha

1 day

Apply on a 5 to 10 day schedule starting at

emergence. Use short spray intervals when disease

pressure is high or plants are growing rapidly.

Good coverage is essential for good results.

Grapevines

Powdery Mildew

NSW, Vic,

WA only

Dilute spraying:

20 mL/100 L

Concentrate

spraying:

Refer to the

Mixing/Application

section.

14 days

Apply by dilute spraying equipment. Apply the

same total amount of product to the target crop

whether applying this product by dilute or

concentrate spraying methods. Apply thoroughly

in the following 5 spray programme:

1. When shoots are 10 cm long

2. Pre-flowering

3. At flowering

4. After fruit set

5. Before bunches close

Barley

Scald

NSW, Vic,

SA, WA,

Tas only

1 L/ha

Speckled Leaf Blotch

MIA and

North-

Western

Victoria

1 L/ha

Wheat

500 mL or

1 L/ha

4 weeks

In areas where this disease frequently affects the

flag leaf, apply at or near mid-tillering.

Azaleas

Petal Blight

All States

200 mL/100 L

Apply thoroughly every 14-21 days from expanded

bud stage till end of flowering.

Sugar cane

Pineapple Disease

Qld,

NSW only

100 mL/100 L

Apply by dip or spray. Ensure thorough wetting of

cut end of setts.

Powdery Mildew

All States

Apply at the first sign of the disease.

Stripe Rust

Use the higher rate only if longer residual effect is

required or if the crop has a yield potential of 4 to

5 tonnes/ha or greater. For spray timings see

General Instructions.

In areas where this disease frequently affects the

flag leaf, apply at 5-6 tillers to disease susceptible

varieties. If moist conditions prevail reinfection

can occur.

NOT TO BE USED FOR ANY PURPOSE OR IN ANY MANNER CONTRARY TO THIS LABEL UNLESS AUTHORISED UNDER

APPROPRIATE LEGISLATION.

WITHHOLDING PERIODS:

CUCURBITS:

DO NOT HARVEST FOR 1 DAY AFTER APPLICATION.

GRAPEVINES AND PEAS:

DO NOT HARVEST FOR 14 DAYS AFTER APPLICATION.

BARLEY AND WHEAT:

DO NOT HARVEST FOR 4 WEEKS AFTER APPLICATION.

DIRECTIONS FOR USE:

RESTRAINTS: DO NOT use with post emergent herbicides known to cause damage when used together with a wetting agent, because

TRIAD 125 has some properties of a wetting agent.

1000/20,000 L: Store in the closed, original container in a cool, well-

ventilated areas. DO NOT store for prolonged periods in direct sunlight.

Storage must be secure so that contents cannot be tampered with. All

locks and/or seals must be in order. If locks or seals are broken prior to

initial use then the integrity of this product cannot be assured. If this

occurs

FARMOZ

Pty.

Ltd.

should

advised

immediately.

This

minibulk/bulk container is reusable and remains the property of FARMOZ

Pty.

Ltd.

rinse

empty

container.

Empty

contents

fully

into

application equipment. Close all valves and return to the point of supply

for refill or storage. No other liquid, solid or pesticide product should be

into

When

empty

return

FARMOZ

Pty.

Ltd.

cleaning,

relabelling and refilling.

SAFETY DIRECTIONS

Poisonous if swallowed. May irritate the eyes and skin. DO NOT inhale

spray mist. When preparing product for use wear elbow-length PVC

gloves. After use and before eating, drinking or smoking, wash hands,

arms and face thoroughly with soap and water. After each day's use,

wash gloves and contaminated clothing.

FIRST AID

If poisoning occurs, contact a doctor or Poisons Information Centre.

Phone Australia 131126. If swallowed, DO NOT induce vomiting. Give a

glass of water.

MSDS

Additional information is listed in the material safety data sheet (MSDS).

A material safety safety data sheet for TRIAD 125 is available from

FARMOZ on request. Call Customer Service on (02) 9431 7800.

CONDITIONS OF SALE: The use of FARMOZ TRIAD 125 Fungicide Spray

being beyond the control of the manufacturer, no warranty expressed or

implied is given by FARMOZ Pty. Ltd., regarding its suitability, fitness or

efficiency for any purpose for which it is used by the buyer, whether in

accordance with the directions or not and FARMOZ Pty. Ltd. accepts no

responsibility for any consequence whatsoever from the use of this

product.

ProductName: FarmozTriad 125 EC Fungicide Spray

Page: 1 of 6

This revisionissued:November, 2009

MATERIAL SAFETY DATASHEET

Issued by: Farmoz Pty Ltd Phone: (02)9431 7800

Section 1 - Identification of Chemical Product and Company

Farmoz PtyLtd,Suite 1, Level4, Building B

207 Pacific Highway StLeonards, NSW 2068

ACN 050 328973 Telephone (02)9431 7800 (24 hours)

Fax(02)9431 7700

Substance: Triadimefon isan azole derivative.

Trade Name: FarmozTriad125 EC Fungicide Spray

Product Use: Agricultural fungicide for use as describedon the product label.

Creation Date: October, 2003

This version issued: November, 2009and isvalid for 5 years from thisdate.

Section 2 - Hazards Identification

Statement of Hazardous Nature

This productis classifiedas:Hazardous accordingto the criteriaof SWA Australia.

Not a Dangerous Good according to theAustralian DangerousGoods (ADG) Code.

Risk Phrases:R65. Harmful: May cause lung damage if swallowed.

SafetyPhrases:S36, S46, S24/25. Wear suitableprotectiveclothing. If swallowed, contact a doctor or Poisons

InformationCentre immediately and showthis container or label. Avoid contact with skin and eyes.

SUSDP Classification:S6

ADG Classification:None allocated.Not a Dangerous Good.

UN Number:Noneallocated

EmergencyOverview

Physical Description & colour: Clear brown liquid.

Odour:Characteristic odour.

Major Health Hazards:For Triadimefon, the 4-hourinhalation LC

is greater than 0.48 mg/L in rats and

approximately the same inmice. Acute toxicity through skin exposure is also fairlylow. The LD

values for the dermal

toxicity of technical Triadimefon are greater than 1000 mg/kg inrats and 2000mg/kg in rabbits. Data regarding eye

and skin irritation are inconclusive. If aspirated, may cause lung damage.

Potential Health Effects

See section 11for Chronic exposure studies.

Inhalation

Short termexposure:Available data indicates that this product isnot harmful. In additionproduct is unlikely to

cause any discomfort or irritation.

Skin Contact:

Short termexposure:Available data indicates that this product is not harmful. It should present no hazards in

normal use. However product is believed to be mildlyirritating, but is unlikely tocause anything more thanmild

transient discomfort.

Eye Contact:

Short termexposure:This product is believed to be mildly irritating,to eyes, but is unlikely to cause anything more

than mild transient discomfort.

Ingestion:

Short termexposure:Because of the low viscosity of this product, it may directly enter the lungs if swallowed, or if

subsequently vomited. Once in the lungs, it is very difficult to remove and can cause severe injury or death.This

product is unlikely to causeany irritationproblems in the short or long term.

Carcinogen Status:

SWA:No significant ingredient is classified as carcinogenic by SWA.

NTP:No significant ingredient is classified as carcinogenic by NTP.

IARC:No significant ingredient isclassified ascarcinogenic by IARC.

ProductName: FarmozTriad 125 EC Fungicide Spray

Page: 2 of 6

This revisionissued:November, 2009

MATERIAL SAFETY DATASHEET

Issued by: Farmoz Pty Ltd Phone: (02)9431 7800

Section 3 - Composition/Information on Ingredients

I I I n n n g g g r r r e e e d d d i i i e e e n n n t t t s s s C C C A A A S S S N N N o o o C C C o o o n n n c c c , , , % % % T T T W W W A A A ( ( ( m m m g g g / / / m m m 3 3 3

) ) ) S S S T T T E E E L L L ( ( ( m m m g g g / / / m m m 3 3 3

) ) )

Triadimefon 43121-43-3 12.5 not set not set

Liquid hydrocarbon secret 61 approx not set not set

Other non hazardous ingredients secret to 100 not set not set

This isa commercial product whose exact ratio of components may vary slightly. Minor quantities of other non

hazardousingredients arealso possible.

The TWA exposure value is the average airborne concentrationof aparticular substance when calculatedover a normal 8 hourworking dayfor a 5

dayworkingweek. The STEL (Short Term Exposure Limit) isan exposure value thatshould notbe exceeded for morethan 15 minutes andshould

not be repeated for more than 4 times per day. There should be atleast 60 minutes between successive exposures atthe STEL. The term "peak "is

used when theTWA limit, because of the rapid action of the substance, should neverbe exceeded, even briefly.

Section 4 - FirstAid Measures

General Information:

You should call The Poisons Information Centre if youfeel that you may have been poisoned, burned orirritated by

this product. The number is13 1126 fromanywhere inAustralia (0800 764 766 inNew Zealand) and is available at all

times.Have thisMSDS withyou when you call.

Inhalation:First aid isnot generally required. If in doubt, contact a Poisons Information Centre or a doctor.

Skin Contact:Blot or brush away excess chemical. Wash gentlyand thoroughly with water (use non-abrasive soap

if necessary)for 10 minutesor untilchemical isremoved.Under runningwater, remove contaminated clothing, shoes

and leather goods (e.g. watchbands andbelts). If irritationpersists, repeat flushingand obtain medical advice.

Eye Contact:Quickly and gently blot or brushproduct away. Flush the contaminated eye(s)with lukewarm, gently

flowingwateruntil the product is removed or until irritation hasceased, while holding the eyelid(s) open. Obtain

medical advice if irritation becomes painful or lasts more than a fewminutes.

Ingestion:If swallowed, doNOT induce vomiting. Wash mouth with water and contact a Poisons Information

Centre, or calla doctor.

Section 5 - Fire Fighting Measures

Fire and Explosion Hazards: This product isclassifiedas aC1 combustible product. There is aslightrisk of an

explosion fromthis product if commercial quantities are involved ina fire. Violent steam generation oreruption may

occur upon application of direct water stream on hot liquids. Vapours fromthis product are heavier than air and may

accumulate in sumps, pits and other low-lyingspaces, forming potentially explosive mixtures. They may also flash

back considerable distances.

Fire decomposition products from this product may be toxic if inhaled. Take appropriate protective measures.

Extinguishing Media:Preferred extinguishing media are carbondioxide, dry chemical, foam, water fog.

Fire Fighting:When fighting fires involving significant quantitiesof this product, wear a splash suit complete with

self contained breathing apparatus.

Flash point:No data

Upper FlammabilityLimit:No data.

Lower FlammabilityLimit:No data.

Autoignitiontemperature:No data.

Flammability Class:C1

Section 6 -Accidental Release Measures

Accidental release:In the event of a majorspill, prevent spillage from entering drainsor water courses. Wear full

protective clothing includingface mask, face shield andgauntlets. All skin areas should be covered. See above under

Personal Protection regarding AustralianStandards relating to personal protectiveequipment. Suitable materials for

protective clothing includerubber, PVC. Stop leak if safe todo so, and containspill. Absorb onto sand, vermiculite or

other suitable absorbent material. If spill istoo large or if absorbent material isnot available, try to create adike to

stop materialspreading orgoing into drains orwaterways.Sweep upand shovelor collect recoverable product into

labelledcontainers for recycling orsalvage, and dispose ofpromptly. After spills, wash area preventingrunoff from

entering drains. If a significant quantity of material entersdrains, advise emergency services. Full details regarding

disposal of used containers, spillageandunused material may be found on the label. If there is any conflict between

this MSDS and the label, instructionsonthe label prevail. Ensure legality of disposal by consulting regulations prior to

disposal. Thoroughly launder protectiveclothingbefore storage orre-use. Adviselaundry of nature of contamination

whensendingcontaminated clothing tolaundry.

ProductName: FarmozTriad 125 EC Fungicide Spray

Page: 3 of 6

This revisionissued:November, 2009

MATERIAL SAFETY DATASHEET

Issued by: Farmoz Pty Ltd Phone: (02)9431 7800

Section 7 - Handling and Storage

Handling:Keep exposureto this product to a minimum, and minimise the quantities kept in work areas. Check

Section 8 of this MSDS for details of personal protectivemeasures,and make sure that those measures arefollowed.

The measuresdetailed below under "Storage" shouldbe followed during handling in order tominimise risks to

personsusing the productin the workplace. Also, avoidcontact or contamination of productwith incompatible

materials listed in Section 10.

Storage:Note that his product iscombustible and therefore, for Storage, meetsthe definitionof Dangerous Goods in

somestates. If you store large quantities (tonnes)of such products,we suggest that you consult your state's

Dangerous Goods laws inorder to clarify your obligations regarding their storage.

Store in the closedoriginalcontainer in adry, cool, well-ventilated area out of direct sunlight. Makesure that the

product doesnot come intocontact with substanceslisted under "Materialsto avoid" in Section 10. Someliquid

preparationssettle orseparate onstanding and may requirestirringbefore use.Check packaging - theremay be

furtherstorage instructionson the label.

Section 8 - Exposure Controls and Personal Protection

The followingAustralian Standards will provide general advice regarding safety clothing and equipment:

Respiratory equipment:AS/NZS 1715, Protective Gloves:AS 2161, Industrial Clothing:AS2919, Industrial Eye

Protection:AS1336andAS/NZS 1337, Occupational ProtectiveFootwear:AS/NZS2210.

SWA Exposure Limits TWA (mg/m 3 ) STEL (mg/m 3 )

Exposure limits have not been established by SWA for anyof the significant ingredients in this product.

The ADI for Triadimefon isset at 0.03mg/kg/day. ThecorrespondingNOEL isset at 2.5mg/kg/day. ADI means

AcceptableDaily Intake and NOEL means No-observable-effect-level. Valuestaken from Australian ADI List, Dec

2008.

Ventilation:No special ventilation requirements arenormally necessary for thisproduct. Howevermake sure that

the work environment remainsclean andthat vapours and mists are minimised.

Eye Protection:Eye protectionsuch asprotective glasses or goggles isrecommended whenthis product is being

used.

Skin Protection:You should avoidcontact even withmild skin irritants. Therefore you should wearsuitable

impervious elbow-length gloves and facial protectionwhenhandling this product. See below for suitable material

types.

Protective Material Types:We suggest that protective clothingbemade from the following materials:rubber,

PVC.

Respirator:Usually, no respiratoris necessary whenusing this product. However, if you have any doubts consult

the AustralianStandard mentioned above.

Safety delugeshowers should be provided near to where this product is beingused.

Section 9 - Physical and Chemical Properties:

Physical Description & colour:Clear brown liquid.

Odour:Characteristic odour.

Boiling Point:Not available.

Freezing/Melting Point: No specific data. Liquid at normal temperatures.

Volatiles: No specific data. Expectedto be low at 100°C.

Vapour Pressure:No data.

Vapour Density:No data.

Specific Gravity: 0.945 – 0.948

Water Solubility:Emulsifiable.

pH:No data.

Volatility:No data.

Odour Threshold:No data.

Evaporation Rate:No data.

Coeff Oil/water distribution: Nodata

Autoignition temp:No data.

Section 10 - Stabilityand Reactivity

Reactivity:This product isunlikely to react ordecompose undernormal storage conditions. However, if you have

any doubts, contact the supplier for advice onshelf life properties.

ProductName: FarmozTriad 125 EC Fungicide Spray

Page: 4 of 6

This revisionissued:November, 2009

MATERIAL SAFETY DATASHEET

Issued by: Farmoz Pty Ltd Phone: (02)9431 7800

Conditions to Avoid:Store in the closed original container in a dry,cool, well-ventilated area out of direct sunlight.

Incompatibilities:strongacids, strongbases, strong oxidising agents.

Fire Decomposition:Carbondioxide,and if combustion isincomplete, carbonmonoxide and smoke. Nitrogen and

its compounds, and undersomecircumstances, oxides ofnitrogen. Occasionallyhydrogencyanide gas. Hydrogen

chloride gas,other compounds of chlorine. Water. Carbon monoxidepoisoningproduces headache, weakness,

nausea, dizziness, confusion, dimnessof vision, disturbance of judgment, andunconsciousness followedby coma

and death. Hydrogen cyanide poisoningsigns andsymptomsareweakness, dizziness, headache, nausea,vomiting,

coma,convulsions, and death. Death results from respiratory arrest. Hydrogencyanide gas acts very rapidly;

symptomsand death can both occur quickly.

Polymerisation:This product is unlikely to undergopolymerisation processes.

Section 11- Toxicological Information

Toxicity: Acute toxicity:At 92.6%, Triadimefon has an acute oral LD

of 300to 600 mg/kgin rats, about1000

mg/kg in mice, and about 500 mg/kg in rabbitsand dogs. Triadimefon has a potential to cause adverse chronic effects

at low to moderate dose levels. Lower potency formulations of Triadimefon havelower acute toxicities (higher LD

values). Acute inhalation toxicity of thecompound ismoderate. The 4-hour inhalation LC

isgreaterthan0.48 mg/L

in rats and approximately the samein mice. Acute toxicity throughskin exposure is also fairly low. The LD

valuesfor

the dermal toxicity of technical Triadimefon are greater than 1000 mg/kg in ratsand 2000 mg/kg in rabbits.Studies of

acute effectsin rats have indicated a potential to induce neurobehavioral effects.Data regarding eye andskin

irritation are inconclusive.

Chronic toxicity:A number of 2-yearstudies have indicated thatthere are several toxic responses to low to

moderate doses of the compound. Long-term studiesof Triadimefon in several species (rat, mouse, dog) over a range

of dosesindicated a reduction in body weight, changes inred bloodcell counts, anincrease inbloodcholesterol

levels, and increased liverweights. Increased liver weights may beseenas anadaptation to toxic stress, rather than

a toxic endpoint related to exposure.

Reproductiveeffects:Female ratsfed up to 90 mg/kg/day of 92.6%Triadimefon over three generations showed a

number of adverse effects.No effectswere notedin thefoetuses atmaternal doses below2.5mg/kg/day. At the

middle doses tested (around 15 mg/kg/day) the second-generationoffspring experienced a decrease in weight gain.

At the highestdose, the females experienced a reduction in body weight and adecrease in fertility. In another study

conducted over two generations, the female ratsshowed decreasedovary weightat the 2.5 mg/kg/day dose.At 90

mg/kg/day reductions in litter size, reduced offspringviability and lower birth weight were observed in second-

generation offspring. Thisevidence suggests it is unlikely that Triadimefon will cause reproductive toxicity inhumans

under normalcircumstances.

Teratogenic effects:The teratogenic potential of Triadimefon isrelatively low. Doses causingbirth defects inrats

were high enough to alsoproduce maternal toxicity. Cleftpalateswere noted inthe offspringof female rats fed

moderate doses of 75 mg/kg/day for an unspecified time period. In a secondstudy, no teratogenic effects were noted

in the offspring of female rats fed 50 mg/kg/day of 92.6% Triadimefon in the formof an emulsion. In another

teratogenicstudy in rats, rib deformitieswere notedathigh maternaldosesof 90mg/kg/day. A study of

occupationally-exposed female workers showed thatthe highest combineddermal and inhalation level of exposure for

workers wasaround 60 µgwhich corresponds to approximately 0.008 mg/kg/shift for a 70 kgworker, a value

considerably lower than thelowest dose that causedteratogenic effects in test animals. Thus, it is unlikely that

Triadimefonwill cause birth defectsinhumans undernormal circumstances.

Mutagenic effects:Six separatestudiesindicate thatthe 92.6%Triadimefon compound is nonmutagenic.Several

other tests were inconclusive. It is unlikely thatthe compound poses a significant mutagenic risk.

Carcinogenic effects:Ina 2-yeardietary study withmice, the highest dose tested (600 mg/kg/day) did notproduce

significant increases in tumorincidence.Due to high mortality, the reliability of this data issuspect. Another 2-year

dietary studyin mice showed increased liver cell hypertrophy (which may be related to tumor formation) at doses of

greaterthan36 mg/kg/day in males and6 mg/kg/dayfor females. Increased livercell adenomawas detected at all

levels, but carcinomawas not detected at any level in thisstudy. Based on thisevidence, noconclusioncan be drawn

about the overall carcinogenicity of Triadimefon.

Organ toxicity:Triadimefon has been associatedwith changes inthe liver, decreasedkidneyweights, and altered

urinary bladder structure inlaboratory animals exposed to18 to 60 mg/kg/day. There isevidence that acute effects on

the central nervoussystemmay also occur.

Fate in humans and animals:After oral administration of a single doseof Triadimefon, most of the compoundwas

eliminated unchanged in the urine and faeceswithin2to 3 days. Some breakdown of a small amount of the

compound occurredin the liver. The compound has a very short residence time in the bloodstream, about 2 ½ hours.

Whenappliedto the skin ofrats, 40% of the applied amount was excreted in urine and faeceswithin 8 days.

Additional amounts (up to 40%) were recovered unabsorbedfrom the skin surface and in the cage.

ProductName: FarmozTriad 125 EC Fungicide Spray

Page: 5 of 6

This revisionissued:November, 2009

MATERIAL SAFETY DATASHEET

Issued by: Farmoz Pty Ltd Phone: (02)9431 7800

Section 12 - Ecological Information

Effects on birds:Triadimefon ranges from slightly toxic to practically nontoxic to birds. For instance, the compound

has anLD

value of greater than 4000 mg/kg in mallard ducks.Japanese quailare less tolerant of the compound

of 2000mg/kg) and canaries are even less tolerant (LD

>1000 mg/kg). Even the mosttolerant species

exhibited some compound-related acute toxicity such as diarrheaand regurgitation within 5minutes of administration

of the highest doses. At the lowest dose tested (500 mg/kg) nosigns of diarrhoeawere noted.

Effects on aquatic organisms:Thecompound is slightly toxic to fish, indicatingthat they are moresusceptible to the

presence of the compoundthan are birds. Bluegill sunfish are the most susceptible, followed closely by goldfish, with

96-hourLC

values of 11mg/L and 10 to50 mg/L, respectively. The compound is only slightly toxic to rainbow trout,

with a reportedLC

of 14 mg/L.

Effects on other organisms:Thecompound is nontoxic to honeybees.

Environmental Fate:

Breakdown insoil and groundwater:Triadimefon has low to moderate persistence in soils. In a sandy loam type of

soil, half of the initial amount of thecompound was lost within 18 days. In loamy soil the half-life was muchshorter

(about 6 days), which indicates that breakdown of thecompound varieswith soil type. Other reportedsoil half-lives

are 14 to 60days with anaverage of 26days. Triadimefon and its residuesare moderately mobile and may have

potential to leach to groundwater.

Breakdown inwater:In water with a pH3.0, 6.0, or 9.0, almost95% of the compound remained after 28weeks. The

compound isvery stable inwater and does not readilyundergo hydrolysis.

Breakdown invegetation:In plants, abreakdown product is triadimenol , and translocation and metabolism may

vary according to plant species. Triadimenolis of comparable toxicity to Triadimefon.

Section 13 - Disposal Considerations

Disposal:Instructionsconcerningthe disposal of this product andits containers are given onthe productlabel.

These shouldbe carefully followed.

Section 14 - Transport Information

ADG Code:This productis not classified as aDangerousGood. No special transport conditions are necessary

unless required by other regulations.

Section 15 - RegulatoryInformation

AICS:All of the significant ingredients inthis formulation are to be found in the public AICS Database.

The followingingredients:Triadimefon, liquid hydrocarbon, are mentioned in theSUSDP.

Section 16 - Other Information

This MSDS contains onlysafety-related information. For other data see product literature.

Acronyms:

ADG Code Australian Code for the Transport of Dangerous Goods by Roadand Rail, 7th Edition

AICS Australian Inventory of Chemical Substances

CAS number Chemical Abstracts Service Registry Number

HazchemNumber Emergency action code ofnumbers andlettersthat provide information to emergency

servicesespecially firefighters

IARC International Agency forResearch onCancer

SWA Safe WorkAustralia, formerlyASCC and NOHSC

NOS Not otherwisespecified

NTP National Toxicology Program (USA)

R-PhraseRisk Phrase

SUSDP Standard for the Uniform Scheduling ofDrugs & Poisons

UN NumberUnited Nations Number

Contact Points:

Call Farmoz on (02)9363 3611 Fax: (02)9363 5977 and ask for the technical manager.

Police and Fire Brigade: Dial 000

Emergencycontact: 1800 024 973 (24 hours)

If ineffective: Dial Poisons Information Centre

( 13 1126 from anywhere in Australia)

ProductName: FarmozTriad 125 EC Fungicide Spray

Page: 6 of 6

This revisionissued:November, 2009

MATERIAL SAFETY DATASHEET

Issued by: Farmoz Pty Ltd Phone: (02)9431 7800

The informationcontained in this MaterialSafetyData Sheet is providedingood faith and is believed to becorrect at the date

hereof. However, it is expectedthat individuals receiving theinformationwillexercisetheirindependent judgement in determining

its appropriateness for a particular purpose. Farmoz PtyLtdmakes no representation as tothe accuracyor comprehensiveness of

the informationand to the fullextent allowedbylawexcludesall liabilitywhatsoever,whetherwith respect to negligence or

otherwise, for any loss or damage arising from or connectionwith the supplyor use of the information inthis MaterialSafetyData

Sheet.

Please readall labels carefully before using product.

This MSDS isprepared in accord withthe SWA document “National Code of Practice for the Preparation of

Material Safety Data Sheets” 2nd Edition [NOHSC:2001(2003)]

Copyright ©Kilford & Kilford Pty Ltd, November,2009.

http://www.kilford.com.au/ Phone (02)9251 4532

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