ACROBAT MZ 690 FUNGICIDE

Australia - English - APVMA (Australian Pesticides and Veterinary Medicines Authority)

Active ingredient:
MANCOZEB; DIMETHOMORPH
Available from:
BASF AUSTRALIA LTD.
INN (International Name):
dimethomorph(90g/kg)+mancozeb(600g/kg)
Pharmaceutical form:
WETTABLE POWDER
Composition:
MANCOZEB CARBAMATE-DITHIOCARBAMATE Active 600.0 g/kg; DIMETHOMORPH MORPHOLINE Active 90.0 g/kg
Units in package:
10kg; 500g; 5kg
Class:
A - Agricultural
Manufactured by:
BASF AUSTRALIA
Therapeutic group:
CUCURBIT | GRAPEVINE | LETTUCE (CLOSED HEAD VARIETIES ONLY) | ONION | POPPY OILSEED | POTATO | CANTALOUPE | CHOKO | CUCUMBER | D
Therapeutic area:
FUNGICIDE
Therapeutic indications:
ALTERNARIA LEAF BLIGHT OR SPOT BLIGHT | ANTHRACNOSE ON CUCURBIT | ANTHRACNOSE OR RING SPOT ON LETTUCE | DOWNY MILDEW | DOWNY MILDEW - PERONOSPORA SPP. | DOWNY MILDEW ON ALLIUM (ONION, GARLIC) | DOWNY MILDEW ON CUCURBIT | DOWNY MILDEW ON LETTUCE | EARLY BLIGHT | GUMMY STEM BLIGHT ON CUCURBIT | LATE OR IRISH BLIGHT ON TOMATO OR POTATO | LEAF BLIGHT | PURPLE BLOTCH | SEPTORIA SPOT ON CUCURBIT | SEPTORIA SPOT ON LETTUCE | ALTERNARIA LEAF SPOT | ALTERNATA SPOT | BROWN SPOT | LEAF SPOT - ALTERNARIA SPP. | SEPTORIA LEAF SPOT
Product summary:
Poison schedule: 5; Withholding period: ; Host/pest details: CUCURBIT: [ALTERNARIA LEAF BLIGHT OR SPOT BLIGHT, ANTHRACNOSE ON CUCURBIT, DOWNY MILDEW ON CUCURBIT, GUMMY STEM BLIGHT ON CUCURBIT, SEPTORIA SPOT ON CUCURBIT]; GRAPEVINE: [DOWNY MILDEW]; LETTUCE (CLOSED HEAD VARIETIES ONLY): [ANTHRACNOSE OR RING SPOT ON LETTUCE, DOWNY MILDEW ON LETTUCE, SEPTORIA SPOT ON LETTUCE]; ONION: [DOWNY MILDEW ON ALLIUM (ONION, GARLIC), LEAF BLIGHT, PURPLE BLOTCH]; POPPY OILSEED: [DOWNY MILDEW - PERONOSPORA SPP.]; POTATO: [EARLY BLIGHT, LATE OR IRISH BLIGHT ON TOMATO OR POTATO]; For the control of various diseases of cucurbits, grapevines, lettuce, onions, oilseed poppies and potatoes.Do NOT apply by aircraft. Do not apply to varieties of lettuce other than head varieties.
Authorization status:
Stopped
Authorization number:
48103
Authorization date:
2018-06-30

Lettuce change

Draft

Label

CAUTION

KEEP

REACH

CHILDREN

READ

SAFETY

DIRECTIONS

BEFORE

OPENING

USING

ACROBAT@

Fungicide

ACTIVE

CONSTITUENT:

90G/KG

DIMETHOMORPH

600G/KG

MANCOZEB

GROUP

FUNGICIDES

22.11.04

Page 1

the control

various diseases

cucurbits, grapevines,

head lettuce,

onions, oilseed poppies and potatoes as

DIRECTIONS

USE table

BASF

BASF Australia

62008437867

Noble

Park

Princes Highway,

Victoria

3174

5 kg

PRIMARY

PACK

CONTAINS

10 x

500g

WATER

SOLUBLE

MEASURE

PACKS

WHICH

IT IS ILLEGAL TO

SELL

SEPARATELY

Registered trademark

ofBASF

Lettuce change

CAUTION

KEEP OUT OF REACH OF CHILDREN

READ SAFETY DIRECTIONS BEFORE OPENING OR USING

ACROBAT® MZ 690 Fungicide

ACTIVE CONSTITUENT: 90G/KG DIMETHOMORPH

600G/KG MANCOZEB

22.11.04

Page 2

BASF

BASF Australia Ltd

62 008 437867

500 Noble Park

Princes Highway,

Victoria 3I 74

500g

NOT TO BE SOLD SEPARATELY.

BEFORE USE,

READ

ALL DIRECTIONS ON

OUTER

PACK.

WATER SOLUBLE PACKAGING.

KEEP DRY.

®= Registered trademark

ofBASF

APVMA Approval No.:

48103/500/1104

Page

DIRECTIONS FOR USE

RESTRAINTS

D NOT

appiy

yalrcra

CROP

DISEASE

DOSE

CRITICAL

COMMENTS

Cucurbits

Downy mildew

2.0kg/ha

7 days

Maintain a regular protectant spray

(Pseudoperonospora

programme.

Apply ACROBAT MZ

cubensis)

when conditions favour disease

NT only

development

but before the disease

Anthracnose (Colletotrichum

is evident.

Apply two consecutive

spp.),

sprays

ACROBAT MZ,

7 to 10

gummy stem blight

days apart, then change to a

(Didymella bryoniae),

fungicide from another chemical

Alternaria leaf spot

group.

Use the shorter interval

(Alternaria spp.),

when conditions favouring infection

Septoria spot (pumpkin)

are creating a high risk. Add a non-

(Septoria spp.)

ionic surfactant

at registered label

rates.

Do NOT apply more than 4

ACROBAT MZ sprays to each crop

as a precaution against development

disease resistance.

Grapevines

Downy mildew

High

28 days

use in crops

intended

(Plasmopara viticola)

volume:

drying.

200g/I00L

Also see

'CAUTION'

section re

export

commodities.

volume:

Apply at 7 to 14 day intervals when

2kg/ha

humid or wet conditions favour

infection but before disease is

evident.

Use the shorter interval

when conditions favouring infection

are creating a high risk.

Apply a

maximum

3 consecutive sprays

before changing to another

fungicide.

For high volume

application,

use a water volume

250 to 1000L/ha,

depending on

canopy volume.

Add a non-ionic

surfactant

at registered label

rates.

Do NOT apply more than 6

ACROBAT sprays per season as a

precaution against

development

disease resistance.

Lettuce (head

Downy mildew

2.0kg/ha

14 days

Maintain a regular protectant spray

varieties only)

(Bremia lactucae),

programme.

Apply when conditions

Anthracnose

favour disease development but

iMarssonina panattonianai,

before the disease is evident.

Septoria

leaf

spot

Apply two consecutive sprays

(Septaria spp.)

ACROBAT MZ,

7 to 10 days apart,

then change to a fungicide from

another chemical

group.

Use the

shorter interval when conditions

favouring infection are creating a

"

':J'\:,

high risk.

Apply in 250 to 500L

_._--<

water per hectare.

Add a non-ionic

".;

surfactant at registered label rates .

\:;;'.\,

Do NOT apply more than 4 sprays

ACROBAT MZ to each crop as

"

/ ' .

a precaution against development

disease resistance

"";.::~'="

Page 4

CROP

DISEASE

DOSE

CRITICAL

COMMENTS

Oilseed

Downy mildew

2.0kg/ha

6 weeks

Maintain a protective spray

poppies

(Peronospora arborescens)

programme at early run-up stage

crop growth.

Apply ACROBAT

MZ when conditions favour disease

development during the late run-up

to hook stage.

Re-apply

0 days

later if required.

Apply in 250 to

500L

water per hectare.

Add a

non-ionic surfactant

at registered

label

rates.

Do NOT apply later

than early flowering stage.

Do NOT apply more than 2 sprays

ACROBAT MZ to each crop as a

precaution against development

disease resistance.

Onions

Downy mildew

2.0kg/ha

7 days

Maintain a regular protectant spray

iPeronospora destructor),

programme.

Apply when conditions

leaf blight

favour disease development

before the disease is evident.

Apply

NT only

two consecutive sprays

Purple blotch

ACROBAT MZ,

7 to 14 days apart,

(Alternaria

perris

then change to a fungicide from

another chemical

group.

Use the

shorter interval when conditions

favouring infection are creating a

high risk.

Apply in 250 to 500L

water per hectare.

Add a non-ionic

surfactant

at registered label rates.

Do NOT apply more than 4 sprays

ACROBAT MZ to each crop as a

precaution against development

disease resistance.

Potatoes

Late blight

2.0kglha

49 days

Maintain a regular protectant spray

(Phytophthora infestanst,

programme.

Apply on a protectant

early blight

schedule at 7 to 10 day intervals

(Alternaria

solaniy

when conditions favour disease

development but before the disease

is evident.

Use the shorter spray

interval

when conditions for disease

development are severe.

Add a non-

ionic surfactant

at registered label

rates.

Apply ACROBA T MZ in 250

to 500 litres

water per hectare.

Do NOT apply more than 4

ACROBA T MZ sprays to each crop

as a precaution against development

disease resistance.

BE USED

PURPOSE,

IN ANY

MANNER,

CONTRARY

THIS

LABEL

UNLESS

AUTHORISED

UNDER

APPROPRIA

LEGISLATION.

Page

WITHHOLDING

PERIODS:

CUCURBITS,

ONIONS:

LETTUCE (HEAD

VARIETIES ONLY):

GRAPEVINES:

OILSEED POPPIES:

POTATOES:

GENERAL

INSTRUCTIONS

DO NOT HARVEST FOR 7 DAYS AFTER APPLICA TION.

DO NOT HARVEST

14 DAYS AFTER APPLICA TION.

DO NOT HARVEST FOR 4 WEEKS AFTER APPLICA TION.

DO NOT HARVEST FOR 6 WEEKS AFTER APPLICA TION.

DO NOT HARVEST FOR 7 WEEKS AFTER APPLICATION.

FUNGICIDE

RESISTANCE

WARNING

GROUP

. . .

FUNGICIDES

ACROBAT MZ 690 Fungicide

is a combination

a Group X and a Group Y fungicide.

fungicide

resistance management,

ACROBA T MZ 690 is both a Group X and a Group Y fungicide.

Some naturally occurring individual

fungi resistant to ACROBAT MZ and other Group Y fungicides containing mancozeb may exist

through normal

genetic variability in any fungal

population.

The resistant

individuals can eventually dominate the fungal

population if

these fungicides are used repeatedly.

These resistant

fungi

may not

be controlled by ACROBAT MZ and other

Group Y fungicides

containing mancozeb, thus resulting in a reduction in efficacy and possible yield loss.

Since the occurrence

resistant

fungi is difficult

to detect prior to use,

BASF Australia Ltd accepts no liability for any losses that

result

from the failure

ACROBAT MZ 690 to control

resistant

fungi.

This product

combines the locally systemic,

translaminar

properties

dimethomorph with the protective properties

mancozeb.

should always

be used as

part

a protective spray

programme and applied before disease symptoms appear.

To prevent or delay the development

strains

disease fungi resistant

dimethomorph,

it is recommended that

this product

is used in spray programmes including fungicides with different

modes

action.

Refer to the CRITICAL COMMENTS section

this label.

Consult a BASF representative for further information if required.

RE-ENTRY

PERIOD

Workers should NOT enter treated areas without

cotton overalls and elbow-length PVC gloves until spray has dried.

CAUTION

Export

treated

fruit

wine

Growers

should note that

Maximum Residue Limits (MRLs)

or import

tolerances do not

exist

in all

markets

fruit

treated with

ACROBAT MZ Fungicide.

Additionally,

some export

markets

have established MRLs

different

to those in Australia.

you are

growing fruit

export

(either

fresh or

as wine),

please

check with BASF Australia or

the Australian Wine Research Institute

http://www.waite.adelaide.edu.au/AWRI/for the latest

information on MRLs and import

tolerances

BEFORE using ACROBAT MZ

Fungicide.

MIXING

Half

fill the spray

and commence agitation.

Add the required number

water soluble bags and allow them to disperse.

Add the

remainder

the water

with agitation running.

Add wetting agent,

if required,

when spray tank is full.

Ensure thorough mixing and

constant agitation to keep the product

in suspension.

Page 6

APPLICATION

Ensure thorough coverage

plants,

especially the underside of leaves and young grape bunches.

COMPATIBILITY

ACROBAT MZ can be tank-mixed with MVP* Bio-encapsulated Insecticide,

CYBOUT® Biological Insecticide,

Dipel* Forte,

Lorsban" EC,

Kocide* Or DELAN® Fungicide.

Avoid mixing with strongly alkaline or acidic materials.

PROTECTION OF WILDLIFE,

FISH,

CRUSTACEANS AND ENVIRONMENT

Highly toxic to fish and other

aquatic organisms.

contaminate ponds,

dams,

streams,

waterways or drains with the chemical

or used containers.

Do NOT apply under

meteorological

conditions or

from spraying equipment

which could be expected to cause spray to drift

onto

nearby susceptible plants,

adjacent crops, crop lands or pastures.

STORAGE AND DISPOSAL

Store in the closed original

container in a dry,

cool,

well-ventilated area out

direct

sunlight.

Ensure that water soluble bags are kept

in sealed moisture-proof original containers.

Puncture,

shred and bury empty containers in a local authority landfill.

no landfill

is available, bury the containers below 500mm in a

disposal

specifically marked and set

up for this purpose clear

waterways,

desirable vegetation and tree roots.

Empty containers

and product should

be burnt.

SAFETY DIRECTIONS

Will

irritate the eyes.

Avoid contact with the eyes.

Repeated exposure may cause allergic disorders.

When opening the container and

using the prepared spray,

wear cotton overalls buttoned to the neck and wrist

and a washable hat

and elbow-length PVC gloves.

Wash

hands after use.

After each day's use, wash gloves and contaminated clothing.

FIRST AID

poisoning occurs,

contact a doctor or Poisons Information Centre.

Telephone 131126 Australia-wide.

Avoid giving alcohol.

MSDS

Additional

information is listed in the Material

Safety Data Sheet.

CONDITIONS OF SALE

conditions and warranties rights and remedies implied by law or arising in contract or tort

whether due to the negligence

ofBASF

Australia Ltd or otherwise are hereby expressly excluded so far as the same may legally be done provided however that

any rights of

the Buyer pursuant to non excludable conditions or warranties

the Trade Practices Act

1974 or any relevant

legislation

any State

are expressly preserved but

the liability

BASF Australia Ltd or

any intermediate Seller

pursuant

thereto shall

be limited

permitted by the said legislation to the replacement of the goods sold or the supply

equivalent goods and aJlliability for indirect

consequential

loss or damage

whatsoever nature is expressly excluded.

This product

must

be used or applied strictly in accordance

with the instructions appearing hereon.

This product

is solely sold for use in Australia and must

be exported without

the prior

written consent

ofBASF

Australia Ltd.

* Registered trademarks

®= Registered trademark

ofBASF

©BASF,2004

Page 7

rrns

PRODUCT

CONSlDERED TO BE A DANGEROUS

GOOD

UNDER

THE AUSTRALIAN

CODE

TRANSPORT OF DANGEROUS GOODS BY ROAD AND RAIL

SPEC1ALIST

ADV1CE IN AN

EMERGENCY ONLY

PHONE

1 800 033 111

TOLL FREE - ALL HOURS -

AUSTRALIA WIDE

Product No.:

Batch No.:

Date

Manufacture:

Expiry Date:

APVMA Approval

No.:

48103/5/1104

Page

CAUTION

KEEP

OUT OF

REACH

CHILDREN

READ

SAFETY

DIRECTIONS

BEFORE

OPENlNG

USING

ACROBAT®

Fungicide

ACTIVE

CONSTITUENT:

90G/KG

DIMETHOMORPH

600GIKG

MANCOZEB

GROUP

FUNGICIDE

the control

various diseases

cucurbits, grapevines,

head lettuce, onions, oilseed poppies and potatoes as per the

DIRECTIONS

USE table

BASF

BASF

Australia Ltd

62 008

437867

500 Noble

Park

Princes Highway,

Victoria

3174

10 kg

®= Registered trademark

BASF

Page 9 of 13

DIRECTIONS FOR USE

RESTRAINTS

aonrv

yalrcra

CROP

DISEASE

DOSE

CRITICAL COMMENTS

Cucurbits

Downy mildew

2.0kg/ha

7 days

Maintain a regular protectant spray

(Pseudoperonospora

programme.

Apply ACROBAT MZ

cubensis)

when conditions favour disease

Qld and NT only

development but before the disease

Anthracnose (Colletotrichum

is evident.

Apply two consecutive

spp.),

sprays

ACROBA T MZ,

7 to 10

gummy stem blight

days apart,

then change to a

(Didymella bryoniae),

fungicide from another chemical

Alternaria leaf spot

group.

Use the shorter interval

(Alternaria spp.),

when conditions favouring infection

Septoria spot (pumpkin)

are creating a high risk. Add a non-

(Sep/oria spp.)

ionic surfactant at registered label

rates.

Do NOT apply more than 4

ACROBAT MZ sprays to each crop

as a precaution against

development

disease resistance.

Grapevines

Downy mildew

High

28 days

Do NOT use in crops intended for

(Plasmopara vi/icola)

volume:

drying.

200g/100L

Also see 'CAUTION'

section re

Low volume:

export commodities.

2kg/ha

Apply at 7 to 14 day intervals when

humid or wet conditions favour

infection but before disease is

evident.

Use the shorter interval

when conditions favouring infection

are creating a high risk.

Apply a

maximum

3 consecutive sprays

before changing to another

fungicide.

For high volume

application,

use a water volume

"

250 to 1000L/ha,

depending on

. ' \

"'\

canopy volume.

Add a non-ionic

surfactant at registered label rates.

Do NOT apply more than 6

ACROBA T sprays per season as a

"-

precaution against development

--._.

disease resistance.

"

CROP

DISEASE

DOSE

CRITICAL

COMMENTS

Lettuce (head

Downy mildew

2.0kg/ha

14 days

Maintain a regular

protectant

spray

varieties only)

(Bremia Taclucae),

programme.

Apply when conditions

Anthracnose

favour disease development but

(Marssonina panattonianat,

before the disease is evident.

Apply

Septoria leaf spot

two consecutive sprays

(Septoria spp.)

ACROBAT MZ,

7 to 10 days apart,

then change to a fungicide from

another chemical group.

Use the

shorter interval

when conditions

favouring infection are creating a

high risk.

Apply in 250 to 500L of

water per hectare.

Add a non-ionic

surfactant at registered label

rates.

Do NOT apply more than 4 sprays

ACROBA T MZ to each crop as a

precaution against

development of

disease resistance.

Oilseed

Downy mildew

2.0kglha

6 weeks

Begin a mancozeb protective spray

poppies

(Peronospora arborescens)

programme at early run-up stage of

crop growth.

Apply ACROBAT

MZ when conditions favour disease

development during the late run-up

to hook stage.

Re-apply 10 days

later if required.

Apply in 250 to

500L

water per hectare.

Add a

non-ionic surfactant at registered

label

rates.

apply later

than early flowering stage.

apply more than 2 sprays

ACROBAT MZ to each crop as a

precaution against

development of

disease resistance.

Onions

Downy mildew

2.0kglha

7 days

Maintain a regular

protectant spray

(Peronospora destructor),

programme. Apply when conditions

leaf blight

favour disease development but

before the disease is evident.

NT only

Apply two consecutive sprays

Purple blotch

ACROBAT MZ,

7 to 14 days apart,

(Alternaria porri)

then change to a fungicide from

another

chemical

group.

Use the

shorter

interval when conditions

favouring infection are creating a

high risk.

Apply in 250 to 500L

water per hectare.

Add a non-ionic

surfactant at registered label rates.

",

Do NOT apply more than 4 sprays

ACROBAT MZ to each crop as a

precaution against

development

disease resistance.

Page 10

Page

CROP

DISEASE

DOSE

CRITICAL

COMMENTS

Potatoes

Late blight

2.0kglha

49 days

Maintain a regular protectant

spray

(Phytophthora infestans),

programme.

Apply on a protectant

early blight

schedule at 7 to 10 day intervals

(Alternaria so/ani)

when conditions favour disease

development but before the disease

is evident.

Use the shorter spray

interval when conditions for disease

development are severe.

Add a non-

ionic surfactant

at registered label

rates.

Apply ACROBAT MZ in 250

to 500 litres

water per hectare.

Do NOT apply more than 4

ACROBAT MZ sprays to each crop

as a precaution against development

disease resistance.

TO BE USED

PURPOSE,

IN ANY MANNER,

CONTRARY

THIS

LABEL UNLESS

AUTHORISED

UNDER

APPROPRIATE

LEGISLATION.

WITHHOLDING

PERIODS:

CUCURBITS,

ONIONS:

LETTUCE (HEAD

VARIETIES ONLY):

GRAPEVINES:

OILSEED POPPIES:

POTATOES:

DO NOT HARVEST FOR 7 DAYS AFTER APPLICA TION.

DO NOT HARVEST FOR 14 DAYS AFTER APPLICA TION.

DO NOT HARVEST FOR 4 WEEKS AFTER APPLICATION.

DO NOT HARVEST FOR 6 WEEKS AFTER APPLICA TION.

DO NOT HARVEST FOR 7 WEEKS AFTER APPLICATION.

GENERAL

INSTRUCTIONS

Page 12

of13

FUNGICIDE

RESISTANCE

WARNING

GROUP

.. .

FUNGICIDES

ACROBAT MZ 690 Fungicide

is a combination

a Group X and a Group Y fungicide.

fungicide

resistance management,

ACROBAT MZ 690 is both a Group X and a Group Y fungicide.

Some naturally occurring individual

fungi

resistant

to ACROBAT MZ and other Group Y fungicides containing mancozeb may exist

through normal

genetic variability in any fungal

population.

The resistant individuals can eventually dominate the fungal

population if

these fungicides

are used repeatedly.

These resistant

fungi

may not

be controlled by ACROBAT MZ and other

Group Y fungicides

containing mancozeb,

thus resulting

in

a reduction in efficacy and possible yield loss.

Since the occurrence

resistant fungi

is difficult

to detect

prior to use,

BASF Australia Ltd accepts no liability for any losses that may

result

from the failure

ACROBAT MZ 690 to control

resistant

fungi.

This product

combines the locally systemic,

translaminar

properties

dimethomorph with the protective properties

mancozeb.

should always

be used as

part

a protective spray

programme and applied before disease symptoms appear.

To prevent

or delay the development

strains

disease fungi

resistant to

dimethomorph,

it is recommended that

this product

is used in spray programmes including fungicides with different

modes

action.

Refer to the CRITICAL COMMENTS section

this label.

Consult

a BASF representative for further information

required.

RE-ENTRY

PERIOD

Workers should NOT enter treated areas without

cotton overalls and elbow-length PVC gloves until spray has dried.

CAUTION

Export

treated

fruit

wine

Growers should note that

Maximum Residue Limits (MRLs)

import

tolerances do not

exist

in all

markets

for fruit

treated with

ACROBAT MZ Fungicide.

Additionally,

some export

markets

have established MRLs different

to those in Australia.

If you are

growing

fruit

for export

(either

fresh or

as wine),

please check with BASF Australia Ltd or the Australian Wine Research Institute

http://www.waite.adelaide.edu.au/AWRI/for the latest

information on MRLs

and import

tolerances BEFORE using ACROBAT MZ

Fungicide.

MIXING

Half

fill the spray vat.

Pre-mix the product

with a small

amount

water,

ensuring all

particles are thoroughly wet,

before adding to

the spray tank with agitation running.

Add wetting agent,

if required,

when spray tank is full.

Ensure thorough mixing and constant

agitation to keep the product in suspension.

APPLICATION

Ensure thorough coverage

plants,

especially the underside

leaves and young grape bunches.

COMPATIBILITY

ACROBAT MZ can be tank-mixed with MVP* Bio-encapsulated Insecticide, CYBOUT® Biological Insecticide, Dipel* Forte,

Lorsban* EC,

Kocide* or

DELAN® Fungicide. Avoid mixing with strongly alkaline or acidic materials.

PROTECTION

WILDLIFE,

FISH,

CRUSTACEANS

ENVIRONMENT

Highly toxic to fish and other aquatic organisms.

Do NOT contaminate ponds,

dams,

streams,

waterways or drains with the chemical

or used containers.

Do NOT apply under

meteorological

conditions or

from spraying equipment

which could be expected to cause spray to drift

onto

nearby susceptible plants,

adjacent crops,

crop lands or pastures.

Page

STORAGE AND DISPOSAL

Store in the closed original container in a dry,

cool,

well-ventilated area out

direct sunlight.

Single rinse before disposal.

Add rinsings to spray tank.

Do NOT dispose

undiluted chemicals on-site.

Puncture and bury empty

containers in a local

authority landfill.

If no landfill

is available,

bury the containers

below 500mm in a disposal

specifically

marked and set

up for this purpose clear

waterways,

desirable vegetation and tree roots.

Empty containers and product

should NOT

be burnt.

SAFETY DIRECTIONS

Will

irritate the eyes.

Avoid contact

with the eyes.

Repeated exposure may cause allergic disorders.

When opening the container and

using the prepared spray,

wear cotton overalls buttoned to the neck and wrist

and a washable hat and elbow-length PVC gloves.

Wash

hands after use.

After each day's use, wash gloves and contaminated clothing.

FIRST AID

If poisoning occurs,

contact a doctor or Poisons Information Centre.

Telephone 131126 Australia-wide.

Avoid giving alcohol.

MSDS

Additional information is listed in the Material

Safety Data Sheet.

CONDITIONS OF SALE

conditions and warranties rights and remedies implied by law or arising in contract or tort

whether due to the negligence

BASF

Australia Ltd or otherwise are hereby expressly excluded so far as the same may legally be done provided however that

any rights

the Buyer pursuant to non excludable conditions or warranties

the Trade Practices Act

1974 or any relevant

legislation

any State

are expressly preserved but

the liability

BASF Australia Ltd or

any intermediate Seller

pursuant

thereto shall

be limited if so

permitted by the said legislation to the replacement

the goods sold or the supply

equivalent goods and all

liability for indirect

consequential

loss or damage

whatsoever nature is expressly excluded.

This product must

be used or applied strictly in accordance

with the instructions appearing hereon.

This product

is solely sold for

use in Australia and must

be exported without

the prior

written consent

ofBASF

Australia Ltd.

Registered trademarks

Registered trademark

ofBASF

BASF,

2004

THIS PRODUCT IS

CONSIDERED TO BE A DANGEROUS GOOD

UNDER

THE AUSTRALIAN CODE

FOR THE TRANSPORT OF DANGEROUS GOODS BY ROAD AND RAIL

FOR SPECIALIST

ADVICE IN AN

EMERGENCY ONI.Y

Product No.:

Batch No.:

Date

Manufacture:

Expiry Date:

APVMA Approval No.:

481 03II OIII 04

PHONE

1 800 033 111

TOLL FREE - ALL HOURS - AUSTRALIA WIDE

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Page 1 of 4

Cyanamid Agriculture Pty. Limited

Material Safety Data Sheet

A.C.N. 008 438 926

5 Gibbon Road,

Baulkham Hills, NSW 2153

____________________________________________

Telephone: (02) 9624 9333

Product Name:

ACROBAT* MZ 690 Fungicide

Emergency: 1 800 033 111

____________________________________________

Classified as hazardous according to criteria of Worksafe Australia.

TRADE NAME:

ACROBAT* MZ 690 Fungicide

OTHER NAMES:

dimethomorph;

(E,Z)4-[3-(4-chlorophenyl)-3-(3,4-dimethoxyphenyl)-acryloyl]

morpholine

plus

mancozeb; manganese ethylenebis (dithicocarbamate)(polymeric) complex with

zinc salt

USE:

Agricultural fungicide

MANUFACTURER'S NAME/ADDRESS

U.N. NUMBER:

Not applicable

Cyanamid Agriculture Pty Limited

DANGEROUS GOODS CLASS:

Not considered a

5 Gibbon Road

dangerous good

Baulkham Hills NSW 2153

SUBSIDIARY RISK:

Not applicable

HAZCHEM CODE:

Not applicable

POISONS SCHEDULE:

PACKAGING GROUP:

Not applicable

EPG:

Not applicable

PHYSICAL DESCRIPTION/PROPERTIES

APPEARANCE AND ODOUR:

Greyish-yellow powder without odour

BOILING POINT °C:

Not applicable

DENSITY kg/L:

Not applicable

VAPOUR PRESSURE:

Not applicable

MELTING POINT:

Not applicable

VAPOUR DENSITY:

Not applicable

EVAPORATION RATE:

Not applicable

SOLUBILITY (WATER):

Forms suspension

PERCENT VOLATILES:

Not applicable

FIRE/EXPLOSION HAZARD

FLASH POINT °C :

Not applicable

AUTOIGNITION °C:

Not available

LEL:

Not available

UEL:

Not available

*Registered trademark of American Cyanamid Company.

ACROBAT MZ 690 Fungicide

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INGREDIENTS

INGREDIENT

CAS No.

PROPORTION (w/w)

dimethomorph

110488-70-5

9.0%

mancozeb

8018-01-7

60.0%

inert ingredients

31.0%

HEALTH HAZARD INFORMATION

HEALTH EFFECTS

ACUTE EFFECTS

The product is considered to be a skin sensitiser and a slight eye irritant.

Repeated exposure may cause allergic disorders.

Otherwise, no adverse health effects are expected if the product is handled in accordance with this Material

Safety Data Sheet and the product label.

SWALLOWED

Harmful if swallowed.

EYE

Will irritate the eyes.

SKIN

The product is considered to be a skin sensitiser and may irritate skin.

INHALED

Relatively low toxicity. May irritate nose and throat.

CHRONIC EFFECTS

Chronic feeding studies in animals do not indicate any cumulative toxicity and show that the compound is neither

a carcinogen nor a teratogen.

FIRST AID

If poisoning occurs, contact a doctor or Poisons Information Centre. Avoid giving alcohol.

SWALLOWED

If poisoning occurs, contact a doctor or Poisons Information Centre. Avoid giving alcohol.

EYE

Flush with water

SKIN

Remove contaminated clothing and wash skin thoroughly with soap and water.

INHALED

ACROBAT MZ 690 Fungicide

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Remove person from contaminated area.

ACROBAT MZ 690 Fungicide

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Page 4 of 4

ADVICE TO DOCTOR

The product is of very low acute oral and dermal toxicity and poisoning is unlikely to occur. Treatment should be

symptomatic.

TOXICITY

Acute Toxicity LD

(mg / kg )

Rat oral

1746

Rat dermal

> 2000

PRECAUTIONS FOR USE

EXPOSURE LIMITS

Limits not established.

ENGINEERING CONTROLS

Ensure adequate ventilation. Avoid raising a dust cloud.

PERSONAL PROTECTION

Avoid contact with eyes. When opening the container and using the prepared spray, wear cotton overalls

buttoned to the neck and wrist and a washable hat and elbow-length PVC gloves. Wash hands after use. After

each day’s use, wash gloves and contaminated clothing.

RE-ENTRY PERIOD

Workers should NOT enter treated areas without cotton overalls and elbow-length PVC gloves until spray has

dried.

FLAMMABILITY

Fine dust clouds may form explosive mixtures with air.

SAFE HANDLING INFORMATION

STORAGE AND TRANSPORT

Store in the closed, original container in a dry, well-ventilated area, as cool as possible. Do not store for

prolonged periods in direct sunlight.

SPILLS AND DISPOSAL

Sweep or vacuum up avoiding the formation of a dust cloud. Place in sealable containers then dispose. Bury in

an approved landfill. If leaking container can be repacked, contact Cyanamid Agriculture Pty. Limited, so that an

overdrum and transport for return to a nominated Cyanamid location can be arranged.

Do not flush to drains or sewers. Do not contaminate streams, rivers or water courses.

Following on-farm use, single rinse bags before disposal. Add rinsings to spray tank. Do not dispose of

undiluted chemical on-site. Puncture and bury empty containers in a local authority landfill. If not available,

bury the containers below 500 mm in a disposal pit specifically marked and set up for this purpose clear of

waterways, vegetation and roots. Do not burn empty containers or product.

FIRE/EXPLOSION HAZARD

ACROBAT MZ 690 Fungicide

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Page 5 of 4

Fine dust may form explosive mixtures with air. May emit toxic fumes of carbon disulphide in a fire.

ACROBAT MZ 690 Fungicide

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Page 6 of 4

EXTINGUISHING MEDIA

Dry powder, CO

, foam or water spray. For fire-fighting, wear full protective clothing and self-contained breathing

apparatus.

OTHER INFORMATION

PROTECTION OF WILDLIFE, FISH, CRUSTACEA AND ENVIRONMENT

Highly toxic to fish and other aquatic organisms. Do NOT contaminate ponds, dams, streams, waterways or

drains with the chemical or used containers.

Do NOT apply under meteorological conditions or from spraying equipment which could be expected to cause

spray to drift onto nearby susceptible plants, adjacent crops, crop lands or pastures.

DISCLAIMER

The information provided in these MSDS’s is based upon sources believed to be accurate. However, the

Company assumes no responsibility for the accuracy, completeness or suitability of this information. The product

user is responsible to determine the suitability of this information for their particular purposes.

CONTACT POINT:

Cyanamid Agriculture Pty. Limited

TELEPHONE:

(02) 9624 9333

EMERGENCY:

1 800 033 111

DATE OF ISSUE:

10 December 1999

SUPERCEDES:

25 September 1997

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