4FARMERS CHLORSULFURON 750 WDG WATER DISPERSIBLE GRANULES

Australia - English - APVMA (Australian Pesticides and Veterinary Medicines Authority)

Active ingredient:
CHLORSULFURON
Available from:
4 FARMERS AUSTRALIA PTY LTD
INN (International Name):
chlorsulfuron(750g/kg)
Pharmaceutical form:
WATER DISPERSIBLE GRANULE
Composition:
CHLORSULFURON UREA-SULFONYL Active 750.0 g/kg
Units in package:
1kg
Class:
A - Agricultural
Manufactured by:
4 FARMERS
Therapeutic group:
BARLEY | CEREAL RYE | OATS | TRITICALE | TRITICALE - PRIOR TO SOWING | WHEAT | WHEAT - PRIOR TO SOWING
Therapeutic area:
HERBICIDE
Therapeutic indications:
AFRICAN TURNIP WEED | AMSINCKIA,YELLOW BURRWEED OR BURR GRASS | ANNUAL OR WIMMERA RYEGRASS | ANNUAL PHALARIS | BALL MUSTARD | BARLEY GRASS | BIFORA, CARROT WEED OR BIRD'S EYE | BLACK BINDWEED | BROME GRASS | CAPE TULIP | CAPEWEED | CHAMOMILE OR MATRICARIA | CHARLOCK | COMMON ICEPLANT | CORN GROMWELL, IRONWEED OR SHEEPWEED | DEADNETTLE | DENSEFLOWER FUMITORY (RED) | DOCK | ERODIUM, CROWFOOT OR STORKSBILL | FAT HEN | FUMITORY | HOARY CRESS OR WHITEWEED | INDIAN HEDGE MUSTARD | LINCOLN WEED, SAND ROCKET OR MUSTARD | LOOSESTRIFE | MELILOTUS OR HEXHAM SCENT | MINTWEED | MOUSE-EAR CHICKWEED | MUSTARD | NEW ZEALAND SPINACH | ONION OR GUILDFORD GRASS | PARADOXA GRASS | PATERSON'S CURSE | PIMPERNELS | PRICKLY LETTUCE | ROUGH POPPY | SAFFRON THISTLE | SALTBUSH | SHEPHERD'S PURSE | SLENDER CELERY | SLENDER, SHORE OR SHEEP THISTLE | SOURSOB OR OXALIS | SPEAR OR BLACK THISTLE | STAGGER WEED | STEMLESS THISTLE | THREE CORNERED JACK OR DOUBLEGEE | TREE HOGWEED | TURNIP WEED | WILD RADISH OR RADISH WEED | WILD TURNIP | WIREW
Product summary:
Poison schedule: 5; Withholding period: WHP: NIL; Host/pest details: BARLEY: [AFRICAN TURNIP WEED, AMSINCKIA,YELLOW BURRWEED OR BURR GRASS, ANNUAL OR WIMMERA RYEGRASS, BALL MUSTARD, BIFORA, CARROT WEED OR BIRD'S EYE, BLACK BINDWEED, CAPE TULIP, CHAMOMILE OR MATRICARIA, CHARLOCK, CORN GROMWELL, IRONWEED OR SHEEPWEED, DEADNETTLE, DENSEFLOWER FUMITORY (RED), DOCK, ERODIUM, CROWFOOT OR STORKSBILL, FAT HEN, HOARY CRESS OR WHITEWEED, LINCOLN WEED, SAND ROCKET OR MUSTARD, MINTWEED, MOUSE-EAR CHICKWEED, MUSTARD, NEW ZEALAND SPINACH, ONION OR GUILDFORD GRASS, PATERSON'S CURSE, PIMPERNELS, PRICKLY LETTUCE, ROUGH POPPY, SALTBUSH, SHEPHERD'S PURSE, SLENDER CELERY, SOURSOB OR OXALIS, SPEAR OR BLACK THISTLE, STAGGER WEED, STEMLESS THISTLE, TREE HOGWEED, TURNIP WEED, WILD RADISH OR RADISH WEED, WILD TURNIP, WIREWEED, KNOTWEED OR HOGWEED]; CEREAL RYE: [AFRICAN TURNIP WEED, AMSINCKIA,YELLOW BURRWEED OR BURR GRASS, ANNUAL OR WIMMERA RYEGRASS, BALL MUSTARD, BIFORA, CARROT WEED OR BIRD'S EYE, BLACK BINDWEED, CAPE TULIP, CHAMOMILE OR MATRICARIA, CHARLOCK, CORN GROMWELL, IRONWEED OR SHEEPWEED, DEADNETTLE, DENSEFLOWER FUMITORY (RED), DOCK, ERODIUM, CROWFOOT OR STORKSBILL, FAT HEN, HOARY CRESS OR WHITEWEED, LINCOLN WEED, SAND ROCKET OR MUSTARD, MINTWEED, MOUSE-EAR CHICKWEED, MUSTARD, NEW ZEALAND SPINACH, ONION OR GUILDFORD GRASS, PATERSON'S CURSE, PIMPERNELS, PRICKLY LETTUCE, ROUGH POPPY, SALTBUSH, SHEPHERD'S PURSE, SLENDER CELERY, SOURSOB OR OXALIS, SPEAR OR BLACK THISTLE, STAGGER WEED, STEMLESS THISTLE, TREE HOGWEED, TURNIP WEED, WILD RADISH OR RADISH WEED, WILD TURNIP, WIREWEED, KNOTWEED OR HOGWEED]; OATS: [AFRICAN TURNIP WEED, AMSINCKIA,YELLOW BURRWEED OR BURR GRASS, ANNUAL OR WIMMERA RYEGRASS, BALL MUSTARD, BIFORA, CARROT WEED OR BIRD'S EYE, BLACK BINDWEED, CAPE TULIP, CHAMOMILE OR MATRICARIA, CHARLOCK, CORN GROMWELL, IRONWEED OR SHEEPWEED, DEADNETTLE, DENSEFLOWER FUMITORY (RED), DOCK, ERODIUM, CROWFOOT OR STORKSBILL, FAT HEN, HOARY CRESS OR WHITEWEED, LINCOLN WEED, SAND ROCKET OR MUSTARD, MINTWEED, MOUSE-EAR CHICKWEED, MUSTARD, NEW ZEALAND SPINACH, ONION OR GUILDFORD GRASS, PATERSON'S CURSE, PIMPERNELS, PRICKLY LETTUCE, ROUGH POPPY, SALTBUSH, SHEPHERD'S PURSE, SLENDER CELERY, SOURSOB OR OXALIS, SPEAR OR BLACK THISTLE, STAGGER WEED, STEMLESS THISTLE, TREE HOGWEED, TURNIP WEED, WILD RADISH OR RADISH WEED, WILD TURNIP, WIREWEED, KNOTWEED OR HOGWEED]; TRITICALE: [AFRICAN TURNIP WEED, AMSINCKIA,YELLOW BURRWEED OR BURR GRASS, ANNUAL OR WIMMERA RYEGRASS, BALL MUSTARD, BIFORA, CARROT WEED OR BIRD'S EYE, BLACK BINDWEED, CAPE TULIP, CHAMOMILE OR MATRICARIA, CHARLOCK, CORN GROMWELL, IRONWEED OR SHEEPWEED, DEADNETTLE, DENSEFLOWER FUMITORY (RED), DOCK, ERODIUM, CROWFOOT OR STORKSBILL, FAT HEN, HOARY CRESS OR WHITEWEED, LINCOLN WEED, SAND ROCKET OR MUSTARD, MINTWEED, MOUSE-EAR CHICKWEED, MUSTARD, NEW ZEALAND SPINACH, ONION OR GUILDFORD GRASS, PATERSON'S CURSE, PIMPERNELS, PRICKLY LETTUCE, ROUGH POPPY, SALTBUSH, SHEPHERD'S PURSE, SLENDER CELERY, SOURSOB OR OXALIS, SPEAR OR BLACK THISTLE, STAGGER WEED, STEMLESS THISTLE, TREE HOGWEED, TURNIP WEED, WILD RADISH OR RADISH WEED, WILD TURNIP, WIREWEED, KNOTWEED OR HOGWEED]; TRITICALE - PRIOR TO SOWING: [AFRICAN TURNIP WEED, AMSINCKIA,YELLOW BURRWEED OR BURR GRASS, ANNUAL OR WIMMERA RYEGRASS, ANNUAL PHALARIS, BALL MUSTARD, BARLEY GRASS, BLACK BINDWEED, BROME GRASS, CAPE TULIP, CAPEWEED, CHARLOCK, COMMON ICEPLANT, CORN GROMWELL, IRONWEED OR SHEEPWEED, DEADNETTLE, DOCK, ERODIUM, CROWFOOT OR STORKSBILL, FAT HEN, FUMITORY, INDIAN HEDGE MUSTARD, LINCOLN WEED, SAND ROCKET OR MUSTARD, LOOSESTRIFE, MELILOTUS OR HEXHAM SCENT, MINTWEED, MOUSE-EAR CHICKWEED, NEW ZEALAND SPINACH, ONION OR GUILDFORD GRASS, PARADOXA GRASS, PATERSON'S CURSE, PIMPERNELS, PRICKLY LETTUCE, ROUGH POPPY, SAFFRON THISTLE, SALTBUSH, SHEPHERD'S PURSE, SLENDER CELERY, SLENDER, SHORE OR SHEEP THISTLE, SOURSOB OR OXALIS, SPEAR OR BLACK THISTLE, STEMLESS THISTLE, THREE CORNERED JACK OR DOUBLEGEE, TREE HOGWEED, TURNIP WEED, WILD TURNIP, WIREWEED, KNOTWEED OR HOGWEED]; WHEAT: [AFRICAN TURNIP WEED, AMSINCKIA,YELLOW BURRWEED OR BURR GRASS, ANNUAL OR WIMMERA RYEGRASS, BALL MUSTARD, BIFORA, CARROT WEED OR BIRD'S EYE, BLACK BINDWEED, CAPE TULIP, CHAMOMILE OR MATRICARIA, CHARLOCK, CORN GROMWELL, IRONWEED OR SHEEPWEED, DEADNETTLE, DENSEFLOWER FUMITORY (RED), DOCK, ERODIUM, CROWFOOT OR STORKSBILL, FAT HEN, HOARY CRESS OR WHITEWEED, LINCOLN WEED, SAND ROCKET OR MUSTARD, MINTWEED, MOUSE-EAR CHICKWEED, MUSTARD, NEW ZEALAND SPINACH, ONION OR GUILDFORD GRASS, PATERSON'S CURSE, PIMPERNELS, PRICKLY LETTUCE, ROUGH POPPY, SALTBUSH, SHEPHERD'S PURSE, SLENDER CELERY, SOURSOB OR OXALIS, SPEAR OR BLACK THISTLE, STAGGER WEED, STEMLESS THISTLE, TREE HOGWEED, TURNIP WEED, WILD RADISH OR RADISH WEED, WILD TURNIP, WIREWEED, KNOTWEED OR HOGWEED]; WHEAT - PRIOR TO SOWING: [AFRICAN TURNIP WEED, AMSINCKIA,YELLOW BURRWEED OR BURR GRASS, ANNUAL OR WIMMERA RYEGRASS, ANNUAL PHALARIS, BALL MUSTARD, BARLEY GRASS, BLACK BINDWEED, BROME GRASS, CAPE TULIP, CAPEWEED, CHARLOCK, COMMON ICEPLANT, CORN GROMWELL, IRONWEED OR SHEEPWEED, DEADNETTLE, DOCK, ERODIUM, CROWFOOT OR STORKSBILL, FAT HEN, FUMITORY, INDIAN HEDGE MUSTARD, LINCOLN WEED, SAND ROCKET OR MUSTARD, LOOSESTRIFE, MELILOTUS OR HEXHAM SCENT, MINTWEED, MOUSE-EAR CHICKWEED, NEW ZEALAND SPINACH, ONION OR GUILDFORD GRASS, PARADOXA GRASS, PATERSON'S CURSE, PIMPERNELS, PRICKLY LETTUCE, ROUGH POPPY, SAFFRON THISTLE, SALTBUSH, SHEPHERD'S PURSE, SLENDER CELERY, SLENDER, SHORE OR SHEEP THISTLE, SOURSOB OR OXALIS, SPEAR OR BLACK THISTLE, STEMLESS THISTLE, THREE CORNERED JACK OR DOUBLEGEE, TREE HOGWEED, TURNIP WEED, WILD TURNIP, WIREWEED, KNOTWEED OR HOGWEED]; Poison schedule: 5; Withholding period: ; Host/pest details: BARLEY: [AFRICAN TURNIP WEED, AMSINCKIA,YELLOW BURRWEED OR BURR GRASS, ANNUAL OR WIMMERA RYEGRASS, BALL MUSTARD, BIFORA, CARROT WEED OR BIRD'S EYE, BLACK BINDWEED, CAPE TULIP, CHAMOMILE OR MATRICARIA, CHARLOCK, CORN GROMWELL, IRONWEED OR SHEEPWEED, DEADNETTLE, DENSEFLOWER FUMITORY (RED), DOCK, ERODIUM, CROWFOOT OR STORKSBILL, FAT HEN, HOARY CRESS OR WHITEWEED, LINCOLN WEED, SAND ROCKET OR MUSTARD, MINTWEED, MOUSE-EAR CHICKWEED, MUSTARD, NEW ZEALAND SPINACH, ONION OR GUILDFORD GRASS, PATERSON'S CURSE, PIMPERNELS, PRICKLY LETTUCE, ROUGH POPPY, SALTBUSH, SHEPHERD'S PURSE, SLENDER CELERY, SOURSOB OR OXALIS, SPEAR OR BLACK THISTLE, STAGGER WEED, STEMLESS THISTLE, TREE HOGWEED, TURNIP WEED, WILD RADISH OR RADISH WEED, WILD TURNIP, WIREWEED, KNOTWEED OR HOGWEED]; CEREAL RYE: [AFRICAN TURNIP WEED, AMSINCKIA,YELLOW BURRWEED OR BURR GRASS, ANNUAL OR WIMMERA RYEGRASS, BALL MUSTARD, BIFORA, CARROT WEED OR BIRD'S EYE, BLACK BINDWEED, CAPE TULIP, CHAMOMILE OR MATRICARIA, CHARLOCK, CORN GROMWELL, IRONWEED OR SHEEPWEED, DEADNETTLE, DENSEFLOWER FUMITORY (RED), DOCK, ERODIUM, CROWFOOT OR STORKSBILL, FAT HEN, HOARY CRESS OR WHITEWEED, LINCOLN WEED, SAND ROCKET OR MUSTARD, MINTWEED, MOUSE-EAR CHICKWEED, MUSTARD, NEW ZEALAND SPINACH, ONION OR GUILDFORD GRASS, PATERSON'S CURSE, PIMPERNELS, PRICKLY LETTUCE, ROUGH POPPY, SALTBUSH, SHEPHERD'S PURSE, SLENDER CELERY, SOURSOB OR OXALIS, SPEAR OR BLACK THISTLE, STAGGER WEED, STEMLESS THISTLE, TREE HOGWEED, TURNIP WEED, WILD RADISH OR RADISH WEED, WILD TURNIP, WIREWEED, KNOTWEED OR HOGWEED]; OATS: [AFRICAN TURNIP WEED, AMSINCKIA,YELLOW BURRWEED OR BURR GRASS, ANNUAL OR WIMMERA RYEGRASS, BALL MUSTARD, BIFORA, CARROT WEED OR BIRD'S EYE, BLACK BINDWEED, CAPE TULIP, CHAMOMILE OR MATRICARIA, CHARLOCK, CORN GROMWELL, IRONWEED OR SHEEPWEED, DEADNETTLE, DENSEFLOWER FUMITORY (RED), DOCK, ERODIUM, CROWFOOT OR STORKSBILL, FAT HEN, HOARY CRESS OR WHITEWEED, LINCOLN WEED, SAND ROCKET OR MUSTARD, MINTWEED, MOUSE-EAR CHICKWEED, MUSTARD, NEW ZEALAND SPINACH, ONION OR GUILDFORD GRASS, PATERSON'S CURSE, PIMPERNELS, PRICKLY LETTUCE, ROUGH POPPY, SALTBUSH, SHEPHERD'S PURSE, SLENDER CELERY, SOURSOB OR OXALIS, SPEAR OR BLACK THISTLE, STAGGER WEED, STEMLESS THISTLE, TREE HOGWEED, TURNIP WEED, WILD RADISH OR RADISH WEED, WILD TURNIP, WIREWEED, KNOTWEED OR HOGWEED]; TRITICALE: [AFRICAN TURNIP WEED, AMSINCKIA,YELLOW BURRWEED OR BURR GRASS, ANNUAL OR WIMMERA RYEGRASS, BALL MUSTARD, BIFORA, CARROT WEED OR BIRD'S EYE, BLACK BINDWEED, CAPE TULIP, CHAMOMILE OR
Authorization status:
Registered
Authorization number:
49836
Authorization date:
2020-07-01

further

lnfonnation see

Material Safety

Data

Sheet.

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49836/01

CHLORSULFURON

Water

Dispersible

Granules

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CONTENTS

CAUTION

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IIIREClIllNS

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CHLORSULFURON

Water Dispersible Granules

AcrlVE CONSTITUENT,

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HERBICIDE

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Page 1/6

SAFETY DATA SHEET

According to Safe Work Australia

Printing date 23.08.2016

Revision: 23.08.2016

43.0

1

. IDENTIFICATION: PRODUCT IDENTIFIER AND CHEMICAL IDENTITY

Product Name: 4FARMERS CHLORSULFURON 750 WDG HERBICIDE

Other Means of Identification:

Mixture

Recommended Use of the Chemical and Restriction on Use:

Agricultural herbicide

Details of Manufacturer or Importer:

4Farmers Australia Pty Ltd

70 McDowell Street

Welshpool WA 6106

Phone Number:

+61 8 9356 3446

Emergency telephone number:

National Poison Information Centre: 13 11 26

2

. HAZARDS IDENTIFICATION

Hazardous Nature:

Not classified as Hazardous according to the Globally Harmonised System of Classification and Labelling of

Chemicals (GHS) and Safe Work Australia criteria.

Not classified as Dangerous Goods according to the Australian Code for the Transport of Dangerous Goods

by Road and Rail. (7th edition)

environment

Aquatic Acute 1

H400 Very toxic to aquatic life.

Aquatic Chronic 1 H410 Very toxic to aquatic life with long lasting effects.

Signal Word

Warning

Hazard Statements

H410 Very toxic to aquatic life with long lasting effects.

Precautionary Statements

P273 Avoid release to the environment.

P391 Collect spillage.

P501 Dispose of contents/container in accordance with local/regional/national regulations.

3

. COMPOSITION AND INFORMATION ON INGREDIENTS

Chemical Characterization: Mixtures

Description:

Mixture of substances listed below with nonhazardous additions.

Hazardous Components:

64902-72-3 Chlorsulfuron (ISO)

Aquatic Acute 1, H400; Aquatic Chronic 1, H410

471-34-1 Carbonic acid, calcium salt (1:1)

Eye Irrit. 2A, H319

<10%

4

. FIRST AID MEASURES

Inhalation:

First aid is not normally required. If inhaled, remove to fresh air. If not breathing, give artificial respiration. If

breathing is difficult, give oxygen. Seek medical attention if breathing problems develop.

Skin Contact:

In case of skin contact, immediately remove contaminated clothing and wash affected areas with water and

soap. Seek medical attention if symptoms occur.

(Contd. on page 2)

Page 2/6

SAFETY DATA SHEET

According to Safe Work Australia

Printing date 23.08.2016

Revision: 23.08.2016

Product Name: 4FARMERS CHLORSULFURON 750 WDG HERBICIDE

(Contd. of page 1)

43.0

Eye Contact:

In case of eye contact, hold eyelids open and flush eye conitnuously with large amounts of water for at least

15 minutes. Seek medical attention if symptoms occur.

Ingestion:

If swallowed, do not induce vomiting. Rinse out mouth with water and give water to drink. Do not give anything

by mouth to an unconscious person. Seek immediate medical attention.

Symptoms Caused by Exposure:

Eye Contact: May cause serious eye irritation and inflammation.

5

. FIRE FIGHTING MEASURES

Suitable Extinguishing Media:

Water fog, foam, dry chemical or carbon dioxide.

Specific Hazards Arising from the Chemical:

Hazardous combustion products include oxides of carbon and nitrogen and hydrogen chloride.

Product is not flammable.

Special Protective Equipment and Precautions for Fire Fighters:

When fighting a major fire wear self-contained breathing apparatus and protective equipment.

6

. ACCIDENTAL RELEASE MEASURES

Personal Precautions, Protective Equipment and Emergency Procedures:

Wear approved dust/particulate filter respirator and full protective clothing. Evacuate all non-essential

personnel from affected area. Do not breathe dust. Ensure adequate ventilation. Avoid generating dust.

Environmental Precautions:

In the event of a major spill, prevent spillage from entering drains or water courses.

Methods and Materials for Containment and Cleaning Up:

Stop leak if safe to do so and sweep granules into a pile and shovel into drums for subsequent disposal. Avoid

generating dust. Provide adequate ventilation. Wash area after spills.

7

. HANDLING AND STORAGE

Precautions for Safe Handling:

Use of safe work practices are recommended to avoid eye or skin contact and inhalation of dust.

Food, beverages and tobacco products should not be stored or consumed where this material is in use.

Always wash hands before smoking, eating, drinking or using the toilet. Wash contaminated clothing and

other protective equipment before storage or re-use. Provide eyewash fountains and safety showers in close

proximity to points of potential exposure.

Conditions for Safe Storage:

Store in a cool, dry and well ventilated area. Keep container tightly closed when not in use. Protect from

extreme temperatures. Keep away from strong oxidising agents, strong acids and strong bases.

8

. EXPOSURE CONTROLS AND PERSONAL PROTECTION

Exposure Standards:

471-34-1 Carbonic acid, calcium salt (1:1)

NES TWA: 10 mg/m³

Engineering Controls:

Maintain air concentration below occupational exposure standards, providing adequate ventilation.

(Contd. on page 3)

Page 3/6

SAFETY DATA SHEET

According to Safe Work Australia

Printing date 23.08.2016

Revision: 23.08.2016

Product Name: 4FARMERS CHLORSULFURON 750 WDG HERBICIDE

(Contd. of page 2)

43.0

Respiratory Protection:

Where an inhalation risk exists, wear a Class P1 (particulate) respirator. At high dust levels, wear a powered

air purifying respirator (PAPR) with Class P3 (Particulate) filter or an air-line respirator or a full-face Class P3

(particulate) respirator. See Australian/New Zealand Standards AS/NZS 1715 and 1716 for more information.

Skin Protection:

Polychloroprene and nitrile rubber gloves. See Australian/New Zealand Standard AS/NZS 2161 for more

information.

When selecting gloves for use against certain chemicals, the degradation resistance, permeation rate and

permeation breakthrough time should be considered.

Occupational protective clothing (depending on conditions in which it has to be used, in particular as regards

the period for which it is worn, which shall be determined on the basis of the seriousness of the risk, the

frequency of exposure to the risk, the characteristics of the workstation of each worker and the performance of

the protective clothing). See Australian/New Zealand Standard AS/NZS 4501 for more information.

Eye and Face Protection:

Eye and face protectors for protection against dust. See Australian/New Zealand Standard AS/NZS 1337 for

more information.

9

. PHYSICAL AND CHEMICAL PROPERTIES

Appearance:

Form:

Granular

Colour:

White to tan

Odour:

Weak characteristic odour

Odour Threshold:

No information available

pH-Value:

No information available

Melting point/Melting range:

No information available

Initial Boiling Point/Boiling Range:

Not applicable

Flash Point:

Not applicable

Flammability:

Product is not flammable.

Auto-ignition Temperature:

Not applicable

Decomposition Temperature:

No information available

Explosion Limits:

Lower:

Not applicable

Upper:

Not applicable

Vapour Pressure:

Not applicable.

Density:

No information available

Relative Density:

Not applicable

Vapour Density:

Not applicable.

Evaporation Rate:

No information available

Solubility in Water:

Wettable

10 . STABILITY AND REACTIVITY

Possibility of Hazardous Reactions:

Hazardous polymerisation will not occur.

Chemical Stability:

Stable at ambient temperature and under normal conditions of use.

Conditions to Avoid:

Extreme temperatures.

Incompatible Materials:

Strong oxidising agents, strong acids and strong bases.

Hazardous Decomposition Products:

Oxides of carbon and nitrogen and hydrogen chloride.

(Contd. on page 4)

Page 4/6

SAFETY DATA SHEET

According to Safe Work Australia

Printing date 23.08.2016

Revision: 23.08.2016

Product Name: 4FARMERS CHLORSULFURON 750 WDG HERBICIDE

(Contd. of page 3)

43.0

11 . TOXICOLOGICAL INFORMATION

Toxicity:

LD

₅₀

/LC

₅₀

Values Relevant for Classification:

471-34-1 Carbonic acid, calcium salt (1:1)

Oral

₅₀

6450 mg/kg (rat)

64902-72-3 Chlorsulfuron (ISO)

Oral

₅₀

5545 mg/kg (rat)

Inhalation LC

₅₀

/4 h >5900 mg/m³ (rat)

Acute Health Effects

Inhalation:

No information available

Skin:

No information available

Eye:

May cause serious eye irritation and inflammation.

Ingestion:

No information available

Skin Corrosion / Irritation:

Based on classification principles, the classification criteria are not met.

Serious Eye Damage / Irritation:

Based on classification principles, the classification criteria are not met.

Respiratory or Skin Sensitisation:

Based on classification principles, the classification criteria are not met.

Germ Cell Mutagenicity:

Based on classification principles, the classification criteria are not met.

Carcinogenicity:

This product does NOT contain any IARC listed chemicals.

Reproductive Toxicity:

Based on classification principles, the classification criteria are not met.

Specific Target Organ Toxicity (STOT) - Single Exposure:

Based on classification principles, the classification criteria are not met.

Specific Target Organ Toxicity (STOT) - Repeated Exposure:

Based on classification principles, the classification criteria are not met.

Aspiration Hazard:

Based on classification principles, the classification criteria are not met.

Chronic Health Effects:

Repeated or prolonged skin exposure may cause irritation, redness and dermatitis. Repeated or prolonged

eye contact may cause conjunctivitis.

Existing Conditions Aggravated by Exposure:

No information available

Additional toxicological information:

The Australian Acceptable Daily Intake (ADI) for chlorsulfuron for a human is 0.05 mg/kg/day, set for the

public for daily, lifetime exposure. This is based on the NOEL of 5 mg/kg/day, the level determined to show no

effects during long term exposure for the most sensitive indicators and the most sensitive species. (Ref:

Comm. Dept. of Health and Ageing Office of Chemical Safety, 'ADI List', June 2014).

12 . ECOLOGICAL INFORMATION

Ecotoxicity:

Toxic to soil organisms.

Aquatic toxicity:

Very Toxic to aquatic life with long lasting effects.

64902-72-3 Chlorsulfuron (ISO)

₅₀

/48 h 370 mg/L (daphnia)

Persistence and Degradability:

No information available

(Contd. on page 5)

Page 5/6

SAFETY DATA SHEET

According to Safe Work Australia

Printing date 23.08.2016

Revision: 23.08.2016

Product Name: 4FARMERS CHLORSULFURON 750 WDG HERBICIDE

(Contd. of page 4)

43.0

Bioaccumulative Potential:

No information available

Mobility in Soil:

No information available

13 . DISPOSAL CONSIDERATIONS

Disposal Methods and Containers:

Dispose according to applicable local and state government regulations.

Special Precautions for Landfill or Incineration:

Please consult your state Land Waste Management Authority for more information.

14 . TRANSPORT INFORMATION

UN Number

ADG

Not regulated

IMDG, IATA

UN3077

Proper Shipping Name

ADG

Not regulated

IMDG

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Chlorsulfuron (ISO)),

MARINE POLLUTANT

IATA

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Chlorsulfuron (ISO))

Dangerous Goods Class

ADG Class:

Not regulated

IMDG Class:

9 Miscellaneous dangerous substances and articles.

Packing Group:

ADG

Not regulated

IMDG, IATA

Marine pollutant:

Symbol (fish and tree)

EMS Number:

F-A,S-F

Hazchem Code:

15 . REGULATORY INFORMATION

Australian Inventory of Chemical Substances:

64902-72-3 Chlorsulfuron (ISO)

471-34-1 Carbonic acid, calcium salt (1:1)

Standard for the Uniform Scheduling of Drugs and Poisons (SUSMP) - Poison Schedule:

Poisons Schedule: 5

16 . OTHER INFORMATION

Date of Preparation or Last Revision:

23.08.2016

Prepared by:

MSDS.COM.AU Pty Ltd www.msds.com.au

Abbreviations and acronyms:

ADG: Australian Dangerous Goods

IMDG: International Maritime Code for Dangerous Goods

IATA: International Air Transport Association

GHS: Globally Harmonised System of Classification and Labelling of Chemicals

CAS: Chemical Abstracts Service (division of the American Chemical Society)

₅₀

: Lethal concentration, 50 percent

₅₀

: Lethal dose, 50 percent

IARC: International Agency for Research on Cancer

(Contd. on page 6)

Page 6/6

SAFETY DATA SHEET

According to Safe Work Australia

Printing date 23.08.2016

Revision: 23.08.2016

Product Name: 4FARMERS CHLORSULFURON 750 WDG HERBICIDE

(Contd. of page 5)

43.0

STEL: Short Term Exposure Limit

TWA: Time Weighted Average

NES: National Exposure Standard (Safe Work Australia - Workplace Exposure Standards For Airborne Contaminants)

Eye Irrit. 2A: Serious eye damage/eye irritation – Category 2A

Aquatic Acute 1: Hazardous to the aquatic environment, short-term (Acute). Category 1

Aquatic Chronic 1: Hazardous to the aquatic environment, long-term (Chronic). Category 1

Disclaimer

This SDS is prepared in accord with the Safe Work Australia document “Code of Practice for the Preparation

of Safety Data Sheets for Hazardous Chemicals - December 2011”

The information contained in this safety data sheet is provided in good faith and is believed to be accurate at

the date of issuance. 4Farmers Australia Pty Ltd makes no representation of the accuracy or

comprehensiveness of the information and to the full extent allowed by law excludes all liability for any loss or

damage related to the supply or use of the information in this material safety data sheet. MSDS.COM.AU Pty

Ltd is not in a position to warrant the accuracy of the data herein. The user is cautioned to make their own

determinations as to the suitability of the information provided to the particular circumstances in which the

product is used.

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