AQUANOMIC SOLID DETERGENT

Primær information

  • Handelsnavn:
  • AQUANOMIC SOLID DETERGENT
  • Brugt til:
  • Mennesker
  • Medicin typen:
  • Medicinsk udstyr

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Lokation

  • Fås i:
  • AQUANOMIC SOLID DETERGENT
    Irland
  • Sprog:
  • engelsk

Status

  • Kilde:
  • Ecolab
  • Autorisationsnummer:
  • 116097E
  • Sidste ændring:
  • 12-03-2018

Produktresumé: dosering, interaktioner, bivirkninger

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

AQUANOMIC SOLID DETERGENT

116097E

1 / 14

SECTION 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE

COMPANY/UNDERTAKING

1.1 Product identifier

Product name

AQUANOMIC SOLID DETERGENT

Product code

116097E

Type of substance

Mixture

For professional users only.

Product dilution information

0.05 % - 0.11 %

1.2 Relevant identified uses of the substance or mixture and uses advised against

Identified uses

Laundry detergent. Automatic process

Recommended restrictions

on use

Reserved for industrial and professional use.

1.3 Details of the supplier of the safety data sheet

Company

Ecolab Ltd.

PO Box 11; Winnington Avenue

Northwich, Cheshire, United Kingdom CW8 4DX

+353 (0)1 276 3500

ccs@ecolab.com

1.4 Emergency telephone number

Emergency telephone

number

+353 (0)1 276 3500

Poison Information Centre

telephone number

For medical professionals only:

+353 (0)1 837 9964 (8am-10pm)

Date of Compilation/Revision

21.07.2014

version

SECTION 2. HAZARDS IDENTIFICATION

2.1 Classification of the substance or mixture

Classification (REGULATION (EC) No 1272/2008)

Product AS SOLD

Skin corrosion , Category 1A

H314

Product AT USE DILUTION

Not a hazardous substance or mixture.

Classification (67/548/EEC, 1999/45/EC)

Product AS SOLD

C; CORROSIVE

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

AQUANOMIC SOLID DETERGENT

116097E

2 / 14

Product AT USE DILUTION

The product does not need to be labelled in accordance with EC directives or respective national

laws.

For the full text of the R-phrases mentioned in this Section, see Section 16.

For the full text of the H-Statements mentioned in this Section, see Section 16.

2.2 Label elements

Labelling (REGULATION (EC) No 1272/2008)

Product AS SOLD

Hazard pictograms

Signal Word

Danger

Hazard Statements

H314

Causes severe skin burns and eye damage.

Precautionary Statements

Prevention:

P280

Wear protective gloves/ eye protection/ face

protection.

Response:

P303 + P361 + P353

IF ON SKIN (or hair): Remove/ Take off

immediately all contaminated clothing. Rinse

skin with water/ shower.

P305 + P351 + P338

IF IN EYES: Rinse cautiously with water

for several minutes. Remove contact lenses, if

present and easy to do. Continue rinsing.

P310

Immediately call a POISON CENTER or

doctor/ physician.

Hazardous components which must be listed on the label:

sodium hydroxide

Product AT USE DILUTION

Not a hazardous substance or mixture.

2.3 Other hazards

Product AS SOLD

None known.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

3.2 Mixtures

Product AS SOLD

Hazardous components

Chemical Name

CAS-No.

EC-No.

REACH No.

Classification

(67/548/EEC)

Classification

(REGULATION (EC) No

1272/2008)

Concentration:

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

AQUANOMIC SOLID DETERGENT

116097E

3 / 14

sodium hydroxide

1310-73-2

215-185-5

01-2119457892-27

C; R35

Skin corrosionCategory 1A;

H314

>= 30 - < 50

alcohols, c12-16,

ethoxylated

68551-12-2

Xn-Xi; R22-

R41-R38

Acute toxicityCategory 4;

H302

Skin irritationCategory 2;

H315

Serious eye damage/eye

irritationCategory 1; H318

>= 10 - < 20

Sodium Carbonate

497-19-8

207-838-8

01-2119485498-19

Xi; R36

Eye irritationCategory 2; H319

>= 5 - < 10

Product AT USE DILUTION

Remarks

No hazardous ingredients

For the full text of the R-phrases mentioned in this Section, see Section 16.

For the full text of the H-Statements mentioned in this Section, see Section 16.

SECTION 4. FIRST AID MEASURES

4.1 Description of first aid measures

Product AS SOLD

In case of eye contact

Rinse immediately with plenty of water, also under the eyelids, for

at least 15 minutes. Remove contact lenses, if present and easy

to do. Continue rinsing. Get medical attention immediately.

In case of skin contact

Wash off immediately with plenty of water for at least 15 minutes.

Use a mild soap if available. Wash clothing before reuse.

Thoroughly clean shoes before reuse. Get medical attention

immediately.

If swallowed

Rinse mouth with water. Do NOT induce vomiting. Never give

anything by mouth to an unconscious person. Get medical

attention immediately.

If inhaled

Remove to fresh air. Treat symptomatically. Get medical attention

if symptoms occur.

Product AT USE DILUTION

In case of eye contact

Rinse with plenty of water.

In case of skin contact

Rinse with plenty of water.

If swallowed

Rinse mouth. Get medical attention if symptoms occur.

If inhaled

Get medical attention if symptoms occur.

4.2 Most important symptoms and effects, both acute and delayed

See Section 11 for more detailed information on health effects and symptoms.

4.3 Indication of immediate medical attention and special treatment needed

Treatment

Treat symptomatically.

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

AQUANOMIC SOLID DETERGENT

116097E

4 / 14

SECTION 5. FIREFIGHTING MEASURES

Product AS SOLD

5.1 Extinguishing media

Suitable extinguishing media

Use extinguishing measures that are appropriate to local

circumstances and the surrounding environment.

Unsuitable extinguishing

media

None known.

5.2 Special hazards arising from the substance or mixture

Specific hazards during

firefighting

Not flammable or combustible.

Hazardous combustion

products

Decomposition products may include the following materials:

Carbon oxides

nitrogen oxides (NOx)

Sulphur oxides

Oxides of phosphorus

5.3 Advice for firefighters

Special protective equipment

for firefighters

: Use personal protective equipment.

Further information

: Fire residues and contaminated fire extinguishing water must be

disposed of in accordance with local regulations. In the event of

fire and/or explosion do not breathe fumes.

SECTION 6. ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures

Product AS SOLD

Advice for non-emergency

personnel

Ensure adequate ventilation. Keep people away from and upwind

of spill/leak. Avoid inhalation, ingestion and contact with skin and

eyes. When workers are facing concentrations above the

exposure limit they must use appropriate certified respirators.

Ensure clean-up is conducted by trained personnel only. Refer to

protective measures listed in sections 7 and 8.

Advice for emergency

responders

If specialised clothing is required to deal with the spillage, take

note of any information in Section 8 on suitable and unsuitable

materials.

Product AT USE DILUTION

Advice for non-emergency

personnel

Refer to protective measures listed in sections 7 and 8.

Advice for emergency

responders

If specialised clothing is required to deal with the spillage, take

note of any information in Section 8 on suitable and unsuitable

materials.

6.2 Environmental precautions

Product AS SOLD

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

AQUANOMIC SOLID DETERGENT

116097E

5 / 14

Environmental precautions

Do not allow contact with soil, surface or ground water.

Product AT USE DILUTION

Environmental precautions

No special environmental precautions required.

6.3 Methods and materials for containment and cleaning up

Product AS SOLD

Methods for cleaning up

Stop leak if safe to do so. Contain spillage, and then collect with

non-combustible absorbent material, (e.g. sand, earth,

diatomaceous earth, vermiculite) and place in container for

disposal according to local / national regulations (see section 13).

Flush away traces with water. For large spills, dike spilled material

or otherwise contain material to ensure runoff does not reach a

waterway. Do not flush into surface water or sanitary sewer

system.

Product AT USE DILUTION

Methods for cleaning up

Stop leak if safe to do so. Contain spillage, and then collect with

non-combustible absorbent material, (e.g. sand, earth,

diatomaceous earth, vermiculite) and place in container for

disposal according to local / national regulations (see section 13).

Flush away traces with water. For large spills, dike spilled material

or otherwise contain material to ensure runoff does not reach a

waterway. Do not flush into surface water or sanitary sewer

system.

6.4 Reference to other sections

See Section 1 for emergency contact information.

For personal protection see section 8.

See Section 13 for additional waste treatment information.

SECTION 7. HANDLING AND STORAGE

7.1 Precautions for safe handling

Product AS SOLD

Advice on safe handling

Do not ingest. Do not get in eyes, on skin, or on clothing. Do not

breathe dust/fume/gas/mist/vapours/spray. Use only with

adequate ventilation. Wash hands thoroughly after handling.

Hygiene measures

Handle in accordance with good industrial hygiene and safety

practice. Remove and wash contaminated clothing before re-use.

Wash face, hands and any exposed skin thoroughly after

handling. Provide suitable facilities for quick drenching or flushing

of the eyes and body in case of contact or splash hazard.

Product AT USE DILUTION

Advice on safe handling

Wash hands after handling. For personal protection see section 8.

Hygiene measures

Wash hands before breaks and immediately after handling the

product.

7.2 Conditions for safe storage, including any incompatibilities

Product AS SOLD

Requirements for storage

areas and containers

Keep out of reach of children. Keep container tightly closed. Store

in suitable labeled containers.

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

AQUANOMIC SOLID DETERGENT

116097E

6 / 14

Storage temperature

-30 °C to 50 °C

Product AT USE DILUTION

Requirements for storage

areas and containers

Keep out of reach of children. Keep container tightly closed. Store

in suitable labeled containers.

7.3 Specific end use(s)

Product AS SOLD

Specific use(s)

Laundry detergent. Automatic process

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 Control parameters

Product AS SOLD

Occupational Exposure Limits

CAS-No.

Components

Value type

(Form of

exposure)

Control

parameters

Update

Basis

1310-73-2

sodium

hydroxide

OELV - 15 min

(STEL)

2 mg/m3

2002-03-12

IR_OEL

8.2 Exposure controls

Product AS SOLD

Appropriate engineering controls

Engineering measures

Effective exhaust ventilation system Maintain air concentrations

below occupational exposure standards.

Individual protection measures

Hygiene measures

Handle in accordance with good industrial hygiene and safety

practice. Remove and wash contaminated clothing before re-use.

Wash face, hands and any exposed skin thoroughly after

handling. Provide suitable facilities for quick drenching or flushing

of the eyes and body in case of contact or splash hazard.

Eye/face protection (EN 166)

Safety glasses

Face-shield

Hand protection (EN 374)

Wear the following personal protective equipment:

Nitrile rubber

butyl-rubber

Impervious gloves

Gloves should be discarded and replaced if there is any indication

of degradation or chemical breakthrough.

Skin and body protection (EN

14605)

Personal protective equipment comprising: suitable protective

gloves, safety goggles and protective clothing

Respiratory protection (EN

143, 14387)

None required if airborne concentrations are maintained below the

exposure limit listed in Exposure Limit Information. Use certified

respiratory protection equipment meeting EU

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

AQUANOMIC SOLID DETERGENT

116097E

7 / 14

requirements(89/656/EEC, 89/686/EEC ), or equivalent, when

respiratory risks cannot be avoided or sufficiently limited by

technical means of collective protection or by measures, methods

or procedures of work organization.

Product AT USE DILUTION

Appropriate engineering controls

Engineering measures

Good general ventilation should be sufficient to control worker

exposure to airborne contaminants.

Individual protection measures

Hygiene measures

Wash hands before breaks and immediately after handling the

product.

Eye/face protection (EN 166)

No special protective equipment required.

Hand protection (EN 374)

No special protective equipment required.

Skin and body protection (EN

14605)

No special protective equipment required.

Respiratory protection (EN

143, 14387)

None required if airborne concentrations are maintained below the

exposure limit listed in Exposure Limit Information. Use certified

respiratory protection equipment meeting EU

requirements(89/656/EEC, 89/686/EEC ), or equivalent, when

respiratory risks cannot be avoided or sufficiently limited by

technical means of collective protection or by measures, methods

or procedures of work organization.

Environmental exposure controls

General advice

: Consider the provision of containment around storage vessels.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on basic physical and chemical properties

Product AS SOLD

Product AT USE DILUTION

Appearance

: Cast Solid

liquid

Colour

: opaque, yellow

colourless

Odour

: Perfumes, fragrances

not significant

11.8 - 13.0, 1 %

10.8 - 11.5

Flash point

Not applicable.

Odour Threshold

no data available

Melting point/freezing point

no data available

Initial boiling point and

boiling range

> 100 °C

Evaporation rate

no data available

Flammability (solid, gas)

no data available

Upper explosion limit

no data available

Lower explosion limit

no data available

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

AQUANOMIC SOLID DETERGENT

116097E

8 / 14

Vapour pressure

no data available

Relative vapour density

no data available

Relative density

1.45 - 1.55

Water solubility

insoluble

Solubility in other solvents

no data available

Partition coefficient: n-

octanol/water

no data available

Auto-ignition temperature

no data available

Thermal decomposition

no data available

Viscosity, kinematic

no data available

Explosive properties

no data available

Oxidizing properties

no data available

9.2 Other information

no data available

SECTION 10. STABILITY AND REACTIVITY

Product AS SOLD

10.1 Reactivity

No dangerous reaction known under conditions of normal use.

10.2 Chemical stability

Stable under normal conditions.

10.3 Possibility of hazardous reactions

No dangerous reaction known under conditions of normal use.

10.4 Conditions to avoid

None known.

10.5 Incompatible materials

Acids

Metals

10.6 Hazardous decomposition products

Decomposition products may include the following materials:

Carbon oxides

nitrogen oxides (NOx)

Sulphur oxides

Oxides of phosphorus

SECTION 11. TOXICOLOGICAL INFORMATION

11.1 Information on toxicological effects

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

AQUANOMIC SOLID DETERGENT

116097E

9 / 14

Product AS SOLD

Information on likely routes of

exposure

Eye contact, Skin contact

Toxicity

Acute oral toxicity

: Acute toxicity estimate : > 2,000 mg/kg

Acute inhalation toxicity

: There is no data available for this product.

Acute dermal toxicity

: There is no data available for this product.

Skin corrosion/irritation

: There is no data available for this product.

Serious eye damage/eye

irritation

: There is no data available for this product.

Respiratory or skin

sensitization

: There is no data available for this product.

Carcinogenicity

: There is no data available for this product.

Reproductive effects

: There is no data available for this product.

Germ cell mutagenicity

: There is no data available for this product.

Teratogenicity

: There is no data available for this product.

STOT - single exposure

: There is no data available for this product.

STOT - repeated exposure

: There is no data available for this product.

Aspiration toxicity

: There is no data available for this product.

Components

Acute oral toxicity

: alcohols, c12-16, ethoxylated

LD50 rat: 1,100 mg/kg

Sodium Carbonate

LD50 rat: 2,800 mg/kg

Acute dermal toxicity

: alcohols, c12-16, ethoxylated

LD50 rabbit: > 2,000 mg/kg

Potential Health Effects

Product AS SOLD

Eyes

Causes serious eye damage.

Skin

Causes severe skin burns.

Ingestion

Causes digestive tract burns.

Inhalation

May cause nose, throat, and lung irritation.

Chronic Exposure

Health injuries are not known or expected under normal use.

Product AT USE DILUTION

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

AQUANOMIC SOLID DETERGENT

116097E

10 / 14

Eyes

Health injuries are not known or expected under normal use.

Skin

Health injuries are not known or expected under normal use.

Ingestion

Health injuries are not known or expected under normal use.

Inhalation

Health injuries are not known or expected under normal use.

Chronic Exposure

Health injuries are not known or expected under normal use.

Experience with human exposure

Product AS SOLD

Eye contact

Redness, Pain, Corrosion

Skin contact

Redness, Pain, Corrosion

Ingestion

Corrosion, Abdominal pain

Inhalation

Respiratory irritation, Cough

Product AT USE DILUTION

Eye contact

No symptoms known or expected.

Skin contact

No symptoms known or expected.

Ingestion

No symptoms known or expected.

Inhalation

No symptoms known or expected.

SECTION 12. ECOLOGICAL INFORMATION

Product AS SOLD

12.1 Ecotoxicity

Environmental Effects

This product has no known ecotoxicological effects.

Product

Toxicity to fish

: no data available

Toxicity to daphnia and other

aquatic invertebrates

: no data available

Toxicity to algae

: no data available

Components

Toxicity to fish

: alcohols, c12-16, ethoxylated

96 h LC50 Fish : 1.5 mg/l

Components

Toxicity to daphnia and other

aquatic invertebrates

: sodium hydroxide

48 h EC50: 40 mg/l

Sodium Carbonate

48 h EC50 Daphnia: 200 mg/l

12.2 Persistence and degradability

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

AQUANOMIC SOLID DETERGENT

116097E

11 / 14

no data available

12.3 Bioaccumulative potential

no data available

12.4 Mobility in soil

no data available

12.5 Results of PBT and vPvB assessment

Product

Assessment

This substance/mixture contains no components considered to be

either persistent, bioaccumulative and toxic (PBT), or very

persistent and very bioaccumulative (vPvB) at levels of 0.1% or

higher.

12.6 Other adverse effects

no data available

SECTION 13. DISPOSAL CONSIDERATIONS

Dispose of in accordance with the European Directives on waste and hazardous waste.Waste

codes should be assigned by the user, preferably in discussion with the waste disposal authorities.

13.1 Waste treatment methods

Product AS SOLD

Product

: Where possible recycling is preferred to disposal or incineration. If

recycling is not practicable, dispose of in compliance with local

regulations. Dispose of wastes in an approved waste disposal

facility.

Contaminated packaging

: Dispose of as unused product. Empty containers should be taken

to an approved waste handling site for recycling or disposal. Do

not re-use empty containers.

European Waste Catalogue

: 200115* - alkalines

Product AT USE DILUTION

Product

: Where possible recycling is preferred to disposal or incineration. If

recycling is not practicable, dispose of in compliance with local

regulations. Dispose of wastes in an approved waste disposal

facility.

Contaminated packaging

: Dispose of as unused product. Empty containers should be taken

to an approved waste handling site for recycling or disposal. Do

not re-use empty containers.

SECTION 14. TRANSPORT INFORMATION

Product AS SOLD

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

AQUANOMIC SOLID DETERGENT

116097E

12 / 14

The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are

in compliance with the selected mode of transport.

Land transport (ADR/ADN/RID)

14.1 UN number

1823

14.2 UN proper shipping

name

SODIUM HYDROXIDE, SOLID

14.3 Transport hazard

class(es)

14.4 Packing group

14.5 Environmental hazards

14.6 Special precautions for

user

None

Air transport (IATA)

14.1 UN number

1823

14.2 UN proper shipping

name

Sodium hydroxide, solid

14.3 Transport hazard

class(es)

14.4 Packing group

14.5 Environmental hazards

14.6 Special precautions for

user

None

Sea Transport (IMDG/IMO)

14.1 UN number

1823

14.2 UN proper shipping

name

SODIUM HYDROXIDE, SOLID

14.3 Transport hazard

class(es)

14.4 Packing group

14.5 Environmental hazards

14.6 Special precautions for

user

None

14.7 Transport in bulk

according to Annex II of

MARPOL 73/78 and the IBC

Code

Not applicable.

Product AT USE DILUTION

Not intended for transport.

SECTION 15. REGULATORY INFORMATION

15.1 Safety, health and environmental regulations/legislation specific for the substance or

mixture

according to Detergents

Regulation EC 648/2004

5 % or over but less than 15 %: Non-ionic surfactants

less than 5 %: Polycarboxylates

Other constituents: Optical brighteners

National Regulations

Take note of Dir 94/33/EC on the protection of young people at work.

Other regulations

Safety, Health and Welfare at Work Act, 2005

European Communities (Classification, Packaging, Labelling and

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

AQUANOMIC SOLID DETERGENT

116097E

13 / 14

Notification of Dangerous Preparations) Regulations 1995. (S.I.

272 of 1995) as amended

15.2 Chemical Safety Assessment

This product contains substances for which Chemical Safety Assessments are still required.

SECTION 16. OTHER INFORMATION

Full text of R-Phrases

Harmful if swallowed.

Causes severe burns.

Irritating to eyes.

Irritating to skin.

Risk of serious damage to eyes.

Full text of H-Statements

H302

Harmful if swallowed.

H314

Causes severe skin burns and eye damage.

H315

Causes skin irritation.

H318

Causes serious eye damage.

H319

Causes serious eye irritation.

Full text of other abbreviations

Prepared by

Regulatory Affairs

Numbers quoted in the MSDS are given in the format: 1,000,000 = 1 million and 1,000 = 1

thousand. 0.1 = 1 tenth and 0.001 = 1 thousandth

REVISED INFORMATION: Significant changes to regulatory or health information for this revision

is indicated by a bar in the left-hand margin of the SDS.

The information provided in this Safety Data Sheet is correct to the best of our knowledge,

information and belief at the date of its publication. The information given is designed only as a

guidance for safe handling, use, processing, storage, transportation, disposal and release and is

not to be considered a warranty or quality specification. The information relates only to the specific

material designated and may not be valid for such material used in combination with any other

materials or in any process, unless specified in the text.

ANNEX: EXPOSURE SCENARIOS

DPD+ Substances:

The following substances are the lead substances that contribute to the mixture Exposure

Scenario according to the DPD+ Rule:

Route

Substance

CAS-No.

EINECS-No.

Ingestion

sodium hydroxide

1310-73-2

215-185-5

Inhalation

sodium hydroxide

1310-73-2

215-185-5

Dermal

sodium hydroxide

1310-73-2

215-185-5

Eyes

sodium hydroxide

1310-73-2

215-185-5

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

AQUANOMIC SOLID DETERGENT

116097E

14 / 14

aquatic environment

No lead substance

Physical properties DPD+ Substances:

Substance

Vapour pressure

Water solubility

POW

Molar Mass

sodium hydroxide

55 hPa

100 g/ml

40 g/mol

To calculate if your downstream Operating Conditions and Risk management Measures are

safe, please calculate your risk factor at the website below:

www.ecetoc.org/tra

Short title of Exposure

Scenario

Laundry detergent. Automatic process

Use descriptors

Main User Groups

Industrial uses: Uses of substances as such or in preparations at

industrial sites

Sectors of end-use

SU3: Industrial uses: Uses of substances as such or in

preparations at industrial sites

Process categories

PROC2: Use in closed, continuous process with occasional

controlled exposure

PROC8b: Transfer of substance or preparation (charging/

discharging) from/ to vessels/ large containers at dedicated

facilities

Product categories

PC35: Washing and cleaning products (including solvent based

products)

Environmental Release

Categories

ERC4: Industrial use of processing aids in processes and

products, not becoming part of articles

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