DUXIL PLUS

Основна информация

  • Търговско наименование:
  • DUXIL PLUS (905789)
  • Използвай за:
  • Хората
  • Вид на лекарството:
  • Медицински устройство

Документи

Локализация

  • Предлага се в:
  • DUXIL PLUS (905789)
    Ирландия
  • Език:
  • английски

Състояние

  • Източник:
  • Ecolab
  • Номер на разрешението:
  • 114657E
  • Последна актуализация:
  • 12-03-2018

кратка характеристика на продукта: дозировка, взаимодействия, странични ефекти.

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

DUXIL PLUS

114657E

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Section: 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE

COMPANY/UNDERTAKING

1.1 Product identifier

Product name

DUXIL PLUS

Product code

114657E

Use of the

Substance/Mixture

Booster

Substance type:

Mixture

For professional users only.

Product dilution information

No dilution information provided.

1.2 Relevant identified uses of the substance or mixture and uses advised against

Identified uses

Laundry aid (non-gasing). Automatic process

Recommended restrictions

on use

Reserved for industrial and professional use.

1.3 Details of the supplier of the safety data sheet

Company

Ecolab Ltd.

PO Box 11; Winnington Avenue

Northwich, Cheshire, United Kingdom CW8 4DX

+353 (0)1 276 3500

ccs@ecolab.com

1.4 Emergency telephone number

Emergency telephone

number

+353 (0)1 276 3500

Poison Information Centre

telephone number

For medical professionals only:

+353 (0)1 837 9964 (8am-10pm)

Date of Compilation/Revision

05.04.2017

Version

Section: 2. HAZARDS IDENTIFICATION

2.1 Classification of the substance or mixture

Classification (REGULATION (EC) No 1272/2008)

Acute toxicity, Category 4

H302

Skin irritation, Category 2

H315

Serious eye damage, Category 1

H318

Skin sensitization, Category 1

H317

Acute aquatic toxicity, Category 1

H400

Chronic aquatic toxicity, Category 2

H411

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2.2 Label elements

Labelling (REGULATION (EC) No 1272/2008)

Hazard pictograms

Signal Word

Danger

Hazard Statements

H302

Harmful if swallowed.

H315

Causes skin irritation.

H318

Causes serious eye damage.

H317

May cause an allergic skin reaction.

H400

Very toxic to aquatic life.

H411

Toxic to aquatic life with long lasting effects.

Precautionary Statements

Prevention:

P273

Avoid release to the environment.

P280

Wear protective gloves/ eye protection/ face

protection.

Response:

P305 + P351 + P338

IF IN EYES: Rinse cautiously with water

for several minutes. Remove contact lenses, if

present and easy to do. Continue rinsing.

P310

Immediately call a POISON CENTER/doctor.

Hazardous components which must be listed on the label:

Alcohols, C13-15, branched and linear, ethoxylated

alcohols, c10-16, ethoxylated

d-Limonene

2.3 Other hazards

None known.

Section: 3. COMPOSITION/INFORMATION ON INGREDIENTS

3.2 Mixtures

Hazardous components

Chemical Name

CAS-No.

EC-No.

REACH No.

ClassificationREGULATION (EC) No

1272/2008

Concentration:

Alcohols, C13-15,

branched and linear,

ethoxylated

157627-86-6

Acute toxicity Category 4; H302

Skin irritation Category 2; H315

Serious eye damage Category 1; H318

Acute aquatic toxicity Category 1; H400

>= 30 - < 50

alcohols, c10-16,

ethoxylated

68002-97-1

500-182-6

Acute toxicity Category 4; H302

Skin irritation Category 2; H315

Serious eye damage Category 1; H318

Acute aquatic toxicity Category 1; H400

>= 20 - < 25

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2-[2-(2-

butoxyethoxy)ethoxy]etha

143-22-6

205-592-6

01-2119475107-38

Serious eye damage Category 1; H318

>= 5 - < 10

Amphoteric surfactants

68604-71-7

271-704-5

Serious eye damage/eye irritation

Category 2;

Eye irritation Category 2; H319

>= 3 - < 5

propan-2-ol

67-63-0

200-661-7

01-2119457558-25

Flammable liquids Category 2; H225

Eye irritation Category 2; H319

Specific target organ toxicity - single

exposure Category 3; H336

>= 2.5 - < 3

d-Limonene

5989-27-5

227-813-5

01-2119529223-47

Nota C Flammable liquids Category 3;

H226

Skin irritation Category 2; H315

Skin sensitization Category 1; H317

Acute aquatic toxicity Category 1; H400

Chronic aquatic toxicity Category 1;

H410

>= 0.5 - < 1

methanol

67-56-1

200-659-6

01-2119433307-44

** Flammable liquids Category 2; H225

Acute toxicity Category 3; H301

Acute toxicity Category 3; H331

Acute toxicity Category 3; H311

Specific target organ toxicity - single

exposure Category 1; H370

>= 0.5 - < 1

Substances with a workplace exposure limit :

2-(2-butoxyethoxy)ethanol

112-34-5

203-961-6

Eye irritation Category 2; H319

>= 0.1 - < 0.25

Diethylene Glycol

111-46-6

203-872-2

01-2119457857-21

Acute toxicity Category 4; H302

Specific target organ toxicity - repeated

exposure Category 2; H372

>= 0.1 - < 0.25

For the full text of the H-Statements mentioned in this Section, see Section 16.

Section: 4. FIRST AID MEASURES

4.1 Description of first aid measures

In case of eye contact

Rinse immediately with plenty of water, also under the eyelids, for

at least 15 minutes. Remove contact lenses, if present and easy

to do. Continue rinsing. Get medical attention immediately.

In case of skin contact

Wash off immediately with plenty of water for at least 15 minutes.

Use a mild soap if available. Wash clothing before reuse.

Thoroughly clean shoes before reuse. Get medical attention.

If swallowed

Rinse mouth. Get medical attention if symptoms occur.

If inhaled

Remove to fresh air. Treat symptomatically. Get medical attention

if symptoms occur.

4.2 Most important symptoms and effects, both acute and delayed

See Section 11 for more detailed information on health effects and symptoms.

4.3 Indication of immediate medical attention and special treatment needed

Treatment

Treat symptomatically.

SAFETY DATA SHEET

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Section: 5. FIREFIGHTING MEASURES

5.1 Extinguishing media

Suitable extinguishing media

Use extinguishing measures that are appropriate to local

circumstances and the surrounding environment.

Unsuitable extinguishing

media

None known.

5.2 Special hazards arising from the substance or mixture

Specific hazards during

firefighting

Not flammable or combustible.

Hazardous combustion

products

Decomposition products may include the following materials:

Carbon oxides

nitrogen oxides (NOx)

Sulphur oxides

Oxides of phosphorus

5.3 Advice for firefighters

Special protective equipment

for firefighters

: Use personal protective equipment.

Further information

: Collect contaminated fire extinguishing water separately. This

must not be discharged into drains. Fire residues and

contaminated fire extinguishing water must be disposed of in

accordance with local regulations. In the event of fire and/or

explosion do not breathe fumes.

Section: 6. ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures

Advice for non-emergency

personnel

Ensure adequate ventilation. Keep people away from and upwind

of spill/leak. Avoid inhalation, ingestion and contact with skin and

eyes. When workers are facing concentrations above the

exposure limit they must use appropriate certified respirators.

Ensure clean-up is conducted by trained personnel only. Refer to

protective measures listed in sections 7 and 8.

Advice for emergency

responders

If specialised clothing is required to deal with the spillage, take

note of any information in Section 8 on suitable and unsuitable

materials.

6.2 Environmental precautions

Environmental precautions

Do not allow contact with soil, surface or ground water.

6.3 Methods and materials for containment and cleaning up

Methods for cleaning up

Stop leak if safe to do so. Contain spillage, and then collect with

non-combustible absorbent material, (e.g. sand, earth,

diatomaceous earth, vermiculite) and place in container for

disposal according to local / national regulations (see section 13).

For large spills, dike spilled material or otherwise contain material

SAFETY DATA SHEET

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to ensure runoff does not reach a waterway.

6.4 Reference to other sections

See Section 1 for emergency contact information.

For personal protection see section 8.

See Section 13 for additional waste treatment information.

Section: 7. HANDLING AND STORAGE

7.1 Precautions for safe handling

Advice on safe handling

Do not ingest. Avoid contact with skin and eyes. Do not get in

eyes, on skin, or on clothing. Do not breathe

dust/fume/gas/mist/vapours/spray. Use only with adequate

ventilation. Wash hands thoroughly after handling.

Hygiene measures

Handle in accordance with good industrial hygiene and safety

practice. Remove and wash contaminated clothing before re-use.

Wash face, hands and any exposed skin thoroughly after

handling. Provide suitable facilities for quick drenching or flushing

of the eyes and body in case of contact or splash hazard.

7.2 Conditions for safe storage, including any incompatibilities

Requirements for storage

areas and containers

Keep out of reach of children. Keep container tightly closed. Store

in suitable labeled containers.

Storage temperature

5 °C to 40 °C

7.3 Specific end uses

Specific use(s)

Laundry aid (non-gasing). Automatic process

Section: 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 Control parameters

Occupational Exposure Limits

Components

CAS-No.

Value type (Form

of exposure)

Control parameters

Basis

propan-2-ol

67-63-0

OELV - 8 hrs

(TWA)

200 ppm

IR_OEL

Further information

Substances which have the capacity to penetrate intact skin when they come

in contact with it, and be absorbed into the body

OELV - 15 min

(STEL)

400 ppm

IR_OEL

Further information

Substances which have the capacity to penetrate intact skin when they come

in contact with it, and be absorbed into the body

methanol

67-56-1

OELV - 8 hrs

(TWA)

200 ppm

260 mg/m3

IR_OEL

Further information

Substances which have the capacity to penetrate intact skin when they come

in contact with it, and be absorbed into the body

Where no specific short-term exposure limit is listed, a figure three times the

long-term exposure limit value should be used

IOEL

Indicative Occupational Exposure Limit Value

2-(2-

butoxyethoxy)ethanol

112-34-5

OELV - 8 hrs

(TWA)

10 ppm

67.5 mg/m3

IR_OEL

SAFETY DATA SHEET

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Further information

IOEL

Indicative Occupational Exposure Limit Value

OELV - 15 min

(STEL)

15 ppm

101.2 mg/m3

IR_OEL

Further information

IOEL

Indicative Occupational Exposure Limit Value

Diethylene Glycol

111-46-6

OELV - 8 hrs

(TWA)

23 ppm

100 mg/m3

IR_OEL

Further information

Where no specific short-term exposure limit is listed, a figure three times the

long-term exposure limit value should be used

DNEL

propan-2-ol

End Use: Workers

Exposure routes: Dermal

Potential health effects: Long-term systemic effects

Value: 888 mg/cm2

End Use: Workers

Exposure routes: Inhalation

Potential health effects: Long-term systemic effects

Value: 500 mg/m3

End Use: Consumers

Exposure routes: Dermal

Potential health effects: Long-term systemic effects

Value: 319 mg/cm2

End Use: Consumers

Exposure routes: Inhalation

Potential health effects: Long-term systemic effects

Value: 89 mg/m3

End Use: Consumers

Exposure routes: Ingestion

Potential health effects: Long-term systemic effects

Value: 26 ppm

methanol

End Use: Workers

Exposure routes: Dermal

Potential health effects: Acute systemic effects

Value: 40 mg/cm2

End Use: Workers

Exposure routes: Inhalation

Potential health effects: Acute systemic effects

Value: 260 mg/m3

End Use: Workers

Exposure routes: Inhalation

Potential health effects: Acute local effects

Value: 260 mg/m3

End Use: Workers

Exposure routes: Dermal

Potential health effects: Long-term systemic effects

Value: 40 mg/cm2

End Use: Workers

Exposure routes: Inhalation

Potential health effects: Long-term systemic effects

SAFETY DATA SHEET

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Value: 260 mg/m3

End Use: Workers

Exposure routes: Inhalation

Potential health effects: Long-term local effects

Value: 260 mg/m3

End Use: Consumers

Exposure routes: Dermal

Potential health effects: Acute systemic effects

Value: 8 mg/cm2

End Use: Consumers

Exposure routes: Inhalation

Potential health effects: Acute systemic effects

Value: 50 mg/m3

End Use: Consumers

Exposure routes: Ingestion

Potential health effects: Acute systemic effects

Value: 8 ppm

End Use: Consumers

Exposure routes: Inhalation

Potential health effects: Acute local effects

Value: 50 mg/m3

End Use: Consumers

Exposure routes: Dermal

Potential health effects: Long-term systemic effects

Value: 8 mg/cm2

End Use: Consumers

Exposure routes: Inhalation

Potential health effects: Long-term systemic effects

Value: 50 mg/m3

End Use: Consumers

Exposure routes: Ingestion

Potential health effects: Long-term systemic effects

Value: 8 ppm

End Use: Consumers

Exposure routes: Inhalation

Potential health effects: Long-term local effects

Value: 50 mg/m3

2-(2-butoxyethoxy)ethanol

End Use: Workers

Exposure routes: Inhalation

Potential health effects: Short-term - local

Value: 101.2 mg/m3

End Use: Workers

Exposure routes: Dermal

Potential health effects: Long-term systemic effects

Value: 20 mg/kg

End Use: Workers

Exposure routes: Inhalation

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

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Potential health effects: Long-term systemic effects

Value: 67.5 mg/m3

End Use: Workers

Exposure routes: Inhalation

Potential health effects: Short-term - local

Value: 67.5 mg/m3

PNEC

propan-2-ol

Fresh water

Value: 140.9 mg/l

Marine water

Value: 140.9 mg/l

Intermittent use/release

Value: 140.9 mg/l

Fresh water

Value: 552 mg/kg

Marine sediment

Value: 552 mg/kg

Soil

Value: 28 mg/kg

Sewage treatment plant

Value: 2251 mg/l

Oral

Value: 160 mg/kg

methanol

Fresh water

Value: 154 mg/l

Marine water

Value: 15.4 mg/l

Intermittent use/release

Value: 1540 mg/l

Sediment

Value: 570.4 mg/kg

Soil

Value: 23.5 mg/kg

Sewage treatment plant

Value: 100 mg/l

2-(2-butoxyethoxy)ethanol

Fresh water

Value: 1 mg/l

Marine water

Value: 0.1 mg/l

Intermittent use/release

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

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Value: 3.9 mg/l

Sewage treatment plant

Value: 200 mg/l

Sediment

Value: 4 mg/kg

Soil

Value: 0.4 mg/kg

Oral

Value: 56 mg/kg

8.2 Exposure controls

Appropriate engineering controls

Engineering measures

Effective exhaust ventilation system. Maintain air concentrations

below occupational exposure standards.

Individual protection measures

Hygiene measures

Handle in accordance with good industrial hygiene and safety

practice. Remove and wash contaminated clothing before re-use.

Wash face, hands and any exposed skin thoroughly after

handling. Provide suitable facilities for quick drenching or flushing

of the eyes and body in case of contact or splash hazard.

Eye/face protection (EN 166)

Safety goggles

Face-shield

Hand protection (EN 374)

Recommended preventive skin protection

Gloves

Nitrile rubber

butyl-rubber

Breakthrough time: 1 – 4 hours

Minimum thickness for butyl-rubber 0.7 mm for nitrile rubber 0.4

mm or equivalent (please refer to the gloves

manufacturer/distributor for advise).

Gloves should be discarded and replaced if there is any indication

of degradation or chemical breakthrough.

Skin and body protection

(EN 14605)

No special protective equipment required.

Respiratory protection (EN

143, 14387)

None required if airborne concentrations are maintained below the

exposure limit listed in Exposure Limit Information. Use certified

respiratory protection equipment meeting EU

requirements(89/656/EEC, 89/686/EEC ), or equivalent, when

respiratory risks cannot be avoided or sufficiently limited by

technical means of collective protection or by measures, methods

or procedures of work organization.

Environmental exposure controls

General advice

: Consider the provision of containment around storage vessels.

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

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Section: 9. PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on basic physical and chemical properties

Appearance

: liquid

Colour

: light yellow

Odour

: Perfumes, fragrances

9.3 - 9.7, 100 %

Flash point

Not applicable.

Odour Threshold

Not applicable and/or not determined for the mixture

Melting point/freezing point

Not applicable and/or not determined for the mixture

Initial boiling point and

boiling range

Not applicable and/or not determined for the mixture

Evaporation rate

Not applicable and/or not determined for the mixture

Flammability (solid, gas)

Not applicable and/or not determined for the mixture

Upper explosion limit

Not applicable and/or not determined for the mixture

Lower explosion limit

Not applicable and/or not determined for the mixture

Vapour pressure

Not applicable and/or not determined for the mixture

Relative vapour density

Not applicable and/or not determined for the mixture

Relative density

0.97 - 0.99

Water solubility

Not applicable and/or not determined for the mixture

Solubility in other solvents

Not applicable and/or not determined for the mixture

Partition coefficient: n-

octanol/water

Not applicable and/or not determined for the mixture

Auto-ignition temperature

Not applicable and/or not determined for the mixture

Thermal decomposition

Not applicable and/or not determined for the mixture

Viscosity, kinematic

Not applicable and/or not determined for the mixture

Explosive properties

Not applicable and/or not determined for the mixture

Oxidizing properties

The substance or mixture is not classified as oxidizing.

9.2 Other information

Not applicable and/or not determined for the mixture

Section: 10. STABILITY AND REACTIVITY

10.1 Reactivity

No dangerous reaction known under conditions of normal use.

10.2 Chemical stability

Stable under normal conditions.

10.3 Possibility of hazardous reactions

SAFETY DATA SHEET

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No dangerous reaction known under conditions of normal use.

10.4 Conditions to avoid

None known.

10.5 Incompatible materials

Acids

10.6 Hazardous decomposition products

Decomposition products may include the following materials:

Carbon oxides

nitrogen oxides (NOx)

Sulphur oxides

Oxides of phosphorus

Section: 11. TOXICOLOGICAL INFORMATION

11.1 Information on toxicological effects

Information on likely routes of

exposure

Inhalation, Eye contact, Skin contact

Product

Acute oral toxicity

: Acute toxicity estimate : 1,504 mg/kg

Acute inhalation toxicity

: 4 h Acute toxicity estimate : > 20 mg/l

Acute dermal toxicity

: Acute toxicity estimate : > 2,000 mg/kg

Skin corrosion/irritation

: There is no data available for this product.

Serious eye damage/eye

irritation

: There is no data available for this product.

Respiratory or skin

sensitization

: There is no data available for this product.

Carcinogenicity

: There is no data available for this product.

Reproductive effects

: There is no data available for this product.

Germ cell mutagenicity

: There is no data available for this product.

Teratogenicity

: There is no data available for this product.

STOT - single exposure

: There is no data available for this product.

STOT - repeated exposure

: There is no data available for this product.

Aspiration toxicity

: There is no data available for this product.

Components

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

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Acute oral toxicity

: Alcohols, C13-15, branched and linear, ethoxylated

LD50 rat: 1,250 mg/kg

alcohols, c10-16, ethoxylated

LD50 rat: 1,000 mg/kg

propan-2-ol

LD50 rat: 5,840 mg/kg

d-Limonene

LD50 rat: 4,400 mg/kg

2-(2-butoxyethoxy)ethanol

LD50 rat: 3,306 mg/kg

Diethylene Glycol

LD50 Humans: 1,120 mg/kg

Components

Acute inhalation toxicity

: alcohols, c10-16, ethoxylated

4 h LC50 rat: 50 mg/l

propan-2-ol

4 h LC50 rat: 30 mg/l

Components

Acute dermal toxicity

: Alcohols, C13-15, branched and linear, ethoxylated

LD50 rat: > 2,000 mg/kg

propan-2-ol

LD50 rabbit: 12,870 mg/kg

d-Limonene

LD50 rabbit: > 5,000 mg/kg

2-(2-butoxyethoxy)ethanol

LD50 rabbit: 2,764 mg/kg

Diethylene Glycol

LD50 rabbit: 13,300 mg/kg

Potential Health Effects

Eyes

Causes serious eye damage.

Skin

Causes skin irritation. May cause allergic skin reaction.

Ingestion

Harmful if swallowed.

Inhalation

Health injuries are not known or expected under normal use.

Chronic Exposure

Health injuries are not known or expected under normal use.

Experience with human exposure

Eye contact

Redness, Pain, Corrosion

Skin contact

Redness, Irritation, Allergic reactions

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

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Ingestion

No information available.

Inhalation

No symptoms known or expected.

Section: 12. ECOLOGICAL INFORMATION

12.1 Ecotoxicity

Environmental Effects

Very toxic to aquatic life. Toxic to aquatic life with long lasting

effects.

Product

Toxicity to fish

: no data available

Toxicity to daphnia and other

aquatic invertebrates

: no data available

Toxicity to algae

: no data available

Components

Toxicity to fish

: propan-2-ol

96 h LC50 Pimephales promelas (fathead minnow): 9,640 mg/l

methanol

96 h LC50: 15,400 mg/l

2-(2-butoxyethoxy)ethanol

96 h LC50 Fish: 1,300 mg/l

Diethylene Glycol

96 h LC50 Pimephales promelas (fathead minnow): 75,200 mg/l

Components

Toxicity to daphnia and other

aquatic invertebrates

: Alcohols, C13-15, branched and linear, ethoxylated

48 h EC50 Daphnia magna (Water flea): 0.317 mg/l

alcohols, c10-16, ethoxylated

48 h EC50: > 0.1 mg/l

Amphoteric surfactants

48 h EC50 Daphnia: > 100 mg/l

propan-2-ol

LC50 Daphnia magna (Water flea): > 10,000 mg/l

methanol

48 h EC50: > 10,000 mg/l

Diethylene Glycol

24 h EC50 Daphnia magna (Water flea): > 10,000 mg/l

Components

Toxicity to algae

: methanol

72 h EC50: 22,000 mg/l

Diethylene Glycol

96 h EC50: 9,362 mg/l

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

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12.2 Persistence and degradability

Product

Biodegradability

: The surfactants contained in the product are biodegradable

according to the requirements of the detergent regulation

648/2004/EC

Components

Biodegradability

Alcohols, C13-15, branched and linear, ethoxylated

Result: Readily biodegradable.

alcohols, c10-16, ethoxylated

Result: Readily biodegradable.

2-[2-(2-butoxyethoxy)ethoxy]ethanol

Result: Readily biodegradable.

Amphoteric surfactants

Result: Readily biodegradable.

propan-2-ol

Result: Readily biodegradable.

d-Limonene

Result: Readily biodegradable.

methanol

Result: Readily biodegradable.

2-(2-butoxyethoxy)ethanol

Result: Readily biodegradable.

Diethylene Glycol

Result: Readily biodegradable.

12.3 Bioaccumulative potential

no data available

12.4 Mobility in soil

no data available

12.5 Results of PBT and vPvB assessment

Product

Assessment

This substance/mixture contains no components considered to be

either persistent, bioaccumulative and toxic (PBT), or very

persistent and very bioaccumulative (vPvB) at levels of 0.1% or

higher.

12.6 Other adverse effects

no data available

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

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Section: 13. DISPOSAL CONSIDERATIONS

Dispose of in accordance with the European Directives on waste and hazardous waste.Waste

codes should be assigned by the user, preferably in discussion with the waste disposal authorities.

13.1 Waste treatment methods

Product

: The product should not be allowed to enter drains, water courses

or the soil. Where possible recycling is preferred to disposal or

incineration. If recycling is not practicable, dispose of in

compliance with local regulations. Dispose of wastes in an

approved waste disposal facility.

Contaminated packaging

: Dispose of as unused product. Empty containers should be taken

to an approved waste handling site for recycling or disposal. Do

not re-use empty containers. Dispose of in accordance with local,

state, and federal regulations.

Guidance for Waste Code

selection

: Organic wastes containing dangerous substances. If this product

is used in any further processes, the final user must redefine and

assign the most appropriate European Waste Catalogue Code. It

is the responsibility of the waste generator to determine the

toxicity and physical properties of the material generated to

determine the proper waste identification and disposal methods in

compliance with applicable European (EU Directive 2008/98/EC)

and local regulations.

Section: 14. TRANSPORT INFORMATION

The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are

in compliance with the selected mode of transport.

Land transport (ADR/ADN/RID)

14.1 UN number

3082

14.2 UN proper shipping

name

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,

N.O.S.

(Alcohol ethoxylate)

14.3 Transport hazard

class(es)

14.4 Packing group

14.5 Environmental hazards

14.6 Special precautions for

user

None

Air transport (IATA)

14.1 UN number

3082

14.2 UN proper shipping

name

Environmentally hazardous substance, liquid, n.o.s.

(Alcohol ethoxylate)

14.3 Transport hazard

class(es)

14.4 Packing group

14.5 Environmental hazards

14.6 Special precautions for

user

None

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

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Sea transport (IMDG/IMO)

14.1 UN number

3082

14.2 UN proper shipping

name

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,

N.O.S.

(Alcohol ethoxylate)

14.3 Transport hazard

class(es)

14.4 Packing group

14.5 Environmental hazards

14.6 Special precautions for

user

None

14.7 Transport in bulk

according to Annex II of

MARPOL 73/78 and the IBC

Code

Not applicable.

Section: 15. REGULATORY INFORMATION

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

according to Detergents

Regulation EC 648/2004

30 % and more: Non-ionic surfactants

less than 5 %: Amphoteric surfactants

Other constituents: Perfumes

Allergens:

d-Limonene

National Regulations

Take note of Dir 94/33/EC on the protection of young people at work.

Other regulations

Safety, Health and Welfare at Work Act, 2005

European Communities (Classification, Packaging, Labelling and

Notification of Dangerous Preparations) Regulations 1995. (S.I.

272 of 1995) as amended

15.2 Chemical Safety Assessment

This product contains substances for which Chemical Safety Assessments are still required.

Section: 16. OTHER INFORMATION

Procedure used to derive the classification according to REGULATION (EC) No 1272/2008

Classification

Justification

Acute toxicity 4, H302

Calculation method

Skin irritation 2, H315

Calculation method

Serious eye damage 1, H318

Calculation method

Skin sensitization 1, H317

Calculation method

Acute aquatic toxicity 1, H400

Calculation method

Chronic aquatic toxicity 2, H411

Calculation method

Full text of H-Statements

H225

Highly flammable liquid and vapour.

H226

Flammable liquid and vapour.

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H301

Toxic if swallowed.

H302

Harmful if swallowed.

H311

Toxic in contact with skin.

H315

Causes skin irritation.

H317

May cause an allergic skin reaction.

H318

Causes serious eye damage.

H319

Causes serious eye irritation.

H331

Toxic if inhaled.

H336

May cause drowsiness or dizziness.

H370

Causes damage to organs.

H372

Causes damage to organs through prolonged or repeated exposure if

swallowed.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Full text of other abbreviations

ADN – European Agreement concerning the International Carriage of Dangerous Goods by

Inland Waterways; ADR – European Agreement concerning the International Carriage of

Dangerous Goods by Road; AICS – Australian Inventory of Chemical Substances; ASTM –

American Society for the Testing of Materials; bw – Body weight; CLP – Classification Labelling

Packaging Regulation; Regulation (EC) No 1272/2008; CMR – Carcinogen, Mutagen or

Reproductive Toxicant; DIN – Standard of the German Institute for Standardisation; DSL –

Domestic Substances List (Canada); ECHA – European Chemicals Agency; EC-Number –

European Community number; ECx – Concentration associated with x% response; ELx – Loading

rate associated with x% response; EmS – Emergency Schedule; ENCS – Existing and New

Chemical Substances (Japan); ErCx – Concentration associated with x% growth rate response;

GHS – Globally Harmonized System; GLP – Good Laboratory Practice; IARC – International

Agency for Research on Cancer; IATA – International Air Transport Association; IBC –

International Code for the Construction and Equipment of Ships carrying Dangerous Chemicals in

Bulk; IC50 – Half maximal inhibitory concentration; ICAO – International Civil Aviation

Organization; IECSC – Inventory of Existing Chemical Substances in China; IMDG – International

Maritime Dangerous Goods; IMO – International Maritime Organization; ISHL – Industrial Safety

and Health Law (Japan); ISO – International Organisation for Standardization; KECI – Korea

Existing Chemicals Inventory; LC50 – Lethal Concentration to 50 % of a test population; LD50 –

Lethal Dose to 50% of a test population (Median Lethal Dose); MARPOL – International

Convention for the Prevention of Pollution from Ships; n.o.s. – Not Otherwise Specified; NO(A)EC

– No Observed (Adverse) Effect Concentration; NO(A)EL – No Observed (Adverse) Effect Level;

NOELR – No Observable Effect Loading Rate; NZIoC – New Zealand Inventory of Chemicals;

OECD – Organization for Economic Co-operation and Development; OPPTS – Office of Chemical

Safety and Pollution Prevention; PBT – Persistent, Bioaccumulative and Toxic substance; PICCS

– Philippines Inventory of Chemicals and Chemical Substances; (Q)SAR – (Quantitative)

Structure Activity Relationship; REACH – Regulation (EC) No 1907/2006 of the European

Parliament and of the Council concerning the Registration, Evaluation, Authorisation and

Restriction of Chemicals; RID – Regulations concerning the International Carriage of Dangerous

Goods by Rail; SADT – Self-Accelerating Decomposition Temperature; SDS – Safety Data Sheet;

TCSI – Taiwan Chemical Substance Inventory; TRGS – Technical Rule for Hazardous

Substances; TSCA – Toxic Substances Control Act (United States); UN – United Nations; vPvB –

Very Persistent and Very Bioaccumulative

Prepared by

Regulatory Affairs

Numbers quoted in the MSDS are given in the format: 1,000,000 = 1 million and 1,000 = 1

thousand. 0.1 = 1 tenth and 0.001 = 1 thousandth

REVISED INFORMATION: Significant changes to regulatory or health information for this revision

is indicated by a bar in the left-hand margin of the SDS.

SAFETY DATA SHEET

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The information provided in this Safety Data Sheet is correct to the best of our knowledge,

information and belief at the date of its publication. The information given is designed only as a

guidance for safe handling, use, processing, storage, transportation, disposal and release and is

not to be considered a warranty or quality specification. The information relates only to the specific

material designated and may not be valid for such material used in combination with any other

materials or in any process, unless specified in the text.

ANNEX: EXPOSURE SCENARIOS

DPD+ Substances:

The following substances are the lead substances that contribute to the mixture Exposure

Scenario according to the DPD+ Rule:

Route

Substance

CAS-No.

EINECS-No.

Ingestion

Alcohols, C13-15, branched and linear,

ethoxylated

157627-86-6

Inhalation

methanol

67-56-1

200-659-6

Dermal

Alcohols, C13-15, branched and linear,

ethoxylated

157627-86-6

Eyes

Alcohols, C13-15, branched and linear,

ethoxylated

157627-86-6

aquatic environment

Alcohols, C13-15, branched and linear,

ethoxylated

157627-86-6

Physical properties DPD+ Substances:

Substance

Vapour pressure

Water solubility

Pow

Molar Mass

methanol

16,927 Pa

32.05 g/mol

To calculate if your downstream Operating Conditions and Risk management Measures are

safe, please calculate your risk factor at the website below:

www.ecetoc.org/tra

Short title of Exposure

Scenario

Laundry aid (non-gasing). Automatic process

Use descriptors

Main User Groups

Industrial uses: Uses of substances as such or in preparations at

industrial sites

Sectors of end-use

SU3: Industrial uses: Uses of substances as such or in

preparations at industrial sites

Process categories

PROC2: Use in closed, continuous process with occasional

controlled exposure

PROC8b: Transfer of substance or preparation (charging/

SAFETY DATA SHEET

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discharging) from/ to vessels/ large containers at dedicated

facilities

Product categories

PC35: Washing and cleaning products (including solvent based

products)

Environmental Release

Categories

ERC4: Industrial use of processing aids in processes and

products, not becoming part of articles