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INTEROX ® AG-DUAL 35 - SAFETY DATA SHEET - according to Regulation (EC) No. 1907/2006

1/10

United Kingdom - Version 1.0 - P 16448

Revision Date 10.12.2010

INTEROX ® AG-DUAL 35

1. PRODUCT AND COMPANY IDENTIFICATION

1.1. Product identifiers

- Product name

INTEROX ® AG-DUAL 35

- Chemical Name

Hydrogen peroxide

- Synonyms

Hydroperoxide, Hydrogen dioxide

- Molecular formula

H2O2

- Type of product

Mixture

1.2. Identified uses / Uses advised against

- Identified uses

Disinfectant

1.3. Manufacturer or supplier's details

- Company

SOLVAY CHEMICALS INTERNATIONAL SA

- Address

RUE DU PRINCE ALBERT, 44

B- 1050 BRUXELLES

- Telephone

+3225096111

- Fax

+3225096624

- E-mail address

sdstracking@solvay.com

1.4. Emergency telephone number

- Emergency telephone number

+44(0)1235 239 670 [CareChem 24] (Europe)

2. HAZARDS IDENTIFICATION

2.1. Classification

Hazard class / Hazard category

R-phrase(s)

R37/38

2.2. Label

2.2.1. Name(s) on label

Hazardous components

Hydrogen peroxide (35 %)

2.2.2. Hazard symbols

Harmful

2.2.3. R-phrase(s)

Harmful if swallowed.

Risk of serious damage to eyes.

R37/38

Irritating to respiratory system and skin.

2.2.4. S-phrase(s)

S 1/2

Keep locked up and out of the reach of children.

In case of contact with eyes, rinse immediately with plenty of water and seek

medical advice.

After contact with skin, wash immediately with plenty of water.

S36/37/39

Wear suitable protective clothing, gloves and eye/face protection.

In case of accident or if you feel unwell, seek medical advice immediately (show

the label where possible).

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3. COMPOSITION/INFORMATION ON INGREDIENTS

3.1. Concentration

Substance name:

Concentration

Hydrogen peroxide

ca. 35 %

CAS-No.: 7722-84-1 / EC-No.: 231-765-0 / Index-No.: 008-003-00-9

REACH Registration Number: 01-2119485845-22

3.2. Hazardous components - According to Regulation (EC) 1272/2008, as amended

Substance name

Hazard class

Hazard category

Route of exposure

H Phrases

Hydrogen peroxide

Oxidizing liquids

Category 1

H271

Acute toxicity

Category 4

Inhalation

H332

Acute toxicity

Category 4

Oral

H302

Skin corrosion

Category 1A

H314

Serious eye damage

Category 1

H318

Target Organ

Systemic Toxicant -

Single exposure

Category 3

Inhalation

H335

3.3. Hazardous components - European Directive 67/548/EEC or 1999/45/EC, as amended

Substance name

Classification

Hazard category

R-phrase(s)

Hydrogen peroxide

O

Oxidising

R 8

C

Corrosive

R35

Xn

Harmful

R20/22

4. FIRST AID MEASURES

4.1. Description of necessary first-aid measures

4.1.1. If inhaled

Move to fresh air.

If symptoms persist, call a physician.

4.1.2. In case of eye contact

Call a physician or poison control centre immediately.

In case of eye contact, remove contact lens and rinse immediately with plenty of water, also under the eyelids, for

at least 15 minutes.

In the case of difficulty of opening the lids, administer an analgesic eye wash (oxybuprocaine).

4.1.3. In case of skin contact

Remove and wash contaminated clothing before re-use.

Wash off with soap and water.

If symptoms persist, call a physician.

4.1.4. If swallowed

Rinse mouth with water.

Do NOT induce vomiting.

Oxygen or artificial respiration if needed.

If symptoms persist, call a physician or Poison Control Centre immediately.

4.2. Most important symptoms/effects, acute and delayed

4.2.1. Inhalation

Inhalation of vapours is irritating to the respiratory system, may cause throat pain and cough.

Risk of: Nose bleeding, chronic bronchitis

4.2.2. Skin contact

Irritation

Risk of: Burn

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4.2.3. Eye contact

Severe eye irritation

Risk of serious damage to eyes.

Symptoms: Redness, Lachrymation, Swelling of tissue

4.2.4. Ingestion

Severe irritation

Symptoms: Nausea, Abdominal pain, Vomiting, Diarrhoea, Risk of chemical pneumonitis from product inhalation.

5. FIRE-FIGHTING MEASURES

5.1. Extinguishing media

5.1.1. Suitable extinguishing media

Water

Water spray

5.1.2. Unsuitable extinguishing media

None.

5.2. Specific hazards arising from the chemical

Oxygen released in thermal decomposition may support combustion

Contact with combustible material may cause fire.

Contact with flammables may cause fire or explosions.

Risk of explosion if heated under confinement.

5.3. Special protective actions for fire-fighters

In the event of fire, wear self-contained breathing apparatus.

Use personal protective equipment.

Wear chemical resistant oversuit

Cool containers / tanks with water spray.

6. ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protective equipment and emergency procedures

6.1.1. Advice for non-emergency personnel

Prevent further leakage or spillage if safe to do so.

Keep away from Incompatible products.

6.1.2. Advice for emergency responders

Evacuate personnel to safe areas.

Keep people away from and upwind of spill/leak.

Use personal protective equipment.

6.2. Environmental precautions

Should not be released into the environment.

If the product contaminates rivers and lakes or drains inform respective authorities.

6.3. Methods and materials for containment and cleaning up

Dam up.

Do not mix waste streams during collection.

Soak up with inert absorbent material.

Keep in properly labelled containers.

Keep in suitable, closed containers for disposal.

Treat recovered material as described in the section "Disposal considerations".

Never return spills in original containers for re-use.

6.4. Reference to other sections

Refer to protective measures listed in sections 7 and 8.

7. HANDLING AND STORAGE

7.1. Precautions for safe handling

Use only in well-ventilated areas.

Use only clean and dry utensils.

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Never return unused material to storage receptacle.

Keep away from Incompatible products.

Keep away from heat.

7.2. Conditions for storage, including incompatibilities

7.2.1. Storage

Keep only in the original container.

Store in a receptacle equipped with a vent.

Store in a well-ventilated place. Keep cool.

Keep container closed.

Keep in a bunded area.

Keep away from Incompatible products.

Keep away from heat/sparks/open flames/hot surfaces. - No smoking.

Regularly check the condition and temperature of the containers.

Electrical equipment should be protected to the appropriate standard.

7.2.2. Packaging material

7.2.2.1. Suitable material

aluminium 99,5 %

stainless steel 304L / 316L

Approved grades of HDPE.

7.3. Specific use(s)

For further information, please contact: Supplier

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1. Control parameters

8.1.1. Exposure Limit Values

Hydrogen peroxide

UK. EH40 Workplace Exposure Limits (WELs) 2007

time weighted average = 1 ppm

time weighted average = 1.4 mg/m3

UK. EH40 Workplace Exposure Limits (WELs) 2007

Short term exposure limit = 2 ppm

Short term exposure limit = 2.8 mg/m3

US. ACGIH Threshold Limit Values 2009

time weighted average = 1 ppm

8.1.2. Other information on limit values

8.1.2.1. Predicted No Effect Concentration

Marine water, 0.0126 mg/l

Fresh water, 0.0126 mg/l

Fresh water sediment, 0.0103 mg/kg

Soil, 0.0023 mg/kg

8.1.2.2. Derived No Effect Level / Derived minimal effect level

Workers, Inhalation, Acute effects, 3 mg/m3

Workers, Inhalation, Prolonged exposure, Local effects, 1.4 mg/m3

8.2. Exposure controls

8.2.1. Appropriate engineering controls

Ensure adequate ventilation.

Apply technical measures to comply with the occupational exposure limits.

8.2.2. Individual protection measures

8.2.2.1. Respiratory protection

In case of insufficient ventilation, wear suitable respiratory equipment.

When workers are facing concentrations above the exposure limit they must use appropriate certified respirators.

Recommended Filter type: NO, P3

8.2.2.2. Hand protection

Impervious gloves

Suitable material: PVC, Natural Rubber, butyl-rubber, Nitrile rubber

Take note of the information given by the producer concerning permeability and break through times, and of

special workplace conditions (mechanical strain, duration of contact).

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8.2.2.3. Eye protection

Chemical resistant goggles must be worn.

If splashes are likely to occur, wear: Tightly fitting safety goggles, Face-shield

8.2.2.4. Skin and body protection

Chemical resistant apron

Suitable material

Natural Rubber

If splashes are likely to occur, wear: Apron, Boots

8.2.2.5. Hygiene measures

Eye wash bottles or eye wash stations in compliance with applicable standards.

Take off contaminated clothing and shoes immediately.

Wash contaminated clothing before re-use.

When using do not eat, drink or smoke.

Wash hands before breaks and at the end of workday.

Handle in accordance with good industrial hygiene and safety practice.

8.2.3. Environmental exposure controls

Dispose of rinse water in accordance with local and national regulations.

9. PHYSICAL AND CHEMICAL PROPERTIES

9.1. Physical and chemical properties

9.1.1. General Information

Appearance

liquid

Colour

colourless

Odour

pungent

Molecular Weight

34 g/mol

9.1.2. Important health safety and environmental information

pH

2.02 (H2O2 50 %)

pKa

pKa1= 11.62 25 °C

Melting point/freezing point

-33 °C (H2O2 35 % )

Boiling point/boiling range

108 °C (H2O2 35 %)

Flash point

not applicable

Evaporation rate

No data

Flammability (solid, gas)

not applicable

Flammability

The product is not flammable.

Explosive properties

Not explosive

Vapour pressure

1 mbar (H2O2 50 %), at 30 °C

Vapour density

1(H2O2 50 %)

Relative density

Bulk density

not applicable

Solubility(ies)

No data

Solubility/qualitative

completely miscible, in all proportions (Water)

Partition coefficient: n-

octanol/water

log Pow: -1.57, Method: calculated value

Autoignition temperature

The product is not flammable.

Decomposition temperature

>= 60 °C, Self-Accelerating decomposition temperature (SADT)

< 60 °C, Slow decomposition

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Viscosity

1.07 mPa.s (H2O2 50 %), at 20 °C

Oxidizing properties

Non oxidizer

9.2. Other information

Surface tension

74 mN/m (H2O2 50 %) 20 °C

10. STABILITY AND REACTIVITY

10.1. Reactivity

Decomposes on heating.

Potential for exothermic hazard

10.2. Chemical stability

Stable under recommended storage conditions.

10.3. Possibility of hazardous reactions

Contact with combustible material may cause fire.

Contact with flammables may cause fire or explosions.

Risk of explosion if heated under confinement.

Fire or intense heat may cause violent rupture of packages.

10.4. Conditions to avoid

Contamination

To avoid thermal decomposition, do not overheat.

10.5. Materials to avoid

Acids, Bases, Metals, Heavy metal salts, Powdered metal salts, Reducing agents, Organic materials, Flammable

materials

10.6. Hazardous decomposition products

Oxygen

11. TOXICOLOGICAL INFORMATION

11.1. Acute toxicity

11.1.1. Acute oral toxicity

LD50, rat, 1,193 - 1,270 mg/kg (H2O2 35 %)

11.1.2. Acute inhalation toxicity

LC50, 1 h, rat , > 0.17 mg/l (H2O2 35 %)

11.1.3. Acute dermal toxicity

LD50, rabbit, > 2,000 mg/kg

11.1.4. Irritation (other route)

Inhalation, Human experience, Irritating to respiratory system.(H2O2 50 %)

11.2. Skin corrosion/irritation

rabbit, Skin irritation

11.3. Serious eye damage/eye irritation

Risk of serious damage to eyes. (H2O2 10 %)

11.4. Respiratory or skin sensitization

guinea pig, Did not cause sensitization on laboratory animals.

11.5. Mutagenicity

In vitro tests have shown mutagenic effects.

Animal testing did not show any mutagenic effects.

Not classified due to inconclusive data.

11.6. Carcinogenicity

Oral, Prolonged exposure, mouse, Target Organs: duodenum, carcinogenic effects

Dermal, Prolonged exposure, mouse, Animal testing did not show any carcinogenic effects.

Inhalation, Prolonged exposure, mouse, Animal testing did not show any carcinogenic effects.

Not classified due to inconclusive data.

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11.7. Toxicity for reproduction

Substance is totally biotransformed (metabolised).

study scientifically unjustified

11.8. Repeated dose toxicity

Oral, Prolonged exposure , mouse, Gastrointestinal tract 300 ppm(m), LOAEL

Oral, Prolonged exposure , mouse, 100 ppm , NOAEL

Inhalation, Repeated exposure , rat, Respiratory system >= 10 ppm(m), LOAEL

Inhalation, Prolonged exposure , rat, 2 ppm , NOAEL

12. ECOLOGICAL INFORMATION

12.1. Toxicity

Fishes, Pimephales promelas, LC50, 96 h, 16.4 mg/l

Fishes, Pimephales promelas, NOEC, 96 h, 4.3 mg/l

Crustaceans, Daphnia magna, EC50, 48 h, 2.4 mg/l, fresh water, semi-static test

Crustaceans, Daphnia magna, NOEC, 48 h, 1 mg/l, fresh water, semi-static test

Algae, Skeletonema costatum, EC50, growth rate, 72 h, 1.38 mg/l

Algae, Skeletonema costatum, NOEC, 72 h, 0.63 mg/l

Algae, Chlorella vulgaris, EC50, Growth rate, 72 h, 4.3 mg/l

Algae, Chlorella vulgaris, NOEC, 72 h, 0.1 mg/l

12.2. Persistence and degradability

12.2.1. Abiotic degradation

Air, indirect photo-oxidation, t 1/2 24 h

Conditions: sensitizer: OH radicals

Water, redox reaction, t 1/2 120 h

Conditions: mineral and enzymatic catalysis, fresh water, salt water

Soil, redox reaction, t 1/2 12 h

Conditions: mineral and enzymatic catalysis

12.2.2. Biodegradation

aerobic, t 1/2, < 2 min

Conditions: biological treatment sludge

Readily biodegradable.

aerobic, t 1/2, from 0.3 - 5 d

Conditions: fresh water

Readily biodegradable.

anaerobic

Conditions: Soil/sediments

not applicable

12.3. Bioaccumulative potential

Bioaccumulative potential: log Pow -1.57,

Result: Does not bioaccumulate.

12.4. Mobility

Water

considerable solubility and mobility

Soil/sediments, log KOC:0.2

non-significant evaporation and adsorption

Air, Volatility, Henry's law constant (H), = 0.75 Pa.m³/mol

Conditions: 20 °C

not significant

12.5. PBT and vPvB assessment

This substance is not considered to be persistent, bioaccumulating and toxic (PBT).

12.6. Other adverse effects

no data available

13. DISPOSAL CONSIDERATIONS

13.1. Waste disposal methods

Limited quantity

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Dilute with plenty of water.

Flush into sewer with plenty of water.

Maximum quantity

Contact manufacturer.

Contact waste disposal services.

In accordance with local and national regulations.

13.2. Contaminated packaging

Empty containers.

Clean container with water.

Dispose of rinse water in accordance with local and national regulations.

Where possible recycling is preferred to disposal or incineration.

In accordance with local and national regulations.

14. TRANSPORT INFORMATION

14.1. International transport regulations

- IATA-DGR

UN number

UN 2014

Class

Packing group

ICAO-Labels

5.1 - Oxidizing substances

8 - Corrosive

Proper shipping name

HYDROGEN PEROXIDE, AQUEOUS SOLUTION

- IMDG

UN number

UN 2014

Class

Packing group

IMDG-Labels

5.1 - Oxidizing substances

8 - Corrosive

HI/UN No.

2014

Proper shipping name

HYDROGEN PEROXIDE, AQUEOUS SOLUTION

- ADR

UN number

UN 2014

Class

Packing group

ADR/RID-Labels

5.1 - Oxidizing substances

8 - Corrosive

HI/UN No.

58 / 2014

Proper shipping name

HYDROGEN PEROXIDE, AQUEOUS SOLUTION

- RID

UN number

UN 2014

Class

Packing group

ADR/RID-Labels

5.1 - Oxidizing substances

8 - Corrosive

HI/UN No.

58 / 2014

Proper shipping name

HYDROGEN PEROXIDE, AQUEOUS SOLUTION

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- ADN

UN number

UN 2014

Class

Packing group

ADR/RID-Labels

5.1 - Oxidizing substances

8 - Corrosive

Proper shipping name

HYDROGEN PEROXIDE, AQUEOUS SOLUTION

IATA: forbidden over 40 %

15. REGULATORY INFORMATION

15.1. Applicable Laws or Regulations

Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning

the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), as amended

Directive 1999/45/EC of the European Parliament and of the Council of 31 May 1999 concerning the

approximation of the laws, regulations and administrative provisions of the Member States relating to the

classification, packaging and labelling of dangerous preparations, as amended

Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on

classification, labelling and packaging of substances and mixtures, as amended

Council Directive 98/24/EC of 7 April 1998 on the protection of the health and safety of workers from the risks

related to chemical agents at work, as amended

COUNCIL DIRECTIVE 96/82/EC on the control of major-accident hazards involving dangerous substances as

amended

Directive 2008/98/EC of the European Parliament and of the Council of 19 November 2008 on waste

EH40/2005. Workplace Exposure Limits, as amended through 1,10, 2007 (WELs) Published by the Health and

Safety Executive (HSE). Issued under the Control of Substances Hazardous to Health Regulations - as amended

15.2. Chemical Safety Assessment

A Chemical Safety Assessment has been carried out for this substance.

See Exposure scenario

15.3. Notification status

Inventory Information

Status

Toxic Substance Control Act list (TSCA)

In compliance with inventory

Australian Inventory of Chemical Substances (AICS)

In compliance with inventory

Canadian Domestic Substances List (DSL)

In compliance with inventory

Korean Existing Chemicals List (ECL)

In compliance with inventory

EU list of existing chemical substances (EINECS)

In compliance with inventory

Japanese Existing and New Chemical Substances (MITI List) (ENCS)

In compliance with inventory

Inventory of Existing Chemical Substances (China) (IECS)

In compliance with inventory

Philippine Inventory of Chemicals and Chemical Substances (PICCS)

In compliance with inventory

New Zealand Inventory of Chemicals (NZIOC)

In compliance with inventory

16. OTHER INFORMATION

16.1. Full text of H-Statements referred to under section 3

H271

May cause fire or explosion; strong oxidiser.

H302

Harmful if swallowed.

H314

Causes severe skin burns and eye damage.

H318

Causes serious eye damage.

H332

Harmful if inhaled.

H335

May cause respiratory irritation.

16.2. Full text of R-phrases referred to under sections 2 and 3

16.2.1. Full text of R-phrases referred to under section 2

Harmful if swallowed.

Risk of serious damage to eyes.

R37/38

Irritating to respiratory system and skin.

16.2.2. Full text of R-phrases referred to under section 3

Heating may cause an explosion.

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Contact with combustible material may cause fire.

R20/22

Harmful by inhalation and if swallowed.

Causes severe burns.

16.3. Other information

New (MSDS)

Distribute new edition to clients

This SDS is only intended for the indicated country to which it is applicable. The European SDS format compliant with the

applicable European legislation is not intended for use nor distribution in countries outside the European Union with the

exception of Norway and Switzerland. Safety datasheets applicable in other countries/regions are available upon request.

The information given corresponds to the current state of our knowledge and experience of the product, and is not

exhaustive. This applies to product which conforms to the specification, unless otherwise stated. In this case of

combinations and mixtures one must make sure that no new dangers can arise. In any case, the user is not exempt from

observing all legal, administrative and regulatory procedures relating to the product, personal hygiene, and protection of

human welfare and the environment.

Print Date: 02.09.2011

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