WHACK 500 FUNGICIDE

Australia - English - APVMA (Australian Pesticides and Veterinary Medicines Authority)

Active ingredient:
CHLOROTHALONIL
Available from:
IMTRADE AUSTRALIA PTY LTD
INN (International Name):
chlorothalonil(500g/L)
Pharmaceutical form:
SUSPENSION CONCENTRATE
Composition:
CHLOROTHALONIL BENZENE Active 500.0 g/L
Units in package:
1000L; 200L; 20L; 500L; 5L
Class:
A - Agricultural
Manufactured by:
IMTRADE AUSTRALIA
Therapeutic group:
ALMOND | APRICOT | BANANA | BOWLING GREEN (SEE LABEL FOR VARIETIES) | BROAD BEAN | BROCCOLI | BRUSSELS SPROUTS | CABBAGE | CAPSI
Therapeutic area:
FUNGICIDE
Therapeutic indications:
ALTERNARIA LEAF BLIGHT OR SPOT BLIGHT | ANTHRACNOSE - COLLETOTRICHUM ACUTATUM | ANTHRACNOSE ON CUCURBIT | ASCOCHYTA LEAF SPOT - ASCOCHYTA RHEI | BLACK SPOT | BLOSSOM BLIGHT - MONILINIA LAXA | BOTRYTIS | BROWN FRUIT ROT - MONILINIA FRUCTICOLA | BROWN PATCH - RHIZOCTONIA SPP. | BUNCH ROT | CERCOSPORA LEAF SPOT | CHOCOLATE SPOT ON BEAN | DOLLAR SPOT | DOWNY MILDEW ON ALLIUM (ONION, GARLIC) | DOWNY MILDEW ON CUCURBIT | DOWNY MILDEW ON GRAPE | DOWNY MILDEW ON PEA | EARLY BLIGHT (TARGET SPOT) | EARLY BLIGHT ON CELERY | EARLY LEAF SPOT ON PEANUT | FRECKLE OR SCAB ON STONE FRUIT | GREY LEAF SPOT - PYRICULARIA GRISEA | GREY LEAF SPOT - STEMPHYLIUM SOLANI | GREY MOULD - BOTRYTIS CINEREA | GUMMY STEM BLIGHT - DIDYMELLA BRYONIAE | LATE BLIGHT OR IRISH BLIGHT | LATE LEAF SPOT ON PEANUT | LEAF BLIGHT - ALTERNARIA CUCUMERINA | LEAF BLIGHT - ALTERNARIA DAUCI | LEAF CURL | LEAF MOULD OF TOMATO | LEAF SPECKLE ON BANANA | LEAF SPOT | LEAF SPOT OR YELLOW SIGATOKA ON BANANA | NET BLOTCH | PEPPERY LEAF SPOT | PURPLE BLOTCH | RING
Product summary:
Poison schedule: 6; Withholding period: WHP: Artichoke bananas capsicum, cel ery cucurbits endive leek okra, pep pers plums radish shallots sweet co rn tomatoes watercress: Do not harv- est for 1 day after application. Beans broccoli brussel sprouts, cabbages c auliflowers rhubarb apricot carrots cherries nectarines peaches, table gr apes peas: Do not harvest for 7 days a fter application. Wine grapes onions: Do not harvest for 14 days after applic ation. Beans peanuts peas: Do not gra ze live- stock on treated crops. Almon ds potatoes peanuts (harvest): Not re quired when used as directed.; Host/pest details: ALMOND: [SHOTHOLE, STONE FRUIT RUST]; APRICOT: [BLOSSOM BLIGHT - MONILINIA LAXA, BROWN FRUIT ROT - MONILINIA FRUCTICOLA, FRECKLE OR SCAB ON STONE FRUIT, SHOTHOLE, STEM END ROTS, STONE FRUIT RUST]; BANANA: [LEAF SPECKLE ON BANANA, LEAF SPOT OR YELLOW SIGATOKA ON BANANA]; BOWLING GREEN (SEE LABEL FOR VARIETIES): [BROWN PATCH - RHIZOCTONIA SPP., DOLLAR SPOT, GREY LEAF SPOT - PYRICULARIA GRISEA]; BROAD BEAN: [CHOCOLATE SPOT ON BEAN, RUST - URANYCES VICIAE-FABAE]; BROCCOLI: [RING SPOT ON BRASSICA/COLE CROP]; BRUSSELS SPROUTS: [RING SPOT ON BRASSICA/COLE CROP]; CABBAGE: [RING SPOT ON BRASSICA/COLE CROP]; CAPSICUM OR PEPPER: [ANTHRACNOSE - COLLETOTRICHUM ACUTATUM, GREY MOULD - BOTRYTIS CINEREA]; CARROT: [LEAF BLIGHT - ALTERNARIA DAUCI]; CAULIFLOWER: [RING SPOT ON BRASSICA/COLE CROP]; CELERY: [EARLY BLIGHT ON CELERY, SEPTORIA LEAF SPOT - SEPTORIA APIICOLA]; CHERRY: [BLOSSOM BLIGHT - MONILINIA LAXA, BROWN FRUIT ROT - MONILINIA FRUCTICOLA, SHOTHOLE, STEM END ROTS, STONE FRUIT RUST]; CHRYSANTHEMUM OR TANACETUM: [ALTERNARIA LEAF BLIGHT OR SPOT BLIGHT, BOTRYTIS, GREY MOULD - BOTRYTIS CINEREA, RUST, SEPTORIA SPOT]; CUCURBIT: [ANTHRACNOSE ON CUCURBIT, DOWNY MILDEW ON CUCURBIT, GUMMY STEM BLIGHT - DIDYMELLA BRYONIAE, LEAF BLIGHT - ALTERNARIA CUCUMERINA, TARGET LEAF SPOT]; ENDIVE: [GREY MOULD - BOTRYTIS CINEREA]; GERANIUM: [ALTERNARIA LEAF BLIGHT OR SPOT BLIGHT, BOTRYTIS, GREY MOULD - BOTRYTIS CINEREA, RUST, SEPTORIA SPOT]; GLOBE ARTICHOKE: [GREY MOULD - BOTRYTIS CINEREA]; GOLF GREEN TURF: [BROWN PATCH - RHIZOCTONIA SPP., DOLLAR SPOT, GREY LEAF SPOT - PYRICULARIA GRISEA]; GRAPE: [BLACK SPOT, BUNCH ROT, DOWNY MILDEW ON GRAPE]; IRIS: [ALTERNARIA LEAF BLIGHT OR SPOT BLIGHT, BOTRYTIS, GREY MOULD - BOTRYTIS CINEREA, RUST, SEPTORIA SPOT]; LEEK: [PURPLE BLOTCH]; NECTARINE: [BLOSSOM BLIGHT - MONILINIA LAXA, BROWN FRUIT ROT - MONILINIA FRUCTICOLA, SHOTHOLE]; OKRA: [LEAF SPOT]; ONION - EXCLUDING SPRING ONION: [DOWNY MILDEW ON ALLIUM (ONION, GARLIC)]; ORNAMENTAL: [ALTERNARIA LEAF BLIGHT OR SPOT BLIGHT, BOTRYTIS, GREY MOULD - BOTRYTIS CINEREA, RUST, SEPTORIA SPOT]; PEA: [DOWNY MILDEW ON PEA]; PEACH: [BLOSSOM BLIGHT - MONILINIA LAXA, BROWN FRUIT ROT - MONILINIA FRUCTICOLA, LEAF CURL, SHOTHOLE, STONE FRUIT RUST]; PEANUT: [EARLY LEAF SPOT ON PEANUT, LATE LEAF SPOT ON PEANUT, NET BLOTCH, PEPPERY LEAF SPOT, RUST ON PEANUT]; PLUM: [BLOSSOM BLIGHT - MONILINIA LAXA, BROWN FRUIT ROT - MONILINIA FRUCTICOLA, SHOTHOLE, STONE FRUIT RUST]; POTATO: [EARLY BLIGHT (TARGET SPOT), LATE BLIGHT OR IRISH BLIGHT]; RADISH: [GREY MOULD - BOTRYTIS CINEREA]; RHUBARB: [ASCOCHYTA LEAF SPOT - ASCOCHYTA RHEI]; SHALLOT: [PURPLE BLOTCH]; SWEET CORN: [TURCICUM LEAF BLIGHT]; TOBACCO: [TOBACCO LEAF SPOT]; TOMATO: [EARLY BLIGHT (TARGET SPOT), GREY LEAF SPOT - STEMPHYLIUM SOLANI, GREY MOULD - BOTRYTIS CINEREA, LEAF MOULD OF TOMATO]; WATERCRESS OR NASTURTIUM: [CERCOSPORA LEAF SPOT]; Poison schedule: 6; Withholding period: ; Host/pest details: ALMOND: [SHOTHOLE, STONE FRUIT RUST]; APRICOT: [BLOSSOM BLIGHT - MONILINIA LAXA, BROWN FRUIT ROT - MONILINIA FRUCTICOLA, FRECKLE OR SCAB ON STONE FRUIT, SHOTHOLE, STEM END ROTS, STONE FRUIT RUST]; BANANA: [LEAF SPECKLE ON BANANA, LEAF SPOT OR YELLOW SIGATOKA ON BANANA]; BOWLING GREEN (SEE LABEL FOR VARIETIES): [BROWN PATCH - RHIZOCTONIA SPP., DOLLAR SPOT, GREY LEAF SPOT - PYRICULARIA GRISEA]; BROAD BEAN: [CHOCOLATE SPOT ON BEAN, RUST - URANYCES VICIAE-FABAE]; BROCCOLI: [RING SPOT ON BRASSICA/COLE CROP]; BRUSSELS SPROUTS: [RING SPOT ON BRASSICA/COLE CROP]; CABBAGE: [RING SPOT ON BRASSICA/COLE CROP]; CAPSICUM OR PEPPER: [ANTHRACNOSE - COLLETOTRICHUM ACUTATUM, GREY MOULD - BOTRYTIS CINEREA]; CARROT: [LEAF BLIGHT - ALTERNARIA DAUCI]; CAULIFLOWER: [RING SPOT ON BRASSICA/COLE CROP]; CELERY: [EARLY BLIGHT ON CELERY, SEPTORIA LEAF SPOT - SEPTORIA APIICOLA]; CHERRY: [BLOSSOM BLIGHT - MONILINIA LAXA, BROWN FRUIT ROT - MONILINIA FRUCTICOLA, SHOTHOLE, STEM END ROTS, STONE FRUIT RUST]; CHRYSANTHEMUM OR TANACETUM: [ALTERNARIA LEAF BLIGHT OR SPOT BLIGHT, BOTRYTIS, GREY MOULD - BOTRYTIS CINEREA, RUST, SEPTORIA SPOT]; CUCURBIT: [ANTHRACNOSE ON CUCURBIT, DOWNY MILDEW ON CUCURBIT, GUMMY STEM BLIGHT - DIDYMELLA BRYONIAE, LEAF BLIGHT - ALTERNARIA CUCUMERINA, TARGET LEAF SPOT]; ENDIVE: [GREY MOULD - BOTRYTIS CINEREA]; GERANIUM: [ALTERNARIA LEAF BLIGHT OR SPOT BLIGHT, BOTRYTIS, GREY MOULD - BOTRYTIS CINEREA, RUST, SEPTORIA SPOT]; GLOBE ARTICHOKE: [GREY MOULD - BOTRYTIS CINEREA]; GOLF GREEN TURF: [BROWN PATCH - RHIZOCTONIA SPP., DOLLAR SPOT, GREY LEAF SPOT - PYRICULARIA GRISEA]; GRAPE: [BLACK SPOT, BUNCH ROT, DOWNY MILDEW ON GRAPE]; IRIS: [ALTERNARIA LEAF BLIGHT OR SPOT BLIGHT, BOTRYTIS, GREY MOULD - BOTRYTIS CINEREA, RUST, SEPTORIA SPOT]; LEEK: [PURPLE BLOTCH]; NECTARINE: [BLOSSOM BLIGHT - MONILINIA LAXA, BROWN FRUIT ROT - MONILINIA FRUCTICOLA, SHOTHOLE]; OKRA: [LEAF SPOT]; ONION - EXCLUDING SPRING ONION: [DOWNY MILDEW ON ALLIUM (ONION, GARLIC)]; ORNAMENTAL: [ALTERNARIA LEAF BLIGHT OR SPOT BLIGHT, BOTRYTIS, GREY MOULD - BOTRYTIS CINEREA, RUST, SEPTORIA SPOT]; PEA: [DOWNY MILDEW ON PEA]; PEACH: [BLOSSOM BLIGHT - MONILINIA LAXA, BROWN FRUIT ROT - MONILINIA FRUCTICOLA, LEAF CURL, SHOTHOLE, STONE FRUIT RUST]; PEANUT: [EARLY LEAF SPOT ON PEANUT, LATE LEAF SPOT ON PEANUT, NET BLOTCH, PEPPERY LEAF SPOT, RUST ON PEANUT]; PLUM: [BLOSSOM BLIGHT - MONILINIA LAXA, BROWN FRUIT ROT - MONILINIA FRUCTICOLA, SHOTHOLE, STONE FRUIT RUST]; POTATO: [EARLY BLIGHT (TARGET SPOT), LATE BLIGHT OR IRISH BLIGHT]; RADISH: [GREY MOULD - BOTRYTIS CINEREA]; RHUBARB: [ASCOCHYTA LEAF SPOT - ASCOCHYTA RHEI]; SHALLOT: [PURPLE BLOTCH]; SWEET CORN: [TURCICUM LEAF BLIGHT]; TOBACCO: [TOBACCO LEAF SPOT]; TOMATO: [EARLY BLIGHT (TARGET SPOT), GREY LEAF SPOT - STEMPHYLIUM SOLANI, GREY MOULD - BOTRYTIS CINEREA, LEAF MOULD OF TOMATO]; WATERCRESS OR NASTURTIUM: [CERCOSPORA LEAF SPOT]; For the control of fungal diseases on almonds, apricots, bananas, carrots, celery, cherries, faba beans, grapes, onions, peaches, peanuts, peas, plums, potatoes, tomatoes, and vegetables.See Restraints, etc. on label
Authorization status:
Registered
Authorization number:
54641
Authorization date:
2019-07-01

Whack

Fungicide-

Drart Label

&

Booklet 18/5/12

Label

POISON

KEEP OUT

REACH

CHILDREN

READ SAFETY INSTRUCTIONS

BEFORE

OPENING OR USING

Whack

500 Fungicide

ACTIVE

CONSTITUENT:

500 giL

CHLOROTHALONIL

GROUP

FUNGICIDE

Approved

For the control

fungal diseases on Almonds, Apricots, Bananas, Carrots, Celery,

Cherries, Faba Beans, Grapes, Onions, Peaches, Peanuts, Peas, Plums, Potatoes,

Tomatoes and Vegetables as per the Directions for Use table.

IMPORTANT:

READ

THIS

LABEL

ATTACHED

LEAFLET

BEFORE

OPENING

USING

THIS

PRODUCT

CONTENTS:

5L, 20L, 200L, 500L,

lOOOL

APVMA

APPROVAL

54641/56994

trade

Australia

151134

Ocean

Street,

Kwinana,

Western

Australia

6167

Tel: 1800 171 799

Fax:

1800 171 788

Web:

www.imtrade.com.au

Infopest

Verified

Wh:u:::k

Fungicide-

Draft

Label

&

Booklet

18/5112

STORAGE AND DISPOSAL

Store

the closed, original container

a cool well-ventilated area. DO NOT store for prolonged periods

direct

sunlight Triple or preferably pressure rinse containers before disposal. Add rinsings

spray tank.

dispose of undiluted chemicals

site.

If recycling,

replace cap and return clean containers to

recycler or

designated collection point.

not recycling, break, crush

puncture and deliver empty packaging for appropriate

disposal

approved waste management facility.

an approved waste management facility is not available,

bury the empty packaging 500mm below the surface

a disposal pit specifically marked and set

for this

purpose clear of waterways, desirable vegetation and tree roots,

compliance with relevant Local, State

Territory government regulations.

Empty containers and product should NOT

burnt.

SAFETY DIRECTIONS

Attacks

eyes

skin.

Avoid contact with

eyes

skin.

inhale spray mist.

Repeated

exposure

cause

allergic disorders. Sensitive workers should

protective clothing. When preparing spray

using the

prepared spray, wear cotton overalls buttoned

the neck

wrist, a washable hat, elbow-length

gloves,

goggles

disposable mist mask covering

mouth

nose.

If clothing becomes contaminated with product or

with spray

remove

clothing immediately. If product

skin,

immediately wash area with

soap

water.

product

eyes,

wash

it out immediately

with

water. After

before eating, drinking or smoking,

wash

hands,

arms

face

thoroughly

with

soap

water. Aner

each

day's

use,

wash gloves, goggles

contaminated clothing.

FIRST AID

poisoning occurs contact a doctor

Poisons Information Centre (Phone Australia

13 1126).

swallowed, DO

NOT induce vomiting.

Give a glass

water.

MATERIAL SAFETY DATA SHEET

Additional information

listed

the Material Safety Data Sheet which can

obtained from your supplier or

trade Australia Pty Ltd website at www.imtrade.com.au

CONDITIONS OF

SALE

lmtrade Australia Pty Ltd shall not be liable for any loss,

tnJury,

damage or death whether consequential or

otherwise whatsoever or howsoever arising whether through negligence or otherwise

connection with the sale

supply use

application

this product. The supply of this product is on the express condition that the purchaser

does not rely on lmtrade's skill or judgment

purchasing or using the same and every person dealing with this

product does so at his own risk absolutely. No representative

lmtrade Australia Ply Ltd has any authority to add

to or alter these conditions.

subje<:t

Code

when

transported

Road

Rail

Australia

No. 3082

APVMA

Approval

54641156994

Batch

Date

Manufacture:

(ADG

Special

Provision

AU01)

ENVIRONMENTALLY HAZARDOUS

SUBSTANCES, LIQUID, N.O.S.

In a

Transport

Emergency

Dial 000

Police

Fire

Brigade

HAZCHEM 3Z

Whack 500

Fungicide-

Draft

Label

&

Booklet 18/5/12

Leaflet

POISON

KEEP

REACH

CHILDREN

READ SAFETY INSTRUCTIONS BEFORE OPENING OR USING

Whack 500 Fungicide

ACTIVE

CONSTITUENT:

500 giL

CHLOROTHALONIL

GROUP

FUNGICIDE

For the control

fungal diseases on Almonds, Apricots, Bananas, Carrots, Celery, Cherries, Faba

Beans, Grapes, Onions, Peaches, Peanuts, Peas, Plums, Potatoes, Tomatoes and Vegetables as per the

Directions for Use table.

IMPORTANT:

READ

THIS

LEAFLET

BEFORE

OPENING

USING

THIS

PRODUCT

APVMA

APPROVAL

54641/56994

trade

Australia

090 151 134

Ocean

Street,

Kwinana,

Western

Australia

6167

Tel: 1800 171 799 Fax: 1800 171 788

Web: www.imtrade.com.au

Whack 500

Fungicide-

Draft Label

&

Booklet 18/5/12

DIRECTIONS FOR USE:

RESTRAINTS:

NOT mix spraying oils or wetting agents with this product.

stone

fruit

except

cherries,

following

additional

restraints

apply:

DO NOT use oils after bud-swell and during the season Whack 500 Fungicide

used after shuck fall.

NOT tank mix Whack 500 Fungicide with

formulations when spraying at shuck fall.

DO NOT exceed 4.6L

Whack 500 Fungicide per hectare of crop.

Rate

Critical

Comments

This table shows rates for dilute spraying. For concentrate spraying refer to the Mixing

uses

table: Apply by dilute or concentrate spraying equipment. Apply the same total amount

Application Section

product to the target crop whether applying this product by dilute or concentrate spraying methods. DO NOT

use at rates greater than 5 times the dilute spraying rate.

Situation

&

Disease

Rate

Critical

Comments

Crop

(days)

Almonds

Shot-hole

230 mU100L

Apply at bud-swell, bud-burst, shuck fall, cap fall. Apply every 10-14 days. Apply 1 week pre-harvest.

(NOT Qld)

(Siigmina carpophila)

Stone Fruit Rust

(Tranzschefia discolor)

Apricots

Brown

Rot-

Fruit

Apply at bud-swell, bud-burst, pink bud, full bloom. Apply

later than 35 days pre-harvest. See also Additional

(NOT Qld)

(Monilinia frocticola)

Restraints for stone fruits.

Blossom Blight

(Monilinia laxa)

Shot-hole

Apply at bud-swell, bud-burst, pink bud, shuck fall, cap fall, then every 10-14 days.

Spray applications later

(Siigmina carpophila)

than 35 days prior to harvest may result

unacceptable fruit skin damage. See also Additional Restraints for

Stone Fruit Rust

stone fruit.

(Tranzschelia discolor)

Freckle

(Venturia carpophilia)

Transit Rot

Apply 7 days pre-harvest.

(Rhizopus stolon/fer)

Cherries

Brown

Rot-

Fruit

230 mU100L

Apply at bud-swell, bud burst, pink bud, early blossom, fill bloom. Apply 3 weeks pre-harvest and 1 week pre-

(Monilinia frocticola)

harvest.

Blossom Blight

(Monilinia

laxa)

(Not

ACT,

Shot-hole

Apply at bud-swell, bud burst, pink bud, shuck fall, cap fall, then every 10-14 days. Apply 1 week pre-harvest.

(Siigmina carpophila)

Stone Fruit Rust

(Tranzschelia discolor)

Transit Rot

Apply 1 week pre-harvest.

(Rhizopus stolon/fer)

Page4

Whack 500

Fungicide-

Draft Label

&

Booklet 18/5/12

Situation

&

Disease

Rate

Critical

Comments

Crop

(days)

Grapes

Downy Mildew

230-300

Dessert

Spray at first appearance

the foliage disease. Apply at 7-14 day intervals particularly during

Note:

russeting

(p/asmopara viticola)

mU100L

wet weather and periods

rapid growth.

For bunch rot, applications at early full bloom, two

some

table

Bunch Rot

weeks later, at veraisson and two weeks prior

harvest.

grape

varieties

(Botrytis cinerea)

Wine

Table

Grapes-

russetting

some varieties may occur.

DO NOT apply after cap fall on these

occur.

varieties.

Black Spot (Anthrracnose)

mU100L

Black Spot has occurred

the vineyard

the last 3 years, apply at budburst and 14

(Eisinoe ampelina)

days later when shoots are 10-15cm long.

weUhumid conditions persist spray again when shoots are 20-30cm long to protect new growth.

Some initial minimal leaf damage on the new shoots

sensitive varieties can occur if spray

treatments are applies at budburst and

the first 14 days after budburst.

vineyards with

history

Black Spot, spray only at the first appearance

the disease on the foliage and then at

7-14

day intervals if weUhumid conditions persist. Applications up to cap-fall will not cause

russettin!l

Table Grape and dried fruit varieties.

Nectarines

Shot-hole

230 mU100L

Apply at bud-swell, pink bud, shuck fall and then repeat each 14 days if weather conditions

(Stigmina carpophila)

favour disease.

Spray applications later than 35 days prior to harvest may result

unacceptable

(NSW, Vic, Tas, SA,

only)

fruit skin damage.

See also Additional Restraints for stone fruits.

Brown

Rot-

Fruit

Apply at first bud-swell, bud burst, pink bud, early blossom and full blossom.

Spray applications

(Monilinia fructicola)

later than 35 days prior to harvest may result

unacceptable fruit skin damage.

See also

Blossom Blight

Additional Restraints for stone fruits.

(Monilinia laxa)

(NSW, Tas

only)

Peaches

Brown

Rot-

Fruit

230 mU100L

Apply at bud-swell, pink bud, early blossom and full bloom. Spray applications later than 35 days

(Monilinia fructicola)

prior to harvest may result

unacceptable fruit skin damage.

See also Additional Restraints for

Blossom Blight

stone fruits.

(Monilinia laxa)

Shot-hole

Apply at bud-swell and continue at

7-14

day intervals.

Spray applications later than 35 days

(Stigmina carpophila)

prior to harvest may result

unacceptable fruit skin damage.

See also Additional Restraints for

Stone Fruit Rust

stone fruits.

(Tranzshelia discolor)

Leaf Curl

Apply at bud-swell

continue at

7-14

day intervals.

QLD spray only at bud-swell. Spray

(Taphdna defonnans)

applications later than 35 days prior to harvest may result

unacceptable fruit skin damage.

See also Additional Restraints for stone fruits.

Plums

Brown

Rot-

Fruit

230 mU100L

Apply at bud-swell, bud-burst, early blossom, pink bud and full bloom.

Spray applications later

(Monilinia fructicola)

than 35 days prior to harvest may result

unacceptable fruit skin damage.

See also Additional

Blossom Blight

Restraints for stone fruits.

(Monilinia lax a)

(Not

ACT, NT)

Stone Fruit Rust

Apply at

bud~swell,

bud burst, shuck fall and cap fall.

Spray applications later than 35

days

prior

(Tranzschelia discolor)

to harvest

result

unacceptable fruit skin damage.

See also Additional Restraints for stone

Shot-hole

fruits.

(Stigmina carpophila)

PageS

Whack 500

Fungicide-

Drart Label

&

Booklet IS/5/12

NON-TREE AND VINE CROPS

Situation

&

Disease

Rate

Critical

Comments

Crop

(days)

Artichoke-

Grey Mould

2.6-

3.3Uha

Apply at 7-10 day intervals

required. Use the higher rate

disease pressure is high.

Globe

(Botrytis cinerea)

(Qid only)

Bananas

Leaf Spot

2.6Uha

North

Qld-

Spray every 14 days late January to end

March.

NOT apply

(Mycosphaerella

(Qtd, NSW, NT

Extend to

days after March and then 28-35 days

the drier months of the year.

to bananas

musico/a)

only)

South

Qld-

Spray every

days from start

December to end

April.

within 14 days

NSW-

Spray every 10-14 days from November to end

May.

applying an

2.2Uha

Spray every 10-14 days from November to end

May and extend to 14-21 days from May to

all based spray

(WA only)

November.

crop damage

will occur

Leaf Speckle

4.3Uha

Spray schedule same as for control of leaf spot. This product will not eradicate infection already present but will

(Mycosphaerella Musae)

prevent the spread

disease.

(Qid, NSW, WA, NT

ontyj

Beans-

Broad

Chocolate Spot

1.6-

2.6Uha

Apply at first sign

disease on the leaves or

weather conditions indicate likely incidence

disease. Repeat

(Faba)

(Botrytis fabae)

at 7-14 day intervals. Use the higher rate

the crop is dense and disease pressure is high.

(Tas

&

Rust

onlvl

fUromyc;es viciae-fabae)

Broccoli,

Ring Spot

2.5-

5Uha

Apply at first sign

disease on the leaves or

weather conditions indicate likely incidence

disease. Repeat

Brussels

(Mycosphaerella

at 14-day intervals. Use the higher rate

the crop is dense and disease pressure is high.

Sprouts,

Brassicico/a)

Cabbages,

Cauliflowers

Capsicums

Grey Mould

2.6-

3.3Uha

Apply at 7-10 day intervals as required. Use the higher rate

disease pressure is high.

Peppers

(Botrytis cinerea)

(Qid only)

Anthracnose

(Colletotrichum

ascutatum)

Carrots

Leaf Blight

2.6Uha or 230

Commence application at first sign of disease and then spray every 7-14 days.

IA/Iematia dauci!

mU100L

Cucurbits

Downy Mildew

2.4-

3.6Uha

Apply

a 7 to

day schedule.

(including

(Pseudoperonospora

Apply rates towards the higher end

the recommended range at 7 day intervals when disease pressure is

Cantaloupe,

Cubensis)

high. Commence spray program early, at first true leaf and before vining or flowering.

Cucumber,

Gummy Stem Blight

Honeydew,

(Didymella bryoniae)

When used at these rates, this product will suppress powdery mildew.

Muskmelon,

Anthracnose

Pumpkin,

(Co/letottichum

Squash,

orbiculate)

Rockmelon,

Leaf Blight

Watermelon,

(Alternaria cucumerina)

Zucchini)

Target Leaf Spot

(Cercospora citrullina)

Belly Rot

Suppression

Belly Rot will be obtained where fruit form on soil when sprayed using the above foliar spray

(Rhinzoctonia so/ani)

program.

Page6

Whack

Fungicide-

Drart

Label

&

Dookld

18/5/12

Situation

&

Disease

Rate

Critical

Comments

Crop

(days)

Celery

Septaria Leaf Spot

2.6Uha or

Apply every 7-14 days. Apply also

seed beds.

(Septoria apilicola)

230 mU100L

Cercospora Early Blight

1.8Uha

Apply every 10-14 days

(Cercospora apii)

(NSW,

only)

Endive

Grey Mould

2.6-

3.3Uha

Apply at

7-10

day intervals

required.

Use the higher rate if disease pressure

high.

(Qid

only)

(Botrytis cinerea)

Leeks, Shallots

Purple Blotch

Apply at first appearance

disease.

Repeat at

day intervals, particularly during wet weather.

(Qid

only)

(Alternaria

porri)

Okra

Leaf Diseases/Spot

Apply at first appearance

disease.

Repeat at

7-10

day intervals.

(Qid

only)

Onions

Downy Mildew

3.3Uha

Apply at first sign

disease on the leaves or

weather conditions indicate likely incidence

disease.

Repeat

(excluding

(Peronospora

day intervals.

Spring

Onions}

destructor)

Ornamentals

Botrytis, Grey Mould,

150 mU100L

Apply at

7-14

day intervals.

day interval under severe conditions. Avoid application to blooms

Azalea,

Chrysanthemum

Rust diseases, Septaria

Hydrangea and Petunia,

s, Geraniums,

and Alternaria Leaf Spot

Iris

&

other

diseases

Ornamentals

(Tas ontv)

Peanuts

Early Leaf Spot

1.6-

2.6Uha

Use higher rate when conditions favour leaf spot

when rust appears.

NOT feed peanut vines to

(Qid, NSW, NT,

(Cercospora

140-230

livestock.

WA, ACT

only)

arachidicola)

mU100L

NSW and

ONLY: Commence application when disease first appears and repeat as necessary to maintain

Late Leaf Spot

control.

(Cercosporidium

QLD ONLY: NORTH AND SOUTH

BURNETT-

Commence spraying when disease appears

repeat when

personatum)

rain

warm moist nights are expected.

Peppery Leaf Spot

ATHERTON

TABLELANDS-

Commence spraying

weeks after planting and repeat at

7-14

day intervals

(Leptosphaerulina trifo/ii)

depending on conditions.

Peanut Rust

(Puccinia arachidis)

Net Blotch

(Didymosphaeria

arachidicola)

Peas

Downy Mildew

1.6-

2.6Uha

Apply at first sign

disease on the leaves or if weather conditions indicate likely incidence

disease.

Repeat

(Tas

only)

(Peronospora viciae)

7-14

day intervals. Use the higher rate

the crop is dense and disease pressure

high.

Potato

Early Blight or Target

1.6-

2.6Uha

Spray at first sign

foliage disease or at flowering time, whichever

earlier.

Spray every

7-14

days until

Spot

within

days

desiccation

harvest..

(Alternaria so/ani)

Late Blight

Irish Blight

(Phytophthora infestans)

Page 7

Whack

Fungicide-

Draft

Label

&

Booklet

18/5/12

Situation

&

Disease

Rate

Critical

Comments

Crop

(days)

Radish

Grey Mould

2.6-

3.3Uha

Apply at 7-10 day intervals as required. Use the higher rate

disease pressure is high.

(Qid only)

(Botrytis cinerea)

Rhubarb

Ascochyta Leaf Spot

200 mU100L

Apply every 10-14 days

(NSW, ACT

(Ascochyta rflei)

Apply

only)

2000Uha

Sweetcorn

Turcicum Leaf Blight

2.6-

3.3Uha

Apply at first appearance

disease.

Repeat at 7-10 day intervals.

(Qid only)

(Exaerohilum

turcicum)

Tobacco

Tobacco Leaf Spot

320 mU100L

Apply every 7 days

seed bed application only.

(QLD only)

(Ascochyta arida)

Tomato

Early Blight or Target

2.6-

3.3Uha

Spray at first appearance

the foliage disease.

Spray at 7-14 day intervals.

Continue into the picking season

Blight

to obtain best results against Leaf Mould and Botrytis Rot.

(Alternaria so/ani)

230-300

Leaf Mould

(Fulvia fulva)

mU100L

Grey Leaf Spot

(Stemphylium so/ani)

Botrytis Rot

Grey

Mould

(Botmis

cinerea)

Turf

&

Lawns,

Dollar Spot

190-300

mU

Use higher rate when disease is already established.

Bowling Greens,

(Sc/erotinia

100m

20-60L

Apply at 7-14 day intervals.

Golf Greens

homeocarpa)

of water

Treated

area-

DO NOT mow

water until turf is thoroughly dry.

(NSW, SA, Qld, WA,

Vic, ACT

only).

Brown Patch

(Rhizoctonia

spp.J

Grey Leaf Spot

35Uha

Apply to leaf

a curative application. DO NOT irrigate for 24 hours after application.

(Stempphy/ium so/ani)

(NSWonly)

Watercress

Cercospora Leaf Spot

-3.3Uha

Apply at 7-14 day intervals as required.

Use the higher rate

disease pressure is high.

(Qid, WA

only)

USED

PURPOSE,

MANNER,

CONTRARY

THIS

LABEL

UNLESS

AUTHORISED

UNDER

APPROPRIATE

LEGISLATION.

Page 8

Whack 500

Fungicide-

Draft

Label

&

Booklet 18/5/12

WITHHOLDING PERIODS:

Artichoke,

Bananas,

Capsicum, Celery,

Cucurbits,

Endive,

Leek,

Okra, Peppers,

Plums,

Radish,

Shallots,

Sweetcorn, Tomatoes, Watercress:

NOT HARVEST FOR

1

DAY AFTER APPLICATION.

Beans,

Broccoli,

Brussel

Sprouts, Cabbages, Cauliflowers,

Rhubarb:

Apricots,

Carrots, Cherries, Nectarines, Peaches, Table Grapes, Peas:

NOT HARVEST FOR 7 DAYS AFTER APPLICATION.

Wine Grapes,

Onions:

NOT HARVEST FOR 14 DAYS AFTER APPLICATION.

Beans, Peanuts, Peas:

NOT GRAZE LIVESTOCK

TREATED CROPS.

Almonds,

Potatoes,

Peanuts

(Harvest):

NOT REQUIRED

WHEN

USED AS DIRECTED

GENERAL INSTRUCTIONS

This

product

is a protectant

fungicide

control

a range

diseases in

fruit

and vegetables.

effective disease

control

good

leaf

cover

must

be achieved before a widespread disease

outbreak

occurs.

Mixing:

Thoroughly shake and invert the pack several times before opening.

Half fill spray vat and with agitation system

running, add the required amount of product.

Application:

Dilute Spraying:

Use a sprayer designed

apply high volumes

water

the point

run-off.

and operate the sprayer to achieve even coverage throughout the crop canopy.

Apply sufficient water

cover the crop

point

run-off.

Avoid excessive run-off.

The required water volume may

determined by applying different test volumes, using different settings on the

sprayer, from industry guidelines or expert advice.

Add the required amount

product specified

the Directions for Use for each 1

water.

Spray to the point

run-off.

The required dilute spray volume will change

sprayer set

and operation may also need to be changed,

the crop grows.

Concentrate Spraying:

Use a sprayer designed and set

for concentrate spraying (that

a sprayer which applies water volumes less

than those required

reach the point

run-off) and matched to the crop being sprayed (e.g. Low Volume Air

Blast).

and operate the sprayer to achieve even coverage throughout the crop canopyusing your chosen water

volume.

Determine the appropriate dilute spray (see dilute spraying above) for crop canopy.

This

needed to calculate

the concentrate mixing rate.

The mixing rate for concentrate spraying can then be calculated

the following way:

EXAMPLE ONLY:

Dilute spray volume

determined above:

For example 1500Liha

Your chosen concentrate spray volume:

For example 500L/ha

The concentration factor

this example

3 x (i.e. 1500.,.500

the dilute label rate

ml/100

then the concentrate rate becomes 3 x 10, that

mli100L

concentrate spray.

The chosen spray volume, amount

product per 1

water, and the sprayer set

and operation may

need

be changed

the crop grows.

For further information

concentrate spraying, users are advised

consult the relevant industry guidelines,

undertake appropriate competency training and follow industry Best Practices.

Application

rates

hectare:

Volume-

200L or more

High

Volume-

500L or more

Aerial

Application

20L or more

Mister-

255L

The volume

water applied should increase

the plants grow

size

maintain adequate cover.

Page 9

Whnck 500 Fungicide- Dntft Label

&

Booklet

18/5/12

COMPATIBILITY

This

product

compatible with

wettable powder and

llowable formulations

of most commonly used fungicides,

insecticides

miticides.

Unless experience

your area has shown other combinations

physically compatible

and non-injurious to your crop

not combine with other chemicals, especially oil-based emulsifiable or flowable

pesticides.

This product should not be mixed with spraying oils or sprayed onto crops that have been sprayed

with

for at least

days after the last spray.

Wetting Agents:

The addition of surfactants does not improve this product's efficiency and under some conditions may cause plant

injury.

FUNGICIDE

GROUP

Whack 500 Fungicide is a member

the multi-site activity group of fungicides.

For fungicide resistance management

the product is a Group

Fungicide.

Some naturally occurring individual fungi resistant to Whack 500 Fungicide and

other Group

Fungicides may exist through normal genetic variability

any fungal population.

The resistant

individuals

eventually dominate the fungal population if these are used repeatedly.

These resistant fungi will not

be controlled

Whack 500 Fungicide or other Group

Fungicides, thus resulting

a reduction

efficiency

possible yield loss.

Since the occurrence of resistant fungi is difficult to detect prior to

use,

trade Australia Pty

accepts

liability for any losses that may result from

failure

Whack

Fungicide to control resistant fungi.

PROTECTION

LIVESTOCK

NOT contaminate feed

foodstuffs

with

this product

empty containers.

PROTECTION

WILDLIFE, FISH, CRUSTACEANS AND ENVIRONMENT

Dangerous

fish.

NOT contaminate streams, rivers

waterways

with

chemical or used containers.

STORAGE AND DISPOSAL

Store

the closed, original container

a cool well-ventilated area.

NOT store for prolonged periods

direct

sunlight. Triple or preferably pressure rinse containers before disposal.

rinsings to spray tank.

NOT dispose

undiluted chemicals

site. If recycling, replace cap

return clean containers to recycler or designated collection

point. If not recycling, break, crush or puncture and deliver empty packaging for appropriate disposal to

approved

waste management facility.

approved waste management facility is not available, bury the empty packaging

500mm below the surface

a disposal pit specifically marked and set up for this purpose clear of waterways, desirable

vegetation

tree

roots,

compliance with

relevant

Local,

State or Territory government regulations.

Emoty

containers and product should NOT

burnt

SAFETY DIRECTIONS

Attacks

eyes

skin.

Avoid

contact

with

eyes

skin.

not inhale spray mist

Repeated

exposure

cause

allergic disorders. Sensitive

workers

should

protective

clothing.

When

preparing

spray

using

prepared

spray,

wear

colton

overalls

buttoned

neck

wrist,

washable

hat,

elbow-length

gloves,

goggles

disposable mist

mask

covering

mouth

nose.

clothing

becomes

contaminated

with

product or

with

spray

remove

clothing

immediately.

product

skin,

immediately

wash

area

with

soap

water.

product

eyes,

wash

it out immediately

with

water.

After

before

eating,

drinking

smoking,

wash

hands,

arms

face

thoroughly

with

soap

water.

After

each

day's

use,

wash

gloves,

goggles

contaminated

clothing.

FIRST AID

If poisoning occurs contact a doctor or Poisons Information Centre (Phone Australia

1126). If

~wallowed,

induce vomiting.

Give a glass

water.

MATERIAL SAFETY DATA SHEET

Additional information

listed

Material Safety Data Sheet which can be obtained from your supplier or lmtrade

Australia Ply

website

www.imtrade.com.au

Page 10

Whack

500

Fungicide-

Draft

Lnbrl

&

Booklet

18/5/12

CONDITIONS

SALE

The use of Whack 500 Fungicide being beyond the control of the manufacturer,

warranty expressed or implied

given by lmtrade Australia Ply

regarding its suitability, fitness

efficiency for any purpose for which it

used by the

buyer, whether

accordance with the directions or not and lmtrade Australia Ply

accepts

responsibility for any

consequence whatsoever from the use

this product.

Not

subject

to

the

ADG

Code

when

transported

by

Road

or

Rail

in

Australia

(ADG

Special

Provision

AU01)

No. 3082

ENVIRONMENTALLY HAZARDOUS

SUBSTANCES, LIQUID, N.O.S.

Transport

Emergency

Dial 000

Police

Fire

Brigade

HAZCHEM 3Z

APVMA

Approval:

54641/56994

Page

II

Safety Data Sheet

SAFETY DATA SHEET

Issued by: Imtrade Australia Pty Ltd

Phone: 1800 171 799

Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)

PRODUCT NAME:

Whack 500 Fungicide

APVMA Product Code:

54641

1 - IDENTIFICATION OF THE MATERIAL AND SUPPLIER

Supplier Name

IMTRADE AUSTRALIA PTY LTD

Address

17 Ocean Street, Kwinana, Western Australia, AUSTRALIA, 6167

Telephone

1800 171 799

Fax

1800 171 788

Emergency

In a Transport Emergency Dial 000 – Police or Fire Brigade

Web site

http://www.imtrade.com.au

Product Use:

Agricultural fungicide for use as described on the product label.

Creation Date:

August, 2008

This version issued:

April, 2014 and is valid for 5 years from this date.

Product type:

Chlorothalonil is a chlorinated aromatic nitrile derivative.

SECTION 2 - HAZARDS IDENTIFICATION

Statement of Hazardous Nature

This product is classified as: T+ Toxic, Xi, Irritating.

Hazardous according to the criteria of SWA Australia.

Not subject to the ADG Code when transported in Australia by Road or Rail (refer to SP AU01). However if

transported by Air or Sea, this provision does not apply. Then the product is classed as Dangerous (Class 9

Environmentally Hazardous) by IATA and IMDG respectively. See details below and in Section 14 of this SDS.

Risk Phrases:

R26, R37, R40, R41, R43, R50/53. Very toxic by inhalation. Irritating to respiratory system. Limited

Evidence of carcinogenic effect. Risk of serious damage to eyes. May cause sensitisation by skin contact. Very toxic

to aquatic organisms, may cause long-term adverse effects to the aquatic environment.

Safety Phrases:

S25, S38, S57, S59, S60, S61, S36/37. Avoid contact with eyes. In case of insufficient ventilation,

wear suitable respiratory equipment. Use appropriate container to avoid environmental contamination. Refer to

manufacturer/supplier for information on recovery/recycling. This material and its container must be disposed of as

hazardous waste. Avoid release to the environment. Refer to special instructions/Safety Data Sheets. Wear suitable

protective clothing and gloves.

SUSMP Classification:

ADG Classification:

Class 9: Miscellaneous dangerous goods.

UN Number:

3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.

GHS Signal word: DANGER

HAZARD STATEMENT:

H317: May cause an allergic skin reaction.

H318: Causes serious eye damage.

H331: Toxic if inhaled.

H335: May cause respiratory irritation.

H351: Suspected of causing cancer.

H410: Very toxic to aquatic life with long lasting effects.

PREVENTION

P102: Keep out of reach of children.

P201: Obtain special instructions before use.

P202: Do not handle until all safety precautions have been read and understood.

P260: Do not breathe fumes, mists, vapours or spray.

P261: Avoid breathing fumes, mists, vapours or spray.

P262: Do not get in eyes, on skin, or on clothing.

P264: Wash contacted areas thoroughly after handling.

Product Name: Whack 500 Fungicide

Page: 2 of 7

SDS Date: April, 2014

SAFETY DATA SHEET

Issued by: Imtrade Australia Pty Ltd

Phone: 1800 171 799

Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)

P271: Use only outdoors or in a well ventilated area.

P272: Contaminated work clothing should not be allowed out of the workplace.

P273: Avoid release to the environment.

P280: Wear protective gloves, protective clothing and eye or face protection.

P281: Use personal protective equipment as required.

P284: Wear respiratory protection.

RESPONSE

P310: Immediately call a POISON CENTRE or doctor/physician.

P363: Wash contaminated clothing before reuse.

P301+P330+P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P302+P352: IF ON SKIN: Wash with plenty of soap and water.

P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.

P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if

present and easy to do. Continue rinsing.

P308+P313: If exposed or concerned: Get medical advice.

P333+P313: If skin irritation or rash occurs: Get medical advice.

P337+P313: If eye irritation persists: Get medical advice.

P391: Collect spillage.

P370+P378: Alcohol resistant foam is the preferred firefighting medium but, if it is not available, normal foam

can be used.

STORAGE

P405: Store locked up.

P403+P233: Store in a well-ventilated place. Keep container tightly closed.

DISPOSAL

P501: Dispose of contents and containers as specified on the registered label.

Emergency Overview

Physical Description & colour

: Pale yellow liquid.

Odour:

Mild, characteristic odour.

Major Health Hazards:

Chlorothalonil is not harmful to mammals by oral or dermal exposure, but it can cause

severe eye and skin irritation in certain formulations. Very high doses may cause a loss of muscle coordination, rapid

breathing, nose bleeding, vomiting, hyperactivity, and death. Dermatitis, vaginal bleeding, bright yellow and/or bloody

urine, and kidney tumours may also occur. Toxic if inhaled, may cause irreversible effects, eye irritant.

Potential Health Effects

Persons sensitised to Chlorothalonil should avoid contact with this product.

Inhalation:

Short Term Exposure:

Available data shows that this product is very toxic, but symptoms are not available. In

addition product is a severe inhalation irritant. Symptoms may include headache, extreme irritation of nose and throat

and increased secretion of mucous in the nose and throat. Other symptoms may also become evident, and may last

long after exposure has ceased.

Long Term Exposure:

No data for health effects associated with long term inhalation.

Skin Contact:

Short Term Exposure:

Classified as a potential sensitiser by skin contact. Exposure to a skin sensitiser, once

sensitisation has occurred, may manifest itself as skin rash or inflammation, and in some individuals this reaction can

be severe. In addition product may be irritating, but is unlikely to cause anything more than mild transient discomfort.

Long Term Exposure:

No data for health effects associated with long term skin exposure.

Eye Contact:

Short Term Exposure

: This product is a severe eye irritant. Symptoms may include stinging and reddening of eyes

and watering which may become copious. Other symptoms such as swelling of eyelids and blurred vision may also

become evident. If exposure is brief, symptoms should disappear once exposure has ceased. However, lengthy

exposure or delayed treatment is likely to cause permanent damage.

Long Term Exposure

: No data for health effects associated with long term eye exposure.

Ingestion:

Short Term Exposure

: Significant oral exposure is considered to be unlikely. However, this product is an oral

irritant. Symptoms may include burning sensation and reddening of skin in mouth and throat. Other symptoms may

also become evident, but all should disappear once exposure has ceased.

Long Term Exposure

: No data for health effects associated with long term ingestion.

Product Name: Whack 500 Fungicide

Page: 3 of 7

SDS Date: April, 2014

SAFETY DATA SHEET

Issued by: Imtrade Australia Pty Ltd

Phone: 1800 171 799

Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)

Carcinogen Status:

SWA:

Chlorothalonil is classified by SWA as a Class 3 Carcinogen, possibly carcinogenic to humans.

See the SWA website for further details. A web address has not been provided as addresses frequently change.

NTP:

No significant ingredient is classified as carcinogenic by NTP.

IARC:

Chlorothalonil is classed 2b IARC - possibly carcinogenic to humans.

See the IARC website for further details. A web address has not been provided as addresses frequently change.

SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTS

Ingredients

CAS No

Conc,%

TWA (mg/m

3

)

STEL (mg/m

3

)

Chlorothalonil

1897-45-6

500g/L

not set

not set

Other non hazardous ingredients

secret

to 100

not set

not set

This is a commercial product whose exact ratio of components may vary slightly. Minor quantities of other non

hazardous ingredients are also possible.

The TWA exposure value is the average airborne concentration of a particular substance when calculated over a normal 8 hour working day for a 5

day working week. The STEL (Short Term Exposure Limit) is an exposure value that should not be exceeded for more than 15 minutes and should

not be repeated for more than 4 times per day. There should be at least 60 minutes between successive exposures at the STEL. The term "peak "is

used when the TWA limit, because of the rapid action of the substance, should never be exceeded, even briefly.

SECTION 4 - FIRST AID MEASURES

General Information:

You should call The Poisons Information Centre if you feel that you may have been poisoned, burned or irritated by

this product. The number is 13 1126 from anywhere in Australia (0800 764 766 in New Zealand) and is available at all

times. Have this SDS with you when you call.

Inhalation:

If inhalation occurs, contact a Poisons Information Centre. Urgent hospital treatment is likely to be

needed. Remove source of contamination or move victim to fresh air. If breathing is difficult, oxygen may be beneficial

if administered by trained personnel, preferably on a doctor's advice. DO NOT allow victim to move about

unnecessarily. Symptoms of pulmonary oedema can be delayed up to 48 hours after exposure.

Skin Contact:

Wash gently and thoroughly with water (use non-abrasive soap if necessary) for 5 minutes or until

chemical is removed.

Eye Contact:

Immediately flush the contaminated eye(s) with lukewarm, gently flowing water for 20 minutes or until

the product is removed, while holding the eyelid(s) open. Take care not to rinse contaminated water into the

unaffected eye or onto the face. Obtain medical attention immediately. Take special care if exposed person is wearing

contact lenses.

Ingestion:

If swallowed, do NOT induce vomiting. Wash mouth with water and contact a Poisons Information

Centre, or call a doctor.

SECTION 5 - FIRE FIGHTING MEASURES

Fire and Explosion Hazards

: This product is classified as a C1 combustible product. There is a slight risk of an

explosion from this product if commercial quantities are involved in a fire. Violent steam generation or eruption may

occur upon application of direct water stream on hot liquids. Vapours from this product are heavier than air and may

accumulate in sumps, pits and other low-lying spaces, forming potentially explosive mixtures. They may also flash

back considerable distances.

Fire decomposition products from this product may be toxic if inhaled. Take appropriate protective measures.

Extinguishing Media

: Alcohol resistant foam is the preferred firefighting medium but, if it is not available, normal

foam can be used.

Fire Fighting

: If a significant quantity of this product is involved in a fire, call the fire brigade. There is little danger of

a violent reaction or explosion if significant quantities of this product are involved in a fire. Recommended personal

protective equipment is full fire kit and breathing apparatus.

Flash point

:

No data

Upper Flammability Limit:

No data.

Lower Flammability Limit:

No data.

Autoignition temperature:

No data.

Flammability Class:

SECTION 6 - ACCIDENTAL RELEASE MEASURES

Accidental release

: In the event of a major spill, prevent spillage from entering drains or water courses. Wear full

protective chemically resistant clothing including eye/face protection, gauntlets and self contained breathing

apparatus. See below under Personal Protection regarding Australian Standards relating to personal protective

equipment. Suitable materials for protective clothing include rubber, PVC. Eye/face protective equipment should

comprise as a minimum, protective goggles. If there is a significant chance that vapours or mists are likely to build up

Product Name: Whack 500 Fungicide

Page: 4 of 7

SDS Date: April, 2014

SAFETY DATA SHEET

Issued by: Imtrade Australia Pty Ltd

Phone: 1800 171 799

Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)

in the cleanup area, we recommend that you use a respirator. Usually, no respirator is necessary when using this

product. However, if you have any doubts consult the Australian Standard mentioned below (section 8). Otherwise,

not normally necessary.

Stop leak if safe to do so, and contain spill. Absorb onto sand, vermiculite or other suitable absorbent material. If spill

is too large or if absorbent material is not available, try to create a dike to stop material spreading or going into drains

or waterways. Because of the environmentally hazardous nature of this product, special care should be taken to

restrict release to waterways or drains. Sweep up and shovel or collect recoverable product into labelled containers

for recycling or salvage, and dispose of promptly. Recycle containers wherever possible after careful cleaning. Refer

to product label for specific instructions. After spills, wash area preventing runoff from entering drains. If a significant

quantity of material enters drains, advise emergency services. Full details regarding disposal of used containers,

spillage and unused material may be found on the label. If there is any conflict between this SDS and the label,

instructions on the label prevail. Ensure legality of disposal by consulting regulations prior to disposal. Thoroughly

launder protective clothing before storage or re-use. Advise laundry of nature of contamination when sending

contaminated clothing to laundry.

SECTION 7 - HANDLING AND STORAGE

Handling

: Keep exposure to this product to a minimum, and minimise the quantities kept in work areas. Check

Section 8 of this SDS for details of personal protective measures, and make sure that those measures are followed.

The measures detailed below under "Storage" should be followed during handling in order to minimise risks to

persons using the product in the workplace. Also, avoid contact or contamination of product with incompatible

materials listed in Section 10.

Storage

: This product is a Scheduled Poison. Observe all relevant regulations regarding sale, transport and storage

of this schedule of poison. Check packaging - there may be further storage instructions on the label.

SECTION 8 - EXPOSURE CONTROLS AND PERSONAL PROTECTION

The following Australian Standards will provide general advice regarding safety clothing and equipment:

Respiratory equipment: AS/NZS 1715, Protective Gloves: AS 2161, Occupational Protective Clothing: AS/NZS 4501

set 2008, Industrial Eye Protection: AS1336 and AS/NZS 1337, Occupational Protective Footwear: AS/NZS2210.

SWA Exposure Limits

TWA (mg/m

3

)

STEL (mg/m

3

)

Exposure limits have not been established by SWA for any of the significant ingredients in this product.

The ADI for Chlorothalonil is set at 0.01mg/kg/day. The corresponding NOEL is set at 1.5mg/kg/day. ADI means

Acceptable Daily Intake; NOEL means No-observable-effect-level. Data from Australian ADI List, June 2013.

No special equipment is usually needed when occasionally handling small quantities. The following instructions are

for bulk handling or where regular exposure in an occupational setting occurs without proper containment systems.

Ventilation:

Make sure that the work environment remains clean and that vapours and mists are minimised.

Eye Protection:

Protective glasses or goggles must be worn when this product is being used. Failure to protect

your eyes may lead to severe harm to them or to general health. Emergency eye wash facilities must also be

available in an area close to where this product is being used.

Skin Protection:

If you believe you may have a sensitisation to this product or any of its declared ingredients, you

should prevent skin contact by wearing impervious gloves, clothes and, preferably, apron. Make sure that all skin

areas are covered. See below for suitable material types.

Protective Material Types:

There is no specific recommendation for any particular protective material type.

Respirator:

Usually, no respirator is necessary when using this product. However, if you have any doubts consult

the Australian Standard mentioned above.

Eyebaths or eyewash stations and safety deluge showers should, if practical, be provided near to where this product

is being handled commercially.

SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES:

Physical Description & colour

Pale yellow liquid.

Odour:

Mild, characteristic odour.

Boiling Point:

Not available.

Freezing/Melting Point:

No specific data. Liquid at normal temperatures.

Volatiles:

No data.

Vapour Pressure:

No data.

Vapour Density:

No data.

Specific Gravity:

1.34

Water Solubility:

Dispersible.

pH:

No data.

Volatility:

No data.

Odour Threshold:

No data.

Product Name: Whack 500 Fungicide

Page: 5 of 7

SDS Date: April, 2014

SAFETY DATA SHEET

Issued by: Imtrade Australia Pty Ltd

Phone: 1800 171 799

Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)

Evaporation Rate:

No data.

Coeff Oil/water distribution

No data

Autoignition temp:

No data.

SECTION 10 - STABILITY AND REACTIVITY

Reactivity:

This product is unlikely to react or decompose under normal storage conditions. However, if you have

any doubts, contact the supplier for advice on shelf life properties.

Conditions to Avoid:

Protect this product from light. Store in the closed original container in a dry, cool, well-

ventilated area out of direct sunlight.

Incompatibilities:

strong acids, strong bases, strong oxidising agents.

Fire Decomposition:

Carbon dioxide, and if combustion is incomplete, carbon monoxide and smoke. Nitrogen and

its compounds, and under some circumstances, oxides of nitrogen. Occasionally hydrogen cyanide gas. Hydrogen

chloride gas, other compounds of chlorine. Water. Carbon monoxide poisoning produces headache, weakness,

nausea, dizziness, confusion, dimness of vision, disturbance of judgment, and unconsciousness followed by coma

and death.

Polymerisation:

This product will not undergo polymerisation reactions.

SECTION 11 - TOXICOLOGICAL INFORMATION

Toxicity:

An information profile for Chlorothalonil is available at http://extoxnet.orst.edu/pips/ghindex.html

Acute toxicity: Chlorothalonil is not harmful to mammals by oral exposure, but it can cause severe eye and skin

irritation in certain formulations. Very high doses may cause a loss of muscle coordination, rapid breathing, nose

bleeding, vomiting, hyperactivity, and death. Dermatitis, vaginal bleeding, bright yellow and/or bloody urine, and

kidney tumours may also occur. The oral LD

is greater than 10,000 mg/kg in rats and 6000 mg/kg in mice. The

acute dermal LD

in both albino rabbits and albino rats is 10,000 mg/kg. An inhalation LC

(4hr), rat of 0.7mg/L has

been quoted. In albino rabbits, 3 mg of chlorothalonil applied to the eyes caused mild irritation that subsided within 7

days of exposure.

Chronic toxicity: In a number of tests of varying lengths of time, rats fed a range of doses of chlorothalonil generally

showed no effects on physical appearance, behaviour, or survival. Skin contact with chlorothalonil may result in

dermatitis or light sensitivity. Human eye and skin irritation is linked to chlorothalonil exposure; 14 of 20 workers

exposed to 0.5% chlorothalonil in a wood preservative developed dermatitis. All workers showed swelling and

inflammation of the upper eyelids. Allergic skin responses have also been noted in farm workers.

Reproductive effects: Studies suggest that chlorothalonil will not affect human reproduction at expected exposure

levels.

Teratogenic effects: Long-term studies indicate that high doses fed to rats caused reduced weight gains for males

and females in each generation studied. A study of birth defects in rabbits showed no effects. Chlorothalonil is not

expected to produce birth defects in humans.

Mutagenic effects: Mutagenicity studies on various animals, bacteria, and plants indicate that chlorothalonil does not

cause any genetic changes. The compound is not expected to pose mutagenic risks to humans.

Carcinogenic effects: Based on evidence from animal studies, chlorothalonil's carcinogenic potential is unclear.

Male and female rats fed chlorothalonil daily over a lifetime developed carcinogenic and benign kidney tumours at the

higher doses. In another study, where mice were fed high daily doses of chlorothalonil for 2 years, females developed

tumours in the fore-stomach area (attributed to irritation by the compound) and males developed carcinogenic and

benign kidney tumours.

Organ toxicity: Chronic studies of rats and dogs fed high dietary levels show that chlorothalonil is toxic to the kidney.

In addition to less urine output, changes in the kidney included enlargement, greenish-brown colour, and development

of small grains.

Fate in humans and animals: Chlorothalonil is rapidly excreted, primarily unchanged, from the body. It is not stored

in animal tissues. Residues have not been found in the tissues or milk of dairy cows fed chlorothalonil.

Classification of Hazardous Ingredients

Ingredient

Risk Phrases

Chlorothalonil:

Conc>=20%: T+; R40; R26; R37; R41; R43

SECTION 12 - ECOLOGICAL INFORMATION

Very toxic to aquatic organisms, may cause long-term adverse effects to the aquatic environment. Insufficient data to

be sure of status.

Effects on birds: Chlorothalonil is practically nontoxic to birds. Most avian wildlife are not significantly affected by this

compound.

Effects on aquatic organisms: Chlorothalonil and its metabolites are highly toxic to fish, aquatic invertebrates, and

marine organisms. Fish, such as rainbow trout, bluegill, and channel catfish are noticeably affected even when

chlorothalonil levels are low (less than 1 mg/L). Its bioaccumulation factor is quite low.

Effects on other organisms: The compound is nontoxic to bees.

Product Name: Whack 500 Fungicide

Page: 6 of 7

SDS Date: April, 2014

SAFETY DATA SHEET

Issued by: Imtrade Australia Pty Ltd

Phone: 1800 171 799

Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)

Environmental Fate:

Breakdown in soil and groundwater: Chlorothalonil is moderately persistent. In aerobic soils, the half-life is from 1

to 3 months.

Breakdown in water: In very basic water (pH 9.0), about 65% of the chlorothalonil was degraded into two major

metabolites after 10 weeks.

Breakdown in vegetation: Chlorothalonil's residues may remain on above-ground crops at harvest, but will dissipate

over time. Chlorothalonil is a fairly persistent fungicide on plants, depending on the rate of application.

SECTION 13 - DISPOSAL CONSIDERATIONS

Disposal:

Special help is available for the disposal of Agricultural Chemicals. The product label will give general

advice regarding disposal of small quantities, and how to cleanse containers. However, for help with the collection of

unwanted rural chemicals, contact ChemClear 1800 008 182 http://www.chemclear.com.au/ and for help with the

disposal of empty drums, contact DrumMuster http://www.drummuster.com.au/ where you will find contact details for

your area.

SECTION 14 - TRANSPORT INFORMATION

Not subject to the ADG Code when transported by Road or Rail in Australia, in packages 500kg(L)

or less; or IBCs, but classed as Dangerous by IATA and IMDG when carried by Air or Sea transport

(see details below).

ADG Code:

3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.

Hazchem Code:

3Z

Special Provisions:

179, 274, AU01

Limited quantities:

ADG 7 specifies a Limited Quantity value of 5 L for this class of product.

Dangerous Goods Class:

Class 9: Miscellaneous Dangerous Goods.

Packaging Group:

Packaging Method:

P001, IBC03, LP01

Class 9 Miscellaneous Dangerous Goods shall not be loaded in the same vehicle or packed in the same freight

container with Dangerous Goods of Class 1 (Explosives).

SECTION 15 - REGULATORY INFORMATION

AICS:

All of the significant ingredients in this formulation are compliant with NICNAS regulations.

The following ingredient: chlorothalonil, is mentioned in the SUSMP.

SECTION 16 - OTHER INFORMATION

This SDS contains only safety-related information. For other data see product literature.

Acronyms:

ADG Code

Australian Code for the Transport of Dangerous Goods by Road and Rail (7

edition)

AICS

Australian Inventory of Chemical Substances

SWA

Safe Work Australia, formerly ASCC and NOHSC

CAS number

Chemical Abstracts Service Registry Number

Hazchem Code

Emergency action code of numbers and letters that provide information to emergency

services especially firefighters

IARC

International Agency for Research on Cancer

NOS

Not otherwise specified

NTP

National Toxicology Program (USA)

R-Phrase

Risk Phrase

SUSMP

Standard for the Uniform Scheduling of Medicines & Poisons

UN Number

United Nations Number

This SDS summarises our best knowledge of the health and safety hazard information on the product,

and how to safely handle and use the product in the workplace. Each user should read this SDS and

consider the information in the context of how the product will be handled and used in the workplace,

including in conjunction with other products. If clarification or further information is needed to ensure that

an appropriate risk assessment can be made the user should contact Imtrade Australia Pty Ltd, or in the

event of an emergency, 000. Our responsibility for products sold is subject to our standard terms and

conditions, a copy of which is sent to our customers and is also available on request.

Please read all labels carefully before using product.

Product Name: Whack 500 Fungicide

Page: 7 of 7

SDS Date: April, 2014

SAFETY DATA SHEET

Issued by: Imtrade Australia Pty Ltd

Phone: 1800 171 799

Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)

This SDS is prepared in accord with the SWA document “Preparation of Safety Data Sheets for Hazardous

Chemicals - Code of Practice” (December 2011)

Copyright © Kilford & Kilford Pty Ltd, April, 2014.

http://www.kilford.com.au/

Phone (02)9251 4532

End of Report

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