WATTYL PROTECTIVE AND MARINE COATINGS SEAPRO CU120 ANTIFOULING

Australia - English - APVMA (Australian Pesticides and Veterinary Medicines Authority)

Active ingredient:
COPPER PRESENT AS CUPROUS OXIDE; DIURON
Available from:
VALSPAR PAINT (AUSTRALIA) PTY LTD
INN (International Name):
Cu as cuprous oxide(543-559g/L)+diuron(62g/L)
Pharmaceutical form:
PAINT
Composition:
COPPER PRESENT AS CUPROUS OXIDE MINERAL-COPPER Active 559.0 g/L; DIURON UREA-SUBSTITUTED Active 62.0 g/L
Units in package:
1L-20L
Class:
A - Agricultural
Manufactured by:
VALSPAR PAINT
Therapeutic group:
BOAT - EXTERIOR (ANTIFOULING)
Therapeutic area:
ANTIFOULING
Therapeutic indications:
FOULING - FOR ANTIFOULING ON BOATS
Product summary:
Poison schedule: 0; Withholding period: WHP: N/A; Host/pest details: BOAT - EXTERIOR (ANTIFOULING): [FOULING - FOR ANTIFOULING ON BOATS]; Poison schedule: 0; Withholding period: ; Host/pest details: BOAT - EXTERIOR (ANTIFOULING): [FOULING - FOR ANTIFOULING ON BOATS]; A single pack, tin-free antifouling (not for aluminium boats or appendages).DO NOT use on aluminium marine craft or fittings.
Authorization status:
Registered
Authorization number:
52242
Authorization date:
2020-07-01

APVMA Label submission: front panel

File name

52242_

44578_1-20L_Biack_FRONT

_MPL_

Dimensions

150mm

120mm

Scale

Date

05/06/08

Seapro Cu120

ACTIVE

CONSTITUENTS:543-559

COPPER

prese

prous

Oxide

DIURON

single-

pack,

tin-

free, antifouling (not for aluminium boats or appendages)

BLACK

THINNER:

.....................

l7D3

ClEANER:

.. .. . .. . .. .

.......

l703

Refer

Technical

Data

Sheet:

P60.01

Contents

10

Lit res

DOM:

01/01/01

208101

!

U:>

'<T

123456

Manufactured

WATTYL

Australia

Steel

Street

Blacktown

2148

APPROVED

LABEL

Info

pest

Verified

APVMA Label submission: back panel

File

name

52242_

44578_1-20L_Biack_Back_MPL-V2a

Dimensions

200mm

lOOmm

Scale

Date

16/06/08

----------------------------------·---------------------

Seapro Cu120

WATTYL

SEAPRO

CU120

ANTIFOULING

DIRECTIONS

APPLICATIONS

ANTIFOULINGS

success

antifouling job

depends

film build

applied

that

a direct effect

life

expectancy.

Irrespective

this product is applied,

owners

responsibility

ensure

that

total

nominated

film

thickness

achieved

Depending

upon

method

appl

tion

prev

ailing

conditions

multiple

coats

necessary.

preferred

method

application is

spray.

USED

PURPOSE,

MANNER,

CONTRARY

THIS

LABEL

UNLESS

AUTHORISED

UNDER

APPROPRIATE

LEGISLATION

GENERAL

INSTRUCTIONS

complete

Mixing

Application instructions

please

read

appropr

Technical

Data

Sheet

carefully.

only

recommended

thinner.

Refer

Technical

Sheet

P60.01

PRECAUTIONS

presence

naked

flame

other

possible

sources

Ignition.

smoke.

Provide

adequate

ventilation

during application.

Avoid

breathing

vapour.

Avoid

contact

with

eyes

skin

Must

used

confined

spaces

without

extractor

organic

vapour

mask.

more

information

refer

General

Information

Sheets

1430

&

1431

Customer

Hotline

Phone

132101

APVM

Approval

Number.

52242/1

BLACK/0508

PROTECTION

WILDLIFE

FISH

CRUSTACEA

ENVIRONMENT

This

product

contains

active conslituent which, if

used

incorrectly.

have

detrimental

effects

marine

life,

contaminate

waterways

with paint,

dust

scrapings,

with

used

containers.

STORAGE

DISPOSAL

KEEP

REACH

CHILDREN

Store

original container,

tightly

closed

cool

, dry

place

re-use

empty

containers.

Dispose

container

crushing

disposing in a

icipal

disposal

site.

SAFETY

DIRESTIONS

: Harmful

swallowed.

irritate

eyes

skin

Avoid

contact

with

eyes

skin.

inhale

vapour.

When

opening

container

wear

cotton

overalls

buttoned

neck

wrist

equivalent clothing), a

washable

elbow-length rubber

gloves.

When

mixing

using

prepared

spray

wear

cotton

overalls

buttoned

neck

wrist

equivalent clothing), a

washable

, elbow -

length

gloves

goggles.

product in

eyes

wash

immediately

with

water.

Wash

hands

after

. After

each

wash

gloves,

goggles

contaminated

clothing.

Ensure

adequate

ventilati

during

use.

FIRST

poisoning

occur

contact

a doctor

Information

Centre

Phone

131126

. II s

wallowed

induce

vomiting.

Give

glass

water.

APPROVED

LABEL

APVMA Label submission: front panel

File name

52242_

44578_1-20L_Biue_FRONT

_MPL_

Dimensions

150mm

120mm

Scale

Date

05/06/08

Seapro Cu120

U120

ANTIFOULING

ACTIVE

CONSTITUENTS

543-559

COPPER

esent

Oxide

DIURON

single-

pack

tin-

free

, antifouling

(not

for aluminium

boats

appendages)

BLUE

THINNER: .......

.. . . .

....

l703

CLEANER: ..

....

.. ..

.........

L703

Refer

Technical

Data

Sheet:

P60.01

Contents

10

Lit res

DOM:

01/01/01

208102.010

123456

Manufactured

WATTYL

Australia

Ltd,

Steel

Street,

Blacktown

2148

APPROVED

LABEL

APVMA Label submission: back panel

File name

44578_1-20L

_ Biue_Back_MPL-V2a

Dimensions

200mm

lOOmm

Scale

Date

G/06/_0a

WATTYL

SEAPRO

CU120

ANTIFOULING

Seapro Cu120

DIRECTIONS

APPLICATIONS

ANTIFOULINGS

success

antifouling job

depends

film build

applied that

a direct effect

life

expectancy.

Irrespective

this

product

applied,

owners

responsibility

ensure

that

total

nominated

film thickness is

achieved.

Depending

upon

method

of application

prevailing

conditions multiple

coats

necessary.

preferred

method

application is

spray

USED

PURPOSE,

MANNER

CONTRARY

THIS

LABEL

UNLESS

AUTHORISED

UNDER

APPROPRIATE

LEGISLATION

GENERAL

INSTRUCTIONS

complete

Mixing

Application instructions

please

read

appropriate

Technical

Data

Sheet

carefully.

only

recommended

thinner.

Refer

Technical

Sheet

P60.01

PRECAUTIONS

presence

naked

flame

other possible

sources

ignition.

smoke

Provide

adequate

ventilation

during application.

Avoid

breathing

vapour.

Avoid

contact

with

eyes

skin.

Must

used

confined

spaces

without

extractor

organic

vapour

mask

more

information

refe

General

Information

Sheets

1430

&

1431

Customer

Hotline

Phone

132101

APVM

Approval

Number

52242/1

BLUE/0508

PROTECTION

WILDLIFE

FISH

CRUSTACEA

ENVIRONMENT

is product

contains

constituent

which,

used

incorrectly,

have

detrimental effects

life,

contaminate

waterways

with paint,

dust

scrapings,

used

containers

STORAGE

DISPOSAL

KEEP

REACH

CHILDREN.

Store

origi

container,

lightly

closed

, in a

cool

place

re-use

empty

containers

Dispose

container

crushing

disposing

municipal

disposal

site.

SAFETY

DIRESTIONS

: Harmful

swallowed

irritate

eyes

skin

Avoid

contact

with

eyes

skin

nhale

vapour.

When

opening

container

wear

cotton

overalls

buttoned

neck

wrist

equivalent clothing), a

washable

elbow

-length rubber

gloves.

When

mixing

using

prepared

spray

wear

cotton

overalls

buttoned

neck

wrist

equivalent clothing), a

washable

hat,

elbow

-length

rubber

love

goggles.

product in

eyes

wash

immediately

with

water

Wash

hands

alter

. Alter

each

wash

gloves

goggles

contaminated

clothing.

Ensure

adequate

ventilation during

FIRST

poisoning

occurs

contact

a doctor

Poisons

Information

Centre.

Phone

131126

swallowed,

induce

vomit

Give

glass

water

APPROVED

LABEL

APVMA Label submission: front panel

52242_

44578_1-

20L_Brown_FRONT

_M PL_

Dimensions

150mm

120mm

Scale

05/06/08

Seapro Cu120

BROWN

THINNER:

........

. .. .

......

....

l703

CLEANER:

.......

........

l703

Refer

Technical

Data

Sheet:

P60.01

Contents 10 Litres

DOM:

01/01/01

Resource:

208103.010

(J'>

123456

Manufactured

WATTYL

Australia

ltd, 4

Steel

Street,

Blacktown

2148

APPROVED

LABEL

APVMA Label submission: back panel

File

name

52242_

44578

1-20L

Brown_Back_MPL

-V2a

Dimensions

200mm

100mm

Scale

-------------

Date

16/06/0

WATTYL

SEAPRO

CU120

ANTIFOULING

Seapro Cu120

DIRECTIONS

APPLICATIONS

ANTIFOULINGS

success

antifouling job

depends

film build

applied that

a direct effect

life

expectancy

Irrespective

this

product

is applied, it is

owners

responsibility

ensure

that

total

nominated

film

thickness

achieved.

Depending

upon

method

application

prevaili

conditions multiple

coats

necessary

preferred

method

application is

spray.

USED

PURPOSE

MANNER

CONTRARY

THIS

LABEL

UNLESS

AUTHORISED

UNDER

APPROPRIATE

LEGISLATION

GENERAL

INSTRUCTIONS

complete

Mixing

Application inslruclions

please

read

appropr

Technical

Data

Sheet

carefully.

only

recommended

thinner.

Refer

Technical

Sheet

P60.01

PRECAUnONS

esence

naked

flame

other

possible

sources

ignition.

smoke

Provide

adequate

ventilation

during application.

Avoid

breathing

vapour

Avoid

contact

with

eyes

skin

Must

used

confined

spaces

without t

extractor

organic

vapour

mask

more

inlormation

refer

General

Information

Sheets

1430

&

1431

Customer

Hotline

Phone

132101

APVM

Approval

Number

. 52242/1-20

BROWN/0508

PROTECTION

WILDLIFE

FISH

CRUSTACEA

ENVIRONMENT

This

product

contains

active constituent

which

used

incorrectly,

have

rimental

effects

marine

life,

contaminate

waterways

with

paint,

dust

scrapings

with

used

containers

STORAGE

DISPOSAL

KEEP

REACH

CHILDREN

Store

original container,

tightly

closed

cool

place

re-use

empty

containers

Dispose

container

crushing

disposing

in a

municipal disposal site.

SAFETY

DIRESTIONS:

Harmful

swallowed.

irritate

eyes

skin

Avoid

contact

with

eyes

skin.

inha

vapour

When

opening

container

wear

cotton

overalls

buttoned

neck

wrist

equivalent

othing)

washable

elbow

-length

rubber

gloves.

When

mixing

using

prepared

spray

wear

cotton

overalls

buttoned

neck

wrist

equivalent clothing), a

washable

elbow

-length

rubber

gloves

goggles

product

eyes

wash

immediately with

water.

Wash

hands

after

. Aller

each

wash

gloves,

goggles

contam

nated

clothing.

Ensure

adequate

ventilation during

FIRST

poisoning

occurs,

contact

a doctor

Poisons

Information

Centre

Phone

131126

swallowed,

induce

vomiting.

Give

glass

water.

APPROVED

LABEL

APVMA Label submission: front panel

File

name

52242_

44578_1-20L_Red_FRONT

_MPL_

Dimensions

150mm

120mm

Scale

Date

05/06/08

Seapro Cu120

SEAPRO

CU120

ANTIFOULING

ACTIVE

CONSTITUENTS

543-559

COPPER

present

Cuprous

Oxide

DIURON

single-

pack,

tin-

free, antifouling (not for aluminium boats or appendages)

RED

THINNER: ..

.....

.....

.. . .. ..

....

L703

CLEANER:

. .. . . . .. .

. .

....

L703

Refer

Technical

Data

Sheet

P60.

Contents

10

Lit res

01/01/01

208104.010

o,!)

123456

Manufactured

WATTYL

Australia

, 4 St

Stree

Blacktown

2148

APPROVED

LABEL

File

name

Dimensions

Scale

Date

Seapro Cu120

APVMA Label submission: back panel

52242_

44578

20L_Red_Back_MPL

-V2a

_m_m_

_m_m_

-----

16/06/08

__

}

WATTYL

SEAPRO

CU120

ANTIFOULING

DIRECTIONS

APPLICATIONS

ANTIFOULINGS

success

antilouling

depends

film build

applied

that

a direct effect

life

expectancy

Irrespective

this product is

applied

owners

responsibility

ensure

that

total

nominated

film thickness is

achieved.

Depending

upon

method

application

prevailing

conditions multiple

coats

necessary

preferred

method

application is

spray.

USED

PURPOSE

MANNER,

CONTRARY

THIS

LABEL

UNLESS

AUTHORISED

UNDER

APPROPRIATE

LEGISLATION

GENERAL

INSTRUCTIONS

complete

Mixing

Application instructions

please

read

appropriate

Technical

Data

Sheet

carefully.

only

recommended

thinner.

Refer

Technical

Sheet

PRECAUTIONS

presence

naked

flame

other possible

sources

ignition.

smoke

Provide

adequate

ventilation

during application.

Avoid

breathing

vapour

Avoid

contact

with

eyes

skin.

Must

used

confined

spaces

without

extractor

organic

vapour

mask.

more

information

refer

General

Information

Sheets.

1430

&

1431

Customer

Hotline

Phone

132101

APVM

Approval

Number

. 52242/1-20

RED/0508

PROTECTION

WILDLIFE

FISH

CRUSTACEA

ENVIRONMENT

This

product

contains

active constituent

which

, if

used

incorrectly,

have

detrimental

effects

marine life,

contaminate

waterways

with

paint,

dust

scrapings,

with

used

containers.

STORAGE

DISPOSAL

KEEP

REACH

CHILDREN

Store

original container,

tightly

closed,

cool

, dry

place.

NOTre-

empty

containers.

Dispose

container

crushing

disposing

municipal

disposal

site.

SAFETY

DIRESTIONS:

Harmful

swallowed

irritate

eyes

skin.

Avoid

contact

with

eyes

skin.

inhale

vapour

When

opening

container

wear

cotton

overalls

buttoned

neck

wrist (or equivalent clothing), a

washable

elbow

length

rubber

gloves.

When

mixing

using

prepared

spray

wear

cotton

overalls

buttoned

neck

wrist

equivalent clothing), a

washable

, elbow-length rubber

gloves

goggles

. II

product

eyes

wash

immediately with

water

Wash

hands

after

. Alter

each

wash

gloves

goggles

contaminated

clothing.

Ensure

adequate

ventilation during

FIRST

AID:

poisoning

occurs,

contact

a doctor

Poisons

Information

Centre

Phone

131126

swallowed

induce

vomiting.

Give

glass

water.

APPROVED

LABEL

Wattyl (Valspar Paint (Australia))

Chemwatch Hazard Alert Code: 3

Wattyl Seapro CU120 Antifouling MCR

Chemwatch: 8073-10

Version No: 8.1.1.1

Safety Data Sheet according to WHS and ADG requirements

Issue Date: 09/01/2014

Print Date: 09/03/2016

Initial Date: Not Available

S.GHS.AUS.EN

SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING

Product Identifier

Product name

Wattyl Seapro CU120 Antifouling MCR

Synonyms

Seapro CU120 Antifouling MCR

Proper shipping name

PAINT (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED

MATERIAL (including paint thinning or reducing compound)

Other means of

identification

Not Available

Relevant identified uses of the substance or mixture and uses advised against

Relevant identified

uses

Use according to manufacturer's directions.

The use of a quantity of material in an unventilated or confined space may result in increased exposure and an irritating

atmosphere developing. Before starting consider control of exposure by mechanical ventilation.

Details of the supplier of the safety data sheet

Registered company

name

Wattyl (Valspar Paint (Australia))

Address

Level 4, 2 Burbank Place Baulkham Hills 2153 NSW Australia

Telephone

+61 2 8867 3333

Fax

+61 2 8867 3344

Website

Not Available

Email

Not Available

Emergency telephone number

Association /

Organisation

Not Available

Emergency telephone

numbers

1800 039 008

Other emergency

telephone numbers

1800 039 008

SECTION 2 HAZARDS IDENTIFICATION

Classification of the substance or mixture

HAZARDOUS CHEMICAL. DANGEROUS GOODS. According to the WHS Regulations and the ADG Code.

CHEMWATCH HAZARD RATINGS

Flammability

3

Toxicity

2

Body Contact

2

Reactivity

1

Chronic

2

0 = Minimum

1 = Low

2 = Moderate

3 = High

4 = Extreme

Poisons Schedule

Continued...

Classification

[1]

Flammable Liquid Category 2, Acute Toxicity (Oral) Category 4, Acute Toxicity (Dermal) Category 4, Acute Toxicity

(Inhalation) Category 4, Carcinogenicity Category 2, Chronic Aquatic Hazard Category 1

Legend:

1. Classified by Chemwatch; 2. Classification drawn from HSIS ; 3. Classification drawn from EC Directive 1272/2008 - Annex

Label elements

GHS label elements

SIGNAL WORD

DANGER

Hazard statement(s)

H225

Highly flammable liquid and vapour.

H302

Harmful if swallowed.

H312

Harmful in contact with skin.

H332

Harmful if inhaled.

H351

Suspected of causing cancer.

H410

Very toxic to aquatic life.

Precautionary statement(s) Prevention

P201

Obtain special instructions before use.

P210

Keep away from heat/sparks/open flames/hot surfaces. - No smoking.

P233

Keep container tightly closed.

P271

Use only outdoors or in a well-ventilated area.

Precautionary statement(s) Response

P308+P313

IF exposed or concerned: Get medical advice/attention.

P363

Wash contaminated clothing before reuse.

P370+P378

In case of fire: Use alcohol resistant foam or normal protein foam for extinction.

P391

Collect spillage.

Precautionary statement(s) Storage

P403+P235

Store in a well-ventilated place. Keep cool.

P405

Store locked up.

Precautionary statement(s) Disposal

P501

Dispose of contents/container in accordance with local regulations.

SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS

Substances

See section below for composition of Mixtures

Mixtures

CAS No

%[weight]

Name

1317-39-1

30-60

Not Available

10-30

resins, unregulated

1330-20-7

5-15

Not avail.

25154-85-2

1335-30-4

Not Available

zinc oxide

330-54-1

copper(I) oxide

xylene

aromatic solvent 100

vinyl chloride/ vinyl isobutylether copolymer

aluminium silicate hydrated

diuron

Chemwatch: 8073-10

Version No: 8.1.1.1

Page 2 of 14

Wattyl Seapro CU120 Antifouling MCR

Issue Date: 09/01/2014

Print Date: 09/03/2016

Continued...

Not Available

pigments, including

13463-67-7

Not Available

ingredients not contributing to the classification

Not Available

NotSpec.

contains less than 0.1% benzene

SECTION 4 FIRST AID MEASURES

Description of first aid measures

Eye Contact

If this product comes in contact with the eyes:

Wash out immediately with fresh running water.

Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally

lifting the upper and lower lids.

Seek medical attention without delay; if pain persists or recurs seek medical attention.

Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.

Skin Contact

If skin contact occurs:

Immediately remove all contaminated clothing, including footwear.

Flush skin and hair with running water (and soap if available).

Seek medical attention in event of irritation.

Inhalation

If fumes or combustion products are inhaled remove from contaminated area.

Lay patient down. Keep warm and rested.

Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid

procedures.

Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket

mask as trained. Perform CPR if necessary.

Transport to hospital, or doctor.

Ingestion

For advice, contact a Poisons Information Centre or a doctor at once.

Urgent hospital treatment is likely to be needed.

If swallowed do NOT induce vomiting.

If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and

prevent aspiration.

Observe the patient carefully.

Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious.

Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink.

Transport to hospital or doctor without delay.

Indication of any immediate medical attention and special treatment needed

For acute or short term repeated exposures to petroleum distillates or related hydrocarbons:

Primary threat to life, from pure petroleum distillate ingestion and/or inhalation, is respiratory failure.

Patients should be quickly evaluated for signs of respiratory distress (e.g. cyanosis, tachypnoea, intercostal retraction, obtundation) and given oxygen.

Patients with inadequate tidal volumes or poor arterial blood gases (pO2 50 mm Hg) should be intubated.

Arrhythmias complicate some hydrocarbon ingestion and/or inhalation and electrocardiographic evidence of myocardial injury has been reported;

intravenous lines and cardiac monitors should be established in obviously symptomatic patients. The lungs excrete inhaled solvents, so that

hyperventilation improves clearance.

A chest x-ray should be taken immediately after stabilisation of breathing and circulation to document aspiration and detect the presence of

pneumothorax.

Epinephrine (adrenalin) is not recommended for treatment of bronchospasm because of potential myocardial sensitisation to catecholamines. Inhaled

cardioselective bronchodilators (e.g. Alupent, Salbutamol) are the preferred agents, with aminophylline a second choice.

Lavage is indicated in patients who require decontamination; ensure use of cuffed endotracheal tube in adult patients. [Ellenhorn and Barceloux: Medical

Toxicology]

for copper intoxication:

Unless extensive vomiting has occurred empty the stomach by lavage with water, milk, sodium bicarbonate solution or a 0.1% solution of potassium

ferrocyanide (the resulting copper ferrocyanide is insoluble).

Administer egg white and other demulcents.

Maintain electrolyte and fluid balances.

Morphine or meperidine (Demerol) may be necessary for control of pain.

If symptoms persist or intensify (especially circulatory collapse or cerebral disturbances, try BAL intramuscularly or penicillamine in accordance with

the supplier's recommendations.

Treat shock vigorously with blood transfusions and perhaps vasopressor amines.

If intravascular haemolysis becomes evident protect the kidneys by maintaining a diuresis with mannitol and perhaps by alkalinising the urine with

sodium bicarbonate.

It is unlikely that methylene blue would be effective against the occassional methaemoglobinemia and it might exacerbate the subsequent haemolytic

episode.

Institute measures for impending renal and hepatic failure.

[GOSSELIN, SMITH & HODGE: Commercial Toxicology of Commercial Products]

A role for activated for charcoals or emesis is, as yet, unproven.

In severe poisoning CaNa2EDTA has been proposed.

[ELLENHORN & BARCELOUX: Medical Toxicology]

titanium dioxide

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SECTION 5 FIREFIGHTING MEASURES

Extinguishing media

Water spray or fog.

Alcohol stable foam.

Dry chemical powder.

Carbon dioxide.

Do not use a water jet to fight fire.

Special hazards arising from the substrate or mixture

Fire Incompatibility

Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may

result

Advice for firefighters

Fire Fighting

Alert Fire Brigade and tell them location and nature of hazard.

May be violently or explosively reactive.

Wear breathing apparatus plus protective gloves in the event of a fire.

Prevent, by any means available, spillage from entering drains or water course.

Fire/Explosion Hazard

Liquid and vapour are highly flammable.

Severe fire hazard when exposed to heat, flame and/or oxidisers.

Vapour may travel a considerable distance to source of ignition.

Heating may cause expansion or decomposition leading to violent rupture of containers.

Combustion products include:, carbon dioxide (CO2), hydrogen chloride, phosgene, other pyrolysis products typical of burning

organic material

SECTION 6 ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Minor Spills

Remove all ignition sources.

Clean up all spills immediately.

Avoid breathing vapours and contact with skin and eyes.

Control personal contact with the substance, by using protective equipment.

Major Spills

Clear area of personnel and move upwind.

Alert Fire Brigade and tell them location and nature of hazard.

May be violently or explosively reactive.

Wear breathing apparatus plus protective gloves.

Personal Protective Equipment advice is contained in Section 8 of the SDS.

SECTION 7 HANDLING AND STORAGE

Precautions for safe handling

Safe handling

Avoid all personal contact, including inhalation.

Wear protective clothing when risk of exposure occurs.

Use in a well-ventilated area.

Prevent concentration in hollows and sumps.

DO NOT allow clothing wet with material to stay in contact with skin

Other information

Store in original containers in approved flame-proof area.

No smoking, naked lights, heat or ignition sources.

DO NOT store in pits, depressions, basements or areas where vapours may be trapped.

Keep containers securely sealed.

Conditions for safe storage, including any incompatibilities

Suitable container

Packing as supplied by manufacturer.

Plastic containers may only be used if approved for flammable liquid.

Check that containers are clearly labelled and free from leaks.

For low viscosity materials (i) : Drums and jerry cans must be of the non-removable head type. (ii) : Where a can is to be

used as an inner package, the can must have a screwed enclosure.

For materials with a viscosity of at least 2680 cSt. (23 deg. C)

For manufactured product having a viscosity of at least 250 cSt.

Storage

incompatibility

Avoid reaction with oxidising agents

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SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION

Control parameters

OCCUPATIONAL EXPOSURE LIMITS (OEL)

INGREDIENT DATA

Source

Ingredient

Material name

TWA

STEL

Peak

Notes

Australia Exposure

Standards

xylene

Xylene (o-, m-, p-

isomers)

350 mg/m3 / 80

655 mg/m3 / 150

Available

Available

Australia Exposure

Standards

diuron

Diuron

10 mg/m3

Not Available

Available

Available

Australia Exposure

Standards

titanium

dioxide

Titanium dioxide

10 mg/m3

Not Available

Available

Available

EMERGENCY LIMITS

Ingredient

Material name

TEEL-1

TEEL-2

TEEL-3

copper(I) oxide

Copper oxide; (Copper(I) oxide)

0.6 mg/m3

16 mg/m3

93 mg/m3

xylene

Xylenes

Not Available

Not Available

Not Available

titanium dioxide

Titanium oxide; (Titanium dioxide)

10 mg/m3

10 mg/m3

10 mg/m3

Ingredient

Original IDLH

Revised IDLH

copper(I) oxide

Not Available

Not Available

resins, unregulated

Not Available

Not Available

xylene

1,000 ppm

900 ppm

aromatic solvent 100

Not Available

Not Available

vinyl chloride/ vinyl

isobutylether copolymer

Not Available

Not Available

aluminium silicate

hydrated

Not Available

Not Available

zinc oxide

Not Available

Not Available

diuron

Not Available

Not Available

pigments, including

Not Available

Not Available

titanium dioxide

N.E. mg/m3 / N.E. ppm

5,000 mg/m3

ingredients not

contributing to the

classification

Not Available

Not Available

contains less than 0.1%

benzene

Not Available

Not Available

Exposure controls

Appropriate

engineering controls

Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed

engineering controls can be highly effective in protecting workers and will typically be independent of worker interactions to

provide this high level of protection.

The basic types of engineering controls are:

Process controls which involve changing the way a job activity or process is done to reduce the risk.

Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker and

ventilation that strategically "adds" and "removes" air in the work environment.

Personal protection

Eye and face

protection

Safety glasses with side shields.

Chemical goggles.

Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy

document, describing the wearing of lenses or restrictions on use, should be created for each workplace or task.

Skin protection

See Hand protection below

Hands/feet protection

Wear chemical protective gloves, e.g. PVC.

Wear safety footwear or safety gumboots, e.g. Rubber

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Body protection

See Other protection below

Other protection

Overalls.

PVC Apron.

PVC protective suit may be required if exposure severe.

Eyewash unit.

Thermal hazards

Not Available

Recommended material(s)

GLOVE SELECTION INDEX

Glove selection is based on a modified presentation of the:

"

Forsberg Clothing Performance Index".

The effect(s) of the following substance(s) are taken into account in the

computer-generated

selection:

Wattyl Seapro CU120 Antifouling MCR

Material

CPI

PE/EVAL/PE

TEFLON

VITON

BUTYL

BUTYL/NEOPRENE

HYPALON

NAT+NEOPR+NITRILE

NATURAL+NEOPRENE

NEOPRENE

NEOPRENE/NATURAL

NITRILE

NITRILE+PVC

PVDC/PE/PVDC

* CPI - Chemwatch Performance Index

A: Best Selection

B: Satisfactory; may degrade after 4 hours continuous immersion

C: Poor to Dangerous Choice for other than short term immersion

NOTE: As a series of factors will influence the actual performance of the

glove, a final selection must be based on detailed observation. -

* Where the glove is to be used on a short term, casual or infrequent

basis, factors such as "feel" or convenience (e.g. disposability), may

dictate a choice of gloves which might otherwise be unsuitable following

long-term or frequent use. A qualified practitioner should be consulted.

Respiratory protection

Type A-P Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000

& 149:2001, ANSI Z88 or national equivalent)

Where the concentration of gas/particulates in the breathing zone,

approaches or exceeds the "Exposure Standard" (or ES), respiratory

protection is required.

Degree of protection varies with both face-piece and Class of filter; the

nature of protection varies with Type of filter.

Required

Minimum

Protection Factor

Half-Face

Respirator

Full-Face

Respirator

Powered Air

Respirator

up to 10 x ES

A-AUS / Class

1 P3

A-PAPR-AUS /

Class 1 P3

up to 50 x ES

Air-line*

up to 100 x ES

A-3 P3

100+ x ES

Air-line**

* - Continuous-flow; ** - Continuous-flow or positive pressure demand

A(All classes) = Organic vapours, B AUS or B1 = Acid gasses, B2 = Acid

gas or hydrogen cyanide(HCN), B3 = Acid gas or hydrogen cyanide(HCN),

E = Sulfur dioxide(SO2), G = Agricultural chemicals, K = Ammonia(NH3),

Hg = Mercury, NO = Oxides of nitrogen, MB = Methyl bromide, AX = Low

boiling point organic compounds(below 65 degC)

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties

Appearance

Coloured flammable liquid with a hydrocarbon solvent odour; not miscible with water.

Physical state

Liquid

Relative density

(Water = 1)

1.60-1.65

Odour

Not Available

Partition coefficient

n-octanol / water

Not Available

Odour threshold

Not Available

Auto-ignition

temperature (°C)

pH (as supplied)

Not Applicable

Decomposition

temperature

Not Available

Melting point /

freezing point (°C)

Not Available

Viscosity (cSt)

Not Available

Initial boiling point

and boiling range (°C)

138-170

Molecular weight

(g/mol)

Not Applicable

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Flash point (°C)

Taste

Not Available

Evaporation rate

Not Available

Explosive properties

Not Available

Flammability

HIGHLY FLAMMABLE.

Oxidising properties

Not Available

Upper Explosive Limit

(%)

Surface Tension

(dyn/cm or mN/m)

Not Available

Lower Explosive Limit

(%)

Volatile Component

(%vol)

25-30

Vapour pressure (kPa)

Not Available

Gas group

Not Available

Solubility in water

(g/L)

Immiscible

pH as a solution (1%)

Not Applicable

Vapour density (Air =

1)

>1.0

VOC g/L

Not Available

SECTION 10 STABILITY AND REACTIVITY

Reactivity

See section 7

Chemical stability

Unstable in the presence of incompatible materials.

Product is considered stable.

Hazardous polymerisation will not occur.

Possibility of

hazardous reactions

See section 7

Conditions to avoid

See section 7

Incompatible materials

See section 7

Hazardous

decomposition

products

See section 5

SECTION 11 TOXICOLOGICAL INFORMATION

Information on toxicological effects

Inhaled

Inhalation of aerosols (mists, fumes), generated by the material during the course of normal handling, may be harmful.

Xylene is a central nervous system depressant

Headache, fatigue, tiredness, irritability and digestive disturbances (nausea, loss of appetite and bloating) are the most

common symptoms of xylene overexposure. Injury to the heart, liver, kidneys and nervous system has also been noted

amongst workers.

If exposure to highly concentrated solvent atmosphere is prolonged this may lead to narcosis, unconsciousness, even coma

and possible death.

Ingestion

Accidental ingestion of the material may be harmful; animal experiments indicate that ingestion of less than 150 gram may

be fatal or may produce serious damage to the health of the individual.

A metallic taste, nausea, vomiting and burning feeling in the upper stomach region occur after ingestion of copper and its

derivatives. The vomitus is usually green/blue and discolours contaminated skin.

Considered an unlikely route of entry in commercial/industrial environments. The liquid may produce gastrointestinal

discomfort and may be harmful if swallowed.

Skin Contact

Skin contact with the material may be harmful; systemic effects may result following absorption.

This material can cause inflammation of the skin on contact in some persons.

The material may accentuate any pre-existing dermatitis condition

Open cuts, abraded or irritated skin should not be exposed to this material

Exposure to copper, by skin, has come from its use in pigments, ointments, ornaments, jewellery, dental amalgams and

IUDs (intra-uterine devices), and in killing fungi and algae. Although copper is used in the treatment of water in swimming

pools and reservoirs, there are no reports of toxicity from these applications.

The material may cause skin irritation after prolonged or repeated exposure and may produce on contact skin redness,

swelling, the production of vesicles, scaling and thickening of the skin.

Eye

There is some evidence to suggest that this material can cause eye irritation and damage in some persons.

Chronic

Substance accumulation, in the human body, may occur and may cause some concern following repeated or long-term

occupational exposure.

There has been some concern that this material can cause cancer or mutations but there is not enough data to make an

assessment.

There is some evidence from animal testing that exposure to this material may result in toxic effects to the unborn baby.

Exposure to the material for prolonged periods may cause physical defects in the developing embryo (teratogenesis).

Chronic solvent inhalation exposures may result in nervous system impairment and liver and blood changes. [PATTYS]

Women exposed to xylene in the first 3 months of pregnancy showed a slightly increased risk of miscarriage and birth

defects. Evaluation of workers chronically exposed to xylene has demonstrated lack of genetic toxicity.

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Antifouling MCR

TOXICITY

IRRITATION

Not Available

Not Available

copper(I) oxide

TOXICITY

IRRITATION

dermal (rat) LD50: >2000 mg/kg

Nil reported

Inhalation (rat) LC50: >200 mg/l1 h

Inhalation (rat) LC50: >30 mg/l4 h

Inhalation (rat) LC50: >5 mg/l4.5 h

Inhalation (rat) LC50: 2.92 mg/l4 h

Inhalation (rat) LC50: 3.34 mg/l4 h

Inhalation (rat) LC50: 3.69 mg/l4 h

Inhalation (rat) LC50: ca.5.63 mg/l4 h

Oral (rat) LD50: 470 mg/kgd

xylene

TOXICITY

IRRITATION

Dermal (rabbit) LD50: >1700 mg/kg

Eye (human): 200 ppm irritant

Inhalation (rat) LC50: 5000 ppm/4h

Eye (rabbit): 5 mg/24h SEVERE

Oral (rat) LD50: 4300 mg/kgt

Eye (rabbit): 87 mg mild

Skin (rabbit):500 mg/24h moderate

aromatic solvent 100

TOXICITY

IRRITATION

Not Available

Not Available

vinyl chloride/ vinyl

isobutylether

copolymer

TOXICITY

IRRITATION

Not Available

Not Available

aluminium silicate

hydrated

TOXICITY

IRRITATION

Dermal (rabbit) LD50: >2000 mg/kg

Not Available

Oral (rat) LD50: >2000 mg/kg

diuron

TOXICITY

IRRITATION

dermal (rat) LD50: >5000 mg/kg

Nil reported

Oral (rat) LD50: 1000 mg/kg

titanium dioxide

TOXICITY

IRRITATION

Inhalation (rat) LC50: >2.28 mg/l4 h

Skin (human): 0.3 mg /3D (int)-mild *

Inhalation (rat) LC50: >3.56 mg/l4 h

Inhalation (rat) LC50: >6.82 mg/l4 h

Inhalation (rat) LC50: 3.43 mg/l4 h

Inhalation (rat) LC50: 5.09 mg/l4 h

Oral (rat) LD50: >2000 mg/kg

Legend:

1. Value obtained from Europe ECHA Registered Substances - Acute toxicity 2.* Value obtained from manufacturer's SDS.

Unless otherwise specified data extracted from RTECS - Register of Toxic Effect of chemical Substances

XYLENE

The material may produce severe irritation to the eye causing pronounced inflammation. Repeated or prolonged exposure to

irritants may produce conjunctivitis.

The material may cause skin irritation after prolonged or repeated exposure and may produce on contact skin redness,

swelling, the production of vesicles, scaling and thickening of the skin.

The substance is classified by IARC as Group 3:

NOT classifiable as to its carcinogenicity to humans.

Evidence of carcinogenicity may be inadequate or limited in animal testing.

Reproductive effector in rats

AROMATIC SOLVENT

100

Asthma-like symptoms may continue for months or even years after exposure to the material ceases. This may be due to a

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Legend:

– Data available but does not fill the criteria for classification

– Data required to make classification available

– Data Not Available to make classification

non-allergenic condition known as reactive airways dysfunction syndrome (RADS) which can occur following exposure to high

levels of highly irritating compound. Key criteria for the diagnosis of RADS include the absence of preceding respiratory

disease, in a non-atopic individual, with abrupt onset of persistent asthma-like symptoms within minutes to hours of a

documented exposure to the irritant. A reversible airflow pattern, on spirometry, with the presence of moderate to severe

bronchial hyperreactivity on methacholine challenge testing and the lack of minimal lymphocytic inflammation, without

eosinophilia, have also been included in the criteria for diagnosis of RADS.

For trimethylbenzenes:

Absorption of 1,2,4-trimethylbenzene occurs after oral, inhalation, or dermal exposure. Occupationally, inhalation and dermal

exposures are the most important routes of absorption although systemic intoxication from dermal absorption is not likely to

occur due to the dermal irritation caused by the chemical prompting quick removal. Following oral administration of the

chemical to rats, 62.6% of the dose was recovered as urinary metabolites indicating substantial absorption . 1,2,4-

Trimethylbenzene is lipophilic and may accumulate in fat and fatty tissues.

for petroleum:

This product contains benzene which is known to cause acute myeloid leukaemia and n-hexane which has been shown to

metabolize to compounds which are neuropathic.

This product contains toluene. There are indications from animal studies that prolonged exposure to high concentrations of

toluene may lead to hearing loss.

This product contains ethyl benzene and naphthalene from which there is evidence of tumours in rodents

Carcinogenicity: Inhalation exposure to mice causes liver tumours, which are not considered relevant to humans.

The material may be irritating to the eye, with prolonged contact causing inflammation. Repeated or prolonged exposure to

irritants may produce conjunctivitis.

The material may cause skin irritation after prolonged or repeated exposure and may produce on contact skin redness,

swelling, the production of vesicles, scaling and thickening of the skin.

DIURON

No significant acute toxicological data identified in literature search.

Diuron is absorbed readily through the gut and lungs while uptake through the skin is more limited. It is slightly toxic to

mammals but juveniles are more susceptible than adults(18). The oral LD50 in rats is 3-4 g/kg and the dermal LD50 is > 2

g/kg(19). An early study indicated that animals fed protein-deficient diets were considerably more vulnerable to diuron

toxicity; rats fed a diet of 3% protein were five times more sensitive to diuron.

Note: Equivocal animal tumorigenic agent by RTECS criteria. NOTE: This substance may contain impurities

(tetrachlorazobenzene and tetrachloroazoxybenzene). Maximum impurity levels are proscribed under various jurisdictions ADI:

0.006 mg/kg/day NOEL: 0.625 mg/kg/day

TITANIUM DIOXIDE

The material may produce moderate eye irritation leading to inflammation. Repeated or prolonged exposure to irritants may

produce conjunctivitis.

The material may cause skin irritation after prolonged or repeated exposure and may produce on contact skin redness,

swelling, the production of vesicles, scaling and thickening of the skin.

Exposure to titanium dioxide is via inhalation, swallowing or skin contact. When inhaled, it may deposit in lung tissue and

lymph nodes causing dysfunction of the lungs and immune system. Absorption by the stomach and intestines depends on

the size of the particle. It penetrated only the outermost layer of the skin, suggesting that healthy skin may be an effective

barrier.

WARNING: This substance has been classified by the IARC as Group 2B: Possibly Carcinogenic to Humans.

* IUCLID

VINYL CHLORIDE/

VINYL

ISOBUTYLETHER

COPOLYMER &

ALUMINIUM SILICATE

HYDRATED

No significant acute toxicological data identified in literature search.

Acute Toxicity

Carcinogenicity

Skin

Irritation/Corrosion

Reproductivity

Serious Eye

Damage/Irritation

STOT - Single

Exposure

Respiratory or Skin

sensitisation

STOT - Repeated

Exposure

Mutagenicity

Aspiration Hazard

SECTION 12 ECOLOGICAL INFORMATION

Toxicity

Ingredient

Endpoint

Test Duration (hr)

Species

Value

Source

copper(I) oxide

LC50

Fish

0.0028mg/L

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copper(I) oxide

NOEC

1440

Fish

0.0022mg/L

copper(I) oxide

EC50

Crustacea

0.00352- 0.00466mg/L

copper(I) oxide

EC50

Crustacea

0.00356- 0.00513mg/L

copper(I) oxide

EC50

Algae or other aquatic plants

0.0165mg/L

xylene

EC50

Crustacea

0.711mg/L

xylene

LC50

Fish

0.0013404mg/L

xylene

EC50

Crustacea

>3.4mg/L

xylene

EC50

Algae or other aquatic plants

4.6mg/L

xylene

NOEC

Algae or other aquatic plants

0.44mg/L

aluminium silicate

hydrated

EC50

Fish

>1.4mg/L

aluminium silicate

hydrated

NOEC

Fish

<1.4mg/L

aluminium silicate

hydrated

EC50

Crustacea

>10000mg/L

aluminium silicate

hydrated

EC50

Algae or other aquatic plants

410mg/L

diuron

Algae or other aquatic plants

0.159mg/L

diuron

EC50

Algae or other aquatic plants

0.00035mg/L

diuron

EC50

Crustacea

1.4mg/L

diuron

EC50

Algae or other aquatic plants

0.00055mg/L

diuron

LC50

Fish

0.5mg/L

diuron

NOEC

Algae or other aquatic plants

0.0000005mg/L

titanium dioxide

LC50

Fish

9.214mg/L

titanium dioxide

EC50

Algae or other aquatic plants

5.83mg/L

titanium dioxide

NOEC

Fish

0.089mg/L

titanium dioxide

EC50

Crustacea

1.23mg/L

titanium dioxide

EC50

Crustacea

0.46mg/L

Legend:

Extracted from 1. IUCLID Toxicity Data 2. Europe ECHA Registered Substances - Ecotoxicological Information - Aquatic Toxicity

3. EPIWIN Suite V3.12 - Aquatic Toxicity Data (Estimated) 4. US EPA, Ecotox database - Aquatic Toxicity Data 5. ECETOC

Aquatic Hazard Assessment Data 6. NITE (Japan) - Bioconcentration Data 7. METI (Japan) - Bioconcentration Data 8. Vendor

Data

For copper:

Atmospheric Fate - Copper is unlikely to accumulate in the atmosphere due to a short residence time for airborne copper aerosols. Airborne coppers,

however, may be transported over large distances. Air Quality Standards: no data available.

Aquatic Fate: Toxicity of copper is affected by pH and hardness of water.

For copper: Ecotoxicity - Significant effects are expected on various species of microalgae, some species of macroalgae, and a range of invertebrates,

including crustaceans, gastropods and sea urchins. Copper is moderately toxic to crab and their larvae and is highly toxic to gastropods (mollusks,

including oysters, mussels and clams). In fish, the acute lethal concentrations of copper depends both on test species and exposure conditions. Waters

with high concentrations of copper can have significant effects on diatoms and sensitive invertebrates, notably cladocerans (water fleas).

For Copper: Typical foliar levels of copper are: Uncontaminated soils (0.3-250 mg/kg) ; Contaminated soils (150-450 mg/kg) ; Mining/smelting soils (6.1-25

mg/kg80 mg/kg300 mg/kg).

Terrestrial Fate: Plants - Generally, vegetation reflects soil copper levels in its foliage. This is dependent upon the bioavailability of copper and the

physiological requirements of species concerned. Crops are often more sensitive to copper than the native flora.

Drinking Water Standards: hydrocarbon total: 10 ug/l (UK max.).

Toxic to aquatic organisms.

Do NOT allow product to come in contact with surface waters or to intertidal areas below the mean high water mark. Do not contaminate water when

cleaning equipment or disposing of equipment wash-waters.

Wastes resulting from use of the product must be disposed of on site or at approved waste sites.

May cause long-term adverse effects in the aquatic environment.

DO NOT discharge into sewer or waterways.

Persistence and degradability

Ingredient

Persistence: Water/Soil

Persistence: Air

copper(I) oxide

HIGH

HIGH

xylene

HIGH (Half-life = 360 days)

LOW (Half-life = 1.83 days)

diuron

HIGH

HIGH

titanium dioxide

HIGH

HIGH

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Bioaccumulative potential

Ingredient

Bioaccumulation

copper(I) oxide

LOW (LogKOW = -2.6276)

xylene

MEDIUM (BCF = 740)

diuron

LOW (BCF = 14)

titanium dioxide

LOW (BCF = 10)

Mobility in soil

Ingredient

Mobility

copper(I) oxide

LOW (KOC = 23.74)

diuron

LOW (KOC = 136)

titanium dioxide

LOW (KOC = 23.74)

SECTION 13 DISPOSAL CONSIDERATIONS

Waste treatment methods

Product / Packaging

disposal

Consult manufacturer for recycling options and recycle where possible .

Consult State Land Waste Management Authority for disposal.

Incinerate residue at an approved site.

Recycle containers if possible, or dispose of in an authorised landfill.

Containers may still present a chemical hazard/ danger when empty.

Return to supplier for reuse/ recycling if possible.

Otherwise:

If container can not be cleaned sufficiently well to ensure that residuals do not remain or if the container cannot be used to

store the same product, then puncture containers, to prevent re-use, and bury at an authorised landfill.

Where possible retain label warnings and SDS and observe all notices pertaining to the product.

SECTION 14 TRANSPORT INFORMATION

Labels Required

Marine Pollutant

HAZCHEM

3YE

Land transport (ADG)

UN number

1263

Packing group

UN proper shipping

name

PAINT (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED

MATERIAL (including paint thinning or reducing compound)

Environmental hazard

Not Applicable

Transport hazard

class(es)

Class

Subrisk

Not Applicable

Special precautions

for user

Special provisions

163 *

Limited quantity

Air transport (ICAO-IATA / DGR)

UN number

1263

Packing group

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UN proper shipping

name

Paint (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base); Paint related

material (including paint thinning or reducing compounds)

Environmental hazard

Not Applicable

Transport hazard

class(es)

ICAO/IATA Class

ICAO / IATA Subrisk

Not Applicable

ERG Code

Special precautions

for user

Special provisions

A3 A72 A192

Cargo Only Packing Instructions

Cargo Only Maximum Qty / Pack

60 L

Passenger and Cargo Packing Instructions

Passenger and Cargo Maximum Qty / Pack

Passenger and Cargo Limited Quantity Packing Instructions

Y341

Passenger and Cargo Limited Maximum Qty / Pack

Sea transport (IMDG-Code / GGVSee)

UN number

1263

Packing group

UN proper shipping

name

PAINT (including paint, lacquer, enamel, stain, shellac solutions, varnish, polish, liquid filler and liquid lacquer base) or PAINT

RELATED MATERIAL (including paint thinning or reducing compound)

Environmental hazard

Marine Pollutant

Transport hazard

class(es)

IMDG Class

IMDG Subrisk

Not Applicable

Special precautions

for user

EMS Number

F-E, S-E

Special provisions

163 367

Limited Quantities

Transport in bulk according to Annex II of MARPOL and the IBC code

Not Applicable

SECTION 15 REGULATORY INFORMATION

Safety, health and environmental regulations / legislation specific for the substance or mixture

COPPER(I) OXIDE(1317-39-1) IS FOUND ON THE FOLLOWING REGULATORY LISTS

Australia Hazardous Substances Information System - Consolidated Lists

Australia Inventory of Chemical Substances (AICS)

XYLENE(1330-20-7) IS FOUND ON THE FOLLOWING REGULATORY LISTS

Australia Exposure Standards

Australia Hazardous Substances Information System - Consolidated Lists

Australia Inventory of Chemical Substances (AICS)

International Agency for Research on Cancer (IARC) - Agents Classified

by the IARC Monographs

AROMATIC SOLVENT 100(NOT AVAIL.) IS FOUND ON THE FOLLOWING REGULATORY LISTS

Not Applicable

VINYL CHLORIDE/ VINYL ISOBUTYLETHER COPOLYMER(25154-85-2) IS FOUND ON THE FOLLOWING REGULATORY LISTS

Australia Inventory of Chemical Substances (AICS)

ALUMINIUM SILICATE HYDRATED(1335-30-4) IS FOUND ON THE FOLLOWING REGULATORY LISTS

Australia Inventory of Chemical Substances (AICS)

DIURON(330-54-1) IS FOUND ON THE FOLLOWING REGULATORY LISTS

Australia Exposure Standards

Australia Hazardous Substances Information System - Consolidated Lists

Australia Inventory of Chemical Substances (AICS)

TITANIUM DIOXIDE(13463-67-7) IS FOUND ON THE FOLLOWING REGULATORY LISTS

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Australia Exposure Standards

Australia Inventory of Chemical Substances (AICS)

International Agency for Research on Cancer (IARC) - Agents Classified

by the IARC Monographs

National Inventory

Status

Australia - AICS

N (aromatic solvent 100)

Canada - DSL

N (aromatic solvent 100)

Canada - NDSL

N (vinyl chloride/ vinyl isobutylether copolymer; xylene; copper(I) oxide; aluminium silicate hydrated; diuron; aromatic

solvent 100)

China - IECSC

N (aromatic solvent 100)

Europe - EINEC /

ELINCS / NLP

N (vinyl chloride/ vinyl isobutylether copolymer; aromatic solvent 100)

Japan - ENCS

N (aromatic solvent 100)

Korea - KECI

N (aromatic solvent 100)

New Zealand - NZIoC

N (aromatic solvent 100)

Philippines - PICCS

N (aromatic solvent 100)

USA - TSCA

N (aromatic solvent 100)

Legend:

Y = All ingredients are on the inventory

N = Not determined or one or more ingredients are not on the inventory and are not exempt from listing(see specific ingredients

in brackets)

SECTION 16 OTHER INFORMATION

Other information

Ingredients with multiple cas numbers

Name

CAS No

copper(I) oxide

1308-76-5, 1317-39-1, 1344-70-3

aluminium silicate

hydrated

1335-30-4, 58425-86-8

titanium dioxide

100292-32-8, 101239-53-6, 116788-85-3, 12000-59-8, 12188-41-9, 12701-76-7, 12767-65-6, 12789-63-8, 1309-63-3, 1317-70-0,

1317-80-2, 1344-29-2, 13463-67-7, 185323-71-1, 185828-91-5, 188357-76-8, 188357-79-1, 195740-11-5, 221548-98-7,

224963-00-2, 246178-32-5, 252962-41-7, 37230-92-5, 37230-94-7, 37230-95-8, 37230-96-9, 39320-58-6, 39360-64-0,

39379-02-7, 416845-43-7, 494848-07-6, 494848-23-6, 494851-77-3, 494851-98-8, 55068-84-3, 55068-85-4, 552316-51-5,

62338-64-1, 767341-00-4, 97929-50-5, 98084-96-9

Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the

Chemwatch Classification committee using available literature references.

A list of reference resources used to assist the committee may be found at:

www.chemwatch.net

The SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are

Risks in the workplace or other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or

available engineering controls must be considered.

Definitions and abbreviations

TWA: Permissible Concentration-Time Weighted Average

STEL: Permissible Concentration-Short Term Exposure Limit

IARC: International Agency for Research on Cancer

ACGIH: American Conference of Governmental Industrial Hygienists

STEL: Short Term Exposure Limit

TEEL: Temporary Emergency Exposure Limit

IDLH: Immediately Dangerous to Life or Health Concentrations

OSF: Odour Safety Factor

NOAEL :No Observed Adverse Effect Level

LOAEL: Lowest Observed Adverse Effect Level

TLV: Threshold Limit Value

LOD: Limit Of Detection

OTV: Odour Threshold Value

BCF: BioConcentration Factors

BEI: Biological Exposure Index

This document is copyright.

Apart from any fair dealing for the purposes of private study, research, review or criticism, as permitted under the Copyright Act, no part may be

reproduced by any process without written permission from CHEMWATCH.

TEL (+61 3) 9572 4700.

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end of SDS

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