TRIFOLAMINE SELECTIVE HERBICIDE

Australia - English - APVMA (Australian Pesticides and Veterinary Medicines Authority)

Active ingredient:
2,4-DB as dma(500g/L)
Available from:
CROP CARE
INN (International Name):
2,4-DB as dma(500g/L)
Pharmaceutical form:
Suspension
Units in package:
5L, 10L, 20L
Class:
AgChem
Therapeutic group:
BARLEY - UNDERSOWN(CLOVER,LUCERNE,MEDIC) | CEREAL - UNDERSOWN WITH MEDIC AND CLOVER | LEGUME CROP | LUCERNE - ESTABLISHED | LUCE
Therapeutic area:
Group I Herbicide
Therapeutic indications:
BATHURST BURR | CALIFORNIAN BURR | CAPEWEED | CHARLOCK | DOCK - SEEDLING | EVENING PRIMROSE | FAT HEN | FUMITORY | HEDGE OR WILD MUSTARD | MARSH OR SMALLFLOWER MALLOW | MEXICAN POPPY | NOOGOORA BURR | PATERSON'S CURSE | PLANTAIN | PRICKLY LETTUCE | SAFFRON THISTLE | SHEPHERD'S PURSE | SLENDER, SHORE OR SHEEP THISTLE | SOLDIER THISTLE | SOW OR MILK THISTLE | SPEAR OR BLACK THISTLE | STINGING OR DWARF NETTLE | THREE CORNERED JACK OR DOUBLEGEE | TURNIP WEED | VARIEGATED THISTLE | WILD OR MEDITERRANEAN TURNIP | WIREWEED, KNOTWEED OR HOGWEED | ANNUAL DWARF NETTLE | ANNUAL NETTLE | BLESSED THISTLE | BRASSICA KABER | BRASSICA SINAPISTRUM | BROADLEAF DOCK SEEDLING | BULL THISTLE | CABBAGE THISTLE | CARDUUS MARIANUS | COCKLEBURR | COMMON PLANTAIN | COMMON SOWTHISTLE | CRAMBLING MUSTARD | CURLED DOCK SEEDLING | DWARF NETTLE | ECHIUM LYCOPSIS | ECHIUM SPP. | ENGLISH STINGING NETTLE | FALLOPIA AVICULARE | FALSE STAR THISTLE | GIANT MUSTARD | HEDGE MUSTARD | HOLY THISTLE | LADY'S THISTLE | LAMBS TONGUE | LESSER NETTLE | L
Product summary:
For the control of seedling broadleaf weeds in seedling and established lucerne, medic and sub.clover pastures and cereals crops undersown with lucerne, medics or clover.See RESTRAINTS, etc. on label
Authorization status:
Registered and available
Authorization number:
50372/0809
Authorization date:
2009-11-16

S e l e c t i v e H e r b i c i d e

ACTIVE CONSTITUENT: 500 g/L 2,4-DB

(present as the dimethylamine salt)

For the control of broadleaf weeds in

seedling and established lucerne, medic and

clover pastures, peanuts and cereal crops

undersown with

lucerne, medic or clover

as specified in the Directions for Use table.

IMPORTANT: READ THE ATTACHED LEAFLET

BEFORE USING THIS PRODUCT.

CONTENTS:

5 LITRES

Crop Care Australasia Pty Ltd

Unit 15/16 Metroplex Avenue, Murarrie Qld 4172

® Trifolamine is a registered trademark of Nufarm Technologies USA Pty Ltd.

CAUTION

KEEP OUT OF REACH OF CHILDREN

READ SAFETY DIRECTIONS BEFORE OPENING OR USING

GROUP

HERBICIDE

I

JOB NO. 022998 | ID. CROC_Trifolamine 20L Label | COLOUR. CMYK | DESIGNER. Khoa Tran

DIMENSIONS. 140mm(w)x140mm(h), PDF @ 100% on A4

50372_47832_5L_Primary_MPL_V1.pdf

APPROVED

LABEL

Info

pest

Verified

GENERAL INSTRUCTIONS

Before opening, carefully read Directions for Use,

Precautionary Statements, Safety Directions and

First Aid Instructions.

STORAGE AND DISPOSAL

Store in the closed, original container in a cool, dry,

well-ventilated locked room or place away from

children, animals, food, feedstuffs, seed and fertilisers.

DO NOT store for prolonged periods in direct sunlight.

Triple or preferably pressure rinse containers before

disposal. Add rinsings to spray tank. DO NOT dispose

of undiluted chemicals on-site. If recycling, replace cap

and return clean containers to recycler or designated

collection point.

If not recycling, break, crush or puncture and bury

empty containers in a local authority landfill. If no

landfill is available, bury the containers below 500 mm

in a disposal pit specifically marked and set up for this

purpose clear of waterways desirable vegetation and

tree roots. Empty containers and product should NOT

be burnt.

SAFETY DIRECTIONS

Poisonous if swallowed. May irritate the eyes and skin.

The product is alkaline. Avoid contact with eyes and

skin. DO NOT inhale spray mist. When preparing spray

wear cotton overalls buttoned to the neck and wrist

and a washable hat and elbow length PVC gloves and

face shield. When using the prepared spray wear

cotton overalls buttoned to the neck and wrist and a

washable hat. If product on skin immediately wash

area with soap and water. After use and before eating,

drinking or smoking, wash hands, arms and face

thoroughly with soap and water. After each day’s use

wash gloves, face shield and contaminated clothing.

FIRST AID

If poisoning occurs, contact a doctor or Poisons

Information Centre: Phone Australia 131 126.

MATERIAL SAFETY DATA SHEET

For further information refer to the Material Safety

Data Sheet (MSDS), which can be obtained from

your supplier or from the Crop Care website –

www.cropcare.com.au

Conditions of sale

Crop Care Australasia Pty Ltd will not accept any

responsibility whatsoever and howsoever arising and

whether for consequential loss or otherwise in

connection with the supply of these goods other than

responsibility for the merchantable quality of the goods

and such responsibilities mandatorily imposed by

Statutes applicable to the sale or supply of these

goods. To the extent allowed by such Statutes the

liability of Crop Care Australasia Pty Ltd is limited to

the replacement of the goods or (at the option of Crop

Care Australasia) the refund of the price paid and

where possible sufficient part of the goods to enable

proper examination being returned to Crop Care

Australasia Pty Ltd within thirty days of delivery.

Crop Care Australasia Pty Ltd

ACN 061 362 347

Unit 15/16 Metroplex Avenue

Murarrie Qld 4172

APVMA Approval No.: 50372/5L/0809

OD022998

BN

DOM

In a Transport

Emergency Dial

000

Police or Fire Brigade

SPECIALIST ADVICE

IN AN EMERGENCY ONLY

1800 033 498

ALL HOURS – AUSTRALIA WIDE

S e l e c t i v e H e r b i c i d e

ACTIVE CONSTITUENT: 500 g/L 2,4-DB

(present as the dimethylamine salt)

For the control of broadleaf weeds in

seedling and established lucerne, medic and

clover pastures, peanuts and cereal crops

undersown with

lucerne, medic or clover

as specified in the Directions for Use table.

IMPORTANT: READ THE ATTACHED LEAFLET

BEFORE USING THIS PRODUCT.

CONTENTS:

10 LITRES

Crop Care Australasia Pty Ltd

Unit 15/16 Metroplex Avenue, Murarrie Qld 4172

® Trifolamine is a registered trademark of Nufarm Technologies USA Pty Ltd.

CAUTION

KEEP OUT OF REACH OF CHILDREN

READ SAFETY DIRECTIONS BEFORE OPENING OR USING

GROUP

HERBICIDE

I

JOB NO. 022998 | ID. CROC_Trifolamine 20L Label | COLOUR. CMYK | DESIGNER. Khoa Tran

DIMENSIONS. 140mm(w)x140mm(h), PDF @ 100% on A4

50372_47832_10L_Primary_MPL_V1.pdf

APPROVED

LABEL

GENERAL INSTRUCTIONS

Before opening, carefully read Directions for Use,

Precautionary Statements, Safety Directions and

First Aid Instructions.

STORAGE AND DISPOSAL

Store in the closed, original container in a cool, dry,

well-ventilated locked room or place away from

children, animals, food, feedstuffs, seed and fertilisers.

DO NOT store for prolonged periods in direct sunlight.

Triple or preferably pressure rinse containers before

disposal. Add rinsings to spray tank. DO NOT dispose

of undiluted chemicals on-site. If recycling, replace cap

and return clean containers to recycler or designated

collection point.

If not recycling, break, crush or puncture and bury

empty containers in a local authority landfill. If no

landfill is available, bury the containers below 500 mm

in a disposal pit specifically marked and set up for this

purpose clear of waterways desirable vegetation and

tree roots. Empty containers and product should NOT

be burnt.

SAFETY DIRECTIONS

Poisonous if swallowed. May irritate the eyes and skin.

The product is alkaline. Avoid contact with eyes and

skin. DO NOT inhale spray mist. When preparing spray

wear cotton overalls buttoned to the neck and wrist

and a washable hat and elbow length PVC gloves and

face shield. When using the prepared spray wear

cotton overalls buttoned to the neck and wrist and a

washable hat. If product on skin immediately wash

area with soap and water. After use and before eating,

drinking or smoking, wash hands, arms and face

thoroughly with soap and water. After each day’s use

wash gloves, face shield and contaminated clothing.

FIRST AID

If poisoning occurs, contact a doctor or Poisons

Information Centre: Phone Australia 131 126.

MATERIAL SAFETY DATA SHEET

For further information refer to the Material Safety

Data Sheet (MSDS), which can be obtained from

your supplier or from the Crop Care website –

www.cropcare.com.au

Conditions of sale

Crop Care Australasia Pty Ltd will not accept any

responsibility whatsoever and howsoever arising and

whether for consequential loss or otherwise in

connection with the supply of these goods other than

responsibility for the merchantable quality of the goods

and such responsibilities mandatorily imposed by

Statutes applicable to the sale or supply of these

goods. To the extent allowed by such Statutes the

liability of Crop Care Australasia Pty Ltd is limited to

the replacement of the goods or (at the option of Crop

Care Australasia) the refund of the price paid and

where possible sufficient part of the goods to enable

proper examination being returned to Crop Care

Australasia Pty Ltd within thirty days of delivery.

Crop Care Australasia Pty Ltd

ACN 061 362 347

Unit 15/16 Metroplex Avenue

Murarrie Qld 4172

APVMA Approval No.: 50372/10L/0809

OD022998

BN

DOM

In a Transport

Emergency Dial

000

Police or Fire Brigade

SPECIALIST ADVICE

IN AN EMERGENCY ONLY

1800 033 498

ALL HOURS – AUSTRALIA WIDE

S e l e c t i v e H e r b i c i d e

ACTIVE CONSTITUENT: 500 g/L 2,4-DB

(present as the dimethylamine salt)

For the control of broadleaf weeds in

seedling and established lucerne, medic and

clover pastures, peanuts and cereal crops

undersown with

lucerne, medic or clover

as specified in the Directions for Use table.

IMPORTANT: READ THE ATTACHED LEAFLET

BEFORE USING THIS PRODUCT.

CONTENTS: 20 LITRES

Crop Care Australasia Pty Ltd

Unit 15/16 Metroplex Avenue, Murarrie Qld 4172

® Trifolamine is a registered trademark of Nufarm Technologies USA Pty Ltd.

CAUTION

KEEP OUT OF REACH OF CHILDREN

READ SAFETY DIRECTIONS BEFORE OPENING OR USING

GROUP

HERBICIDE

I

JOB NO. 022998 | ID. CROC_Trifolamine 20L Label | COLOUR. CMYK | DESIGNER. Khoa Tran

DIMENSIONS. 140mm(w)x140mm(h), PDF @ 100% on A4

50372_47832_20L_Primary_MPL_V1.pdf

APPROVED

LABEL

GENERAL INSTRUCTIONS

Before opening, carefully read Directions for Use,

Precautionary Statements, Safety Directions and

First Aid Instructions.

STORAGE AND DISPOSAL

Store in the closed, original container in a cool, dry,

well-ventilated locked room or place away from

children, animals, food, feedstuffs, seed and fertilisers.

DO NOT store for prolonged periods in direct sunlight.

Triple or preferably pressure rinse containers before

disposal. Add rinsings to spray tank. DO NOT dispose

of undiluted chemicals on-site. If recycling, replace cap

and return clean containers to recycler or designated

collection point.

If not recycling, break, crush or puncture and bury

empty containers in a local authority landfill. If no

landfill is available, bury the containers below 500 mm

in a disposal pit specifically marked and set up for this

purpose clear of waterways desirable vegetation and

tree roots. Empty containers and product should NOT

be burnt.

SAFETY DIRECTIONS

Poisonous if swallowed. May irritate the eyes and skin.

The product is alkaline. Avoid contact with eyes and

skin. DO NOT inhale spray mist. When preparing spray

wear cotton overalls buttoned to the neck and wrist

and a washable hat and elbow length PVC gloves and

face shield. When using the prepared spray wear

cotton overalls buttoned to the neck and wrist and a

washable hat. If product on skin immediately wash

area with soap and water. After use and before eating,

drinking or smoking, wash hands, arms and face

thoroughly with soap and water. After each day’s use

wash gloves, face shield and contaminated clothing.

FIRST AID

If poisoning occurs, contact a doctor or Poisons

Information Centre: Phone Australia 131 126.

MATERIAL SAFETY DATA SHEET

For further information refer to the Material Safety

Data Sheet (MSDS), which can be obtained from

your supplier or from the Crop Care website –

www.cropcare.com.au

Conditions of sale

Crop Care Australasia Pty Ltd will not accept any

responsibility whatsoever and howsoever arising and

whether for consequential loss or otherwise in

connection with the supply of these goods other than

responsibility for the merchantable quality of the goods

and such responsibilities mandatorily imposed by

Statutes applicable to the sale or supply of these

goods. To the extent allowed by such Statutes the

liability of Crop Care Australasia Pty Ltd is limited to

the replacement of the goods or (at the option of Crop

Care Australasia) the refund of the price paid and

where possible sufficient part of the goods to enable

proper examination being returned to Crop Care

Australasia Pty Ltd within thirty days of delivery.

Crop Care Australasia Pty Ltd

ACN 061 362 347

Unit 15/16 Metroplex Avenue

Murarrie Qld 4172

APVMA Approval No.: 50372/20L/0809

OD022998

BN

DOM

In a Transport

Emergency Dial

000

Police or Fire Brigade

SPECIALIST ADVICE

IN AN EMERGENCY ONLY

1800 033 498

ALL HOURS – AUSTRALIA WIDE

022998_CROC_Trifolamine 20L Label.qxd 7/9/09 9:49 AM Page 2

CAUTION

KEEP OUT OF REACH OF CHILDREN

READ SAFETY DIRECTIONS BEFORE OPENING OR USING

Trifolamine

®

Selective Herbicide

ACTIVE CONSTITUENT: 500 g/L 2,4-DB

present as the dimethylamine salt

GROUP

HERBICIDE

For the control of broadleaf weeds in seedling

and established lucerne, medic and clover pastures,

peanuts and cereal crops undersown with lucerne, medic

or clover as specified in the Directions for Use table.

READ COMPLETE DIRECTIONS FOR USE

BEFORE USING THIS PRODUCT.

Crop Care Australasia Pty Ltd

ACN 061 362 347

Unit 15/16 Metroplex Avenue

Murarrie QLD 4172

Ph: (07) 3909 2000

APVMA Approval

No.: 50372/0809

® Trifolamine is a registered trademark of Nufarm Technologies USA Pty Ltd.

GENERAL INSTRUCTIONS

Before opening, carefully read Directions for Use, Precautionary

Statements, Safety Directions and First Aid Instructions.

MIXING

Mix with the required amount of water in the spray tank or mixing

vessel. Apply using a low-volume boom spray fitted with fan jets, or by

aircraft. Use mains or rain water for mixing. If not available, water with a

hardness of less than 500 ppm (expressed as calcium carbonate

equivalent) can be used but is not preferred. DO NOT tank mix Liase

with Trifolamine in hard water for this may cause nozzle blockages.

APPLICATION

Apply using boom or spot spray equipment. Application must be

uniform. Nozzle type, output, speed and pressure should be adjusted to

deliver a Coarse spray quality (ASAE S 527) in 110-220 litres per

hectare by ground application and a minimum of 40 litres per hectare by

aerial application.

COMPATIBILITY

This product can be tank mixed with Flowable Diuron and Diuron 900

DF for use in lucerne only. This mix can be very damaging to clovers.

Trifolamine is compatible with Broadstrike but not for control of

Paterson’s curse or doublegee - refer to Broadstrike label. The

effectiveness of Dimethoate, Metasystox, Le Mat and Imidan may be

reduced by alkaline hydrolysis if tank mixed with this product. For these

situations the addition of Spraymate LI 700 is recommended which

should be added to the tank first. The addition of Bonza Spray Adjuvant

can improve control of weeds under some conditions, for example

moisture stress but may also increase early effects on legumes. When

tank mixing add the required amount of compatible product (and

surfactant if recommended) when the spray tank is nearly full and while

continuously agitating. If left overnight, agitate thoroughly before

spraying.

RESISTANT WEEDS WARNING

Trifolamine Selective Herbicide is a member of the Phenoxys group of

herbicides. T

rifolamine has the disruptors of plant cell growth mode of

action. For weed resistance management Trifolamine is a Group I

herbicide.

Some naturally-occurring weed biotypes resistant to Trifolamine and

other disruptors of plant cell growth herbicides may exist through normal

genetic variability in any weed population. The resistant individuals can

eventually dominate the weed population if these herbicides are used

repeatedly. These resistant weeds will not be controlled by Trifolamine

or other disruptors of plant cell growth herbicides.

Since the occurrence of resistant weeds is difficult to detect prior to use,

Crop Care Australasia Pty Ltd accepts no liability for any losses that

may result from the failure of Trifolamine to control resistant weeds.

PROTECTION OF CROPS, NATIVE AND OTHER NON-TARGET

PLANTS

Drift Warning:

DO NOT apply under meteorological conditions or from spraying

equipment which could be expected to cause spray to drift onto nearby

susceptible plants, adjacent crops, crop lands or pastures.

Avoid spray drift and vapour movement onto susceptible crops such as

cotton, tobacco, tomatoes, vines, lupins, fruit trees and ornamentals.

PROTECTION OF LIVESTOCK

SPRAY-GRAZING WARNING: Some pasture weeds can be controlled

by Spray-Grazing a combination of herbicide treatment followed by

heavy grazing 7-10 days later. Sprayed weeds become more palatable

to stock and a higher intake of some weed species after spraying can

cause stock deaths and other problems. Increased quantities of

poisonous plants may be eaten by stock when the Spray-Grazing

technique is being used. Take care if pastures are dominated by

Caltrop, Capeweed, Cape Tulip, Paterson’s Curse (Salvation Jane) or

Variegated Thistle. With Paterson’s Curse preferably graze stock soon

destined for slaughter and avoid extended periods of grazing. Avoid

grazing with young or breeding stock. DO NOT graze horses or pigs on

Paterson’s Curse (Salvation Jane) infested pasture.

PROTECTION OF WILDLIFE, FISH CRUSTACEAN AND

ENVIRONMENT

DO NOT contaminate streams, rivers or waterways with the product or

used containers.

STORAGE AND DISPOSAL

Store in the closed, original container in a dry, cool, well-ventilated area,

away from children, animals, food, feedstuffs, seed and fertilisers. DO

NOT store for prolonged periods in direct sunlight. Triple or preferably

pressure rinse containers before disposal. Add rinsings to spray tank.

DO NOT dispose of undiluted chemicals on-site. If recycling, replace

cap and return clean containers to recycler or designated collection

point.

If not recycling, break, crush or puncture and bury empty containers in a

local authority landfill. If no landfill is available, bury the containers

below 500 mm in a disposal pit specifically marked and set up for this

purpose clear of waterways desirable vegetation and tree roots. Empty

containers and products should NOT be burnt.

SAFETY DIRECTIONS

Poisonous if swallowed. May irritate the eyes and skin. The product is

alkaline. Avoid contact with eyes and skin. DO NOT inhale spray mist.

When preparing spray wear cotton overalls buttoned to the neck and

wrist and a washable hat, elbow-length PVC gloves and face shield.

When using the prepared spray wear cotton overalls buttoned to the

neck and wrist and a washable hat. If product on skin immediately wash

area with soap and water. After use and before eating, drinking or

smoking, wash hands, arms and face thoroughly with soap and water.

After each day’s use wash gloves, face shield and contaminated

clothing.

FIRST AID

If poisoning occurs, contact a Doctor or Poisons Information Centre.

Phone Australia 13 11 26.

MATERIAL SAFETY DATA SHEET

For further information refer to the Material Safety Data Sheet (MSDS),

which can be obtained from your supplier or from the Crop Care

website - www.cropcare.com.au

CONDITIONS OF SALE

Crop Care Australasia Pty Ltd will not accept any responsibility

whatsoever and howsoever arising and whether for consequential loss

or otherwise in connection with the supply of these goods other than

responsibility for the merchantable quality of the goods and such

responsibilities mandatorily imposed by Statutes applicable to the sale

or supply of these goods. To the extent allowed by such Statutes the

liability of Crop Care Australasia Pty Ltd is limited to the replacement of

the goods or (at the option of Crop Care Australasia) the refund of the

price paid and where possible sufficient part of the goods to enable

proper examination being returned to Crop Care Australasia Pty Ltd

within thirty days of delivery.

Crop Care Australasia Pty Ltd

ACN 061 362 347

Unit 15/16 Metroplex Avenue

Murarrie QLD 4172

Tel.: (07) 3909 2000

APVMA Approval No.: 50372/0809

GROUP

HERBICIDE

I

In a Transport

Emergency Dial

000

Police or Fire Brigade

SPECIALIST ADVICE

IN EMERGENCY ONLY

1800 033 498

ALL HOURS- AUSTRALIA WIDE

I

50372_47832_Leaflet_Primary_MPL_V1.pdf

Dimensions: 368mm (w) x 242mm (h); PDF @ 100% on A3 size

DIRECTIONS FOR USE

RESTRAINTS

DO NOT apply if rain is expected within 4 hours.

DO NOT apply to crop or weeds under stress (not actively growing) due to periods of extreme cold or heat, moisture stress (water logged or

drought affected), poor nutrition or previous herbicide treatments as increased levels of crop effect and/or reduced levels of weed control may

result.

DO NOT use with hard water (>500 ppm) or water containing suspended matter.

Situation & Crop

Weeds Controlled

State

Rate/ha

Critical Comments

Lucerne,

- seedling and established

Clover and Medic Pastures,

- seedling and established

Legumes showing acceptable

tolerance Clover

- Arrow leaf cvs Cefalu, Zulu II

- Balansa cvs Bolta, Frontier, Paradana

Berseem cv Elite II

- Persian cvs Nitro, Lazer, Leeton, Prolific,

Shaftal

- Rose cv Hykon

- Red

- Sub cvs Coolamon, Dalkeith, Gosse,

Goulburn, Junee, Nungarin, Riverina,

Seaton Park, Trikkala, Urana

- White cv NuSiral etc

Medic

- Barrel cvs Caliph, Parabinga

- Burr (polymorpha) cv Circle valley

- Gama cvs Paraponto, Sapo

- Murex cv Zodiac

- Snail cvs Robinson, Sava

Serradella

- French cv Erica

Sown Pasture containing Clover or Medics

Sub. clover pasture

Peanuts

- Runner types

- Virginia types

- Spanish types

Wheat, Barley, Oats, Triticale and Cereal

Rye undersown with lucerne, medic or

clover

Spot spraying (All Situations)

Amaranths

Amaranthus spp

Burrs

- Bathurst

Xanthium spinosum

- Californian

Xanthium orientale

- Noogoora

Xanthium strumarium

Capeweed

Arctotheca calendula

Charlock

Sinapis arvensis

Dock (seedlings)

Rumex spp

Evening primrose

Oenothera stricta

Fat hen

Chenopodium album

Fumitory spp

Fumaria spp

Marshmallow

Malva parviflora

Mexican poppy

Argemone spp

Mustards

Sisymbrium spp

Paterson’s curse (Salvation Jane)

Echium plantagineum

Plantains (Flat weeds)

Plantago spp

Prickly lettuce

Lactuca serriola

Shepherd’s purse

Capsella bursapastoris

Sowthistle

Sonchus oleraceus

Spiny emex (Doublegee)

Emex australis

Stinging nettle

Urtica urens

Thistles

- Saffron

Carthamus lanatus

- Slender

Carduus pycnocephalus

- Soldier

Picnomon acarna

- Spear

Cirsium vulgare

- Variegated

Silybum marianum

Turnip weed

Rapistrum rugosum

Wild (Mediterranean) turnip

Brassica tournefortii

Wireweed

Polygonum aviculare

Refer to Weeds Controlled in Lucerne

Refer to Weeds Controlled in Lucerne

Doublegee

Emex australis

Ipomoea spp

including

- Bellvine

Ipomoea plebeia

- Morning glory

Ipomoea purpurea

- Red convolvulus

Ipomoea hederifolia

Spiny emex

Emex australis

Thornapples

Datura spp

Refer to Weeds Controlled in Lucerne

Refer to Weeds Controlled in Lucerne

States

States

WA only

Qld only

States

1 - 3.2L

1 - 3.2L

1 - 3.2L

1.2L

1.3 - 1.7L

2.1 - 3.2L

200 -

400mL/100L

water

Spray seedling weeds at the 2-6 leaf stage when seedling lucerne

has between 1-8 trifoliate leaves. Use lower end of rate range only

for 2-4 leaf weeds under good growing conditions or for spray

grazing. Small weeds which have been growing slowly under stress

and are therefore physiologically older may not be well controlled.

To avoid leaf distortion cut or graze established lucerne before

spraying. Unless “Spray-Grazing” DO NOT cut, mow or graze for 4

weeks after application to maximise weed control.

Spray weeds at the 2-6 leaf stage when seedling medic and clover

has between 1-8 trifoliate leaves. use lower end of rate range only for

2-4 leaf weeds under good growing conditions or for spray grazing.

Medic and Clover safety Trifolamine may reduce initial vigour of

most pasture legumes. Depending on inherent tolerance this may not

result in reduced spring growth or seed yield. T

olerance can vary

between seasons, legume type and cultivars. Because of the

continuing introduction of new pasture legumes and cultivars caution

is advised before applying Trifolamine to any new legume.

Caution is especially advised if a treated crop is intended for seed

production. Application beyond the 8 trifoliate leaf stage can increase

the chance of reduced vigour and production. The use of higher rates

can also increase vigour reduction. DO NOT exceed 3L/ha when

spraying Robinson or Sava snail Medic. Do not exceed 2.5L/ha when

spraying Sapo or Paraponto gama medic. DO NOT use on Berseen

clover or on Red clover when it is being harvested for seed. Growth

of Red clover may be retarded. Trifolamine is unsafe to use on

Biserrula, Gland clover, Popany vetch and Orion, Santiago and

Serena medics due to the risk of excessive growth and seed.

Trifolamine is unsafe to use on chicory and plantain.

Apply when clovers or medics are at the 1-8 trifoliate leaf stage.

Grass seedlings should have 3 or more leaves.

Medic and Clover safety refer to the Critical Comments above.

Spray when Doublegee has less than 14 leaves: best results are

obtained when weed has 6-8 leaves. Clover should have 2-8 trifoliate

leaves. DO NOT apply to pastures when one or more false breaks in

the season occur, as uneven germination will result.

Doublegee which emerge after spraying will not be controlled.

Medic and Clover safety refer to the Critical Comments above.

Apply between 1 and 12 weeks after seedlings have emerged. Use

the lower end of the rate range for control of Ipomoea spp weeds

only.

Spray weeds at the 2-6 leaf stage when seedling lucerne, medic and

clover has between 1-8 trifoliate leaves. Use lower rate for 2-4 leaf

weeds under good growing conditions.

Apply to cereals after the

“double ridge” stage which is normally through tillering after the main

shoot has five leaves until booting (Z15-33). The time to “double

ridge” stage will vary depending on growing conditions and variety.

Medic and Clover safety refer to the Critical Comments above.

Use lower rate for easy to kill weeds eg Fat hen or Variegated thistle.

For harder to kill weeds eg Capeweed, Marshmallow, use higher rate.

Where difficult to wet, hairy or very thick weed populations are

present, add Chemwet 1000 to the spray mixture at a rate of

65mL/100L water.

NOT TO BE USED FOR ANY PURPOSE, OR IN ANY MANNER CONTRARY TO THIS LABEL UNLESS

AUTHORISED UNDER APPROPRIATE LEGISLATION.

WITHHOLDING PERIOD: DO NOT GRAZE OR CUT FOR STOCK FEED FOR 7 DAYS AFTER APPLICATION.

Trifolamine® Leaflet 2 9/9/09 11:49 AM Page 1

Dimensions: 242mm (w) x 368mm (h); PDF @ 100% on A3 size

CS: 1.5.27

Page: 1 Material Safety Data Sheet

Infosafe No™3NU1H August 2011 ISSUED by CRPCARE Issue Date:

TRIFOLAMINE Selective Herbicide Product Name

Classified as hazardous

1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER

Product Name TRIFOLAMINE Selective Herbicide

Product Code 0272

Product Type Group I Herbicide

CompanyName Crop Care Australasia Pty Ltd (ABN 53 061 362 347)

Address Unit 15/16 Metroplex Avenue Murarrie

Queensland 4172 Australia

Emergency Tel. 1800 033 498 (24hr Australia)

Telephone/Fax

Number Tel: +61 7 3909 2000

Fax: +61 7 3909 2010

Recommended Use For the control of broadleaf weeds in seedling and established lucerne, medic

and clover pastures and cereal crops undersown with lucerne, medic or clover

as specified in the Directions for Use table on the label.

Other Information This MSDS describes, to the best of our knowledge, the properties of the

concentrated product. The physical properties and some of the assessments do

not apply to the properties of the product once it has been diluted for

application. Acute health effects of the diluted product are likely to be

much less severe.

2. HAZARDS IDENTIFICATION

Hazard

Classification Classified as hazardous

HAZARDOUS SUBSTANCE.

NON-DANGEROUS GOODS.

Hazard classification according to the criteria of NOHSC.

Dangerous goods classification according to the Australia Dangerous Goods

Code.

Risk Phrase(s) Classified as hazardous

R22 Harmful if swallowed.

R41 Risk of serious damage to eyes.

SafetyPhrase(s) S13 Keep away from food, drink and animal feeding stuffs.

S2 Keep out of reach of children.

S26 In case of contact with eyes, rinse immediately with plenty of water and

seek medical advice.

S37/39 Wear suitable gloves and eye/face protection.

Other Information Poisons Schedule S5

3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical

Characterization Liquid

CAS Proportion Name Ingredients

94-82-6 2,4-DB (present

as the

dimethylamine

salt) 500 g/L

Water Balance

Other ingredients

(considered

non-hazardous) 10-30 %

4. FIRST AID MEASURES

Inhalation Remove affected person to fresh air until recovered.

Ingestion If swallowed do NOT induce vomiting; seek medical advice immediately and show

this container or label or contact the Poisons Information Centre on 13 11 26

(Aust). Make every effort to prevent vomit from entering the lungs by careful

placement of the patient.

The above first aid instructions are mandated by the Commonwealth Department

of Health and Ageing via the National Drugs and Poisons Schedule. These

instructions are suitable for ingestion of spray solution and small amounts of

concentrate; however, if SUBSTANTIAL AMOUNTS of the concentrate have been

Print Date: 26/08/2011 CS: 1.5.27

CS: 1.5.27

Page: 2 Material Safety Data Sheet

Infosafe No™3NU1H August 2011 ISSUED by CRPCARE Issue Date:

TRIFOLAMINE Selective Herbicide Product Name

Classified as hazardous

swallowed (more than about one tablespoon for an adult person) AND if medical

assistance is more than 30 minutes away, the induction of vomiting should be

CONSIDERED, preferably based on MEDICAL ADVICE if a physician can be contacted

by phone. All care must be taken to prevent vomit from being inhaled. Do not

give anything by mouth to a semi-conscious or unconscious person.

Skin Wash affected areas thoroughly with soap and water.

Remove contaminated clothing and launder before re-use.

Eye If in eyes, hold eyelids open and wash with copious amounts of water for at

least 15 minutes.

Seek medical advice.

Advice to Doctor Treat symptomatically.

5. FIRE FIGHTING MEASURES

Suitable

Extinguishing Media If involved in a fire, the product will not burn. Choose extinguishing media

to suit the burning material.

Hazards from

Combustion

Products Non-combustible.

If involved in a fire, it will emit carbon monoxide, phosgene and possibly

oxides of phosphorous.

Special Protective

Equipment for fire

fighters Breathable air apparatus may have to be worn if material is involved in fires

especially in confined spaces.

Other Information STOP FIRE WATER FROM ENTERING DRAINS OR WATER BODIES.

6. ACCIDENTAL RELEASE MEASURES

Spills & Disposal Contain spill and absorb with clay, sand, soil or proprietary absorbent (such

as vermiculite).

Collect in sealed open top containers for disposal.

Personal Protection For appropriate personal protective equipment (PPE), refer Section 8.

7. HANDLING AND STORAGE

Conditions for Safe

Storage Store in the closed, original container in a dry, well ventilated area out of

direct sunlight.

Keep container tightly sealed and do not store with seed, fertilisers or

foodstuffs.

Other Information Equipment that has been used for this chemical should not be used for the

application of other materials to sensitive plants, unless it has been well

washed out with hot soapy water or 1% solution of ammonia, followed by several

clear water rinses.

Sprayed weeds may become more palatable to stock and a higher intake of some

weeds may result in stock poisoning and death from causes such as nitrate

poisoning. Care should be taken especially where capeweed, Paterson's curse

and variegated thistles predominate in the pasture.

Always read the label and any attached leaflet before use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

National Exposure

Standards No exposure standard for this product has been set, however, an exposure

standard has been set for dimethylamine vapour at 2 ppm.

Engineering

Controls Use in a well ventilated area only.

Personal Protective

Equipment When opening the container and preparing the spray wear cotton overalls

buttoned to the neck and wrist and a washable hat, elbow-length PVC gloves and

face shield or goggles.

Hygiene Measures After use and before eating, drinking or smoking, wash hands, arms and face

thoroughly with soap and water.

After each day's use, wash contaminated clothing and safety equipment.

9. PHYSICAL AND CHEMICAL PROPERTIES

Form Liquid

Appearance Brown liquid

Odour Faint ammoniacal odour.

Print Date: 26/08/2011 CS: 1.5.27

CS: 1.5.27

Page: 3 Material Safety Data Sheet

Infosafe No™3NU1H August 2011 ISSUED by CRPCARE Issue Date:

TRIFOLAMINE Selective Herbicide Product Name

Classified as hazardous

MeltingPoint Approx -5°C

Boiling Point 100°C

Solubility in Water Soluble in water.

Specific Gravity 1.179 - 1.181

pH Value 9.8 - 10.1

VapourPressure Active ingredient considered non volatile

Volatile Component 16 - 30%

FlashPoint Not flammable

Flammability Not flammable.

Flammable Limits -

Lower Not flammable

10. STABILITY AND REACTIVITY

Incompatible

Materials Reaction of the concentrate or spray mix with acids will precipitate solid

2,4-DB acid and largely de-activate the product and cause blockages in spray

equipment.

The addition of a strong alkali such as caustic soda will cause release of

dimethylamine vapour.

Dimethylamine is moderately toxic, LD50 (oral, rat) is 700 mg/kg and a TLV of

2 ppm (TWA) has been set.

Hazardous ReactionsKeep away from strong oxidising agents.

Hazardous

Polymerization Hazardous polymerisation is not possible.

11. TOXICOLOGICAL INFORMATION

Toxicology

Information No harmful effects are expected if the precautions on the label and this MSDS

are followed.

Inhalation When applying the product as a spray avoid breathing in spray mist.

Ingestion May cause irritation to mouth, throat and stomach.

Skin Prolonged contact with the concentrate may cause irrritation and cause skin

eruptions.

Eye The concentrate will cause severe irritation and possible damage unless washed

off immediately.

Chronic Effects Chronic Overexposure: Weight loss and damage to liver and kidneys may be

expected if exposure is excessive.

Acute Toxicity- OralLD50 (rat) 700 mg/kg for technical 2,4-DB

LD50 (rat) 700 mg/kg for dimethylamine

Acute Toxicity -

Dermal LD50 (rat) 800 mg/kg for technical 2,4-DB

Human Effects Symptoms of acute overexposure may include:

headache, nausea, dizziness and vomiting.

In extreme cases, possibly twitching and spasms, dyspnea, cyanosis and

exhaustion.

Other Information The Australian Acceptable Daily Intake (ADI) for 2,4-DB for a human is 0.004

mg/kg/day, set for the public for daily, lifetime exposure. This is based on

the NOEL of 1.9 mg/kg/day,the level determined to show no effects during long

term exposure for the most sensitive indicators and the most sensitive

species. (Ref: Comm. Dept. of Health and Ageing Office of Chemical Safety and

Environmental Health, 'ADI List', June 2006).

12. ECOLOGICAL INFORMATION

Persistence /

Degradability Average field half life of 2,4-DB dimethylamine salt is 10 days.

Other Precautions Do not spray in high winds.

Do not contaminate dams, waterways or sewers with this product.

Environ.Protection Spray drift can cause damage, read the label for more information.

Print Date: 26/08/2011 CS: 1.5.27

CS: 1.5.27

Page: 4 Material Safety Data Sheet

Infosafe No™3NU1H August 2011 ISSUED by CRPCARE Issue Date:

TRIFOLAMINE Selective Herbicide Product Name

Classified as hazardous

Acute Toxicity - Fish The following is data for the active ingredient, 2,4-DB amine salt and esters.

LC50 (96hr) for rainbow trout is 4 mg/l.

Acute Toxicity -

Other Organisms Not toxic to bees.

13. DISPOSAL CONSIDERATIONS

Product Disposal On site disposal of the concentrated product is not acceptable.

Ideally, the product should be used for its intended purpose. If there is a

need to dispose of the product, approach local authorities who hold periodic

collections of unwanted chemicals (ChemClear®).

Container Disposal Do not use this container for any other purpose.

Triple rinse containers, add rinsate to the spray tank, then offer the

container for recycling/reconditioning, or puncture top, sides and bottom and

dispose of in landfill in accordance with local regulations.

drumMUSTER is the national program for the collection and recycling of empty,

cleaned, non returnable crop production and on-farm animal health chemical

containers. If the label on your container carries the drumMUSTER symbol,

triple rinse the container, ring your local Council, and offer the container

for collection in the program.

If recycling, replace cap and return clean containers to recycler or

designated collection point.

If not recycling, puncture or shred and bury containers in local authority

landfill.

If no landfill is available, bury the containers below 500mm in a disposal pit

specifically marked and set up for this purpose clear of waterways, desirable

vegetation and tree roots.

Empty containers and product should not be burnt.

14. TRANSPORT INFORMATION

Transport

Information It is good practice not to transport agricultural chemical products with

food, food related materials and animal feedstuffs.

Storage and

Transport Considered non dangerous for transport by the Australian Code for the

Transport of Dangerous Goods by Road and Rail.

15. REGULATORY INFORMATION

Poisons Schedule S5

Packaging &

Labelling CAUTION

KEEP OUT OF REACH OF CHILDREN

READ SAFETY DIRECTIONS BEFORE OPENING OR USING

Hazard Category Harmful,Irritant

AICS (Australia) All of the components in this product are listed on the Australian Inventory

of Chemical Substances.

16. OTHER INFORMATION

Date of preparation

or last revision of

MSDS Reviewed 26/08/2011

Contact

Person/Point Normal Hours: Mrs Kathleen Marsh Phone: +61 3 9282 1000

After Hours: Shift Supervisor Phone: 1800 033 498

Revisions

Highlighted The MSDS was reviewed. Minor changes were made to the information.

...End Of MSDS...

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Print Date: 26/08/2011 CS: 1.5.27

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