SUSCON BLUE SOIL INSECTICIDE

Australia - English - APVMA (Australian Pesticides and Veterinary Medicines Authority)

Active ingredient:
CHLORPYRIFOS
Available from:
NUFARM AUSTRALIA LIMITED
INN (International Name):
chlorpyrifos(140g/kg)
Pharmaceutical form:
GRANULAR FORMULATION
Composition:
CHLORPYRIFOS ORGANOPHOSPHORUS Active 140.0 g/kg
Units in package:
10kg; 15kg; 20kg
Class:
A - Agricultural
Therapeutic group:
SUGAR CANE | INTER-ROW SPRAYING | RATOON SUGAR CANE | SUGARCANE
Therapeutic area:
INSECTICIDE
Therapeutic indications:
BUNDABERG CANEGRUB | CANEGRUB - LEPIDIOTA NEGATORIA | CANEGRUB - LEPIDIOTA PICTICOLLIS | CANEGRUB - LEPIDIOTA SQUAMULATA | CHILDERS CANEGRUB | CONSOBRINA CANEGRUB-REF LABEL LIFE STAGE | FRENCH'S CANEGRUB | GREYBACK CANEGRUB | RHOPAEA CANEGRUB | SOUTHERN ONE-YEAR CANEGRUB | WIREWORM | NEGATORIA CANEGRUB | PICTICOLLIS CANEGRUB | SOUTHERN 1 YEAR CANEGRUB | SQUAMULATA CANEGRUB
Product summary:
Poison schedule: 6; Withholding period: WHP: n/a.; Host/pest details: SUGAR CANE: [BUNDABERG CANEGRUB, CANEGRUB - LEPIDIOTA NEGATORIA, CANEGRUB - LEPIDIOTA PICTICOLLIS, CANEGRUB - LEPIDIOTA SQUAMULATA, CHILDERS CANEGRUB, CONSOBRINA CANEGRUB-REF LABEL LIFE STAGE, FRENCH'S CANEGRUB, GREYBACK CANEGRUB, RHOPAEA CANEGRUB, SOUTHERN ONE-YEAR CANEGRUB, WIREWORM]; Poison schedule: 6; Withholding period: ; Host/pest details: SUGAR CANE: [BUNDABERG CANEGRUB, CANEGRUB - LEPIDIOTA NEGATORIA, CANEGRUB - LEPIDIOTA PICTICOLLIS, CANEGRUB - LEPIDIOTA SQUAMULATA, CHILDERS CANEGRUB, CONSOBRINA CANEGRUB-REF LABEL LIFE STAGE, FRENCH'S CANEGRUB, GREYBACK CANEGRUB, RHOPAEA CANEGRUB, SOUTHERN ONE-YEAR CANEGRUB, WIREWORM]; Controls cane grubs for up to three years using sustained control technology.
Authorization status:
Registered
Authorization number:
47538
Authorization date:
2020-07-01

Scale: 55% on A4

Bag front 570mm

x 360mm

VVIde

POISON

KEEP

REACH

CHILDREN

READ

SAFETY

DIRECTIONS

BEFORE

OPENING

USING

BLUE

SOIL

INSECTICIDE

GROUP

Controls

cane

~rubs

three

years

using

susta1ned

control

technology

INNER

MUST

SOLD

SEPARATELY.

DESTROY

WHIL

PRODUCT

STILL

REMA

IMPORTANT:

READ

ATTACHED

LEAFlET

BEFORE

NET CONTENTS:

20kg

Crop

Austra

liasia

Unit

5116

Avenue.

Murarrie

4172

STORAGE

AND

DIS

P

OSAL

Store

closed

original

container

well-ventilated

area

direct

sunlight.

store

prolonged

periods

temperatures

below

Shake

contents

into

applicator

until

empty.

dispose

product

site.

Puncture

shred

bury

empty

containers

local

authority

landfill.

landfill

available

bury

containers

below

disposal

specifically

marked

this

purpose

clear

waterways

desirable

vegetation

tree

roots.

Empty

containers

product

should

burnt.

SAFETY

DIRECTIONS

Harmful

swallowed.

Will

irritate

eyes.

Repeated

exposure

have

cumulative

poisoning

effect.

Obtain

emerge

supply

atropine

tablets

0.6mg

Avoid

contact

with

eyes.

When

opening

container

using

product

cotton

overalls

buttoned

neck

wrist

equivalent

clothing

elbow

length

gloves

goggles

disposable

dust

mask.

hands

after

After

each

wash

gloves,

goggles

contaminated

clothing.

FIRST

AID

poisoning

occurs,

tact

doctor

Poisons

Information

Centre.

Phone

Australia

131126

Additional

information

is

listed

in

the

Material

Safety

Da

ta

Sheet.

Conditions

of

Sal

e

Crop

Care

Australasia

will

accept

responsibility

whatsoever

howsoever

arising

whether

consequential

loss

otherwise

connectio

with

supply

these

goods

other

respo

sibility

merchantable

quality

goods

such

responsibilities

mandatorily

imposed

Statutes

applicable

sale

supply

these

goods

extent

allowed

such

Statutes

liability

Crop Care

Australasia

limited

replacement

goods

option

Care

Australasia

Ltd)

price

paid

itional

upon

clai

being

ting

where

possib

le su

fficie

part

goods

enable

proper

exami-

natio

being

returned

Crop

Care

stralasia

within

thirty

days

delivery.

In

a

Transport

Emergency

Dial

000

Police

or

Fire

Brigade

SPECIALIST

ADVICE

IN

AN

EMERGENCY

ONLY

1800 033 498

All

HOURS

-

AUSTRALIA

WIDE

suSCon

Registered

ademark.

APVMA

Approval

47538

20KG

1206

Crop

Care

Australasia

362 347

Unit

Metroplex

Avenue

Murarrie

4172

Tel:

(07)

3909

2000

1689

11.06

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where greyback grub

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PROTECTION

WILDLI

FE, FISH, CRUSTACEANS AND

ENVIRONMENT

Dangerous

fish and other aquat

Invertebrates.

DO N

contaminate

reams, rivers

wateiWays with the

chemical

used containers.

DO NOT

leave granules above ground

they are dangerous

to wildlife. particularly birds.

STORAGE AND DISPOSAL

Store in the closed, original

ainer

dry. well-ventilated

area

-30"C

direct sunlight. DO NOT store

pro-

longed periods

tempe

ratures

below

··

·c.

Shake bagJbox

contents

into the applicator

til empty.

Do not dispose

produc

Puncture or shred and bury

empty

containers

a local authority landfill.

landfill

available, bu

the containers below

SOOmm

in a

disp

osal pit

specifically marked and

for this purpose clear

terways, desirable vegetation and tree roots.

containers and product should

burnt.

SAFETY DIRECTIONS

Harmful

swallowed. Will irritate the eyes. Repeated minor

exposure

have a cumulative poisoning effect. Obtain an

emergency

supply

atropine tablets 0.6mg. Avoid

with eyes. When opening the container and using the product

wear

cotton

overalls buttoned

the neck and wrist (or

equivalent clothing},

elbow

-length PVC gloves, goggles and

disposable dust mask. Wash hands after use.

After

each day's

use. wash gloves, goggles and contaminated clothing.

FIRST

isoning

occu

contact

octor

Poisons Information

Centre. Phone Australia 131126.

tional

nformation

listed

Material

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Care

tralasia

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36234

Unit

115 Metroplex Avenue

Murarrie

4172

: (0

3909

2000

APVMA

Approval

No.: 47538/1206

! WM/

A1041-BKT

POISON

KEEP

REACH

CHILDREN

READ

DIRE

CTIONS

EFORE

OPEN

suSCon

·

BLUE

SOIL

INSECTICIDE

ACTIVE

CONSTITUENT:

gJkg

LORPYRIFOS

anti

erase

compound!

GROUP

i I

:]

IN

SECTICI

DE

Controls cane grubs

three years

using sustained control technology.

IMPORTANT

READ

THIS

LEAFLET

BEFORE

USING

PRODUCT

Crop

Care

Australas

Unrt

Me!rople~

Murame

4172

CS: 1.5.27

Page: 1 Material Safety Data Sheet

Infosafe No™3NU7O November 2011 ISSUED by CRPCARE Issue Date:

suSCon Blue Soil Insecticide Product Name

Classified as hazardous

1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER

Product Name suSCon Blue Soil Insecticide

Product Code 1041

Product Type Group 1B Insecticide

CompanyName Crop Care Australasia Pty Ltd (ABN 53 061 362 347)

Address Unit 15/16 Metroplex Avenue Murarrie

Queensland 4172 Australia

Emergency Tel. 1800 033 498 (24hr Australia)

Telephone/Fax

Number Tel: +61 7 3909 2000

Fax: +61 7 3909 2010

Recommended Use This product controls cane grubs for up to three years using sustained control

technology.

2. HAZARDS IDENTIFICATION

Hazard

Classification Classified as hazardous

HAZARDOUS SUBSTANCE.

NON-DANGEROUS GOODS.

Hazard classification according to the criteria of NOHSC.

Dangerous goods classification according to the Australia Dangerous Goods

Code.

Risk Phrase(s) Classified as hazardous

R21/22 Harmful in contact with skin and if swallowed.

SafetyPhrase(s) S13 Keep away from food, drink and animal feeding stuffs.

S2 Keep out of reach of children.

S46 If swallowed, seek medical advice immediately and show this container or

label.

Other Information Poisons Schedule S6

3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical

Characterization Solid

CAS Proportion Name Ingredients

2921-88-2 Chlorpyrifos 140g/kg

Other ingredients

(considered

non-hazardous) >60%

SubstanceChemical

Family Organophosphate

4. FIRST AID MEASURES

Inhalation Over-exposure by inhalation is improbable. Check for other causes of observed

symptoms and seek medical advice.

Ingestion Rinse mouth and then drink plenty of water.

If poisoning occurs, contact a doctor or the Poisons Information Centre

(Australia) on 13 11 26.

Skin Wash affected areas thoroughly with soap and water.

Remove contaminated clothing and launder before re-use.

If irritation persists, seek medical advice.

Eye If in eyes, hold eyelids open and wash with copious amounts of water for at

least 15 minutes.

Seek medical advice if irritation develops or persists.

First Aid Facilities If poisoning occurs, contact a doctor or the Poisons Information Centre

(Australia) on 13 11 26.

Advice to Doctor An anticholinesterase compound.

The active ingredient is embedded in a polymer matrix. It is highly

improbable that it can be swallowed, excessive exposure via skin or eye

contact is possible, but unlikely. A treatment for cholinesterase inhibition

Artificial respiration should be started at the first sign of respiratory

Print Date: 24/11/2011 CS: 1.5.27

CS: 1.5.27

Page: 2 Material Safety Data Sheet

Infosafe No™3NU7O November 2011 ISSUED by CRPCARE Issue Date:

suSCon Blue Soil Insecticide Product Name

Classified as hazardous

failure. Cautious administration of fluids is advised, as well as general

supportive and symptomatic pharmacological treatment and absolute rest. As

early as possible, administer 2 mg of atropine sulfate i.v. and 1000-2000 mg

of pralidoxime chloride or 250 mg of obidoxime chloride (adult dose) i.v. to

patients suffering from severe respiratory difficulties, convulsions, and

unconsciousness. Repeated doses of 2 mg of atropine sulfate should be given,

as required, based on the respiration, blood pressure, pulse frequency,

salivation, and convulsion conditions. The dose and the frequency of atropine

varies with each patient, but the patient should remain fully atropinised

(signs include dilated pupils, dry mouth, skin flushing). Diazepam should be

given in all but the mildest cases in doses of 10 mg, s.c. or i.v., which may

be repeated as required. For children, the doses are 0.04-0.08 mg of

atropine/kg body weight, 250 mg of pralidoxime chloride per child, or 4-8 mg

of obidoxime chloride/kg body weight. Morphine, barbiturates, phenothiazine

derivatives, tranquillizers, and all kinds of central stimulants are

contraindicated.

5. FIRE FIGHTING MEASURES

Suitable

Extinguishing Media Water fog, foam, carbon dioxide or dry chemical.

Hazards from

Combustion

Products Non-combustible.

If involved in a fire, it will emit oxides of carbon, oxides of nitrogen and

possibly hydrogen chloride, sulfur oxides or phosphorus oxides.

Special Protective

Equipment for fire

fighters Breathable air apparatus must be worn when fighting a fire in which this

product is involved.

Other Information STOP FIRE WATER FROM ENTERING DRAINS OR WATER BODIES.

6. ACCIDENTAL RELEASE MEASURES

Spills & Disposal Recover the product by sweeping up or vacuuming without raising dust.

Collect spilled material and waste in sealable open-top type containers for

disposal.

Personal Protection For appropriate personal protective equipment (PPE), refer Section 8.

7. HANDLING AND STORAGE

Precautionsfor Safe

Handling Do NOT contaminate dams, rivers or streams, or any other water bodies with

chemical or used containers.

Conditions for Safe

Storage Store in the closed, original container in a dry, well ventilated area out of

direct sunlight.

Other Information Always read the label and any attached leaflet before use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

National Exposure

Standards Safe Work Australia has set the following exposure standard for chlorpyrifos:

TLV (TWA) 0.2 mg/m3, STEL -. SK

'SK' notice - absorption through the skin may be a significant source of

exposure. The exposure standard is invalidated if such contact should occur.

The active ingredient is embedded in a plastic matrix.

The physical nature of the product significantly reduces contact with the

active ingredient.

Engineering

Controls Handle in well ventilated areas, generally natural ventilation is adequate.

Personal Protective

Equipment When using the product, wear cotton overalls buttoned to the neck and wrist

(or equivalent clothing), elbow-length PVC gloves,goggles and disposable dust

cartridge.

Hygiene Measures After use and before eating, drinking or smoking, wash hands, arms and face

thoroughly with soap and water.

After each day's use, wash contaminated clothing and safety equipment.

Requirements

Concerning Special

Training Check State or Territory regulations that require people who use pesticides in

their job or business to have training in the application of the materials.

Print Date: 24/11/2011 CS: 1.5.27

CS: 1.5.27

Page: 3 Material Safety Data Sheet

Infosafe No™3NU7O November 2011 ISSUED by CRPCARE Issue Date:

suSCon Blue Soil Insecticide Product Name

Classified as hazardous

9. PHYSICAL AND CHEMICAL PROPERTIES

Form Solid

Appearance Blue granules

Odour Mild mercaptan odour

MeltingPoint 100°C for product

Solubility in Water Not soluble.

VapourPressure 2.7 mPa for chlorpyrifos

Octanol/Water

PartitionCoefficient Kow Log P is 4.7 for chlorpyrifos

Flammability Non combustible material.

10. STABILITY AND REACTIVITY

Chemical Stability Stable under normal conditions.

Hazardous

Polymerization Hazardous polymerisation is not possible.

11. TOXICOLOGICAL INFORMATION

Toxicology

Information No harmful effects are expected if the precautions on the label and this MSDS

are followed.

Inhalation Not a likely route of exposure due to the physical form of the product.

Ingestion Possible symptoms of exposure include: nausea, vomiting and central nervous

system depression.

Skin Not a likely route of exposure due to the physical nature of the product.

Eye Not a likely route of exposure due to the physical nature of the product.

Chronic Effects Regular exposure may result in lowering of cholinesterase activity which will

recover within a few days after exposure ceases.

Reproductive

Toxicity Data indicates no reproductive effects.

Data indicates no teratogenic effects.

Carcinogenicity Data indicates no carcinogenic effects.

Acute Toxicity- OralLD50 (rat) >800 mg/kg for the product

Acute Toxicity -

Dermal LD50 (rat) >2000 mg/kg for chlorpyrifos

Acute Toxicity -

Inhalation LC50 (rat) (4hr) >0.2 mg/l for chlorpyrifos

Eye Irritation Not an eye irritant.

Skin Irritation Not a skin irritant.

Skin Sensitisation Product is not a skin sensitiser.

Other Information The Australian Acceptable Daily Intake (ADI) for chlorpyrifos for a human is

0.003 mg/kg/day, set for the public for daily, lifetime exposure. This is

based on the NOEL of 0.03 mg/kg/day, the level determined to show no effects

during long term exposure for the most sensitive indicators and the most

sensitive species. (Ref: Comm. Dept. of Health and Ageing Office of Chemical

Safety and Environmental Health, 'ADI List', June 2011).

12. ECOLOGICAL INFORMATION

Persistence /

Degradability Average field half life of chlorpyrifos is 33 - 56 days.

Known Harmful

Effectsonthe

Environment The product is a marine pollutant for sea transport.

Other Precautions Do not contaminate streams, rivers or waterways with the chemical or used

containers.

Do not leave granules above ground as they are dangerous to wildlife,

Print Date: 24/11/2011 CS: 1.5.27

CS: 1.5.27

Page: 4 Material Safety Data Sheet

Infosafe No™3NU7O November 2011 ISSUED by CRPCARE Issue Date:

suSCon Blue Soil Insecticide Product Name

Classified as hazardous

particularly birds.

Acute Toxicity - Fish The following is data for the active ingredient, chlorpyrifos.

LC50 (96hr) for rainbow trout is 0.007 - 0.051 mg/l.

LC50 (96hr) for rainbow trout is 8.5 mg/l for a similar product

Acute Toxicity -

Daphnia LC50 (48hr) for daphnia is 0.0017 mg/l for chlorpyrifos.

Acute Toxicity -

Other Organisms The following data is for the active ingredient, chlorpyrifos.

LD50 for mallard ducks is 490 mg/kg

Bees: Toxic to bees. LD50 0.07 µg/bee.

Because of its physical state, this product is not expected to be toxic to

bees.

13. DISPOSAL CONSIDERATIONS

Product Disposal Ideally, the product should be used for its intended purpose. If there is a

need to dispose of the product, approach local authorities who hold periodic

collections of unwanted chemicals (ChemClear®).

Container Disposal Shake the last amount of product from the bag into application equipment.

Do not dispose of undiluted chemicals on site. Puncture or shred and bury

empty containers in a local authority landfill.

If no landfill is available, bury the containers below 500mm in a disposal pit

specifically marked and set up for this purpose clear of waterways, desirable

vegetation and tree roots.

Empty containers and product should not be burnt.

14. TRANSPORT INFORMATION

Storage and

Transport Considered non dangerous for road and rail transport (in packaging) by the

Australian Code for the Transport of Dangerous Goods by Road and Rail. Ref:

ADG7; SP No. AU01.

For bulk shipments as Class 9, use UN 3077, HazChem code 2Z.

UN Number (Sea

Transport) 3077

IMO Class/Packing

Group Class 9; Packing Group III

IMO Marine

Pollutant Marine Pollutant

IMO Proper

Shipping Name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.

(Contains Chlorpyrifos)

15. REGULATORY INFORMATION

Poisons Schedule S6

Packaging &

Labelling POISON

KEEP OUT OF REACH OF CHILDREN

READ SAFETY DIRECTIONS BEFORE OPENING OR USING

Hazard Category Harmful

AICS (Australia) All of the components in this product are listed on the Australian Inventory

of Chemical Substances.

16. OTHER INFORMATION

Date of preparation

or last revision of

MSDS Reviewed 23/11/2011

Contact

Person/Point Normal Hours: Mrs Kathleen Marsh Phone: +61 3 9282 1000

After Hours: Shift Supervisor Phone: 1800 033 498

Revisions

Highlighted The MSDS was reviewed. Minor changes were made to the information.

...End Of MSDS...

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Print Date: 24/11/2011 CS: 1.5.27

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