SUMITHION 1000EC INSECTICIDE

Australia - English - APVMA (Australian Pesticides and Veterinary Medicines Authority)

Active ingredient:
FENITROTHION
Available from:
SUMITOMO CHEMICAL AUSTRALIA PTY LIMITED
INN (International Name):
fenitrothion(1000g/L)
Pharmaceutical form:
EMULSIFIABLE CONCENTRATE
Composition:
FENITROTHION ORGANOPHOSPHORUS Active 1000.0 g/L
Units in package:
10L; 2.4L; 205L; 20L; 5L
Class:
A - Agricultural
Manufactured by:
SUMITOMO CHEMICAL
Therapeutic group:
APPLE | BROILER POULTRY HOUSE,LITTER,WALL & ROOF | CABBAGE | CEREAL CROP | CHERRY | FEED BIN | FEED SHED | GRAIN STORAGE AREA AN
Therapeutic area:
INSECTICIDE
Therapeutic indications:
AUSTRALIAN PLAGUE LOCUST | BLACK BEETLE | CORBIE | FLOUR BEETLES | GRAIN WEEVIL | INDIAN MEAL MOTH | LESSER GRAIN BORER | LESSER MEALWORM | MIGRATORY LOCUST | OXYCANUS GRASS GRUB | PASTURE COCKCHAFER | SAWTOOTHED GRAIN BEETLE | SITONA WEEVIL | SPUR-THROATED LOCUST | STORED GRAIN INSECT PESTS | TROPICAL WAREHOUSE MOTH | UNDERGROUND GRASS GRUB | WINGLESS GRASSHOPPER | WINTER CORBIE | BLACK BEETLE | DARKLING BEETLE | GRAIN BORER | LITTER BEETLE | NOMADACRIS GUTTULOSA | SITOPHILUS GRANARIUS | SITOPHILUS ORYZAE | SITOPHILUS ZEAMAIS | TRIBOLIUM CASTANEUM | TRIBOLIUM CONFUSUM | TRIBOLIUM SPP.
Product summary:
Poison schedule: 6; Withholding period: WHP: Stored Cereal Grain:Hold grain tr eated at 12ppm* in store and do not use for processing into food for human co nsumption or for stock feed for 90 days after treatment. *ppm+Parts per millio n fenitrothion on grain (mg/kg). Crops for human consumption: Apples cabbage s cherries grapes, lettuce soyabean tomato cereal crops: Do not harvest f or 14 days after application. Crops fo r animal consumption/stockfeed: Pasture and Lucerne where stock have not been oversprayed:Do not graze for 7 days af ter application or withhold stock from slaughter for 14 days after applicatio n whichever is appropriate. Do not cut for stockfeed for 14 days after applic ation. Pasture (including Lucerne) wher e stock have been oversprayed:Do not sl aughter for 14 days after application. Sorghum cereal straw and fodder, past ure seed crops forage crops:Do not gra ze or cut for stock feed for 14 days af ter application.; Host/pest details: APPLE: [AUSTRALIAN PLAGUE LOCUST, MIGRATORY LOCUST, SPUR-THROATED LOCUST, WINGLESS GRASSHOPPER]; BROILER POULTRY HOUSE,LITTER,WALL & ROOF: [BLACK BEETLE, LESSER MEALWORM]; CABBAGE: [AUSTRALIAN PLAGUE LOCUST, MIGRATORY LOCUST, SPUR-THROATED LOCUST, WINGLESS GRASSHOPPER]; CEREAL CROP: [AUSTRALIAN PLAGUE LOCUST, MIGRATORY LOCUST, SPUR-THROATED LOCUST, WINGLESS GRASSHOPPER]; CHERRY: [AUSTRALIAN PLAGUE LOCUST, MIGRATORY LOCUST, SPUR-THROATED LOCUST, WINGLESS GRASSHOPPER]; FEED BIN: [FLOUR BEETLES, GRAIN WEEVIL, INDIAN MEAL MOTH, SAWTOOTHED GRAIN BEETLE, STORED GRAIN INSECT PESTS, TROPICAL WAREHOUSE MOTH]; FEED SHED: [BLACK BEETLE, LESSER MEALWORM]; GRAIN STORAGE AREA AND/OR FACILITY: [FLOUR BEETLES, GRAIN WEEVIL, INDIAN MEAL MOTH, SAWTOOTHED GRAIN BEETLE, STORED GRAIN INSECT PESTS, TROPICAL WAREHOUSE MOTH]; GRAPE: [AUSTRALIAN PLAGUE LOCUST, MIGRATORY LOCUST, SPUR-THROATED LOCUST, WINGLESS GRASSHOPPER]; LETTUCE: [AUSTRALIAN PLAGUE LOCUST, MIGRATORY LOCUST, SPUR-THROATED LOCUST, WINGLESS GRASSHOPPER]; LUCERNE: [AUSTRALIAN PLAGUE LOCUST, MIGRATORY LOCUST, SITONA WEEVIL, SPUR-THROATED LOCUST, WINGLESS GRASSHOPPER]; MILL AND/OR FOOD PROCESSING PLANT: [FLOUR BEETLES, GRAIN WEEVIL, INDIAN MEAL MOTH, SAWTOOTHED GRAIN BEETLE, STORED GRAIN INSECT PESTS, TROPICAL WAREHOUSE MOTH]; PASTURE: [AUSTRALIAN PLAGUE LOCUST, CORBIE, MIGRATORY LOCUST, OXYCANUS GRASS GRUB, PASTURE COCKCHAFER, SPUR-THROATED LOCUST, UNDERGROUND GRASS GRUB, WINGLESS GRASSHOPPER, WINTER CORBIE]; PASTURE SEED AND FORAGE CROPS: [AUSTRALIAN PLAGUE LOCUST, MIGRATORY LOCUST, SPUR-THROATED LOCUST, WINGLESS GRASSHOPPER]; PEST CONTROL - GRAIN PROTECTION: [FLOUR BEETLES, GRAIN WEEVIL, INDIAN MEAL MOTH, LESSER GRAIN BORER, SAWTOOTHED GRAIN BEETLE, STORED GRAIN INSECT PESTS, TROPICAL WAREHOUSE MOTH]; SORGHUM - GRAZING: [AUSTRALIAN PLAGUE LOCUST, MIGRATORY LOCUST, SPUR-THROATED LOCUST, WINGLESS GRASSHOPPER]; SOYBEAN: [AUSTRALIAN PLAGUE LOCUST, MIGRATORY LOCUST, SPUR-THROATED LOCUST, WINGLESS GRASSHOPPER]; STORED CEREAL GRAIN: [FLOUR BEETLES, GRAIN WEEVIL, INDIAN MEAL MOTH, SAWTOOTHED GRAIN BEETLE, STORED GRAIN INSECT PESTS, TROPICAL WAREHOUSE MOTH]; STORED CEREAL GRAIN - 3-6 MONTHS STORAGE: [FLOUR BEETLES, GRAIN WEEVIL, INDIAN MEAL MOTH, SAWTOOTHED GRAIN BEETLE, STORED GRAIN INSECT PESTS, TROPICAL WAREHOUSE MOTH]; STORED CEREAL GRAIN - FOR UP TO 3 MONTHS: [FLOUR BEETLES, GRAIN WEEVIL, INDIAN MEAL MOTH, SAWTOOTHED GRAIN BEETLE, STORED GRAIN INSECT PESTS, TROPICAL WAREHOUSE MOTH]; STORED PRODUCT FACILITIES: [FLOUR BEETLES, GRAIN WEEVIL, INDIAN MEAL MOTH, SAWTOOTHED GRAIN BEETLE, STORED GRAIN INSECT PESTS, TROPICAL WAREHOUSE MOTH]; TOMATO: [AUSTRALIAN PLAGUE LOCUST, MIGRATORY LOCUST, SPUR-THROATED LOCUST, WINGLESS GRASSHOPPER]; TRANSPORT EQUIPMENT: [FLOUR BEETLES, GRAIN WEEVIL, INDIAN MEAL MOTH, SAWTOOTHED GRAIN BEETLE, STORED GRAIN INSECT PESTS, TROPICAL WAREHOUSE MOTH]; For the control of locust and grasshopper pests of broadacre and horticultural crops, for the protection of cereal grain against stored product insect pests and for the control of various pests of pasture.DO NOT APPLY BY AIRCRAFT AT RATES > 350mL/ha. USE IN STORED GRAIN IN WA BY BULK HANDLING AUTHORITIES ONLY. See RESIDUES MANAGEMENT section of label.
Authorization status:
Registered
Authorization number:
50775
Authorization date:
2019-07-01

POISON

KEEP

REACH

CHILDREN

READ

SAFETY

DIRE&nONS

BEFORE

OPENING

GROUP

il

:J

INSEC

CIDE

control

ocust

grasshopper

pests

broadacre

cu.ltu

iOo:

protection

cereal

stored

product

nsect

pests

various

pests

paslure

Direct

table

IMPORTANT:

READ

ATTACHED

BOOKLET

BEFORE

USING

THIS

PRODUCT

SUMITOMO

OiEMICAL

,..Lid

011255

242--EI'PIIII-2111

Pbocll:(aZ)171Z-

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CONTENTS:

ORGANOPHOSPHOROUS

PEST

CIDE,

LIQUID,TOXIC

(FEN

TROTHION)

3018

HAZCHEM

PACKAGING

GROUP

Transport

Emergency

Dial

Police

Fire

Brigade

PROTECTIO

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N'VMA

Approval

50775/2

Info

pest

Verified

POISON

KEEP OUT OF REACH OF CHILDREN

READ SAFETY DIRECTIONS BEFORE OPENING OR USING

SUMITHION®

OOOEC

INSECTICIDE

ACTIVE CONSTITUENT:

1000 g/L FENITROTHION

antichol

inesterase

compound

GROUP

INSECTICIDE

For the control

locust and grasshopper pests

broadacre and horticultural crops,

for the protection

cereal grain against stored product insect pests and for the

control

various pests

pasture as per Directions for Use table.

IMPORTANT: READ THE ATTACHED

BOOKLET

BEFORE USING THIS

PRODUCT

CONTENTS 2.4L, 5L, 20L, 205L

SUMITOMO

CHEMICAL

SUMITOMO CHEMICAL AUSTRALIA PTY L

242 "Beecroft Road

EPPING

NSW 2121

Tel: 02 8752 9000

096 255

PROTECTION OF LIVESTOCK, FISH, CRUSTACEA AND ENVIRO

NM

ENT

DO NOT apply under meteorological conditions

from spraying equipment which

could be expected to cause spray drift

run-off onto sensitive areas such as natural

streams, rivers, wetlands, natural surface waters, waterways, human dwellings and

neighbouring properties. Buffer zones should be observed as per label directions.

Dangerous to fish. DO NOT contaminate streams, rivers

waterways with the

chemical

used containers.

Dangerous to bees. DO NOT spray any plants in flower while bees are foraging.

STORAGE AND DISPOSAL

Store in the closed original container in a cool, well-ventilated area. Do not store

prolonged periods in direct sunlight.

Triple

preferably pressure rinse containers before disposal. Add rinsings to spray

tank. Do not dispose

undiluted chemicals on site.

recycling, replace cap and

return clean containers to recycler

designated collection point.

not recycling, break, crush

puncture and bury empty containers

a local

authority landfill.

no landfill is available, bury the containers below 500mm in a

disposal pit specifically marked and set up for this purpose clear

waterways,

desirable vegetation and tree roots. Empty containers and product should not be

burnt.

SAFE

TY

DIRECTIONS

Product is poisonous if absorbed by skin contact, ·inhaled

swallowed. Repeated

minor exposure may have a cumulative poisoning effect. Avoid contact with eyes

and skin. Do not inhale spray mist.

When opening the container, preparing spray and using the prepared spray, wear

cotton overalls buttoned to the neck and wrist and washable hat, elbow-length PVC

gloves and face shield. When using in enclosed areas, wear goggles and half-

facepiece respirator with combined dust and gas cartridge.

product on skin,

immediately wash area with soap and water. After use and before eating, drinking

smoking, wash hands, arms and face thoroughly with soap and water. After each

day's use, wash contaminated clothing, gloves, face shield, goggles and respirator

rubber wash with detergent and warm water.

FIRST AID

swallowed, splashed on skin

in eyes,

"-"'

@~a~'Cf

contact a Poisons Information

Centre (Phone: Australia

126)

a doctor at once.

Remove any contaminated

clothing and wash skin thoroughly.

swallowed, activated charcoal may be advised.

Give Atropine if instructed.

----

----

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- ---

------

----

- -- -]

Sumithion 1000EC Insec

label

(5077

4/xxx

· .

22/0212010

______

_____

________

____

_____

____

____

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_______

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EXCLUSION

LIABILITY

Unless otherwise expressly stated

writing neither Sumitomo Chemical Australia Pty Ltd nor the distributor has

any knowledge

the particular use to which the buyer proposes to put this product.

purchasing this product

the buyer must rely solely upon their own skill and judgement as to its suitability for the particular purpose for

which it is required.

Except to the extent that exclusion

denial

liability is prohibited under the Trade

Practices Act

any relevant state legislation, Sumitomo Chemical Australia Pty Ltd and the distributor expressly

exclude any warranty as to the quality or fitness

any goods sold for any purpose whatsoever and deny all

responsibility in contract tort negligence

otherwise for any harm

damage resulting from the use

such

goods

from acting on the advice or recommendations as to such use given in good faith by any representative

Sumitomo Chemical Australia Pty Ltd

the distributor.

these conditions are unacceptable to the buyer, the

goods should be returned to Sumitomo Chemical Australia Pty Ltd unopened within seven (7) days for refund

purchase price.

UN No. 3018

ORGANOPHOSPHOROUS PESTICIDE, LIQUID, TOXIC (FENITROTHION)

PACKAGING GROUP Ill, HAZCHEM 2X

In a Transport Emergency

Dial 000

Police or Fire Brigade

SPECIALIST ADVICE IN EMERGENCY ONLY

1800 024 973

HOURS-

AUSTRALIA WIDE

APVMA Approval No: 50775/2.4L/011 0

APVMA Approval No: 50775/5L/011 0

APVMA Approval No: 50775/20L/011 0

APVMA Approval No: 50775/205L/011 0

Batch No:

Date

Manufacture:

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ACTIVE

CONSTI

UENT

1000

g/1.

RDTHIDN

compou

contr?

ocus

grasshopper

pests

broad

acre

horticu

protection

cereal

stored

product

insect

pests

mllf~

l:=-:;:::::;.­

pests

pasture

ections

IMPORTANT:

ATTACHED

BEFORE

THIS

PROD

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Sumltcmo

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BIICIOft

Raid

EPPINGJI&W2111

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(02)

8752 8000

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conditions

from

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couldbiiXPIC!edtociiUStspraydtlflorrun-

onto

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such

natural

strums,

~vera,

wl!!lands

natural

surfa

wata11,

watarways,

human

wellings

ghbo

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rope

Buller

zonas

ould

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l di

rections

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llsh.

contamlnata

streams

waterwoys

with

chem

conta

Dang

sraus

spray

ants

llowerwh

bees

orag

DISP

Store

osed

glna

container

In a

cool

·venmated

store

onged

In di

rect

unli

prefe

ly pr

essure

ners

fore

sposa

slngs

tank

spose

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In a

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purpose

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Product

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absorbed

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ashed

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Centre

: Ausnlla

126)

doctor

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cloth

wash

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ough

ly. If

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acti

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Inst

ucted

EXCLUSI

LIABILitY

otherw

expressly

tated

ther

Chem

Austra

r the dl

strtb

or h

know

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poses

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buyer

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ly u

skill

udgement

lar pu

rpose

It Is

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Except

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Is pro

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mergency

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SPEC

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IN E

MERG

ENCY

ONLY

HOURS

AUSTRAUA

1800

POISON

KEEP

OUT

OF

REACH OF CHILDREN

READ SAFETY DIRECTIONS BEFORE OPENING

OR

USING

SUMITHION®

1

OOOEC

INSECTICIDE

ACTIVE CONSTITUENT:

1000 g/L FENITROTHION

An anticholinesterase compound

GROUP

INSECTICIDE

For the control

locust and grasshopper pests

broad acre and horticultural crops,

for the protection

cereal grain against stored product insect pests and

control

various pests

pasture as per Directions for Use table.

IMPORTANT: READ THE ATTACHED BOOKLET BEFORE USING THIS

PRODUCT

CONTENTS 2.4L, 5L, 20L, 205L

SUMITOMO

CHEMICAL

SUMITOMO CHEMICAL AUSTRALIA PTY LTD

242 Beecroft Road

~PPI

NSW 2121

Tel: 02 8752 9000

25"5

®Registered Trademark

Sumitomo Chemical Co. Japan

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-----

Sumithion 1

OOOEC

Insecticide draft label (507751 Oct 2009)

03/1112009

____

____

____

____

_______

____

_____

~<!f!!!_~t--~

-----

PROTECTION OF

LI

VESTOCK, FISH, CRUSTACEA AND ENVIRO

NM

ENT

DO NOT apply under meteorological conditions or from spraying equipment which

could be expected to cause spray drift

run-off onto sensitive areas such as natural

streams, rivers, wetlands, natural surface waters, waterways, human dwellings and

neighbouring properties. Buffer zones should be observed as per label directions.

Dangerous to fish.

NOT contaminate streams, rivers

waterways with the

chemical

used containers.

Dangerous to bees. DO NOT spray any plants in flower while bees are foraging.

STORAGE AND DISPOSAL

Store in the closed original container in a cool, well-ventilated area. Do not store

prolonged periods in direct sunlight.

Triple

preferably pressure rinse containers before disposal. Add rinsings to spray

tank. Do not dispose

undiluted chemicals on site. If recycling, replace cap and

return clean containers to recycler

designated collection point.

not recycling, break, crush

puncture and bury empty containers

a local

authority landfill.

no landfill

available, bury the containers below 500mm in a

disposal pit specifically marked and set up for this purpose clear

waterways,

desirable vegetation and tree roots. Empty containers and product should not be

burnt.

SAFETY DIRECTIONS

Product is poisonous

absorbed by skin contact, ·inhaled

swallowed. Repeated

minor exposure may have a cumulative poisoning effect. Avoid contact with eyes

and skin. Do not inhale spray mist.

When

opening the container, preparing spray and using the prepared spray, wear

cotton overalls buttoned to the neck and wrist and washable hat, elbow-length PVC

gloves and face shield. When using in enclosed areas, wear goggles and half-

facepiece respirator with combined dust and gas cartridge.

product on skin,

immediately wash area with soap and water. After use and before eating,

inking

smoking, wash hands, arms and face thoroughly with soap and water. After each

day's use, wash contaminated clothing, gloves, face shield, goggles and respirator

and if rubber wash with detergent and warm water.

FIRST AID

swallowed, splashed on skin

in eyes,

contact a Poisons Information

Centre (Phone: Australia

126)

a doctor at once.

Remove any contaminated

clothing and wash skin thoroughly. If swallowed, activated charcoal may be advised.

Give Atropine

instructed.

f

slimiihion

toooEc

tnse

cii

cide

(i;.-;iii

a

beli5o

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_____

~~2d3

~----

-------

----

---------

-----

-----

EXCLUSION OF LIABILITY

Unless otherwise expressly stated in writing neither Sumitomo Chemical Australia Pty Ltd nor the distributor has

any knowledge

the particular use to which the buyer proposes to put this product.

purchasing this product

the buyer must rely solely upon their own skill and judgement

to its suitability for the particular purpose for

which it is required. Except to the extent that exclusion or denial

liability is prohibited under the Trade

Practices Act

relevant state legislation, Sumitomo Chemical Australia Pty Ltd and the distributor expressly

exclude any warranty as to the quality

fitness

any goods sold for any purpose whatsoever and deny all

responsibility

contract tort negligence or otherwise for any harm or damage resulting from the use

such

goods or from acting on the advice

recommendations as to such use given

good faith by any representative

Sumitomo Chemical Australia Pty Ltd

the distributor. If these conditions are unacceptable to the buyer, the

goods should

returned to Sumitomo Chemical Australia Pty Ltd unopened within seven (7) days for refund

purchase price.

UN No. 3018

ORGANOPHOSPHOROUS PESTICIDE, LIQUID, TOXIC (FENITROTHION)

PACKAGING GROUP Ill, HAZCHEM

a Transport Emergency

Dial 000

Police

Fire Brigade

SPECIALIST ADVICE

EMERGENCY ONLY

1800 024 973

HOURS-

AUSTRALIA WIDE

APVMA Approval

50775/2.4L/0110

APVMA Approval No: 50775/5L/011 0

APVMA Approval No: 50775/20L/011 0

APVMA Approval No: 50775/205L/011 0

Batch

Date

Manufacture:

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- ----------------

Sumithion 1000EC

secticide draft label (50774/xxxx/0110)

22/02/2010

_____

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!:::!

,_!!

...,

""

....

--lo.

&::

0

E

0

i

?f2.

"

TIOII

N/CROP

Slrutl

eatme

Cetnl grlin

StG."~~!

pmdu:a

store

f'klur

v,-an-houses

pmc~sing

ttwport

.r'pmurt.

tni'n!l f

e!i:l

ureaJ

gra·

stol!d

inbu"

l(fOtp!fiGdsol

3-Sm

ontla.

olecl1o:J

Ancer!!lQli

S!Jol'!

~1b-J!k

orpWdii!SS

lhL1

ltlf!!

monttli.

tmea

!:<S!~!de!t!al

grain,

tacks

at

b~~s

etc.

1 Prolet

rpoJllyho:zs!

, v.-a

roola:-d

feeds

<ds

Stored

rodu~llns!t

p!sts

~clulf~

suscop:b~

so.Hn

~e~:eifi

oratn

~:.!~~~;:~005,

moth(butnotlesserorW

bater

Pasts

abvvep

slesse~

grinbom

ltss

ermu:V.

·orm(atti

beetle

oamng

b!Etie

(6~ckt~<e!le

S

tat!s

(L1WAf!)f

bt£<

auU:JOOes

RATE

v.-aar

U1 1

Mt!r

2J>P111)"

6lln

watu

(6ppm)

tOOL

watar

Ratuas

!lO'i-aplls

Sum~M

nug~!:d

~te:ctintil

L't!

~COnYn~

VIOOL

Wii~(IOL

d"

'!Jt!dSPri'/

~uts7Dm~

L-...2

----~--

---l..-____.1..______.

L..:.__

_________

ACnVE

SnTUEHT:

1000

g/1.

FEHITROTHION

antichol!neste.ast

compound

GROUP

11:1

CTICIDE

k>r

control

locust

g.ass

hopper

pests

broadacre

hortlcu

ural

crops.

tection

cereal

against

stored

product

insect

pests

control

various

pests

pasture

Directions

IMPORTANT

READ

THIS

BOOKLET

BEfORE

THIS

PRODUCT

THIS

BOOKLET

PART

LABEl

SUMiTOMO

CHEMICAL

--1'11'1.1!1

lo!!t

01109SIS5

-RooiEJ'PViGNSW

(QIJ175Uootl

CRITICAL

COMM

IITS

pp:,.'y

mht!Jre

tor.

~')~

dilJtt

s~ey

poJlr)'

sh!d

rtw,

wa:s

roo!.

Spray

llld

oll'le

p!ices

where

b~tles

lt4~

b;fo!l

S')rulf.r,o

lli.er

hlpfD'."!

®W'Ied

'her

spt3)'

-.::oipoii!td

"'to

lltet.

ho:sse

laye

b!rds

recerttJ

treat!d

sh!ds.

vo:d

contam.1atlon

c:h)ck!n

d and

a!O'N

S')fiY

ch b1

n!~Xt

shed

Sp;ay

sheds

alte

r n ch

baich

.Grs

Is l

o:lt

siKHt:'/

befo

re·stoc

. ·ng.

<0

>

---L.~

0

cf2.

i

---;-

f

!,;?

!i

-

H~HJHU

iJJfi~~ru

JJ1!

"-

fPHPH

~PPHfH

DIRECTIDIIS

(con

Yn""

d)

SITUAT

N/CRO

PEST

Pcl

stui'!,

Pasture

S

eed

Sp:~

lt\."Dated

must.

Cr

o-;>s

.

Fo

r

1ge

C

rops

Mlgn!ory

locust

nc~lf"'

ll!Wlg

Sorg

hum

,

lucerne,

~~::

ans.

C!

r

nl

{~less

G

tassl'.oppoo.r

Ap;>

:

es

,

Ca~~!J

S

pJ

:

-throatr:d

locust,

C

he;rt!s,

Gra

pa..s,

M9ratof)'

locus

t

lett!Jee

and

Tomatoes

\

1

f

ill

!(ess

G

ras

s

tloppu

PastJrt,

Pas

ture

SeW

Australian

Piagn

L

ocust

C

rops,

foiage

C

ro;>s

ncwr.·~

aU>

o.~h"Jm

Luttrne

Ce

rea

l

Cro

ps,

~!li\S,

~ilges,

hsrrt--..s,

Gr

ar..s

.

lettuce

iiid

Torni!~s

Luce

rM

Sl o:

iJWe!'r11

Pastu

re

Pa

s

ture

Cocktllafer

Corb

'e, \'li

r.

t!

r

Corb'~

RATE

Q'd,

2701D

&

.Jln

on.'y

USW,

VIC,

SA

&1'/Ao

SW,V~

WAo1¥

300:rlfna

550mtlha

300mllh3

1151

'/,Q:d,

&

00mllh3

~~5,

SAo-

/,Tas

SAon.'y

Taso

n,

y

250

m

l.Jha

ml/ha

300

m

!fttJ

0011Vha

~S011l/na

-----

------

----~

RECTIOilS

(

conYD"'

d)

ITUATION/CROP

PEST

STATE

RATE

U

OOu

gr

oJOO

G

ms

G

ru

::t

'!(/v"'

SOD-

aoo

m

vr.a

:nl ·

t.Ollh>

(b.)

'ti

ii

:JSON!I

V.c.

1.

1

.3!1h.J

SA

,

Taso

IIOT

USED

PURPOSE

MAIIIIER

APPROPRIATE

LEGISLATION

FOLLOWIUG

CROPS

YUlES

CABBAGES

IES,

GRAPES,

LETTUCE,

SOYA

BEAU

TOMATO

OTHER

PURPOSE

(PESnTHAU

LOCUST

AIID

GRASSHOPPER

COIHROL

APPLY

THIS

PRODUCT

AIRCRAFT

RATES

GREAT

THAll

DMLJHA

STORED

GRAUl

BULK

ilDllllG

DillY

RESIDUES

MAUAGEMEilT

APPLICATIDII

IITERVALS

Pa

stu

re,

l

ucerne

vals of

less

Ulan

11!\en

used

graz

IIOT

app~

ervals

of l

14 d

when

app~

ervals

less

Ulan

days

where

stoc

verspraylld

Pa

sture

sud

crops

, ce

rea

l

crops

, Ia

rage

c

rops,

orn

ln

g

so

rg

hum,

appl

cabbages,

chenles,

pes,lelluce

oes,

soybean

pp~a

lnlervals

less

Ulan

days

UdJys(G)

CRmCAL

EIITS

Relet

lo

Genual l

n.

st

ro

cllo

ns

on

B

utfu

ton

es

pr

i

or

to

use

.

Use

o!Er

nte

tJ

ro:.~gh

s

:.

lab:t:

boo'Tl

spr

ayer

in

cco;ts

a~alnst

adul

ushop~ms

For

P.n

lrm

&

Fore~e

Cr

ops:

A:;lp~

a

max!

trrJ

m

ol3 S

ltr

i'fS

per

pa.ddot~

per

yea

r.

For

Cere1

l

Cr

ops:

Apr;t':f

a

mut

11

Jm

of

3

sprays

p!r

per

Qft)'lt

3

i1Q

S!a.son.

Refer

to

Crop

Sa

f

ety

setllon

uo

du

oerall

n"rot

for

So

rg

bg:mYlll

!

IIU.

Refer

to

Gl

netal

l.'

utroct

lo

n.s

on

B

utf

u Zonu

pr

io

r to

u"

.

U

se

t~re

rate

t

h:

ough

subb

'.e

boo

m

spra)'!lln

d

!ti

S!

crops

t~ga

~:as

ad:~l

ras~

op;t~

R

efer

to C

ro

p

S1

f

ety

secl

ton

ao

der

Gen

eral

liu

lr

ucll

o

as

fo

r

S

or

g

bum

nr

lelle.s.

Re

fer lo

Ge

neralln

s!ruc

li

ons

on

B

oHer

Zon

es

pri

or

to

usa

.

App~

Octobu

to

Dec

em

ber

or

L1

a!Au

mn

wh

en

ad

u

ls

OCC

JI'

ln

dasm~ing

)!rs

U

se

the

lo

v.'!St

r

a:E

poss

h2

to

a

c.

'l!e"

r'l

fect.'ve

c

ontrol

;..,...

n

"''

lmll!bn<

'"

"'

<h l , .

,,.;

Refer

to

Ge

neral l

ns!rotlions

on

B

uff

er

Zon

es

pr

i

or

to us!.

0

1\t'y

1

app

r

catio

n

"eat

for

each

paddock.

S

pra

y

Ap

rfl

to

JJ':f

as

a

raJ1

fal

of

mo

re

than

7mm

Is

req

a:r

ed

b~tore

cockchaJm

s

urfa

ce aM

fe.~

SpiJY

raLt

a

!l

ls

~=!t

~=o~~·~:~~=::n~~

Use

Refe

r

10

dratlio

o

r1

B

vff

u

Zo

ne

s

prior

lo uu.

ONy

1

af)p

!:

.ca

tlo

n

"'

' y

ear

p;

r

m:'tted

l

or

nth

paddock.

S

)ray

May

to

Ju

':f

lo

r

COrb

'e

a1li

AugJst

to

Seflem~

f

or

Co

r

b'e

when

damag

numb

ers

occu

r.

S

pot

sp;ay

;.

'YJ

Is

lobe

u

S!

d

where

poss:"b:e

.

Use

tffl

krii'

E.St

ra

te

poss

ib'e

to

ath

:t·

n:r;ffect

i\'ero

nt

ro

l

days

da)"l

ITICAL

OMMEIITS

Refer

10

Ge

neral lntlfltli

ons

on

Bt$tu

Zo

ne

s

prior

l

one

.

0

Do

)'1

app

r

ca

Uon

y

e.a

r

pwnlt

ed

f

!>l

each

doc~

Sp~ay

to

J

JJ

'Y

whs

n

fi

ll'I

S

h

an

s

tim!i

ated

eed~

attN;ty

.

Use

tre

l

ow

est

f1t

e

po

ssi):e

to

ach

'

eve

effedNe

co

ntro

l.

~::~

~;:a

~~::~!:

:~:~o~~

IS!

.

Spray

Ap

iil

lo

lata

J;,

me

Yt

il

en

gn

r

!)s

aa

ca

us

L

1g

pastu

re

d

am

ac!. U

se

the

laNes

!

rate

tD

a

thi!

ve

e

tf

ect.\"B

co

itro

l.

CONTRARY

THIS

LABEL

UNLESS

AUTHOR

UIIOER

WITHHOLDIII

PERIOD

S

tored

Cere

al

Gra

in

at12pp

slore

ocess

pllon

stockfeed

days

aller

lreat

ment.

ppm

=

P"cJlip

:rm.lon

~!tt

m~-:g)

Crgos

lor

hu

man

con

sump

ll

on

pples,

bbages

ies,

grapes

leltuce

soya

bean,

omato,

cerea

cro

ps

!lOT

HARVEST

DAYS

AFTERAPPLI

Cr

oas

lor

an

im

al

consumo

!l

pn/s

l

gctleed

aslu

erne

where

stock

have

overs

prayed

IIOT

GRAZE

DAYS

AFTER

PPLICATIDi

WITHHOLD

FROM

SLAUGHTER

DAYS

AFTER

APPLICATIOII

WIIICliEVER

APPROPRIATE

llDTCUT

STOCKFEED

DAYS

AFTER

APPLICATIOII.

Pasture

incl

lucerne

where

slockhave

been

rsprayed

IIDTSLAUGHTER

AFTER

APPLICATON

Sorgh

cerea

straw

and !

odder,

lure

seed

crops,

fora

crops

IIDT

GRAZE

STOCK

FEED

DAYS

FTER

LICATIOII.

-----------------------------~------------------------------

c____

"'

r-.>

r-.>

w

r-.>

....

r-.>

r-.>

"'

r-.>

....

r-.>

r-.>

w

.---

-.::1

w

0>

r-.>

«>

,....,

w

c..o..>

w

w

>

:,.,

f----J

_..~

C)i[

cf2.

fPHPf

GEtlERAllllSTRUCTIOtlS

INSECTICIDE

STAIICE

WARIIIIIG

IGROUPiii:

INSE

ICIO<

Lnsetlicid!

s!VIt!

ma;.ag

!tl\~ri

umruon

OOOEC

lns!Ctkilf

Group

lns~!i:k

Som'

ni~Jrlly

occu

rrin

~.ct

b»t)'psi

resistln

S1.11

100DEC

lnsl!Cli::id

othu

ins!ttitii

exist

throug~

r.oum

!!i!tic

v-diab~

il'l

i\m:

a~il.

istint

!Mduis

t¥ezttul.')y

opu'atiol-1

umlhion

100!l:C

~t;clda

oth!l'

s!ctici:l~l:

rep!a~

erte:ih'e

n!ss

1J1nll00.

1000!C

s!ttici:l!l

resls:l

iii£Y

id!.I!.'S

nlficant!'

re-dt

curr

en.:e

resista

ntllid!

cfilto

d:l!ct

pOOr

'»G

Ch!mital

Ausntia

cc!pts

r!!b~

lonM

res!ltlrom

fdtlre

nlh!o:l

DOOEC

lns!cticl

totitrol

!stln

s!tts.

hhkm

000E

llmttitid!

sub!!tl

cf"

strl.!e~~s

further

inlon

rutioo

:Jcl

'Ol.Jf

local

uppo:!f

Ch~cll

Austn:iJ

llrj

repre~

~tiv801'klttld~i

trre

tofilgricl:1urac7D

ntmV

l ln:

aximu

Efficl!.,cy

prod

grin

protection

d!p!nd~

upon

1s!Jibution

through

orin.

lJia

zbs~t!

L'ifestition

u;tW.!,

su:nte;

y

stureconle

h. L

12J..

a:ld

stong!t-a:np

mllJre

ofb~aN

2rc.

ui'e

ooBI.

sptay

i'nm~dllla

us!.

Sfo011

000E

td~.J1liY

tCifwat!rW'Itl.

m:laol:it~welbe

rJton"me

gtospny

ain):

1£1.1e

spra

through

:ia!ize

grain

pnyL,

u'pm~

~orllnt

spn~

Mzzl!

mustba

t)plb~

SPliYPi

tt!In.

Cltt

eomp:e

tion

'h1:J1

sptiy

!tftJ!pJ'Mr.l

ut!tls

thwi~r

CROP

SAFETY

urn'Won

0DEC

Inset

'cid

disco'out'i

tion

ffill1Y

sorg~.um.

LtlV!s

so.1u

soro:

vvi!ti!S

spott!d

aft!:r

spny'

8<5

, Al

ltis

:fen

~tfe

Hvueiy

d!.mged,

esp!ch~

rvh1h

st;ag~

check

holf.

made

l'!h

nmufacturer

approprlJ!!

b;:t

oreapp:-tation

ismt<f!

ei,.

;rvvieti!s.

LICATIOIISAIID

BUFFER

r,r~ol

oet~sts

Grassl'lDppm,

ee-.

luC!

Ir>!

a::Vi!

stur

o:ltcht!u. C

ocb:!

flllt!r

orti.!l.

STORAGE

AIID

POSAL

Stn!!

origm.l

tlk'~o!r

cool,

·\·en

li:at!

vu .

sb:lrtl

lfllect

pcd'uab','J

ressu

eor.ta:rar

b!fora

disposal.

rinsing

Spri'/

tan(.

cf,spose

ndlute

ch~i!

s!te.

rep~te

Cift

etur

c:etn

ntaln~

ncyc~c

i!.!d

~>"

ncyc

tna..(.

trosh

nt:llJre

b:.:ry

empty

eooti

local

uthori

lilldril

landfil

ab:S,

ntainm

bfow

5Dem11

disposal

sp~el'ICt!Jy~d

setup

01Ws

pufPOS!

'it!twa

, desh.b:!

tion

dtrearoGts

Err-P~J'CO

~~;.rstndproOOc

I)U'

r.ot

b,btJrt

SAFETY

OJRECTIOJIS

Ptnd.

~sonol.

~tlby

s.<i.l

act,

!'!11

"

Ow'!:J

R:p~i

milor

exposure

haY!

cumu's:iv!

o.i!n

e.t"fett

cont!c

w;j)

~;es

n~inh

!spraymSt

D<;l

lJi!

con!i.

prepu

pra-J

pr!plfed

sprcy,

wn

c

otto.

erc.'lsbt.emmdtnlf"

emcltar

lar.clwa

sl'lab'

tlll.!.'bo-N·Ie«~PVCo'ove.s

shl~

lllsn

e.n~

mas.

wear

f.fa

rasp'ntor

comb

it!d

tiitrkJQ3

roduct

s"UI,

i'Ml!litte.)'wash

-;'111

soap

il!l

Alret

b;roreea~;~

dr\nkiioor

smokin

v..-ash

hands,

acalJiOf

ough

soap

andWilet.

d1)'s us!,

wash

contil!Mite

cloth

·rr

srt!'d,

r~Q1Q"!s

resplnror

bb!l

v.'Uh

d!t!ft!!nl

warm

w!lu.

FIRSTAIO

OZ:.O

tt-ed,

sp'nhd

·nor

tjts,

'1~::d,

.uct a

l.sQns

.!omu

·a.

Austra'2

octl){

once.

emtm

contlmbat!

clothllg

VIti

s:cin

lhorou

swt'

aNed,

t:trnm

chmoll

b'

GlvaA.tro

iflnstru

EXCLUS

IOII

LIABILITY

otl'lerv;is!

u:presSJ'y

st!t!:J

lting

l'l!lt>!t

u1\.

rtno

h!Jnkal

Austri

PI)'

dis~'!Df

knoi'l<!

~:ulu

tlic

L'i!l

b-J)'U

f'Ot)oses.

ttts

pro~u~

purthJsflg

trus

produc

1:'1!

bll)

must

re.'y

upon

thW"

ski~

judgw

tita.

lllh!

p!lti

purposa

l

ot

which

ills

Except

!

e:xt!.

tt!Jt

ex()'usion

01

d!r.Ill

EJb!ty

pro'ibled

under

th!l

rad!l

Pn:&es

01

re:~

stat~

~~~lztioo

IJ'Illom

h!lTI:Cal

AJJstra

tlia

strib

expressly

exclutl!

wvranty

Q!ll.1y

fitnn

()Ods

ufPOS

w

Its!lmr

a.1d

d!fly

S:P!I

connct

:eor

1!.uwis

MrmOI'

danuga

r!.iu~g

S!:ch

ooo:Ss

ctin

gonthaa

ihic!IOI'rttomm~datio

sastos

husag

iYUik1

0oodh

byc.s

~----

A.er

:~ :

i!pp.'y

m'/l'la.

llOT

app,'yw

a buffu z

30()m

when

VP't\

~num

iitU

~clud'.r.

liT.:te

natura1

slream

rivers,

wal!tways

human

d011·a

"'

r.!.

hbouM

propeti~

Groun

dap;~

llan:

Apply

nitroth

sist!d,

mi.s

g

,t.:ectro

tatie

oomsprayu

oomspnysandElttlros11llc

liOTa

pp.'ywft.hout

buffer

LEAS

5!)matra~ol350m'lhl

db~ow

LEAS

greatet

than

35tkn

'/lla

ns.itiv

areu

inct

(b14

notfmlt!

na~raJ

eams.

Mrs,

ct!!WJ)'S,

d"h'

;ISOJ'rl~~

bouringprop

!tli

ir·

apply

'ilho:.t

urfet

LEAS

t'ii.M

35Dm'/l'll

ar.1

L.EAS

al!S

e gre

tfl!.11

Dm'/h

ii~n

cpp~

upwin

sQ-n

k'lt!uding

notlim:!!d

na!U

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Sumitomo Sumithion

1000EC Insecticide

Sumitomo Chemical Australia

Page 1 of 6

January 2010

MATERIAL SAFETY DATA SHEET

Sumitomo Sumithion

®

1000EC Insecticide

SECTION 1: IDENTIFICATION OF THE MATERIAL AND SUPPLIER

Product Name:

Sumitomo Sumithion

1000EC Insecticide

Other Names:

Sumithion 1000EC

Recommended Use:

Sumithion 1000EC is an insecticide for the control of locusts

and grasshoppers.

Company:

Sumitomo Chemical Australia Pty Ltd

A.B.N. 21 081 096 255

Address:

242 Beecroft Road, Epping, NSW 2121

Telephone Number:

(02) 8752 9000(Mon–Fri 8am–5pm EST)

Emergency Telephone Number:

1800 024 973 (24 hours) (EMERGENCIES ONLY)

Website:

www.sumitomo-chem.com.au

SECTION 2: HAZARDS IDENTIFICATION

Hazard Classification:

Hazardous according to the criteria of the Australian Safety and Compensation

Council (ASCC).

Risk Phrases:

R36 – Irritating to eyes.

R38 – Irritating to skin.

R22 – Harmful if swallowed.

R50 – Very toxic to aquatic organisms.

R53 – May cause long-term adverse effects in the aquatic environment.

R56 – Toxic to soil organisms.

R57 – Toxic to bees.

Safety Phrases:

S23 – Do not breathe fumes/ vapour/ spray.

S24 – Avoid contact with skin.

S25 – Avoid contact with eyes.

SUSDP Classification

(Poison Scheduling):

ADG Classification:

Classified as a Dangerous Good (under the Australian Code for the Transport of

Dangerous Goods by Road and Rail (ADG Code).

Correct Shipping Name:

ORGANOPHOSPHORUS PESTICIDE, LIQUID,TOXIC (fenitrothion mixture).

Dangerous Goods Class: 6.1

UN Number: 3018

Hazchem Code: 2X

Packaging Group: III

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

Chemical Identity

CAS number

Proportion

Fenitrothion

122-14-5

> 60%

Iso-butanol

78-83-1

<10%

Aromatic hydrocarbon

64742-94-5

< 10%

Other ingredients determined as non hazardous

to 100%

Sumitomo Sumithion

1000EC Insecticide

Sumitomo Chemical Australia

Page 2 of 6

January 2010

SECTION 4: FIRST AID MEASURES

If poisoning occurs, immediately contact a doctor or Poisons Information Centre (Phone Australia

131126; New Zealand 0800 764 766), and follow the advice given. Show this Material Safety Data

Sheet to a doctor.

General:

In case of accident or if you feel unwell, seek medical advice immediately

(show label where possible).

Swallowed:

If swallowed,

Skin contact:

contact a Poisons Information Centre or a doctor at once. If

swallowed, activated charcoal may be advised. Give atropine if instructed.

If splashed on skin,

Eye contact:

contact a Poisons Information Centre or a doctor at

once. Remove contaminated clothing and wash skin thoroughly with soap

and water. Launder contaminated clothing before re-use.

If in eyes,

Inhalation:

hold eyes open and flood with water for at least 15 minutes and

contact a Poisons Information Centre or a doctor at once.

If inhaled, remove from contaminated area to fresh air. Contact a Poisons

Information Centre or a doctor at once.

Note to physician:

Apply basic aid and decontamination procedures. Treat symptomatically.

SECTION 5: FIRE FIGHTING MEASURES

Flashpoint:

> 70

Flammable limits:

Auto-ignition temperature:

C (Active Ingredient)

Suitable Extinguishing

Media:

Small fire: Use dry chemical, carbon dioxide or water spray.

Large fire: Use water spray, fog or foam – Do not use water jets.

Hazards from Combustion

Products:

This product is combustible. Normal combustion forms carbon dioxide and

water

vapour,

produce

oxides

sulphur,

nitro

phosphorus. Incomplete combustion can produce carbon monoxide.

Prevent electrostatic discharge and No Smoking. Above the flashpoint an

explosive mixture can be formed.

Precautions for Fire

Fighting and Special

Protective Equipment:

In case of fire, the evolution of dangerous gases is possible.

Ensure

respiratory

equipment

available.

Evacuate

immediate

area.

Advise Fire Brigade of nature of hazard. Wear full protective equipment,

including breathing apparatus. Remove drums from site of fire, if possible,

overheating

cause

drums

explode.

Surrounding

containers

should be cooled using a fine water spray. All run-off must be contained.

Hazchem Code:

SECTION 6: ACCIDENTAL RELEASE MEASURES

Emergency Telephone Number:

1800 024 973 (24 hours)

(EMERGENCIES ONLY)

METHODS AND MATERIALS FOR CONTAINMENT AND CLEAN UP PROCEDURES

SPILLS

Stop the source of the spill if it is safe to do so. Contain the spill to prevent further contamination of

the soil, surface water, or ground water. Wear personal protective equipment as specified in Section

8. Do not allow material to enter sewers or bodies of water.

Small Spills:

(Liquid spill)

Apply absorbent inert material such as soil, dry sand or vermiculite to the spill area.

Sweep up material when absorption is complete and contain in a refuse vessel for

disposal. If necessary, wash the spill area with an alkali detergent and water and

absorb and contain as above.

Sumitomo Sumithion

1000EC Insecticide

Sumitomo Chemical Australia

Page 3 of 6

January 2010

On completion of clean up remove and wash all contaminated clothing and equipment

with detergent and water. Any heavily contaminated clothing should be placed in a

plastic garbage bag and placed in a sealable drum. Do not smoke, eat or drink during

the clean-up operation.

Large Spills:

(Liquid Spill)

Place leaking containers into salvage drums. Apply absorbent inert material such as

soil, dry sand or vermiculite to the spill area. Form a barricade around spill and in front

of drains or waterways in spill vicinity, using soil or other non reactive material. Sweep

up material and contain in a refuse vessel for disposal.

Contact emergency services as required.

On completion of clean up remove and wash all contaminated clothing and equipment

with detergent and water. Any heavily contaminated clothing should be placed in a

plastic garbage bag and placed in a sealable drum. Do not smoke, eat or drink during

the clean-up operation.

Disposal:

Contaminated material must be disposed of in accordance with all State and/or Local

regulations.

SECTION 7: HANDLING AND STORAGE

Precautions for

Safe Handling:

DO NOT USE OR STORE near flame, sparks or hot surfaces. Use only in well

ventilated area. Keep container closed. Do not mix with water (except for normal

preparation).Keep out of reach of children, unauthorised persons and animals. After

handling and before eating, drinking or smoking, wash hands, arms and face with soap

and water. For personal protection, see Section 8.

Conditions for

Safe Storage:

Keep out of reach of children, unauthorised persons and animals. Store in the closed,

original container in a cool, well ventilated-area. Do not store for prolonged periods in

direct sunlight. Keep away from heat. Do not store near food, feedstuffs, fertiliser or

seed. Store at ambient temperatures.

Ensure

containers

correctly

labelled

securely

sealed.

Classified

dangerous substance for transport purposes.

Fire and

Explosion

Prevention:

This product is combustible. Prevent electrostatic discharge and No Smoking.

Above the flashpoint an explosive mixture can be formed.

SECTION 8: EXPOSURE CONTROLS AND PERSONAL PROTECTION

NATIONAL EXPOSURE STANDARDS

Australian Safety and Compensation Council (ASCC) exposure standards have not been assigned for the

active ingredient or anionic surfactant.

Exposure Standards for surfactant constituent:

iso-butanol

Exposure Standards for aromatic

hydrocarbon:

Exposure Limit:

Exposure Limit:

152 mg/m

n/a STEL

100 mg/m

n/a STEL

BIOLOGICAL LIMIT VALUES

Production workers and agricultural workers handling this product regularly should be monitored for the

effects of organophosphate pesticides. A baseline level should be established prior to any potential

exposure. See Guidelines for Health Surveillance [NOHSC: 7039 (1995)].

ENGINEERING CONTROLS

No engineering control measures are allocated to the use of this product, however always use in a well

ventilated area. Do not inhale mist.

Sumitomo Sumithion

1000EC Insecticide

Sumitomo Chemical Australia

Page 4 of 6

January 2010

PERSONAL PROTECTIVE EQUIPMENT

Product is poisonous if absorbed by skin contact, inhaled or swallowed. Repeated minor exposure may

have a cumulative poisoning effect. Avoid contact with eyes and skin. Do not inhale spray mist.

When opening the container, preparing spray and using the prepared spray, wear cotton overalls buttoned

to the neck and wrist and washable hat, elbow-length PVC gloves and face shield. When using in enclosed

areas, wear goggles and half-face piece respirator with combined dust and gas cartridge. If product on skin,

immediately wash area with soap and water. After use and before eating, drinking or smoking, wash

hands, arms and face thoroughly with soap and water. After each day’s use, wash contaminated clothing,

gloves, face shield, goggles and respirator and if rubber wash with detergent and water.

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

Vapour Pressure:

ACTIVE INGREDIENT SPECIFIC:

1.37 x 10

mm Hg at 20

Viscosity:

37.6 cP at 22

Ignition Temperature:

Appearance:

PRODUCT SPECIFIC:

Brown clear liquid.

Odour:

Slightly characteristic odour

pH:

3.0 – 7.0

Vapour Density:

Boiling Point:

Melting Point:

Solubility in water:

Emulsifiable in water.

Density:

1.28 – 1.30 g/mL

Viscosity:

Flashpoint:

>70

Explosive Limits:

Ignition Temperature:

SECTION 10: STABILITY AND REACTIVITY

Chemical Stability:

Stable for 3 years after manufacturing under recommended storage and

handling conditions (See Section 7). Unstable in light, particularly UV

light.

Conditions to Avoid:

Avoid high temperatures and direct sunlight. Isolate from sources of

heat, naked flames or sparks.

Incompatible Materials:

Alkaline materials and oxidizing agents.

Hazardous Decomposition

Products:

Emits toxic and irritating fumes under fire conditions (See also Section

Hazardous Reactions:

SECTION 11: TOXICOLOGICAL INFORMATION

ACUTE HEALTH EFFECTS (Formulated Product)

Toxicology

Swallowed:

MODERATELY TOXIC.

(male rat) = 420 mg/kg and LD

(female rat) = 910 mg/kg)

Accidental ingestion of small amounts may be harmful.

Sumitomo Sumithion

1000EC Insecticide

Sumitomo Chemical Australia

Page 5 of 6

January 2010

Skin:

MODERATELY TOXIC.

(male rat) = 1110 mg/kg and LD

(female rat) >1500 mg/kg)

Contact with skin may be harmful.

ACUTE HEALTH EFFECTS (Active Ingredient)

Inhalation:

MODERATELY TOXIC.

rat (4 hour) > 2.21 mg/L of air)

Inhalation of vapour may be harmful.

Irritation (Formulated Product)

Skin:

NON-IRRITANT.

Eye:

IRRITANT.

Irritation (Active Ingredient)

Sensitisation

Skin:

NOT A SKIN SENSITISER.

CHRONIC HEALTH EFFECTS (Active Ingredient)

In long-term dietary chronic studies in rat and mouse, no evidence was seen for treatment-related

carcinogenicity.

OTHER TOXICOLOGICAL INFORMATION (Active Ingredient)

Not mutagenic, embryotoxic or teratogenic.

Like

other

organophosphate

pesticides,

fenitrothion

acts

inhibiting

activity

enzyme

acetylcholinesterase, which is important in the conduction of impulses to nerves and muscles. Fenitrothion

is oxidized in animals, insects and plants to derivatives that are more potent inhibitors of cholinesterase

than the parent compound. In mammals, both the parent compound and its derivatives are predominantly

metabolised in the liver and then mostly excreted within a 24-hour period. However, in some cases,

suppression of metabolism of the compound during its repeated administration can lead to an extended

persistence in the body. In addition, ultraviolet radiation induced breakdown products can be more toxic to

mice than the parent compound.

SECTION 12: ECOLOGICAL INFORMATION

DO NOT contaminate streams, rivers or waterways with the chemical or used containers.

ECOTOXICITY(Active Ingredient)

Toxic to fish:

Rainbow trout (96 hour) = 1.3 mg/L

Bluegill sunfish (96 hour) = 2.5 mg/L

Highly toxic to aquatic

invertebrates:

Daphnia magna (48 hour) = 8.6 µg/L

Toxic to algae:

Selenastrum capricornutum (96 hour) = 1.3 mg/L

Low toxicity to toxic to birds:

Acute Oral LD

Quail = 23.6 mg/kg.

Acute Oral LD

Ringneck pheasant = 34.5 mg/kg.

Acute Oral LD

Mallard duck = 1190 mg/kg.

Highly toxic to bees.

Highly toxic to earthworms.

ENVIRONMENTAL FATE (Active Ingredient)

(half life and mobility)

Sumitomo Sumithion

1000EC Insecticide

Sumitomo Chemical Australia

Page 6 of 6

January 2010

Fenitrothion and metabolites adsorb moderately strongly to soils and do not leach significantly. Vapour

transport is likely to be significant in view of the moderate vapour pressure, although volatilisation will be

limited to a short period after application as fenitrothion does not persist on vegetation or soil surfaces.

Fenitrothion appears relatively stable in air. Fenitrothion degrades through microbial metabolism with

typical half-lives of a few weeks under aerobic conditions. Residues entering water dissipate through

photolysis and microbial metabolism with half-lives typically less than a day, as well as through uptake into

biota to moderate levels, accompanied by metabolism.

SECTION 13: DISPOSAL CONSIDERATIONS

Product:

This material must be disposed of as a hazardous waste. Disposal should be

in accordance with local, national or state regulations.

Contaminated

Packaging:

Triple or preferably pressure rinse containers before disposal. Add rinsings to

spray tank. Do not dispose of undiluted chemicals on site. If recycling,

replace cap and return clean containers to recycler or designated collection

point. If not recycling, break, crush or puncture and bury empty containers in

a local authority landfill. If no landfill is available, bury the containers below

500 mm in a disposal pit specifically marked and set up for this purpose clear

of waterways, desirable vegetation and tree roots. Empty containers and

product should not be burnt.

SECTION 14: TRANSPORT INFORMATION

Rail / Road (ADR / RID)

Classified as dangerous in the meaning of railroad transport regulations.

Proper Shipping Name

ORGANOPHOSPHORUS PESTICIDE, LIQUID, TOXIC. (fenitrothion mixture)

Class:

Sub Risk Class

Not applicable

UN Number

3018

Hazchem Code

Packing Group

Sea (IMDG Code)

Classified as dangerous in the meaning of sea transport regulations.

Proper Shipping Name

ORGANOPHOSPHORUS PESTICIDE, LIQUID, TOXIC. (fenitrothion mixture)

Class:

Sub Risk Class

Not applicable

UN Number

3018

Hazchem Code

Packing Group

Air (ICAO / IATA)

Classified as dangerous in the meaning of air transport regulations.

Proper Shipping Name

ORGANOPHOSPHORUS PESTICIDE, LIQUID, TOXIC. (fenitrothion mixture)

Class:

Sub Risk Class

Not applicable

UN Number

3018

Hazchem Code

Packing Group

SECTION 15: REGULATORY INFORMATION

Registration Status:

This product is currently registered under the Australian Pesticides and

Veterinary Medicines Authority (APVMA) with the following approval number

50775/0401.

SECTION 16: OTHER INFORMATION

Abbreviations:

NA

Not Applicable

NDA

No Data Available

Revision Date:

28 January 2010

Revision Number:

Reason for revision:

Change of formulation and address

Sumitomo Sumithion

1000EC Insecticide

Sumitomo Chemical Australia

Page 7 of 6

January 2010

THE INFORMATION GIVEN IN THIS MSDS IS BASED ON DATA AVAILABLE AS OF THE REVISION DATE GIVEN

HEREIN, AND BELIEVED TO BE CORRECT. EACH USER SHOULD READ THIS MSDS AND CONSIDER THE

INFORMATION IN THE CONTEXT OF HOW THE PRODUCT WILL BE HANDLED AND USED IN THE WORKPLACE

INCLUDING IN CONJUNCTION WITH OTHER PRODUCTS. IF CLARIFICATION OR FURTHER INFORMATION IS

NEEDED TO ENSURE THAT AN APPROPRIATE RISK ASSESSMENT CAN BE MADE, THE USER SHOULD

CONTACT THIS COMPANY.

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