SHARP SHOOTER TRIFORINE ROSE SPRAY CONCENTRATE

Australia - English - APVMA (Australian Pesticides and Veterinary Medicines Authority)

Active ingredient:
TRIFORINE; DIMETHYL FORMAMIDE
Available from:
Denbies Group Pty ltd
INN (International Name):
triforine(20g/L)
Pharmaceutical form:
EMULSIFIABLE CONCENTRATE
Composition:
TRIFORINE AMINE/AMIDE Active 20.0 g/L; DIMETHYL FORMAMIDE SOLVENT Other 25.0 g/L
Units in package:
1L; 250mL; 500mL
Class:
A - Agricultural
Manufactured by:
AUSGRO TECHNOLOGIES
Therapeutic group:
ROSE | STURT'S DESERT ROSE
Therapeutic area:
FUNGICIDE
Therapeutic indications:
BLACK SPOT - COLLETOTRICHUM ACUTATUM | POWDERY MILDEW | RUST | ANTHRACNOSE
Product summary:
Poison schedule: 5; Withholding period: WHP: N/A; Host/pest details: ROSE: [BLACK SPOT - COLLETOTRICHUM ACUTATUM, POWDERY MILDEW, RUST]; Poison schedule: 5; Withholding period: ; Host/pest details: ROSE: [BLACK SPOT - COLLETOTRICHUM ACUTATUM, POWDERY MILDEW, RUST]; For the systemic control of black spot, powdery mildew, and rust on roses in the home garden.DO NOT use a wetting agent. DO NOT apply when soil is dry and plants are suffering from stress. DO NOT apply when temperature are above 30 C. DO NOT apply in cold or slow drying conditions
Authorization status:
Registered
Authorization number:
54083
Authorization date:
2019-07-01

----~~--~~----~~~--~~~~~~~~~-

MAIN

PANEL

CAUTION

KEEP OUT OF REACH OF CHILDREN

READ SAEETY DIRECTIONS

BEHlRE

OPENING OR \JSING

SHARP SHOOTER

TRlFORlNE

ROSE SPRAY CONCENTRATE

ACTIVE

CONSTITUENT:

20 giL TRlFORINE

SOLVENT:

giL

DIMETHYL FORMAMIDE

( ROSE PICTURE )

PRODULY

AUSTRALIAN

For the Systemic Control

black

spot,

powdery mildew and rust on roses in the

home garden

250mL.

500mL

1

Litre

""

"

1\'hRillM"

APPROVED

LABEL

JTEXT)

Label

5,4:ot.3/03QJ

Date:

....

b

..

J.

9.:;$.

,_'SIgnature:

....

.....

:~.:,.

Page 1

---------------------------

REAR

PANEL

USE:

use wetting agent.

apply when soil is

and plants are

suffcrinp from Sires" _

apply

when temperature

are above 30 C.

apply in cold or slow drying

conditions

SHARP

SHOOTER

TRIFORINE

ROSE

SPRAY

CONCENTRATE

CROP

-----

ROSES

All types

DlSEASI,

Black Spot

Powdery Mildew

Rust

RATL

1 litre

waler

TO Al'PLY

Spray foliage thoroughly at intervals

7-10

days for as long as the

disease is active

BATCH

DOM.,

Approval No:

54083/0

30:'

Ausgro Technologies PIL

DANDENONG

VIC3175

( 03 ) 9793 0299

( Class 3

Diamond)

1170

ETHANOL(ETHYLALCOHOL)

ETHANOL

SOLUTION

(ETHYL

ALCOHOL

SOLUTION)

SAFETY-DIRECTIONS

Avoid contact with eyes and skin

Do not

inhale spray mist.

After

use and before

eating,

drinking

smoking wash

hands,

arms

-and-face thoroughly

with

soap

and water.

FIRST

Ifpoisoning

occurs,

contact

a Doctor or Poison Information

Centre.

PHONE

13 11 26

BE USED

PURPOSE

OR IN

MANNER,

CONTRARY

THIS

LABEL

UNLESS AUTHORISED

---HOW-l'O-PREPARE

Shake

bottle before use

Remove

child

proof

Using the measuring cylinder,

measure out the product and

add the required amount

water

-l.Rinsc measuring cylinder

5. Replace child

proof

CAUTION

Do not allow chemical

containers or spray to get into drains

sewers,

streams or ponds

STORAGE

&

DISPOSAL

Store in closed original containers

a cool dry place out

the reach

children.

Do not store in direct

sunlight.

Dispose

empty

containers by wrapping in

paper,

placing in plastic

and putting

in garbage.

Page

Product Name:SharpShooterTriforine RoseSpray Concentrate

Page:1of5

Thisrevisionissued:July,2010November,2010

MATERIAL SAFETYDATASHEET

Issued by:AusgroTechnologies PtyLtd Phone:0397930299

SECTION 1-IDENTIFICATIONOFCHEMICALPRODUCTANDCOMPANY

Ausgro TechnologiesPtyLtd Phone:0397930299

POBox2003

East DandenongVic3175

Substance: Ethanolsolution.

TradeName: SharpShooterTriforineRoseSpray Concentrate

ProductUse: Systemicrose sprayfor use asdescribedonproductlabel.

CreationDate: March,2003

Revision Date: July,2010

Section 2-HazardsIdentification

RiskPhrases: R11.Highlyflammable.

SafetyPhrases: S29,S33.Donotemptyinto drains.Take precautionarymeasuresagainst staticdischarges.

SUSDPClassification: S5

ADGClassification: Class3ETHANOL SOLUTION

UNNumber: 1170

EmergencyOverview

PhysicalDescription&colour : Clear, colourlessliquid.

Odour: Characteristicalcoholodour.

MajorHealth Hazards: Triforine hasalowacuteoralanddermaltoxicityandamoderate acuteinhalationtoxicity.

No significant riskfactorshavebeenfound for thisproduct.

PotentialHealth Effects

Inhalation:

Shorttermexposure: Available dataindicatesthatthisproduct isnotharmful.Inaddition product isunlikelyto

cause anydiscomfort orirritation.

LongTermexposure: No data for healtheffectsassociatedwith longterminhalation.

Skin Contact:

Shorttermexposure: Available dataindicatesthatthisproduct isnotharmful.It shouldpresentnohazardsin

normaluse.However product maybe mildlyirritating,butisunlikelytocauseanything more than mild discomfort

which should disappearonce contact ceases.

LongTermexposure: No data for healtheffectsassociatedwith longtermskin exposure.

EyeContact:

Shorttermexposure :Available datashowsthat thisproduct isnotharmful. However product maybemildly

irritatingtoeyes,butisunlikelytocauseanything more than mild discomfort which shoulddisappear onceproductis

removed.

LongTermexposure :No data for healtheffectsassociatedwith longtermeyeexposure.

Ingestion:

Shorttermexposure :Thisproduct isunlikelyto cause anyirritationproblemsin theshort orlong term.

LongTermexposure :No data for healtheffectsassociatedwith longtermingestion.

Carcinogen Status:

NOHSC: No significantingredientisclassifiedascarcinogenicbyNOHSC.

NTP: No significant ingredientisclassifiedascarcinogenicbyNTP.

IARC: DimethylFormamide isClass3-unclassifiableastocarcinogenicitytohumans.

Section 3-Composition/Information on Ingredients

Product Name:SharpShooterTriforine RoseSpray Concentrate

Page:2of5

Thisrevisionissued:July,2010November,2010

MATERIAL SAFETYDATASHEET

Issued by:AusgroTechnologies PtyLtd Phone:0397930299

Ingredients CASNo Conc,% TWA(mg/m 3 ) STEL(mg/m 3 )

Triforine 26644-46-2 2 not set not set

Dimethylformamide 68-12-2 2.5 30 not set

Ethanol 64-17-5 to100 1880 not set

Thisisacommercialproduct whose exact ratio ofcomponentsmayvaryslightly.Minor quantitiesofothernon

hazardousingredientsarealso possible.

TheTWAexposurevalueistheaverageairborneconcentrationofaparticularsubstancewhencalculatedoveranormal8hourworkingdayfora5

dayworkingweek.TheSTEL(ShortTermExposureLimit)isanexposurevaluethatshouldnotbeexceededformorethan15minutesandshould

notberepeatedformorethan4timesperday.Thereshouldbeatleast60minutesbetweensuccessiveexposuresattheSTEL.Theterm"peak"is

usedwhentheTWAlimit,becauseoftherapidactionofthesubstance,shouldneverbeexceeded,evenbriefly.

Section 4-FirstAidMeasures

GeneralInformation:

You should callThePoisonsInformationCentreifyoufeelthatyou mayhave been poisoned,burned orirritatedby

thisproduct. Thenumberis131126fromanywhere inAustralia (0800 764 766inNewZealand)andisavailableatall

times. Have thisMSDSwithyouwhenyou call.

Inhalation: First aid isnotgenerallyrequired.Ifin doubt, contact aPoisonsInformationCentreor adoctor.

SkinContact: Irritationisunlikely.However,ifirritationdoesoccur, flushwithlukewarm, gentlyflowingwater for 5

minutesor untilchemicalisremoved. Ifindoubtobtainmedicaladvice.

Eye Contact: No effectsexpected.Ifirritationdoesoccur, flush contaminated eye(s)with lukewarm, gentlyflowing

waterfor 5 minutesor untiltheproductisremoved. Obtainmedicaladvice ifirritationbecomespainfulorlastsmore

thana fewminutes.

Ingestion: First aid isnotgenerallyrequired.Ifin doubt,contact aPoisonsInformationCentreor adoctor.

Section 5-FireFighting Measures

Fire andExplosionHazards : Thisproduct isclassifiedasaC1 combustible product. Thereisamoderateriskof

anexplosionfromthisproduct ifcommercialquantitiesare involved in afire.Firefightersshouldtake care and

appropriate precautions.Anyexplosionwilllikelyspreadthe fire to surrounding materials.Waterspraymaybe used

tocooldrumsinvolvedinafire,reducing the chancesofanexplosion.Vapoursfromthisproduct areheavierthanair

and mayaccumulatein sumps, pitsand otherlow-lying spaces, formingpotentiallyexplosive mixtures. Theymayalso

flash backconsiderable distances.

Fire decompositionproductsfromthisproduct maybetoxicifinhaled. Take appropriateprotective measures.

ExtinguishingMedia :Preferredextinguishingmedia are carbondioxide,drychemical, foam, waterfog.Water fog

or finesprayisthepreferredmediumfor large fires.

Fire Fighting :Immediatelyevacuatetheareaofunnecessarypersonnel.

Flashpoint : Approx13°C

UpperFlammability Limit: 19%

LowerFlammabilityLimit: 3.5%

Autoignitiontemperature: No data.

Flammability Class:C1

Section 6-AccidentalReleaseMeasures

Accidentalrelease :In the eventofa majorspill, prevent spillage fromenteringdrainsorwatercourses. Evacuate

thespillarea and denyentrytounnecessaryandunprotectedpersonnel. Asa minimum, wearoveralls, gogglesand

gloves.Suitablematerialsfor protective clothinginclude rubber, PVC.Stop leakifsafe to do so,and containspill.

Absorbontosand,vermiculiteor other suitable absorbent material. Ifspillistoolargeor ifabsorbentmaterialisnot

available,tryto createa dike to stop materialspreading orgoing intodrainsorwaterways.Avoid usingsawdust or

other combustible material.Sweepup andshovelor collect recoverableproductintolabelledcontainersfor recycling

or salvage,anddisposeofpromptly. Recycle containerswherever possibleafter carefulcleaning.After spills,wash

area preventingrunofffromenteringdrains. Ifasignificant quantityofmaterialentersdrains,adviseemergency

services. Thismaterialmaybesuitable for approvedlandfill. Ensure legalityofdisposalbyconsulting regulationsprior

todisposal. Thoroughlylaunder protective clothing before storage orre-use.Advise laundryofnature of

contaminationwhensending contaminatedclothingtolaundry.

Product Name:SharpShooterTriforine RoseSpray Concentrate

Page:3of5

Thisrevisionissued:July,2010November,2010

MATERIAL SAFETYDATASHEET

Issued by:AusgroTechnologies PtyLtd Phone:0397930299

Section 7-Handlingand Storage

Handling :Keep exposuretothisproduct toa minimum, andminimise thequantitieskept inworkareas. Check

Section8ofthisMSDSfor detailsofpersonalprotective measures, andmake sure that those measuresare followed.

Themeasuresdetailed belowunder"Storage"shouldbefollowed duringhandlinginordertominimise risksto

personsusingtheproductin theworkplace.Also,avoid contactor contaminationofproductwithincompatible

materialslisted inSection10.

Storage :Thisproduct isaScheduledPoison. Observe allrelevant regulationsregardingsale,transportandstorage

ofthisclassofpoison.Store inacool,wellventilated area, and make sure that surroundingelectricaldevicesand

switchesare suitable.Checkcontainersperiodicallyforleaks. Containersshould be kept closedinordertominimise

contaminationandpossibleevaporation.Make sure thatthe product doesnot come intocontactwith substances

listed under"Materialstoavoid"inSection 10. Ifyou keep more than100Lofflammable liquidsofPackagingGroupsI

andor II,youprobablyrequire alicense todoso. Ifyouhave anydoubts,we suggestyou contactyour licensing

authorityin order to clarifyyourobligations. Checkpackaging-there maybe further storage instructionsonthelabel.

Section 8-ExposureControlsand PersonalProtection

ThefollowingAustralianStandardswillprovide generaladvice regarding safetyclothingandequipment:

Respiratoryequipment:AS/NZS1715, Protective Gloves:AS2161, IndustrialClothing:AS2919,IndustrialEye

Protection:AS1336andAS/NZS1337, OccupationalProtective Footwear:AS/NZS2210.

Exposure Limits TWA(mg/m 3 ) STEL (mg/m 3 )

Ethanol 1880 not set

TheADI forTriforine issetat0.02mg/kg/day.Thecorresponding NOEL issetat2.7mg/kg/day.

ADI meansAcceptable DailyIntake andNOEL meansNo-observable-effect-level.ValuestakenfromAustralian ADI

List, Dec2002.

Ventilation: No specialventilation requirementsarenormallynecessaryfor thisproduct. However make sure that

theworkenvironment remainscleanandthatvapoursand mistsare minimised.

Eye Protection: Eye protectionisnotnormallynecessarywhen thisproduct isbeingused.However,ifindoubt,

wear suitableprotective glassesor goggles.

SkinProtection: Theinformationathandindicatesthat thisproductisnotharmfuland thatnormallyno specialskin

protectionisnecessary.However,we suggestthatyouroutinelyavoid contactwith allchemicalproductsandthatyou

wear suitablegloves(preferablyelbow-length)when handling thisproduct.

Protective MaterialTypes: There isnospecificrecommendationfor anyparticular protectivematerialtype.

Respirator: Usually, no respiratorisnecessarywhen using thisproduct. However,ifyouhaveanydoubtsconsult

theAustralian Standard mentionedabove.

Section 9-Physicaland ChemicalProperties:

PhysicalDescription&colour :Clear, colourlessliquid.

Odour: Characteristicalcoholodour.

BoilingPoint: Approx78°Cat100kPa

Freezing/MeltingPoint: No specificdata.Liquid atnormaltemperatures.

Volatiles: Approx95%

VapourPressure: No data.

VapourDensity: No data.

SpecificGravity: Approx0.8

WaterSolubility: Completelysoluble.

pH: No data.

Volatility: No data.

OdourThreshold: No data.

EvaporationRate: No data.

CoeffOil/waterdistribution : No data

Section 10-Stabilityand Reactivity

Product Name:SharpShooterTriforine RoseSpray Concentrate

Page:4of5

Thisrevisionissued:July,2010November,2010

MATERIAL SAFETYDATASHEET

Issued by:AusgroTechnologies PtyLtd Phone:0397930299

Reactivity: Thisproduct isunlikelytoreact ordecompose undernormalstorageconditions. However, ifyouhave

anydoubts, contact the supplier for advice on shelflifeproperties.

ConditionstoAvoid: Thisproduct shouldbekeptin acoolplace,preferablybelow 30°C.Keep awayfromsources

ofsparksor ignition.Handle and opencontainerscarefully.Anyelectricalequipmentin thearea ofthisproduct should

beflame proofed.

Incompatibilities: oxidisingagents.

Fire Decomposition: Carbon dioxide,andifcombustionisincomplete, carbonmonoxideand smoke.Water.

Carbon monoxide poisoning producesheadache,weakness, nausea, dizziness, confusion,dimnessofvision,

disturbance ofjudgment, andunconsciousnessfollowedbycoma anddeath.

Polymerisation: Thisproduct isunlikelyto undergopolymerisationprocesses.

Section 11-ToxicologicalInformation

Toxicity: Noneofthe ingredientsin thisproduct ispresentin sufficient concentrationsastooffer anysignificant

healthhazard.

Section 12-EcologicalInformation

Thisproduct isbiodegradable.Itshould not offer anysignificantthreatto the environment.

Section 13-DisposalConsiderations

Disposal: Containersshouldbeemptiedascompletelyaspracticalbefore disposal. Ifpossible,recyclecontainers

either in-houseor sendtorecycle company. Ifthisisnotpractical, sendto acommercialwastedisposalsite.Please

doNOTdisposeinto sewersor waterways.

Section 14-TransportInformation

ADGCode: 1170,ETHANOL (ETHYLALCOHOL)orETHANOL SOLUTION (ETHYLALCOHOLSOLUTION)

HazchemCode: 2[Y]E

SpecialProvisions: SP144,SP184

DangerousGoodsClass: Class3,Flammable liquids.

PackagingGroup: II

PackagingMethod: 3.8.3,RT1

Class3Flammable Liquidsshallnot beloadedin thesame vehicle orpackedin the same freight containerwith

Classes1(Explosives),2.1(Flammable Gaseswhereflammable liquidsandflammable gasesarebothin bulk), 2.3

(ToxicGases), 4.2(SpontaneouslyCombustible Substances), 5.1(OxidisingAgents), 5.2(OrganicPeroxides), 6

(ToxicSubstances, exceptFlammable Liquid isnitromethane), and7 (Radioactive Substances). Theymayhowever

beloadedin thesame vehicle orpackedin the same freightcontainerwith Classes2.1 (Flammable Gasesexcept

where theFlammable Liquidsand Flammable Gasesare inbulk), 2.2(Non-Flammable Non-ToxicGases), 4.1

(Flammable Solids), 4.3(DangerousWhenWetSubstances), 6(ToxicSubstances, exceptwhere Flammable Liquid is

nitromethane),8(CorrosiveSubstances), 9(MiscellaneousDangerousGoods), Foodstuffsor foodstuffempties.

Section 15-RegulatoryInformation

AICS: Allofthe significantingredientsin thisformulationaretobe found in the publicAICSDatabase.

Section 16-OtherInformation

ThisMSDScontains onlysafety-relatedinformation. Forotherdata see product literature.

Acronyms:

ADGCode AustralianCodefor theTransport ofDangerousGoodsbyRoadandRail

AICS Australian InventoryofChemicalSubstances

CASnumber ChemicalAbstractsServiceRegistryNumber

Product Name:SharpShooterTriforine RoseSpray Concentrate

Page:5of5

Thisrevisionissued:July,2010November,2010

MATERIAL SAFETYDATASHEET

Issued by:AusgroTechnologies PtyLtd Phone:0397930299

Hazchem Number Emergencyactioncodeofnumbersand lettersthatprovideinformationto

emergencyservicesespeciallyfirefighters

IARC InternationalAgencyfor Research on Cancer

NOHSC NationalOccupationalHealthand SafetyCommission

NOS Not otherwise specified

NTP NationalToxicologyProgram(USA)

SUSDP Standard for the UniformScheduling ofDrugs&Poisons

UN Number UnitedNationsNumber

THISMSDSSUMMARISESOURBESTKNOWLEDGEOFTHEHEALTHANDSAFETYHAZARDINFORMATIONOFTHEPRODUCTAND

HOWTOSAFELYHANDLEANDUSETHEPRODUCTINTHEWORKPLACE.EACHUSERMUSTREVIEWTHISMSDSINTHECONTEXTOF

HOWTHEPRODUCTWILLBEHANDLEDANDUSEDINTHEWORKPLACE.

IFCLARIFICATIONORFURTHERINFORMATIONISNEEDEDTOENSURETHATANAPPROPRIATERISKASSESSMENTCANBEMADE,

THEUSERSHOULDCONTACTTHISCOMPANYSOWECANATTEMPTTOOBTAINADDITIONALINFORMATIONFROMOURSUPPLIERS

OURRESPONSIBILITYFORPRODUCTSSOLDISSUBJECTTOOURSTANDARDTERMSANDCONDITIONS,ACOPYOFWHICHISSENT

TOOURCUSTOMERSANDISALSOAVAILABLEONREQUEST.

Pleasereadalllabelscarefullybeforeusingproduct.

ThisMSDSispreparedin accordwith theNOHSCdocument “NationalCode ofPracticeforthe

PreparationofMaterialSafetyDataSheets”2ndEdition[NOHSC:2011(2003)]

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