SAFARI 600EC HERBICIDE

Australia - English - APVMA (Australian Pesticides and Veterinary Medicines Authority)

Active ingredient:
TRICLOPYR PRESENT AS THE BUTOXYETHYL ESTER
Available from:
ADAMA Australia Pty Limited
INN (International Name):
triclopyr as butotyl(600g/L)
Pharmaceutical form:
EMULSIFIABLE CONCENTRATE
Composition:
TRICLOPYR PRESENT AS THE BUTOXYETHYL ESTER PYRIDINE-PYRIDINOXY Active 600.0 g/L
Units in package:
1000L; 10L; 110L; 20L
Class:
A - Agricultural
Manufactured by:
ADAMA AUST
Therapeutic group:
BASAL BARK | COMMERCIAL/INDUSTRIAL LAND | FALLOW CROP LAND WEED CONTROL | FENCELINE WEED CONTROL | FIRE TRAIL | FIREBREAK WEED C
Therapeutic area:
HERBICIDE
Therapeutic indications:
ACACIA GENUS | AFRICAN BOXTHORN | ANGOPHORA | AUSTRALIAN OR NATIVE BLACKTHORN | BANKSIA | BITTER BARK OR QUININE TREE | BLACK OR BRISBANE BLACK WATTLE | BLACKBERRY | BLACKBERRY IN ASSOC WITH OTHER WEED (SEE | BRIGALOW | BROADLEAF HOPBUSH | BROOMS | BROWN SALWOOD OR HICKORY WATTLE | BUDDA OR FALSE SANDALWOOD | CAMEL OR AFGHAN MELON | CAMPHOR LAUREL | CAMPHOR LAUREL - SEEDLING | CAPEWEED | CASTOR OIL BUSH | CHILEAN CESTRUM | CHINEE APPLE | COMMON PRICKLY PEAR | DAWSON GUM | ENGLISH BROOM | ENGLISH IVY | EUCALYPTUS | EUCALYPTUS - SEEDLING UP TO 2 M TALL | EUCALYPTUS SPECIES - SEE LABEL | FENNEL | FURZE OR GORSE | GREEN OR EARLY BLACK WATTLE | GROUNDSEL BUSH | HOREHOUND | LANTANA - LANTANA CAMARA | LANTANA SPP. | NARROW LEAF HOP BUSH | NEEDLEWOOD | OLIVE | OLIVE - OLEA EUROPAEA | PADDY MELON | PAPERBARK | PRICKLY ACACIA | PRIVET | RUBBER VINE | SAFFRON THISTLE | SILVER WATTLE | SMOOTH TREE OR DROOPING PRICKLY PEAR | SWEET BRIAR OR WILD ROSE | TIGER PEAR | TREE-OF-HEAVEN | TURPENTINE BUSH | YELLOW WOOD | AFGHAN ME
Product summary:
Poison schedule: 6; Withholding period: WHP: In Tasmania for Blackberry: Do not treat bushes carrying mature or near mature fruit. For Native Vegetation: Us e of Safari 600 on native vegetation mu st be done in accordance with State and /or Local Legislation. Pasture and Sor ghum: Not required when used as directe d.; Host/pest details: BASAL BARK: [AFRICAN BOXTHORN, AUSTRALIAN OR NATIVE BLACKTHORN, BITTER BARK OR QUININE TREE, BROOMS, BROWN SALWOOD OR HICKORY WATTLE, BUDDA OR FALSE SANDALWOOD, CAMPHOR LAUREL, CASTOR OIL BUSH, CHINEE APPLE, COMMON PRICKLY PEAR, DAWSON GUM, EUCALYPTUS, GREEN OR EARLY BLACK WATTLE, GROUNDSEL BUSH, LANTANA SPP., NEEDLEWOOD, OLIVE, PAPERBARK, PRICKLY ACACIA, PRIVET, RUBBER VINE, SILVER WATTLE, SMOOTH TREE OR DROOPING PRICKLY PEAR, SWEET BRIAR OR WILD ROSE, TIGER PEAR, TREE-OF-HEAVEN, YELLOW WOOD]; COMMERCIAL/INDUSTRIAL LAND: [ACACIA GENUS, AFRICAN BOXTHORN, ANGOPHORA, AUSTRALIAN OR NATIVE BLACKTHORN, BANKSIA, BITTER BARK OR QUININE TREE, BLACK OR BRISBANE BLACK WATTLE, BLACKBERRY, BLACKBERRY IN ASSOC WITH OTHER WEED (SEE, BRIGALOW, BROWN SALWOOD OR HICKORY WATTLE, BUDDA OR FALSE SANDALWOOD, CAMPHOR LAUREL - SEEDLING, CAPEWEED, CASTOR OIL BUSH, CHILEAN CESTRUM, CHINEE APPLE, COMMON PRICKLY PEAR, DAWSON GUM, ENGLISH BROOM, ENGLISH IVY, EUCALYPTUS - SEEDLING UP TO 2 M TALL, EUCALYPTUS SPECIES - SEE LABEL, FENNEL, FURZE OR GORSE, GREEN OR EARLY BLACK WATTLE, GROUNDSEL BUSH, HOREHOUND, LANTANA - LANTANA CAMARA, NEEDLEWOOD, OLIVE - OLEA EUROPAEA, PAPERBARK, PRICKLY ACACIA, PRIVET, RUBBER VINE, SAFFRON THISTLE, SILVER WATTLE, SMOOTH TREE OR DROOPING PRICKLY PEAR, SWEET BRIAR OR WILD ROSE, TIGER PEAR, TREE-OF-HEAVEN, YELLOW WOOD]; FALLOW CROP LAND WEED CONTROL: [CAMEL OR AFGHAN MELON, PADDY MELON]; FENCELINE WEED CONTROL: [BROADLEAF HOPBUSH, NARROW LEAF HOP BUSH, TURPENTINE BUSH]; FIRE TRAIL: [BROADLEAF HOPBUSH, NARROW LEAF HOP BUSH, TURPENTINE BUSH]; FIREBREAK WEED CONTROL: [CAMEL OR AFGHAN MELON, PADDY MELON]; FOREST: [ACACIA GENUS, AFRICAN BOXTHORN, ANGOPHORA, AUSTRALIAN OR NATIVE BLACKTHORN, BANKSIA, BITTER BARK OR QUININE TREE, BLACK OR BRISBANE BLACK WATTLE, BLACKBERRY, BLACKBERRY IN ASSOC WITH OTHER WEED (SEE, BRIGALOW, BROWN SALWOOD OR HICKORY WATTLE, BUDDA OR FALSE SANDALWOOD, CAMPHOR LAUREL - SEEDLING, CAPEWEED, CASTOR OIL BUSH, CHILEAN CESTRUM, CHINEE APPLE, COMMON PRICKLY PEAR, DAWSON GUM, ENGLISH BROOM, ENGLISH IVY, EUCALYPTUS - SEEDLING UP TO 2 M TALL, EUCALYPTUS SPECIES - SEE LABEL, FENNEL, FURZE OR GORSE, GREEN OR EARLY BLACK WATTLE, GROUNDSEL BUSH, HOREHOUND, LANTANA - LANTANA CAMARA, NEEDLEWOOD, OLIVE - OLEA EUROPAEA, PAPERBARK, PRICKLY ACACIA, PRIVET, RUBBER VINE, SAFFRON THISTLE, SILVER WATTLE, SMOOTH TREE OR DROOPING PRICKLY PEAR, SWEET BRIAR OR WILD ROSE, TIGER PEAR, TREE-OF-HEAVEN, YELLOW WOOD]; NON-CROP AREA - GENERAL: [ACACIA GENUS, AFRICAN BOXTHORN, ANGOPHORA, AUSTRALIAN OR NATIVE BLACKTHORN, BANKSIA, BITTER BARK OR QUININE TREE, BLACK OR BRISBANE BLACK WATTLE, BLACKBERRY, BLACKBERRY IN ASSOC WITH OTHER WEED (SEE, BRIGALOW, BROWN SALWOOD OR HICKORY WATTLE, BUDDA OR FALSE SANDALWOOD, CAMPHOR LAUREL - SEEDLING, CAPEWEED, CASTOR OIL BUSH, CHILEAN CESTRUM, CHINEE APPLE, COMMON PRICKLY PEAR, DAWSON GUM, ENGLISH BROOM, ENGLISH IVY, EUCALYPTUS - SEEDLING UP TO 2 M TALL, EUCALYPTUS SPECIES - SEE LABEL, FENNEL, FURZE OR GORSE, GREEN OR EARLY BLACK WATTLE, GROUNDSEL BUSH, HOREHOUND, LANTANA - LANTANA CAMARA, NEEDLEWOOD, OLIVE - OLEA EUROPAEA, PAPERBARK, PRICKLY ACACIA, PRIVET, RUBBER VINE, SAFFRON THISTLE, SILVER WATTLE, SMOOTH TREE OR DROOPING PRICKLY PEAR, SWEET BRIAR OR WILD ROSE, TIGER PEAR, TREE-OF-HEAVEN, YELLOW WOOD]; PASTURE: [ACACIA GENUS, AFRICAN BOXTHORN, ANGOPHORA, AUSTRALIAN OR NATIVE BLACKTHORN, BANKSIA, BITTER BARK OR QUININE TREE, BLACK OR BRISBANE BLACK WATTLE, BLACKBERRY, BLACKBERRY IN ASSOC WITH OTHER WEED (SEE, BRIGALOW, BROWN SALWOOD OR HICKORY WATTLE, BUDDA OR FALSE SANDALWOOD, CAMPHOR LAUREL - SEEDLING, CAPEWEED, CASTOR OIL BUSH, CHILEAN CESTRUM, CHINEE APPLE, COMMON PRICKLY PEAR, DAWSON GUM, ENGLISH BROOM, ENGLISH IVY, EUCALYPTUS - SEEDLING UP TO 2 M TALL, EUCALYPTUS SPECIES - SEE LABEL, FENNEL, FURZE OR GORSE, GREEN OR EARLY BLACK WATTLE, GROUNDSEL BUSH, HOREHOUND, LANTANA - LANTANA CAMARA, NEEDLEWOOD, OLIVE - OLEA EUROPAEA, PAPERBARK, PRICKLY ACACIA, PRIVET, RUBBER VINE, SAFFRON THISTLE, SILVER WATTLE, SMOOTH TREE OR DROOPING PRICKLY PEAR, SWEET BRIAR OR WILD ROSE, TIGER PEAR, TREE-OF-HEAVEN, YELLOW WOOD]; RIGHTS OF WAY: [ACACIA GENUS, AFRICAN BOXTHORN, ANGOPHORA, AUSTRALIAN OR NATIVE BLACKTHORN, BANKSIA, BITTER BARK OR QUININE TREE, BLACK OR BRISBANE BLACK WATTLE, BLACKBERRY, BLACKBERRY IN ASSOC WITH OTHER WEED (SEE, BRIGALOW, BROWN SALWOOD OR HICKORY WATTLE, BUDDA OR FALSE SANDALWOOD, CAMPHOR LAUREL - SEEDLING, CAPEWEED, CASTOR OIL BUSH, CHILEAN CESTRUM, CHINEE APPLE, COMMON PRICKLY PEAR, DAWSON GUM, ENGLISH BROOM, ENGLISH IVY, EUCALYPTUS - SEEDLING UP TO 2 M TALL, EUCALYPTUS SPECIES - SEE LABEL, FENNEL, FURZE OR GORSE, GREEN OR EARLY BLACK WATTLE, GROUNDSEL BUSH, HOREHOUND, LANTANA - LANTANA CAMARA, NEEDLEWOOD, OLIVE - OLEA EUROPAEA, PAPERBARK, PRICKLY ACACIA, PRIVET, RUBBER VINE, SAFFRON THISTLE, SILVER WATTLE, SMOOTH TREE OR DROOPING PRICKLY PEAR, SWEET BRIAR OR WILD ROSE, TIGER PEAR, TREE-OF-HEAVEN, YELLOW WOOD]; SORGHUM: [PADDY MELON]; STUBBLE WEED CONTROL: [CAMEL OR AFGHAN MELON, PADDY MELON]; WEED CONTROL BY CUT STUMP APPLICATION: [AFRICAN BOXTHORN, AUSTRALIAN OR NATIVE BLACKTHORN, BITTER BARK OR QUININE TREE, BROOMS, BROWN SALWOOD OR HICKORY WATTLE, BUDDA OR FALSE SANDALWOOD, CAMPHOR LAUREL, CASTOR OIL BUSH, CHINEE APPLE, COMMON PRICKLY PEAR, DAWSON GUM, EUCALYPTUS, GREEN OR EARLY BLACK WATTLE, GROUNDSEL BUSH, LANTANA SPP., NEEDLEWOOD, OLIVE, PAPERBARK, PRICKLY ACACIA, PRIVET, RUBBER VINE, SILVER WATTLE, SMOOTH TREE OR DROOPING PRICKLY PEAR, SWEET BRIAR OR WILD ROSE, TIGER PEAR, TREE-OF-HEAVEN, YELLOW WOOD]; Poison schedule: 6; Withholding period: ; Host/pest details: BASAL BARK: [AFRICAN BOXTHORN, AUSTRALIAN OR NATIVE BLACKTHORN, BITTER BARK OR QUININE TREE, BROOMS, BROWN SALWOOD OR HICKORY WATTLE, BUDDA OR FALSE SANDALWOOD, CAMPHOR LAUREL, CASTOR OIL BUSH, CHINEE APPLE, COMMON PRICKLY PEAR, DAWSON GUM, EUCALYPTUS, GREEN OR EARLY BLACK WATTLE, GROUNDSEL BUSH, LANTANA SPP., NEEDLEWOOD, OLIVE, PAPERBARK, PRICKLY ACACIA, PRIVET, RUBBER VINE, SILVER WATTLE, SMOOTH TREE OR DROOPING PRICKLY PEAR, SWEET BRIAR OR WILD ROSE, TIGER PEAR, TREE-OF-HEAVEN, YELLOW WOOD]; COMMERCIAL/INDUSTRIAL LAND: [ACACIA GENUS, AFRICAN BOXTHORN, ANGOPHORA, AUSTRALIAN OR NATIVE BLACKTHORN, BANKSIA, BITTER BARK OR QUININE TREE, BLACK OR BRISBANE BLACK WATTLE, BLACKBERRY, BLACKBERRY IN ASSOC WITH OTHER WEED (SEE, BRIGALOW, BROWN SALWOOD OR HICKORY WATTLE, BUDDA OR FALSE SANDALWOOD, CAMPHOR LAUREL - SEEDLING, CAPEWEED, CASTOR OIL BUSH, CHILEAN CESTRUM, CHINEE APPLE, COMMON PRICKLY PEAR, DAWSON GUM, ENGLISH BROOM, ENGLISH IVY, EUCALYPTUS - SEEDLING UP TO 2 M TALL, EUCALYPTUS SPECIES - SEE LABEL, FENNEL, FURZE OR GORSE, GREEN OR EARLY BLACK WATTLE, GROUNDSEL BUSH, HOREHOUND, LANTANA - LANTANA CAMARA, NEEDLEWOOD, OLIVE - OLEA EUROPAEA, PAPERBARK, PRICKLY ACACIA, PRIVET, RUBBER VINE, SAFFRON THISTLE, SILVER WATTLE, SMOOTH TREE OR DROOPING PRICKLY PEAR, SWEET BRIAR OR WILD ROSE, TIGER PEAR, TREE-OF-HEAVEN, YELLOW WOOD]; FALLOW CROP LAND WEED CONTROL: [CAMEL OR AFGHAN MELON, PADDY MELON]; FENCELINE WEED CONTROL: [BROADLEAF HOPBUSH, NARROW LEAF HOP BUSH, TURPENTINE BUSH]; FIRE TRAIL: [BROADLEAF HOPBUSH, NARROW LEAF HOP BUSH, TURPENTINE BUSH]; FIREBREAK WEED CONTROL: [CAMEL OR AFGHAN MELON, PADDY MELON]; FOREST: [ACACIA GENUS, AFRICAN BOXTHORN, ANGOPHORA, AUSTRALIAN OR NATIVE BLACKTHORN, BANKSIA, BITTER BARK OR QUININE TREE, BLACK OR BRISBANE BLACK WATTLE, BLACKBERRY, BLACKBERRY IN ASSOC WITH OTHER WEED (SEE, BRIGALOW, BROWN SALWOOD OR HICKORY WATTLE, BUDDA OR FALSE SANDALWOOD, CAMPHOR LAUREL - SEEDLING, CAPEWEED, CASTOR OIL BUSH, CHILEAN CESTRUM, CHINEE APPLE, COMMON PRICKLY PEAR, DAWSON GUM, ENGLISH BROOM, ENGLISH IVY, EUCALYPTUS - SEEDLING UP TO 2 M TALL, EUCALYPTUS SPECIES - SEE LABEL, FENNEL, FURZE OR GORSE, GREEN OR EARLY BLACK WATTLE, GROUNDSEL BUSH, HOREHOUND, LANTANA - LANTANA CAMARA, NEEDLEW
Authorization status:
Registered
Authorization number:
52318
Authorization date:
2020-07-01

RELEVANT

LABELPART!CLiLARS

__

:·.·~·\-''·p~o·

··1~s·

...

"N"

·····

~··.

.......

:

-~--'-.1

......

. . .

OUT

OF

REACH

OF

CHILDREN

DIRECTIONS

BEFORE

OPENING

OR

USING

Approv~d

DIRECTIONS

Restraints:

apply

weeds

which

may.

stressed

(not

actively

growing)

prolonged

periods

e(<treme

cold,

moisture

stress

(water-logged

drought

affected),

poor

nutrition,

presence

disease,

previous

herbicide

treatment

reduced

levels

of control

result.

spray

rain

likely within

hour

foliage

from

rain

dew.

However,

when

tank

mixed

with

Wipe-Out

45.0,

this

time

extends

hours.

burn

off,

Clear

blackberry

other

woody

weeds

months

after

spraying.

WOODY

WEED

SITUATIONS

Table

High

Volume

Spraying

General

Instructions-

Applicatio·n

section

application

method

details.

AGRICULTURAL

NON-CROP

AREAS,

COMMERCIAL

INDUSTRIAL

AREAS,

FORESTS,

PASTURES

j:\ND

RIGHTS-OF-WAY.

WEEDS

CONTROLLED

WEED

GROWTH

STAGE

African

Boxthorn

Less

than

2m tall

Angophora,

tall

Banksia

regrowth

Blackberry

Active

growth

during

late

Spring

early

Autumn

association

with

During

flowe'ring

StJohn's

Wort

(Nov-Jan)

Brigalow

tall

Brooms:

English

Spring

mid-Summer

prior

formation

Camphor

Laurel

Seedlings

tall

Capeweed

Rosette

Common

Prickly

Pear

Active

growth

English

Active

growth

during

late

Spring

late

Summer

Eucalyptus

Seedlings

regrowth

from

smalllignotubers,

tall

SAFARI

HERBICIDE

FILENAME:

52318/

_RLP

STATE

RATE/100

WATER

only

170mL

States

NSW,

Vic,

only

Qld,

only

States

only

80mL

States

only

glyphosate

(360

g/L)

Qld,SA,WA,

only

NSW,

Vic,Tas

only

560mL

PAGE

CRITICAL

COMMENTS

higher

rate

larger

regrowth.

Ensure

weed

dense

foliage.

Where

herbicides

other

than

Group

I herbicides

have

been

used,

allow two

seasons

regrowth

occur

before

spraying

with

SAFARI

subsequent

regrowth

seedlings

should

sprayed

after

hardening

off.

Apply

thorough

foliage

spray.

least

1000

L ofwater/ha.

treat

growing

trees

other

plants

death

ofthe

host

result.

This

mixture

selective

grasses.

100%

concentrate

non-ionic

surfactant

(eg.

Wetspray

1000)

mU100

water for best

results.

DATE:

26/02/13

PRINT

100%

PAPER

RELEVANT

LABEL

PARTICULARS

WOODY

WEED

SITUATIONS

Tillile

High

Volume

Spraying-

continued

',S!ie'Generallnstructions- Applicatlon

section

for application

method

details.

AGRICULTURAL

NON-CROP

AREAS,

COMMERCIAL

INDUSTRIAL

AREAS,

FORESTS,

PASTURES

RIGHTS-OF-WAY.

WEEDS

CONTROLL~D

WEED

GROWTH

STAGE

STATE

Fennel

1 to 2

tall

only

Green

Cestrum

Qld,

NSW,

only

Groundsel

Bush

Seedlings,

tall

States

(Baccharis

halimifolia)

2to 3m tall

Gorse

Spring

Summer

Horehound

Rosette

only

Saffron

Thistle

stage

liger

Pear

Active

growth

States

Wattles,

including

Seedlings,

tall

Silver

Wattle,

2 to 3m tall

Black

Wattle

Table

Aerial Application

Helicopter

NSW,

Vic,

Tas,

only

Helicopter

fixed wing aircraft

(Old

only)

RATE/100

WATER

320mL

or340mL

170mL

80mL

160mL

320mL

General

Instructions- Application

section

application

method

details.

CRITICAL

COMMENTS

Some

regrowth

expected

following

season

which

sprayed

after

hardening

off.

100%

concentrate

non-io"nic

wetting

agent

rate

mU100

water.

Retreatment

regrowth

necessary.

higher

water

rate

older

hardened

plants.

AGRICULTURAL

NON-CROP

AREAS,

COMMERC,IAL

INDUSTRIAL

AREAS,

FORESTS,

PASTURES

RIGHTS-OF-WAY.

WEEDS

CONTROLLED

WEED

GROWTH

STAGE

STATE

RATE/ha

CRITICAL

COMMENTS

Blackberry

Late.

Spring

Autumn

States

Avoid

overspray/drift

onto

waterways.

Table

Controlled

Droplet Application

(C.D.A:)

Generallnstructions·"'·Application

section

for application

·method

details.

AGRICULTURAL

NON-CROP

AREAS,

COMMERCIAL

INDUSTRIAL

AREAS,

FORESTS,

PASTURES

RIGHTS-OF-WAY.

WEEDS

CONTROLLED

WEED

GROWTH

STAGE

STATE

RATE/1

L water

CRITICAL

COMMENTS

Blackberry

Late

Spring

Autumn

States

TableD:

Volume

High

Concentrate

Application

Techniques

(Gas

Powered

Gun,

Sprinkler

Sprayer)

General

Instructions-

Application

section

application

method

details.

AGRICULTU.RAL

NON-CROP

AREAS,

COMMERCIAL

INDUSTRIAL

AREAS,

FORESTS,

PASTURES

RIGHTS-OF-WAY.

WEEDS

CONTROLLED

WEED

GROWTH

STAGE

Blackberry

Late

Spring

Autumn

Eucalypt

seedlings

1to2mtall

SAFARI

HERBICIDE

FILENAME:

.52318/

_RLP

STATE

RATE/10

L water

States

PAGE20F6

CRITICAL

COMMENTS

DATE:

26/02/13

PRINT

100%

PAPER

RELEVANT

LABEL

PARTICULARS

Table

E:

Basal

Bark

and

Cut

Stump

Treatment

General

Instructions-

Application

section

application

method

details.

AGRICULTURAL

NON-CROP

AREAS,

COMMERCIAL

AND

INDUSTRIAL

AREAS,

FORESTS,

PASTURES

AND

RIGHTS-OF-WAY.

WEEDS

CONTROLLED

WEED

GROWTH

STAGE

STATE

RATE/60

L

DIESEL

CRITICAL

COMMENTS

African

Boxthorn

Basal

bark:

States

Australian

Blackthorn

Plants

basal

diameter

Broom

only

1.25

Brown

Salwood

Cut

stump:

States

Bitter

Bark

Plants

Old,

only

Castor

Oil.

excess

basal

bark

States

Chinee

Apple

sizes

Dawson

only

Eucalypts

(except

States

Dawson

Guml,

False

Sandalwood,

Green

Wattle,

Lantana,

Needlewood

Olive

only

NSWonly

Paperbark

Teatree,

States

Rubbervine,

Silver

Wattle

Sweet

Briar

ZL·

Yellow-wood

only

Camphor

Laurel

Basal

bark:

Qld,

only

Plants

basal

diameter

Common

Prickly

Pear.

States

Apply

thorough

foliage

spray.

Groundsel

Bush

Cut

stump:

Treat

from

early

Summer

rains

April

when

(Baccharis

halimifo!ial

Plants

regrowth

apparent.

Prickly

Acacia

excess

basal

bark

sizes

Privet

Treatment

carried

time

year.

Smooth

Tree

Pear,

L

Apply

thorough

foliage

spray.

Tiger

Pear

Tree

Heaven

AGRICULTURAL

(NON-CROP

AREAS,

COMMERCIAL

AND

INDUSTRIAL

AREAS,

FORESTS,

PASTURES

AND

RIGHTS-OF-WAYI

FENCELINES

AND

FIRE

TRAILS

only

WEEDS

CONTROLLED

WEED

GROWTH

STAGE

Broadleaf

Hopbush,

Basal

bark:

Narrowleaf

Hopbush,

Plants

Turpentine

Bush

basal

diameter

SAFARI

HERBICIDE

FILENAME:

52318/

STATE

RATE/60

L

DIESEL

NSWonly

PAGE30F6

CRITICAL

COMMENTS

DATE:

26/02/13

PRINT

100%

PAPER

RELEVANT

LABEL

PARTICULARS

CROPPING/FALLOW

SITUATIONS

General

Instructions- Application

section

application

method

details

FALLOW,

STUBBLE,

FIREBREAKS

WEEDS

CONTROLLED

WEED

GROWTH

STAGE

STATE

RATE/ha

CRITICAL

COMMENTS

Camei!Afghan,

Bitter)

diameter

Qld,

NSW,

Vic,

120ml0

There

some

strains

melon

that

Melon

WAonly

controlled.

Contact

your

FARMOZ

representative

Citrullus

lanatus)

Runners

from

160ml0

more

information.

diameter

crop

such

Uptake*

Spraying

Prickly

Paddy

Melon

diameter

80ml.O

ml/100

L water

0-C-Trate*

Crop

L/100

water.

ICucumis

Runners

from

160ml0

oils

when

tank

mixing

with

Wipe-Out"

myriocarpus)

diameter

Herbicide.

Compatibility

section.

Thi's

mixture

selective

grasses.

When

using

SAFAR1.600

Wipe-Out450

aerial

application,

observance

buffer

zone

metres

protect

riative

tree

species

required.

SORGHUM

(Apply

between

6 leaf

stage,

when

secondary

roots

have

developed.)

WEEDS

CONTROLLED

WEED

GROWTH

STAGE

STATE

RATE/ha

CRITICAL

COMMENTS

Prickly

Paddy

Melon

diameter

Qld,

only.

crop

oils,

severe

crop

damage

occur.

Fusing

sorghum

prop

roots

observed

this

worse

under

stress

!e.g.

root

disease).

Should

only

mixed

with

Starane*

Herbicide

atrazine

1500

flowable

only)

increased

weed

spectrum.

USED

PURPOSE,

MANNER,

CONTRARY

THIS

LABEL

UNLESS

AUTHORISED

UNDER

APPROPRIATE

LEGISLATION.

TASMANIA

BLACKBERRY:

TREAT

BUSHES

CARRYING

MATURE

NEAR

MATURE

FRUIT.

NATIVE

VEGETATION:

SAFARI

NATIVE

VEGETATION

MUST

DONE

ACCORDANCE

WITH

STATE

AND/OR

LOCAL

LEGISLATION.

WITHHOLDING

PERIODS:

PASTURE:

REQUIRED

WHEN

USED

DIRECTED.

SORGHUM:

REQUIRED

WHEN

USED

DIRECTED.

SAFARI600

HERBICIDE

PAGE

FILENAME:

52318/

DATE:

26/02/13

PRINT

100%

PAPER

RELEVANT

LABEL

PARTICULARS

C',f.Nf.RI.\L

ti\ISJfU..!ClJQNS

.··

RESISTANT

WEEDS

WARNING

SA~A_RI"'

Herbicid~

member

GROUP

HERBICIDE

pyndmes

group

herb1c1des.

product

the disrupters

plant cell growth

mode

action.

weed

resistance

management,

product

Group

herbicide.

Some

naturally-occurring

weed

biotypes

resistant

product

other

Group

herbicides

exist

through

normal

genetic

variability

weed population.

resistant individuals can eventually

dominate

wee·d

population

these

herbicides

used

repeatedly.

These

resistant weeds will not

controlled

SAFARI

Group

herbicides.

Since

occurrence

resistant

weeds

difficult to detect prior

use.

FARMOZ

Pty.

Ltd.

accepts

liability for

losses

that

result

from

failure

SAFARI

control resistant

weeds.

Strategies

minimise

risk

herbicide

resistance

available.

Contact

your

farm

chemical

supplier,

consultant,

local

Depa·rtment

Agriculture, or

local

FARMOZ

representative.

COMPATIBILITY

Fallow Situations

SAFARI

compatible

with

following'products:

Ester

(2,4-D

ester),

2,4-D

amine

(2,4-D amine), Zulu.,

(2,4-D

isopropylamine),

Flagship®

200,

glyphosate, Lontrel*, Starane*

200,

Wipe-Out.,

450,

Wipe-Out"'

Plus,

Victory.,

Strike-Out®

500EC

Insecticide.

When

mixing.

with

Wipe-Out450

Wipe-Out

Plus

refer

Wipe-Out

label

rate

adjuvants

recommended.

Uptake*

Spraying

Trate*

Crop

Oil.

Sorghum

SAFARI

is compatible with

Flagship®

200,

Starane*

200,

Farmozine

(atrazine

flowable

products

only).

MINIMUM

RE-CROPPING

PERIODS

Before

using

SAFARI

tank

mixes

with

other

herbicides,

check

plant-back information

product labels.

time between

spraying

planting will

determined

the product with the

longest

plant-back

period.

Observe

following

RE-CROPPING

periods

SAFARI

Wheat,

barley,

sorghum,

maize

days

Chickpeas,

soybeans,

sunflowers

days

Cotton

days

MIXING

Half fill

spray unit with water

required amount of

SAFARI

remaining

water

with

agitator

running.

required, then

crop oils

wetters (surfactants). Maintain

mechanical

by-pass

agitation

spray

tank

during

spraying.

Only

sufficient

solution

immediate

daily

avoid

storing.

Basal

Bark

Stump

Application:

Quarter

fill

spray

unit

mixing

container

with

diesel

and add

required

amount

SAFARI

remaining

diesel

shake

agitate

thoroughly

contents.

Periodically

shake

agitate

stop

product settling

out.

Only

sufficient solution for immediate daily

avoid

storing.

APPLICATION

WOODY

WEED

SITUATIONS

Weeds

need

actively growing for herbicides

have

optimum

effect.

Delay

treatment until all regrowth

time

grow

metre

high

in situations which

have

been

bulldozed,

slashed,

burnt,

ploughed

areas

having

previous

chemical

treatment.

High

Volume

Spraying:

Thorough

coverage

foliage

arid

stems

point

run-off

essential,

however,

avoid

excess

spraying

which

wasteful

chemical.

Hand

Gun:

Apply

recommended

give

full

coverage

leaves

stems

through

a No.6

8 tip

1500

kPa.

spray

volume

3,000

4,000

L per infested hectare

OOm')

should

used

weed

infestation.

Knapsack:

Used

small

infestations,

where

penetration

canopy

essential.

spray

volume

infested

area

should

used.

Aerial Application

Apply

water/ha.

calibrated

aircraft

apply

half overlap passes.

Nozzle

configurations should produce

droplets

less

than

micron

diameter

(e.g.

08/45).

potential for

damage

from

drift

greatly reduced

avoiding

unsuitable

spraying

conditions

using

spray

pressure

nozzles

minimise

production

small

droplets.

spray when wind

exceeds

km/hr and/or air

temperature

reaches

30°C.

SAFARI

HERBICIDE

PAGE50F6

FILENAME:

52318/

_RLP

-c~c~t~-~~~~il

orllplet'A'iiilii;;'~tiiJ~

ic.o.AJ

···

··.

Results

similar to

high

volume

spraying

obtained using

·Micron Herbi*

similar

equipment.

Select a

nozzle

give

a flow

rate

mUsec

sweeping

action

approximately

m/sec

ensure a droplet density of 20/cm'.

a marking agent

recommended

equipment

manufacturers,

check spray

coverage.

Also,

consult

directions

provided

with

C.D.A.

unit.

Volume

High

Concentrate Application Techniques:

Good

control

will

achieved,

similar

high

volume

application, where

bush

size

enables

good

coverage

bush.

a marking

agent,

recommended

the equipment manufacturers, to

check

spray

coverage.

powered

gun:

Apply

shots

obtain

uniform

coverage

surface

area

bush.

This

relates

droplets/em'

leaf

surface.

Sprinkler

sprayer:

This

technique

involves

using

a micro sprinkler

which

connected to a hollow fibre glass

attached to a

pressure

knapsack

sprayer.

pressures

kPa)

and·

apply

with a

slow

sweeping

action

over

plants

ensuring

even

coverage

leaves.

Basal

Bark

Stump

Treatment:

SAFARI

diesel.

of diesel

a herbicide carrier

affect the rubber

seals

some

sprayers.

avoid

this,

sprayers which

Viton*

seals

fittings.

Basal

Bark

Method:

apply

stems

this

repel

diesel

mixture.

Apply

only

with

hand-directed

equipment

such

pressure

sprayer

paint

brush.

Spray

equipment

should

used

pressures,

kPa,

avoid

excessive

splashing

drift. Species with

old,

rough

bark require

more

thorough

wetting

than

smooth

barked

species.

Liberally

spray

paint the

bark

around

stem

from

ground

level

high,

wetting

thoroughly

point

run-off

(unless

otherwise

stated).

Stump

Method:

Stems

should

less

than

above

ground.

Immediately

apply

SAFARI

diesel

mixture

liberally

freshly cut

stump

spray

painting

surface

sides

ofthe

stem.

"

CROPPING/FALLOW

SITUATIONS

Boom

Application

Application of

SAFARI

minimum

spray

volume

recommended.

Flat

nozzles

recommended,

using

pressures

range

200-300

kPa.

!;loom

height

must

ensure

double

overlap

nozzle

patterns.

Aerial Application

allow

SAFARI

to physically drift

onto

desirable

plants. Aircra·ft

used

apply

SAFARI

fallow

situations, wheri

ground

application

equipment

cannot

used

due.to

prolonged

conditions.

minimum

spray

volume

should

used

with flat

noizle configurations.

apply

SAFARI

aircraft

when

wind

exceeds

km/hr and/or air temperature reaches

30°C.

Droplets with

average

size·

Volume·

Mean

Dia.meter)

micron

diameter

recommended.

CLEANING

SPRAY

EQUIPMENT

Water-Based

Cleaning

Rinsing:

After

using

SAFARI

empty

spray

u~it

completely

drain

whole·

system.

Thoroughly

wash

inside

spray unit

using

pressure

hose.

Drain

spray

unit

clean

filters

tank,

pump,

lines,

hoses

nozzles.

After

cleaning

spray unit

above,

quarter fill with

clean

water

circulate

through

pump,

lines,

hoses

nozzles.

Drain

repeatthe

rinsing

procedure

twice.

Decontamination:

Before

spraying

cotton

.and

other

sensitive

crops,

with equipment that

been

used

to

apply

SAFARI

Protection

Crops,

Native

Other

Non-Target

Plants

section.

Wash

tank

rinse

system

above.

Then

quarter fill

tank

and add

alkali detergent (e.g. liquid

SURF,

OMO,

DRIVE

mU100

water

powder

equivalent

g/100

L of water)

circulate throughout

system

least

minutes.

Drain

whole

system

.Remove

filters

nozzles

clean

them

separately.

Finally,

flush

system

with

clean

water

allow

drain.

Rinse

water

should

discharged

onto

designated

disposal

area

this is unavailable,

onto

unused

land away

from

desirable plants

water

courses.

Diesel-Based

Cleaning

Rinsing:

After

using

SAFARI

empty

spray

unit completely

drain

whole

system.

Thoroughly

wash

inside the spray unit

using

pressure

hose

Drain

spray

unit

clean

filters

tank,

pump,

lines,

hoses

nozzles.

DATE:

26/02/13

PRINT

100%

~APER

RELEVANT

LABEL

PARTICULARS

completion

spraying,

use a degreaser such as

Caltex

Kwik-D:

Grease*

remove

traces

diesel

from

sprayer.

Rinse

tank

spray

through

nozzles

with

water

remove

degreaset:

Decontamination:

After

the above, quarter

fill

the tank

with

clean

water

alkali

detergent

(e.g.

liquid

SURF,

OMO,

OMOMATIC,

DRIVE

water

the powder

equivalent

water). Shake

operate spray to circulate

washing solution

throughout the sprayer

spray the solution through the nozzle.

Rinse

well

with clean water

remove-

detergent.

clean

brushes

container,

spray

liberally

with

degreaser.

Hose

thoroughly with clean water and repeat

using

detergents (see

above).

this

equipment

purpose.

PROTECTION

CROPS,

NATIVE

OTHER

NON-

TARGET

PLANTS

Crops

susceptible

SAFARI

include,

limited

peas, lupins, lucerne,

navy

beans, .soybeans

other legumes;

cotton,

fruit,

hops,

ornamentals, shade trees

Pinus

spp.,

potatoes,

saffloWer,.

sugarbeet,

sunflower,

tobacco, tomatoes, vegetables

vines.

SAFARI

damaging

susceptible

crops

during

both

growing

dormant

periods. Grasses are

normally

unaffected

establish

quickly

after

treatment.

allow

physical

spray

drift

onto

waterways,nativE!

vegetation

susceptible crops. Whenusirig

SAFARI

Wipe-Out

aerial

application

fallow

situations, observance

·buffer

zone

metres

protect

native

tree species

required.

apply

under

yveather

conditions,

from

spraying

equipment,

that

cause spray

drift

onto

nearby susceptible plants/crops,

cropping

lands

pastures.

PROTECTION

LiVESTOCK

Poisonous

plants

maybecome

more

palatable after

spraying

stock

should

kept

away

from

these plants uritilthey

have

died

down.

PROTECTION

WILDLIFE,

FISH,

CRUSTACEANS

ENVIRONMENT

This

product

highly

toxic to fish and other aquatic organisms.

contaminate streams,

rivers

waterways

with

chemical

used

containers.

STORAGE

DISPOSAL

Store

closed original container

a cool, well-ventilated area.

store

prolonged

periods

direct

sunlight.

store

near

food,

feedstuffs, fertilisers

seed.

re-use containers.

Triple

rinse.containers

before

disposal.

rinsings

spray

tank.

dispose

undiluted

chemicals

site.

recycling,

replace

return clean containers

recycler

a designated collection

point.

recycling, break, crush

puncture

del_iver

empty

packaging

approved

waste management

facility.

an·

approved

waste f[lanagemeritfacility

available

bury

empty

packaging

below

surface

a disposal

specifically

marked

for.this

purpos~,

clear

waterways, desirable vegetation

tree roots,

compliance with relevant

Local,

State

Territory

government

regulations.

burn

enipty

containers

product.

Enviniilrum

Micro

Matic

Valve

(110

Store

original

sealed

Envirodrum

cool

well-ventilated

area.

store

prolonged

periods in.direct

sunlight.

tamper

with

Micro

Matic

valve

security seal.

contaminate

Envirodrum

with

water

foreign

matter.

After

each use

product,

please ensure that the

Micro

Matic

coupler

delivery

system

hoses are disconnected, triple rinsed

with

clean water and

drained

accordingly.

When

the contents

Envirodrum

have

been

used, please returri the

Envirodrum

point

purchase.

Envirodrum

remains

property

FARMOZ

Pty.

Ltd.

1000

Store

the closed,

original

container

cool,

well-yentilated

area.

store

prolonged

periods

direct

sunlight.

Storage must

secure

that contents cannot

tampered

with.

locks

and/or

seals

must

order.

locks

seals are

broken

prior

initial

then

the integrity

this product cannot

assured. lfthis occurs

FARMOZ

Pty.

Ltd.

should be advised immediately.

This

minibulk

container

reusable

remains

property

FARMOZ

Pr{.

Ltd.

rinse

erripty

container.

Empty

contents

fully

into

application

equipment.

Close

valves

return

tothe

point

supply

refill

storage.

other

liquid,

solid

pesticide

produptsh.ould

into

When

empty

return

FARMOZ

Pty.

Ltd.

cleaning,

relabelling

refilling.

SAFARI

HERBICIDE

PAGE60F6

FILENAME:

52318/

SMALL

SPILL

MANAGEMENT

. ·

Wear protective

equipment

(see

Safety.

Directions).

Apply

absorbent

material.such

earth, sand, clay granules

cat litter to the

spill.

Sweep

·material

disposal

when

absorption

completed

contain

a refuse vessel

disposal (see Storage

Disposal

section).

necessary

wash

spill

area

with

alkali

detergent

water

absorb

wash

liquid

above

disposal.

SAFETY

DIRECTIONS

Poisonous

swallowed.

irritate the eyes

skin.

Avoid

contact

with

eyes

skin.

When

opening

container

preparing the

spray

using

prepared

spray wear

cotton

overalls

buttoned

the neck and wrist

a washable

and elbow length rubber gloves. Wash hands after

use.

After

each

daysuse

wash gloves

and contaminated

clothing.

FIRST

poisoning

occurs

.contact

a doctor

Poisons

Information

Centre.

Phone

Australia

131126.1f

eyes,

hold

eyes

open,

flood

with.

water

at least

minutes

see a

doctor.

MATERIAL

SAFETY

DATA

SHEET

Additipnal information

listed

the material safety data sheet

(MSDS).

material

safety

data

sheet

SAFARI

available

from

FARMOZ

request.

Call

Customer

Service

(02)

9431

7800.

CONDITIONS

SALE:

SAFARI

Herbicide

being

beyond

control

manufacturer,

warranty

expressed

implied

given

FARMOZ

Pty.

Ltd.,

regarding

suitability,

fitness

efficiency

purpose

which

used

buyer,

whether

accordance

with

directions

.FARMOZ

Pty.

ltd.

accepts

responsibility

consequence

whatsoever

from

this

product.

®Registered

Trademarks

FARMOZ

Pty.ltd.

*Other

Trademarks

No:3082

ENVIRONMENTALLY

HAZARDOUS

SUBSTANCE,

LIQUID,

N.O.S.

PACKAGING

GROUP:

HAZCHEM

CODE:

Farmoz

Pty.

ltd.

Suite

1,-Level4,

Building

Pacific

Highway

Leonards

2065

Australia

Tel:

(02)

9431

7800

Fax:

(02)

9431

7700

APVMAApproval

52318/SC'f

IJ-

Batch

Date

Manufacture

DATE:

26/02/13

PRINT

100%

PAPER

Product Name: Safari 600EC Herbicide

Page: 1 of 6

This revision issued: August, 2012

SAFETY DATA SHEET

Issued by: Adama Australia Pty Ltd

Phone: (02)9431 7800 (office hours)

Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)

Section 1 - Identification of The Material and Supplier

Adama Australia Pty Ltd, Suite 1, Level 4,

Building B

207 Pacific Highway St Leonards, NSW 2065

ACN 050 328 973

Telephone (02)9431 7800 (office hours)

Emergency 1800 024 973 (24 hours)

Fax (02)9431 7700

Chemical nature:

Triclopyr is an aryloxyalkanoic acid derivative. It is presented here as an ester.

Trade Name:

Safari 600EC Herbicide

Product Use:

Agricultural herbicide for use as described on the product label.

Creation Date:

July, 2006

This version issued:

August, 2012

and is valid for 5 years from this date.

Section 2 - Hazards Identification

Statement of Hazardous Nature

This product is classified as:

Xi. T. N. Hazardous according to the criteria of SWA.

Not subject to the ADG Code when transported in Australia by Road or Rail in packages 500kg(L) or less; or IBCs

(refer to SP AU01). However if transported by Air or Sea, this provision does not apply. Then the product is classed

as Dangerous (Class 9 Environmentally Hazardous) by IATA and IMDG respectively. See details below and in

Section 14 of this MSDS.

Risk Phrases:

R22, R43, R54, R36/38, R50/53. Harmful if swallowed. May cause sensitisation by skin contact.

Toxic to flora. Irritating to eyes and skin. Very toxic to aquatic organisms, may cause long-term adverse effects to the

aquatic environment.

Safety Phrases:

S2, S13, S20, S26, S28, S29, S62, S20/21, S24/25, S36/37/39. Keep out of reach of children.

Keep away from food, drink and animal feeding stuffs. When using, do not eat or drink. In case of contact with eyes,

rinse immediately with plenty of water and contact a doctor or Poisons Information Centre. After contact with skin,

wash immediately with plenty of soap and water. Do not empty into drains. If swallowed, do not induce vomiting: seek

medical advice immediately and show this MSDS. When using, do not eat, drink or smoke. Avoid contact with skin

and eyes. Wear suitable protective clothing, gloves and eye/face protection.

SUSMP Classification:

ADG Classification:

Class 9: Miscellaneous dangerous goods.

UN Number:

3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.

Emergency Overview

Physical Description & colour

: Clear brown liquid.

Odour:

No data.

Major Health Hazards:

irritating to eyes and skin, harmful if swallowed, possible skin sensitiser.

Potential Health Effects

Inhalation

Short term exposure:

Available data indicates that this product is not harmful. In addition product is unlikely to

cause any discomfort or irritation.

Long Term exposure:

No data for health effects associated with long term inhalation.

Skin Contact:

Short term exposure:

Classified as a potential sensitiser by skin contact. Exposure to a skin sensitiser, once

sensitisation has occurred, may manifest itself as skin rash or inflammation, and in some individuals this reaction can

be severe. In addition product is a skin irritant. Symptoms may include itchiness and reddening of contacted skin.

Other symptoms may also become evident, but all should disappear once exposure has ceased.

Long Term exposure:

No data for health effects associated with long term skin exposure.

Eye Contact:

Short term exposure

: This product is an eye irritant. Symptoms may include stinging and reddening of eyes and

watering which may become copious. Other symptoms may also become evident. If exposure is brief, symptoms

Product Name: Safari 600EC Herbicide

Page: 2 of 6

This revision issued: August, 2012

SAFETY DATA SHEET

Issued by: Adama Australia Pty Ltd

Phone: (02)9431 7800 (office hours)

Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)

should disappear once exposure has ceased. However, lengthy exposure or delayed treatment may cause permanent

damage.

Long Term exposure

: No data for health effects associated with long term eye exposure.

Ingestion:

Short term exposure

: Significant oral exposure is considered to be unlikely. Available data shows that this product

is harmful, but symptoms are not available. This product is unlikely to cause any irritation problems in the short or long

term.

Long Term exposure

: No data for health effects associated with long term ingestion.

Carcinogen Status:

SWA:

No significant ingredient is classified as carcinogenic by SWA.

NTP:

No significant ingredient is classified as carcinogenic by NTP.

IARC:

No significant ingredient is classified as carcinogenic by IARC.

Section 3 - Composition/Information on Ingredients

Ingredients

CAS No

Conc,%

TWA (mg/m

3

)

STEL (mg/m

3

)

Triclopyr (as butoxyethanol ester)

64700-56-7

600g/L

not set

not set

Other non hazardous ingredients

secret

to 100

not set

not set

This is a commercial product whose exact ratio of components may vary slightly. Minor quantities of other non

hazardous ingredients are also possible.

The TWA exposure value is the average airborne concentration of a particular substance when calculated over a normal 8 hour working day for a 5

day working week. The STEL (Short Term Exposure Limit) is an exposure value that may be equalled (but should not be exceeded) for no longer

than 15 minutes and should not be repeated more than 4 times per day. There should be at least 60 minutes between successive exposures at the

STEL. The term "peak "is used when the TWA limit, because of the rapid action of the substance, should never be exceeded, even briefly.

Section 4 - First Aid Measures

General Information:

You should call The Poisons Information Centre if you feel that you may have been poisoned, burned or irritated by

this product. The number is 13 1126 from anywhere in Australia (0800 764 766 in New Zealand) and is available at all

times. Have this MSDS with you when you call.

Inhalation:

First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor.

Skin Contact:

Wash gently and thoroughly with warm water (use non-abrasive soap if necessary) for 10-20 minutes

or until product is removed. Under running water, remove contaminated clothing, shoes and leather goods (e.g.

watchbands and belts) and completely decontaminate them before reuse or discard. If irritation persists, repeat

flushing and seek medical attention.

Eye Contact:

Immediately flush the contaminated eye(s) with lukewarm, gently flowing water for 20 minutes or until

the product is removed, while holding the eyelid(s) open. Take care not to rinse contaminated water into the

unaffected eye or onto the face. Obtain medical attention immediately. Take special care if exposed person is wearing

contact lenses.

Ingestion:

If swallowed, do NOT induce vomiting. Wash mouth with water and contact a Poisons Information

Centre, or call a doctor.

Section 5 - Fire Fighting Measures

Fire and Explosion Hazards

: This product is classified as a C1 combustible product. There is no risk of an

explosion from this product under normal circumstances if it is involved in a fire.

Fire decomposition products from this product may be toxic if inhaled. Take appropriate protective measures.

Extinguishing Media

: Try to contain spills, minimise spillage entering drains or water courses.

Fire Fighting

: If a significant quantity of this product is involved in a fire, call the fire brigade. There is little danger of

a violent reaction or explosion if significant quantities of this product are involved in a fire. Recommended personal

protective equipment is full fire kit and and breathing apparatus.

Flash point

:

95°C

Upper Flammability Limit:

No data.

Lower Flammability Limit:

No data.

Autoignition temperature:

No data.

Flammability Class:

Product Name: Safari 600EC Herbicide

Page: 3 of 6

This revision issued: August, 2012

SAFETY DATA SHEET

Issued by: Adama Australia Pty Ltd

Phone: (02)9431 7800 (office hours)

Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)

Section 6 - Accidental Release Measures

Accidental release

: In the event of a major spill, prevent spillage from entering drains or water courses. Wear full

protective clothing including eye/face protection. All skin areas should be covered. See below under Personal

Protection regarding Australian Standards relating to personal protective equipment. Suitable materials for protective

clothing include rubber, PVC. Eye/face protective equipment should comprise as a minimum, protective goggles. If

there is a significant chance that vapours or mists are likely to build up in the cleanup area, we recommend that you

use a respirator. It should be fitted with a type G cartridge, suitable for agricultural chemicals.

Stop leak if safe to do so, and contain spill. Absorb onto sand, vermiculite or other suitable absorbent material. If spill

is too large or if absorbent material is not available, try to create a dike to stop material spreading or going into drains

or waterways. Because of the environmentally hazardous nature of this product, special care should be taken to

restrict release to waterways or drains. Sweep up and shovel or collect recoverable product into labelled containers

for recycling or salvage, and dispose of promptly. Recycle containers wherever possible after careful cleaning. Refer

to product label for specific instructions. After spills, wash area preventing runoff from entering drains. If a significant

quantity of material enters drains, advise emergency services. Full details regarding disposal of used containers,

spillage and unused material may be found on the label. If there is any conflict between this MSDS and the label,

instructions on the label prevail. Ensure legality of disposal by consulting regulations prior to disposal. Thoroughly

launder protective clothing before storage or re-use. Advise laundry of nature of contamination when sending

contaminated clothing to laundry.

Section 7 - Handling and Storage

Handling

: Keep exposure to this product to a minimum, and minimise the quantities kept in work areas. Check

Section 8 of this MSDS for details of personal protective measures, and make sure that those measures are followed.

The measures detailed below under "Storage" should be followed during handling in order to minimise risks to

persons using the product in the workplace. Also, avoid contact or contamination of product with incompatible

materials listed in Section 10.

Storage

: This product is a Scheduled Poison. Observe all relevant regulations regarding sale, transport and storage

of this schedule of poison. Check packaging - there may be further storage instructions on the label.

Section 8 - Exposure Controls and Personal Protection

The following Australian Standards will provide general advice regarding safety clothing and equipment:

Respiratory equipment: AS/NZS 1715, Protective Gloves: AS 2161, Occupational Protective Clothing: AS/NZS 4501

set 2008, Industrial Eye Protection: AS1336 and AS/NZS 1337, Occupational Protective Footwear: AS/NZS2210.

SWA Exposure Limits

TWA (mg/m

3

)

STEL (mg/m

3

)

Exposure limits have not been established by SWA for any of the significant ingredients in this product.

The ADI for Triclopyr (as butoxyethanol ester) is set at 0.01mg/kg/day. The corresponding NOEL is set at 1mg/kg/day.

ADI means Acceptable Daily Intake and NOEL means No-observable-effect-level. Values taken from Australian ADI

List, Sept 2011.

No special equipment is usually needed when occasionally handling small quantities. The following instructions are

for bulk handling or where regular exposure in an occupational setting occurs without proper containment systems.

Ventilation:

No special ventilation requirements are normally necessary for this product. However make sure that

the work environment remains clean and that vapours and mists are minimised.

Eye Protection:

Protective glasses or goggles should be worn when this product is being used. Failure to protect

your eyes may cause them harm. Emergency eye wash facilities are also recommended in an area close to where

this product is being used.

Skin Protection:

If you believe you may have a sensitisation to this product or any of its declared ingredients, you

should prevent skin contact by wearing impervious gloves, clothes and, preferably, apron. Make sure that all skin

areas are covered. See below for suitable material types.

Protective Material Types:

We suggest that protective clothing be made from the following materials: rubber,

PVC.

Respirator:

If there is a significant chance that vapours or mists are likely to build up in the area where this product

is being used, we recommend that you use a respirator. It should be fitted with a type G cartridge, suitable for

agricultural chemicals.

Eyebaths or eyewash stations and safety deluge showers should be provided near to where this product is being

used.

Product Name: Safari 600EC Herbicide

Page: 4 of 6

This revision issued: August, 2012

SAFETY DATA SHEET

Issued by: Adama Australia Pty Ltd

Phone: (02)9431 7800 (office hours)

Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)

Section 9 - Physical and Chemical Properties:

Physical Description & colour

Clear brown liquid.

Odour:

No data.

Boiling Point:

Not available.

Freezing/Melting Point:

No specific data. Liquid at normal temperatures.

Volatiles:

No data.

Vapour Pressure:

0.4752 x10-6kPa at 25°C

Vapour Density:

No data.

Specific Gravity:

1.20 at 20°C

Water Solubility:

Emulsifiable.

pH:

6.7 (10% emulsion in water)

Volatility:

No data.

Odour Threshold:

No data.

Evaporation Rate:

No data.

Coeff Oil/water distribution

No data

Autoignition temp:

No data.

Section 10 - Stability and Reactivity

Reactivity:

This product is unlikely to react or decompose under normal storage conditions. However, if you have

any doubts, contact the supplier for advice on shelf life properties.

Conditions to Avoid:

Store in the closed original container in a dry, cool, well-ventilated area out of direct sunlight.

Incompatibilities:

strong acids, strong bases, strong oxidising agents.

Fire Decomposition:

Carbon dioxide, and if combustion is incomplete, carbon monoxide and smoke. Nitrogen and

its compounds, and under some circumstances, oxides of nitrogen. Occasionally hydrogen cyanide gas in reducing

atmospheres. Hydrogen chloride gas, other compounds of chlorine. Water. Carbon monoxide poisoning produces

headache, weakness, nausea, dizziness, confusion, dimness of vision, disturbance of judgment, and

unconsciousness followed by coma and death.

Polymerisation:

This product will not undergo polymerisation reactions.

Section 11 - Toxicological Information

Local Effects:

Target Organs:

see below

Classification of Hazardous Ingredients

Ingredient

Risk Phrases

Triclopyr (as Butoxyethanol Ester)

Conc>=25%: Xn; R22

SYSTEMIC (OTHER TARGET ORGAN) EFFECTS:

For the active ingredient, in animals, effects have been reported on the following organs: Blood, kidney, liver.

For Glycol Ethers, in animals, effects have been reported in the testes.

CANCER INFORMATION: In long-term animal studies with ethylene glycol butyl ether, small but statistically

significant increases in tumours were observed in mice but not rats. The effects are not believed to be relevant to

humans. If the material is handled in accordance with proper industrial handling procedures, exposures should not

pose a carcinogenic risk to man. Active ingredient did not cause cancer in laboratory animals.

TERATOLOGY (BIRTH DEFECTS): Did not cause birth defects in laboratory animals. Has been toxic to the foetus

in lab animals at doses toxic to the mother.

REPRODUCTIVE EFFECTS: In laboratory animals studies, effects on reproduction have been seen only at doses

that produced significant toxicity to the parent animals.

MUTAGENICITY (EFFECTS ON GENETIC MATERIAL): For the active ingredient: In vitro genetic toxicity studies

were negative. Animal genetic toxicity studies were negative.

Section 12 - Ecological Information

This product is toxic to flora. Very toxic to aquatic organisms, may cause long-term adverse effects to the aquatic

environment. This product is biodegradable. It will not accumulate in the soil or water or cause long term problems.

Product Name: Safari 600EC Herbicide

Page: 5 of 6

This revision issued: August, 2012

SAFETY DATA SHEET

Issued by: Adama Australia Pty Ltd

Phone: (02)9431 7800 (office hours)

Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)

ENVIRONMENTAL FATE: Triclopyr butoxyethyl ester is rapidly hydrolysed to triclopyr acid in soil and

water.

MOVEMENT & PARTITIONING:

Based largely or completely on information for the active ingredient.

Bioconcentration potential is moderate (BCF between 100 and 3000 or Log Pow between 3 and 5).

Measured log octanol/water partition coefficient (Log Pow) is 4.09.

Log air/water partition coefficient (Log Kaw) is -4.0.

DEGRADATION & PERSISTENCE:

Based largely or completely on information for the active ingredient.

Biodegradation under aerobic static laboratory conditions is moderate (BOD20 or BOD28/ThOD between

10 and 40%).

ECOTOXICOLOGY:

Based largely or completely on information for the active ingredient.

Fish LC

= 0.36 mg/L in the most sensitive species tested. Algae 24 hour EC

= 0.1 mg/L in the most

sensitive species tested.

Bird acute LD

= 735 mg/kg in the most sensitive species tested.

Section 13 - Disposal Considerations

Disposal:

Instructions concerning the disposal of this product and its containers are given on the registered label.

These should be carefully followed. Special help is available for the disposal of Agricultural Chemicals. The product

label will give general advice regarding disposal of small quantities, and how to cleanse containers. However, for help

with the collection of unwanted rural chemicals, contact ChemClear 1800 008 182 http://www.chemclear.com.au/ and

for help with the disposal of empty drums, contact DrumMuster http://www.drummuster.com.au/ where you will find

contact details for your area.

Section 14 - Transport Information

Not subject to the ADG Code when transported by Road or Rail in Australia, in packages 500kg(L)

or less; or IBCs, but classed as Dangerous by IATA and IMDG when carried by Air or Sea transport

(see details below).

ADG Code:

3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.

Hazchem Code:

3Z

Special Provisions:

179, 274, AU01

Limited quantities:

ADG 7 specifies a Limited Quantity value of 5 L for this class of product.

Dangerous Goods Class:

Class 9: Miscellaneous Dangerous Goods.

Packaging Group:

Packaging Method:

P001, IBC03, LP01

Class 9 Miscellaneous Dangerous Goods shall not be loaded in the same vehicle or packed in the same freight

container with Dangerous Goods of Class 1 (Explosives).

Section 15 - Regulatory Information

AICS:

All of the significant ingredients in this formulation are compliant with NICNAS regulations.

The following ingredients: Triclopyr (as butoxyethanol ester), are mentioned in the SUSMP.

Section 16 - Other Information

This MSDS contains only safety-related information. For other data see product literature.

Acronyms:

ADG Code

Australian Code for the Transport of Dangerous Goods by Road and Rail, 7th Edition

AICS

Australian Inventory of Chemical Substances

SWA

Safe Work Australia, formerly ASCC and NOHSC

CAS number

Chemical Abstracts Service Registry Number

Hazchem Code

Emergency action code of numbers and letters that provide information to emergency

services especially firefighters

IARC

International Agency for Research on Cancer

NOS

Not otherwise specified

Product Name: Safari 600EC Herbicide

Page: 6 of 6

This revision issued: August, 2012

SAFETY DATA SHEET

Issued by: Adama Australia Pty Ltd

Phone: (02)9431 7800 (office hours)

Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)

NTP

National Toxicology Program (USA)

R-Phrase

Risk Phrase

SUSMP

Standard for the Uniform Scheduling of Medicines & Poisons

UN Number

United Nations Number

Contact Points:

Call Adama on (02)9431 7800 and ask for the technical manager.

Fax: (02)9431 7700

Police and Fire Brigade:

Dial 000

Emergency contact:

1800 024 973 (24 hours)

If ineffective:

Dial Poisons Information Centre

(

13 1126 from anywhere in Australia)

The information contained in this Material Safety Data Sheet is provided in good faith and is believed to be correct at the date

hereof. However, it is expected that individuals receiving the information will exercise their independent judgement in determining

its appropriateness for a particular purpose. Adama Australia Pty Ltd makes no representation as to the accuracy or

comprehensiveness of the information and to the full extent allowed by law excludes all liability whatsoever, whether with respect

to negligence or otherwise, for any loss or damage arising from or connection with the supply or use of the information in this

Material Safety Data Sheet.

Please read all labels carefully before using product.

This MSDS is prepared in accord with the SWA document “National Code of Practice for the Preparation of

Material Safety Data Sheets” 2nd Edition [NOHSC:2011(2003)]

Copyright © Kilford & Kilford Pty Ltd, August, 2012.

http://www.kilford.com.au/

Phone (02)9251 4532

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