RYEDOWN HERBICIDE

Australia - English - APVMA (Australian Pesticides and Veterinary Medicines Authority)

Active ingredient:
diclofop-methyl(375g/L)
Available from:
GROW CHOICE
INN (International Name):
diclofop-methyl(375g/L)
Pharmaceutical form:
Emulsifiable
Units in package:
20L,110L,200L
Class:
AgChem
Therapeutic group:
BARLEY | CANOLA | CEREAL RYE | LINSEED CROP | LUPIN | PASTURE LEGUME SEED CROP | PEA | POPPY OILSEED | SAFFLOWERS | TRITICALE |
Therapeutic area:
Group A Herbicide
Therapeutic indications:
ANNUAL OR WIMMERA RYEGRASS | COMMON BARB GRASS | WILD OAT | RIGID RYEGRASS | WIMMERA RYEGRASS
Product summary:
A post-emergent herbicide for control of annual ryegrass, common barbgrass and wild oats in wheat, linseed, peas, and other crops.
Authorization status:
Registered and available
Authorization number:
54003/0301
Authorization date:
2001-04-09

POISON

KEEP OUT OF REACH OF CHILDREN

READ SAFETY DIRECTIONS BEFORE OPENING OR USING

RYEDOWNTM

HERBICIDE

ACTIVE CONSTITUENT: 375gIL

DICLOFOP-METHYL

SOLVENT: 534gIL HYDROCARBON LIQUID

Group

..

Herbicide

A Post-emergent herbicide Control

Annual Ryegrass,

Common Barbgrass and

Wild Oats in Wheat, Linseed,

Peas and other Crops as listed in the Directions for

Use table.

CONTENTS:

20, 110, 200

LITRES

GROW

CHOICE

PTY.

LTD

113 Fitzroy Street

Tamworth

2340

Tel:

02 67 663 979

069 839 961

Trademark

Grow Choice

14 March 2001

N.R.A.

APPROVED

~BEL

}J'EXT)

Label

~'07.

70/

Date:

I:.t

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Signature:4~.??:;:.~~~/

Page 1

CROP

WEED

STATE

WEED

RATE

CRITICAL

COMMENTS

STAGE

1111.

Wheat,

linseed,

Annual

(Wimmera)

States

to4leaf

Apply generally 3 to

weeks

after sowing,

triticale,

ryegrass

when

cereals

usually

5 leaves.

canola,

barley,

apply

only

when

crop

is 4 to 5

safflower, rye,

leafstage.

barley

wetting

agent

0.25%

a.i.

water

Common

barbgrass

NSWOnIy

1.25

spray

tank.

, This

irrespective

ofvoiume

waterlha

rate

Ryedown

Herbicide.

wetting

agent

mixing

with

some

other

sprays

(refer

compatibility).

Lupins,

peas

Annual

ryegrass

NSW,

Vic, Tas.,

leaf

WAonly

Common

barbgrass

NSWOnIy

1.25

Wheat,

linseed,

Wild

Oats

States

leaf

barley,

apply

only

when

crop

is 4

triticale,

leaf

stage.

void

double

spraying

(overlap)

safflower, rye,

at the

maximum

rate

l.5Uha.

crops

barley.

canola

other

than

barley,

rate

most

weeds

leaf

spraying 4

6 weeks

after

sowing.

especially

northern

wetting

agent

as above.

3w

leaf

(not

Use 1.5 L rate

OOly

growing

conditionsare

barley)

very favourable and

weeds

are 2

leaf

weeks

after

sowing,

cereals

usually

2w31eaf

Lupins,

peas

Wild

Oats

NSW.

Vic,

Tas,

2w

leaf

WAonlv

leaf

Pasture

legume

Annual ryegrass

States

leaf

wetting

agent

as above.

Ensure

seed crops

thorough

coverage

weeds.

WildOat'i

Oilseed

Wild Oats,

annual

only

critical

0.5

wetting

agent.

Apply

poppies

ryegrass (refer critical

comments

accordance

with

recommendations

made

comments)

Department

Agriculture

or the

poppy

contractina

comoanv.

DIRECTIONS

Restraints:

apply

rainfall is expected within 2 hours.

spray when temperatures are higher

than

25°C.

apply to weeds or crop under stress due to,

for e.g.,

very dry,

very wet,

nutrient

deficient

frost or diseased conditions

NOT TO BE USED

ANY PURPOSE,

ORIN

ANY MANNER, CONTRARY TO THIS

LABEL UNLESS AUTHORISED UNDER APPROPRIATE LEGISLATION.

WITHHOLDING PERIOD

GRAZING:

DO NOT GRAZE

STOCKFEED

7 WEEKS

AFTER

APPLICATION.

CROP HARVEST: NOT REQUIRED WHEN USED AS DIRECTED

14 March 2001

Page 2

"

GENERAL

INSTRUCTIONS

best

results apply

when

growing

conditions

good

weeds

crop

which

stressed from

fuctors

such

as severe frost,

waterlogging

conditions.

Avoid applying

crops

which are

covered

frost.

Wild

oats

germinating after application

will

often

stunted

will

seriously

compete

with

the crop.

Results indicate

that

a spray

mixture

be left overnight without loss

efficiency,

spraying cannot be

completed

it is recommended that

spray mixture be

used

same day it is prepared.

MIXING

Fill

spray

tank

about

thirds

full

with

clean

water

then

required

amount

down

Herbicide

reminder

water

with

agitation system engaged.

a wetting agent is required add

this

last

prevent excessive foaming

APPLICATION

apply

Ryedown

Herbicide to base

weeds

ensure

penetration.

COMPATmILITY

broadleafweed

control in wheat,

barley, triticale

rye,

following compatibilities

indicated.

Ryedown

Herbicide may be mixed with

following

products

without a significant loss

activity: Brornoxynil,

Lontrel'

(up to 150mL/ha), dimethoate,

omethoate

and phosmet.

Ryedown

Herbicide

be mixed

with

the following

products,

some loss

grass

weed

control and/or speed

ofkill

should be expected: Bromoxynil

Tigrex'

(max.

800 mL/ha),

MCPA

(max.

mL/ha).

Ryedown

Herbicide may be mixed

with

the following products,

some

loss

wild

control

should be expected:

Jaguar'

to 750 mL/ha), Eclipse'

g!ha).

When

mixing

with

broadleafherbicides

a non-ionic surfactant (lOOOgIL) at

rate

of250

100L

spray solution.

Reductions in

grass

weed

control

(as indicated above)

be minimised

using

a minimum

of80

water

ground

30 L

air,

ifwild

oats

present, use

RyedownHerbicide/ha

(except barley).

use Brornoxynil

MCPA

rates above 1.4

L/ha

when

mixing

with

Ryedown

Herbicide.

Allow

least

10 days

between

any application

ofRyedown

Herbicide

other

herbicides containing

4-D,

dicamba

other

similar sprays,

which

should preferably follow

Ryedown

Herbicide.

in oilseed poppies in Tasmania only:

Ryedown

Herbicide

be mixed

with

pesticides as

recommended by

Department

Agriculture

poppy

contracting company.

Where phalaris is present,

Ryedown

Herbicide

andPuma'

be applied

together

the respective

recommended rates.

Wetting agent should be

added

to this mixture at

the rate recommended

Ryedown

Herbicide

label

March

2001

Page

RESISTANT

WEEDS

WARNING

Ryedown

Herbicide is a member

aryloxphenoxypropionate

group

herbicides.

Ryedown

Herbicide is

inhibitor

acetyl

carboxylase.

weed

resistance management

Ryedown

Herbicide

is a

Group

A herbicide.

Some

naturally-occurring

weed

biotypes resistant

Ryedown

Herbicide and

other

herbicides which inhibit

acetyl

carboxylase

exist through

normal

genetic

variability in

weed

population.

The resistant

individuals

eventually dominate

weed

population

these herbicides

used

repeatedly.

These

resistant

weeds

will

be controlled by

Ryedown

Herbicide

other

inlnbitors

acetyl

carboxylase.

Since occurrence

resistant

weeds

is difficult to

detect

prior

use,

Grow

Choice

accepts no

liability fur

losses

that

result from

failure

Ryedown

Herbicide

control resistant weeds.

EQUIPMENT

Ground

Sprayers - Standard

boom

sprays only

recommended

must

be fitted

with

by-pass-pass

mechanical agitation.

is recommended

approximately 50 to 150 L waterlha

a droplet size

microns.

apply

with

boomless

jets

misters.

Aircraft -

Best

results have

been

obtained using

waterlha

with

a steady cross wind

swath

width

18 metres.

fur a droplet size

microns.

exaggerate

swath

width.

Aircraft operators should consult manufacturer for details.

PROTECTION

WILDLIFE,

FISH,

CRUSTACEANS

ENVIRONMENT

contaminate streams, rivers,

waterways

with

chemical

used

containers.

PROTECTION

CROP,

NATIVE AND

OrnER

NON-TARGET

PLANTS

apply under

weather

conditions

from

spraying equipment

that

cause spray to drift onto

nearby susceptible plants, adjacent

crops

(eg. maize,

sorghum,

rice)

crop

lands

pasture.

plant

susceptible

crops

(eg.

maize,

sorghum, rice) for 10

weeks

after application.

UNDERSOWN

CLOVERS

MEDICS

Ryedown Herbicide Selective Herbicide

does

affect

undersown

clovers

medics

other

broadleaf

crops,

no activity against

broadleaf

weeds.

STORAGE

DISPOSAL

Store

closed, original container in a cool, well ventilated

area

store for

prolonged

periods

in direct sunlight.

Triple

preferably pressure

rinse

containers before disposal.

rinsings to spray tank.

dispose

undiluted chemicals

site.

recycling, replace

return

clean

containers to recycler

designated collection point.

recycling, break,

crush,

puncture

bury

empty

containers in a local authority landfill.

landfill is available, bury

containers below

500mm

a disposal

specifically

marked

set up for

this purpose clear

waterways,

desirable

vegetation

tree

roots.

Empty

containers

product

should

be burnt.

14 March 2001

Page 4

"

SAFETY DIRECTIONS

The product may irritate the eyes

skin.

Avoid contact with eyes and skin

do not inhale spray

mist.

When preparing spray,

wear

cotton

overalls buttoned to the neck

and wrist,

and washable hat

elbow-

length PVC gloves and face shield.

After use and before eating, drinking or smoking, wash hands,

arms

face thoroughly with

soap

water.

After each day'S use,

wash gloves,

face shield and contaminated

clothing.

FIRST AID

poisoning occurs, contact a doctor

Poisons Information Centre (Tel:

MATERIAL SAFETY DATA SHEET

Additional information is listed in the

Material

Safety

Data

Sheet which is available from the supplier.

ADVICE TO PHYSICIAN

No antidote is available

treatment should be symptomatic.

Gastric lavage with medical charcoal in

water is recommended.

Induce diuresis and monitor electrolyte and fluid balance.

Observe

kidney

function.

NOTICE TO BUYER

Grow

Choice

Pty.

Ltd.

will

be held liable for any loss,

injury or damage,

indirect

consequential, arising from the sale,

supply,

application

this product.

product is not

to be used for any purpose

in any way contrary to label instructions.

Batch No:

NRAApprovalNo:54-603

3

01

Date

Manufacture:

Not Trademarks

Grow Choice

14 March 2001

Page 5

GrowChoicePtyLtd Page1of4 Ryedown

Product Name: RyedownHerbicide

StatementofHazardousNature:

ClassifiedashazardousaccordingtothecriteriaoftheNationalOccupationalHealth&

SafetyCommission(NOHSC)–S6

I IDENTIFICATION

ProductName: Ryedown Herbicide

ChemicalName: DiclofopMethyl,Solvesso200,ProprietarySurfactant(aromatic

sulphonatesandethyleneoxidecondensatetlype)

Use: ForpostemergentcontrolofAnnualRyegrass,CommonBarbgrassand

WildOatsinWheat,Barley,Linseed,Peasandothercrops.

PhysicalAppearance&Properties:

AppearanceandOdour: Lighttodarkbrownliquidwitharomaticodour

BoilingPoint°C: >226

MeltingPoint: <0 0 C

VapourPressure: 0.17kPa@38 0 C(forsolvent),0.034mPa

@20 0 CfoAI

VolatileComponent 40–50%

SpecificGravity: 1.090–1.098

Flashpoint: 92 0 C

FlammabilityLimits: Lower0.6%,higher7%

AutoignitionTemp: Notknown,>226 0 C

Rel.VapourDensity: >1(forsolvent)

Form: Liquid

OtherProperties: Formsanemulsioninwater

INGREDIENTS:

Component CASNo Proportion(w/v)

DiciofopMethyl 51338-27-3 375G/I

Solvesso200 40-50%

ProprietarySurfactant(aromaticsulphonates

Andethyleneoxidecondensatetype) 10-20%

TOXICITYDATA:

Fortheproduct: Toxictomammals

AcuteoralLD50(rat):2000mg/Kg

AcutedermalLD50(rat):5000mg/Kg

AcuteinhalationLC50(rate,1hour):14–20mg/L

GROW CHOICE PTY LTD

ABN 62 069 839 961

113 Fitzroy Street

Tamworth NSW 2340

MATERIALSAFETY DATA SHEET

GrowChoicePtyLtd Page2of4 Ryedown

AcuteoralLD50(rats):557-580mg/Kg

AcutedermalLD50(femalerats):>2000mg/Kg

Toxicitytobirds:

EightdaydietaryLD50(quailandduck):>20,000mg/Kg

Toxicitytofish:

Toxictofish

LC50(Orfe)2.19mg/L(24hours)

LC50(Orfe)2.07mg/L(48hours)

1.81mg/L(96hours)

TheAustralianAcceptableDailyIntake(ADI)ofdiclofop-methylforahumanis0.002mg/kg/day,setforthe

publicfordaily,lifetimeexposure.ThisisbasedontheNOELof0.25mg/kg/day,theleveldeterminedto

shownoeffectsduringlongtermexposureforthemostsensitiveindicatorsandthemostsensitivespecies.

(Ref:Comm.Dept.ofHumanServicesandHealth,“ADIList”,AGPS<May1994)

II HEALTHHAZARDDATA

HEALTHEFFECTS:

ACUTEEFFECTS

Swallowed: Theconcentrateisofrelativelylowtoxicity.Theproducthasbeen

assessedusingtheWorksafeCriteriaandhasbeenfoundtobenon-

hazardous.

Eye: Prolongedcontactoftheeyewiththeconcentratemaycauseirritation..

Skin: Theconcentratemayirritatetheskin.Prolongedorrepeatedexposureto

thesolventpresentmaycausedefattingoftheskinwhichcouldleadto

secondarydermatitis.

Inhaled: Avoidinhalingspraymist.

ChronicEffects: Noneknown.

FIRSTAID:

Swallowed: Ifswallowedandifmorethan15minutesfromahospital,induce

vomiting,preferablyusingIpecacSyrup(APF).Donotapplymouthto

mouthresuscitationifmaterialingested.

Eye: Immediatelyirrigatewithcopiousquantityofwaterforatleast15

minutes.Eyelidstobeheldopen..

Skin: Removecontaminatedclothingandlaunderbeforere-use.Washaffected

areasthoroughlywithsoapandwater.

Inhaled: Removepatienttofreshairuntilrecovered.Giveartificialresuscitationif

breathinghasstopped.

AdvicetoDoctor: Noantidoteisavailableandtreatmentshouldbesymptomatic.Gastric

lavagewithmedicinalcharcoalinwaterisrecommendedinductdiuresis

andmonitorelectrolyteandfluidbalance.Observekidneyfunction.Once

vomitinghasoccurredtreatmentmayberequiredtopreventthesolvent

presentcausingpulmonarypneumonitis.

III PRECAUTIONSFORUSE:

ExposureLimits:

Noexposurestandardshavebeensetforthisproduct.Themanufacturerofthesolventhasrecommendeda

TLVof100ppmforthesolvent.

EngineeringControls:

Naturalonlyalthoughalocalexhaustshouldbeprovidedifmaterialishandledinconfinedspacesto

minimiseexposuretosolventvapours.

PersonalProtection:

Mayirritatetheeyesandskin.Avoidcontactwitheyesandskin.DONOTinhalespraymist.Whenpreparing

sprayandusingthepreparedspray,wearcottonoverallsbuttonedtotheneckandwristandwashablehat,

elbow-lengthPVCglovesandfaceshield.Afteruseandbeforeeating,drinkingorsmoking,washhands,

armsandfacethoroughlywithsoapandwater.Aftereachday’suse,washgloves,faceshieldand

contaminatedclothing.

GrowChoicePtyLtd Page3of4 Ryedown

Flammability:

Combustible

Environment:

DONOTcontaminatestreams,riversorwaterwayswiththechemicalorusedcontainers.Disposeofused

containersinaresponsiblemanner.

IV SAFEHANDLINGINFORMATION:

StorageandTransport:

Donotuseorstorenearheatornakedflames.Storeinclosed,originalcontainerinawell-ventilatedarea

awayfromchildren,animals,food,feedstuffs,seedandfertilizers.

Transport:ConsiderednonhazardousfortransportbytheAustralianCodefortheTransportofDangerous

GoodsbyRoadandRail.

PackagingandLabelling

POISONS6

Nottobetaken

Keepoutofreachofchildren

Readsafetydirectionsbeforeopening

TheproducthasbeenassessedaccordingtotheWorksafecriteriaforclassifyinghazardoussubstancesandis

classifiedasnothazardous.

SpillsandDisposal

Containspillandabsorbwithsandorproprietaryabsorbent(vermiculite).Preventfromenteringdrains,

waterwaysofsewers.Collectinsealedopen-topcontainersfordisposal.Triplerinsecontainers,addrinsings

tothespraytank,thenoffercontainerforrecycling/reconditioning,orpuncturetop,sidesandbottomand

disposeofinlandfillinaccordancewithlocalregulations.On-sitedisposalofconcentrateisnotacceptable.

Fire/ExplosionHazard

Mayemittoxicfumesifinvolvedinfiresorexposedtoextremeheat.SCBAshouldbewornbyfirefighters.

Allotherpersonnelshouldbemovedtothewindwardsideofanyfire.

ExtinguishingMedia:Foam,carbondioxide

Controlfirewater,theproductisaherbicide.

ReactivityData:

Keepawayfromstrongoxidisingagents.Willnotpolymerise.

V OTHERINFORMATION:

Disclaimer:

TheinformationprovidedintheseMSDS’sisbaseduponsourcesbelievedtobeaccurate.However,the

Companyassumesnoresponsibilityfortheaccuracy,completenessorsuitabilityofthisinformation.The

productuserisresponsibletodeterminethesuitabilityofthisinformationfortheirparticularpurposes.

INCASEOFEMERGENCYDIAL000

IFINEFFECTIVE:PHONEPOISONSINFORMATIONCENTRE

SPECIALISTCOMPANYADVICE:

GrowChoicePtyLtd

113FitzroyStreet,

TAMWORTHNSW2340

Phone:0267663979

Fax:0267662922

DISCLAIMER:

GrowChoicePtyLtd Page4of4 Ryedown

This Material Safety Data Sheet has been developed according to the WORKSAFE/NOHSC Code of Practice.

Thedata,informationandrecommendationsherein(“information”)arerepresentedingoodfaithandbelievedtobe

correct as of the data hereof.

The purpose of this Material Safety Data Sheet is to describe product in terms of their safety requirements.

GrowChoicePtyLtdmakesnorepresentationofmerchantability,fitnessforaparticularpurposeofapplication,orofany

other nature with respect to the information or the product to which the information refers (“the product”).

Theinformationissuppliedupontheconditionthatthepersonsreceivingsamewillmaketheirowndeterminationasto

its suitability for their purpose prior to the use of the product.

Thephysicaldatashownhereinaretypicalvaluesbasedonthematerialtested.Thesevaluesshouldnotbeconstruedasa

guaranteed analysis of any specific lot or as guaranteed specification for the product or specific lots thereof.

Due care should be taken to make sure that the use or disposal of this product and/or its packaging is in compliance with

relevant Federal, State and Local Government regulations.

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