ORICA ECLIPSE GRANULATED CHLORINE FOR SWIMMING POOLS

Australia - English - APVMA (Australian Pesticides and Veterinary Medicines Authority)

Active ingredient:
CHLORINE PRESENT AS CALCIUM HYPOCHLORITE
Available from:
IXOM OPERATIONS PTY LTD
INN (International Name):
Cl as Ca hypochlorite(650g/kg)
Pharmaceutical form:
GRANULAR FORMULATION
Composition:
CHLORINE PRESENT AS CALCIUM HYPOCHLORITE MINERAL-CHLORINE Active 650.0 g/kg
Units in package:
10kg; 20kg; 2kg; 40kg; 4kg
Class:
A - Agricultural
Manufactured by:
IXOM OPERATIONS
Therapeutic group:
SWIMMING POOL
Therapeutic area:
ALGICIDE
Therapeutic indications:
ALGAE | BACTERIA
Product summary:
Poison schedule: 5; Withholding period: WHP: n/a.; Host/pest details: SWIMMING POOL: [ALGAE, BACTERIA]; Poison schedule: 5; Withholding period: ; Host/pest details: SWIMMING POOL: [ALGAE, BACTERIA]; For the control of algae and bacteria in swimming pools.
Authorization status:
Registered
Authorization number:
51310
Authorization date:
2019-07-01

Product Name: Orica Eclipse Granulated Chlorine

Description:

2,4,

10.20

& 40

CDS: 10645

Ref:

\CL_HYPO\CAHY_LAB.doc

Page 1 of 4

File Number: TBA

Date: 16 September

1998

Version: 1.03

Text above this line and

Dane1

indicators in italics are not included in the label

FRONT PANEL

CAUTION

KEEP OUT OF REACH OF CHILDREN

FIRE AND EXPLOSION HAZARD

READ SAFETY DIRECTIONS BEFORE OPENING OR USING

ORICA ECLIPSE GRANULATED

CHLORINE FOR SWIMMING POOLS

Active Constituent: 650 g/kg available CHLORINE (Cl)

present as CALCIUM HYPOCHLORITE

For the control of algae and bacteria in swimming pools.

NET:

2,4.10,20

&

40 Kg

ORICA AUSTRALIA OPERATION PTY LTD

1 Nicholson Street Melbourne 3001

A.C.N. 004 117 828

Orica, the Orica Logo and Eclipse are trade marks of Orica Group companies.

N.R.Aa

APPROVEDLABEL(TEXT)

Label No:

.-%%?/!?.fg

.,...

Product Name: Orica Eclipse Granulated Chlorine

Description: 2,4,

IO.20

&

40 Kg

CDS:

10645

Page 2 of 4

File Number: TBA

Date:

September

1998

Ref:

\CL_HYPO\CAHY_LAB.doc

Version: 1.03

Text above this line and panel indicators in italics are not included in the label

LEFT PANEL

DIRECTIONS FOR USE

RESTRAINTS: DO NOT

use this product in spa pool water.

DO NOT

use in a fixed or

floating dispenser.

SPA/POOL VOLUME

*STABILISED POOLS

UNSTABILISED

FREE CHLORINE

( LITRES)

DAILY CHLORINE

POOLS DAILY

CONCENTRATION

DOSAGE

CHLORINE DOSAGE

10,000

litres

of water

INITIAL START UP

SHOCK TREATMENT

CHLORINATION

7 x daily dosage

daily dosage

4 x daily dosage

daily

dosage

Refer to

required

levels

table

lo-15 mg/L

mg/L

* Contains chlorine stabiliser, such as

cyanuric

acid.

These dosage rates are only a guide to try and achieve the required levels of free chlorine.

REQUIRED LEVELS

TYPE OF POOL

LEVEL OF

TOTAL

MINIMUM FREE CHLORINE

STABILISER

ALKALINITY

LEVEL

(mgk)

(Optimum

(mm)

(mm)

Range)

minimum

Cold Water

Above 26

“C

UNSTABILISED

to 7.6

STABILISED

30-50

DO NOT EXCEED A CONCENTRATION OF 50

mg/L

OF ISOCYANURATE

!36+?_7S~~

POSE

IN AN

M A N N E R

CONTRARY

THIS

LABEL UNLESS AUTHORISED UNDER APPROPRIATE LEGISLATION.

r&

Product Name: Orica Eclipse Granulated Chlorine

Page 3 of 4

Description:

2,4,

10, 20

&

40 Kg

File Number: TBA

CDS: 10645

Date:

16 September 1998

Ref:

\CL_HYPO\CAHY_LAB.doc

Version: 1.03

Text above this line and panel indicators in italics are not included in the label

BACK LABEL

-

RIGHT PANEL

GENERAL INSTRUCTIONS

The correct level of free chlorine should be maintained for several hours prior to and during

swimming

activity.

Chlorine levels and

pH

should be tested daily by use of a reliable test kit

using fresh testing reagents. If pH falls below the required level add dry alkali, if it rises above

add dry acid or hydrochloric acid. Dose pool in the evening when pool is not in use.

Stabiliser

levels

should be tested monthly by your local pool shop or by use of a reliable test kit.

SUPER CHLORINATION

During the swimming season Super-Chlorinate once per week. After Super-Chlorination the

pH balance of your pool should be checked.

WINTER

MAINTENANCE

A Super-Chlorination dose once a month is necessary to maintain your pool in good condition

during

winter.

CAUTION: Not to be used as a food container.

SAFETY

DIRECTIONS

Highly reactive oxidising chlorine compound. May cause fire and explosion or produce severe

burns. Product will irritate the eyes, nose, throat and skin. Avoid contact with eyes, skin and

clothing. Do not inhale dust. Do not allow the product to come in contact with other chemicals,

especially acids, or with combustible materials such as paper, fabric, sawdust or kerosene. Do

not allow to get damp. Use clean containers for dispensing. Do not mix with other chemicals.

Do not mix with different types of chlorinating chemicals. Mix with water only. Do not add

water to the product

add the product to water, but in case of fire, drench with water. Store

undercover in a dry, clean, cool, well ventilated place away from sunlight.

Store and transport

all containers in an upright position.

In case of spillage, flush with large quantities of water.

Wash hands after use.

FIRST AID

If poisoning occurs, contact a doctor or Poisons Information Centre (phone 13 1126). If

swallowed, DO NOT induce vomiting. Give a glass of water. If skin contact occurs, remove

contaminated clothing and wash skin thoroughly. If in eyes, hold eyes open, flood with water

for at least 15 minutes and see a doctor.

Product Name: Orica Ecliose Granulated Chlorine

Page4

Description: 2, 4,

&

40 Kg

FileNumber:TBA

CDS: 10645

Ref:

\CL_HYPO\CAHY_LAB.doc

Date: 16 September 1998

Version: 1.03

Text above this line and

uanel

indicators in italics are not included in the label

BACK LABEL

-

RIGHT PANEL (Cont.)

CALCIUM HYPOCHLORITE, HYDRATED

UN NO.

2880

FOR SPECIALIST ADVICE IN EMERGENCY CALL ORICA

AUSTRALIA’S 24 HOUR EMERGENCY RESPONSE SERVICE ON

DIAL 1 800 033 111

ALL HOURS

AUSTRALIA WIDE

NRA Approval Number:

310,

/.ycf’

,<

LABEL LAY-OUT

FOR

ORICA ECLIPSE GRANULATED CHLORINE

FOR SWIMMING POOLS

2kg,

4kg

&

40kg PRODUCTS

SINGLE WRAP AROUND LABEL

Left

Panel

Front

Right

Panel

Panel

1Okg

&

20kg PRODUCTS

FRONT LABEL

BACK LABEL

Panel

Right

Panel

Material Safety Data Sheet

1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER

Product Name:

ORICA ECLIPSE GRANULATED CHLORINE FOR SWIMMING

POOLS

Recommended Use:

Swimming pool chemical, algicide, biocide, oxidant.

Supplier:

Orica Australia Pty Ltd

ABN:

004 117 828

Street Address:

1 Nicholson Street,

Melbourne 3000

Australia

Telephone Number:

+61 3 9665 7111

Facsimile:

+61 3 9665 7937

Emergency Telephone:

1 800 033 111 (ALL HOURS)

2. HAZARDS IDENTIFICATION

This material is hazardous according to criteria of ASCC; HAZARDOUS SUBSTANCE.

Classified as Dangerous Goods by the criteria of the Australian Dangerous Goods Code (ADG Code) for Transport by

Road and Rail; DANGEROUS GOODS.

Risk Phrases:

Contact with combustible material may cause fire. Harmful if swallowed. Contact with acids liberates

toxic gas. Causes burns. Risk of serious damage to eyes. Very toxic to aquatic organisms.

Safety Phrases:

Avoid contact with skin and eyes. In case of contact with eyes, rinse immediately with plenty of water

and seek medical advice. Wear suitable protective clothing, gloves and eye/face protection. In case of

accident or if you feel unwell, seek medical advice immediately (show the label whenever possible).

Poisons

Schedule:

S6 Poison.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Components / CAS Number

Proportion

Risk Phrases

Calcium hydroxide

1305-62-0

1-5%

R38, R41

Water

7732-18-5

7-16%

Calcium hypochlorite

7778-54-3

>60%

R8, R22, R31, R34, R41, R50

Product Name:

ORICA ECLIPSE GRANULATED CHLORINE FOR SWIMMING POOLS

Substance No:

000031064512

Issued:

12/11/2008

Version:

4

Page 1 of 8

Material Safety Data Sheet

4. FIRST AID MEASURES

For advice, contact a Poisons Information Centre (Phone eg. Australia 131 126; New Zealand 0 800 764766) or a doctor.

Inhalation:

Remove victim from area of exposure - avoid becoming a casualty. Remove contaminated clothing

and loosen remaining clothing. Allow patient to assume most comfortable position and keep warm.

Keep at rest until fully recovered. If patient finds breathing difficult and develops a bluish

discolouration of the skin (which suggests a lack of oxygen in the blood - cyanosis), ensure airways

are clear of any obstruction and have a qualified person give oxygen through a face mask. Apply

artificial respiration if patient is not breathing. Seek immediate medical advice.

Skin Contact:

If skin or hair contact occurs, immediately remove any contaminated clothing and wash skin and

hair thoroughly with running water. If swelling, redness, blistering or irritation occurs seek medical

assistance.

Eye Contact:

Immediately wash in and around the eye area with large amounts of water for at least 15 minutes.

Eyelids to be held apart. Remove clothing if contaminated and wash skin. Urgently seek medical

assistance. Transport to hospital or medical centre.

Ingestion:

Immediately rinse mouth with water. If swallowed, do NOT induce vomiting. Give a glass of water.

Seek immediate medical assistance.

Medical attention

and special

treatment:

Treat symptomatically. Can cause corneal burns. Delayed effects from exposure to chlorine

(decomposition product) can include shortness of breath, severe headache, pulmonary oedema

and pneumonia.

5. FIRE FIGHTING MEASURES

Hazards from combustion

products:

Non combustible, but will support combustion of other materials.

Precautions for fire fighters and

special protective equipment:

Not combustible, however will support the combustion of other materials. Calcium

hypochlorite is a powerful oxidising agent and decomposes violently upon heating

liberating oxygen, and toxic chlorine gas. In case of fire, area must be evacuated and

specialist fire fighters called. Only large quantities of water should be used as an

extinguishing agent. If excess water is not available DO NOT attempt to extinguish

the fire; use available water to prevent the spread of fire to adjacent property.

Attending fire fighters should keep upwind if possible and wear full protective

equipment including rubber boots and self-contained breathing apparatus. A fire in

the vicinity of calcium hypochlorite should be extinguished in the most practical

manner but avoid contaminating this material with the fire fighting agent, including

water. Decomposes on contact with water evolving toxic chlorine gas. Once fire is

extinguished, wash area thoroughly with excess water. Ensure that drains are not

Product Name:

ORICA ECLIPSE GRANULATED CHLORINE FOR SWIMMING POOLS

Substance No:

000031064512

Issued:

12/11/2008

Version:

4

Page 2 of 8

Material Safety Data Sheet

blocked with solid material. Maintenance of excess water during cleaning up

operation is essential. Combustible material involved in the incident should be

removed to a safe open area for controlled burning or for further drenching with water

prior to collection for disposal.

Suitable Extinguishing Media:

Coarse water spray, fine water spray, normal foam, dry agent (carbon dioxide, dry

chemical powder).

Hazchem Code:

6. ACCIDENTAL RELEASE MEASURES

Emergency procedures:

Shut off all possible sources of ignition. Clear area of all unprotected personnel. If

contamination of sewers or waterways has occurred advise local emergency services.

For large spills notify the Emergency Services.

Methods and materials for

containment and clean up:

Wear protective equipment to prevent skin and eye contact and breathing in

vapours/dust. Air-supplied masks are recommended to avoid inhalation of toxic material.

DO NOT return spilled material to original container. DO NOT add small amounts of water

to calcium hypochlorite. Sweep up, avoiding generation of dust, then immediately spread

as a thin layer in uncontaminated, dry, open area to reduce the possibility of local hot

spots forming.

Where a spill has occurred in a confined space or an inadequately ventilated enclosure

and the material is damp and evolving chlorine, the rate of chlorine evolution can be

reduced by covering the thinly spread solid with soda ash.

7. HANDLING AND STORAGE

This material is a Scheduled Poison S6 and must be stored, maintained and used in accordance with the relevant

regulations.

Conditions for safe storage:

Store in a cool, dry, well ventilated place and out of direct sunlight. Store away from

foodstuffs. Store away from incompatible materials described in Section 10. Keep dry -

reacts with water, may lead to drum rupture. Keep containers closed when not in use -

check regularly for spills.

Precautions for safe handling:

Avoid skin and eye contact and breathing in dust. Keep out of reach of children.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Occupational Exposure Limits:

No value assigned for this specific material by the National Occupational Health and Safety Commission. However,

Exposure Standard(s) for constituent(s):

Calcium hydroxide: 8hr TWA = 5 mg/m3

As published by the National Occupational Health and Safety Commission.

Product Name:

ORICA ECLIPSE GRANULATED CHLORINE FOR SWIMMING POOLS

Substance No:

000031064512

Issued:

12/11/2008

Version:

4

Page 3 of 8

Material Safety Data Sheet

TWA - The time-weighted average airborne concentration over an eight-hour working day, for a five-day working week

over an entire working life.

These Exposure Standards are guides to be used in the control of occupational health hazards. All atmospheric

contamination should be kept to as low a level as is workable. These exposure standards should not be used as fine

dividing lines between safe and dangerous concentrations of chemicals. They are not a measure of relative toxicity.

Engineering controls:

Ensure ventilation is adequate and that air concentrations of components are controlled below quoted Exposure

Standards. Avoid generating and breathing in dusts. Use with local exhaust ventilation or while wearing dust mask. Keep

containers closed when not in use.

Personal Protective Equipment:

The selection of PPE is dependant on a detailed risk assessment. The risk assessment should consider the work

situation, the physical form of the chemical, the handling methods, and environmental factors.

Orica Personal Protection Guide No. 1, 1998: F - OVERALLS, SAFETY SHOES, CHEMICAL GOGGLES, GLOVES,

DUST MASK.

Wear overalls, chemical goggles and impervious gloves. Avoid generating and inhaling dusts. If dust exists, wear dust

mask/respirator meeting the requirements of AS/NZS 1715 and AS/NZS 1716. Always wash hands before smoking,

eating, drinking or using the toilet. Wash contaminated clothing and other protective equipment before storage or re-use.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical state:

Solid

Colour:

White

Odour:

Chlorine

Molecular Formula:

Ca(OCl)2

Solubility:

Soluble in water.

Specific Gravity:

2.35

Relative Vapour Density (air=1):

Not available

Vapour Pressure (20 °C):

Not available

Flash Point (°C):

Not available

Flammability Limits (%):

Not available

Autoignition Temperature (°C):

Not available

% Volatile by Weight:

Not available

Solubility in water (g/L):

Not available

Melting Point/Range (°C):

Not available

Decomposition Point (°C):

ca. 180

pH:

Not available

Product Name:

ORICA ECLIPSE GRANULATED CHLORINE FOR SWIMMING POOLS

Substance No:

000031064512

Issued:

12/11/2008

Version:

4

Page 4 of 8

Material Safety Data Sheet

10. STABILITY AND REACTIVITY

Chemical stability:

Powerful oxidising agent. Calcium hypochlorite (dry or hydrated) and its mixtures are

incompatible with dichloroisocyanuric acid, ammonium nitrate, trichloroisocyanuric acid,

or any chloroisocyanurate. Reacts with water liberating chlorine.

Conditions to avoid:

Avoid exposure to heat.

Incompatible materials:

Calcium hypochlorite (dry or hydrated) and its mixtures are incompatible with

dichloroisocyanuric acid, ammonium nitrate, trichloroisocyanuric acid, or any

chloroisocyanurate, strong acids, aluminium, iron, lead, magnesium, and zinc.

Incompatible with organic materials , combustible materials , reducing agents , ammonia ,

nitrogen compounds , acidic materials , and chlorinated isocyanuric acid (organic

bleaching powder) .

Hazardous decomposition

products:

Chlorine.

Hazardous reactions:

Reacts with water liberating toxic chlorine gas. Decomposition occurs on contact with

heat , reducing agents , and combustible materials .

11. TOXICOLOGICAL INFORMATION

No adverse health effects expected if the product is handled in accordance with this Safety Data Sheet and the product

label. Symptoms or effects that may arise if the product is mishandled and overexposure occurs are:

Ingestion:

Swallowing can result in nausea, vomiting, diarrhoea, abdominal pain and chemical burns to the

gastrointestinal tract.

Eye contact:

A severe eye irritant. Corrosive to eyes; contact can cause corneal burns. Contamination of eyes can

result in permanent injury.

Skin contact:

Contact with skin will result in severe irritation. Corrosive to skin - may cause skin burns.

Inhalation:

Breathing in dust may result in respiratory irritation. Chlorine, evolved from decomposition when wet, is a

severe respiratory irritant, corrosive, and highly toxic. Delayed effects can include shortness of breath,

headache, pulmonary oedema, and pneumonia.

Long Term Effects:

No information available for the product.

Toxicological Data:

Oral LD50 (rat):

790-1260 mg/kg.

Product Name:

ORICA ECLIPSE GRANULATED CHLORINE FOR SWIMMING POOLS

Substance No:

000031064512

Issued:

12/11/2008

Version:

4

Page 5 of 8

Material Safety Data Sheet

12. ECOLOGICAL INFORMATION

Ecotoxicity

Avoid contaminating waterways.

Persistence/degradability and mobility

This material is biodegradable.

Aquatic toxicity:

Very toxic to aquatic organisms.

96hr LC50 (fish):

0.15 mg/L (Atlantic silverside)

13. DISPOSAL CONSIDERATIONS

Disposal methods:

Refer to Waste Management Authority. Dispose of material through a licensed waste

contractor. Clean containers with water.

14. TRANSPORT INFORMATION

Road and Rail Transport

Classified as Dangerous Goods by the criteria of the Australian Dangerous Goods Code (ADG Code) for Transport by

Road and Rail; DANGEROUS GOODS.

OXIDIZING

AGENT

5.1

UN No:

2880

Class-primary

5.1 Oxidizing Agent

Packing Group:

Proper Shipping Name:

CALCIUM HYPOCHLORITE, HYDRATED

Hazchem Code:

Marine Transport

Classified as Dangerous Goods by the criteria of the International Maritime Dangerous Goods Code (IMDG Code) for

transport by sea; DANGEROUS GOODS.

UN No:

2880

Class-primary:

5.1 Oxidizing Agent

Packing Group:

Proper Shipping Name:

CALCIUM HYPOCHLORITE, HYDRATED

Air Transport

Classified as Dangerous Goods by the criteria of the International Air Transport Association (IATA) Dangerous Goods

Regulations for transport by air; DANGEROUS GOODS.

UN No:

2880

Class-primary:

5.1 Oxidizing Agent

Packing Group:

Product Name:

ORICA ECLIPSE GRANULATED CHLORINE FOR SWIMMING POOLS

Substance No:

000031064512

Issued:

12/11/2008

Version:

4

Page 6 of 8

Material Safety Data Sheet

Proper Shipping Name:

CALCIUM HYPOCHLORITE, HYDRATED

15. REGULATORY INFORMATION

Classification:

This material is hazardous according to criteria of ASCC; HAZARDOUS SUBSTANCE.

Hazard Category:

Xn: Harmful

C: Corrosive

Risk Phrase(s):

R8: Contact with combustible material may cause fire.

R22: Harmful if swallowed.

R31: Contact with acids liberates toxic gas.

R34: Causes burns.

R41: Risk of serious damage to eyes.

R50: Very toxic to aquatic organisms.

Safety Phrase(s):

S24/25: Avoid contact with skin and eyes.

S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical

advice.

S36/37/39: Wear suitable protective clothing, gloves and eye/face protection.

S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label

whenever possible).

Poisons Schedule:

S6 Poison.

This material is listed on the Australian Inventory of Chemical Substances (AICS).

16. OTHER INFORMATION

In: 'The Dictionary of Substances and their Effects'. Ed.Gangolli S. Royal Society of Chemistry, 1999.

Reason(s) for Issue:

5 Yearly Revised Primary MSDS

This MSDS summarises to our best knowledge at the date of issue, the chemical health and safety hazards of the

material and general guidance on how to safely handle the material in the workplace. Since Orica Limited cannot

anticipate or control the conditions under which the product may be used, each user must, prior to usage, assess and

control the risks arising from its use of the material.

If clarification or further information is needed, the user should contact their Orica representative or Orica Limited at the

contact details on page 1.

Orica Limited's responsibility for the material as sold is subject to the terms and conditions of sale, a copy of which is

Product Name:

ORICA ECLIPSE GRANULATED CHLORINE FOR SWIMMING POOLS

Substance No:

000031064512

Issued:

12/11/2008

Version:

4

Page 7 of 8

Material Safety Data Sheet

available upon request.

Product Name:

ORICA ECLIPSE GRANULATED CHLORINE FOR SWIMMING POOLS

Substance No:

000031064512

Issued:

12/11/2008

Version:

4

Page 8 of 8

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