NUFARM INVADER 600 HERBICIDE

Australia - English - APVMA (Australian Pesticides and Veterinary Medicines Authority)

Active ingredient:
triclopyr as butotyl(600g/L)
Available from:
NUFARM
INN (International Name):
triclopyr as butotyl(600g/L)
Pharmaceutical form:
Emulsifiable
Units in package:
1L, 5L, 10L, 20L, 110L, 200L, 1000L
Class:
AgChem
Therapeutic group:
AGRICULTURAL NON-CROP AREAS | COMMERCIAL/INDUSTRIAL LAND | FALLOW CROP LAND WEED CONTROL | FENCELINE WEED CONTROL | FIRE TRAIL |
Therapeutic area:
Group I Herbicide
Therapeutic indications:
ACACIA OR WATTLE SEEDLING | AFRICAN BOXTHORN | ANGOPHORA - REGROWTH | AUSTRALIAN OR NATIVE BLACKTHORN | BANKSIA - REGROWTH | BITTER BARK OR QUININE TREE | BLACK OR BRISBANE BLACK WATTLE | BLACKBERRY | BRIGALOW | BROADLEAF HOPBUSH | BROOMS | BROWN SALWOOD OR HICKORY WATTLE | BUDDA OR FALSE SANDALWOOD | CAMEL OR AFGHAN MELON | CAMPHOR LAUREL | CAPEWEED | CHILEAN CESTRUM | CHINEE APPLE | COMMON PRICKLY PEAR | DAWSON GUM | ENGLISH BROOM | ENGLISH IVY | EUCALYPTUS | EUCALYPTUS - SEE LABEL FOR EXCEPTIONS | EUCALYPTUS - SEEDLING UP TO 2 M TALL | FENNEL | FURZE OR GORSE | GREEN OR EARLY BLACK WATTLE | GROUNDSEL BUSH | HOREHOUND | LANTANA - LANTANA CAMARA | NARROW LEAF HOP BUSH | NEEDLEWOOD | OLIVE - OLEA EUROPAEA | PADDY MELON | PAPERBARK | PRICKLY ACACIA | PRIVET | RUBBER VINE | SAFFRON THISTLE | SILVER WATTLE | SMOOTH TREE OR DROOPING PRICKLY PEAR | ST JOHN'S WORT | SWEET BRIAR OR WILD ROSE | THORNAPPLE | TIGER PEAR | TREE-OF-HEAVEN | TURPENTINE BUSH | YELLOW WOOD | AFGHAN MELON | BITTER MELON | BLACKBERRY WITH ST
Product summary:
For the control of various woody and broadleaf weeds.See RESTRAINTS on label
Authorization status:
Registered and available
Authorization number:
49998/51463
Authorization date:
2010-11-08

Info

pest

Verified

CS: 1.7.2

Page:

Safety Data Sheet

Infosafe No™ 3NU4U

August 2016

ISSUED by NUFARM

Issue Date :

INVADER 600 Herbicide

Product Name :

Classified as hazardous

1. Identification

INVADER 600 Herbicide

GHS Product

Identifier

0521

Product Code

Group I Herbicide

Product Type

NUFARM AUSTRALIA LIMITED. (ABN 80 004 377 780)

Company Name

103-105 Pipe Road Laverton North

Victoria 3026 Australia

Address

Tel: +61 3 9282-1000

Fax: +61 3 9282-1001

Telephone/Fax

Number

1800 033 498 (24hr Australia)

Emergency phone

number

For the control of various woody and broadleaf weeds as specified in the

Directions for Use table on the label.

Recommended use of

the chemical and

restrictions on use

This Safety Data Sheet describes the properties of the concentrated product.

The physical properties and the assessments may not apply to the properties of

the product once it has been diluted for application.

Other Information

2. Hazard Identification

OT4 Acute Toxicity - Oral: Category 4

SS-1 Sensitization - Skin: Category 1

ED2A Eye Damage/Irritation: Category 2A

AA1 Hazardous to the Aquatic Environment - Acute Hazard: Category 1

GHS classification of

substance/mixture

WARNING

Signal Word (s)

H302 Harmful if swallowed.

H317 May cause an allergic skin reaction.

H319 Causes serious eye irritation.

H400 Very toxic to aquatic life.

Hazard Statement (s)

P101 If medical advice is needed, have product container or label at hand.

P102 Keep out of reach of children.

P103 Read label before use.

General

Precautionary

Statement (s)

Exclamation mark, Environment,

The below pictograms are GHS Hazard symbols for workplace use only.

See SECTION 14 for Dangerous Goods information.

Pictogram (s)

P264 Wash hands and exposed skin thoroughly after handling.

P270 Do not eat, drink or smoke when using this product.

P280 Wear protective gloves, clothing, eye and face protection.

Precautionary

statement –

Prevention

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P330 Rinse mouth.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes.

Remove contact lenses, if present and easy to do. Continue rinsing.

P337+P313 If eye irritation persists: Get medical advice/attention.

Precautionary

statement – Response

Poisons Schedule S6

Other Information

3. Composition/information on ingredients

Liquid

Chemical

Characterization

Name

Proportion

Ingredients

Triclopyr (present as

the butoxyethyl ester)

64700-56-7

600 g/L

Other non-hazardous

ingredients

Balance

Print Date: 19/08/2016

CS: 1.7.2

CS: 1.7.2

Page:

Safety Data Sheet

Infosafe No™ 3NU4U

August 2016

ISSUED by NUFARM

Issue Date :

INVADER 600 Herbicide

Product Name :

Classified as hazardous

Name

Proportion

Ingredients

Butyl diglycol

112-34-5

10-30 %

4. First-aid measures

Remove affected person to fresh air until recovered. If symptoms develop or

persist, seek medical advice.

Inhalation

If swallowed do NOT induce vomiting; seek medical advice immediately and show

this container or label or contact the Poisons Information Centre on 13 11 26

(Aust). Make every effort to prevent vomit from entering the lungs by careful

placement of the patient.

Ingestion

Remove contaminated clothing and launder before re-use.

Wash affected areas thoroughly with soap and water.

Seek medical advice, but only after the exposed skin has been thoroughly

washed.

Skin

If in eyes, hold eyelids open and wash with copious amounts of water for at

least 15 minutes.

Seek medical advice.

Eye contact

If poisoning occurs, contact a doctor or the Poisons Information Centre

(Australia) on 13 11 26.

First Aid Facilities

Treat symptomatically.

Advice to Doctor

5. Fire-fighting measures

Water fog, foam, carbon dioxide or dry chemical.

Suitable

extinguishing media

If involved in a fire, it will emit oxides of carbon, oxides of nitrogen,

hydrogen chloride and possibly phosgene.

Hazards from

Combustion

Products

Breathable air apparatus may have to be worn if material is involved in fires

especially in confined spaces.

Special Protective

Equipment for fire

fighters

Specific hazards

arising from the

chemical

STOP FIRE WATER FROM ENTERING DRAINS OR WATER BODIES.

Other Information

6. Accidental release measures

Contain spill and absorb with clay, sand, soil or proprietary absorbent (such

as vermiculite).

Collect spilled material and waste in sealable open-top type containers for

disposal.

Spills & Disposal

For appropriate personal protective equipment (PPE), refer Section 8.

Personal Protection

7. Handling and storage

Do NOT contaminate dams, rivers or streams, or any other water bodies with

chemical or used containers.

Precautions for Safe

Handling

Store in the closed, original container in a dry, cool well ventilated area

out of direct sunlight.

Keep container tightly sealed and do not store with seed, fertilisers or

foodstuffs.

Conditions for safe

storage, including

any incompatabilities

See label for detailed information on cleaning of spray equipment.

Tank Cleaning

Always read the label and any attached leaflet before use.

Other Information

8. Exposure controls/personal protection

EU. exposure standards for triclopyr are TWA 67.5mg/m3, STEL 101.2 mg/m3.

Other Exposure

Information

Handle in well ventilated areas, generally natural ventilation is adequate.

Appropriate

engineering controls

It is good practice to wear suitable personal protective equipment (PPE).

When opening the container, preparing spray and using the prepared spray

Personal Protective

Equipment

Print Date: 19/08/2016

CS: 1.7.2

CS: 1.7.2

Page:

Safety Data Sheet

Infosafe No™ 3NU4U

August 2016

ISSUED by NUFARM

Issue Date :

INVADER 600 Herbicide

Product Name :

Classified as hazardous

wear cotton overalls buttoned to the neck and wrist and a washable hat,

elbow-length PVC gloves and face shield or goggles.

After use and before eating, drinking or smoking, wash hands, arms and face

thoroughly with soap and water.

After each day's use, wash contaminated clothing and safety equipment.

Hygiene Measures

Check State or Territory regulations that require people who use pesticides in

their job or business to have training in the application of the materials.

Requirements

Concerning Special

Training

9. Physical and chemical properties

Liquid

Form

Amber liquid

Appearance

Disperses in water.

Solubility in Water

1.21

Specific Gravity

4-6 (1% in water)

0.48 mPa (triclopyr butoxyethyl ester)

Vapour Pressure

95°C

Flash Point

Combustible liquid C1. (AS1940).

Flammability

10. Stability and reactivity

Stable under normal conditions.

Chemical Stability

Hazardous polymerisation is not possible.

Hazardous

Polymerization

11. Toxicological Information

No harmful effects are expected if the precautions on the label and this MSDS

are followed.

Toxicology

Information

LD50 (rat) 803 mg/kg for triclopyr butoxyethyl ester

Acute Toxicity - Oral

LD50 (rabbit) >2000 mg/kg for triclopyr butoxyethyl ester

Acute Toxicity -

Dermal

LC50 (rat) (4hr) >4.8 mg/l for triclopyr butoxyethyl ester

Acute Toxicity -

Inhalation

Ingestion of the concentrate in relatively large amounts can result in

headache, nausea, lethargy, motor weakness and incoordination.

Ingestion

High vapour concentrations of the solvent while handling the concentrate are

irritating to the eyes and the respiratory tract.

Inhalation

May irritate the skin.

May cause sensitisation by prolonged skin contact.

Skin

Will irritate the eyes.

Prolonged and repeated skin contact may result in skin sensitisation.

Skin Sensitisation

Triclopyr has been assessed in animals and some data exists that triclopyr is

a substance which causes some concern for humans owing to possible

carcinogenic effects from long term exposure, but in respect of which the

available information is not adequate for making a satisfactory assessment.

Carcinogenicity

Based on available data, repeated exposures are not anticipated to cause

additional significant adverse effects.

Chronic Effects

Moderate eye irritant.

Serious eye

damage/irritation

Data indicates no mutagenic effects.

Mutagenicity

Mild to moderate skin irritant.

Skin

corrosion/irritation

The Australian Acceptable Daily Intake (ADI) for triclopyr for a human is

0.005 mg/kg/day, set for the public for daily, lifetime exposure. This is

based on the NOEL of 0.5 mg/kg/day, the level determined to show no effects

during long term exposure for the most sensitive indicators and the most

sensitive species. (Ref: Comm. Dept. of Health and Ageing, Office of Chemical

Other Information

Print Date: 19/08/2016

CS: 1.7.2

CS: 1.7.2

Page:

Safety Data Sheet

Infosafe No™ 3NU4U

August 2016

ISSUED by NUFARM

Issue Date :

INVADER 600 Herbicide

Product Name :

Classified as hazardous

Safety, 'ADI List', December 2015).

12. Ecological information

Triclopyr butoxyethyl ester is rapidly hydrolysed to triclopyr acid in soil

and water. Triclopyr acid is degraded by microbial action and photodecomp-

osition. Triclopyr acid, in soil, has a half-life of approximately forty

days, depending on soil and climatic conditions. In water, triclopyr acid

will decompose rapidly with a half-life of one to two days. Minimal leaching

of triclopyr acid may occur in light soils under high rainfall conditions.

Contamination of ground water by triclopyr is highly unlikely.

If used according to the label, Invader 600 will not be harmful to the

environment.

Persistence and

degradability

Do not contaminate dams, waterways or sewers with this product or the

containers which have held this product.

Other Precautions

Spray drift can cause damage, read the label for more information.

Marine pollutant.

Environmental

Protection

The following is data for the active ingredient, triclopyr as the butoxyethyl

ester.

LC50 (96hr) for the most sensitive species tested is 0.31 mg/l.

Acute Toxicity - Fish

LC50 (48hr) for daphnia is 0.66 mg/l for triclopyr butoxyethyl ester.

Acute Toxicity -

Daphnia

EC50 (48hr) for algae is 0.193 mg/l.

Acute Toxicity -

Algae

Bees: Not toxic to bees. LD50 >100 µg/bee.

LD50 for bobwhite quail is 735 mg/kg for triclopyr butoxyethyl ester

Acute Toxicity -

Other Organisms

13. Disposal considerations

DO NOT dispose of undiluted chemicals on site. Ideally, the product should be

used for its intended purpose. If there is a need to dispose of the product,

approach local authorities who hold periodic collections of unwanted chemicals

(ChemClear®).

Product Disposal

Do not use this container for any other purpose.

Triple or preferably pressure rinse inner bladder or containers before

disposal. Add rinsings to the spray tank. If recycling, replace cap and

return clean containers to recycler or designated collection point.

If not recycling, break, crush or puncture and deliver empty packaging for

appropriate disposal at an approved waste management facility.

If an approved waste management facility is not available, bury the empty

packaging 500mm below the surface in a disposal pit specifically marked and

set up for this purpose clear of waterways, desirable vegetation and tree

roots, in compliance with relevant local, state or territory government

regulations.

drumMUSTER is the national program for the collection and recycling of

empty, cleaned, non returnable crop production and on-farm animal health

chemical containers. If the label on your container carries the drumMUSTER

symbol, triple rinse the container, ring your local Council, and offer the

container for collection in the program.

Returnable containers: empty contents fully into application equipment.

Replace cap, close all valves and return to the point of supply for refill or

storage.

DO NOT burn empty containers or product.

Container Disposal

14. Transport information

It is good practice not to transport agricultural chemical products with

food, food related materials and animal feedstuffs.

Transport

Information

Considered non dangerous for road and rail transport (in packaging, including

IBCs not greater than 3000 Lt each) by the Australian Code for the Transport

of Dangerous Goods by Road and Rail. Ref: ADG7; SP No. AU01.

For bulk shipments as Class 9, use UN 3082, HazChem code 2Z.

Storage and

Transport

UN 3082

UN Number (Sea

Transport)

Print Date: 19/08/2016

CS: 1.7.2

CS: 1.7.2

Page:

Safety Data Sheet

Infosafe No™ 3NU4U

August 2016

ISSUED by NUFARM

Issue Date :

INVADER 600 Herbicide

Product Name :

Classified as hazardous

Class 9; Packing Group III

IMO Class/Packing

Group

Marine Pollutant

IMO Marine

Pollutant

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.

(contains Triclopyr butoxyethyl ester)

IMO Proper

Shipping Name

15. Regulatory information

Australia: WHS regulations (2011) - Schedule 11: classification not listed.

Regulatory

Information

Poisons Schedule

POISON

KEEP OUT OF REACH OF CHILDREN

READ SAFETY DIRECTIONS BEFORE OPENING OR USING

Packaging &

Labelling

This product is registered with the Australian Pesticides and Veterinary

Medicines Authority (APVMA). APVMA product number: 49998.

Other Information

16. Other Information

Revised 19/08/2016

This SDS replaces document dated February 2012.

Date of preparation

or last revision of

EFSA Scientific Report (2005) 56, 1-103 conclusion on the peer review of

triclopyr

Literature

References

Normal Hours: Mrs Kathleen Marsh Phone: +61 3 9282 1000

After Hours: Shift Supervisor Phone: 1800 033 498

Contact Person/Point

The SDS was reviewed to include GHS requirements.

Revisions

Highlighted

...End Of MSDS...

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Print Date: 19/08/2016

CS: 1.7.2

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