NUFARM ELECT 500 FLOWABLE FUNGICIDE

Australia - English - APVMA (Australian Pesticides and Veterinary Medicines Authority)

Active ingredient:
CHLOROTHALONIL
Available from:
NUFARM AUSTRALIA LIMITED
INN (International Name):
chlorothalonil(500g/L)
Pharmaceutical form:
LIQUID
Composition:
CHLOROTHALONIL BENZENE Active 500.0 g/L
Units in package:
1000L; 10L; 200L; 20L; 5L
Class:
A - Agricultural
Therapeutic group:
ALMOND | APRICOT | BANANA | BOWLING GREEN | BROCCOLI | BRUSSELS SPROUTS | BULBOUS IRIS | CABBAGE | CAPSICUM OR PEPPER | CARROT |
Therapeutic area:
FUNGICIDE
Therapeutic indications:
ALTERNARIA LEAF BLIGHT OR SPOT BLIGHT | ALTERNARIA LEAF SPOT - A. CUCUMERINA | ANTHRACNOSE ON CUCURBIT | ANTHRACNOSE ON VINES/RUBUS SPP. | ASCOCHYTA LEAF SPOT - ASCOCHYTA SPP. | BLACK SPOT - COLLETOTRICHUM ACUTATUM | BLOSSOM BLIGHT - MONILINIA LAXA | BOTRYTIS | BROWN PATCH | BROWN ROT | BROWN ROT - MONILINIA SPP. | CERSOSPORA LEAF BLIGHT OR SPOT | CHOCOLATE SPOT ON BEAN | DOLLAR SPOT | DOWNY MILDEW | DOWNY MILDEW ON ALLIUM (ONION, GARLIC) | DOWNY MILDEW ON CUCURBIT | DOWNY MILDEW ON GRAPE | EARLY BLIGHT ON CELERY | EARLY BLIGHT OR TARGET BLACKSPOT | FRECKLE OR SCAB ON STONE FRUIT | FRUIT OR BELLY RHIZOCTONIA ROT | GREY LEAF SPOT - STEMPHYLIUM SOLANI | GREY MOULD - BOTRYTIS CINEREA | GREY MOULD/BUNCH ROT OF VINE | GUMMY STEM BLIGHT OR SPUR BLIGHT | LATE LEAF SPOT ON PEANUT | LATE OR IRISH BLIGHT ON TOMATO OR POTATO | LEAF BLIGHT | LEAF CURL | LEAF SPECKLE ON BANANA | LEAF SPOT | LEAF SPOT OR YELLOW SIGATOKA ON BANANA | NET BLOTCH | PEPPERY LEAF SPOT | PURPLE BLOTCH | RING SPOT ON BRASSICA/COLE CROP | RUST | RU
Product summary:
Poison schedule: 6; Withholding period: ; Host/pest details: ALMOND: [SHOT HOLE, STONE FRUIT RUST]; APRICOT: [BLOSSOM BLIGHT - MONILINIA LAXA, BROWN ROT, FRECKLE OR SCAB ON STONE FRUIT, SHOT HOLE, STEM END ROTS, STONE FRUIT RUST]; BANANA: [LEAF SPECKLE ON BANANA, LEAF SPOT OR YELLOW SIGATOKA ON BANANA]; BOWLING GREEN: [BROWN PATCH, DOLLAR SPOT, GREY LEAF SPOT - STEMPHYLIUM SOLANI]; BROCCOLI: [RING SPOT ON BRASSICA/COLE CROP]; BRUSSELS SPROUTS: [RING SPOT ON BRASSICA/COLE CROP]; BULBOUS IRIS: [ALTERNARIA LEAF BLIGHT OR SPOT BLIGHT, BOTRYTIS, GREY MOULD - BOTRYTIS CINEREA, RUST, SEPTORIA LEAF SPOT - SEPTORIA SPP.]; CABBAGE: [RING SPOT ON BRASSICA/COLE CROP]; CAPSICUM OR PEPPER: [BLACK SPOT - COLLETOTRICHUM ACUTATUM, GREY MOULD - BOTRYTIS CINEREA]; CARROT: [LEAF BLIGHT]; CAULIFLOWER: [RING SPOT ON BRASSICA/COLE CROP]; CELERY: [EARLY BLIGHT ON CELERY, SEPTORIA LEAF SPOT - SEPTORIA SPP.]; CHERRY: [BROWN ROT, BROWN ROT - MONILINIA SPP., SHOT HOLE, STEM END ROTS, STONE FRUIT RUST]; CHRYSANTHEMUM OR TANACETUM: [ALTERNARIA LEAF BLIGHT OR SPOT BLIGHT, BOTRYTIS, GREY MOULD - BOTRYTIS CINEREA, RUST, SEPTORIA LEAF SPOT - SEPTORIA SPP.]; CUCUMBER: [ALTERNARIA LEAF SPOT - A. CUCUMERINA, ANTHRACNOSE ON CUCURBIT, DOWNY MILDEW ON CUCURBIT, FRUIT OR BELLY RHIZOCTONIA ROT, GUMMY STEM BLIGHT OR SPUR BLIGHT, TARGET LEAF SPOT]; CUCURBIT: [ALTERNARIA LEAF SPOT - A. CUCUMERINA, ANTHRACNOSE ON CUCURBIT, DOWNY MILDEW ON CUCURBIT, FRUIT OR BELLY RHIZOCTONIA ROT, GUMMY STEM BLIGHT OR SPUR BLIGHT, TARGET LEAF SPOT]; ENDIVE: [GREY MOULD - BOTRYTIS CINEREA]; FABA BEAN: [CHOCOLATE SPOT ON BEAN, RUST]; GERANIUM: [ALTERNARIA LEAF BLIGHT OR SPOT BLIGHT, BOTRYTIS, GREY MOULD - BOTRYTIS CINEREA, RUST, SEPTORIA LEAF SPOT - SEPTORIA SPP.]; GLOBE ARTICHOKE: [GREY MOULD - BOTRYTIS CINEREA]; GOLF GREEN TURF: [BROWN PATCH, DOLLAR SPOT, GREY LEAF SPOT - STEMPHYLIUM SOLANI]; GRAPE: [ANTHRACNOSE ON VINES/RUBUS SPP., DOWNY MILDEW ON GRAPE, GREY MOULD/BUNCH ROT OF VINE]; HONEY-DEW MELON: [ALTERNARIA LEAF SPOT - A. CUCUMERINA, ANTHRACNOSE ON CUCURBIT, DOWNY MILDEW ON CUCURBIT, FRUIT OR BELLY RHIZOCTONIA ROT, GUMMY STEM BLIGHT OR SPUR BLIGHT, TARGET LEAF SPOT]; LEEK: [PURPLE BLOTCH]; NECTARINE: [BROWN ROT - MONILINIA SPP., SHOT HOLE]; OKRA: [LEAF SPOT]; ONION: [DOWNY MILDEW ON ALLIUM (ONION, GARLIC)]; ORNAMENTAL: [ALTERNARIA LEAF BLIGHT OR SPOT BLIGHT, BOTRYTIS, GREY MOULD - BOTRYTIS CINEREA, RUST, SEPTORIA LEAF SPOT - SEPTORIA SPP.]; PEA: [DOWNY MILDEW]; PEACH: [BROWN ROT, BROWN ROT - MONILINIA SPP., LEAF CURL, SHOT HOLE, STONE FRUIT RUST]; PEANUT: [LATE LEAF SPOT ON PEANUT, LEAF SPOT, NET BLOTCH, PEPPERY LEAF SPOT, RUST ON PEANUT]; PLUM: [BROWN ROT, BROWN ROT - MONILINIA SPP., SHOT HOLE, STONE FRUIT RUST]; POTATO: [EARLY BLIGHT OR TARGET BLACKSPOT, LATE OR IRISH BLIGHT ON TOMATO OR POTATO]; PUMPKIN: [ALTERNARIA LEAF SPOT - A. CUCUMERINA, ANTHRACNOSE ON CUCURBIT, DOWNY MILDEW ON CUCURBIT, FRUIT OR BELLY RHIZOCTONIA ROT, GUMMY STEM BLIGHT OR SPUR BLIGHT, TARGET LEAF SPOT]; RADISH: [GREY MOULD - BOTRYTIS CINEREA]; RHUBARB: [ASCOCHYTA LEAF SPOT - ASCOCHYTA SPP.]; ROCKMELON OR CANTALOUP: [ALTERNARIA LEAF SPOT - A. CUCUMERINA, ANTHRACNOSE ON CUCURBIT, DOWNY MILDEW ON CUCURBIT, FRUIT OR BELLY RHIZOCTONIA ROT, GUMMY STEM BLIGHT OR SPUR BLIGHT, TARGET LEAF SPOT]; SQUASH: [ALTERNARIA LEAF SPOT - A. CUCUMERINA, ANTHRACNOSE ON CUCURBIT, DOWNY MILDEW ON CUCURBIT, FRUIT OR BELLY RHIZOCTONIA ROT, GUMMY STEM BLIGHT OR SPUR BLIGHT, TARGET LEAF SPOT]; SWEET CORN: [TURCICUM LEAF BLIGHT]; TOBACCO: [TOBACCO LEAF SPOT]; TOMATO: [BOTRYTIS, EARLY BLIGHT OR TARGET BLACKSPOT, GREY LEAF SPOT - STEMPHYLIUM SOLANI, GREY MOULD - BOTRYTIS CINEREA]; WATERCRESS OR NASTURTIUM: [CERSOSPORA LEAF BLIGHT OR SPOT]; WATERMELON: [ALTERNARIA LEAF SPOT - A. CUCUMERINA, ANTHRACNOSE ON CUCURBIT, DOWNY MILDEW ON CUCURBIT, FRUIT OR BELLY RHIZOCTONIA ROT, GUMMY STEM BLIGHT OR SPUR BLIGHT, TARGET LEAF SPOT]; ZUCCHINI: [ALTERNARIA LEAF SPOT - A. CUCUMERINA, ANTHRACNOSE ON CUCURBIT, DOWNY MILDEW ON CUCURBIT, FRUIT OR BELLY RHIZOCTONIA ROT, GUMMY STEM BLIGHT OR SPUR BLIGHT, TARGET LEAF SPOT]; For the control of fungus disease on almonds, apricots, artichokes, bananas, capsicums, carrots, celery, cherries, cole crops, cucurbits, endive, faba beans, grapes, leeks, nectarines, okra, onions, ornamentals, peaches, peanuts, peas, plums, potatoes, ra
Authorization status:
Stopped
Authorization number:
50052
Authorization date:
2018-06-30

Info

pest

Verified

CS: 1.7.2

Page:

Safety Data Sheet

Infosafe No™ 3NU11

June 2016

ISSUED by NUFARM

Issue Date :

ELECT 500 Flowable Fungicide

Product Name :

Classified as hazardous

1. Identification

ELECT 500 Flowable Fungicide

GHS Product

Identifier

5780

Product Code

Group M5 Fungicide

Product Type

NUFARM AUSTRALIA LIMITED. (ABN 80 004 377 780)

Company Name

103-105 Pipe Road Laverton North

Victoria 3026 Australia

Address

Tel: +61 3 9282-1000

Fax: +61 3 9282-1001

Telephone/Fax

Number

1800 033 498 (24hr Australia)

Emergency phone

number

For the control of fungus disease on almonds, apricots, artichokes, bananas,

capsicums, carrots, celery, cherries, cole crops, cucurbits, endive, faba

beans, grapes, leeks, nectarines, okra, onions, ornamentals, peaches, peanuts,

peas, plums, potatoes, radish, rhubarb, sweetcorn, tobacco, tomatoes, turf and

watercress as specified in the Directions for Use table on the label.

Recommended use of

the chemical and

restrictions on use

This Safety Data Sheet describes the properties of the concentrated product.

The physical properties and the assessments may not apply to the properties of

the product once it has been diluted for application.

Other Information

2. Hazard Identification

CA2 Carcinogenicity: Category 2

SE-3RES STOT Single Exposure Category 3 (respiratory tract irritation)

IT 2 Acute Toxicity - Inhalation: Category 2

SS-1 Sensitization - Skin: Category 1

ED1 Eye Damage/Irritation: Category 1

GHS classification of

substance/mixture

DANGER

Signal Word (s)

H351 Suspected of causing cancer.

H335 May cause respiratory irritation.

H330 Fatal if inhaled.

H318 Causes serious eye damage.

H317 May cause an allergic skin reaction.

Hazard Statement (s)

P101 If medical advice is needed, have product container or label at hand.

P102 Keep out of reach of children.

P103 Read label before use.

General

Precautionary

Statement (s)

Corrosion, Exclamation mark, Health hazard, Skull and crossbones,

The below pictograms are GHS Hazard symbols for workplace use only.

See SECTION 14 for Dangerous Goods information.

Pictogram (s)

P202 Do not handle until all safety precautions have been read and understood.

P271 Use only outdoors or in a well-ventilated area.

P260 Do not breathe mists and spray.

P284 Wear respiratory protection.

P280 Wear protective gloves, clothing, eye and face protection.

P272 Contaminated work clothing should not be allowed out of the workplace.

Precautionary

statement –

Prevention

P308+P313 IF exposed or concerned: Get medical advice/attention.

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a

position comfortable for breathing.

P310 Immediately call a POISON CENTER or doctor/physician.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes.

Remove contact lenses, if present and easy to do. Continue rinsing.

P310 Immediately call a POISON CENTER or doctor/physician.

P302+P352 IF ON SKIN: Wash with plenty of soap and water.

P332+P313 If skin irritation occurs: Get medical advice/attention.

P363 Wash contaminated clothing before reuse.

Precautionary

statement – Response

Print Date: 30/06/2016

CS: 1.7.2

CS: 1.7.2

Page:

Safety Data Sheet

Infosafe No™ 3NU11

June 2016

ISSUED by NUFARM

Issue Date :

ELECT 500 Flowable Fungicide

Product Name :

Classified as hazardous

Poisons Schedule S6

Other Information

3. Composition/information on ingredients

Liquid

Chemical

Characterization

Name

Proportion

Ingredients

Chlorothalonil

1897-45-6

500 g/L

Other ingredients

(considered

non-hazardous)

Balance

4. First-aid measures

Remove affected person to fresh air until recovered. If symptoms persist,

seek medical attention immediately.

Inhalation

Rinse mouth and then drink plenty of water.

Do not give anything by mouth to a semi-conscious or unconscious person.

If vomiting occurs, give more water to drink to assist dilution.

Ingestion

Wash affected areas thoroughly with soap and water.

Remove contaminated clothing and launder before re-use.

If irritation persists, seek medical advice.

Skin

If in eyes, hold eyelids open and wash with copious amounts of water for at

least 15 minutes.

Seek medical advice immediately.

Eye contact

If poisoning occurs, contact a doctor or the Poisons Information Centre

(Australia) on 13 11 26.

First Aid Facilities

Treat symptomatically.

Persons having allergic reactions respond to treatment with antihistamines

or steroid creams and/or systemic steroids.

Advice to Doctor

5. Fire-fighting measures

Water fog, foam, carbon dioxide or dry chemical.

Suitable

extinguishing media

May emit toxic fumes of hydrogen chloride or phosgene if involved in fires or

exposed to extreme heat.

Hazards from

Combustion

Products

Breathable air apparatus must be worn when fighting a fire in which this

product is involved.

Special Protective

Equipment for fire

fighters

Considered low risk due to water content, however upon evaporation of water

the product is combustible.

Specific hazards

arising from the

chemical

STOP FIRE WATER FROM ENTERING DRAINS OR WATER BODIES.

Other Information

6. Accidental release measures

Contain spill and absorb with clay, sand, soil or proprietary absorbent (such

as vermiculite).

Collect spilled material and waste in sealable open-top type containers for

disposal.

Dispose of at a landfill in accordance with local regulations.

Spills & Disposal

For appropriate personal protective equipment (PPE), refer Section 8.

If product has dried out and the possibility of dust generation exists, wear

a suitable respirator.

Personal Protection

Place damaged containers in recovery bins (if available) and return to

manufacturer.

If large liquid spills occur, attempt to recover as much spilt material from

sumps and bunded areas, as possible, before absorbing remaining material into

vermiculite or other absorbent.

Clean-up Methods -

Large Spillages

Prevent from entering drains, waterways or sewers.

Environmental

Precautions

7. Handling and storage

Print Date: 30/06/2016

CS: 1.7.2

CS: 1.7.2

Page:

Safety Data Sheet

Infosafe No™ 3NU11

June 2016

ISSUED by NUFARM

Issue Date :

ELECT 500 Flowable Fungicide

Product Name :

Classified as hazardous

Do NOT contaminate dams, rivers or streams, or any other water bodies with

pesticide or used containers.

Precautions for Safe

Handling

Store in the closed, original container in a cool, well ventilated area.

Do not store for prolonged periods in direct sunlight.

Keep container tightly sealed and do not store with seed, fertilisers or

foodstuffs.

Store in a locked enclosure.

Conditions for safe

storage, including

any incompatabilities

Always read the label and any attached leaflet before use.

Other Information

8. Exposure controls/personal protection

No exposure standards have been set for this product or the active

ingredients.

Occupational

exposure limit values

Use in a well ventilated area only.

Appropriate

engineering controls

Do not inhale spray mist.

Respiratory

Protection

When opening the container, preparing spray and using the prepared spray wear

cotton overalls buttoned to the neck and wrist and a washable hat,

elbow-length PVC gloves and goggles and disposable mist mask.

Personal Protective

Equipment

After use and before eating, drinking or smoking, wash hands, arms and face

thoroughly with soap and water.

After each day's use, wash contaminated clothing and safety equipment.

Hygiene Measures

Check State or Territory regulations that require people who use pesticides in

their job or business to have training in the application of the materials.

Requirements

Concerning Special

Training

9. Physical and chemical properties

Liquid

Form

White opaque liquid

Appearance

Disperses in water.

Solubility in Water

1.230

Specific Gravity

7 - 8.5

0.076 mPa @ 25°C for chlorothalonil

Vapour Pressure

~50%

Volatile Component

Kow Log P is 2.92 (25°C, chlorothalonil)

Partition Coefficient:

n-octanol/water

Non combustible material.

Flammability

10. Stability and reactivity

Stable under normal conditions.

Chemical Stability

Keep away from strong oxidising agents.

Possibility of

hazardous reactions

Hazardous polymerisation is not possible.

Hazardous

Polymerization

11. Toxicological Information

LD50 (rat) >5000 mg/kg for chlorothalonil

Acute Toxicity - Oral

LD50 (rat) >5000 mg/kg for chlorothalonil

Acute Toxicity -

Dermal

LC50 (rat) (4hr) 0.1 mg/l for chlorothalonil

Acute Toxicity -

Inhalation

May cause irritation to mouth, throat and stomach.

Possible symptoms of exposure include: nausea, vomiting and central nervous

system depression.

Ingestion

Not a likely route of exposure when handling the concentrate.

However, care should be taken to avoid the inhalation of excessive amounts

Inhalation

Print Date: 30/06/2016

CS: 1.7.2

CS: 1.7.2

Page:

Safety Data Sheet

Infosafe No™ 3NU11

June 2016

ISSUED by NUFARM

Issue Date :

ELECT 500 Flowable Fungicide

Product Name :

Classified as hazardous

of spray mist during field spraying, respiratory irritation may occur.

May irritate the skin.

Prolonged or repeated exposure may cause skin sensitisation.

Skin

The concentrate will cause severe irritation and possible damage unless washed

off immediately.

Chlorothalonil is a skin sensitiser.

Skin Sensitisation

Classified as a carcinogen based on limited evidence from studies with

experimental animals.

Carcinogenicity

Data indicates no teratogenic effects.

Reproductive

Toxicity

Liver and kidney damage has been noted in laboratory animals that have been

fed excessive doses of chlorothalonil.

Reports of human experience in use of chlorothalonil products demonstrate

that some individuals become sensitive to contact with this compound.

Chronic Effects

The product is an eye irritant.

Serious eye

damage/irritation

The product is a respiratory irritant.

Respiratory

Irritation

Mild skin irritant.

Skin

corrosion/irritation

The Australian Acceptable Daily Intake (ADI) for chlorothalonil for a human is

0.01 mg/kg/day, set for the public for daily, lifetime exposure. This is based

on the NOEL of 1.5 mg/kg/day, the level determined to show no effects during

long term exposure for the most sensitive indicators and the most sensitive

species. (Ref: Comm. Dept. of Health and Ageing, Office of Chemical Safety,

'ADI List', December 2015).

Other Information

12. Ecological information

Average field half life of chlorothalonil is 7 - 30 days.

Adsorption studies indicate that chlorothalonil has very low mobility.

In water, half life for chlorothalonil is 4.5 hours to 9 days.

Persistence and

degradability

Highly toxic to fish and aquatic organisms.

Known Harmful

Effects on the

Environment

Marine pollutant.

Environmental

Protection

The following is data for the active ingredient, chlorothalonil.

LC50 (96hr) for rainbow trout is 0.043 mg/l.

LC50 (96hr) for bluegill sunfish is 0.059 mg/l.

Acute Toxicity - Fish

LC50 (48hr) for daphnia magna is 70 µg/l

Acute Toxicity -

Daphnia

EC50 (120hr) for Selenastrum capricornutum is 210 µg/l.

Acute Toxicity -

Algae

The following data is for the active ingredient, chlorothalonil.

Not toxic to bees.

Birds: Toxic to birds. LD50 for mallard ducks is >4,640 mg/kg

Acute Toxicity -

Other Organisms

13. Disposal considerations

On site disposal of the concentrated product is not acceptable.

Ideally, the product should be used for its intended purpose. If there is a

need to dispose of the product, approach local authorities who hold periodic

collections of unwanted chemicals (ChemClear®).

Product Disposal

Do not use this container for any other purpose.

Triple or preferably pressure rinse containers before disposal. Add

rinsings to the spray tank.

If recycling, replace cap and return clean containers to recycler or

designated collection point.

If not recycling, puncture or shred and bury containers in local authority

landfill.

If no landfill is available, bury the containers below 500mm in a disposal

pit specifically marked and set up for this purpose clear of waterways,

desirable vegetation and tree roots.

drumMUSTER is the national program for the collection and recycling of

Container Disposal

Print Date: 30/06/2016

CS: 1.7.2

CS: 1.7.2

Page:

Safety Data Sheet

Infosafe No™ 3NU11

June 2016

ISSUED by NUFARM

Issue Date :

ELECT 500 Flowable Fungicide

Product Name :

Classified as hazardous

empty, cleaned, non returnable crop production and on-farm animal health

chemical containers. If the label on your container carries the drumMUSTER

symbol, triple rinse the container, ring your local Council, and offer the

container for collection in the program.

Empty containers and product should not be burnt.

14. Transport information

Considered non dangerous for road and rail transport (in packaging, including

IBCs not greater than 3000 Lt each) by the Australian Code for the Transport

of Dangerous Goods by Road and Rail. Ref: ADG7; SP No. AU01.

For bulk shipments as Class 9, use UN 3082, HazChem code 2Z.

Storage and

Transport

3082

UN Number (Sea

Transport)

Class 9; Packing Group III

IMO Class/Packing

Group

Marine Pollutant

IMO Marine

Pollutant

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.

(contains Chlorothalonil)

IMO Proper

Shipping Name

15. Regulatory information

WHS Schedule 11, item 34: Acute toxicity category 2 (inihilation).

Regulatory

Information

Poisons Schedule

POISON

KEEP OUT OF REACH OF CHILDREN

READ SAFETY DIRECTIONS BEFORE OPENING OR USING

Packaging &

Labelling

This product is registered with the Australian Pesticides and Veterinary

Medicines Authority (APVMA). APVMA product number: 50052.

Other Information

16. Other Information

Revised 30/06/2016.

This SDS replaces document dated February 2014.

Date of preparation

or last revision of

Normal Hours: Mrs Kathleen Marsh Phone: +61 3 9282 1000

After Hours: Shift Supervisor Phone: 1800 033 498

Contact Person/Point

The SDS was reviewed. Various changes were made to the information.

Revisions

Highlighted

...End Of MSDS...

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Print Date: 30/06/2016

CS: 1.7.2

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