neodisher LaboClean GK

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Date revised: 11.03.2016

Print date: 11.03.16

2 / GB- 800681-003-01

Version: 2 / GB

Replaces Version: 1 /

Safety data sheet in accordance with regulation (EC) No

1907/2006

neodisher LaboClean GK

Page 1(10)

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

neodisher LaboClean GK

1.2. Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/preparation

Washing and cleaning products (including solvent based products)

1.3. Details of the supplier of the safety data sheet

Address:

Chemische Fabrik Dr. Weigert GmbH & Co. KG

Mühlenhagen 85

D-20539 Hamburg

Telephone no.

+49 40 789 60 0

Fax no.

+49 40 789 60 120

www.drweigert.com

E-mail address of person responsible for this SDS:

sida@drweigert.de

1.4. Emergency telephone number

GBK/ Infotrac: (USA domestic) 1 800 535 5053 or international +1 352 323 3500

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification (Regulation (EC) No. 1272/2008)

Classification (Regulation (EC) No. 1272/2008)

Skin Irrit. 2

H315

Eye Irrit. 2

H319

STOT SE 3

H335

Aquatic chronic 2

H411

2.2. Label elements

Labelling according to regulation (EC) No 1272/2008

Hazard pictograms

Signal word

Warning

Hazard statements

H315

Causes skin irritation.

H319

Causes serious eye irritation.

H335

May cause respiratory irritation.

H411

Toxic to aquatic life with long lasting effects.

Precautionary statements

Date revised: 11.03.2016

Print date: 11.03.16

2 / GB- 800681-003-01

Version: 2 / GB

Replaces Version: 1 /

Safety data sheet in accordance with regulation (EC) No

1907/2006

neodisher LaboClean GK

Page 2(10)

P261

Avoid breathing dust/fume/gas/mist/vapours/spray.

P273

Avoid release to the environment.

P280

Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352

IF ON SKIN: Wash with plenty of soap and water.

P305+P351+P338

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact

lenses, if present and easy to do. Continue rinsing.

P310

Immediately call a POISON CENTER or doctor.

Dispose only when container is empty and closed. For disposal of product

residues, refer to Safety Data Sheet.

Hazardous component(s) to be indicated on label (Regulation (EC) No. 1272/2008)

contains

trisodium phosphate

Supplemental information

Contact with acids liberates toxic gas.

2.3. Other hazards

No special hazards have to be mentioned.

SECTION 3: Composition/information on ingredients

Hazardous ingredients

trisodium phosphate

CAS No.

10101-89-0

EINECS no.

231-509-8

Registration no.

02-2119752908-24

Concentration

>= 50 %

Classification

Xi, R36/37/38

Classification (Regulation (EC) No. 1272/2008)

Skin Irrit. 2

H315

Eye Irrit. 2

H319

STOT SE 3

H335

troclosene sodium

CAS No.

2893-78-9

EINECS no.

220-767-7

Registration no.

01-2119489371-33

Concentration

>= 1 < 10 %

Classification

Xn, R22

Xi, R36/37

O, R8

N, R50/53

E, R2

Classification (Regulation (EC) No. 1272/2008)

Acute Tox. 4

H302

Aquatic Chronic 1

H410

Aquatic Acute 1

H400

Eye Irrit. 2

H319

Ox. Sol. 2

H272

STOT SE 3

H335

SECTION 4: First aid measures

4.1. Description of first aid measures

Date revised: 11.03.2016

Print date: 11.03.16

2 / GB- 800681-003-01

Version: 2 / GB

Replaces Version: 1 /

Safety data sheet in accordance with regulation (EC) No

1907/2006

neodisher LaboClean GK

Page 3(10)

General information

Remove contaminated clothing immediately and dispose of safely. In any case show the physician the

Safety Data Sheet.

After inhalation

Ensure supply of fresh air. When dust is intensively inhaled, seek medical help immediately.

After skin contact

Wash off immediately with soap and water. Take medical treatment.

After eye contact

Separate eyelids, wash the eyes thoroughly with water (15 min.). Summon a doctor immediately.

After ingestion

If swallowed, seek medical advice immediately and show this container or label. Rinse mouth thoroughly

with water. Let plenty of water be drunk in small gulps. Do not induce vomiting.

Adhere to personal protective measures when giving first aid

First aider: Pay attention to self-protection!

4.2. Most important symptoms and effects, both acute and delayed

Until now no symptoms known so far.

4.3. Indication of any immediate medical attention and special treatment needed

Hints for the physician / hazards

In the case of swallowing with subsequent vomiting, aspiration of the lungs can occur which can lead to

chemical pneumonia or asphyxiation.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media

Product itself is non-combustible; adapt fire extinguishing measures to surrounding areas.

Non Suitable extinguishing media

Compatible with all usual extinguishing media.

5.2. Special hazards arising from the substance or mixture

In case of combustion evolution of dangerous gases possible.

5.3. Advice for firefighters

Special protective equipment for fire-fighting

Do not inhale explosion and/or combustion gases. In case of combustion use a suitable breathing

apparatus.

Other information

Collect contaminated fire-fighting water separately, must not be discharged into the drains. Fire residues

and contaminated fire-fighting water must be disposed of in accordance with the local regulations.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Avoid contact with skin, eyes and clothing.

6.2. Environmental precautions

Do not discharge into the drains/surface waters/groundwater. Knock down dust with water spray jet.

6.3. Methods and material for containment and cleaning up

Pick up mechanically. Dispose of absorbed material in accordance with the regulations.

Date revised: 11.03.2016

Print date: 11.03.16

2 / GB- 800681-003-01

Version: 2 / GB

Replaces Version: 1 /

Safety data sheet in accordance with regulation (EC) No

1907/2006

neodisher LaboClean GK

Page 4(10)

6.4. Reference to other sections

Refer to protective measures listed in sections 7 and 8.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Advice on safe handling

Avoid the formation and deposition of dust. Keep container tightly closed.

7.2. Conditions for safe storage, including any incompatibilities

Requirements for storage rooms and vessels

Keep in original packaging, tightly closed. Provide solvent-resistant and impermeable floor.

Storage class according to TRGS 510

Storage class according to

TRGS 510

Non- combustible solids

7.3. Specific end use(s)

no data

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Other information

Contains no substances with occupational exposure limit values.

8.2. Exposure controls

General protective and hygiene measures

Do not inhale dust/fumes/aerosols. Avoid contact with skin and eyes. Do not eat, drink or smoke during

work time. Wash hands before breaks and after work. Clean skin thoroughly after work; apply skin

cream.

Respiratory protection

Use breathing apparatus in dust-laden atmosphere. Dust mask

Hand protection

Chemical resistant gloves (EN 374)

Appropriate Material

neoprene

Appropriate Material

vinyl

Appropriate Material

butyl rubber

Appropriate Material

nitrile

Eye protection

Safety glasses with side protection shield (EN 166)

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Form

solid

Colour

white

Odour

characteristic

Odour threshold

Remarks

not determined

pH value

Value

appr.

Date revised: 11.03.2016

Print date: 11.03.16

2 / GB- 800681-003-01

Version: 2 / GB

Replaces Version: 1 /

Safety data sheet in accordance with regulation (EC) No

1907/2006

neodisher LaboClean GK

Page 5(10)

Concentration/H2O

Melting point

Remarks

not determined

Freezing point

Remarks

not determined

Initial boiling point and boiling range

Remarks

not determined

Flash point

Remarks

Not applicable

Evaporation rate (ether = 1) :

Remarks

not determined

Flammability (solid, gas)

evaluation

not determined

Upper/lower flammability or explosive limits

Remarks

not determined

Vapour pressure

Remarks

not determined

Vapour density

Remarks

not determined

Density

Remarks

not determined

Solubility in water

Remarks

not determined

Solubility(ies)

Remarks

not determined

Partition coefficient: n-octanol/water

Remarks

not determined

Ignition temperature

Remarks

not determined

Decomposition temperature

Remarks

not determined

Viscosity

Remarks

not determined

Explosive properties

evaluation

not determined

Oxidising properties

evaluation

None known

9.2. Other information

Other information

None known

SECTION 10: Stability and reactivity

10.1. Reactivity

No hazardous reactions when stored and handled according to prescribed instructions.

Date revised: 11.03.2016

Print date: 11.03.16

2 / GB- 800681-003-01

Version: 2 / GB

Replaces Version: 1 /

Safety data sheet in accordance with regulation (EC) No

1907/2006

neodisher LaboClean GK

Page 6(10)

10.2. Chemical stability

No hazardous reactions known.

10.3. Possibility of hazardous reactions

No hazardous reactions known.

10.4. Conditions to avoid

No hazardous reactions known.

Decomposition temperature

Remarks

not determined

10.5. Incompatible materials

Evolution of chlorine under influence of acids.

10.6. Hazardous decomposition products

Irritant gases/vapours

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute oral toxicity

Species

LD50

>

2000

mg/kg

Method

calculated value (Regulation (EC) No. 1272/2008)

Acute oral toxicity (Components)

troclosene sodium

Species

LD50

1400

mg/kg

Acute dermal toxicity

Remarks

not determined

Acute dermal toxicity (Components)

troclosene sodium

Species

LD50

>

5000

mg/kg

Source

IUCLID

Acute inhalational toxicity

Remarks

not determined

Skin corrosion/irritation

evaluation

irritant

Serious eye damage/irritation

evaluation

irritant

Sensitization

Remarks

not determined

Subacute, subchronic, chronic toxicity

Remarks

not determined

Mutagenicity

Remarks

not determined

Reproductive toxicity

Remarks

not determined

Date revised: 11.03.2016

Print date: 11.03.16

2 / GB- 800681-003-01

Version: 2 / GB

Replaces Version: 1 /

Safety data sheet in accordance with regulation (EC) No

1907/2006

neodisher LaboClean GK

Page 7(10)

Carcinogenicity

Remarks

not determined

Specific Target Organ Toxicity (STOT)

Remarks

Inhalation may lead to irritation of the respiratory tract.

Aspiration hazard

No special hazards have to be mentioned.

Experience in practice

Inhalation of dusts may irritate the respiratory tract.

Other information

There is no data available on the product apart from the information given in this subsection.

SECTION 12: Ecological information

12.1. Toxicity

General information

not determined

Fish toxicity (Components)

troclosene sodium

Species

Bluegill (Lepomis macrochirus)

LC50

0,28

mg/l

Duration of exposure

Source

IUCLID

Daphnia toxicity (Components)

troclosene sodium

Species

Daphnia magna

LC50

0,18

0,21

mg/l

Duration of exposure

Source

IUCLID

12.2. Persistence and degradability

General information

not determined

12.3. Bioaccumulative potential

General information

not determined

Partition coefficient: n-octanol/water

Remarks

not determined

12.4. Mobility in soil

General information

not determined

12.5. Results of PBT and vPvB assessment

General information

not determined

12.6. Other adverse effects

General information

not determined

Date revised: 11.03.2016

Print date: 11.03.16

2 / GB- 800681-003-01

Version: 2 / GB

Replaces Version: 1 /

Safety data sheet in accordance with regulation (EC) No

1907/2006

neodisher LaboClean GK

Page 8(10)

General information / ecology

Do not allow to enter soil, waterways or waste water canal.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Disposal recommendations for the product

Allocation of a waste code number, according to the European Waste Catalogue (EWC), should be

carried out in agreement with the regional waste disposal company.

Disposal recommendations for packaging

Packaging that cannot be cleaned should be disposed off in agreement with the regional waste disposal

company.

SECTION 14: Transport information

Land transport ADR/RID

14.1. UN number

UN 3077

14.2. UN proper shipping name

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (troclosene sodium)

14.3. Transport hazard class(es)

Class

Label

14.4. Packing group

Packing group

Limited Quantity

5 kg

Transport category

14.5. Environmental hazards

ENVIRONMENTALLY HAZARDOUS

Tunnel restriction code

Marine transport IMDG/GGVSee

14.1. UN number

UN 3077

14.2. UN proper shipping name

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (troclosene sodium)

14.3. Transport hazard class(es)

Class

14.4. Packing group

Packing group

14.5. Environmental hazards

Marine Pollutant

IMDG-Code segregation

group

Not applicable

Air transport ICAO/IATA

14.1. UN number

UN 3077

14.2. UN proper shipping name

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (troclosene sodium)

14.3. Transport hazard class(es)

Class

14.4. Packing group

Packing group

14.5. Environmental hazards

ENVIRONMENTALLY HAZARDOUS

Date revised: 11.03.2016

Print date: 11.03.16

2 / GB- 800681-003-01

Version: 2 / GB

Replaces Version: 1 /

Safety data sheet in accordance with regulation (EC) No

1907/2006

neodisher LaboClean GK

Page 9(10)

Information for all modes of transport

14.6. Special precautions for user

See Sections 6 to 8

Other information

14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code

Not applicable

SECTION 15: Regulatory information ***

15.1. Safety, health and environmental regulations/legislation specific for the substance

or mixture

Major-accident categories acc. 96/82/EC

Category

9.II

Dangerous for environment

200.000

500.000

Ingredients (Regulation (EC) No 648/2004)

30 % and more: ***

phosphates

less than 5 %:

chlorine-based bleaching agents

Water Hazard Class (Germany)

Water Hazard Class

(Germany)

WGK 1

Remarks

Classification according to Annex 4 VwVwS

VOC

VOC (EU)

Other information

The product does not contain substances of very high concern (SVHC).

15.2. Chemical safety assessment

For this mixture a chemical safety assessment has not been carried out.

SECTION 16: Other information

R-phrases listed in Chapter 3

Risk of explosion by shock, friction, fire or other sources of ignition.

Harmful if swallowed.

Contact with acids liberates toxic gas.

36/37

Irritating to eyes and respiratory system.

36/37/38

Irritating to eyes, respiratory system and skin.

50/53

Very toxic to aquatic organisms, may cause long-term adverse effects in

the aquatic environment.

Contact with combustible material may cause fire.

Hazard statements listed in Chapter 3

H272

May intensify fire; oxidiser.

H302

Harmful if swallowed.

H315

Causes skin irritation.

H319

Causes serious eye irritation.

H335

May cause respiratory irritation.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

CLP categories listed in Chapter 3

Acute Tox. 4

Acute toxicity, Category 4

Date revised: 11.03.2016

Print date: 11.03.16

2 / GB- 800681-003-01

Version: 2 / GB

Replaces Version: 1 /

Safety data sheet in accordance with regulation (EC) No

1907/2006

neodisher LaboClean GK

Page 10(10)

Aquatic Acute 1

Hazardous to the aquatic environment, acute, Category 1

Aquatic Chronic 1

Hazardous to the aquatic environment, chronic, Category 1

Eye Irrit. 2

Eye irritation, Category 2

Ox. Sol. 2

Oxidising solid, Category 2

Skin Irrit. 2

Skin irritation, Category 2

STOT SE 3

Specific target organ toxicity - single exposure, Category 3

Supplemental information

Relevant changes compared with the previous version of the safety data sheet are marked with: ***

This information is based on our present state of knowledge. However, it should not constitute a

guarantee for any specific product properties and shall not establish a legally valid relationship.

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