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Date revised: 18.10.2016

Print date: 28.06.17

3 / GB- 800793-004-01

Version: 3 / GB

Replaces Version: 2 /

Safety data sheet in accordance with regulation (EC) No

1907/2006

neodisher CM tabs swiss

Page 1(10)

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

neodisher CM tabs swiss

1.2. Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/preparation

Washing and cleaning products (including solvent based products)

1.3. Details of the supplier of the safety data sheet

Address:

Chemische Fabrik Dr. Weigert GmbH & Co. KG

Mühlenhagen 85

D-20539 Hamburg

Telephone no.

+49 40 789 60 0

Fax no.

+49 40 789 60 120

www.drweigert.com

E-mail address of person responsible for this SDS:

sida@drweigert.de

1.4. Emergency telephone number

GBK/ Infotrac: (USA domestic) 1 800 535 5053 or international +1 352 323 3500

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification (Regulation (EC) No. 1272/2008)

Classification (Regulation (EC) No. 1272/2008)

Eye Irrit. 2

H319

2.2. Label elements

Labelling according to regulation (EC) No 1272/2008

Hazard pictograms

Signal word

Warning

Hazard statements

H319

Causes serious eye irritation.

Precautionary statements

P305+P351+P338

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact

lenses, if present and easy to do. Continue rinsing.

P337+P313

If eye irritation persists: Get medical advice/attention.

Dispose only when container is empty and closed. For disposal of product

residues, refer to Safety Data Sheet.

Hazardous component(s) to be indicated on label (Regulation (EC) No. 1272/2008)

Date revised: 18.10.2016

Print date: 28.06.17

3 / GB- 800793-004-01

Version: 3 / GB

Replaces Version: 2 /

Safety data sheet in accordance with regulation (EC) No

1907/2006

neodisher CM tabs swiss

Page 2(10)

contains

sodium carbonate peroxyhydrate

2.3. Other hazards

No special hazards have to be mentioned.

SECTION 3: Composition/information on ingredients

3.2. Mixtures

Hazardous ingredients

sodium carbonate peroxyhydrate

CAS No.

15630-89-4

EINECS no.

239-707-6

Registration no.

01-2119457268-30

Concentration

>=

<

Classification (Regulation (EC) No. 1272/2008)

Ox. Sol. 3

H272

Acute Tox. 4

H302

Eye Dam. 1

H318

Concentration limits (Regulation (EC) No. 1272/2008)

Eye Dam. 1

H318

>= 25 %

Eye Irrit. 2

H319

>= 7,5 < 25 %

potassium carbonate

CAS No.

584-08-7

EINECS no.

209-529-3

Registration no.

01-2119532646-36

Concentration

>=

<

Classification (Regulation (EC) No. 1272/2008)

Skin Irrit. 2

H315

Eye Irrit. 2

H319

STOT SE 3

H335

sodium carbonate

CAS No.

497-19-8

EINECS no.

207-838-8

Registration no.

01-2119485498-19

Concentration

>=

<

Classification (Regulation (EC) No. 1272/2008)

Eye Irrit. 2

H319

SECTION 4: First aid measures

4.1. Description of first aid measures

General information

Remove contaminated clothing immediately and dispose of safely. In any case show the physician the

Safety Data Sheet.

After inhalation

Ensure supply of fresh air. When dust is intensively inhaled, seek medical help immediately.

After skin contact

Wash off immediately with soap and water. Consult a doctor if skin irritation persists.

After eye contact

Separate eyelids, wash the eyes thoroughly with water (15 min.). Summon a doctor immediately.

Date revised: 18.10.2016

Print date: 28.06.17

3 / GB- 800793-004-01

Version: 3 / GB

Replaces Version: 2 /

Safety data sheet in accordance with regulation (EC) No

1907/2006

neodisher CM tabs swiss

Page 3(10)

After ingestion

If swallowed, seek medical advice immediately and show this container or label. Rinse mouth thoroughly

with water. Let plenty of water be drunk in small gulps. Do not induce vomiting.

Adhere to personal protective measures when giving first aid

First aider: Pay attention to self-protection!

4.2. Most important symptoms and effects, both acute and delayed

Until now no symptoms known so far.

4.3. Indication of any immediate medical attention and special treatment needed

Hints for the physician / hazards

In the case of swallowing with subsequent vomiting, aspiration of the lungs can occur which can lead to

chemical pneumonia or asphyxiation.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media

Product itself is non-combustible; adapt fire extinguishing measures to surrounding areas.

Non suitable extinguishing media

Full water jet

5.2. Special hazards arising from the substance or mixture

In case of combustion evolution of dangerous gases possible.

5.3. Advice for firefighters

Special protective equipment for fire-fighting

Do not inhale explosion and/or combustion gases. In case of combustion use a suitable breathing

apparatus.

Other information

Collect contaminated fire-fighting water separately, must not be discharged into the drains. Fire residues

and contaminated fire-fighting water must be disposed of in accordance with the local regulations.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Avoid contact with skin, eyes and clothing.

6.2. Environmental precautions

Do not discharge into the drains/surface waters/groundwater. Knock down dust with water spray jet.

6.3. Methods and material for containment and cleaning up

Pick up mechanically. Dispose of absorbed material in accordance with the regulations.

6.4. Reference to other sections

Refer to protective measures listed in Sections 7 and 8.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Advice on safe handling

Avoid the formation and deposition of dust. Keep container tightly closed.

7.2. Conditions for safe storage, including any incompatibilities

Recommended storage temperature

Date revised: 18.10.2016

Print date: 28.06.17

3 / GB- 800793-004-01

Version: 3 / GB

Replaces Version: 2 /

Safety data sheet in accordance with regulation (EC) No

1907/2006

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Page 4(10)

Value

>

<

Requirements for storage rooms and vessels

Keep in original packaging, tightly closed.

Hints on storage assembly

Do not store with combustible materials.

Storage class according to TRGS 510

Storage class according to

TRGS 510

Non- combustible solids

Further information on storage conditions

Protect from heat and direct sunlight.

7.3. Specific end use(s)

no data

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Other information

Contains no substances with occupational exposure limit values.

8.2. Exposure controls

General protective and hygiene measures

Do not inhale dust/fumes/aerosols. Avoid contact with skin and eyes. Do not eat, drink or smoke during

work time. Wash hands before breaks and after work. Clean skin thoroughly after work; apply skin

cream.

Respiratory protection

Use breathing apparatus in dust-laden atmosphere. Dust mask

Hand protection

Chemical resistant gloves (EN 374)

Permanent hand contact

Appropriate Material

neoprene

Material thickness

>=

0,65

Breakthrough time

>

Appropriate Material

butyl

Material thickness

>=

Breakthrough time

>

Appropriate Material

nitrile

Material thickness

>=

Breakthrough time

>

Short-term hand contact

Appropriate Material

nitrile

Material thickness

>=

0,11

Eye protection

Safety glasses with side protection shield (EN 166)

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Form

solid

Colour

white

Odour

odourless

Odour threshold

Date revised: 18.10.2016

Print date: 28.06.17

3 / GB- 800793-004-01

Version: 3 / GB

Replaces Version: 2 /

Safety data sheet in accordance with regulation (EC) No

1907/2006

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Page 5(10)

Remarks

not determined

pH value

Value

10,5

10,7

Concentration/H2O

Melting point

Remarks

not determined

Freezing point

Remarks

not determined

Initial boiling point and boiling range

Remarks

not determined

Flash point

Remarks

Not applicable

Evaporation rate (ether = 1) :

Remarks

not determined

Flammability (solid, gas)

evaluation

not determined

Upper/lower flammability or explosive limits

Remarks

not determined

Vapour pressure

Remarks

not determined

Vapour density

Remarks

not determined

Density

Remarks

not determined

Solubility in water

Remarks

soluble

Solubility(ies)

Remarks

not determined

Partition coefficient: n-octanol/water

Remarks

not determined

Ignition temperature

Remarks

not determined

Decomposition temperature

Remarks

not determined

Viscosity

Remarks

Not applicable

Explosive properties

evaluation

not determined

Oxidising properties

evaluation

oxidizing

9.2. Other information

Other information

None known

SECTION 10: Stability and reactivity

Date revised: 18.10.2016

Print date: 28.06.17

3 / GB- 800793-004-01

Version: 3 / GB

Replaces Version: 2 /

Safety data sheet in accordance with regulation (EC) No

1907/2006

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Page 6(10)

10.1. Reactivity

No hazardous reactions when stored and handled according to prescribed instructions.

10.2. Chemical stability

No hazardous reactions known.

10.3. Possibility of hazardous reactions

No hazardous reactions known.

10.4. Conditions to avoid

Protect from heat and direct sunlight.

Decomposition temperature

Remarks

not determined

10.5. Incompatible materials

Acids, Reducing agents

10.6. Hazardous decomposition products

Irritant gases/vapours

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute oral toxicity

Species

LD50

>

2000

mg/kg

Method

calculated value (Regulation (EC) No. 1272/2008)

Acute oral toxicity (Components)

sodium carbonate peroxyhydrate

Species

LD50

1034

mg/kg

Method

Value taken from the literature

sodium carbonate

Species

LD50

2800

mg/kg

Acute dermal toxicity

Remarks

Based on available data, the classification criteria are not met.

Acute dermal toxicity (Components)

sodium carbonate peroxyhydrate

Species

rabbit

LD50

>

2000

mg/kg

Method

OECD 402

sodium carbonate

Species

rabbit

LD50

>

2000

mg/kg

Acute inhalational toxicity

Remarks

Based on available data, the classification criteria are not met.

Acute inhalative toxicity (Components)

sodium carbonate

Species

mouse

LC50

mg/l

Duration of exposure

Date revised: 18.10.2016

Print date: 28.06.17

3 / GB- 800793-004-01

Version: 3 / GB

Replaces Version: 2 /

Safety data sheet in accordance with regulation (EC) No

1907/2006

neodisher CM tabs swiss

Page 7(10)

sodium carbonate

Species

LC50

mg/l

Duration of exposure

Skin corrosion/irritation

Remarks

Based on available data, the classification criteria are not met.

Serious eye damage/irritation

evaluation

irritant

Sensitization

Remarks

Based on available data, the classification criteria are not met.

Subacute, subchronic, chronic toxicity

Remarks

Based on available data, the classification criteria are not met.

Mutagenicity

Remarks

Based on available data, the classification criteria are not met.

Reproductive toxicity

Remarks

Based on available data, the classification criteria are not met.

Carcinogenicity

Remarks

Based on available data, the classification criteria are not met.

Specific Target Organ Toxicity (STOT)

Remarks

not determined

Aspiration hazard

No special hazards have to be mentioned.

Experience in practice

Inhalation of dusts may irritate the respiratory tract.

Other information

There is no data available on the product apart from the information given in this subsection.

SECTION 12: Ecological information

12.1. Toxicity

General information

not determined

Fish toxicity (Components)

sodium carbonate peroxyhydrate

Species

Fathead minnow (Pimephales promelas)

LC50

70,7

mg/l

Duration of exposure

sodium carbonate

Species

Bluegill (Lepomis macrochirus)

LC50

mg/l

Duration of exposure

Daphnia toxicity (Components)

sodium carbonate peroxyhydrate

Species

Daphnia pulex

EC50

mg/l

Duration of exposure

sodium carbonate peroxyhydrate

Species

Daphnia pulex

Date revised: 18.10.2016

Print date: 28.06.17

3 / GB- 800793-004-01

Version: 3 / GB

Replaces Version: 2 /

Safety data sheet in accordance with regulation (EC) No

1907/2006

neodisher CM tabs swiss

Page 8(10)

NOEC

mg/l

Duration of exposure

sodium carbonate

Species

Ceriodaphnia spec

EC50

mg/l

Duration of exposure

Bacteria toxicity (Components)

sodium carbonate peroxyhydrate

Species

activated sludge

EC50

mg/l

Duration of exposure

12.2. Persistence and degradability

General information

not determined

12.3. Bioaccumulative potential

General information

not determined

Partition coefficient: n-octanol/water

Remarks

not determined

12.4. Mobility in soil

General information

not determined

12.5. Results of PBT and vPvB assessment

General information

not determined

Evaluation of persistance and bioaccumulation potential

The product contains no PBT or vPvB substances.

12.6. Other adverse effects

General information

not determined

General information / ecology

Do not allow to enter soil, waterways or waste water canal.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Disposal recommendations for the product

Allocation of a waste code number, according to the European Waste Catalogue (EWC), should be

carried out in agreement with the regional waste disposal company.

Disposal recommendations for packaging

Packaging that cannot be cleaned should be disposed off in agreement with the regional waste disposal

company.

SECTION 14: Transport information

Land transport ADR/RID

Marine transport

IMDG/GGVSee

Air transport ICAO/IATA

Date revised: 18.10.2016

Print date: 28.06.17

3 / GB- 800793-004-01

Version: 3 / GB

Replaces Version: 2 /

Safety data sheet in accordance with regulation (EC) No

1907/2006

neodisher CM tabs swiss

Page 9(10)

14.1. UN number

Non-dangerous goods

The product does not constitute a

hazardous substance in sea

transport.

The product does not constitute a

hazardous substance in air

transport.

Information for all modes of transport

14.6. Special precautions for user

See Sections 6 to 8

Other information

14.7. Transport in bulk according to Annex II of Marpol and the IBC Code

Not applicable

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance

or mixture

Ingredients (Regulation (EC) No 648/2004)

30 % and more:

phosphates

15 % or over but less than 30 %:

oxygen-based bleaching agents

Water Hazard Class (Germany)

Water Hazard Class

(Germany)

WGK 1

Remarks

Classification according to Annex 4 VwVwS

VOC

VOC (EU)

Other information

The product does not contain substances of very high concern (SVHC).

15.2. Chemical safety assessment

For this preparation a chemical safety assessment has not been carried out.

SECTION 16: Other information

Hazard statements listed in Chapter 3

H272

May intensify fire; oxidiser.

H302

Harmful if swallowed.

H315

Causes skin irritation.

H318

Causes serious eye damage.

H319

Causes serious eye irritation.

H335

May cause respiratory irritation.

CLP categories listed in Chapter 3

Acute Tox. 4

Acute toxicity, Category 4

Eye Dam. 1

Serious eye damage, Category 1

Eye Irrit. 2

Eye irritation, Category 2

Ox. Sol. 3

Oxidising solid, Category 3

Skin Irrit. 2

Skin irritation, Category 2

STOT SE 3

Specific target organ toxicity - single exposure, Category 3

Supplemental information

Relevant changes compared with the previous version of the safety data sheet are marked with: ***

This information is based on our present state of knowledge. However, it should not constitute a

guarantee for any specific product properties and shall not establish a legally valid relationship.

Date revised: 18.10.2016

Print date: 28.06.17

3 / GB- 800793-004-01

Version: 3 / GB

Replaces Version: 2 /

Safety data sheet in accordance with regulation (EC) No

1907/2006

neodisher CM tabs swiss

Page 10(10)

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