MULTICROP GLYPHOSATE 360 WEEDKILLER

Australia - English - APVMA (Australian Pesticides and Veterinary Medicines Authority)

Active ingredient:
GLYPHOSATE PRESENT AS THE ISOPROPYLAMINE SALT
Available from:
MULTICROP (AUST.) PTY.LTD.
INN (International Name):
glyphosate as ipa(360g/L)
Pharmaceutical form:
AQUEOUS CONCENTRATE
Composition:
GLYPHOSATE PRESENT AS THE ISOPROPYLAMINE SALT GLYCINE Active 360.0 g/L
Units in package:
1.25L; 1L; 2.5L
Class:
A - Agricultural
Manufactured by:
MULTICROP (AUST.)
Therapeutic group:
DOMESTIC AREA - OUTDOORS | AIR VENTS | AROUND DOORS | AROUND FOUNDATIONS | BEHIND DOWNPIPES | CRACKS | CREVICES | CUBBY HOUSE |
Therapeutic area:
HERBICIDE
Therapeutic indications:
ANNUAL WEEDS | PERENNIAL WEED | WOODY WEED (SEE LABEL) | PERENNIAL WEEDS | WOODY WEEDS
Product summary:
Poison schedule: 5; Withholding period: WHP:N/A; Host/pest details: DOMESTIC AREA - OUTDOORS: [ANNUAL WEEDS, PERENNIAL WEED, WOODY WEED (SEE LABEL)]; Poison schedule: 5; Withholding period: ; Host/pest details: DOMESTIC AREA - OUTDOORS: [ANNUAL WEEDS, PERENNIAL WEED, WOODY WEED (SEE LABEL)]; Kills weeds and grasses in the home garden.
Authorization status:
Registered
Authorization number:
54147
Authorization date:
2019-07-01

Product Name:

Multicrop Glyphosate 360 Weedkiller

Page

10[2

Descriotion:

File Number:

Product Code:

Date:

06106/01

Notes:

Version:

DRAFT3

CAUTION

KEEP

REACH

CHILDREN

READ SAFETY DIRECTIONS BEFORE OPENING

USING

Multicrop"

Glyphosate 360

WEED

KILLER

ACTIVE CONSTITUENT:

360 gIL GLYPHOSATE

(present as isopropylamine salt)

Kills weeds and grasses in the home garden

Contents:

1 L,

1.25 L,

2.5 L

--------

N.R.A.

APPROVED

LABEL

(TEXT)

f>'f

Label

Date:

..

5.

JO.!.

..I~(

Signature:"'::.~u.<,.....?

.........

c:'I

.

Product

Name:

Multicrop G1yphosate 360 Weedkiller

Page

20[2

Description:

File Number:

Product Code"

Date:

06/06/01

Notes:

Version:

DRAFT3

treat

rain is likely within 6 hours.

DISTURB tr

eate

wee s

avs a

er treatmen .

WEEDS

RATE

APPLY

CONTROLLED

General

mixed

Timing:

Apply when weeds are actively growing.

For best results on

weeds

(Annual

perennial weeds treat after flowering.

Treat woody weeds from

perennial

water

flowering to leaf fall (Jan-May).

DO NOT spray plants bearing edible

weeds)

berries.

Woody

Weeds

Application:

Uniform and complete spray to wet all leaves.

should not occur.

water

spray will

cover 10 square metres.

For difficult to wet weeds,

addition

a non-ionic surfactant is recommended at

a rate

600g/L product (or equivalent) per

IL sprav solution.

USED

PURPOSE,

IN ANY

MANNER,

CONTRARY

THIS

LABEL

UNLESS

AUTHORISED

prepare

Mix this product with clean water.

Use only plastic or plastic lined,

brass,

copper,

fibre glass stainless

steel,

aluminium containers for mixing and application. DO NOT mix more than can be used within 5

days.

Wash out spray equipment thoroughly after use.

Caution

DO NOT allow spray to contact or drift onto plants you do not want to kill.

Accidental contact must be

hosed immediately to reduce injury to plant. DO

let chemical containers or spray to get into drains,

sewers,

streams or ponds.

DO NOT spray directly on humans,

pets,

exposed food,

food preparation areas

or food utensils.

SAFETY

DIRECTIONS

Avoid contact with eyes and skin.

Wash hands after use.

FIRST AID

If poisoning occurs,

contact a doctor or Poisons Information Centre on 13

11

STORAGE AND DISPOSAL

Store in the closed,

original

container in a cool

dry place out

reach of

children.

Do not

store

in direct sunlight.

Dispose of empty container by wrapping in paper,

placing in a plastic bag and

putting in the garbage.

Batch Number

Date

Manufacture

NRA Approval No.

54147/0601

Multicrop Pty Ltd

926 Mountain Highway

Bayswater, Vic 3153

Phone:

(03) 9720 2200

1

MATERIAL SAFETY DATA SHEET

Issued by: Multicrop (Aust) Pty Ltd

Phone: +61 3 8720 2100 (business hours)

Poisons Information Centre: 13 1126 from any where in Australia (0800 764 766 in New Zealand)

THIS MSDS SUMMARISES TO OUR BEST KNOWLEDGE AS AT THE ISSUE DATE THE CHEMICAL HEALTH AND SAFETY HAZARD OF

MATERIAL AND GENERAL GUIDANCE ON HOW TO SAFELY HANDLE THE MATERIAL. MULTICROP(AUST) PTY LTD CANNOT CONTROL OR

ANTICIPATE THE CONDITION AND ENVIRONMENT UNDER WHICH THE PRODUCT IS USED OR STORED, EACH USER MUST, PRIOR TO USE,

UNDERSTAND ANY RISK ARISING FROM USE OF THE MATERIAL IN THE COMPOSITION OF THIS PRODUCT.

MATERIAL SAFETY DATA SHEET

Product Name: Multicrop Glyphosate 360 Weed Killer

This revision issued: December 2012

Multicrop (Aust) Pty Ltd

Phone: +61 3 8720 2100

6-10 Koornang Rd

Fax:

+61 3 9720 5051

Scoresby, Vic 3179

Trade Name:

Multicrop Glyphosate 360 Weed Killer Concentrate

Product Codes:

92305

Product Use:

Non Selective Herbicide

Statement of Hazardous Nature:

Based on available information, this material is not classified as hazardous

according to criteria of NOHSC Australia.

Statement of Dangerous Nature:

Not a Dangerous Good according to the Australian Dangerous Goods (ADG) Code.

Poisons Schedule (Aust):

This material is a Scheduled Poison S5 and must be stored, maintained and used in accordance with the relevant regulations.

SUSDP Classification:

ADG Classification:

None allocated. Not a Dangerous Good under the ADG Code.

UN Number:

None allocated.

Ingredients

CAS No

Proportion

Glyphosate as the Isopropylamine salt

38641-94-0

360g/L

Surfactant

medium content

Inert components and water

7732-18-5

medium content

This is a commercial product whose exact ratio of components may vary slightly. Minor qualities of other non hazardous

ingredients are also possible.

The SWA TWA exposure value is the average airborne concentration of a particular substance when calculated over a normal 8 hour

working day for a 5 day working week. The STEL (Short Term Exposure Limit) is an exposure value that may be equalled (but should not be

exceeded) for no longer than 15 minutes and should not be repeated more than 4 times per day. There should be a least 60 minutes

between successive exposures at the STEL. The term “peak” is used when the TWA limit, because of the rapid action of the substance,

should never be exceeded, even briefly.

Section 3 – Composition/Information on Ingredients

Section 2 – Hazards Identification

Section 1 – Identification of the Material and Supplier

2

MATERIAL SAFETY DATA SHEET

Issued by: Multicrop (Aust) Pty Ltd

Phone: +61 3 8720 2100 (business hours)

Poisons Information Centre: 13 1126 from any where in Australia (0800 764 766 in New Zealand)

THIS MSDS SUMMARISES TO OUR BEST KNOWLEDGE AS AT THE ISSUE DATE THE CHEMICAL HEALTH AND SAFETY HAZARD OF

MATERIAL AND GENERAL GUIDANCE ON HOW TO SAFELY HANDLE THE MATERIAL. MULTICROP(AUST) PTY LTD CANNOT CONTROL OR

ANTICIPATE THE CONDITION AND ENVIRONMENT UNDER WHICH THE PRODUCT IS USED OR STORED, EACH USER MUST, PRIOR TO USE,

UNDERSTAND ANY RISK ARISING FROM USE OF THE MATERIAL IN THE COMPOSITION OF THIS PRODUCT.

General Information:

If poisoning occurs, contact a doctor or Poisons Information Centre (Phone Australia 131 126, New

Zealand 03 4747 000).

Inhalation:

Remove victim from exposure – avoid becoming a casualty. Remove contaminated clothing and

loosen remaining clothing. Allow patient to assume most comfortable position and keep warm.

Keep at rest until fully recovered. Seek medical advice if effects persist.

Skin Contact:

If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running

water. If swelling, redness, blistering or irritation occurs seek medical assistance.

Eye Contact:

If in eyes wash out immediately with water. In all cases of eye contamination it is sensible

precaution to seek medical advice.

Ingestion:

Rinse mouth with water. If swallowed, do NOT induce vomiting. Give a glass of water to drink. Never

give anything by the mouth to an unconscious patient. If vomiting occurs give further water. Seek

medical advice.

Notes to physician:

Treat symptomatically.

Specific hazards:

Non-combustible material.

Fire fighting further advice:

Not combustible, however following evaporation of aqueous component residual material

can burn if ignited. On burning will emit toxic fumes. Fire fighters to wear self-contained

breathing apparatus and suitable protective clothing if risk of exposure to vapour or

products of combustion.

Hazchem Code:

Not Applicable.

Suitable extinguishing media:

Not combustible, however, if material is involved in a fire use water fog (or if unavailable

fine water spray), foam, dry agent (carbon dioxide, dry chemical powder).

Flash Point:

Upper Flammability Limit:

Autoignition temperature:

Flammability Class:

Small Spills:

Wear protective equipment to prevent skin and eye contamination. Wipe up with absorbent (clean

rag or paper towels). Collect and seal in properly labeled containers or drums for disposal.

Section 4 – First Aid Measures

Section 5 – Fire Fighting Measures

Section 6 – Accidental Release Measures

Section 6 – Accidental Release Measures

3

MATERIAL SAFETY DATA SHEET

Issued by: Multicrop (Aust) Pty Ltd

Phone: +61 3 8720 2100 (business hours)

Poisons Information Centre: 13 1126 from any where in Australia (0800 764 766 in New Zealand)

THIS MSDS SUMMARISES TO OUR BEST KNOWLEDGE AS AT THE ISSUE DATE THE CHEMICAL HEALTH AND SAFETY HAZARD OF

MATERIAL AND GENERAL GUIDANCE ON HOW TO SAFELY HANDLE THE MATERIAL. MULTICROP(AUST) PTY LTD CANNOT CONTROL OR

ANTICIPATE THE CONDITION AND ENVIRONMENT UNDER WHICH THE PRODUCT IS USED OR STORED, EACH USER MUST, PRIOR TO USE,

UNDERSTAND ANY RISK ARISING FROM USE OF THE MATERIAL IN THE COMPOSITION OF THIS PRODUCT.

Section 8 – Exposure Control & Personal Protection

Large Spills:

Slippery when spilt. Avoid accidents, clean up immediately. Wear protective equipment to prevent

skin and eye contamination. Contain – prevent run off into drains and waterways. Use absorbent

(soil, sand or other inert material). Collect and seal in properly labeled containers or drums for

disposal. If contamination of crops or waterways has occurred advise emergency services or State

Department of Agriculture. If contamination of sewers or waterways has occurred advise local

emergency services.

Dangerous Goods – Initial Emergency Response Guide No: Not Applicable.

Handling:

Avoid eye contact and repeated or prolonged skin contact.

Storage:

Store in a cool, dry, well ventilated place and out of direct sunlight. Store in a locked room or place

away from children, animals, food, feedstuffs and fertilizer. Keep containers closed when not in use -

check regularly for leaks.

This material is a Scheduled Poison S5 and must be stored, maintained and used in accordance with

the relevant regulations.

National occupational exposure limits: No value assigned for this specific material by the National Occupational Health and

Safety Commission (NOHSC Australia).

Biological Limit Values:

As per the “National Model Regulations for the Control of Workplace Hazardous

Substances [NOHSC: 1005 (1994)]” the ingredients in this material do not have a

Biological Limited Allocated.

Substances (NOHSC: 1005 (1994)” the ingredients in this material do not have a

Biological Limit Allocated.

Engineering measures:

Natural ventilation should be adequate under normal use conditions. Keep

containers closed when not in use.

Personal protection equipment:

Overalls, Safety Shoes, Safety Glasses, Gloves.

Avoid eye contact and repeated or prolonged skin contact. Wear overalls, safety glasses and impervious gloves.

Always wash hands before smoking, eating, drinking or using the toilet. Wash contaminated clothing and other protective

equipment before storing or re-using.

Protective Material Types:

Respirator:

Physical Description & Colour:

Viscous Yellow coloured liquid.

Solubility:

Soluble in water.

Odour:

Odourless to slight amine odour.

Specific Gravity:

1.2

Section 9 – Physical & Chemical Properties

Section 7 – Handling & Storage

4

MATERIAL SAFETY DATA SHEET

Issued by: Multicrop (Aust) Pty Ltd

Phone: +61 3 8720 2100 (business hours)

Poisons Information Centre: 13 1126 from any where in Australia (0800 764 766 in New Zealand)

THIS MSDS SUMMARISES TO OUR BEST KNOWLEDGE AS AT THE ISSUE DATE THE CHEMICAL HEALTH AND SAFETY HAZARD OF

MATERIAL AND GENERAL GUIDANCE ON HOW TO SAFELY HANDLE THE MATERIAL. MULTICROP(AUST) PTY LTD CANNOT CONTROL OR

ANTICIPATE THE CONDITION AND ENVIRONMENT UNDER WHICH THE PRODUCT IS USED OR STORED, EACH USER MUST, PRIOR TO USE,

UNDERSTAND ANY RISK ARISING FROM USE OF THE MATERIAL IN THE COMPOSITION OF THIS PRODUCT.

Relative Vapour Density (air=1):

N/Av

pH:

N/Av

Boiling Point:(°C):

100 approx

Volatiles:

N/A

Vapour Pressure: (20 °C)

N/Av

Flash Point:

N/App

Flammability Limits (%)

N/App

Autoignition Temperature (

o

C):

N/App

Vapour Density:

Melting Point/Range (°C)

0 approx.

(Typical values only – consult specification sheet)

N/A Not Available N/App Not Applicable

Chemical stability:

Stable for at least 5 years under normal conditions of warehouse storage.

Conditions to avoid:

No information available.

Incompatible:

Strong oxidizing agents, strong acids and strong alkalis.

Hazardous decomposition products:

No information available.

Hazardous reactions:

Hazardous polymerisation does not occur.

No adverse health effects expected if the product is handled in accordance with the Safety Data Sheet and the product label.

Symptoms or effects that may arise if the product is mishandled and overexposure occurs are.

Acute Effects

Inhalation:

Material may be irritant to mucous membranes and respiratory tract.

Skin contact:

Contact with skin may result in irritation.

Eye contact:

May be an eye irritant.

Ingestion:

No adverse effects expected however large amounts may cause nausea and vomiting.

Long Term Effects:

No information available for product.

Section 11 – Toxicological Information

::

Section 10 – Stability & Reactivity

::

5

MATERIAL SAFETY DATA SHEET

Issued by: Multicrop (Aust) Pty Ltd

Phone: +61 3 8720 2100 (business hours)

Poisons Information Centre: 13 1126 from any where in Australia (0800 764 766 in New Zealand)

THIS MSDS SUMMARISES TO OUR BEST KNOWLEDGE AS AT THE ISSUE DATE THE CHEMICAL HEALTH AND SAFETY HAZARD OF

MATERIAL AND GENERAL GUIDANCE ON HOW TO SAFELY HANDLE THE MATERIAL. MULTICROP(AUST) PTY LTD CANNOT CONTROL OR

ANTICIPATE THE CONDITION AND ENVIRONMENT UNDER WHICH THE PRODUCT IS USED OR STORED, EACH USER MUST, PRIOR TO USE,

UNDERSTAND ANY RISK ARISING FROM USE OF THE MATERIAL IN THE COMPOSITION OF THIS PRODUCT.

Acute toxicity/Chronic toxicity: No LD50 data available for the product. However for the constituent Glyphosate as the

Isopropylamine salt;

Oral LD50 (rat):

4050 mg/kg

4 hr Inhalation LC50 (rat):

>1.3 mg/l air

Avoid contaminating waterways.

Ecotoxicity:

No information available. However for the constituent Glyphosate,

Avian Toxicity:

Oral LD50 (Bobwhite Quail):

>3850 mg/kg

LC50 (Quail and Ducks):

>4640 mg/kg (8 day dietary)

Aquatic Toxicity:

96h LC50 (trout):

86 mg/L

96h LC50 (Bluegill sunfish):

120 mg/L

48h EC50 (Daphnia):

>780mg/L

Bee Toxicity:

LD50 (contact):

>0.1 mg/bee

LD50 (oral):

>0.1 mg/bee

Persistence and degradability: No information available.

Mobility:

No information available.

Disposal: Triple or preferably pressure rinse containers before disposal. Add rinsing to spray tank. Do not dispose of

undiluted chemicals on-site. If recycling, replace cap and return clean containers to recycler or designated collection point. If

not recycling, break, crush or puncture and bury empty containers in a local authority landfill. If no landfill is available, bury

the containers below 500 mm in a disposal pit specifically marked and set up for this purpose clear of waterways, desirable

vegetation and tree roots. Empty containers and product should not be burnt.

For further information refer to State/Territory Land Waste Management Authority.

ADG Code:

This product is not classified as a Dangerous Good. No special transport conditions are necessary unless

required by other regulations.

Poisons Schedule (Aust): S5

All the constituents of this material are listed on the Australian Inventory of Chemical Substances (AICS) or

are Australian Pesticides and Veterinary Medicines Authority (APVMA) approved active constituents.

Section 15 – Regulatory

Information

Section 13 – Disposal Considerations

Section 12 – Ecological Information

Section 14 – Transport Information

6

MATERIAL SAFETY DATA SHEET

Issued by: Multicrop (Aust) Pty Ltd

Phone: +61 3 8720 2100 (business hours)

Poisons Information Centre: 13 1126 from any where in Australia (0800 764 766 in New Zealand)

THIS MSDS SUMMARISES TO OUR BEST KNOWLEDGE AS AT THE ISSUE DATE THE CHEMICAL HEALTH AND SAFETY HAZARD OF

MATERIAL AND GENERAL GUIDANCE ON HOW TO SAFELY HANDLE THE MATERIAL. MULTICROP(AUST) PTY LTD CANNOT CONTROL OR

ANTICIPATE THE CONDITION AND ENVIRONMENT UNDER WHICH THE PRODUCT IS USED OR STORED, EACH USER MUST, PRIOR TO USE,

UNDERSTAND ANY RISK ARISING FROM USE OF THE MATERIAL IN THE COMPOSITION OF THIS PRODUCT.

This MSDS contains only safety-related information. For other data see product literature.

Acronyms:

ADG Code

Australian code for the Transport of Dangerous Goods by Road and Rail (7

edition)

AICS

Australian Inventory of Chemical Substances

SWA

Safe Work Australia, formerly ASCC and NOHSC

CAS number

Chemical Abstracts Service Registry Number

Hazchem Code

Emergency action code of numbers and letters that provide information to emergency services

especially firefighters

IARC

International Agency for research on cancer

NOS

Not otherwise specified

NTP

National Toxicology Program (USA)

R-Phrase

Risk Phrase

SUSDP

Standard for Uniform Scheduling of Drugs & Poisons

UN Number

United Nations Number

Section 16 – Other Information

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