STOMP 330E HERBICIDE

Main information

  • Trade name:
  • STOMP 330E HERBICIDE
  • Class:
  • AgChem
  • Medicine domain:
  • Plants
  • Medicine type:
  • Allopathic drug

Documents

Localization

  • Available in:
  • STOMP 330E HERBICIDE
    Australia
  • Language:
  • English

Therapeutic information

  • Therapeutic group:
  • AVOCADO | BAHIA GRASS | BANANA | BARLEY - PRE-PLANT | BENT LAWN OR TURF | BROAD BEAN | BROCCOLI TRANSPLANTS | BUFFALO GRASS LAWN
  • Therapeutic area:
  • HERBICIDE
  • Therapeutic indications:
  • AMARANTH OR AMARANTHUS | ANNUAL NETTLES - SUPRESSION | ANNUAL NETTLES - URTICA SPP. | ANNUAL OR WIMMERA RYEGRASS | ANNUAL RYEGRASS | ANNUAL SEDGE(CYPERUS SPP.) - SUPPRESSION | ASTHMA PLANT | AWNLESS BARNYARD GRASS | BARNYARD GRASS OR WATER GRASS | BARNYARD OR WATER GRASS | BATHURST BURR | BINDWEED | BLACKBERRY NIGHTSHADE | BLACKBERRY NIGHTSHADE - SUPPRESSION | BLADDER KETMIA | BLUE BILLYGOAT WEED | BROWN BEETLE OR SILVER TOP GRASS | BUTTON GRASS | CALTROP OR YELLOW VINE | CALTROP OR YELLOW VINE - SUPPRESSION | CAPEWEED | CHICKWEED | COBBLER'S PEGS | COMMON HELIOTROPE | COMMON SIDA | COMMON SOWTHISTLE - SUPPRESSION | COMMON VERBENA | COMMON VERBENA - SUPRESSION | CRESTED GOOSEFOOT | CROWSFOOT GRASS | CURIOUS WEED | DEADNETTLE | DOCK - SEEDLING | DWARF AMARANTH OR BOGGABRI WEED | EARLY SPRING GRASS | ERODIUM, CROWFOOT OR STORKSBILL | FAT HEN | FUMITORY - SUPPRESSION | GIANT OR BLACK PIGWEED | GLOSSY NIGHTSHADE | GREEN AMARANTH | GREEN FAT HEN | GREEN SUMMER GRASS | GUINEA GRASS | INDIAN HEDGE MUSTARD | INDIAN H

Other information

Status

  • Source:
  • Australian Pesticides and Veterinary Medicines Authority (APVMA)
  • Authorization status:
  • Registered
  • Authorization number:
  • 31824
  • Last update:
  • 09-08-2016

Summary of Product characteristics: dosage,interactions,side effects

Page:1 Material Safety Data Sheet

Infosafe No. 3NU49 July 2004 ISSUED by CRPCARE Issue Date :

STOMP® 330E Herbicide Product Name :

Classified as hazardous according to criteria of NOHSC

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND COMPANY

Product Name STOMP® 330E Herbicide

Product Code 0761

Product Use For the control of annual ryegrass and wireweed in wheat, barley and peas and

annual grasses and certain broadleaved weeds in various crops as shown in the

Directions For Use Table.

Company Name Crop Care Australasia Pty Ltd (ABN 53 061 362 347)

Address 77 Tingira Street Pinkenba

Queensland 4008 Australia

Emergency Tel. 1800 033 498

Telephone/Telex

Number Tel: (07) 3867 9100 Fax: (07) 3867 9110

Product Type Group D Herbicide

Other Information This MSDS describes, to the best of our knowledge, the properties of the

concentrated product. The physical properties and some of the assessments do not

apply to the properties of the product once it has been diluted for application.

Acute health effects of the diluted product are likely to be much less severe.

2. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical

Characterization Liquid

Ingredients Name CAS Proportion

578 g/L 64742-94-5 Hydrocarbon Liquid

330 g/L 40487-42-1 Pendimethalin technical

5-10 % Surfactants

3. HAZARDS IDENTIFICATION

Harmful if swallowed.

Harmful: may cause lung damage if swallowed.

Other Information Poisons Schedule 5

4. FIRST AID MEASURES

Inhalation Remove to fresh air, apply artifical respiration if necessary.

Ingestion Give water or milk to drink. DO NOT induce vomiting.

Skin Wash affected areas thoroughly with soap and water.

Remove contaminated clothing and launder before re-use.

Eye If in eyes, hold eyelids open and wash with copious amounts of water for at least

15 minutes.

First Aid Facilities If poisoning occurs, contact a doctor or Poisons Information Centre on 13 11 26

(Australia).

Advice to Doctor Treat symptomatically.

If vomiting occurs, solvent present may cause pulmonary pneumonitis.

5. FIRE FIGHTING MEASURES

Extinguishing MediaWater fog, foam, carbon dioxide or dry chemical.

Hazardous

Combustion Products If involved in a fire, it will emit oxides of carbon, oxides of nitrogen and

possibly cyanides.

Emergency Action in

case of Fire If exposed to fire, keep container cool by spraying with water.

If possible, remove other containers from the area of fire.

Protective EquipmentBreathable air apparatus may have to be worn in confined spaces.

Other Information Prevent fire water from entering drains or water bodies.

Page:2 Material Safety Data Sheet

Infosafe No. 3NU49 July 2004 ISSUED by CRPCARE Issue Date :

STOMP® 330E Herbicide Product Name :

Classified as hazardous according to criteria of NOHSC

6. ACCIDENTAL RELEASE MEASURES

Spills & Disposal Contain spill and absorb with clay, sand, soil or proprietary absorbent (such as

vermiculite).

Collect spilled material and waste in sealable open-top type containers for

disposal.

Personal Protection For appropriate personal protective equipment (PPE), refer Section 8.

7. HANDLING AND STORAGE

Handling For personal protective equipment (PPE) and hygiene advice, refer Section 8.

Pendimethalin is coloured and will strongly stain skin and clothing. If skin has

been exposed to the product, thorough washing with soap and water will remove any

excess product. The colour on the skin is not deep and will naturally disappear

over a few days.

Storage Store in the closed, original container in a dry, cool well ventilated area out of

direct sunlight.

Do not store below 5 °C. Extended storage below 5°C can result in the formation

of crystals on the bottom of the container. If crystallisation does occur, store

the container on its side at room temperature and rock occassionally until

crystals re-dissolve.

8. EXPOSURE CONTROLS, PERSONAL PROTECTION

Exposure Limits No exposure standard has been established for this product.

The manufacturer of the solvent has recommended an occupational exposure limit of

100 mg/m3; 17ppm TWA, as total hydrocarbon.

Respiratory ProtectionDo not inhale spray mist.

Personal Protective

Equipment When opening the container, preparing the spray and using the prepared spray, wear

cotton overalls buttoned to the neck and wrist (or equivalent clothing) and a

washable hat, nitrile or elbow-length PVC gloves and face shield or goggles.

Eng. Controls Handle in well ventilated areas, generally natural ventilation is adequate.

Hygiene Measures Wash concentrate from skin and eyes immediately.

After use and before eating, drinking or smoking, wash hands, arms and face

thoroughly with soap and water.

After each day's use, wash contaminated clothing and safety equipment.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance Clear liquid with yellow-orange tinge

Odour Solvent odour

Melting Point Some crystallisation occurs between 0 and -7°C

Solubility in Water Forms an emulsion in water.

0.54mg/l pH4 ; 0.33 mg/l pH7

The product will emulsify in water forming a yellow, milky emulsion.

Boiling Point 183-210°C (for solvent)

Specific Gravity

(H2O=1) 0.988

Vapour Pressure Pendimethalin 4.0mPa @ 25°C; Solvent 0.1kPa @20°C

Volatile Component 50-60%

Partition co-efficient,

n-octanol/water Kow Log P is 5.2 (pH7.0)

Surface Tension 32.5 CP

Flash Point 65°C

Flammability Combustible liquid C1.

Ignition Temperature>450°C (solvent)

Page:3 Material Safety Data Sheet

Infosafe No. 3NU49 July 2004 ISSUED by CRPCARE Issue Date :

STOMP® 330E Herbicide Product Name :

Classified as hazardous according to criteria of NOHSC

Flammable Limits

LEL 0.6 vol% for solvent

Flammable Limits

UEL 0.7 vol% for solvent

Kinematic Viscosity 3 x 10-6 m2/s

10. STABILITY AND REACTIVITY

Hazardous

Polymerization Hazardous polymerisation is not possible.

Hazardous Reaction Keep away from strong oxidising agents, may react violently.

Conditions to Avoid Prolonged reaction with water can cause slow decomposition and the formation of

acid which may attack drums.

If a part open drum is to be stored, ensure that no water has been added to the

drum.

Technical pendimethalin (before formulation) has exhibited exothermic

decomposition at around 200°C. Avoid heating the product to high temperatures.

11. TOXICOLOGICAL INFORMATION

Inhalation High vapour concentrations of the solvent while handling the concentrate are

irritating to the eyes and the respiratory tract, may cause headaches and

dizziness, can be anaesthetic and may have other central nervous system effects.

When applying the product as a spray avoid breathing in spray mists.

Ingestion The concentrate is of low toxicity if swallowed.

If aspirated into the lung, e.g. from vomiting, the presence of solvent may

result in chemical pneumonitis or other lung damage.

Skin The concentrate is not considered a serious toxic hazard.

Prolonged contact with the concentrate can cause defatting of the skin and may

result in dermatitis.

Eye The concentrate may cause irritation after short contact with the eyes, but

permanent damage is not anticipated.

Chronic Effects Based on available data, repeated exposures are not anticipated to cause

additional significant adverse effects.

Reproductive ToxicityData indicates no reproductive effects.

Data indicates no teratogenic effects.

Mutagenicity Data indicates no mutagenic effects.

Carcinogenicity A marked depression in body weight and a statistically significant increase in

benign thyroid tumors (follicular adenomas) were observed at the highest dose

level (5000ppm) in a lifetime (24 month) rat study, not considered to be relevant

to humans. (1)

Acute Toxicity - OralLD50 (rat) >5000 mg/kg for pendimethalin

Acute Toxicity -

Dermal LD50 (rat) >2000 mg/kg for pendimethalin

Acute Toxicity -

Inhalation LC50 (rat) (4hr) >320 mg/l

Eye Irritation Not an eye irritant.

Skin Irritation Not a skin irritant.

Skin Sensitisation Prolonged and repeated skin contact may result in skin sensitisation.

Other Information The Australian Acceptable Daily Intake (ADI) for pendimethalin for a human is 0.1

mg/kg/day, set for the public for daily, lifetime exposure. This is based on the

NOEL of 12 mg/kg/day, the level determined to show no effects during long term

exposure for the most sensitive indicators and the most sensitive species. (Ref:

Comm. Dept. of Health and Ageing, 'ADI List', TGA, August 2003).

Page:4 Material Safety Data Sheet

Infosafe No. 3NU49 July 2004 ISSUED by CRPCARE Issue Date :

STOMP® 330E Herbicide Product Name :

Classified as hazardous according to criteria of NOHSC

12. ECOLOGICAL INFORMATION

Known Harmful

Effects on the

Environment The product is a marine pollutant for sea transport.

Other Precautions Do not contaminate dams, waterways or sewers with this product.

Do not spray in high winds.

Environ. Protection Spray drift can cause damage.

Acute Toxicity - Fish Toxic to fish. LC50 (96hr) for rainbow trout is 0.14 mg/l.

LC50 (96 hr) for bluegill sunfish is 0.2 mg/l.

LC50 (96 hr) for channel catfish is 0.42 mg/l.

Acute Toxicity - Other

Organisms Dietary LC50 (8d) for bobwhite quail is 4187 mg/kg

LD50 for mallard duck is 10388 mg/kg

Bees: Not toxic to bees. LD50 >50 µg/bee.

13. DISPOSAL CONSIDERATIONS

Product Disposal On site disposal of the concentrated product is not acceptable.

Ideally, the product should be used for its intended purpose. If there is a need

to dispose of the product, approach local authorities who hold periodic

collections of unwanted chemicals (ChemCollect).

Container Disposal Triple rinse containers, add rinsate to the spray tank, then offer the container

for recycling/reconditioning, or puncture top, sides and bottom and dispose of in

landfill in accordance with local regulations.

drumMUSTER is the national program for the collection and recycling of empty,

cleaned, non returnable crop production and on-farm animal health chemical

containers. If the label on your container carries the drumMuster symbol, triple

rinse the container, ring your local Council, and offer the container for

collection in the program.

Returnable containers: empty contents fully into application equipment. Replace

cap, close all valves and return to the point of supply for refill or storage.

Puncture or shred and bury containers in local authority landfill.

If no landfill is available, bury the containers below 500mm in a disposal pit

specifically marked and set up for this purpose clear of waterways, desirable

vegetation and tree roots.

Empty containers and product should not be burnt.

14. TRANSPORT INFORMATION

U.N. Number None Allocated

Proper Shipping

Name None Allocated

DG Class None Allocated

Hazchem Code None Allocated

Packing Group None Allocated

Storage and TransportConsidered non dangerous for transport by the Australian Code for the Transport of

Dangerous Goods by Road and Rail.

UN Number (Sea

Transport) 3082

IMO Class/Packing

Group Class 9; Packing Group III

IMO Proper Shipping

Name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.

(contains Pendimethalin)

15. REGULATORY INFORMATION

Risk Phrase R22 Harmful if swallowed.

R65 Harmful: may cause lung damage if swallowed.

Page:5 Material Safety Data Sheet

Infosafe No. 3NU49 July 2004 ISSUED by CRPCARE Issue Date :

STOMP® 330E Herbicide Product Name :

Classified as hazardous according to criteria of NOHSC

Safety Phrase S13 Keep away from food,drink and animal feeding stuffs.

S2 Keep out of reach of children.

S25 Avoid contact with eyes.

S62 If swallowed, do not induce vomiting; seek medical advice immediately and show

this container or label.

Poisons Schedule S5

Hazard Category Harmful

Packaging &

Labelling CAUTION

KEEP OUT OF REACH OF CHILDREN

READ SAFETY DIRECTIONS BEFORE OPENING OR USING

AICS (Australia) All of the components in this product are listed on the Australian Inventory of

Chemical Substances.

16. OTHER INFORMATION

Contact Person/PointNormal Hours: Mr Volker Maier Phone: (03) 9282 1000

After Hours: Shift Supervisor Phone: 1800 033 498

References (1) European Union review report for the active substance Pendimethalin

7477/V1/98 final, dated 13th January 2003.

Revisions HighlightedThe MSDS was reviewed. Minor changes were made to the information.

See also Section 11, Carcinogenicity and References in Section 16.

...End Of MSDS...

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