LOGRAN B-POWER HERBICIDE

Australia - English - APVMA (Australian Pesticides and Veterinary Medicines Authority)

Active ingredient:
BUTAFENACIL; TRIASULFURON
Available from:
SYNGENTA AUSTRALIA PTY LTD
INN (International Name):
butafenacil(200g/kg)+triasulfuron(520g/kg)
Pharmaceutical form:
WATER DISPERSIBLE GRANULE
Composition:
BUTAFENACIL PYRIMIDINE Active 200.0 g/kg; TRIASULFURON UREA-SULFONYL Active 520.0 g/kg
Units in package:
1.5kg; 1kg; 2kg
Class:
A - Agricultural
Manufactured by:
SYNGENTA AUST
Therapeutic group:
WHEAT
Therapeutic area:
HERBICIDE
Therapeutic indications:
AFRICAN TURNIP WEED | AMSINCKIA,YELLOW BURRWEED OR BURR GRASS | ANNUAL OR WIMMERA RYEGRASS | ANNUAL RYEGRASS | BALL MUSTARD | BLACK BINDWEED | BURR MEDIC | CAPEWEED | CHAMOMILE OR MATRICARIA | CLIMBING BUCKWHEAT | CLOVER | COMMON COTULA OR CARROT WEED | CORN GROMWELL, IRONWEED OR SHEEPWEED | CRASSULA - SUPPRESSION | DEADNETTLE | DENSEFLOWER FUMITORY | HEDGE OR WILD MUSTARD | INDIAN HEDGE MUSTARD | LESSER SWINECRESS OR BITTERCRESS | LONDON ROCKET | MEDIC | MEXICAN POPPY - SUPPRESSION | NEW ZEALAND SPINACH | PARADOXA GRASS | PATERSON'S CURSE | PRICKLY LETTUCE | ROUGH POPPY | SHEPHERD'S PURSE | SKELETON WEED - SUPPRESSION | SLENDER CELERY | SMALLFLOWER FUMITORY | SOURSOB OR OXALIS - SUPPRESSION | SOWTHISTLES | SPINY EMEX | STAGGER WEED | STEMLESS THISTLE | THREE CORNERED JACK OR DOUBLEGEE | TURNIP WEED | VARIEGATED THISTLE - SUPPRESSION | VETCHES | VOLUNTEER CHICKPEA | VOLUNTEER FABA BEAN | VOLUNTEER FIELD PEA | WARD'S WEED | WILD OAT | WILD RADISH - SUPPRESSION | WILD RADISH OR RADISH WEED | WILD TURNIP | WIREW
Product summary:
Poison schedule: 0; Withholding period: WHP:GRAZE: DO NOT GRAZE OR CUT FOR STOC K FOOD FOR 7 WEEKS AFTER APPLICATION. HARVEST: NOT REQUIRED WHEN USED AS DIRE CTED.; Host/pest details: WHEAT: [AFRICAN TURNIP WEED, AMSINCKIA,YELLOW BURRWEED OR BURR GRASS, ANNUAL OR WIMMERA RYEGRASS, ANNUAL RYEGRASS, BALL MUSTARD, BLACK BINDWEED, BURR MEDIC, CAPEWEED, CHAMOMILE OR MATRICARIA, CLIMBING BUCKWHEAT, CLOVER, COMMON COTULA OR CARROT WEED, CORN GROMWELL, IRONWEED OR SHEEPWEED, CRASSULA - SUPPRESSION, DEADNETTLE, DENSEFLOWER FUMITORY, HEDGE OR WILD MUSTARD, INDIAN HEDGE MUSTARD, LESSER SWINECRESS OR BITTERCRESS, LONDON ROCKET, MEDIC, MEXICAN POPPY - SUPPRESSION, NEW ZEALAND SPINACH, PARADOXA GRASS, PATERSON'S CURSE, PRICKLY LETTUCE, ROUGH POPPY, SHEPHERD'S PURSE, SKELETON WEED - SUPPRESSION, SLENDER CELERY, SMALLFLOWER FUMITORY, SOURSOB OR OXALIS - SUPPRESSION, SOWTHISTLES, SPINY EMEX, STAGGER WEED, STEMLESS THISTLE, THREE CORNERED JACK OR DOUBLEGEE, TURNIP WEED, VARIEGATED THISTLE - SUPPRESSION, VETCHES, VOLUNTEER CHICKPEA, VOLUNTEER FABA BEAN, VOLUNTEER FIELD PEA, WARD'S WEED, WILD OAT, WILD RADISH - SUPPRESSION, WILD RADISH OR RADISH WEED, WILD TURNIP, WIREWEED, KNOTWEED OR HOGWEED]; For knockdown, pre-emergent and residual control of various weeds prior to planting wheat.See Restraints, PRECAUTIONS, etc. on label. DO NOT apply by aircraft.
Authorization status:
Registered
Authorization number:
53545
Authorization date:
2020-07-01

Label image proudly supplied by

infopest@dpi.qld.gov.au

Page1of7/V4

Date ofIssue:May2010

SAFETY DATASHEET

Section 1:IDENTIFICATIONOF THEMATERIALANDSUPPLIER

Product Name: LOGRAN ®

B-PowerHerbicide

OtherNames: Propershippingname: EnvironmentallyHazardous

Substance,Solid,N.O.S. (ButafenacilandTriasulfuron)

Applicableonlyformarineandairtransport

Product code: A12338A

RecommendedUse: Herbicide fortheknockdown,pre-emergentand

residualcontrolofvariousweedspriorto

planting wheat

CompanyDetails: SyngentaCropProtectionPtyLimited

ABN33002933 717

Address: Level1,2-4Lyonpark Road

MACQUARIEPARKNSW 2113

AUSTRALIA

TelephoneNumber: (02)8876 8444

EmergencyTelephoneNumber:24hours-1800 033111

Section2:HAZARDSIDENTIFICATION

HazardClassification: Notclassified asahazardouschemicalaccording to the

Australian criteria forthe classificationofchemicals

Risk Phrases:

SafetyPhrases:

Section3:COMPOSITION/ INFORMATIONONINGREDIENTS

SUBSTANCE

ChemicalIdentityofPureSubstance:Butafenacil Triasulfuron

Synonym: CGA276854 CGA131036

CASNumber: 134605-64-4 82097-50-5

MIXTURE

ChemicalIdentityof Ingredients CASNo Proportion

(%w/w)

Butafenacil 134605-64-4 200

Triasulfuron 82097-50-5 520

Otheringredientsdetermined nottobehazardous - to 100

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LOGRANB-PowerHerbicide May2010

Section 4:FIRSTAIDMEASURES

DescriptionofNecessary

FirstAidMeasures: In case ofpoisoningbyanyexposure route contactadoctoror

PoisonsInformation Centreon 131126.

Have theproductlabelorSDSwithyouwhen callingorgoing for

treatment.

Ingestion: Ifswallowed,seekmedicaladviceimmediately. DO

NOTinduce vomiting

Eye contact: Rinse immediatelywith plentyofwater,alsounder

the eyelids,foratleast15minutes.Remove

contactlenses. Immediatemedicalattentionis

required

Skincontact: Take offallcontaminated clothingimmediately.

Wash offimmediatelywithplentyofwater.Ifskin

irritationpersists,calla doctor.Wash contaminated

clothingbefore re-use

Inhalation: Remove to fresh air.Ifbreathingisirregularor

stopped,administerartificialrespiration.Keep

patientwarmand atrest.CalladoctororPoisons

Information Centreimmediately

PoisoningSymptoms: Poisoning symptomsin laboratoryanimalswerenon-specific

MedicalAdvice: Treatsymptomatically

Section5:FIREFIGHTINGMEASURES

SuitableExtinguishingMedia: Smallfires

Use waterspray,alcohol-resistantfoam,drychemicalorcarbon

dioxide. DONOTuse a solidwaterstreamasit mayscatter

and spread fire

Large fires

Use alcohol-resistantfoamorwaterspray. DONOTuse a solid

waterstreamasitmayscatterandspreadfire

HazardsfromCombustion

Products: Astheproductcontainscombustible organiccomponents,fire

willproducedenseblacksmoke containing hazardousproducts

ofcombustion (seeSection10).Exposure to decomposition

productsmaybea hazard to health

SpecialProtective Precautions

andEquipment forFireFighters: Wearfullprotective clothing and self-contained breathing

apparatus. DONOTallowrun-offfromfirefightingtoenter

drainsorwatercourses.Coolclosed containersexposed to fire

withwaterspray

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LOGRANB-PowerHerbicide May2010

Section6:ACCIDENTALRELEASEMEASURES

EmergencyProcedures: In case ofspillageitisimportanttotake allstepsnecessaryto

Avoideye and skin contact

Avoidcontamination ofwaterways

MethodsandMaterialsfor

Containment andCleanUp: Procedureforspill

(1)Keep allbystandersaway

(2)Wearfulllength clothingand PVCgloves

(3)Reposition anyleaking containersso asto minimise

leakage

(4)Fora productspill:Sweepgranuleconcentrateinto a pile.

Fora prepared sprayspill:Damand absorb spillwithan

absorbentmaterial(e.g.sand orsoil).

(5)Shovelintodrums

(6)Ifagriculturalsoilhasbeencontaminatedconsiderthe

optionofremoving and disposing ofthe contaminatedsoil

to allowvegetation togrowand to stop further

contamination.

(7)Disposalofthe materialwilldependupon the extentofthe

spill

Forquantitiesup to50 kg ofproductburyin a secure

landfill site

Forquantitiesgreaterthan50 kg seekadvice fromthe

manufacturer(use emergencycontactnumberbelow)

before attempting disposal. Contain in a securelocation

untildisposalmethodisestablished

(8)Decontaminate spillareawith detergentandwaterand

rinsewith the smallestvolume ofwaterpracticable

(9)Clean allcontaminatedequipmentbyrinsing inadilute

solutionof1litre sodiumhypochlorite(0.2%)solution,to

200 litresofwater

Section7:HANDLINGANDSTORAGE

PrecautionsforSafeHandling: Willirritate the eyesand skin. Avoid contactwitheyesand skin.

Ifproductgetsonskin,immediatelywash areawith soap and

water.Wash handsafteruse.When opening container,

preparingandusing the prepared spray,wear:

cottonoverallsbuttoned tothe neckandwrist(orequivalent

clothing)

awashable hat

elbowlengthPVCgloves.

Aftereach day’susewashglovesand contaminated clothing.

ConditionsforSafeStorage: Storeinthe closed,originalcontainerina dry,cool,well

ventilated area outofdirectsunlight.

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LOGRANB-PowerHerbicide May2010

Section8:EXPOSURECONTROLS/ PERSONALPROTECTION

ALWAYSREADAND FOLLOWTHELABELINSTRUCTIONSAND WARNINGS

NationalExposureStandards: No exposure standardallocated

SyngentaExposureStandards: Component Exposure limit Value type

Butafenacil 10mg/m 3

TWA

Triasulfuron 3mg/m 3 TWA

Biological LimitValues: Nobiologicallimitsallocated

EngineeringControls: No specialrequirements. Productisusedoutdoors

PersonalProtectiveEquipment:Willirritate the eyesand skin. Avoid contactwitheyesand skin.

Ifproductgetson skin,immediatelywashareawith soap and

water.Wash handsafteruse.When opening container,

preparingandusing the prepared spray,wear:

cottonoverallsbuttoned tothe neckandwrist(orequivalent

clothing)

awashable hat

elbowlengthPVCgloves.

Aftereach day’susewashglovesand contaminated clothing.

Section9:PHYSICALANDCHEMICALPROPERTIES

Appearance: Lightbeige tobrown

granules BoilingPoint/Range: Notavailable

Odour: Weak Freezing/MeltingPoint: Notavailable

pH: 4-8at1%w/v Solubility: Notavailable

VapourPressure: Notavailable Bulk Density: 0.4-0.6g/cm 3

Fllamability

(solid,gas): NothighlyflammableExplosive Properties: Notexplosive

OxidisingProperties: Notoxidising

MinimumIgnition

Temperature: 440°C Corrosiveness: Notcorrosive

Dust ExplosionC;ass Formsflammabledust

clouds

MinimumIgnition

Energy: 10–30 mJ Burningnumber: 2at20°C

2 at100°C

Section10: STABILITYAND REACTIVITY

Chemical Stability: Stableundernormalconditions

ConditionstoAvoid: Noneknown

Incompatible Materials: None known

HazardousDecomposition

Products: Combustion orthermaldecompositionwillevolve toxicand

irritantvapours

Hazardous Reactions: None known

Hazardouspolymerizationdoesnotoccur

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LOGRANB-PowerHerbicide May2010

Section11: TOXICOLOGICALINFORMATION

HealthEffectsfromLikelyRoutesofExposure:

Acute: Oral toxicity: LOWTOXICITY

Testson ratsindicate thisproducthasa lowtoxicityfollowing

single dosesofa similarformulation

= >2,000mg/kg)

Dermaltoxicity: LOWTOXICITY

Testsonratsindicate thisproducthasa lowtoxicityfollowing

skin contactwitha similarformulation

=>2,000mg/kg)

Inhalation: LOWTOXICITY

Testson ratsindicate thisproductisnotharmfuldueto

inhalation ofactive ingredients

(4hour)=>5,185mg/L air,triasulfuron)

(4 hour)=>5,100 mg/L air,butafenacil)

Skinirritation: NON IRRITANT

Eyeirritation: NON IRRITANT

Sensitisation: NOTASENSITISER

Chronic: Butafenacilandtriasulfurontechnicalhasbeenextensivelytested on laboratory

mammalsand intesttube systems.No evidencewasobtainedofmutagenic,

carcinogenicorteratogeniceffects.

Section12:ECOLOGICALINFORMATION

The followinginformationwasderived fromcomponents:

Ecotoxicity: Toxicity tofish: Slightlytoxictofish

Oncorhynchusmykiss(rainbowtrout):

=20mg/L,96 h

Toxicitytodaphnia

and otheraquatic

invertebrates: Slightlytoxictoaquaticinvertebrates

Daphniamagna(Waterflea):

>43mg/L,48 h

Toxicitytoalgae: Veryhighlytoxictoalgae

Pseudokirchneriella subcapitata(green algae):

=0.0125mg/L,72h

Persistence and

Degradability: Butafenacilispersistentin soilorwater

Triasulfuron ispersistentinsoil orwater

Mobility Butafenacilhaslowmobilityin soil

Triasulfuronhasmediummobilityin soil

Bioaccumulative

Potential: Butafenacildoesnotbioaccumulate

Triasulfuron hasalowpotentialto bioaccumulate

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LOGRANB-PowerHerbicide May2010

Section13: DISPOSALCONSIDERATIONS

DisposalMethodsand

Containers: Rinse containersbefore disposal.Add rinsingsto spraytank.DONOT

disposeofundilutedchemicalson site.Disposeofata localauthority

landfill.Ifnolandfillisavailable,burythe containersbelow500 mmin a

disposalpitspecificallymarked and setup forthispurpose clearof

waterways,desirablevegetation and tree roots.Emptycontainersand

productshould notbe burnt.

SpecialPrecautions

forLandfillor

Incineration: Notapplicable

Section 14: TRANSPORT INFORMATION

LAND TRANSPORT

ADG Notadangerousgood inAustralia

UN Number: None allocated PackingGroup: None allocated

UNProperShipping

Name: None allocated SpecialPrecautions

for User: None allocated

Class: None allocated HazchemCode: None allocated

SubsidiaryRisk: Noneallocated

SEATRANSPORT

IMDG

UN Number: 3077 SubsidiaryRisk: None allocated

UNProperShipping

Name: EnvironmentallyHazardous

Substance,Solid, N.O.S.

(ButafenacilandTriasulfuron) PackingGroup: III

Class: 9 MarinePollutant: Marine pollutant

AIR TRANSPORT

IATA-DGR

UN Number: 3077 SubsidiaryRisk: None allocated

UNProperShipping

Name: EnvironmentallyHazardous

Substance,Solid, N.O.S.

(Butafenaciland Triasulfuron) PackingGroup: III

Class: 9

Section15: REGULATORYINFORMATION

APVMAProductNumber: 53545

PoisonsSchedule(SUSDP): Exempt

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LOGRANB-PowerHerbicide May2010

Section 16: OTHERINFORMATION

Dateof preparationorlast revision: May2010

Sourceof Data:The information providedin thisSDSissourced fromSyngenta internalstudies

whichhave beenconducted according to Regulatoryrequirementsincluding OECDandCIPAC

GuidelinesandECDirectives.Acomprehensivepackageoftoxicologicalandenvironmentaldata for

the active ingredientsofthisproducthasbeen submitted tothegovernmenthealth and environment

authoritiesand hasbeen evaluatedbyexperttoxicologistsand environmentalscientists.

Note:Thisproduct isaregisteredagriculturalchemicalandmust,therefore,beusedin

accordancewiththecontainerlabeldirections

CONTACTPOINT:RegulatoryAffairsManager,Syngenta Crop ProtectionPty Limited

(02)88768444

24HOURSEMERGENCYCONTACT:1800 033111

ThisMaterialSafetyDataSheetsummarisesourbestknowledge ofthe healthandsafetyhazard

information ofthe productand howto safelyhandleand use the productin theworkplace. Eachuser

shouldreadthisSDSandconsidertheinformationinthecontextofhowtheproductwillbehandled

andusedin theworkplace includinginconjunctionwithotherproducts.

Ifclarificationorfurtherinformationisneededtoensurethatanappropriateriskassessmentcanbe

made,the usershould contactthiscompany.

®

Registered trademarkofaSyngenta Group Company

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