FARMOZ MANCOZEB 750 DF AGRICULTURAL FUNGICIDE

Australia - English - APVMA (Australian Pesticides and Veterinary Medicines Authority)

Active ingredient:
MANCOZEB
Available from:
ADAMA Australia Pty Limited
INN (International Name):
mancozeb(750g/kg)
Pharmaceutical form:
DRY FLOWABLE
Composition:
MANCOZEB CARBAMATE-DITHIOCARBAMATE Active 750.0 g/kg
Units in package:
10kg; 20kg; 25kg
Class:
A - Agricultural
Manufactured by:
ADAMA AUST
Therapeutic group:
ALMOND | APPLE | BANANA | BEETROOT | BROAD BEAN | BROCCOLI | BRUSSELS SPROUTS | CABBAGE | CAPSICUM OR PEPPER | CARNATION | CARRO
Therapeutic area:
FUNGICIDE
Therapeutic indications:
ALTERNARIA LEAF BLIGHT OR SPOT BLIGHT | ALTERNARIA LEAF SPOT - ALTERNARIA SPP. | ALTERNARIA SPOT | ANGULAR LEAF SPOT - P. GRISEOLA | ANTHRACNOSE | ANTHRACNOSE - COLLETOTRICHUM SPP. | ANTHRACNOSE ON BEAN | ANTHRACNOSE ON COLE CROP/BRASSSICA | ANTHRACNOSE ON CUCURBIT | ANTHRACNOSE ON MANGO | ANTHRACNOSE OR RING SPOT ON LETTUCE | ASCOCHYTA BLIGHT | BITTER ROT | BLACK PIT | BLACK PIT - SUPPRESSION | BLACK SPOT | BLACK SPOT ON APPLES | BLACK SPOT ON CITRUS | BLACK SPOT ON PEARS | BLUE MOULD ON TOBACCO | BOTRYTIS | BROWN CITRUS RUST MITE | BROWN ROT | BROWN SPOT ON PASSIONFRUIT | BROWN SPOT ON TOBACCO | CERCOSPORA LEAF SPOT | CERSOSPORA LEAF BLIGHT OR SPOT | CHOCOLATE SPOT ON BEAN | CITRUS BUD MITE | CITRUS RUST MITE OR MAORI MITE | CORDANA LEAF SPOT - SUPPRESSION | DOWNY MILDEW | DOWNY MILDEW ON ALLIUM (ONION, GARLIC) | DOWNY MILDEW ON COLE CROP/BRASSICA | DOWNY MILDEW ON CUCURBIT | DOWNY MILDEW ON GRAPE | DOWNY MILDEW ON LETTUCE | EARLY BLIGHT OR TARGET BLACKSPOT | FLY SPECK | FRECKLE OR SCAB ON STONE FRUIT | FRO
Product summary:
Poison schedule: 5; Withholding period: WHP: HARVEST GREEN BEANS CARROTS CE LERY COLE CROPS CUCURBITS GARLIC ON ION PEAS, SOYBEANS TOMATOES: DO N OT HARVEST FOR 7 DAYS AFTER APPLICATION . ALMONDS BEETROOT CAPSICUM COTTON, FENNEL LETTUCE PEANUTS POME FRUIT, RHUBARB SILVERBEET SPINACH STONE FRU IT: DO NOT HARVEST FOR 14 DAYS AFTER APPLICATION CUSTARD APPLE MANGOES P ASSIONFRUIT, PAWPAWS (PAPAYA): DO N OT HARVEST FOR 1 DAY AFTER APPLICATION. GREEN LEGUMES PULSE CROPS -GREEN CRO PS for fresh consumption DO NOT HARVE ST FOR 7 DAYS AFTER APPLICATION -GRAIN CROPS for dry beans: DO NOT HARVEST FOR 4 WEEKS AFTER APPLICATION GRAPEVIN ES: DO NOT HARVEST FOR 30 DAYS AFTER APPLICATION POPPIES: DO NOT HARVEST FOR 49 DAYS AFTER APPLICATION BANANAS CITRUS POTATOES TOBACCO: NOT REQU IRED WHEN USED AS DIRECTED. GRAZING CO TTON: DO NOT ALLOW LIVESTOCK TO GRAZE COTTON CROP STUBBLE OR GIN TRASH TH AT HAS BEEN TREATED WITH MANCOZEB 750 DF AGRICULTURAL FUNGICIDE. GREEN LE GUMES PEANUTS PULSE CROPS for dry bea ns: DO NOT GRAZE OR CUT FOR STOCKFOOD FOR 14 DAYS AFTER LAST APPLICATION PAPAYA: DO NOT USE OR SUPPLY TREATED PAPAYA INCLUDING LEAVES FOR STOCK FOO D. SOYBEANS: DO NOT GRAZE OR CUT FOR STOCKFOOD FOR 14 DAYS AFTER LAST APP LICATION.; Host/pest details: ALMOND: [BROWN ROT]; APPLE: [BITTER ROT, BLACK SPOT ON APPLES, FLY SPECK, RIPE FRUIT SPOT, RIPE OR TARGET SPOT ON POME-PEZICULA SPP, SOOTY BLOTCH ON APPLE, PEAR OR CITRUS]; BANANA: [BLACK PIT, BLACK PIT - SUPPRESSION, CORDANA LEAF SPOT - SUPPRESSION, FRUIT SPECKLE - SUPPRESSION (D. TORULOSA, LEAF SPECKLE - SUPPRESSION, LEAF SPOT OR YELLOW SIGATOKA ON BANANA]; BEETROOT: [CERSOSPORA LEAF BLIGHT OR SPOT, DOWNY MILDEW]; BROAD BEAN: [ANGULAR LEAF SPOT - P. GRISEOLA, ANTHRACNOSE, ANTHRACNOSE ON BEAN, ASCOCHYTA BLIGHT, BLACK SPOT, CHOCOLATE SPOT ON BEAN, GREY MOULD - BOTRYTIS DIGITATUM, LEAF BLIGHT (A. FABAE) - SUPPRESSION, RUST, RUST - URANYCES VICIAE-FABAE]; BROCCOLI: [ALTERNARIA SPOT, ANTHRACNOSE ON COLE CROP/BRASSSICA, DOWNY MILDEW ON COLE CROP/BRASSICA, RING SPOT ON BRASSICA/COLE CROP]; BRUSSELS SPROUTS: [ALTERNARIA SPOT, ANTHRACNOSE ON COLE CROP/BRASSSICA, DOWNY MILDEW ON COLE CROP/BRASSICA, RING SPOT ON BRASSICA/COLE CROP]; CABBAGE: [ALTERNARIA SPOT, ANTHRACNOSE ON COLE CROP/BRASSSICA, DOWNY MILDEW ON COLE CROP/BRASSICA, RING SPOT ON BRASSICA/COLE CROP]; CAPSICUM OR PEPPER: [TARGET SPOT]; CARNATION: [ALTERNARIA LEAF BLIGHT OR SPOT BLIGHT, RUST]; CARROT: [ALTERNARIA LEAF BLIGHT OR SPOT BLIGHT, CERSOSPORA LEAF BLIGHT OR SPOT]; CAULIFLOWER: [ALTERNARIA SPOT, ANTHRACNOSE ON COLE CROP/BRASSSICA, DOWNY MILDEW ON COLE CROP/BRASSICA, RING SPOT ON BRASSICA/COLE CROP]; CELERY: [SEPTORIA LEAF SPOT - SEPTORIA SPP.]; CHERRY: [BROWN ROT, FRECKLE OR SCAB ON STONE FRUIT, RUST, SHOTHOLE]; CHICKPEA: [ASCOCHYTA BLIGHT, BLACK SPOT, CHOCOLATE SPOT ON BEAN, GREY MOULD - BOTRYTIS DIGITATUM, RUST]; CHRYSANTHEMUM OR TANACETUM: [BOTRYTIS, RUST, SEPTORIA LEAF SPOT - SEPTORIA SPP.]; CITRUS: [BLACK SPOT ON CITRUS, BROWN CITRUS RUST MITE, CITRUS BUD MITE, CITRUS RUST MITE OR MAORI MITE]; COTTON: [ALTERNARIA LEAF SPOT - ALTERNARIA SPP.]; CUCUMBER: [ANTHRACNOSE ON CUCURBIT, DOWNY MILDEW ON CUCURBIT, GUMMY STEM BLIGHT ON CUCURBIT]; CUCURBIT: [SEPTORIA SPOT]; CUSTARD APPLE: [PSEUDOCERCOSPORA FRUIT SPOT]; FABA BEAN: [ASCOCHYTA BLIGHT, BLACK SPOT, CHOCOLATE SPOT ON BEAN, GREY MOULD - BOTRYTIS DIGITATUM, RUST, SHOTHOLE]; FENNEL: [LEAF BLIGHT]; FERN: [BOTRYTIS]; FIELD PEA: [ASCOCHYTA BLIGHT, BLACK SPOT, CHOCOLATE SPOT ON BEAN, GREY MOULD - BOTRYTIS DIGITATUM, RUST]; FLOWER: [SEPTORIA LEAF SPOT - SEPTORIA SPP.]; GARLIC: [DOWNY MILDEW ON CUCURBIT, PURPLE BLOTCH]; GLADIOLUS: [BOTRYTIS, RUST, SEPTORIA LEAF SPOT - SEPTORIA SPP.]; GRAPEVINE: [BLACK SPOT, DOWNY MILDEW ON GRAPE, LEAF SPOT, PHOMOPSIS CANE, PHOMOPSIS CANE - DEAD ARM]; GREEN BEAN: [ANGULAR LEAF SPOT - P. GRISEOLA, ANTHRACNOSE, RUST]; LENTIL: [ASCOCHYTA BLIGHT, BLACK SPOT, CHOCOLATE SPOT ON BEAN, GREY MOULD - BOTRYTIS DIGITATUM, RUST]; LETTUCE: [ALTERNARIA SPOT, ANTHRACNOSE OR RING SPOT ON LETTUCE, DOWNY MILDEW ON LETTUCE, RING SPOT, SEPTORIA LEAF SPOT - SEPTORIA SPP.]; LUPIN: [ANTHRACNOSE, ASCOCHYTA BLIGHT, BLACK SPOT, CHOCOLATE SPOT ON BEAN, GREY MOULD - BOTRYTIS DIGITATUM, RUST]; MANGO: [ANTHRACNOSE ON MANGO]; MELON: [ANTHRACNOSE ON CUCURBIT, DOWNY MILDEW ON CUCURBIT, GUMMY STEM BLIGHT ON CUCURBIT]; NECTARINE: [BROWN ROT]; ONION: [DOWNY MILDEW ON ALLIUM (ONION, GARLIC), PURPLE BLOTCH]; PASSIONFRUIT: [ANTHRACNOSE - COLLETOTRICHUM SPP., BROWN SPOT ON PASSIONFRUIT, SEPTORIA LEAF SPOT - SEPTORIA SPP.]; PAWPAW: [BLACK SPOT]; PEA: [ANTHRACNOSE, CHOCOLATE SPOT ON BEAN, DOWNY MILDEW ON CUCURBIT, LEAF BLIGHT (A. FABAE) - SUPPRESSION, RUST - URANYCES VICIAE-FABAE]; PEANUT: [CERCOSPORA LEAF SPOT, RUST ON PEANUT]; PEAR: [BITTER ROT, BLACK SPOT ON PEARS, FLY SPECK, PEAR SCAB, RIPE FRUIT SPOT, RIPE OR TARGET SPOT ON POME-PEZICULA SPP, SOOTY BLOTCH ON APPLE, PEAR OR CITRUS]; POPPY: [DOWNY MILDEW]; POTATO: [EARLY BLIGHT OR TARGET BLACKSPOT, LATE OR IRISH BLIGHT ON TOMATO OR POTATO]; POTATO SEED PIECE: [FUSARIUM SEEDPIECE ROT]; PULSE CROP: [ASCOCHYTA BLIGHT, BLACK SPOT, CHOCOLATE SPOT ON BEAN, GREY MOULD - BOTRYTIS DIGITATUM, RUST]; PUMPKIN: [ANTHRACNOSE ON CUCURBIT, DOWNY MILDEW ON CUCURBIT, GUMMY STEM BLIGHT ON CUCURBIT, SEPTORIA LEAF SPOT - SEPTORIA SPP.]; RHUBARB: [DOWNY MILDEW, RUST]; ROCKMELON OR CANTALOUP: [ANTHRACNOSE ON CUCURBIT, DOWNY MILDEW ON CUCURBIT, GUMMY STEM BLIGHT ON CUCURBIT]; ROSE: [BLACK SPOT]; SHRUB: [SEPTORIA LEAF SPOT - SEPTORIA SPP.]; SILVER BEET: [CERSOSPORA LEAF BLIGHT OR SPOT, DOWNY MILDEW]; SOYBEAN: [SOYBEAN RUST]; SPINACH: [CERSOSPORA LEAF BLIGHT OR SPOT, DOWNY MILDEW]; SQUASH: [ANTHRACNOSE ON CUCURBIT, DOWNY MILDEW ON CUCURBIT, GUMMY STEM BLIGHT ON CUCURBIT]; STONE FRUIT (SEE LABEL FOR EXCEPTIONS): [BROWN ROT, FRECKLE OR SCAB ON STONE FRUIT, RUST, SHOTHOLE]; TOBACCO: [BLUE MOULD ON TOBACCO, BROWN SPOT ON TOBACCO, FROG EYE SPOT ON TOBACCO]; TOMATO: [ANTHRACNOSE - COLLETOTRICHUM SPP., EARLY BLIGHT OR TARGET BLACKSPOT, GREY LEAF SPOT - STEMPHYLIUM SOLANI, LATE OR IRISH BLIGHT ON TOMATO OR POTATO, LEAF MOULD OF TOMATO, PHOMA RIPE ROT]; TURF: [FUNGAL DISEASES - FUSARIUM SPP., HELMINTHOSPORIUM DISEASE, RHIZOCTONIA]; VETCH: [ASCOCHYTA BLIGHT, BLACK SPOT, CHOCOLATE SPOT ON BEAN, GREY MOULD - BOTRYTIS DIGITATUM, RUST]; ZUCCHINI: [ANTHRACNOSE ON CUCURBIT, DOWNY MILDEW ON CUCURBIT, GUMMY STEM BLIGHT ON CUCURBIT]; Poison schedule: 5; Withholding period: ; Host/pest details: ALMOND: [BROWN ROT]; APPLE: [BITTER ROT, BLACK SPOT ON APPLES, FLY SPECK, RIPE FRUIT SPOT, RIPE OR TARGET SPOT ON POME-PEZICULA SPP, SOOTY BLOTCH ON APPLE, PEAR OR CITRUS]; BANANA: [BLACK PIT, BLACK PIT - SUPPRESSION, CORDANA LEAF SPOT - SUPPRESSION, FRUIT SPECKLE - SUPPRESSION (D. TORULOSA, LEAF SPECKLE - SUPPRESSION, LEAF SPOT OR YELLOW SIGATOKA ON BANANA]; BEETROOT: [CERSOSPORA LEAF BLIGHT OR SPOT, DOWNY MILDEW]; BROAD BEAN: [ANGULAR LEAF SPOT - P. GRISEOLA, ANTHRACNOSE, ANTHRACNOSE ON BEAN, ASCOCHYTA BLIGHT, BLACK SPOT, CHOCOLATE SPOT ON BEAN, GREY MOULD - BOTRYTIS DIGITATUM, LEAF BLIGHT (A. FABAE) - SUPPRESSION, RUST, RUST - URANYCES VICIAE-FABAE]; BROCCOLI: [ALTERNARIA SPOT, ANTHRACNOSE ON COLE CROP/BRASSSICA, DOWNY MILDEW ON COLE CROP/BRASSICA, RING SPOT ON BRASSICA/COLE CROP]; BRUSSELS SPROUTS: [ALTERNARIA SPOT, ANTHRACNOSE ON COLE CROP/BRASSSICA, DOWNY MILDEW ON COLE CROP/BRASSICA, RING SPOT ON BRASSICA/COLE CROP]; CABBAGE: [ALTERNARIA SPOT, ANTHRACNOSE ON COLE CROP/BRASSSICA, DOWNY MILDEW ON COLE CROP/BRASSICA, RING SPOT ON BRASSICA/COLE CROP]; CAPSICUM OR PEPPER: [TARGET SPOT]; CARNATION: [ALTERNARIA LEAF BLIGHT OR SPOT BLIGHT, RUST]; CARROT: [ALTERNARIA LEAF BLIGHT OR SPOT BLIGHT, CERSOSPORA LEAF BLIGHT OR SPOT]; CAULIFLOWER: [ALTERNARIA SPOT, ANTHRACNOSE ON COLE CROP/BRASSSICA, DOWNY MILDEW ON COLE CROP/BRASSICA, RING SPOT ON BRASSICA/COLE CROP]; CELERY: [SEPTORIA LEAF SPOT - SEPTORIA SPP.]; CHERRY: [BROWN ROT, FRECKLE OR SCAB ON STONE FRUIT, RUST, SHOTHOLE]; CHICKPEA: [ASCOCHYTA BLIGHT, BLACK SPOT, CHOCOLATE SPOT ON BEAN, GREY MOULD - BOTRYTIS DIGITATUM, RUST]; CHRYSANTHEMUM OR TANACETUM: [BOTRYTIS, RUST, SEPTORIA LEAF SPOT - SEPTORIA SPP.]; CITRUS: [BLACK SPOT ON CITRUS, BROWN CITRUS
Authorization status:
Stopped
Authorization number:
48049
Authorization date:
2020-07-01

FARMOZ MANCOZEB 750 DF AGRICULTURAL FUNGICIDE

PAGE 1 OF 5

DATE: 13/07/12

FILENAME: 48049/56804_RPL_V2

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RELEVANT LABEL PARTICULARS

For the control of certain fungus diseases of

field crops, vegetables, fruit, tobacco, turf

and ornamentals as specified in the

Directions for Use table.

www.farmoz.com.au

CROP

DISEASE

RATE/

HECTARE

RATE/

100 L

CRITICAL COMMENTS

WHP

FIELD CROPS

Cotton -

Pima var. only

Alternaria Leaf Spot

2.5 kg

To maximise control ensure thorough coverage of all

plant surfaces. Begin applications as soon as disease

symptoms appear. Repeat before each infection period

but no later than 7 to 10 days after the last application.

DO NOT apply more than 4 sprays per season.

14 days (H)

DIRECTIONS FOR USE

Restraints:

DO NOT use on hydroponically grown crops.

DO NOT use on container, greenhouse or glasshouse grown crops.

DO NOT incorporate this product with an Integrated Mite Control program.

ACTIVE CONSTITUENT: 750 g/kg MANCOZEB

Mancozeb

750 DF

CAUTION

KEEP OUT OF REACH OF CHILDREN

READ SAFETY DIRECTIONS BEFORE OPENING OR USING

GROUP

FUNGICIDE

M3

A G R I C U LT U R A L F U N G I C I D E

Peanuts

Cercospora Leaf Spot,

Rust

1.7 to 2.2 kg

Apply at 10 to 14 day intervals commencing when disease

symptoms first appear. Use the higher rate and shorter

intervals during weather conditions favourable to disease

development.

14 days (H)

14 days (G)

Pulse crops

(grown for dry

beans), including

but not limited to:

Broadbeans,

Chickpeas,

Faba beans,

Field peas, Lentils,

Lupins, Vetches

Ascochyta Blight,

Black Spot,

Botrytis Grey Mould,

Chocolate Spot,

Rust

1.0 to 2.2 kg

Spray when leaves, flowers or pods on plants first show

signs of infection and weather conditions are likely to

remain humid or wet and favour disease development.

If disease pressure is severe and conditions favour

spread of disease repeat sprays at 2 to 3 weeks to

protect new growth and developing pods. Use higher rate

for dense crops and if disease is severe and repeat more

frequently if severe disease persists.

For improved coverage add Wetspray

1000

10-15 mL/100 L spray solution.

4 weeks (H)

14 days (G)

Tobacco

Blue Mould,

Brown Spot,

Frog Eye Leaf Spot

2.2 kg

200 g

Spray at 7 day intervals following a spray at

transplanting. Spray to wet seedlings without run-off.

Start spraying when plants are 1.5 cm across then twice

weekly. Field treatments: Apply at 7 day intervals

commencing 10 days after transplanting and ceasing 7 to

10 days before the first harvest.

Seed Bed Treatments: As a substitute for control of Blue

Mould by fumigation, apply the product when seedlings

are 1.5 cm across and then repeat twice weekly. Wet the

seedlings evenly without run-off.

required

Faba beans

Cercospora

Lupins

Anthracnose

CONTENTS: 10kg, 20 kg, 25 kg

RLP

APPROVED

Infopest

Verified

FARMOZ MANCOZEB 750 DF AGRICULTURAL FUNGICIDE

PAGE 2 OF 5

DATE: 13/07/12

FILENAME: 48049/56804_RPL_V2

PRINT 100% ON A4 PAPER

RELEVANT LABEL PARTICULARS

CROP

DISEASE

RATE/

HECTARE

RATE/

100 L

CRITICAL COMMENTS

WHP

VEGETABLES

Beans, green

Volume of application for ground equipment apply 100

L/ha; for aircraft apply at least 30 L/ha.

For improved coverage add Wetspray 1000

10-20 mL/100 L spray solution.

DO NOT apply more than 4 applications per season.

Broadbeans

(including

faba beans)

Peas

(including

sugar snap and

snow peas)

Anthracnose,

Rust

1.7 to 2.2 kg

150 to 200 g

Apply when disease symptoms first appear and repeat at

7 to 10 day intervals. Use the higher rate and shorter

spray interval during weather conditions favourable to

disease development. Spray when leaves, flowers or

pods on most plants first show signs of infection and

weather conditions are likely to remain humid or wet and

favour disease development.

7 days (H)

14 days (G)

Chocolate Spot

Botrytis fabae

1.7 to 2.5 kg

If disease pressure is severe and conditions favour

spread of disease, repeat the spray treatment at 2 to 3

week intervals to protect new growth and developing

pods. Use higher rate for dense crops and if disease is

severe. Repeat more frequently if severe disease

persists.

Rust (

Uromyces Peas

viciae-fabae

Angular Leaf Spot

Suppression of Leaf Blight

Ascochyta fabae

Peas

Downy Mildew

1.7 to 2.2 kg

150 to 200 g

Apply when disease symptoms first appear and repeat at

7 to 10 day intervals. Use the higher rate and shorter

spray interval during weather conditions favourable to

disease development.

7 days (H)

Capsicum

Target Spot

2 to 3 kg

150 to 200 g

Spray at first sign of disease. Repeat at 7 to 10 day

intervals.

DO NOT apply more than 8 applications per season.

14 days (H)

Carrots

Alternaria Leaf Spot,

Cercospora Leaf Spot

1.7 to 2.2 kg

150 to 200 g

Spray at first sign of disease, then at 7 to 10 day intervals

or more frequently depending on blight conditions.

DO NOT apply more than 4 applications per season.

7 days (H)

Celery

Septoria Leaf Spot

(Leaf Blight)

1.7 to 2.2 kg

150 to 200 g

Spray at first sign of disease. Repeat at 7 to 10 day

intervals.

DO NOT apply more than 4 applications per season.

7 days (H)

COLE CROPS

Broccoli,

Brussels Sprouts,

Cabbage,

Cauliflower

Alternaria Spot,

Anthracnose,

Downy Mildew,

Ring Spot

1.7 to 2.2 kg

150 to 200 g

Spray at first sign of disease. Repeat at 7 to 10 day

intervals.

DO NOT apply more than 8 applications per season.

7 days (H)

CUCURBITS

Canteloupe,

Cucumber, Melons,

Pumpkin, Squash,

Zucchini

Anthracnose,

Downy Mildew,

Gummy Stem Blight,

Septoria Spot

1.7 to 2.2 kg

150 to 200 g

Apply when disease symptoms first appear and then

repeat at 7 to 10 day intervals. Use higher rate and

shorter intervals during weather conditions favourable to

disease development.

DO NOT apply more than 8 applications per season.

7 days (H)

Fennel (Tas only)

Leaf Blight

Cercosporidium

2.2 kg

Apply as a ground spray if disease symptoms are present

in November, allowing for one repeat treatment 10 to 14

days later. Aerial application may be required in

prolonged wet periods.

14 days (H)

Potatoes

Early Blight (Target Spot),

Late Blight (Irish Blight)

1.7 to 2.2 kg

150 to 200 g

Apply when disease symptoms first appear and then

repeat at 7 to 10 day intervals. Use higher rate and

shorter intervals during weather conditions favourable to

disease development.

DO NOT apply more than 8 applications per season.

required

Tomatoes

Anthracnose,

Early Blight (Target Spot),

Grey Leaf Spot,

Late Blight (Irish Blight),

Leaf Mould (

Fulvia fulva

Phoma Rot

2 to 3 kg

150 to 200 g

Spray at first sign of disease. Repeat at 7 to 10 day

intervals.

DO NOT apply to tomato seedlings before transplanting.

7 days (H)

Lettuce

Anthracnose,

Downy Mildew,

Septoria Leaf Spot

1.7 to 2.2 kg

150 to 200 g

Apply when disease symptoms first appear and then

repeat at 7 to 10 day intervals. Use higher rate and

shorter intervals during weather conditions favourable to

disease development.

14 days (H)

Rhubarb

Downy Mildew,

Rust

1.7 to 2.2 kg

150 to 200 g

14 days (H)

Spinach,

Silverbeet,

Beetroot

Cercospora Leaf Spot,

Downy Mildew

1.7 to 2.2 kg

150 to 200 g

14 days (H)

Onion and Garlic

Downy Mildew,

Purple Blotch

2.2 to 3.5 kg

150 to 200 g

7 days (H)

Soybeans

Rust

2.2 kg

Commence spraying at first sign of disease and then at

7 to 10 day intervals while warm, rainy weather

conditions prevail.

7 days (H)

14 days (G)

Poppies

Downy Mildew

2.5 kg

Apply as a protectant spray when weather conditions

favour disease development. Repeat spray on 14 day

intervals if conditions persist.

7 weeks (H)

FARMOZ MANCOZEB 750 DF AGRICULTURAL FUNGICIDE

PAGE 3 OF 5

DATE: 13/07/12

FILENAME: 48049/56804_RPL_V2

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RELEVANT LABEL PARTICULARS

CROP

DISEASE

RATE/

HECTARE

RATE/

100 L

CRITICAL COMMENTS

WHP

Black Pit,

Cordana Leaf Spot,

Fruit Speckle,

Leaf Speckle

2.2 kg

200 g

North Queensland, WA, NT: Apply every two weeks

during the wet season. Extend to three weeks after this

and then four to five weeks during the drier months

returning to three weeks prior to the next wet season.

* For concentrate spraying using misters, refer to

Concentrate Spraying under APPLICATION to

determine appropriate rate.

ORNAMENTALS

Carnations

Alternaria Leaf Spot,

Rust

150 to 200 g

Apply when disease symptoms first appear and then

repeat at 7 to 14 day intervals.

Roses: DO NOT apply more than 8 applications per

season.

Turf

Fusarium,

Rhizoctonia,

Helminthosporium

200 to 250

g/100 sq.

metres

Spray in sufficient water for adequate coverage. Apply

every 7 days throughout susceptible periods.

DO NOT feed grass clippings from treated areas to

poultry or animals.

Flowers, Shrubs

Septoria Leaf Spot

150 to 200 g

Ferns

Botrytis Leaf Spot

75 to 100 g

Gladioli

Chrysanthemums

Grey Mould (

Botrytis

Septoria Leaf Spot, Rust

150 to 200 g

Roses

Black Spot

150 to 200 g

Spray at weekly intervals during flowering and then at

two week intervals until near harvest.

Anthracnose

Colletotrichum musae

2.2 kg + 3.5

to 4 L

miscible

summer oil

200 g plus

600 mL

miscible

summer oil

FRUIT

Bananas

Leaf Spot (Sigatoka)

Mycosphaerella musicola)

2.2 to 4.5 kg

(NSW 2.2

kg) + 3.5 to

4.2 L

summer oil

or miscible

summer oil

200 g plus

600 mL

summer oil

Apply when weather conditions favour disease outbreak.

Repeat treatments in accordance with locally

recommended spray schedules. Use sufficient water to

ensure coverage.

New South Wales:

Ground Application:

Apply at three week intervals from

December or January until May.

Aerial Application: Apply at 7 to 10 day intervals from

December or January until May.

South Queensland: Apply at three week intervals from

December or January until May.

required

Spray at first sign of rust or citrus mite (usually December to May).

Brown Citrus Mite,

Citrus Rust Mite

Spray at bud burst and repeat 7 to 10 days later.

Phomopsis Cane and

Leaf Spot

150 to 200 g

Spray at weekly intervals during flowering then fortnightly near

harvest.

Anthracnose

(NSW only)

200 g plus

600 mL

miscible

summer oil

Apply when blossom malformation is observed, usually February.

Citrus Bud Mite

Citrus

Black Spot

required

200 g

On heavy Soil: Add 250 mL polyphase summer oil per 100 L. Spray at

8 and 15 weeks following a Bordeaux (5-5-100) spray at petal fall.

On light Soil: Add 250 mL polyphase summer oil per 100 L plus 12 mL

Wetspray 1000 according to the adjuvant label per 100 L. Spray at 6

and 13 weeks following a Bordeaux (3.5-3.5-100) spray at petal fall.

Queensland, NT: Add 600 mL polyphase summer oil or miscible

summer oil per 100 L and spray at six to twelve weeks after a copper

spray at 0.5 to 0.75 petal fall.

Custard apples

Pseudocercospora Fruit

Spot

1 day (H)

200 g

DO NOT apply during flowering.

Apply at 3 to 4 week intervals from first fruit set until harvest. Apply at

2 week intervals in wet cloudy weather.

Mangoes

Anthracnose

Colletotrichum

gloeosporioides

1 day

200 g

Spray at weekly intervals during flowering then monthly until harvest.

Use sufficient water for good coverage.

DO NOT apply as a tank mix with Suprathion

400 EC as phytotoxicity

may result.

Passionfruit

Brown Spot

Alternaria passiflorae

Septoria Spot

1 day

150 g

Apply at 10 to 14 day intervals from October to May and every 21 to

28 days for remainder of year.

OTHER FRUITS

Grapevines

Black Spot,

Downy Mildew

30 days

200 g

For Black Spot control spray commencing at bud burst. Repeat every

14 days. If Downy Mildew is expected begin spray application at

10 to 15 cm stage of shoot growth. Continue the program at intervals

of 10 to 14 days until disease threat is over.

TREE AND VINE CROPS

In the following table, all rates are given for dilute spraying.

For concentrate spraying, refer to the Application section.

CRITICAL COMMENTS

For all tree and vine crops in this table: Apply by dilute or

concentrate spraying equipment. For concentrate spraying, refer to

the Application Section. Apply the same total amount of product to

the target crop whether applying this product by dilute or

concentrate spraying methods.

CROP

DISEASE

RATE/

100 L

WHP

FARMOZ MANCOZEB 750 DF AGRICULTURAL FUNGICIDE

PAGE 4 OF 5

DATE: 13/07/12

FILENAME: 48049/56804_RPL_V2

PRINT 100% ON A4 PAPER

RELEVANT LABEL PARTICULARS

STONE FRUITS

Almonds

Apricots

Cherries

Nectarines

Peaches

Plums (except

Wilson plums)

Brown Rot,

Freckle,

Rust,

Shot Hole

14 days

150 to 200 g

Spray at early bloom (1-10%) mid to full bloom (50-100%), petal and

shuck fall, then at intervals of 14 days.

TREE AND VINE CROPS –

continued

CRITICAL COMMENTS

CROP

DISEASE

RATE/

100 L

WHP

NOT TO BE USED FOR ANY PURPOSE, OR IN ANY MANNER, CONTRARY TO THIS LABEL UNLESS AUTHORISED

UNDER APPROPRIATE LEGISLATION.

WITHHOLDING PERIOD:

HARVEST

GREEN BEANS, CARROTS, CELERY, COLE CROPS, CUCURBITS, GARLIC, ONION, PEAS, SOYBEANS, TOMATOES:

DO NOT HARVEST FOR 7 DAYS AFTER APPLICATION.

ALMONDS, BEETROOT, CAPSICUM, COTTON, FENNEL, LETTUCE, PEANUTS, POME FRUIT, RHUBARB, SILVERBEET, SPINACH, STONE FRUIT:

DO NOT HARVEST FOR 14 DAYS AFTER APPLICATION.

CUSTARD APPLE, MANGOES, PASSIONFRUIT, PAWPAWS (PAPAYA):

DO NOT HARVEST FOR 1 DAY AFTER APPLICATION.

GREEN LEGUMES, PULSE CROPS

– GREEN CROPS for fresh consumption:

DO NOT HARVEST FOR 7 DAYS AFTER APPLICATION.

– GRAIN CROPS for dry beans:

DO NOT HARVEST FOR 4 WEEKS AFTER APPLICATION.

GRAPEVINES:

DO NOT HARVEST FOR 30 DAYS AFTER APPLICATION.

POPPIES:

DO NOT HARVEST FOR 49 DAYS AFTER APPLICATION.

BANANAS, CITRUS, POTATOES, TOBACCO:

NOT REQUIRED WHEN USED AS DIRECTED.

GRAZING

COTTON:

DO NOT ALLOW LIVESTOCK TO GRAZE COTTON CROP, STUBBLE OR GIN TRASH THAT

HAS BEEN TREATED WITH MANCOZEB 750 DF AGRICULTURAL FUNGICIDE.

GREEN LEGUMES, PEANUTS, PULSE CROPS for dry beans: DO NOT GRAZE OR CUT FOR STOCKFOOD FOR 14 DAYS AFTER LAST APPLICATION.

PAPAYA:

DO NOT USE OR SUPPLY TREATED PAPAYA INCLUDING LEAVES FOR STOCK FOOD.

SOYBEANS:

DO NOT GRAZE OR CUT FOR STOCKFOOD FOR 14 DAYS AFTER LAST APPLICATION.

GENERAL INSTRUCTIONS

Before opening, carefully read Directions for Use, Precautionary

Statements, Safety Directions and First Aid.

MANCOZEB 750 DF Agricultural Fungicide is a protectant fungicide for

the control of certain fungus diseases in many crops. For best results,

apply product thoroughly to the treated crop in a regular spray

program.

FUNGICIDE RESISTANCE WARNING

FARMOZ

56804MANCOZEB

Agricultural Fungicide is a member of the

Multi-site activity group of fungicides. For fungicide resistance

management MANCOZEB 750 DF is a Group M3 fungicide. Some

naturally occurring individual fungi resistant to MANCOZEB 750 DF and

other Group M3 fungicides may exist through normal genetic variability

in any fungal population. The resistant individuals can eventually

dominate the fungal population if these fungicides are used repeatedly.

These resistant fungi will not be controlled by MANCOZEB 750 DF or

other Group M3 fungicides, thus resulting in a reduction in efficacy

and possible yield loss.

Since the occurrence of resistant fungi is difficult to detect prior to

use, FARMOZ Pty. Ltd. accepts no liability for the losses that may result

from the failure of MANCOZEB 750 DF to control resistant fungi.

WARNING – BANANAS

Under certain conditions the surface of recently emerged fruit is

particularly prone to marking damage from spray applications where a

petroleum spray oil is included. Where applications containing a

petroleum spray oil will be made to very rapidly growing fruit in hot

conditions with strong direct sunlight, it is recommended that bunches

be bagged prior to spraying to minimise risk of fruit marking.

MIXING

Partly fill spray tank with water and agitate while adding this product

slowly. Continue agitation after filling and during spraying to ensure

spray mixture is uniform and to prevent product setting out. For low

volume or aerial application prepare a slurry or premix when adding to

the spray tank. Additional insecticides, fungicides, surfactants, etc.

should be added after the product is in suspension. Rinse out spray

tank pumps and nozzles at the end of the day.

SURFACTANTS

The addition of a surfactant such as Wetspray 1000 will improve initial

spray deposits, fungicide redistribution and weatherability. Refer to

manufacturers label instructions for further details.

APPLICATION

This product may be applied as a high volume dilute spray to fruit tree

and vine crops and some row crops. Apply sufficient spray volume to

wet all leaf surfaces to the point of run-off. The spray equipment

should be adjusted so that the spray is evenly distributed, thoroughly

covering all plant surfaces.

Dilute Spraying

Use a sprayer designed to apply high volumes of water up to the

point of run-off and matched to the crop being sprayed.

Set up and operate the sprayer to achieve even coverage throughout

the crop canopy. Apply sufficient water to cover the crop to the point

of run-off. Avoid excessive run-off.

The required water volume may be determined by applying different

test volumes, using different settings on the sprayer, from industry

guidelines or expert advice.

Add the amount of product specified in the Directions for Use table

for each 100 L of water. Spray to the point of run-off.

The required dilute spray volume will change and the sprayer set up

and operation may also need to be changed as the crop grows.

The spray volume will vary according to the treated crop and should

be increased when spraying large or dense plants to ensure thorough

coverage. The spray volume should also be increased throughout the

growing season as the crop increases in size. Suitable spray volumes

for mature crops are as follows:

Vine crops

– 200 to 1100 L/ha.

Pome and Stone Fruit

– 1100 to 4000 L/ha.

Citrus

– 4000 to 8000 L/ha.

GROUP

FUNGICIDE

M3

Pawpaws

(Papaya)

Black Spot

1 day (H)

200 g

Add mancozeb plus a wetting agent at 10 to 14 day intervals during

periods conducive to disease.

POME FRUITS

Apples

Pears

Apple Scab (Black Spot),

Bitter Rot, Fly Speck,

Pear Scab, Ripe Fruit Spot,

Sooty Blotch, Target Spot

14 days

150 to 200 g

Spray at 7 to 14 day intervals following green tip copper spray.

Use higher rate and shorter spray interval during prolonged wet

conditions. Product not suitable for use in integrated mite control

programs (Tas only).

FARMOZ MANCOZEB 750 DF AGRICULTURAL FUNGICIDE

PAGE 5 OF 5

DATE: 13/07/12

FILENAME: 48049/56804_RPL_V2

PRINT 100% ON A4 PAPER

RELEVANT LABEL PARTICULARS

Concentrate Spraying

Use a sprayer designed and set up for concentrate spraying (that is a

sprayer which applies water volumes less than those required to

reach the point of run-off) and matched to the crop being sprayed.

Set up and operate the sprayer to achieve even coverage throughout

the crop canopy using your chosen water volume.

Determine an appropriate dilute spray volume (See Dilute Spraying

above) for the crop canopy. This is needed to calculate the

concentrate mixing rate.

The mixing rate for concentrate spraying can be then calculated in

the following way:

EXAMPLE ONLY

1. Dilute spray volume as determined above: For example 1000 L/ha

2. Your chosen concentrate spray volume: For example 250 L/ha

3. The concentration factor in this example is: 4 X (i.e. 1000 L/250 L = 4)

4. If the dilute label rate is 250 g/100 L, then the concentrate rate

becomes 4 x 250, that is 1 kg/100 L of concentrate spray.

The chosen spray volume, amount of product per 100 L of water, and

the sprayer set up and operation may need to be changed as the crop

grows.

For further information on concentrate spraying, users are advised to

consult relevant industry guidelines, undertake competency training

and follow industry Best Practices.

Concentrate and ground application sprays

This product may be applied as a concentrate spray through low

volume air blast equipment or as a ground application through spray

booms. Adjust the rate to ensure that the correct amount is applied per

hectare from the particular equipment used. Use the higher rate on

larger plants and when weather conditions favour the development of

disease.

Aerial application

This product may be applied by agricultural aircraft. Use at least 30 to

50 litres spray mixture per hectare. Reference should be made to the

Directions for Use table for the correct rate of application in specific

crop situations.

SPRAY TIMING

Apply treatments when weather conditions favour disease outbreak

and continue until the threat of disease has passed. Repeated

applications are necessary to protect new plant growth and as

conditions favour disease development, reduce the spray interval.

COMPATIBILITY

This product may be harmful to

Typhlodromus pyri

and should not be

used in orchards where integrated control methods are practiced.

Most commonly used agricultural fungicides and insecticides are

compatible with MANCOZEB 750 DF, however reference should be

made to the other manufacturer's recommendations before preparing

tank mixes. This product is not compatible with Lime Sulphur. With

Mango crops this product should not be mixed with Suprathion

400 EC

as the tank mix may cause phytotoxicity.

Bananas

Foliar fertilisers:

Before applying mixtures of foliar fertilisers to this

product, seek advice from the manufacturer of the product and/or

conduct a jar test with the product(s), with MANCOZEB 750 DF and the

appropriate volume of water to test physical compatibility. Foliar

fertilisers can cause damage to banana leaves and fruit. Test mixtures

over a small area initially to check for crop safety. Since FARMOZ Pty.

Ltd. cannot guarantee the quality of other products mixed with

MANCOZEB 750 DF, the user accepts all responsibility for the

performance of these mixtures.

PRECAUTIONS

DO NOT use human flaggers/markers unless they are protected by

engineering controls such as enclosed cabs.

Re-Entry:

DO NOT allow entry into treated areas until spray has dried.

When prior entry is necessary, wear personal protective equipment as

specified in the Safety Directions. Clothing must be laundered after

each day’s use.

PROTECTION OF WILDLIFE, FISH, CRUSTACEANS AND

ENVIRONMENT

Dangerous to fish. DO NOT contaminate streams, rivers or waterways

with the chemical or used containers.

STORAGE AND DISPOSAL

Store in the closed, original container, in a well ventilated area away

from children, animals, food, feedstuffs, seed and fertilisers. DO NOT

store for prolonged periods in direct sunlight. DO NOT allow container

to become wet or over-heated in storage. Users are reminded that this

product should be used before the stated expiry date. Single rinse

before disposal. Add rinsings to spray tank. Puncture or shred and

deliver empty packaging to an approved waste management facility. If

an approved waste management facility is not available, bury the

empty packaging 500 mm below the surface in a disposal pit

specifically marked and set up for this purpose clear of waterways,

desirable vegetation and tree roots, in compliance with relevant Local,

State or Territory government regulations. DO NOT burn empty

containers or product.

SAFETY DIRECTIONS

May irritate the eyes and skin. Repeated exposure may cause allergic

disorders. Avoid contact with eyes and skin. DO NOT inhale dust.

Wash hands after use. When opening the container and preparing

spray wear cotton overalls, over normal clothing, buttoned to the neck

and wrist, a washable hat, elbow-length PVC gloves, goggles, and

disposable dust face mask covering mouth and nose. When using the

prepared spray wear cotton overalls, over normal clothing, buttoned to

the neck and wrist, a washable hat and elbow-length PVC gloves. After

each day’s use, wash gloves face shield or goggles and contaminated

clothing.

FIRST AID

If poisoning occurs, contact a Doctor or Poisons Information Centre.

Phone Australia 131126. Avoid giving alcohol.

MATERIAL SAFETY DATA SHEET

Additional information is listed in the material safety data sheet

(MSDS). A material safety data sheet for MANCOZEB 750 DF

is available from FARMOZ on request. Call Customer Service on (02)

9431 7800.

CONDITIONS OF SALE: The use of FARMOZ MANCOZEB 750 DF Agricultural Fungicide

being beyond the control of the manufacturer, no warranty expressed or implied is

given by FARMOZ Pty. Ltd., regarding its suitability, fitness or efficiency for any

purpose for which it is used by the buyer, whether in accordance with the directions

or not and FARMOZ Pty. Ltd. accepts no responsibility for any consequence

whatsoever resulting from the use of this product.

Registered trademarks of a Makhteshim-Agan Company

UN No 3077

ENVIRONMENTALLY HAZARDOUS

SUBSTANCE, SOLID, N.O.S.

(CONTAINS MANCOZEB)

PACKING GROUP: III

HAZCHEM CODE: 2X

MISCELLANEOUS

DANGEROUS

GOODS

9

Farmoz Pty. Ltd.

ABN 55 050 328 973

Suite 1, Level 4, Building B,

207 Pacific Highway

St Leonards NSW 2065 Australia

Tel: (02) 9431 7800 Fax: (02) 9431 7700

APVMA Approval No: 48049/56804

Batch No.

Date of Manufacture

Product Name: Farmoz Mancozeb 750 DF Agricultural Fungicide

Page: 1 of 6

This revision issued: August, 2012

SAFETY DATA SHEET

Issued by: Farmoz Pty Ltd

Phone: (02)9431 7800 (office hours)

Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)

Section 1 - Identification of The Material and Supplier

Farmoz Pty Ltd, Suite 1, Level 4, Building B

207 Pacific Highway St Leonards, NSW 2068

ACN 050 328 973

Telephone (02)9431 7800 (office hours)

Emergency 1800 024 973 (24 hours)

Fax (02)9431 7700

Chemical nature:

Mancozeb is a dithiocarbamate compound.

Trade Name:

Farmoz Mancozeb 750 DF Agricultural Fungicide

Product Use:

Agricultural fungicide for use as described on the product label.

Creation Date:

July, 2003

This version issued:

August, 2012

and is valid for 5 years from this date.

Section 2 - Hazards Identification

Statement of Hazardous Nature

This product is classified as:

Hazardous according to the criteria of SWA Australia.

Not subject to the ADG Code when transported in Australia by Road or Rail in packages 500kg(L) or less; or IBCs

(refer to SP AU01). However if transported by Air or Sea, this provision does not apply. Then the product is classed

as Dangerous (Class 9 Environmentally Hazardous) by IATA and IMDG respectively. See details below and in

Section 14 of this MSDS.

Risk Phrases:

R37, R43, R51. Irritating to respiratory system. May cause sensitisation by skin contact. Toxic to

aquatic organisms.

Safety Phrases:

S22, S28, S38, S60, S61. Do not breathe dust. After contact with skin, wash immediately with

plenty of soap and water. In case of insufficient ventilation, wear suitable respiratory equipment. This material and its

container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions or

safety data sheets.

SUSMP Classification:

ADG Classification:

Class 9: Miscellaneous dangerous goods.

UN Number:

3077, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.

Emergency Overview

Physical Description & colour

: Yellow powder.

Odour:

Mild sulfurous odour.

Major Health Hazards:

Mancozeb is practically nontoxic via the oral route with reported oral LD

of greater than

5000 mg/kg to greater than 11,200 mg/kg in rats. Via the dermal route it is practically nontoxic as well, with reported

dermal LD

values of greater than 10,000 mg/kg in rats, and greater than 5000 mg/kg in rabbits. It is a mild skin

irritant and sensitizer, and a mild to moderate eye irritant in rabbits. Workers with occupational exposure to Mancozeb

have developed sensitization rashes.

Potential Health Effects

See section 11 for Chronic exposure studies.

Inhalation

Short term exposure:

Available data indicates that this product is not harmful. However product is a severe

inhalation irritant. Symptoms may include headache, extreme irritation of nose and throat and increased secretion of

mucous in the nose and throat. Other symptoms may also become evident, and may last long after exposure has

ceased.

Skin Contact:

Short term exposure:

Classified as a potential sensitiser by skin contact. Exposure to a skin sensitiser, once

sensitisation has occurred, may manifest itself as skin rash or inflammation, and in some individuals this reaction can

be severe. In addition product may be irritating, but is unlikely to cause anything more than mild transient discomfort.

Eye Contact:

Short term exposure

: This product may be irritating to eyes, but is unlikely to cause anything more than mild

transient discomfort.

Ingestion:

Short term exposure

: This product is unlikely to cause any irritation problems in the short or long term.

Product Name: Farmoz Mancozeb 750 DF Agricultural Fungicide

Page: 2 of 6

This revision issued: August, 2012

SAFETY DATA SHEET

Issued by: Farmoz Pty Ltd

Phone: (02)9431 7800 (office hours)

Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)

Carcinogen Status:

SWA:

No significant ingredient is classified as carcinogenic by SWA.

NTP:

No significant ingredient is classified as carcinogenic by NTP.

IARC:

No significant ingredient is classified as carcinogenic by IARC.

Section 3 - Composition/Information on Ingredients

I

I

I

n

n

n

g

g

g

r

r

r

e

e

e

d

d

d

i

i

i

e

e

e

n

n

n

t

t

t

s

s

s

C

C

C

A

A

A

S

S

S

N

N

N

o

o

o

C

C

C

o

o

o

n

n

n

c

c

c

,

,

,

%

%

%

T

T

T

W

W

W

A

A

A

(

(

(

m

m

m

g

g

g

/

/

/

m

m

m

3

3

3

)

)

)

S

S

S

T

T

T

E

E

E

L

L

L

(

(

(

m

m

m

g

g

g

/

/

/

m

m

m

3

3

3

)

)

)

Mancozeb

8018-01-7

not set

not set

Other non hazardous ingredients

secret

to 100

not set

not set

This is a commercial product whose exact ratio of components may vary slightly. Minor quantities of other non

hazardous ingredients are also possible.

The TWA exposure value is the average airborne concentration of a particular substance when calculated over a normal 8 hour working day for a 5

day working week. The STEL (Short Term Exposure Limit) is an exposure value that should not be exceeded for more than 15 minutes and should

not be repeated for more than 4 times per day. There should be at least 60 minutes between successive exposures at the STEL. The term "peak "is

used when the TWA limit, because of the rapid action of the substance, should never be exceeded, even briefly.

Section 4 - First Aid Measures

General Information:

You should call The Poisons Information Centre if you feel that you may have been poisoned, burned or irritated by

this product. The number is 13 1126 from anywhere in Australia (0800 764 766 in New Zealand) and is available at all

times. Have this MSDS with you when you call.

Inhalation:

If inhalation occurs, contact a Poisons Information Centre, or call a doctor at once. Remove source of

contamination or move victim to fresh air. If breathing is difficult, oxygen may be beneficial if administered by trained

personnel, preferably on a doctor's advice. DO NOT allow victim to move about unnecessarily. Symptoms of

pulmonary oedema can be delayed up to 48 hours after exposure.

Skin Contact:

If poisoning occurs, contact a Poisons Information Centre, or call a doctor at once. Irritation is

unlikely. However, if irritation does occur, flush with lukewarm, gently flowing water for 5 minutes or until chemical is

removed. If in doubt obtain medical advice.

Eye Contact:

No effects expected. If irritation does occur, flush contaminated eye(s) with lukewarm, gently flowing

water for 5 minutes or until the product is removed. Obtain medical advice if irritation becomes painful or lasts more

than a few minutes.

Ingestion:

First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor.

Section 5 - Fire Fighting Measures

Fire and Explosion Hazards

: There is no risk of an explosion from this product under normal circumstances if it is

involved in a fire. This product, if scattered, may form flammable or explosive dust clouds in air.

Fire decomposition products from this product may be toxic if inhaled. Take appropriate protective measures.

Extinguishing Media

: Water fog or fine spray is the preferred medium for large fires. Try to contain spills, minimise

spillage entering drains or water courses.

Fire Fighting

: If a significant quantity of this product is involved in a fire, call the fire brigade. There is little danger of

a violent reaction or explosion if significant quantities of this product are involved in a fire. Recommended personal

protective equipment is full fire kit and and breathing apparatus.

Flash point

:

Not flammable.

Upper Flammability Limit:

No data.

Lower Flammability Limit:

No data.

Autoignition temperature:

No data.

Flammability Class:

No data.

Section 6 - Accidental Release Measures

Accidental release

: In the event of a major spill, prevent spillage from entering drains or water courses. Wear full

protective chemically resistant clothing including face mask, face shield, gauntlets and self contained breathing

apparatus. See above under Personal Protection regarding Australian Standards relating to personal protective

equipment. Suitable materials for protective clothing include rubber, PVC. Stop leak if safe to do so, and contain spill.

Sweep up and shovel or collect recoverable product into labelled containers for recycling or salvage, and dispose of

promptly. After spills, wash area preventing runoff from entering drains. If a significant quantity of material enters

drains, advise emergency services. Full details regarding disposal of used containers, spillage and unused material

may be found on the label. If there is any conflict between this MSDS and the label, instructions on the label prevail.

Product Name: Farmoz Mancozeb 750 DF Agricultural Fungicide

Page: 3 of 6

This revision issued: August, 2012

SAFETY DATA SHEET

Issued by: Farmoz Pty Ltd

Phone: (02)9431 7800 (office hours)

Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)

Ensure legality of disposal by consulting regulations prior to disposal. Thoroughly launder protective clothing before

storage or re-use. Advise laundry of nature of contamination when sending contaminated clothing to laundry.

Section 7 - Handling and Storage

Handling

: Keep exposure to this product to a minimum, and minimise the quantities kept in work areas. Check

Section 8 of this MSDS for details of personal protective measures, and make sure that those measures are followed.

The measures detailed below under "Storage" should be followed during handling in order to minimise risks to

persons using the product in the workplace. Also, avoid contact or contamination of product with incompatible

materials listed in Section 10.

Storage

: This product is a Scheduled Poison. Observe all relevant regulations regarding sale, transport and storage

of this class of poison. Store packages of this product in a cool place. Store in the closed original container in a dry,

cool, well-ventilated area out of direct sunlight. Make sure that the product does not come into contact with

substances listed under "Materials to avoid" in Section 10. Check packaging - there may be further storage

instructions on the label.

Section 8 - Exposure Controls and Personal Protection

The following Australian Standards will provide general advice regarding safety clothing and equipment:

Respiratory equipment: AS/NZS 1715, Protective Gloves: AS 2161, Occupational Protective Clothing: AS/NZS 4501

set 2008, Industrial Eye Protection: AS1336 and AS/NZS 1337, Occupational Protective Footwear: AS/NZS2210.

SWA Exposure Limits

TWA (mg/m

3

)

STEL (mg/m

3

)

Exposure limits have not been established by SWA for any of the significant ingredients in this product.

The ADI for Mancozeb is set at 0.006mg/kg/day. The corresponding NOEL is set at 0.6mg/kg/day. ADI means

Acceptable Daily Intake and NOEL means No-observable-effect-level. Values taken from Australian ADI List, Sept

2011.

Ventilation:

No special ventilation requirements are normally necessary for this product. However make sure that

the work environment remains clean and that dusts are minimised.

Eye Protection:

Eye protection such as protective glasses or goggles is recommended when this product is being

used.

Skin Protection:

If you believe you may have a sensitisation to this product or any of its declared ingredients, you

should prevent skin contact by wearing impervious gloves, clothes and, preferably, apron. Make sure that all skin

areas are covered. See below for suitable material types.

Protective Material Types:

We suggest that protective clothing be made from the following materials: rubber,

PVC.

Respirator:

If there is a significant chance that dusts are likely to build up in the area where this product is being

used, we recommend that you use a suitable Dust Mask.

Section 9 - Physical and Chemical Properties:

Physical Description & colour

Yellow powder.

Odour:

Mild sulfurous odour.

Boiling Point:

Not applicable.

Freezing/Melting Point:

Mancozeb decomposes without melting at 192-204°C

Volatiles:

No specific data. Expected to be low at 100°C.

Vapour Pressure:

Negligible at normal room temperatures.

Vapour Density:

No data.

Specific Gravity:

No data.

Water Solubility:

Dispersible.

pH:

No data.

Volatility:

No data.

Odour Threshold:

No data.

Evaporation Rate:

No data.

Coeff Oil/water distribution

No data

Autoignition temp:

No data.

Section 10 - Stability and Reactivity

Reactivity:

This product is unlikely to react or decompose under normal storage conditions. However, if you have

any doubts, contact the supplier for advice on shelf life properties.

Conditions to Avoid:

None known. Store in the closed original container in a dry, cool, well-ventilated area out of

direct sunlight.

Product Name: Farmoz Mancozeb 750 DF Agricultural Fungicide

Page: 4 of 6

This revision issued: August, 2012

SAFETY DATA SHEET

Issued by: Farmoz Pty Ltd

Phone: (02)9431 7800 (office hours)

Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)

Incompatibilities:

strong acids, strong bases, strong oxidising agents.

Fire Decomposition:

Carbon dioxide, and if combustion is incomplete, carbon monoxide and smoke. Nitrogen and

its compounds, and under some circumstances, oxides of nitrogen. Occasionally hydrogen cyanide gas. Oxides of

sulfur (sulfur dioxide is a respiratory hazard) and other sulfur compounds. Most will have a foul odour. Water.

manganese and zinc compounds. Carbon monoxide poisoning produces headache, weakness, nausea, dizziness,

confusion, dimness of vision, disturbance of judgment, and unconsciousness followed by coma and death. Hydrogen

cyanide poisoning signs and symptoms are weakness, dizziness, headache, nausea, vomiting, coma, convulsions,

and death. Death results from respiratory arrest. Hydrogen cyanide gas acts very rapidly; symptoms and death can

both occur quickly.

Polymerisation:

This product is unlikely to undergo polymerisation processes.

Section 11 - Toxicological Information

Toxicity:

An information profile for Mancozeb is available at http://extoxnet.orst.edu/pips/ghindex.html

Acute toxicity: Mancozeb is practically nontoxic orally with reported oral LD50 of more than 5000 to more than

11,200 mg/kg in rats. Dermally it is also practically nontoxic, with reported dermal LD50 values of more than 10,000

mg/kg in rats, and more than 5000 mg/kg in rabbits. It is a mild skin irritant and sensitizer, and a mild to moderate eye

irritant in rabbits. Workers with occupational exposure to Mancozeb have developed sensitization rashes.

Chronic toxicity: No toxicological effects were apparent in rats fed dietary doses of 5 mg/kg/day in a long-term study.

Impaired thyroid function was observed as lower iodine uptake after 24 months in dogs fed doses of 2.5 and 25

mg/kg/day of Mancozeb, but not in those dogs fed 0.625 mg/kg/day. A major toxicological concern in situations of

chronic exposure is the generation of ethylenethiourea (ETU) in the course of Mancozeb metabolism, and as a

contaminant in Mancozeb production. ETU may also be produced when EBDCs are used on stored produce, or

during cooking. In addition to having the potential to cause goiter, a condition in which the thyroid gland is enlarged,

this metabolite has produced birth defects and cancer in experimental animals.

Reproductive effects: In a three-generation rat study with Mancozeb at a dietary level of 50 mg/kg/day there was

reduced fertility but no indication of embryotoxic effects. It is unlikely that Mancozeb will produce reproductive effects

in humans under normal circumstances.

Teratogenic effects: No teratogenic effects were observed in a three-generation rat study with Mancozeb at a dietary

level of 50 mg/kg/day. Developmental abnormalities of the body wall, central nervous system, eye, ear, and

musculoskeletal system were observed in experimental rats which were given a very high dose of 1320 mg/kg of

Mancozeb on the 11th day of pregnancy. In view of the conflicting evidence, the teratogenicity of Mancozeb is

properly known.

Mutagenic effects: Mancozeb was found to be mutagenic in one set of tests, while in another it did not cause

mutations. Mancozeb is thought to be similar to Maneb, which was not mutagenic in the Ames Test. Data regarding

the mutagenicity are inconclusive but suggest that Mancozeb is either not mutagenic or weakly mutagenic.

Carcinogenic effects: No data are available regarding the carcinogenic effects of Mancozeb. While studies of other

EBDCs indicate they are not carcinogenic, ETU (a Mancozeb metabolite), has caused cancer in experimental animals

at high doses. Thus, the carcinogenic potential of Mancozeb is not currently known.

Organ toxicity: The main target organ of Mancozeb is the thyroid gland; the effects may be due to the metabolite

ETU.

Fate in humans and animals: Mancozeb is rapidly absorbed into the body from the gastrointestinal tract, distributed

to various target organs, and almost completely excreted in 96 hours. ETU is the major Mancozeb metabolite of

toxicological significance, with carbon disulfide as a minor metabolite.

Section 12 - Ecological Information

Effects on birds: Mancozeb is not harmful to birds, with reported -day dietary LC50 values in bobwhite quail and

mallard ducklings of greater than 10,000 ppm. The 10-day dietary LC50 values of 6400 ppm and 3200 ppm are

reported for mallard ducks and Japanese quail, respectively.

Effects on aquatic organisms: Mancozeb is moderately to highly toxic to fish and aquatic organisms.

Effects on other organisms: Mancozeb is not toxic to honeybees.

Environmental Fate:

Breakdown in soil and groundwater: Mancozeb is of low soil persistence, with a reported field half-life of 1 to 7

days. Mancozeb rapidly and spontaneously degrades to ETU in the presence of water and oxygen. ETU may persist

for longer, on the order of 5 to 10 weeks. Because Mancozeb is practically insoluble in water, it is unlikely to infiltrate

groundwater.

Breakdown in water: Mancozeb degrades in water with a half-life of 1 to 2 days in slightly acidic to slightly alkaline

conditions.

Breakdown in vegetation: When used as directed, Mancozeb is not poisonous to plants.

Section 13 - Disposal Considerations

Disposal:

Instructions concerning the disposal of this product and its containers are given on the registered label.

These should be carefully followed. Special help is available for the disposal of Agricultural Chemicals. The product

Product Name: Farmoz Mancozeb 750 DF Agricultural Fungicide

Page: 5 of 6

This revision issued: August, 2012

SAFETY DATA SHEET

Issued by: Farmoz Pty Ltd

Phone: (02)9431 7800 (office hours)

Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)

label will give general advice regarding disposal of small quantities, and how to cleanse containers. However, for help

with the collection of unwanted rural chemicals, contact ChemClear 1800 008 182 http://www.chemclear.com.au/ and

for help with the disposal of empty drums, contact DrumMuster http://www.drummuster.com.au/ where you will find

contact details for your area.

Section 14 - Transport Information

Not subject to the ADG Code when transported by Road or Rail in Australia, in packages 500kg(L)

or less; or IBCs, but classed as Dangerous by IATA and IMDG when carried by Air or Sea transport

(see details below).

ADG Code:

3077, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.

Hazchem Code:

Special Provisions:

179, 274, AU01

Limited quantities:

ADG 7 specifies a Limited Quantity value of 5 kg for this class of product.

Dangerous Goods Class:

Class 9: Miscellaneous Dangerous Goods.

Packaging Group:

Packaging Method:

P002, IBC08, LP02

Class 9 Miscellaneous Dangerous Goods shall not be loaded in the same vehicle or packed in the same freight

container with Dangerous Goods of Class 1 (Explosives).

Section 15 - Regulatory Information

AICS:

All of the significant ingredients in this product are compliant with NICNAS regulations.

Section 16 - Other Information

Much of the Information in this MSDS came from Extoxnet, a Pesticide Information Project of Cooperative Extension

Offices of Cornell University, Oregon State University, the University of Idaho, and the University of California at Davis

and the Institute for Environmental Toxicology, Michigan State University.

This MSDS contains only safety-related information. For other data see product literature.

Acronyms:

ADG Code

Australian Code for the Transport of Dangerous Goods by Road and Rail, 7th Edition

AICS

Australian Inventory of Chemical Substances

CAS number

Chemical Abstracts Service Registry Number

Hazchem Number

Emergency action code of numbers and letters that provide information to emergency

services especially firefighters

IARC

International Agency for Research on Cancer

SWA

Safe Work Australia, formerly ASCC and NOHSC

NOS

Not otherwise specified

NTP

National Toxicology Program (USA)

R-Phrase

Risk Phrase

SUSMP

Standard for the Uniform Scheduling of Medicines & Poisons

UN Number

United Nations Number

Contact Points:

Call Farmoz on (02)9431 7800

Fax: (02)9431 7700 and ask for the technical manager.

Police and Fire Brigade:

Dial 000

Emergency contact:

1800 024 973 (24 hours)

If ineffective:

Dial Poisons Information Centre

(

13 1126 from anywhere in Australia)

The information contained in this Material Safety Data Sheet is provided in good faith and is believed to be correct at the date

hereof. However, it is expected that individuals receiving the information will exercise their independent judgement in determining

its appropriateness for a particular purpose. Farmoz Pty Ltd makes no representation as to the accuracy or comprehensiveness of

the information and to the full extent allowed by law excludes all liability whatsoever, whether with respect to negligence or

otherwise, for any loss or damage arising from or connection with the supply or use of the information in this Material Safety Data

Sheet.

Please read all labels carefully before using product.

Product Name: Farmoz Mancozeb 750 DF Agricultural Fungicide

Page: 6 of 6

This revision issued: August, 2012

SAFETY DATA SHEET

Issued by: Farmoz Pty Ltd

Phone: (02)9431 7800 (office hours)

Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)

This MSDS is prepared in accord with the SWA document “National Code of Practice for the Preparation of

Material Safety Data Sheets” 2nd Edition [NOHSC:2011(2003)]

Copyright © Kilford & Kilford Pty Ltd, August, 2012.

http://www.kilford.com.au/

Phone (02)9251 4532

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