DELAN 700 WG FUNGICIDE

Australia - English - APVMA (Australian Pesticides and Veterinary Medicines Authority)

Active ingredient:
DITHIANON
Available from:
BASF AUSTRALIA LTD.
INN (International Name):
dithianon(700g/kg)
Pharmaceutical form:
WATER DISPERSIBLE GRANULE
Composition:
DITHIANON QUINONE Active 700.0 g/kg
Units in package:
2kg; 5kg
Class:
A - Agricultural
Manufactured by:
BASF AUSTRALIA
Therapeutic group:
APPLE | APRICOT | CANNING VARIETY OF PEACH | CHERRY | GRAPEVINE | NECTARINE | PEACH | PEAR | PLUM | PRUNE | STONE FRUIT | APRICO
Therapeutic area:
FUNGICIDE
Therapeutic indications:
BITTER ROT | BLACK SPOT - COLLETOTRICHUM ACUTATUM | BLACK SPOT/SCAB IN APPLE/PEAR | BROWN ROT | DOWNY MILDEW | FRECKLE OR SCAB ON STONE FRUIT | LEAF CURL | LEAF SPOT - ALTERNARIA CERCOSPORA | PEACH BLIGHT | PHOMOPSIS CANE - DEAD ARM | RUST | SCAB | SHOTHOLE | ANTHRACNOSE | APPLE SCAB | CERCOSPORA | CLASTEROSPORIUM | FRECKLE (SCAB) | FRUCTICOLA | LEAF BLIGHT - P. VITICOLA | PEAR SCAB | PHYLLOS | SHOT HOLE | VENTURIA PIRINA
Product summary:
Poison schedule: 6; Withholding period: WHP:Canning Peaches : Do not apply late r than 1 day before harvest. Fruit oth er than canning peaches : Do not apply later than 21 days before harvest. Apr icots Nectarines Peaches: Do not appl y later than 21 days before harvest,; Host/pest details: APPLE: [BITTER ROT, BLACK SPOT/SCAB IN APPLE/PEAR]; APRICOT: [BROWN ROT, FRECKLE OR SCAB ON STONE FRUIT]; CANNING VARIETY OF PEACH: [BROWN ROT]; CHERRY: [BROWN ROT]; GRAPEVINE: [BLACK SPOT - COLLETOTRICHUM ACUTATUM, DOWNY MILDEW, LEAF SPOT - ALTERNARIA CERCOSPORA, PHOMOPSIS CANE - DEAD ARM]; NECTARINE: [BROWN ROT, FRECKLE OR SCAB ON STONE FRUIT, LEAF CURL, RUST]; PEACH: [BROWN ROT, FRECKLE OR SCAB ON STONE FRUIT, LEAF CURL, RUST]; PEAR: [BLACK SPOT/SCAB IN APPLE/PEAR]; PLUM: [BROWN ROT, RUST]; PRUNE: [BROWN ROT, RUST]; STONE FRUIT: [PEACH BLIGHT, SCAB, SHOTHOLE]; Poison schedule: 6; Withholding period: ; Host/pest details: APPLE: [BITTER ROT, BLACK SPOT/SCAB IN APPLE/PEAR]; APRICOT: [BROWN ROT, FRECKLE OR SCAB ON STONE FRUIT]; CANNING VARIETY OF PEACH: [BROWN ROT]; CHERRY: [BROWN ROT]; GRAPEVINE: [BLACK SPOT - COLLETOTRICHUM ACUTATUM, DOWNY MILDEW, LEAF SPOT - ALTERNARIA CERCOSPORA, PHOMOPSIS CANE - DEAD ARM]; NECTARINE: [BROWN ROT, FRECKLE OR SCAB ON STONE FRUIT, LEAF CURL, RUST]; PEACH: [BROWN ROT, FRECKLE OR SCAB ON STONE FRUIT, LEAF CURL, RUST]; PEAR: [BLACK SPOT/SCAB IN APPLE/PEAR]; PLUM: [BROWN ROT, RUST]; PRUNE: [BROWN ROT, RUST]; STONE FRUIT: [PEACH BLIGHT, SCAB, SHOTHOLE]; For the control of certain diseases of stone fruit, pome fruit and vines.DO NOT apply if it is likely to rain before spray is dry. DO NOT apply to wet crops
Authorization status:
Registered
Authorization number:
50029
Authorization date:
2017-07-01

POISON

KEEP OUT OF REACH OF CHILDREN

READ SAFETY DIRECTIONS BEFORE OPENING OR USING

DELAN® 700 WG FUNGICIDE

ACTIVE CONSTITUENT: 700 g/kg DITHIANON

GROUP

~uFUNGICIDE

Approved

For control

certain diseases

stone fruit, pome fruit and vines as specified

DIRECTIONS FOR USE table.

READ THE ATTACHED LEAFLET BEFORE USE.

CONTENTS: 2

BASF Australia Ltd ABN 62 008 437 867

Level 12, 28 Freshwater Place Southbank VICTORIA 3006

APVMA

Approval

50029/

(V21

0113)

Registered trademark

BASF

APVMA Approval No.: 50029/

5~146

Page

DELAN®

FUNGICIDE

Label

Page

DBASF

Chemical

Company

STORAGE

AND

DISPOSAL

Store

closed,

original

container,

dry,

cool,

well-ventilated

area

direct

sunlight.Triple

preferably

pressure

rinse

containers

before

disposal.

rinsings

spray

tank.

dispose

undiluted

chemicals

on-site.

recycling,

replace

return

clean

containers·

recycler

designated

collection

point.

recycling,

break,

crush,

puncture

bury

empty

containers

local

authority

landfill.

landfill

available,

bury

containers

below

disposal

specifically

marked

this

purpose

clear

waterways,

desirable

vegetation

tree

roots.

Empty

containers

product

should

burnt.

SAFETY

DIRECTIONS

Poisonous

swallowed.

Harmful

inhaled.

Will

damage

eyes.

Will

irritate

skin.

Avoid

contact

with

eyes

skin.

inhale

dust.

Repeated

exposure

cause

allergic

disorders.

When

opening

container

preparing

spray,

wear

cotton

overalls

buttoned

neck

wrist

washable

hat,

elbow-length

gloves

goggles.

When

using

prepared

spray,

wear

cotton

overalls

buttoned

neck

wrist

washable

elbow-length

gloves.

product

skin,

immediately

wash

area

with

soap

water.

product

eyes,

wash

immediately

with

water.

After

before

eating,

drinking

smoking,

wash

hands,

arms

face

thoroughly

with

soap

water.

After

each

day's

wash

gloves,

goggles

contaminated

clothing.

Human

flaggers

must

protected

mechanical

means

such

enclosed

vehicle

cabs.

FIRST

AID

poisoning

occurs

contact

doctor

Poisons

Information

Centre.

Phone

Australia

131126.

MATERIAL

SAFETY

DATA

SHEET

Additional

information

listed

Material

Safety

Data

Sheet.

CONDITIONS

OF

SALE

conditions

warranties

rights

remedies

implied

arising

contract

tort

whether

negligence

BASF

Australia

otherwise

hereby

expressly

excluded

same

legally

done

provided

however

that

rights

Buyer

pursuant

non-

excludable

conditions

warranties

Trade

Practices

relevant

legislation

State

expressly

preserved

the.

liability

BASF

Australia

intermediate

Seller

pursuant

thereto

shall

limited

permitted

said

legislation

replacement

goods

sold

supply

equivalent

goods

liability

indirect

consequential

loss

damage

whatsoever

nature

expressly

excluded.

This

product

must

used

applied

strictly

accordance

with

instructions

appearing

hereon.

This

product

solely

sold

Australia

must

exported

without

prior

written

consent

BASF

Australia

Ltd.

APVMA

Approval

50029/

1-'-lo

Batch

Date

Manufacture:

BASF

Australia

Level

Freshwater

Place

Southbank

VICTORIA

3006

SPECIALIST

ADVICE

EMERGENCY

ONLY

PHONE

1800

TOLL

FREE-ALL

HOURS-AUSTRALIA

WIDE

APVMA

Approval

50029/

(V210113)

Page

c

DELAf~®

FUNGICIDE

Leaflet

The Chemical Company

POISON

KEEP OUT OF REACH OF CHILDREN

READ SAFETY DIRECTIONS BEFORE OPENING OR USING

DELAN® 700 WG FUNGICIDE

ACTIVE CONSTITUENT: 700 g/kg DITHIANON

!GROUP

lt~Q)FUNGICIDE

For control

certain diseases

stone fruit, pome fruit and vines as specified

DIRECTIONS FOR USE table.

READ THIS LEAFLET BEFORE USE.

CONTENTS: 2

BASF Australia

ABN 62 008 437 867

Level 12, 28 Freshwater Place Southbank VICTORIA 3006

APVMA

f\pproval

50029/

(V210113)

Registered trademark

BASF

APVMA Approval No.: 50029/

58'-=tttc

Page

DELAN®

FUNGICIDE

DIRECTIONS

RESTRAINTS

apply

likely

rain

before

spray

dry.

apply

crops.

Leaflet

DBASF

Chemical

Company

apply

DELAN

under

slow

drying

conditions

increase

fruit

russet

occur.

following

table,

rates

given

dilute

spraying.

concentrate

CRITICAL

COMMENTS

spraying,

refer

Mixing/Application

section.

uses

this

table:

Apply

~--'c~R--=-O:L.:P.=!.1..~-=-o-'-'=lsc:::E--=-As-=-:E::-r

ST~A:':::T=E:----r--=R::-::A-=T=-E

----.-:-:w-=n=H-::-H:-::0:-:-L-=-oi:::-:N:-=G----1

dilute

concentrate

spraying

Apples

Pears

PERIOD

equipment.

Black

states

spot/apple

scab

Bitter

Glomerella

cingulate)

Black

spot/

only

/pear

scab

18g/1

water

(harvest)

g/100

water

(harvest)

NSW,

Tas,

g/100

water

only

only

water

Apply

same

total

amount

product

the target crop, whether

applying this product

dilute or

concentrate spraying methods.

apples

intended

cold

store,

apply

later

than

days

from

harvest.

This

does

apply

apples

intended

Controlled

Atmosphere

storage.

apply

during

blossoming,

only.

days

Apply

intervals

over

primary

infection

period

from

green

petal

fall

continue

intervals

thereafter

while

conditions

permit

infection.

product

also

used

protectant

addition

(Group

fungicides.

Apply

intervals

from

petal

fall

days

before

harvest,

using

shorter

interVal

during

periods

high

humidity.

Applications

later

half

season

will

assist

control

post

harvest

development

bitter

rot.

program

sprays

black

spot

control

apples

will

also

provide

control

bitter

rot.

days

Apply

from

finger

stage

every

days

while

conditions

permit

infection.

higher

rate

when

where

conditions

highly

favourable

primary

infection.

APVMA

Approval

50029/

Page

(V210113)

e_-

[eaffet

-a·BASF

The Chemical Company

following

table,

rates

given

dilute

spraying.

concentrate

CRITICAL

COMMENTS

1-s-:!':;p=-'lra-:-:yii=-'ng"'-',-'-re,fe"-r-=-=to=-:t:;_he=-M:..:..:..::...;ixi::.._n~~/

A:....:.J~gt:..J:..:.:_pllic::...:_ac::.;tio::..;.;n:...rs-=-ec:...::ti:..:..:on:.:.:..

-.--------l

uses

this

table:

Apply

CROP

DISEASE

STATE

RATE

WITHHOLDING

dilute

concentrate

spraying

PERIOD

equipment.

Apply

same

total

amount

product

target

crop,

whether

applying

this

product

dilute or

concentrate

spraying

methods.

Grape

vines

Downy

mildew

States

water

days

Apply

when

shoots

long,

prior

infection

occurring.

While

conditions

permit

infection,

continue

applications

intervals

weather,

decreasing

days

weather.

protect

bunches,

apply

during

flowering

weeks

later,

then

every

days

above.

(apply

(harvest)

Canning

peaches

Apricots,

cherries,

nectarines,

peaches,

plums,

prunes

minimum

L/ha

shoots

0-15

length

minimum

1000

L/ha

thereafter)

aircraft

g/ha

Black

spot

water

Phomopsis

states

cane

water

leaf

spot

Brown

NSW,

Vic,

Tas,

only

g/100

water

plus

non-ionic

wetting

f--=:-:--:---:---1

agent

only

NSW,

Tas,

Vic,

only

only

APVMA

Approval

50029/

(V210113)

(harvest)

days

(harvest)

Apply

every

weeks

from

bud-burst

flowering

higher

rate

Phomopsis

control

when

where

conditions

favourable

disease

development.

Apply

according

local

recommendations

budswell,

full

bloom,

petal

fall,

shuck

fall

weeks

days

before

harvest.

Apply

according

local

recommendations

budswell,

full

bloom,

petal

fall,

shuck

fall

weeks,

weeks

days

before

harvest.

Apply

according

local

recommendations

budswell,

full

bloom,

petal

fall,

shuck

fall

weeks

before

harvest.

Within

days

harvest

another

registered

fungicide.

Apply

according

local

recommendations

budswell,

full

bloom,

petal

fall,

shuck

fall

weeks

before

harvest.

Within

days

harvest

another

registered

fungicide.

Page

5 of9

DELAN®

FUNGICIDE

Leaflet

BASF

Chemical

Company

following

table,

rates

given

dilute

spraying.

concentrate

CRITICAL

COMMENTS

~s:.r:>P~Ira:~_lY:.:..:iinQ.;g,c...;..r.::..:ef,=.:er:.....:to=-..:.:.:th~e~M~ix..:.:.:in¥J/..:.:.:A=pplli-=-=ca=tio.:...:.n.:..,:s:....:...e..:_:ct::,-:.io'='n.

---.-:-=:-::-::-:-:::-::-::----::--i

uses

this

table:

Apply

CROP

DISEASE

STATE

RATE

WITHHOLDING

dilute

concentrate

spraying

Apricots,

Freckle

states

g/100

nectarines,

water

plus

peaches

non-ionic

wetting

agent

Nectarine,

Leaf

curl

states

peaches

Rust

water

plus

non-ionic

wetting

agent

Plums,

water

prunes

plu,s

non-ionic

wetting

agent

stone

Shothole,

g/100

fruit

scab/peach

water

plus

blight

non-ionic

wetting

agent·

PERIOD

equipment.

days

(harvest)

Apply

same

total

amount

product

target crop, whether

applying this product

dilute or

concentrate spraying methods.

Apply

according

local

recommendations

early

bloom

shuck

fall

then

monthly

intervals

until

days

before

harvest.

Apply

early

budswell.

addition

summer

grade

spraying

will

improve

effectiveness.

Apply

according

local

recommendations

about

monthly

intervals

from

shuck

fall

until

days

before

harvest.

Apply

according

local

recommendations

leaf

fall

early

blossoming.

USED

PURPOSE,

MANNER,

CONTRARY

THIS

LABEL

UNLESS

AUTHORISED

UNDER

APPROPRIATE

LEGISLATION.

WITHHOLDING

PERIODS:

CANNING

PEACHES:

APPLY

LATER

THAN

BEFORE

HARVEST.

FRUIT

OTHER

THAN

CANNING

PEACHES:

APPLY

LATER

THAN

DAYS

BEFORE

HARVEST.

GENERAL

INSTRUCTIONS

member

Multi-site

Activity

Group

fungicides.

fungicide

resistance

management,

DELAN

Group

fungicide.

Some

naturally

occurring

individual

fungi

resistant

DELAN

exist

through

normal

genetic

variability

fungal

population.

resistant

individuals

eventually

dominate

fungal

population

this

fungicide

used

repeatedly.

These

resistant

fungi

will

controlled

DELAN,

thus

resulting

reduction

efficacy

possible

yield

loss.

Since

occurrence

resistant

fungi

difficult

detect

prior

use,

BASF

Australia

accepts

liability

losses

that

result

from

failure

DELAN

control

resistant

fungi.

MIXING

With

agitation

system

operating,

pour

measured

volume

DELAN

Fungicide

slowly

into

required

volume

water

spray

vat.

thoroughly

then

other

compatible

spray

materials.

Sprays

containing

DELAN

Fungicide

should

used

within

hours

preparation

they

should

agitated

continuously

during

this

period.

APVMA

Approval

50029/

(V210113)

Page

The Chemical Company

WETTING

AGENTS

addition

non-ionic

wetting

agent

required

when

DELAN

Fungicide

being

applied

stone

fruit.

Where

wetting

agent

required

Fungicide,

added

required

other

pesticides,

provided

non-ionic.

APPLICATION

Dilute

Spraying

sprayer

designed

apply

high

spray

volumes,

point

run-off

matched

crop

being

sprayed.

operate

sprayer

achieve

even

coverage

throughout

crop

canopy.

Apply

sufficient

spray

solution

cover

crop

point

run-off.

Avoid

excessive

run-off.

required

spray

volume

achieve

point

determined

applying

different

test

volumes,

using

different

settings

sprayer,

from

industry

guidelines

other

expert

advice.

+Add

amount

product

specified

Directions

Table

each

water.

Spray

point

run-

+The

required

dilute

spray

volume

achieve

point

will

change

sprayer

operation

also

need

changed,

crop

grows.

Concentrate

Spraying

sprayer

designed

concentrate

spraying

(that

sprayer

which

applies

spray

volumes

less

than

those

required

reach

point

run-off)

matched

crop

being

sprayed.

operate

sprayer

achieve

even

coverage

throughout

crop

canopy

using

your

chosen

spray

volume.

Determine

appropriate

dilute

spray

volume

(See

Dilute

Spraying

above)

crop

canopy.

This

needed

calculate

concentrate

mixing

rate.

mixing

rate

concentrate

spraying

then

calculated

following

way:

EXAMPLE

ONLY

Dilute

spray

volume

determined

above:

example

1500

L/ha

Your

chosen

concentrate

spray

volume:

example

Llha

concentration

factor

this

example

(i.e.

1500

dilute

label

rate

mL/100

then

concentrate

rate

becomes

(that

product

water

concentrate

spraying).

chosen

spray

volume,

amount

product

water,

sprayer

operation

need

changed

crop

grows.

further

information

concentrate

spraying,

users

advised

consult

relevant

industry

guidelines,

undertake

appropriate

competency

training

follow

industry

Best

Practices.

GRAPE

VINES

APPLICATION

GROUND

EQUIPMENT.

When

applying

dilute

spray,

apply

sufficient

volume

leaf

surfaces

point

runoff.

Apply

medium

fine

spray

preferably

using

cone

nozzles.

Air-blast

sprayers

recommended

application

vines

with

very

dense

foliage.

APPLICATION

AIRCRAFT.

Apply

minimum

litres

water

hectare.

applied

with

hydraulic

nozzles

rotary

atomizers

operated

produce

droplets

with

V.M.D.

around

microns.

Avoid

application

calm

very

windy

conditions

when

temperature

humidity

cause

rapid

drying.

COMPATIBILITY

Fungicide

compatible

with

following:

Bayfidan+

250EC,

Bogard+

chlorpyrifos

Folidol+

M500,

Folimat+

800,

Gusathion+

350,

Lebaycid+,

Metasystox+

(i),

Nitofol+,

NUDRIN®,

Nustar+

Systhane+

Topas+

TORQUE®,

wettable

sulphur.

APVMA

Approval

50029/

(V21

0113)

Page

DELAN®

FUNGICIDE

Leaflet

DBASF

Chemical

Company

DELAN

Fungicide

should

mixed

with

more

than

other

material,

other

than

non-ionic

wetting

agent.

DELAN

Fungicide

incompatible

with

Agridex+,

Tokuthion+,

chlorpyrifos

iprodione

(Rovral+),

vinclozolin

(Ronilan+)

winter

summer

oils,

except

where

mentioned

under

stone

fruit.

also

incompatible

with

alkaline

materials

such

lime

sulphur,

lime

Bordeaux

mixture.

Under

certain

conditions

incompatible

with

spraying

oils

some

other

liquid

formulations

(see

below).

Spraying

Oils:

DELAN

Fungicide

should

only

applied

with

Winter

Summer

oils

dormant

burst

stages.

other

times

should

applied

with

these

materials

before

after

cover

sprays.

Liquid

Formulations:

DELAN

Fungicide

should

applied

pome

fruit

Santa

Rosa

Wilson

plums

mixed

with

liquid

formulations

liable

cause

ring

spot

However

mixed

with

following

application

other

stone

fruit:

Folidol

M500,

Lebaycid

Metasystox

(i).

CROP

SAFETY

climatic

conditions

time

application

result

slow

drying

spray

deposit,

some

varieties

fruit

show

minor

skin

russeting.

PROTECTION

OF

WILDLIFE,

FISH,

CRUSTACEANS

AND

ENVIRONMENT

Dangerous

fish.

contaminate

streams,

rivers

waterways

with

chemical

used

container.

STORAGE

AND

DISPOSAL

Store

closed,

original

container,

dry,

cool,

well-ventilated

area

dir~ct

sunlight.

method

disposal

container

depends

container

type.

Read

"Storage

Disposal"

instructions

label

that

attached

container.

SAFETY

DIRECTIONS

Poisonous

swallowed.

Harmful

inhaled.

Will

damage

eyes.

Will

irritate

skin.

Avoid

contact

with

eyes

skin.

inhale

dust.

Repeated

exposure

cause

allergic

disorders.

When

opening

container

preparing

spray,

wear

cotton

overalls

buttoned

neck

wrist

washable

hat,

elbow-length

gloves

goggles.

When

using

prepared

spray,

wear

cotton

overalls

buttoned

neck

wrist

washable

elbow-length

gloves.

product

skin,

immediately

wash

area

with

soap

water.

product

eyes,

wash

immediately

with

water.

After

before

eating,

drinking

smoking,

wash

hands,

arms

face

thoroughly

with

soap

water.

After

each

day's

wash

gloves,

goggles

contaminated

clothing.

Human

flaggers

mu~t

protected

mechanical

means

such

enclosed

vehicle

cabs.

FIRST

AID

poisoning

occurs

contact

doctor

Poisons

Information

Centre.

Phone

Australia

131126.

MATERIAL

SAFETY

DATA

SHEET

Additional

information

listed

Material

Safety

Data

Sheet.

CONDITIONS

OF

SALE

conditions

warranties

rights

remedies

implied

arising

contract

tort

whether

negligence

BASF

Australia

otherwise

hereby

expressly

excluded

same

legally

done

provided

however

that

rights

Buyer

pursuant

non-

excludable

conditions

warranties

Trade

Practices

1974

relevant

legislation

State

expressly

preserved

liability

BASF

Australia

intermediate

Seller

pursuant

thereto

shall

limited

permitted

said

legislation

replacement

·the

·goods

sold

supply

equivalent

goods

liability

indirect

consequential

loss

damage

whatsoever

nature

expressly

excluded.

This

product

must

used

applied

strictly

accordance

with

instructions

appearing

hereon.

This

product

solely

sold

Australia

must

exported

without

prior

written

consent

BASF

Australia

Ltd.

APVMA

Approval

50029/

4-0

Batch

Date

Manufacture:

Registered

trademark

BASF

APVMA

Approval

50029/

(V210113)

Page

BASF

Chemical

Company

BASF

Australia

Level12,

Freshwater

Place

Southbank

VICTORIA

3006

The Chemical Company

SPECIALIST

ADVICE

EMERGENCY

ONLY

PHONE

1800

TOLL

FREE-ALL

HOURS-AUSTRALIA

WIDE.

APVMA

Approval

50029/

(V21

0113)

Page

Safety data sheet

Page: 1/11

BASF Safety data sheet

Date / Revised: 18.12.2013

Version: 4.1

Product: DELAN 700 WG FUNGICIDE

Classified as hazardous according to criteria of NOHSC

(58431750/SDS_CPA_AU/EN)

Date of print 19.12.2013

1. Substance/preparation and company identification

DELAN 700 WG FUNGICIDE

Use: crop protection product, fungicide

Manufacturer/supplier:

BASF Australia Limited (ABN 62 008 437 867)

Level 12, 28 Freshwater Place Southbank

Victoria 3006, AUSTRALIA

Telephone: +61 3 8855-6600

Telefax number: +61 3 8855-6511

Emergency information:

BASF Emergency Advice Number: 1800 803 440 (24h) [within Australia]

BASF Emergency Advice Number: + 61 3 8855 6666 [outside Australia]

2. Hazard identification

HAZARDOUS SUBSTANCE, DANGEROUS GOOD

Harmful if swallowed.

Risk of serious damage to eyes.

Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Keep locked-up and out of reach of children.

Keep away from food, drink and animal feeding stuffs.

When using do not eat, drink or smoke.

In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

This material and its container must be disposed of in a safe way.

Wear eye/face protection.

If swallowed, seek medical advice immediately and show this container or label.

Use appropriate container to avoid environmental contamination.

Page: 2/11

Version: 4.1

BASF Safety data sheet

Date / Revised: 18.12.2013

Product: DELAN 700 WG FUNGICIDE

Classified as hazardous according to criteria of NOHSC

(58431750/SDS_CPA_AU/EN)

Date of print 19.12.2013

3. Composition/information on ingredients

Chemical nature

crop protection product, fungicide, water dispersible granules

> 75 µm

Hazardous ingredients

Dithianon

Content (W/W): 70 %

CAS Number: 3347-22-6

EC-Number: 222-098-6

Hazard symbol(s): T, N

R-phrase(s): 22, 23, 40, 41, 43, 50/53

The wording of the hazard symbols and R-phrases is specified in section 16 if dangerous ingredients

are mentioned.

4. First-Aid Measures

General advice:

First aid personnel should pay attention to their own safety. If the patient is likely to become

unconscious, place and transport in stable sideways position (recovery position). Immediately

remove contaminated clothing.

If inhaled:

Keep patient calm, remove to fresh air, seek medical attention. Immediately administer a

corticosteroid from a controlled/metered dose inhaler.

On skin contact:

Immediately wash thoroughly with plenty of water, apply sterile dressings, consult a skin specialist.

On contact with eyes:

Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open,

consult an eye specialist.

On ingestion:

Immediately rinse mouth and then drink 200-300 ml of water, seek medical attention.

Note to physician:

Symptoms: The most important known symptoms and effects are described in the labelling (see

section 2) and/or in section 11., Further important symptoms and effects are so far not known.

Treatment: Symptomatic treatment (decontamination, vital functions).

Page: 3/11

Version: 4.1

BASF Safety data sheet

Date / Revised: 18.12.2013

Product: DELAN 700 WG FUNGICIDE

Classified as hazardous according to criteria of NOHSC

(58431750/SDS_CPA_AU/EN)

Date of print 19.12.2013

5. Fire-Fighting Measures

Suitable extinguishing media:

dry powder, foam, water spray

Unsuitable extinguishing media for safety reasons:

carbon dioxide

Specific hazards:

carbon monoxide, carbon dioxide, nitrogen oxides, sulfur oxides

The substances/groups of substances mentioned can be released in case of fire.

Special protective equipment:

Wear self-contained breathing apparatus and chemical-protective clothing.

Further information:

In case of fire and/or explosion do not breathe fumes. Keep containers cool by spraying with water if

exposed to fire. Collect contaminated extinguishing water separately, do not allow to reach sewage

or effluent systems. Dispose of fire debris and contaminated extinguishing water in accordance with

official regulations.

6. Accidental Release Measures

Personal precautions:

Use personal protective clothing. Avoid contact with the skin, eyes and clothing. Avoid dust

formation.

Environmental precautions:

Do not discharge into the subsoil/soil. Do not discharge into drains/surface waters/groundwater.

Methods for cleaning up or taking up:

For small amounts: Contain with dust binding material and dispose of.

For large amounts: Sweep/shovel up.

Avoid raising dust. Dispose of absorbed material in accordance with regulations. Collect waste in

suitable containers, which can be labeled and sealed. Clean contaminated floors and objects

thoroughly with water and detergents, observing environmental regulations.

7. Handling and Storage

Handling

No special measures necessary if stored and handled correctly. Ensure thorough ventilation of

stores and work areas. When using do not eat, drink or smoke. Hands and/or face should be washed

before breaks and at the end of the shift.

Protection against fire and explosion:

Dust can form an explosive mixture with air. Avoid dust formation. Prevent electrostatic charge -

sources of ignition should be kept well clear - fire extinguishers should be kept handy.

Page: 4/11

Version: 4.1

BASF Safety data sheet

Date / Revised: 18.12.2013

Product: DELAN 700 WG FUNGICIDE

Classified as hazardous according to criteria of NOHSC

(58431750/SDS_CPA_AU/EN)

Date of print 19.12.2013

Storage

Segregate from foods and animal feeds.

Further information on storage conditions: Keep away from heat. Protect against moisture. Protect

from direct sunlight.

Protect from temperatures above: 40 °C

Changes in the properties of the product may occur if substance/product is stored above indicated

temperature for extended periods of time.

8. Exposure controls and personal protection

Components with occupational exposure limits

no exposure standard allocated

Personal protective equipment

Respiratory protection:

Suitable respiratory protection for higher concentrations or long-term effect: Particle filter with

medium efficiency for solid and liquid particles (e.g. EN 143 or 149, Type P2 or FFP2)

Hand protection:

Suitable chemical resistant safety gloves (EN 374) also with prolonged, direct contact

(Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to

EN 374): E.g. nitrile rubber (0.4 mm), chloroprene rubber (0.5 mm), butyl rubber (0.7 mm) and other

Eye protection:

Tightly fitting safety goggles (splash goggles) (e.g. EN 166)

Body protection:

Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting

boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case

of dust).

General safety and hygiene measures:

The statements on personal protective equipment in the instructions for use apply when handling

crop-protection agents in final-consumer packing. Wearing of closed work clothing is recommended.

Store work clothing separately. Keep away from food, drink and animal feeding stuffs.

9. Physical and Chemical Properties

Form:

granules

Colour:

brown

Odour:

characteristic

pH value:

approx. 3 - 5

(1 %(m), approx. 20 °C)

(as suspension)

Page: 5/11

Version: 4.1

BASF Safety data sheet

Date / Revised: 18.12.2013

Product: DELAN 700 WG FUNGICIDE

Classified as hazardous according to criteria of NOHSC

(58431750/SDS_CPA_AU/EN)

Date of print 19.12.2013

Melting point:

> 20 °C

Boiling point:

The product is a non-volatile solid.

Flash point:

not applicable

Flammability:

not highly flammable

(Regulation 440/2008/EC,

A.10)

Lower explosion limit:

As a result of our experience with this

product and our knowledge of its

composition we do not expect any

hazard as long as the product is used

appropriately and in accordance with

the intended use.

Upper explosion limit:

As a result of our experience with this

product and our knowledge of its

composition we do not expect any

hazard as long as the product is used

appropriately and in accordance with

the intended use.

Self ignition:

not self-igniting

(Method: Regulation

440/2008/EC, A.16)

Explosion hazard:

not explosive

(Directive 92/69/EEC, A.14)

Fire promoting properties:

not fire-propagating

(Regulation 440/2008/EC,

A.17)

Vapour pressure:

The product has not been tested.

Bulk density:

528 - 600 kg/m3

Relative vapour density (air):

negligible, Information based on the

main components.

Solubility in water:

dispersible

Partitioning coefficient n-octanol/water (log Pow):

not applicable

Viscosity, dynamic:

not applicable

10. Stability and Reactivity

Conditions to avoid:

See MSDS section 7 - Handling and storage.

Thermal decomposition:

not determined

Page: 6/11

Version: 4.1

BASF Safety data sheet

Date / Revised: 18.12.2013

Product: DELAN 700 WG FUNGICIDE

Classified as hazardous according to criteria of NOHSC

(58431750/SDS_CPA_AU/EN)

Date of print 19.12.2013

Substances to avoid:

strong acids, strong bases, strong oxidizing agents

Hazardous reactions:

No hazardous reactions if stored and handled as prescribed/indicated.

Hazardous decomposition products:

No hazardous decomposition products if stored and handled as prescribed/indicated.

11. Toxicological Information

Acute toxicity

Assessment of acute toxicity:

Virtually nontoxic after a single skin contact. Virtually nontoxic by inhalation. Of high toxicity after

single ingestion.

LD50 rat (oral): 273 mg/kg (Directive 84/449/EEC, B.1)

LC50 rat (by inhalation):

Not inhalable due to the physico-chemical properties of the product.

LD50 rat (dermal): > 4,000 mg/kg (OECD Guideline 402)

No mortality was observed.

Irritation

Assessment of irritating effects:

May cause severe damage to the eyes. Not irritating to the skin.

Primary skin irritation rabbit: non-irritant (Directive 84/449/EEC, B.4)

Primary irritations of the mucous membrane rabbit: Risk of serious damage to eyes. (Directive

84/449/EEC, B.5)

Sensitization

Assessment of sensitization:

The product has not been tested. The statement has been derived from the properties of the

individual components. Sensitization after skin contact possible.

Information on: Dithianon

Guinea pig maximization test guinea pig: Caused skin sensitization in animal studies. (OECD

Guideline 406)

An aqueous solution was tested.

----------------------------------

Repeated dose toxicity

Assessment of repeated dose toxicity:

The product has not been tested. The statement has been derived from the properties of the

individual components.

Page: 7/11

Version: 4.1

BASF Safety data sheet

Date / Revised: 18.12.2013

Product: DELAN 700 WG FUNGICIDE

Classified as hazardous according to criteria of NOHSC

(58431750/SDS_CPA_AU/EN)

Date of print 19.12.2013

Information on: dithianon

Assessment of repeated dose toxicity:

Repeated exposure may affect certain organs. Damages the kidneys.

----------------------------------

Genetic toxicity

Assessment of mutagenicity:

The product has not been tested. The statement has been derived from the properties of the

individual components. Mutagenicity tests revealed no genotoxic potential.

Carcinogenicity

Assessment of carcinogenicity:

The product has not been tested. The statement has been derived from the properties of the

individual components.

Information on: dithianon

Assessment of carcinogenicity:

Long term administration of organotoxic doses revealed a carcinogenic effect. In long-term studies in

mice in which the substance was given by feed, a carcinogenic effect was not observed.

----------------------------------

Reproductive toxicity

Assessment of reproduction toxicity:

The product has not been tested. The statement has been derived from the properties of the

individual components. The results of animal studies gave no indication of a fertility impairing effect.

Developmental toxicity

Assessment of teratogenicity:

The product has not been tested. The statement has been derived from the properties of the

individual components.

Information on: dithianon

Assessment of teratogenicity:

The substance did not cause malformations in animal studies; however, toxicity to development was

observed at high doses which impaired body weight gain in parental animals.

----------------------------------

Other relevant toxicity information

Misuse can be harmful to health.

12. Ecological Information

Ecotoxicity

Assessment of aquatic toxicity:

Very toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment.

Page: 8/11

Version: 4.1

BASF Safety data sheet

Date / Revised: 18.12.2013

Product: DELAN 700 WG FUNGICIDE

Classified as hazardous according to criteria of NOHSC

(58431750/SDS_CPA_AU/EN)

Date of print 19.12.2013

The product has not been tested. The statement has been derived from the properties of the

individual components.

Information on: Dithianon

Toxicity to fish:

LC50 (96 h) 0.044 mg/l, Oncorhynchus mykiss (Directive 84/449/EEC, C.1)

----------------------------------

Information on: Dithianon

Aquatic invertebrates:

EC50 (48 h) 0.26 mg/l, Daphnia magna (OECD Guideline 202, part 1)

----------------------------------

Information on: Dithianon

Aquatic plants:

EC50 (72 h) 0.298 mg/l (growth rate), Selenastrum capricornutum (Guideline 92/69/EEC, C.3)

No observed effect concentration (72 h) 0.025 mg/l (growth rate), Pseudokirchneriella subcapitata

(Guideline 92/69/EEC, C.3)

----------------------------------

Mobility

Assessment transport between environmental compartments:

The product has not been tested. The statement has been derived from the properties of the

individual components.

Information on: Dithianon

Assessment transport between environmental compartments:

Following exposure to soil, adsorption to solid soil particles is probable, therefore contamination of

groundwater is not expected.

----------------------------------

Persistence and degradability

Assessment biodegradation and elimination (H2O):

The product has not been tested. The statement has been derived from the properties of the

individual components.

Information on: Dithianon

Assessment biodegradation and elimination (H2O):

According to OECD criteria the product is not readily biodegradable but inherently biodegradable.

----------------------------------

Bioaccumulation potential

Assessment bioaccumulation potential:

The product has not been tested. The statement has been derived from the properties of the

individual components.

Information on: Dithianon

Bioaccumulation potential:

Page: 9/11

Version: 4.1

BASF Safety data sheet

Date / Revised: 18.12.2013

Product: DELAN 700 WG FUNGICIDE

Classified as hazardous according to criteria of NOHSC

(58431750/SDS_CPA_AU/EN)

Date of print 19.12.2013

Bioconcentration factor: 28 (3 d), Oncorhynchus mykiss (OECD Guideline 305 E)

Does not accumulate in organisms.

----------------------------------

Additional information

Other ecotoxicological advice:

Do not discharge product into the environment without control.

13. Disposal Considerations

Must be sent to a suitable incineration plant, observing local regulations.

Contaminated packaging:

Contaminated packaging should be emptied as far as possible and disposed of in the same manner

as the substance/product.

14. Transport Information

Domestic transport:

Hazard class:

Packing group:

ID number:

UN 2588

Hazard label:

6.1, EHSM

Proper shipping name:

PESTICIDE, SOLID, TOXIC, N.O.S. (contains DITHIANON)

Further information

Hazchem Code:2X

IERG Number:34

Sea transport

IMDG

Hazard class:

Packing group:

ID number:

UN 2588

Hazard label:

6.1, EHSM

Marine pollutant:

Proper shipping name:

PESTICIDE, SOLID, TOXIC, N.O.S. (contains DITHIANON)

Air transport

IATA/ICAO

Hazard class:

Packing group:

ID number:

UN 2588

Hazard label:

Proper shipping name:

PESTICIDE, SOLID, TOXIC, N.O.S. (contains DITHIANON)

Page: 10/11

Version: 4.1

BASF Safety data sheet

Date / Revised: 18.12.2013

Product: DELAN 700 WG FUNGICIDE

Classified as hazardous according to criteria of NOHSC

(58431750/SDS_CPA_AU/EN)

Date of print 19.12.2013

15. Regulatory Information

Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) (Australia):

Poisons Schedule: Drugs & Poisons, Schedule 6

Hazard symbol(s)

Harmful.

Irritant.

Dangerous for the environment.

R-phrase(s)

Harmful if swallowed.

Risk of serious damage to eyes.

R50/53

Very toxic to aquatic organisms, may cause long-term adverse effects

in the aquatic environment.

S-phrase(s)

S1/2

Keep locked-up and out of reach of children.

Keep away from food, drink and animal feeding stuffs.

S20/21

When using do not eat, drink or smoke.

In case of contact with eyes, rinse immediately with plenty of water and

seek medical advice.

This material and its container must be disposed of in a safe way.

Wear eye/face protection.

If swallowed, seek medical advice immediately and show this container

or label.

Use appropriate container to avoid environmental contamination.

Hazard determining component(s) for labelling: DITHIANON

Other regulations

If other regulatory information applies that is not already provided elsewhere in this safety data

sheet, then it is described in this subsection.

Registration status:

AICS, AU

blocked / not listed

APVMA 50029

16. Other Information

Full text of hazard symbols and R-phrases if mentioned as hazardous components in section 3:

Toxic.

Page: 11/11

Version: 4.1

BASF Safety data sheet

Date / Revised: 18.12.2013

Product: DELAN 700 WG FUNGICIDE

Classified as hazardous according to criteria of NOHSC

(58431750/SDS_CPA_AU/EN)

Date of print 19.12.2013

Dangerous for the environment.

Harmful if swallowed.

Toxic by inhalation.

Limited evidence of a carcinogenic effect.

Risk of serious damage to eyes.

May cause sensitization by skin contact.

50/53

Very toxic to aquatic organisms, may cause long-term adverse effects in

the aquatic environment.

Vertical lines in the left hand margin indicate an amendment from the previous version.

The data contained in this safety data sheet are based on our current knowledge and experience and

describe the product only with regard to safety requirements. The data do not describe the product's

properties (product specification). Neither should any agreed property nor the suitability of the product for

any specific purpose be deduced from the data contained in the safety data sheet. It is the responsibility

of the recipient of the product to ensure any proprietary rights and existing laws and legislation are

observed.

Similar products

Search alerts related to this product

View documents history

Share this information