DAIRY POWER DEFENDER LOW FOAM ACID SANITISER

Australia - English - APVMA (Australian Pesticides and Veterinary Medicines Authority)

Active ingredient:
ALKYL ARYL SULFONIC ACID; PHOSPHORIC ACID
Available from:
ECOLAB PTY LIMITED
INN (International Name):
phosphoric acid(502g/L)+alkyl aryl sulphonic acid(96g/L)
Pharmaceutical form:
AQUEOUS CONCENTRATE
Composition:
ALKYL ARYL SULFONIC ACID EMULSIFIERS & SURFACTANTS-ANIO Active 96.0 g/L; PHOSPHORIC ACID MINERAL-PHOSPHORUS-ACID Active 502.0 g/L
Units in package:
100L; 110L; 200L; 20L
Class:
A - Agricultural
Manufactured by:
ECOLAB
Therapeutic group:
MILKING EQUIPMENT | MILKING MACHINE
Therapeutic area:
DAIRY CLEANSER
Therapeutic indications:
RESIDUE, DIRT IN MILKING EQUIPMENT
Product summary:
Poison schedule: 6; Withholding period: WHP: N/A; Host/pest details: MILKING EQUIPMENT: [RESIDUE, DIRT IN MILKING EQUIPMENT]; Poison schedule: 6; Withholding period: ; Host/pest details: MILKING EQUIPMENT: [RESIDUE, DIRT IN MILKING EQUIPMENT]; Defender is a low foam high acid detergent based sanitiser. It contains no iodine and can be used in hot or cold water. Suitable for use in most automatic vat and line wash systems.
Authorization status:
Registered
Authorization number:
49190
Authorization date:
2020-07-01

UN1760

CORROSIVE

LIQUID

N,O,S.

(CONTAINS

ortho·PHOSPHORIC

ACID)

POISON

KEEP

REACH

CHILDREN

READ

SAFETY

DIRECTIONS

BEFORE

OPENING

USING

DA.IRV

POVVER

DEFENDER

LOW FOAM ACID SANITISER

Active Constituents:

502g/L PHOSPHORIC ACID,

96g/L ALKYLARYL SULPHONIC ACID

DEFENDER is a low foam high acid based sanitiser.

It contains no iodine and can be used in hot or cold water.

Suitable for use in most

automatic vat and line wash systems.

DIRECTIONS FOR USE:

SITUATION

RATE

CRITICAL COMMENTS

MILKING PLANT - Sanitise before or after miking when the plant

Allow a volume of 5L of water per set

has been washed and rinsed well.

Use DEFENDER in hot or cold

30mL per 10L

cups, or 10L if reverse flow

cleaning.

water for 2 to 3 minutes.

Restrictions on sanitiser flow rat and air agitation

MILK VATS - AUTO WASH - Add sufficient

sanitiser to the

30mL per 10L

will

reduce possible foam problems.

reservoir

to suit water volume to be circulated.

A maximum pH of 4 in solution is desirable.

Consult with a Campbell

Cleantec Representative if

water hardness is extreme.

Version: 3.01

Date: 20 June 2002

Label: 3/3

APPROVED

LABEL

(TEXT)

Label

49'(9Q/Q.7.92.

Date:

?-:~

.

..I.

.I..~.'?-.

Signature:

PRODUCT CODE

15354

1·20L

6815100·100L

6815110·110L

6815200·200L

BATCH NO.:

USE BY DATE:

NOT TO BE USED FOR ANY PURPOSE,

OR IN ANY MANNER CONTRARY TO THIS

LABEL

UNLESS AUTHORISED UNDER APPROPRIATE

LEGILSATION.

PROTECTION OF WILDLIFE,

FISH,

CRUSTACEA AND ENVIRONMENT:

Do not contaminate streams,

rivers or waterways with the chemical

used containers.

STORAGE and DISPOSAL:

Store in closed, original

container in a cool, well-ventilated area.

Do not store for prolonged periods in direct

sunlight.

Triple or preferably pressure rinse containers before disposal.

Add rinsings to spray tank.

Do not dispose of undiluted chemicals on site.

If recycling,

replace cap and return clean containers to a recycler or designated collection point.

If not recycling,

break, crush or puncture and bury empty

containers in a local

authority landfill.

If not available bury the containers below 500mm in a disposal

pit specifically marked and set up for this

purpose clear of waterways,

vegetation and roots.

Empty containers and product

should not be burnt.

SAFETY DIRECTIONS:

Corrosive.

Attacks eyes, nose,

throat

and skin.

Avoid contact

with eyes,

skin and clothing.

Do not inhale vapour or spray

mist.

When

preparing product

for use, wear cotton overalls buttoned to the neck and wrist

and a washable hat,

rubber apron,

elbow-length neoprene

DATE OF

MANUFACTURE'

gloves,

face shield and chemical

resistant

footwear.

If clothing becomes contaminated with product

remove clothing immediately.

If product

on skin,

immediately wash area with soap and water.

If product

in eyes, wash it out immediately with water.

After use and before eating,

drinking or smoking,

wash hands,

arms and face thoroughly with soap and water.

After each day's use, wash gloves,

face shield and contaminated clothing.

FIRST AID:

If poisoning occurs, contact

a doctor or Poisons Information Centre,

phone Australia 13 11 26.

If swallowed,

do NOT induce vomiting.

APPROVAL

49190/0

7<':lGive a glass of water.

If in eyes,

hold eyes open, flood with water for at least

15 minutes and see a doctor.

If skin contact

occurs,

remove

contaminated clothing and wash skin thoroughly.

further

information

refer to Material

Safety Data Sheet.

Campbell

Brothers

Limited

Trading

Campbell

Cleantec

Head

Office:

Perivale

Street,

Darra

4076

Australia

Customer

Service:

1800

Emergency

Number:

1800628724

Incorporated

Queensland

DAIRYPOWER DEFENDER 1. Identificationofthe material and supplier

Material Safety Data Sheet

Trade name ofproduct DAIRY POWER DEFENDER

Emergencytelephone

number :

PHOSPHORIC ACID, SOLUTION ADG :

:

Material uses Cleaning product : Supplier :ECOLAB PTY LTD (A.B.N. 59 000 449 990)

6 Hudson Ave, Castle Hill NSW2154

Customer Service phone: 1 800 022 002

Free FaxNumber: 1 800 655679

Date ofissue : Use 0.3% in water

6 February2012 Product dilution information:

2. Hazards identification

Safetyphrases S26- In case ofcontact with eyes, rinse

immediatelywith plentyof water and seek

medical advice.

S28- After contact with skin, wash immediately

with plentyofwater.

S36/37/39- Wear suitable protective clothing,

gloves and eye/face protection.

S45- In case ofaccident or if you feel unwell,

seekmedical advice immediately(show the

label where possible). : Classification C - Corrosive :

Risk phrases R34- Causes burns.

R41- Riskofserious damage to eyes. : Statementof

hazardous/dangerous

nature :Classified as hazardousaccording to the

criteria ofSafe WorkAustralia andclassified

as dangerous goodsaccording to the ADG

Code. Product AS SOLD Product ATUSE DILUTION

Not applicable. Not classifiedas hazardousaccording to

the criteria of Safe WorkAustralianor

classified as dangerous goodsaccording

to the ADG Code.

Not classified.

Not applicable.

Ingredient name CAS number Concentration% (w/w)

phosphoric acid 7664-38-2 30 - 60

propyleneglycol 57-55-6 <10

dodecylbenzenesulfonic acid 27176-87-0 <10

propan-2-ol 67-63-0 <10

3. Composition/informationoningredients

Product AS SOLD

Product ATUSE DILUTION Other ingredients, determinednot to be hazardous according to Safe WorkAustralia criteria, and not dangerous according

to the ADG Code, make up the product concentration to 100%.

Ingredients, determined not to be hazardous according to Safe WorkAustralia criteria, and not dangerous according to the

ADG Code, make up the product concentration to 100%.

Page: 1/7 914577 Date of issue 06-February-2012 :

DAIRY POWER DEFENDER

Do not induce vomiting. Rinse mouth; then drink

one or two large glasses ofwater. Contact a

doctor or a Poisons InformationCentre (Phone:

13 11 26). Never give anythingbymouth to an

unconscious person. Ifvomiting occurs, the head

should be kept lowso that vomit does not enter

Skin contact In case ofcontact, immediatelyflush eyes with

plentyofwater for at least 15 minutes. Get

medical attention immediately.

In case ofcontact, immediatelyflush skin with

plentyofwater for at least 15 minutes while

removing contaminatedclothingand shoes. Get

medical attention immediately. Wash clothing

before reuse. Clean shoes thoroughlybefore

reuse.

Ifinhaled, remove tofresh air. Ifnot breathing,

give artificial respiration. If breathing is difficult,

give oxygen. Get medical attention immediately.

Notes to physician Probable mucosal damage maycontraindicate

the use of gastric lavage. Measures against

circulatoryshock, respiratorydepression and

Eye contact :

:

:

:

4. First-aid measures

Product AS SOLD Product ATUSE DILUTION

Rinse with plentyofrunning water. Get

medical attention if symptoms occur.

In case ofcontact, immediatelyflush skin with

plentyofwater. Get medical attention if

symptoms occur. Wash clothing before

reuse.

Remove tofresh air. Get medical attention if

symptoms occur.

Do not induce vomiting. Rinse mouth; then

drinkone or two large glasses ofwater.

Contact a doctor or a Poisons Information

Centre (Phone: 13 11 26).

No specific treatment. Treat symptomatically.

Use an extinguishing agent suitable for the surrounding fire. Extinguishingmedia

5. Fire-fighting measures

Promptlyisolate the scene byremoving all persons fromthe vicinityofthe incident if

there is a fire. No action shallbe taken involving anypersonal riskor without suitable

training.

No specific hazard. Hazchem code :2R

Fire/explosionhazards : :

Hazardous thermal

decomposition products Decompositionproducts mayincludethe following materials:

carbon dioxide

carbon monoxide

sulfur oxides

phosphorus oxides Special protective

equipmentfor fire-fighters :Fire-fighters should wear appropriate protective equipment and self-contained breathing

apparatus (SCBA) with a full face-piece operatedin positive pressure mode. Fire-fighting media and

instructions Product AS SOLD

Environmental

precautions Personal precautions

Avoid dispersal of spilt materialand runoffand

contact withsoil, waterways, drains and sewers.

Informthe relevant authorities if the product has

caused environmental pollution(sewers,

waterways, soilor air). Immediatelycontact emergencypersonnel.

Keep unnecessarypersonnel away. Use

suitableprotective equipment. :

: 6. Accidental release measures

Product AS SOLD Product ATUSE DILUTION

Immediatelycontact emergencypersonnel.

Keep unnecessarypersonnel away. Use

suitableprotective equipment.

Avoid dispersal of spilt materialand runoff

and contact with soil, waterways, drains and

sewers. Informthe relevant authorities if the

product has caused environmental pollution

(sewers, waterways, soilor air).

Page: 2/7 914577 Date of issue 06-February-2012 :

DAIRY POWER DEFENDER

6. Accidental release measures

:Stop leakif without risk. Movecontainers from

spillarea. Approach the release fromupwind.

Prevent entryinto sewers, water courses,

basements or confined areas. Wash spillages

into an effluent treatment plant or proceed as

follows. Contain andcollect spillage with non-

combustible, absorbent materiale.g. sand,

earth, vermiculite or diatomaceous earth and

place incontainer fordisposal according to local

regulations (see section 13). The spilled

materialmaybe neutralized with sodium

carbonate, sodiumbicarbonate or sodium

hydroxide. Dispose ofvia a licensed waste

disposal contractor. Contaminatedabsorbent

materialmaypose the same hazard as the spilt

product. Note: see section 1for emergency

contact informationand section 13 for waste

Methods for cleaning

up Stop leakif without risk. Movecontainers

fromspillarea. Prevent entryinto sewers,

water courses, basements or confined areas.

Wash spillages into an effluent treatment

plant or proceed as follows. Contain and

collect spillage with non-combustible,

absorbent materiale.g. sand, earth,

vermiculite or diatomaceous earth and place

in container for disposal accordingto local

regulations (see section 13). Dispose ofvia a

licensed waste disposal contractor. Note: see

section 1for emergencycontact information

and section 13 for waste disposal.

Handling

Put on appropriate personal protective

equipment (see Section 8). Eating, drinking and

smoking should be prohibitedin areas where

this materialis handled, stored and processed.

Workers should wash hands and face before

eating, drinking and smoking. Remove

contaminated clothing and protective equipment

before enteringeating areas. Do not get ineyes

or on skin or clothing. Do not breathe vapour or

mist. Do not ingest. Ifduring normal use the

materialpresents a respiratoryhazard, use only

with adequate ventilationor wear appropriate

respirator. Keep in theoriginal container or an

approved alternative made froma compatible

material, kept tightlyclosed when not in use.

Keep awayfromalkalis. Emptycontainers

retain product residue and can behazardous.

Do not reuse container.

Keep container tightlyclosed. Keep container in

: 7. Handlingand storage

Product AS SOLD Product ATUSE DILUTION

Put on appropriate personal protective

equipment (see Section 8). Eating, drinking

and smoking should be prohibitedin areas

where this materialis handled, stored and

processed. Workers should wash hands and

face before eating, drinking and smoking.

Remove contaminated clothing and protective

equipment before entering eating areas.

Keep container tightlyclosed. Keep container

in a cool, well-ventilatedarea.

phosphoric acid Safe Work Australia (Australia, 8/2005).

STEL: 3 mg/m³ 15 minute(s).

TWA: 1 mg/m³ 8 hour(s).

propyleneglycol Safe Work Australia (Australia, 8/2005).

TWA: 10 mg/m³ 8 hour(s). Form: Particulate

TWA: 474 mg/m³ 8 hour(s). Form: Vapor and particulates

TWA: 150 ppm8 hour(s). Form: Vapor and particulates

propan-2-ol Safe Work Australia (Australia, 8/2005).

STEL: 1230 mg/m³ 15 minute(s).

STEL: 500 ppm15 minute(s).

Ingredient name Exposure limits 8. Exposure controls/personalprotection

Occupational exposure limits Product AS SOLD

Page: 3/7 914577 Date of issue 06-February-2012 :

DAIRY POWER DEFENDER

8. Exposure controls/personalprotection

Engineering measures Ifuser operations generate dust, fumes, gas,

vapour or mist, use processenclosures, local

exhaust ventilationor other engineering controls

to keep worker exposure to airborne

contaminants belowanyrecommended or

statutorylimits.

Wash hands, forearms and face thoroughlyafter handling chemical products, before

eating, smoking and using the lavatoryand at theend of the working period.

Appropriatetechniques shouldbe used to remove potentiallycontaminatedclothing.

Wash contaminatedclothingbefore reusing. Ensure that eyewash stations and

Personal protection

Ifventilation is inadequate, use respirator that

will protect against organic vapour and

dust/mist. Respiratoryprotection should

conformto AS/NZS 1715 and AS/NZS 1716.

Wear synthetic apron, other protective

equipment as necessaryto prevent skin

Use chemical-resistant, impervious gloves.

Recommended: Elbowlength PVC gloves. Hands Wear chemical splash goggles. For continued

or severe exposure wear a face shield over the

goggles. Eyes

:

: :

TWA: 400 ppm8 hour(s).

sulphuric acid Safe Work Australia (Australia, 8/2005).

STEL: 3 mg/m³ 15 minute(s).

TWA: 1 mg/m³ 8 hour(s).

Product AS SOLD Product ATUSE DILUTION

No special ventilationrequirements. Good

general ventilationshould besufficient to

control worker exposure to airborne

contaminants. Ifthis product contains

ingredients with exposure limits, use process

enclosures, local exhaust ventilationor other

engineeringcontrols to keep worker exposure

belowanyrecommended or statutorylimits.

Recommended: Safetyglasses.

Recommended: PVC gloves.

A respirator is not needed under normal and

intended conditions of product use.

No special protective clothing is required.

>100°C (>212°F) Physical state

Boiling point Liquid.

Faint odour Odour

pH Brown Colour

Flash point > 100°C

Product does not support combustion. 0 to 1 [Conc. (% w/w): 100%] :

:

:

:

Relative density :1.25 to 1.27 :

Solubility Easilysolublein thefollowing materials: cold

water and hot water. : : 9. Physical and chemical properties

Product AS SOLD Product ATUSE DILUTION

Liquid.

Brown

Faint odour

> 100°C 4.5 to 5.5

The product is stable. Stability

Highlyreactive or incompatible with thefollowing materials: alkalis.

Reactive or incompatible with thefollowing materials: organic materials, metals and

moisture.

Do not mix with bleach or other chlorinated products - will cause chlorine gas. Materials to avoid :

: Conditions to avoid No specific data. : 10. Stabilityandreactivity

Product AS SOLD

Stability

Page: 4/7 914577 Date of issue 06-February-2012 :

DAIRY POWER DEFENDER

10. Stabilityandreactivity

Hazardous decomposition

products Under normal conditions of storage and use, hazardous decompositionproducts should

not be produced. :

Possibility of hazardous

reactions :Under normal conditions of storage and use, hazardous reactions will not occur.

11. Toxicological information

Potential acute healtheffects

Inhalation Maygive offgas, vapor or dust that is very

irritating or corrosive to the respiratorysystem. :

Ingestion Maycause burnsto mouth, throat andstomach. :

Skin contact Corrosive to the skin. Causes burns. :

Eye contact Corrosive to eyes. Causesburns. :

Potential chronic health effects

Carcinogenicity

Mutagenicity No known significant effectsor criticalhazards.

No known significant effectsor criticalhazards. :

:

Product AS SOLD Product ATUSE DILUTION

No known significant effectsor critical

hazards.

No known significant effectsor critical

hazards.

No known significant effectsor critical

hazards.

No known significant effectsor critical

hazards.

12. Ecological information

Mobility Not available. : LogP

ow BCF Potential Bioaccumulative potential

Other adverse effects :Harmful to aquatic organisms. Maycause long-termadverse effectsin theaquatic

environment. Product/ingredientname

propyleneglycol -0.92 - low

Ecotoxicity data

propyleneglycol Acute EC50 >10000 mg/L 48 hours

Acute LC50 >62000 mg/L 96 hours

Acute LC50 55770 mg/L 96 hours

Acute LC50 710mg/L 96 hours

propan-2-ol Acute LC50 11130 mg/L 96 hours

Acute LC50 10400 mg/L 96 hours

Acute LC50 9640 mg/L 96 hours

Acute LC50 6550 mg/L 96 hours

Product/ingredientname Species Result Exposure

Product AS SOLD

Not available. :

Page: 5/7 914577 Date of issue 06-February-2012 :

DAIRY POWER DEFENDER

Methods ofdisposal :The generation of waste shouldbe avoided or

minimised wherever possible. Empty

containers or liners mayretain some product

residues. This materialand its container must

be disposed ofin a safe way. Significant

quantities of waste product residues shouldnot

be disposed ofvia the foul sewer but processed

in a suitable effluent treatment plant. Dispose

ofsurplus and non-recyclable productsvia a

licensed waste disposal contractor. Disposal of

this product, solutions and anyby-products

should at all times complywith therequirements

ofenvironmental protection and waste disposal

legislationand anyregionallocal authority

requirements. Avoid dispersal of spilt material

and runoffand contact with soil, waterways,

13. Disposal considerations

Product AS SOLD Product ATUSE DILUTION

The generation of waste shouldbe avoided or

minimised wherever possible. Empty

containers or liners mayretain some product

residues. This materialand its container

must be disposed ofin a safe way.

Significant quantities ofwaste product

residues should not be disposed of via the

foul sewer but processed in a suitable effluent

treatment plant. Dispose ofsurplus and non-

recyclableproducts via a licensed waste

disposal contractor. Disposal of this product,

solutions and anyby-productsshould at all

times complywith therequirements of

environmental protection and waste disposal

legislationand anyregionallocal authority

requirements. Avoid dispersal of spilt

materialand runoffand contact with soil,

waterways, drains and sewers.

14. Transport information

Regulation UN numberProper shipping name Classes Packing

group

ADG PHOSPHORIC ACID, SOLUTION 8 III UN1805 Additional information

Hazchem code

Product AS SOLD

Product ATUSE DILUTION

Not intended for transport. IMDG UN1805 PHOSPHORIC ACID, SOLUTION 8 III Emergencyschedules

(EmS)

F-A, S-B

15. Regulatoryinformation

Standard for the Uniform Scheduling of Medicines andPoisons

Control ofScheduled Carcinogenic Substances

Ingredient name Schedule

No listed substance Schedule6 Australia inventory(AICS) AU Classification

: :

Allsubstances are listed on AICSor exempt. C - Corrosive

R34- Causes burns.

R41- Riskofserious damage to eyes. Product AS SOLD Product ATUSE DILUTION

Not classified. Not applicable. Classified as hazardousaccording to the

criteria ofSafe WorkAustralia andclassified

as dangerous goodsaccording to the ADG

Code. Not classifiedas hazardousaccording to

the criteria of Safe WorkAustralianor

classified as dangerous goodsaccording

to the ADG Code.

Page: 6/7 914577 Date of issue 06-February-2012 :

DAIRY POWER DEFENDER

Theaboveinformationisbelievedtobecorrectwithrespecttotheformulausedtomanufacturetheproductin

thecountryoforigin.Asdata,standards,andregulationschange,andconditionsofuseandhandlingare

beyondourcontrol,NOWARRANTY,EXPRESSORIMPLIED,ISMADEASTOTHECOMPLETENESSOR

CONTINUING ACCURACY OF THIS INFORMATION. Disclaimer References : 16. Other information

Date ofprevious issue No previous validation Prepared by RegulatoryAffairs

-ADG Code - Australian Transport of Dangerous Goods

-Adopted National Exposure Standard for Atmospheric Contaminants inthe Occupational Environment

-ApprovedCriteria for ClassifyingHazardous Substances

-List of Designated Hazardous Substances

-NationalCode ofPractice for the Labelling ofWorkplace Substances

-NationalCode ofPractice for the PreparationofMaterial SafetyData Sheets

-NationalModel Regulations for the ControlofScheduled Carcinogenic Substances

-NationalModel Regulations for the ControlofWorkplace Hazardous Substances

-Standardfor the Uniform Scheduling of Medicines and Poisons :

Page: 7/7 914577 Date of issue 06-February-2012 :

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