CAMPBELL TRICOP FUNGICIDE

Australia - English - APVMA (Australian Pesticides and Veterinary Medicines Authority)

Active ingredient:
COPPER (CU) PRESENT AS COPPER OCTANOATE
Available from:
Colin Campbell (Chemicals) Pty Ltd
INN (International Name):
Cu as octanoate(18g/L)
Pharmaceutical form:
SUSPENSION CONCENTRATE
Composition:
COPPER (CU) PRESENT AS COPPER OCTANOATE MINERAL-COPPER Active 18.0 g/L
Units in package:
10L; 200L; 25L
Class:
A - Agricultural
Manufactured by:
COLIN CAMPBELL
Therapeutic group:
BEAN | CELERY | CUCURBIT | NECTARINE | PEA | PEACH | POTATO | TOMATO | VINE | BERRY | CANTALOUPE | CHOKO | CUCUMBER | FABA BEAN
Therapeutic area:
FUNGICIDE
Therapeutic indications:
ASCOCHYTA BLIGHT | DOWNY MILDEW | EARLY BLIGHT (TARGET SPOT) | HALO BLIGHT | LATE BLIGHT OR IRISH BLIGHT | LEAF CURL | POWDERY MILDEW | RUST | SEPTORIA LEAF SPOT - SEPTORIA APIICOLA | CELERY LEAF SPOT | IRISH BLIGHT | LATE BLIGHT | LEAF BLIGHT - S. APIICOLA | TARGET SPOT
Product summary:
Poison schedule: 6; Withholding period: WHP: Do not apply later than 1 day bef ore harvest.; Host/pest details: BEAN: [HALO BLIGHT, RUST]; CELERY: [SEPTORIA LEAF SPOT - SEPTORIA APIICOLA]; CUCURBIT: [DOWNY MILDEW, POWDERY MILDEW]; NECTARINE: [LEAF CURL]; PEA: [ASCOCHYTA BLIGHT, POWDERY MILDEW]; PEACH: [LEAF CURL]; POTATO: [EARLY BLIGHT (TARGET SPOT), LATE BLIGHT OR IRISH BLIGHT]; TOMATO: [EARLY BLIGHT (TARGET SPOT), LATE BLIGHT OR IRISH BLIGHT]; VINE: [DOWNY MILDEW]; Poison schedule: 6; Withholding period: ; Host/pest details: BEAN: [HALO BLIGHT, RUST]; CELERY: [SEPTORIA LEAF SPOT - SEPTORIA APIICOLA]; CUCURBIT: [DOWNY MILDEW, POWDERY MILDEW]; NECTARINE: [LEAF CURL]; PEA: [ASCOCHYTA BLIGHT, POWDERY MILDEW]; PEACH: [LEAF CURL]; POTATO: [EARLY BLIGHT (TARGET SPOT), LATE BLIGHT OR IRISH BLIGHT]; TOMATO: [EARLY BLIGHT (TARGET SPOT), LATE BLIGHT OR IRISH BLIGHT]; VINE: [DOWNY MILDEW]; For the control of certain diseases of fruit and vegetables.
Authorization status:
Registered
Authorization number:
53090
Authorization date:
2020-07-01

I---~

53090 Campbell Tricop Fungicide

Date controlled label version

3 February 2003

POISON

Page I

KEEP OUT OF REACH OF CHILDREN

READ SAFETY DIRECTIONS BEFORE OPENING OR USING

TRICOP

FUNGICIDE

ACTIVE CONSTITUENT:

18g/L COPPER (Cll) present as

COPPER OCTANOATE

GROUP"

FUNGICIDE

CONTROL

CERTAIN

DISEASES

FRUIT

AND VEGETABLES AS

DIRECTIONS

TABLE

CONTENTS:

10,25, 200L

Batch No:

Date

Manufacture:

Distribnted

COLIN CAMPBELL (CHEMICALS) PTY LTD.

5 Blackfriar Place,

WETHERILL PARK, N.S.W. 2164

Telephone: (02)

9725 2544

"M~.A.

APPROVED

LABEL

(TEXT)

label

9.3.'.9..9:Q;.p.4.9.3

Date:

.1.2

./.04../.Q.;).

'1'(

19oa

ure: .

.....

.....

:.,..

RZ·

TRICOP 53090.doc

----------------------

53090 Campbell Tricop Fungicide

Date controlled label version

3 February 2003

Page 2

DIRECTIONS

USE:

RESTRAINTS:

DO NOT apply wben poor drying conditions exist

apply when either hot or frost prone conditions prevail.

Crop

Disease

Rate

Withholding

Critical

Comments

oeriod

tree

vine crcns

Beans

Halo

Blight

1.5U

1 day

Apply

as a protectant

first

sign

100L

infection when plants

15-20 em

2.2~

high.

Repeat

every

10-14

day,

3.5L1ha

required.

U"

higher

rate

when

conditions favour disease.

Rust

IVIOOL

Spray

first

sign

infection.

Repeat

2.2 L/ha

necessary

everv

10-14

days.

Celery

Septaria

Leaf

lUlOOL

Spray

every

10-14

days.

Wh""

Spot

(N8W,

weather

conditions favour

disease (ie

T",

cool weather)

spray

every

days.

SA,WA,

Cucurbits

Powdery

Spray at

first

sign

disease.

Repeat

mildew,

every

7-10

days.

Downy

mildew

Peas

Powdery

Spray at

first

sign of

disease.

Repeat

mildew,

every 10-14 days.

Ascochyta

Potatoes

Target

Spot

IUIOOL

Spray every 10-14 days as

necessary

(Early Blight),

8L1ha

until

maturity. May reduce yield under

~~sh

Bl~~ht

dry conditions

Late Blizht

Tomatoes

Target

Spot

IUtOOL

onset

disease spray every 7-14

(Early Blight)

2.2lJha

days depending on severity of disease

and weather conditions.

Irish

Blight

Begin applying spray at

first

sign

(Late Blight)

disease and repeat

every 10-14 days.

seedling

stage

spray

only

when

necessarv as erowth mav be inhibited.

Tree

Vine

Croos

Rate

Critical Comments

i l l

the following table,

all rates are given for dilute spraying.

For all uses in this table: Apply by

For concentrate spraying,

refer to the General

Instructions /

dilute or concentrate spraying

Spraying Instructions for Tree and Vine Crops.

equipment. Apply the same total

amount of product to the target crop

Crop

Disease

Rate

Withholding

whether applying this product by dilute

period

or concentrate soravina methods

Nectarines

Leaf Curl

IU100L

I day

Spray at bud swell prior to early signs

ofleaflbloom develonment.

Peaches

Leaf Curl

Spray at bud swell prior to early signs

of leaf/bloom

devel~nment.

Vines

Downy

First spray when shoots are IOcm long

Mildew

and re-apply as necessary.

US~i~gher

rates when infection levels are hi

RZ - TRICOP53090.doc

._-----_._---_._-----

53090 Campbell Tricop Fungicide

Date

controlled label version

February

2003

USED

ANY PURPOSE,

CONTRARY

THIS

LABEL

UNLESS

APPROPRIATE

LEGISLATION.

Page

30[5

IN ANY MANNER,

AUTHORISED

UNDER

WITHHOLDING

PERIOD (WHP)

DO NOT APPLY

LATER

THAN I

BEFORE

HARVEST.

GENERAL

INSTRUCTIONS:

Mixing:

Shake

well

before use.

The recommended quantity may be added directly to the

water

in the spray vat

with

the agitators running.

this product

is to be used in a

mixture

with

an emulsifiable concentrate,

add it after making the emulsion.

Spraying

Instructions for

Tree

and Vine Crops

Good control requires good coverage. Application should be made using sufficient

water

to ensure thorough coverage.

Dilute spraying

Use a sprayer designed to apply

high

volumes

water up to the point

run-

and matched to the crop being sprayed.

up and operate the sprayer to achieve even coverage throughout the crop

canopy.

Apply

sufficient water to cover the crop to the point

run-off

Avoid

excessive

run-off

required water volume

be determined

applying different test

volumes,

using different settings on the sprayer, from industry guidelines or

expert advice.

the amount

product specified in the Directions for

table for each

100L

water.

Spray to the point

ron-off.

required dilute spray volume will

change and the sprayer set up and

operation

also need to be changed, as the crop grows.

2. Concentrate spraying

a sprayer designed and set up for concentrate spraying (that is a sprayer

which applies water volumes less than those required to reach the point

run-

off) and matched to the crop being sprayed.

Set up and operate the sprayer to achieve even coverage throughout the crop

canopy using your chosen water volume.

Determine an appropriate dilute spray volume (see Dilute Spraying above) for

the crop canopy. This is needed to calculate the concentrate mixing rate.

mixing rate for concentrate spraying can then be calculated in the

following way.

EXAMPLE ONLY

Dilute spray volume as determined above:

for example 1500Uha.

Your

chosen concentrate spray volume:

for example

500Uha.

The concentration factor in this example is : 3 X (i.e.

1500L

1500L

the dilute label rate is 40mLl100L, then the concentrate rate becomes 3 x 40,

that is 120mLlIOOL

concentrate spray.

chosen spray volume, amount

product

tOOL

water, and the

sprayer

up and operation

need to be changed as the crop grows.

RZ - TRICOP 53090.doc

_._-------------------

53090

Campbell Tricop Fungicide

Date

controlled label version

February

2003

Page

further information on concentrate spraying,

users are advised to consult

relevant industry guidelines, undertake appropriate competency training and

follow industry Best Practice.

FUNGICIDE

RESISTANCE WARNING

GROUP"

FUNGICIDE

fungicide resistance management Tricop Fungicide is a Group Y Fungicide.

Some

naturally occurring individual fungi resistant to Tricop Fungicide and other Group Y

fungicides

exist

through normal genetic variability in any fungal

population.

resistant individuals can eventually dominate the fungi population

these fungicides

used

repeatedly.

These resistant fungi

will

not be controlled

Tricop Fungicide

other

Group

fungicides, thus resulting in a reduction in efficacy and possible

yield loss.

Since the occurance

resistant fungi

is difficult to detect prior to use,

Colin Campbell Chemicals Pty Ltd accepts no liability for any losses that

result

from the failure

Tricop Fungicide to control resistant fungi.

Compatibility:

TRICOP

compatible with spray oils,

with

most

commonly used fungicides,

insecticides

and miticides.

compatibility is

concern,

consult

Colin Campbell

Chemicals.

Re-entry

allow entry into treated areas

until

spray has

dried.

prior

entry is

necessary,

wear

cotton overalls buttoned to the neck and wrist

(or equivalent clothing)

and chemical resistant gloves.

Clothing must be laundered after each

day's

use.

Protection

Wildlife, Fish, Crustaceans

&

Environment:

contaminate

streams,

rivers

waterways

with

chemical

used

container.

Storage:

Store in the

closed,

original

container

a dry,

well-ventilated area,

cool

possible

direct sunlight.

Disposal:

Triple or

preferably pressure rinse containers before disposal.

rinsings to spray

tank.

dispose

undiluted chemicals

on-site.

recycling,

replace cap and

return

clean

containers to recycler or

designated collection point.

recycling,

break,

crush,

or puncture and bury empty containers in a local

authority landfill.

landfill

available,

bury containers

below

500mm

in a disposal

specifically

marked and

up for this purpose,

clear

waterways,

desirable vegetation and tree

roots.

Empty

containers and product should not

be burnt.

Safety Directions:

Will

irritate the eyes.

Avoid contact

with eyes.

When

opening the

container

preparing spray,

wear

cotton overalls buttoned to the neck and wrists,

and elbow-

length

gloves.

Wash hands

after

use.

After

each

day's

use,

wash

gloves

contaminated clothing.

RZ - TRICOP 53090,doc

53090 Campbell Tricop Fungicide

Date controlled label

version

3 February 2003

Page 5

First Aid:

poisoning occurs, contact a doctor or Poisons Information Centre (phone 131126).

Material

Safety

Data

Sheet:

further information, refer to the Material Safety Data Sheet

CONDmONS

OF SALE

Agricultural,

horticultural

and pastoral

preparations in their

application involve varying factors such as ditrering conditions,

snil,

climate and

methods

nfapplication

over which lhe vendor does not

have control,

Whilst Colin Campbell (Chemicals) Ply.

Ltd believes that

goods sold by il

true

to label and are effective and safe for purpose indicated the company and the seller hereby expressly negate and exclude any express Or

implied condition,

statement or warranty, statutory or otherwise,

as 10 quality or fitness

any goods sold for any purpose Of

pU1pOSeS

whatsoever

except

such warranties and conditions,

ifany,

as are implied by the Trade Practices Act

1974

(Commonwealth).

The eompany and the seller aeoept

no responsibility for any loss, harm or damage whatsoever snffered from the use

ofsueh

goods

for any pU'Pose or purposes irrespective

whether

or not

the buyer was acting in reliance upon the advice recommendatiou or represenlation

ofthe

seller or any repw;enlative agent

enl]lloyee

the company as to such use except in respect

of breaches

conditions and warranties,

ifany,

implied by the Trade Practices Act

respe<;1

such breaches

liability

the company and the seller shall be limited to the replacemenl

of the goods or the supply

eqnivalent

goods,

or the

paymcntofthc

cost

replacing the

goods.

Approval No:

53090/0

'1-0:~

- TRTCQP 53090.doc

COLIN CAMPBELL (CHEMICALS) PTY. LTD.

MATERIAL SAFETY DATA SHEET

Date of Issue: 1 July 2012

MSDS 2012 Tricop Fungicide

Page 1 of 5

1)

IDENTIFICATION OF THE MATERIAL AND SUPPLIER

Product Name:

CAMPBELL TRICOP FUNGICIDE

Other Names:

Copper, copper soap

Chemical Group:

Recommended Use:

Fungicide for use on horticultural crops.

Supplier Details:

Colin Campbell (Chemicals) Pty Ltd ABN 29 000 045 590

5 Blackfriar Place

Wetherill Park NSW 2164

Telephone:

(02) 9725 2544

Fax:

(02) 9604 7768

Email:

cccsyd@campbellchemicals.com.au

Website:

www.campbellchemicals.com.au

Contact:

Product Development Manager – (02) 9725 2544

Emergency

Telephone Number:

(02) 9725 2544 – 8am to 6pm Monday to Friday.

2)

HAZARDS IDENTIFICATION

HAZARDOUS SUBSTANCE - NON DANGEROUS GOOD

Hazardous

classification:

Hazardous according to the criteria of the National Occupational Health &

Safety Commission (NOHSC)

Risk phrases:

R43 - May cause sensitisation by skin contact.

Safety phrases:

See sections 4,5,6,7,8,10,12,13

ADG Classification

Not a Dangerous good for transport by road or rail according to the

Australian Code for the Transport of Dangerous Goods by Road and Rail.

SUSDP classification:

Not scheduled (Standard for the Uniform Scheduling of Drugs & Poisons)

3)

COMPOSITION/INFORMATION ON INGREDIENTS

Ingredients

CAS Number

Concentration

Copper octanoate

20543-04-8

18% (1.8% copper)

Inert ingredients

Non hazardous

>60%

4)

FIRST AID MEASURES

If poisoning occurs, immediately contact a doctor or Poison Information Centre (Ph: 13 11 26)

and follow the advice given. Show this Material Safety Data Sheet to the doctor.

Inhalation:

If inhaled remove to fresh air and keep at rest. If not breathing, give artificial

respiration. If breathing is difficult, give oxygen.

Skin Contact:

Carefully remove contaminated clothing. Wash affected areas with soap and water.

COLIN CAMPBELL (CHEMICALS) PTY. LTD.

MATERIAL SAFETY DATA SHEET

Date of Issue: 1 July 2012

MSDS 2012 Tricop Fungicide

Page 2 of 5

4)

FIRST AID MEASURES continued

Eye contact:

Check and remove any contact lenses. Rinse eyes immediately with clean water

for at least 15 minutes and seek medical aid.

Ingestion:

If victim is fully conscious, immediately give large quantities of water to drink

and get medical help. Never give anything by mouth to an unconscious person.

First Aid facilities

Ensure eye wash and safety shower are available.

Medical

Attention:

There is no specific antidote. Treat symptomatically.

5)

FIRE FIGHTING MEASURES

Extinguishing media

Water spray, foam, dry chemical, carbon dioxide (CO

Hazard from

combustion

products

None known.

Precautions for

fighting fires

Fire

fighters

should

wear

full

protective

gear,

including

self-contained

breathing apparatus (AS/NZS 1715/1716). Keep unnecessary people away. If

it can be done safely remove intact containers from the fire. Bund area with

sand or earth to prevent contamination of drains or waterways. Dispose of

extinguishing agent and spillage safely later.

Hazchem Code

Not applicable.

6)

ACCIDENTAL RELEASE MEASURES

Avoid contact with spilled material or contaminated surfaces. Do not smoke, eat or drink during the

clean

process.

Wear

personal

protective

clothing

equipment

detailed

Section

PERSONAL PROTECTION. Keep people and animals away. Contain spill and absorb with earth,

sand, clay or other absorbent material. Prevent spilled material from entering drains or watercourses.

Collect and store in properly labelled drums for safe disposal. Clean floor with a damp cloth and place

it in the drum. Seal drums and label ready for safe disposal. Deal with all spillages immediately. If

contamination of drains, streams, watercourses etc is unavoidable warn the local water authority.

7)

HANDLING AND STORAGE

Handling

Keep out of reach of children. Will irritate eyes and skin. Avoid contact with eyes

and skin. Do not inhale spray mist. After use and before eating, drinking or smoking

wash hands, arms and face thoroughly with soap and water. After each day’s use

wash gloves and contaminated clothing.

Storage

Store in the closed original container in a cool well ventilated area.. Do not store for

prolonged periods in direct sunlight. Store in a locked room away from children,

animals, food, animal feed, seed and fertilisers.

Flammability

Not flammable.

COLIN CAMPBELL (CHEMICALS) PTY. LTD.

MATERIAL SAFETY DATA SHEET

Date of Issue: 1 July 2012

MSDS 2012 Tricop Fungicide

Page 3 of 5

8)

EXPOSURE CONTROL/PERSONAL PROTECTION

Exposure

Standards

No exposure standards have been assigned.

Biological Limit

Values

None allocated

Engineering

Controls

Use in a well ventilated area only.

Personal

Protective

Equipment

Eyes:

Safety goggles or face shield

Clothing:

Cotton overalls buttoned to the neck and wrists and a

washable hat.

Gloves:

Elbow length chemical resistant PVC gloves

Respiratory:

Approved dust

or pesticide respirator with a dust

filter.

9)

PHYSICAL AND CHEMICALS PROPERTIES

Appearance:

Opaque turquoise coloured liquid

Odour:

No discernible smell

Vapour pressure:

Not determined

Vapour density:

Not determined

Boiling point:

Freezing/Melting point:

Not determined

pH:

Solubility:

Emulsifies in water

Specific gravity:

0.98 g/cm

Flash point:

>400

Flammability (explosive) limit:

Not determined

Auto ignition temperature:

Not determined

Partition coefficient

(octanol/water):

Not determined

10)

STABILITY AND REACTIVITY

Chemical stability:

Stable under normal conditions of use.

Conditions to avoid:

None known

Incompatible materials :

None known

Hazardous

decomposition

products:

None known

Hazardous reactions:

None. Hazardous polymerisation is not possible.

COLIN CAMPBELL (CHEMICALS) PTY. LTD.

MATERIAL SAFETY DATA SHEET

Date of Issue: 1 July 2012

MSDS 2012 Tricop Fungicide

Page 4 of 5

11)

TOXICOLOGICAL INFORMATION

Inhalation:

Inhalation of dust may result in respiratory irritation.

Skin contact:

May cause sensitisation by prolonged skin contact.

Eye contact:

May irritate the eyes.

Ingestion:

Product toxicity is low.

ANIMAL TOXICITY DATA – PRODUCT

Acute:

Oral toxicity

rat >2000mg/kg (practically non-toxic)

n irritating. Eye Acute

inhalation 4hr. LC

(Rat) 0.38mg/L.

Dermal toxicity:

rabbit > 2000mg/kg (slightly toxic)

Inhalation toxicity:

rat (4 hour) 0.38mg/L

Skin irritation:

Non irritating.

Eye irritation:

(Rabbit):moderately irritating.

Irritation of mucous

membranes:

May cause irritation

Sensitisation:

No data

Chronic:

Chronic exposure not likely from normal use. No known medical conditions known to be aggravated

with exposure. Not carcinogenic or mutagenic.

12)

ECOLOGICAL INFORMATION

Ecotoxicity:

No data

Environmental fate,

persistence and

degradability,

mobility

As an element, copper can persist indefinitely. However, it will bind to

water particulates and sediment.

13)

DISPOSAL CONSIDERATIONS

Triple or preferable pressure rinse containers before disposal. Add rinsings to the mixing tank. Do not

dispose of undiluted chemical on-site. If recycling, replace cap and return clean containers to recycler

or designated collection point. If not recycling, break, crush or puncture and bury empty containers in a

local authority landfill. If no landfill is available bury the containers below 500mm in a disposal pit

specifically marked and set up for this purpose clear of waterways, desirable vegetation and tree roots.

Empty containers and product should not be burnt.

COLIN CAMPBELL (CHEMICALS) PTY. LTD.

MATERIAL SAFETY DATA SHEET

Date of Issue: 1 July 2012

MSDS 2012 Tricop Fungicide

Page 5 of 5

14)

TRANSPORT INFORMATION

UN Number:

Not applicable

Proper Shipping

name:

Not applicable

Class and subsidiary

risk:

Not applicable

Packing Group:

Not applicable

EPG:

Not applicable

Hazchem code:

Not applicable

15)

REGULATORY INFORMATION

Registered under the Agricultural and Veterinary Chemicals Act 1988 (Commonwealth) Australian

Pesticides and Veterinary Medicines Authority approval number: 53090

16)

OTHER INFORMATION

This MSDS summarises our best knowledge of the health and safety hazard information of the product

and how to safely handle and use the product in the workplace. Each user should read this MSDS and

consider the information in the context of the how the product will be handled and used in the

workplace including in conjunction with other products.

If clarification or further information is needed to ensure that an appropriate risk assessment can be

made the user should contact this company.

END OF MSDS

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