BRUNNINGS BINDII & CLOVER KILL SELECTIVE WEED KILLER

Australia - English - APVMA (Australian Pesticides and Veterinary Medicines Authority)

Active ingredient:
DICAMBA PRESENT AS THE DIMETHYLAMINE SALT; MCPA PRESENT AS THE DIMETHYLAMINE SALT
Available from:
BRUNNINGS GARDEN PRODUCTS PTY LTD
INN (International Name):
MCPA as dma(135g/L)+dicamba as dma(23g/L)
Pharmaceutical form:
AQUEOUS CONCENTRATE
Composition:
DICAMBA PRESENT AS THE DIMETHYLAMINE SALT BENZOIC ACID-ARYLALIPHATIC Active 23.0 g/L; MCPA PRESENT AS THE DIMETHYLAMINE SALT PHENOXY ACIDS-MCPA-AMINE Active 135.0 g/L
Units in package:
500mL
Class:
A - Agricultural
Manufactured by:
BRUNNINGS GARDEN PRO
Therapeutic group:
LAWN | TURF
Therapeutic area:
HERBICIDE
Therapeutic indications:
BINDY-EYE | BROADLEAF WEEDS | CAPEWEED | CLOVER | CREEPING OXALIS | CUDWEED | DANDELION - TARAXACUM OFFICINALE | DOCK | PLANTAIN | RIBWORT, RIBGRASS OR LAMB'S TONGUE | WIREWEED, KNOTWEED OR HOGWEED | BINDII | BOGAN FLEA | BROADLEAF DOCK | BROADLEAF GRASS | CALOTIS HISPIDULA | CLOVER SORREL | COMMON DANDELION | COMMON PLANTAIN | CURLED DOCK | ENGLISH DANDELION | EUROPEAN DANDELION | FALLOPIA AVICULARE | JO-JO | LAMBS TONGUE | NARROW LEAF PLANTAIN | ONEHUNGA WEED | RUMEX BROWNII | RUMEX CRISPUS | RUMEX OBTUSIFOLIUS | SMALL-LEAVED OXALIS | STAR BURR | TARAXACUM SPP. | TRIANTHEMA DECANDRA | TRIANTHEMA GALERICULATA | TRUE DANDELION | WOOD SORREL (YELLOW) | YELLOW WOOD SORREL | ZALEYA DECANDRA | ZALEYA GALERICULATA
Product summary:
Poison schedule: 5; Withholding period: WHP: N/A; Host/pest details: LAWN: [BINDY-EYE, BROADLEAF WEEDS, CAPEWEED, CLOVER, CREEPING OXALIS, CUDWEED, DANDELION - TARAXACUM OFFICINALE, DOCK, PLANTAIN, RIBWORT, RIBGRASS OR LAMB'S TONGUE, WIREWEED, KNOTWEED OR HOGWEED]; TURF: [BINDY-EYE, BROADLEAF WEEDS, CAPEWEED, CLOVER, CREEPING OXALIS, CUDWEED, DANDELION - TARAXACUM OFFICINALE, DOCK, PLANTAIN, RIBWORT, RIBGRASS OR LAMB'S TONGUE, WIREWEED, KNOTWEED OR HOGWEED]; Poison schedule: 5; Withholding period: ; Host/pest details: LAWN: [BINDY-EYE, BROADLEAF WEEDS, CAPEWEED, CLOVER, CREEPING OXALIS, CUDWEED, DANDELION - TARAXACUM OFFICINALE, DOCK, PLANTAIN, RIBWORT, RIBGRASS OR LAMB'S TONGUE, WIREWEED, KNOTWEED OR HOGWEED]; TURF: [BINDY-EYE, BROADLEAF WEEDS, CAPEWEED, CLOVER, CREEPING OXALIS, CUDWEED, DANDELION - TARAXACUM OFFICINALE, DOCK, PLANTAIN, RIBWORT, RIBGRASS OR LAMB'S TONGUE, WIREWEED, KNOTWEED OR HOGWEED]; Controls bindii, clover, and other broadleaf weeds in home lawns.
Authorization status:
Registered
Authorization number:
53000
Authorization date:
2020-07-01

SELECTIVEWEED KILLER

KIlBP

OUT OF

R!!ACH

OF CHllDRI!N

R!!AD

SAFBTY

DIRECTIONS

BBfORBOPENINOORUSINO

Controls Bindii, Clover and other

broadleaf weeds in home lawns.

ACTIVECONSTITUENTS:

13Sg/L

MCPA

PrelcPl

u

dimethyl,mine

1.11.

23a1L

DICAMBA

....

dlmethyllmine

salt.

FIRST

AID: If

poisoning

occura,

conlact

doctor

ofPoisoo.lnformalion Cen".

131126).

swallowed

and If

more

than

minul

from

hospllal.lnduee

vomiting,

preferably

using

Ipecac

Syrup

Brunnlngs

OaRlen

ProduCiS

Suite3/256

Jasper

Road

BenUelgh

VIc,

3204

(03)

95769901

Approval

Number

53000/0600

SAPETY

DIREC110NS

Harmful

absorbed

skin

contacl

Inhaled

swallowed.

Will

irritate

the eyes

ain.

Inhale

vapour.

When

opening

oonlalner

preparing

spray,

wear

cotton

overalll

buboned

ned<

orwri.1

equivalent),

washable

hal,

elbow

length

glovOl

anda

faee

shield

808g1

When

using

prepa

...d

spray,

wear

axton

overatla

buttoned

10the

neck

wrist

equivalent).

Wlshable

haland

elbow

IClIgih

PVCglov

. . .

IfproduCi

ey",

wash

Immediately

with

water.

Aftor

useand

bero

eating,

drinking

or

smoking,

wash

hands.

anna

and

face

thoroughty

with

soap

water.

After

each

day's

use,

wash

aJoves,

face

ableld

goggles

'contamln.1ed

clotlling.

STORAGE

DISPOSAL:

Store

inthe

closed,

original

container

In

a cool

dry

place

oul althe

reach

chlldreo.

store

dlreCisunltght.

Dispose

empty

container

wrapping

paper,

placing

plastic

bag.od

pUlling

garbage.

CAUTION:

allow

.pray

drift

contll:l

foliage

or

roots

want

ahrubl,

ftowm.

treea

or

vegetabl

. . .

apply

uoder

windy

oondltlons.

allrm

c~emic.a1

contalne",

spray

drains,

streanil

ponds.

spray

directly

on humus, petsor

food

preparation

areas.

Do

not

feed

trealed

grass

clippings

poultry

,livestock or

pets.

Dangerous

to

fish.

Do

nDI

contaminate

water

for

garden

or

domestic

supplies.

Treats 300 square metres.

(Picture)

CAUTION

Brunnings

Clover

Kill

Bindii &

500ml

CRITICAL COMMENTS: Weeds are killed

slowly over a period of

weeks.

HOW TO PREPARE: Shake contents well

before using. You can use tho inside of this

bottle

cap for measuring purposes. A

full

contains Bml,

USED

OTHER

PURPO$E OR

MANNER,

CONTRARY

TlDS

LABEL UNLESS

AUTHOKISED

.

RATE:

40ml in

1211tr08

water

square metres

80ml in 24 litres water

48 square metres

APPLY: Apply by

means

watering can with a sprinkle bar

a1tachment

coarse garden sprayer. Wash out spray

equipmeot thoroughly after use. Applywhen

weed is growing and rain is not expected.

WEEDS CONTROLLED:

BINDI!

(Jo-Jo,

Onehunga), CLOVERS,

Bmadleaf Weeds including Cudweed,

Wireweed,

Dandelion, Capeweed, Dock,

Lambs Tongue 'plantains, Creeping Oaalls (not

Tas).

SITUATION; Grass lawns and

turf.

USE:

NOT mow or fertlllse for

days before or after application.

apply if rain is

expected

within

hours. DO

apply

lawr,o

suffering

fmm stress. DO

NOT use on Buffalo Lawns. DO NOT

lawns less than 3 months old or

L1PPIA,

DICHONDRA or CLOVER lawnsor instant

Inwns unli16 weeks after laying.

BARCODE

Batch No.

N.R.A.

APPROVED

LABEL

(TEXT)

",n..

IN,,·

S?DOO

/0(;,00

Date'

IU··

.

tJ..

.I.C

l...A:n.".~\.

Signature:~a=~

········

········

····7

Page 1 of

13 June

2000

Bindii & Clover Con500ml

1

st

September 2009

Page 1 of 5

Material Safety Data Sheet

Product Name:

Bindii & Clover Con 500ml

1.

IDENTIFICATION OF THE MATERIAL AND SUPPLIER

Address:

Suite 3, 256 Jasper Road, McKinnon, Victoria, AUSTRALIA, 3204

Telephone:

(03) 9576 9901

Fax

(02) 9576 9902

Emergency

13 11 26

Use(s)

Selective herbicide to control bindii, clover and other broadleaf weeds in lawns.

MSDS Date

September 2009

2.

HAZARDS IDENTIFICATION

THIS MATERIAL IS HAZARDOUS ACCORDING TO CRITERIA OF ASCC; HAZARDOUS SUBSTANCE

NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE

UN No.

None Allocated

DG Class

None Allocated

Subsidiary Risk(s) None Allocated

Pkg Group

None Allocated

Hazchem Code

None Allocated

EPG

None Allocated

3.

COMPOSITION / INFORMATION ON INGREDIENTS

4.

FIRST AID MEASURES

Eye

If in eyes, hold eyelids apart and flush the eye continuously with running water. Continue flushing until advised to stop

by the Poison Information Centre or a doctor, or for at least 15 minutes.

Inhalation

Remove victim from area of exposure – avoid becoming a casualty. Seek immediate medical advice.

Skin

If skin contact occurs, remove contaminated clothing and wash skin with soap and water. If irritation occurs, seek

medical advice.

Ingestion

Rinse mouth with water. If swallowed, give a glass of water to drink. If vomiting occurs give further water. Seek

immediate medical assistance.

Ingredient

Formula

CAS No.

Content

MCPA

C9-H9-Cl-O3

94-74-6

13.5%

DICAMBA

Not Available

1918-00-9

2.3%

WATER

7732-18-5

>60%

WETTING AGENT

Not Available

Not Available

<1%

Bindii & Clover Con500ml

1

st

September 2009

Page 2 of 5

Advice to Doctor

Treat symptomatically.

5.

FIRE FIGHTING MEASURES

Hazards from combustion products

Non-combustible material. Decomposes on heating, emitting toxic fumes including those of hydrogen

chloride.

Fire and Explosion

Fire fighters to wear self-contained breathing apparatus and suitable protective clothing if risk of exposure to

products of decomposition.

Extinguishing

Not combustible, however, if material is involved in a fire use: Water fog (or if unavailable fine water spray),

foam, dry agent (carbon dioxide, dry chemical powder).

6.

ACCIDENTAL RELEASE MEASURES

Spillage

If spilt (bulk), contact emergency services where appropriate. Clear area of all unprotected personnel. Wear splash-

proof goggles, elbow-length PVC/rubber groves, a Type A (Organic vapour) respirator, coveralls and boots. Cover spill

with carbon (sand, vermiculite or similar) collect and place in sealable container for disposal.

Emergency procedures

If contamination of sewers or waterways has occurred advise local emergency services.

7.

STORAGE AND HANDLING

Storage

Store in a cool, dry, well ventilated place and out of direct sunlight. Keep containers closed when not in use – check

regularly for leaks.

Handling

Keep out of reach of children. Avoid skin and eye contact and breathing in vapour, mists and aerosols.

8.

EXPOSURE CONTROLS / PERSONAL PROTECTION

Occupational Exposure Limits

No value assigned for this specific material by the National Occupational Health and Safety Commission.

Engineering Controls

Natural ventilation should be adequate under normal use conditions. Keep containers closed when not in use.

PPE

Avoid contact with eyes and skin. Do NOT inhale spray mist. After use and before eating, drinking or smoking, wash

hands, arms and face thoroughly with soap and water.

Bindii & Clover Con500ml

1

st

September 2009

Page 3 of 5

9.

PHYSICAL AND CHEMICAL PROPERTIES

Appearance

CLEAR RED COLOUR

Solubility (water)

SOLUBLE

Odour

MILD AMMONIA ODOUR

Specific Gravity

1.05 (APPROX)

pH

NOT AVAILABLE

% Volatiles

NOT AVAILABLE

Vapour Pressure

NOT AVAILABLE

Flammability

NOT RELEVANT

Vapour Density

NOT AVAILABLE

Flash Point

NOT RELEVANT

Boiling Point

NOT AVAILABLE

Upper Explosion Limit

NOT RELEVANT

Melting Point

NOT AVAILABLE

Lower Explosion Limit

NOT RELEVANT

Evaporation Rate

NOT AVAILABLE

Autoignition Temperature

NOT RELEVANT

10.

STABILITY AND REACTIVITY

Chemical Stability

Stable under normal conditions.

Conditions to Avoid

Avoid contact with foodstuffs. Avoid exposure to heat, sources of ignition and open flame.

Material to Avoid

Incompatible with oxidising agents (eg. hypochlorites, peroxides), acids (eg. nitric acid) and alkalis (eg. hydroxides).

Decomposition

May evolve highly toxic gases (chlorides, hydrogen chloride, carbon oxides, hydrocarbons, phosgene) when heated to

decomposition.

11.

TOXICOLOGICAL INFORMATION

No adverse health effects expected if the product is handled in accordance with this Safety Data Sheet and the product

label. Symptoms or effects that may arise if the product is mishandled and overexposure occurs are:

Health Hazard Summary

No adverse health effects if the product is handled in accordance with this Safety data Sheet and the product label.

Symptoms or effects may arise if the product is mishandled and overexposure occurs are :-

Inhalation

Breathing in mists or aerosols may produce respiratory irritation.

Ingestion

Swallowing can result in nausea, vomiting, diarrhoea, and gastrointestinal irritation. Further symptoms may include

muscular spasms, urinary incontinence and dyspnea cyanosis.

Skin

Contact may result in irritation, redness, itching, pain and rash.

Eye

A severe eye irritant. Contamination of eyes can result in permanent injury.

Toxicity Data

No LD50 data available for the product. However, for constituent(s) (1)

Oral LD50 (rat):

700-1160 mg/kg (MCPA); 1707 mg/kg (Dicamba)

Dermal LD50 (rat):

>4000 mg/kg (MCPA); >2000 mg/kg (Dicamba)

Inhalation LC50 (rat):

>6.36 mg/L/4hr (MCPA)

Bindii & Clover Con500ml

1

st

September 2009

Page 4 of 5

12.

ECOLOGICAL INFORMATION

Environment

Limited eco-toxicity data was available for this product at the time this report was prepared. Ensure appropriate

measures are taken to prevent this product from entering the environment. Avoid contaminating waterways.

Aquatic toxicity

Toxic to fish.

13.

DISPOSAL CONSIDERATIONS

Waste Disposal

Rinse empty container, puncture and recycle or dispose of safely with domestic rubbish.

Legislation

Dispose of in accordance with relevant local legislation.

14.

TRANSPORT INFORMATION

NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE

NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE IMDG CODE

NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE IATA CODE

Shipping Name None Allocated

UN no.

None Allocated

DG Class

None Allocated

Subsidiary Risk(s) None Allocated

Pkg Group

None Allocated

Hazchem Code None Allocated

EPG

None Allocated

15.

REGULATORY INFORMATION

Classification

This material is hazardous according to criteria of ASCC; HAZARDOUS SUBSTANCE

Poison Schedule

Classified as a Schedule 5 (S5) Poison using the criteria in the Standard for the Uniform Scheduling of Drugs and Poisons

(SUSDP).

AICS

All chemicals listed on the Australian Inventory of Chemical Substances (AICS).

Hazard Category

Xi: Irritant

Risk Phase(s)

S23: Do not breathe capour/mist/aerosol

S24/25: Avoid contact with skin and eyes.

S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible)

Bindii & Clover Con500ml

1

st

September 2009

Page 5 of 5

16.

OTHER INFORMATION

Additional Information

RESPIRATORS:

In general the use of respirators should be limited and engineering controls employed to avoid exposure. If

respiratory equipment must be worn, ensure correct respirator selection and training is undertaken. Remember

that some respirators may be extremely uncomfortable when used for long periods. The use of air powered or air

supplied respirators should be considered where prolonged or repeated use is necessary

HERBICIDES:

Herbicides are classed as selective when they are used to kill weeds without harming the crop and as non-selective

when the purpose is to kill all vegetation. Herbicides can affect plants either by contact or translocation. Contact

herbicides kill the plant parts to which the chemical is applied, while translocated herbicides are absorbed either by

roots or above-ground parts of plants and then move within the plant system to distant tissues.

HEALTH EFFECTS FROM EXPOSURE:

It should be noted that the effects from exposure to this product will depend on several factors including: frequency

and duration of use; quantity used; effectiveness of control measures; protective equipment used and method of

application. Given that it is impractical to prepare a report which would encompass all possible scenarios, it is

anticipated that users will assess the risks and apply control methods where appropriate.

PERSONAL PROTECTIVE EQUIPMENT GUIDELINES

The recommendation for protective equipment contained within this report is provided as a guide only. Factors such

as method of application, working environment, quantity used, product concentration and the availability of

engineering controls should be considered before final selection of personal protective equipment is made.

Disclaimer

This document is based on information concerning the product which has been provided to BGP by the

manufacturer or obtained from third party sources and is believed to represent the current state of knowledge as to

the appropriate safety and handling precautions for the product at the time of issue.

While BGP has taken all due care to include accurate and up-to-date information in this MSDS, it does not provide any

warranty as to accuracy or completeness. As far as lawfully possible, BGP accepts no liability for any loss, injury or

damage (including consequential loss) which may be suffered or incurred by any person as a consequence

of their reliance on the information contained in this MSDS.

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