4FARMERS TRIADIMENOL 150 C FLOWABLE FUNGICIDE/INSECTICIDE SEED TREATMENT

Australia - English - APVMA (Australian Pesticides and Veterinary Medicines Authority)

Active ingredient:
CYPERMETHRIN; TRIADIMENOL
Available from:
4 FARMERS AUSTRALIA PTY LTD
INN (International Name):
triadimenol(150g/L)+cypermethrin(4g/L)
Pharmaceutical form:
SUSPENSION CONCENTRATE
Composition:
CYPERMETHRIN PYRETHROID Active 4.0 g/L; TRIADIMENOL TRIAZOLE Active 150.0 g/L
Units in package:
10L; 20L; 5L
Class:
A - Agricultural
Manufactured by:
4 FARMERS
Therapeutic group:
BARLEY | OATS | WHEAT
Therapeutic area:
MIXED FUNCTION SEED TREAT
Therapeutic indications:
BUNT | COVERED SMUT (BUNT) - TILLETIA SPP. | FLAG SMUT ON CEREAL | GRANARY WEEVIL | INDIAN MEAL MOTH | LEAF SCALD - SUPPRESSION | LESSER GRAIN BORER | LOOSE SMUT - USTILAGO AVENAE | POWDERY MILDEW OF SEEDLING INFECTION | RICE WEEVIL | RUST-RED FLOUR BEETLE | SAWTOOTHED GRAIN BEETLE | SPECKLED LEAF BLOTCH - SUPPRESSION | STRIPE RUST - SUPPRESSION | TROPICAL WAREHOUSE MOTH | BUNT | COMMON BUNT | GRAIN BORER | SEEDBORNE FLAG SMUT | SEEDLING INFECTIONS | SOILBORNE FLAG SMUT | TRILLETIA TRITICI | USTILAGO NUDA (TRITICI)
Product summary:
Poison schedule: 5; Withholding period: WHP: Do not graze or cut for stock feed within 5 weeks of sowing.; Host/pest details: BARLEY: [COVERED SMUT (BUNT) - TILLETIA SPP., GRANARY WEEVIL, INDIAN MEAL MOTH, LEAF SCALD - SUPPRESSION, LESSER GRAIN BORER, LOOSE SMUT - USTILAGO AVENAE, POWDERY MILDEW OF SEEDLING INFECTION, RICE WEEVIL, RUST-RED FLOUR BEETLE, SAWTOOTHED GRAIN BEETLE, STRIPE RUST - SUPPRESSION, TROPICAL WAREHOUSE MOTH]; OATS: [COVERED SMUT (BUNT) - TILLETIA SPP., GRANARY WEEVIL, INDIAN MEAL MOTH, LESSER GRAIN BORER, LOOSE SMUT - USTILAGO AVENAE, RICE WEEVIL, RUST-RED FLOUR BEETLE, SAWTOOTHED GRAIN BEETLE, TROPICAL WAREHOUSE MOTH]; WHEAT: [BUNT, FLAG SMUT ON CEREAL, GRANARY WEEVIL, INDIAN MEAL MOTH, LESSER GRAIN BORER, LOOSE SMUT - USTILAGO AVENAE, RICE WEEVIL, RUST-RED FLOUR BEETLE, SAWTOOTHED GRAIN BEETLE, SPECKLED LEAF BLOTCH - SUPPRESSION, STRIPE RUST - SUPPRESSION, TROPICAL WAREHOUSE MOTH]; For the control of bunt, smuts and suppression of leaf diseases in wheat, barley, and oats; For the protection against insect pests of stored grain.DO NOT treat physically damaged seed.
Authorization status:
Registered
Authorization number:
53583
Authorization date:
2020-07-01

Caution

KEEP OUT OF REACH OF CHILDREN

READ SAFETY DIRECTIONS BEFORE OPENING OR USING

TRIADIMENOL 150 C Flowable

Fungicide/Insecticide Seed Treatment

ACTIVE CONSTITUENTS:

150 gIL

TRIADIMENOL

4g/L

CYPERMETHRIN

GROUP

FUNGICIDE

GROUP

III

INSECTICIDE

I

Wheat:

For control

of bunt, flag smut and loose smut, and suppression of seedling stripe rust and

speckled leaf blotch.

Barley:

For control

of covered smut,

loose smut and powdery mildew and suppression of leaf scald.

Oats:

For control

of Loose and covered smut.

For protection against insect pests of

stored grain.

5L, (10 L

or 20 L)

NET

4 FARMERS PTY.

LTO.

A.C.N.

067443485

643 MURRAY STREET,

WEST PERTH,

WESTERN AUSTRALIA 6005

(08) 9356 3445

4 Farmers Triadimenol

150 C Flowable Fungicide/Insecticide Seed Treatment -

N.R.A.

~:~~~:~&~~€.Jl~~~.~

Date:

..1..5

.

./09./

./:~.:d-l

Signature:

.....

.).~

Page 1 of

12/12/01

GENERAL INSTRUCTIONS

In Wheat:

4Farmers Triadimenol

150 C Flowable Fungicidellnsecticide Seed Treatment,

especially at the higher rate of

150 mL /

100 Kg seed,

may delay emergence.

Crop will

recover

rapidly in moist soil

types.

However,

seed treated with the 150 mL /

100 Kg seed,

should not be

sown in soils that

are likely to clod or crust over after sowing.

Sowing 4Farmers Triadimenol

150 C

Flowable Fungicide/Insecticide Seed Treatment treated wheat deeper that

50 mm may slightly

reduce percentage plant

establishment in heavier soils and sowing rates may need to be adjusted

accordingly.

The possible delay in emergence of wheat treated with the 150 mL /

100 Kg seed

rate may counteract the advantage of suppression of

speckled leaf blotch.

Germination may be

reduced if poor quality seed is used (cracked or shrivelled) -

best to use high quality seed.

Treated seed may be held over for sowing in the following season.

If so, additional

insecticide

treatment may be necessary.

If the seed is not used immediately after treatment,

it should be

stored in a dry, well

ventilated place. Treated seed which will

not used for sowing at all

should be

destroyed.

FUNGICIDE RESISTANCE WARNING:

Triadimenolis

Group

C Fungicide and a member

the D.M.I

group of

fungicides.

fungicide resistance management,

4Farmers Triadimenol

150 C Flowable Fungicide/Insecticide

Seed Treatment is a

Group

C fungicide.

Some naturally occurring individual

fungi

resistant

to 4Farmers Triadimenol

150 C Flowable

Fungicidellnsecticide Seed Treatment

and other

Group C fungicides may exist

through normal

genetic variability in any fungal

population.

The resistant

individuals can eventually dominate the

fungi

population

these

fungicides

are used

repeatedly.

These resistant

fungi

will

controlled by 4Farmers Triadimenol

150 C Flowable Fungicidellnsecticide Seed Treatment

other

Group

C fungicides,

thus resulting in efficacy and possible yield loss.

Since the occurrence of

resistant

fungi

is difficult to detect prior to use,

4Farmers Pty Ltd accepts

no liability for any losses that

may result from the failure of 4Farmers Triadimenol

150 C Flowable

Fungicidellnsecticide Seed Treatment to control

resistant fungi.

INSECTICIDE RESISTANCE WARNING:

GROUP

III

INSECTICIDE

For insecticide resistance management 4FARMERS TRIADIMENOL 150 C Flowable

Fungicidellnsecticide Seed Treatment is a Group 3A insecticide.

Some naturally occurring insect

biotypes resistant to 4FARMERS TRIADIMENOL 150 C Flowable Fungicide/Insecticide Seed

Treatment and other Group 3A insecticides may exist through normal

genetic variability in any

insect

population.

The resistant

individuals can eventually dominate the insect

population if

4FARMERS TRIADIMENOL 150 C Flowable Fungicide/Insecticide Seed Treatment or other

Group 3A insecticides are used repeatedly.

The effectiveness of 4FARMERS TRIADIMENOL 150

C Flowable Fungicide/lnsecticide Seed Treatment on resistant individuals could be significantly

reduced.

4 Farmers Triadimenol150 C Flowable Fungicide/Insecticide Seed Treatment -

Page 2 of

12/12/01

Since occurrence

resistant individuals is difficult to detect prior to use,

4 Farmers Pty Ltd

accepts no liability for any losses that may result

from the failure of 4FARMERS TRIADIMENOL

150 C Flowable Fungicide/lnsecticide Seed Treatment to control

resistant

insects.

4FARMERS TRIADIMENOL 150 C Flowable Fungicide/lnsecticide Seed Treatment may be

subject to specific resistance management strategies.

For further information,

contact your local

supplier,

4Farmers Pty Ltd representative or local

agricultural

department agronomist.

MIXING for

in a pickle pot or similar (liquid application)

The required quantity of

4Farmers Triadimenol

150 C Flowable Fungicide/Insecticide Seed

Treatment

should be thoroughly mixed with a small

quantity

clean,

filtered water to make a

creamy mix.

Add this blend to the required quantity

water in the tank and mix thoroughly.

Agitate prior to and during spraying.

DO NOT mix more than can be used for the day's seeding.

DO NOT tank mix with trace elements or other chemicals without first checking compatibility.

SEED QUALITY

4Farmers Pty Ltd TRIADIMENOL 150 C Flowable Fungicide/lnsecticide Seed Treatment should

not be used on seed with more than 12% moistu re content,

as the treatment

can raise the level

0.6%.

Seed to be treated should be

the highest quality.

Poor quality (sprouted,

cracked,

pinched etc.)

seed

should not

be used.

Cleaning of equipment:

Clean equipment (augers etc.) with water after use.

If changing from this water based product to

an EC formulated product or vice versa,

ensure complete dryness with Methylated spirits (or

similar).

Failure to do so will

result

in clogging

equipment.

PRECAUTION:

If possible,

use a separate auger for treating seed.

If using the same auger

treating grain and

moving grain for human consumption,

ensure auger is completely cleaned as above.

PROTECTION OF LIVESTOCK

Seed treated with this product must not

be used for animal

consumption,

poultry feed or

mixed with animal

feed.

DO NOT allow seed treated with this product to contaminate grain intended for animal

consumption.

PROTECTION OF WILDLIFE,

FISH,

CRUSTACEA

ENVIRONMENT

DO NOT feed treated seed or otherwise expose to wild or domestic birds or other animals.

Harmful

to fish.

DO NOT contaminate

streams,

rivers,

dams

waterways

with

chemical

used

containers.

Used containers or bags which have held treated seed must be correctly disposed of.

Storage and Disposal

and Protection of Others.

When treated seed is stored it should be kept

apart from other grain.

Such bags or other

containers should

clearly be marked to indicate

contents have been treated with 4Farmers

Triadimenol

150 C Flowable fungicide seed treatment.

4 Farmers Triadimenol150 C Flowable Fungicide/Insecticide Seed Treatment-

Page 3 of

12/12/01

Store the unused product

in the closed original

container in a cool, well

ventilated area.

Do not

store for prolonged periods in direct

sunlight.

Do not allow seed treated with this product

to contaminate grain intended for human consumption.

Do not use seed treated with 4Farmers Triadimenol

150 C Flowable Fungicide/Insecticide Seed

Treatment for human consumption.

Bags which have held seed treated with this product

are not to be used for any other purpose.

Triple rinse containers that

have held the chemical

product

before disposal

and add rinsings to the

spray tank.

DO NOT dispose of undiluted chemicals on site.

Puncture

&

bury empty containers in

a local

authority land fill.

If no land fill

available,

bury containers to a depth of

500 mm in a

disposal

pit specifically marked and set up for this purpose,

clear of waterways,

desirable

vegetation and tree roots. Empty containers and product

should not be burnt.

SAFETY DIRECTIONS:

May irritate the eyes and skin.

Facial

skin contact

may cause temporary facial

numbness.

Avoid contact with eyes and skin

Do not

inhale mist.

Wear a face mask while handling the product and treated seed.

After

use and before eating,

drinking or smoking,

wash hands,

arms and face thoroughly with

soap and water.

FIRST AID:

If poisoningoccurs,

contact

a doctor or Poisons Information Centre (Phone:

131126)

further

information

see Material

Safety Data Sheet

which

can be obtained from the

supplier.

CONDITIONS OF SALE:

The use of

4Farmers Triadimenol

150 C Flowable Fungicide/lnsecticide Seed Treatment,

being

beyond the control

the manufacturer,

no warranty expressed or

implied is given by 4Farmers

Pty.

Ltd.

regarding its suitability,

fitness or

efficacy for

any purpose for

which it

is used by the

buyer,

whether

in accordance with the directions or

and 4Farmers Pty.

ltd.

accepts

responsibility for any consequences whatsoever resulting from the use of this product.

4 Farmers Triadimenol150 C Flowable Fungicide/Insecticide Seed Treatment-

Page 4 of

12/12/01

DIRECTIONS

RESTRAINT:

DO NOT treat

physically damaged seed.

Croo

Disease

1

Pest

State

Rate

Critical

Comments

Wheat

Bunt, Flag smut (seed and

NSW,

100 mL

Thorough mixing is essential.

Ensure

soil

borne), loose smut.

ACT,

/100

that

recommended

rate is applied

Suppression of seedling

TASSA

seed

evenly

over

seed.

infections of strioe rust.

WAONLY

minimum

mL and a maximum

Oats

Covered and loose smut

mixture

Barley

Covered and loose smut,

(Triadimenol

water)

suppression of seedling

seed.

Gently

stir

mixture

infections of oowderv mildew

Suppression of seedling

NSWACT

regularly.

infections of leaf scald

SAWA

Use the 150

U100

Kg seed rate in areas

ONLY

where foliar diseases frequently occur

Wheat

Bunt, flag smut (seed and

NSWACT

150

mU

and where any of the following are

soil

borne), loose smut.

VICTAS

100 Kg

required:

Suppression of seedling

seed

- Longer suppression of stripe rust on

infections of stripe rust.

ONLY

seedlings

Suppression of seedling

NSWACT

-control

of seeding infections of powdery

infections of speckled leaf

VICTAS

mildew

-suppression of speckled leaf blotch

blotch

ONLY

wheat

Barley

Covered and loose smut,

NSWACT

- extended suppression of leaf scald in

control

of seedling infections

VICTAS

barley: and use higher rate on more

of powdery mildew.

susceptible varieties or where disease

Suppression of seedling

ONLY

pressure is heavy

infections of leaf scald

Wheat

Protection against insect

100 or

Both rates give protection against

Barley

pests of stored grains:

insect pests.

rate appropriate to

Oats

Granary weevil, Indian meal

TASSA

100 Kg

disease

control

required.

moth, Lesser grain borer,

WAONLY

seed

Rice weevil, Rust-red Flour

beetle, Sawtooth grain

beetle, Tropical

warehouse

moth

NOT TO BE USED FOR ANY PURPOSE, OR IN ANY MANNER, CONTRARY TO THIS LABEL UNLESS

AUTHORISED UNDER APPROPRIATE LEGISLATION.

WITHHOLDING PERIOD:

DO NOT GRAZE OR CUT FOR STOCK FEED WITHIN 5 WEEKS OF SOWING

IN A TRANSPORT EMERGENCY DIAL 000 POLICE OR FIRE BRIGADE.

APPROVAL

NO.:

53583/1201

Batch No.:

Date

Manufacture:

Farmers

Triadimenol150 C

Flowable

Fungicidellnsecticide

Seed

Treatment

Page

5 of

12/12/01

4Farmers Triadimenol 150 C Flowable Fungicide/Insecticide

Hazard Alert Code: MODERATE

Chemwatch Material Safety Data Sheet

Issue Date: 22-Sep-2009

CHEMWATCH 21-1254

XC9317SC

Version No:2.0

CD 2011/1 Page 1 of 8

Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME

4Farmers Triadimenol 150 C Flowable Fungicide/Insecticide

SYNONYMS

"4Farmers Triadimenol 150 C Flowable Fungicide/Insecticide Seed Treatment", "4Farmers Triadimenol SC Seed Dressing"

PRODUCT USE

Dressing for cereal grain to control insects during storage and diseases during growth.

SUPPLIER

Company: 4Farmers

Address:

1/70 McDowell Street

Welshpool, 6106

Australia

Telephone: +61 8 9356 3445

Fax: +61 8 9356 3447

Email: admin@4farmers.com.au

Website: http://www.4farmers.com.au/msds/

Section 2 - HAZARDS IDENTIFICATION

STATEMENT OF HAZARDOUS NATURE

HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS. According to NOHSC Criteria, and ADG Code.

CHEMWATCH HAZARD RATINGS

Flammability

Toxicity

Body Contact

Reactivity

Chronic

SCALE:

Min/Nil=0

Low=1

Moderate=2

High=3

Extreme=4

RISK

SAFETY

■ Irritating to eyes, respiratory system and

Do not breathe gas/fumes/vapour/spray.

skin.

■ Limited evidence of a carcinogenic effect.

Use only in well

ventilated areas.

■ Toxic to aquatic organisms, may cause long-

Keep container in a well

ventilated place.

term adverse effects in the aquatic

environment.

■ Inhalation, skin contact and/or ingestion

Avoid exposure - obtain special instructions

may produce health damage*.

before use.

■ Cumulative effects may result following

To clean the floor and all

objects contaminated

exposure*.

by this material, use water.

■ May possibly affect fertility*.

Keep container tightly closed.

■ May possibly be harmful to the foetus/

This material

and its container must be disposed

embryo*.

of in a safe way.

■ Possible risk of harm to breastfed babies*.

Keep away from food, drink and animal

feeding

stuffs.

continued...

4Farmers Triadimenol 150 C Flowable Fungicide/Insecticide

Hazard Alert Code: MODERATE

Chemwatch Material Safety Data Sheet

Issue Date: 22-Sep-2009

CHEMWATCH 21-1254

XC9317SC

Version No:2.0

CD 2011/1 Page 2 of 8

Section 2 - HAZARDS IDENTIFICATION

* (limited evidence).

In case of contact with eyes, rinse with plenty

of water and contact Doctor or Poisons Information

Centre.

If swallowed, IMMEDIATELY contact Doctor or

Poisons Information Centre. (show this container

or label).

Use appropriate container to avoid environmental

contamination.

Avoid release to the environment. Refer to

special instructions/Safety data sheets.

Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS

NAME

CAS RN

triadimenol

55219-65-3

cypermethrin

52315-07-8

glycerol

56-81-5

10-30

dye, emulsifier, inerts, gum

<30

water

7732-18-5

balance

Section 4 - FIRST AID MEASURES

SWALLOWED

IF SWALLOWED, REFER FOR MEDICAL ATTENTION, WHERE POSSIBLE, WITHOUT DELAY.

For advice, contact a Poisons Information Centre or a doctor.

Urgent hospital treatment is likely to be needed.

In the mean time, qualified first-aid personnel should treat the patient following observation and employing supportive

measures as indicated by the patient's condition.

EYE

■ If this product comes in contact with the eyes:

Wash out immediately with fresh running water.

Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting

the upper and lower lids.

Seek medical attention without delay; if pain persists or recurs seek medical attention.

Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.

SKIN

■ If skin contact occurs:

Immediately remove all contaminated clothing, including footwear.

Flush skin and hair with running water (and soap if available).

Seek medical attention in event of irritation.

INHALED

If fumes or combustion products are inhaled remove from contaminated area.

Lay patient down. Keep warm and rested.

Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid

procedures.

Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket

mask as trained. Perform CPR if necessary.

NOTES TO PHYSICIAN

■ Treat symptomatically.

Following exposures to chlorophenoxy compounds:

Acute toxic reactions are rare. The by-product of production, dioxin, may be implicated in subacute features such as hepatic

enlargement, chloracne, neuromuscular symptoms and deranged porphyrin metabolism.

Large intentional

overdoses result in coma, metabolic acidosis, myalgias, muscle weakness, elevated serum creatine kinase,

myoglobinuria, irritation of the skin, eyes, respiratory tract and gut and mild renal and hepatic dysfunction.

Several cases of sensorimotor peripheral neuropathies have been associated with chronic dermal exposure to 2,4-D. For acute

exposures the usual methods of gut and skin contamination (lavage, charcoal, cathartic) are recommended in the first several

hours. Alkalisation of the urine and generous fluid replacement have the added benefit of treating any myoglobinuria present.

Monitor metabolic acidosis, hyperthermia, hyperkalaemia, myoglobinuria and hepatic/renal dysfunction. for 2,4-

continued...

4Farmers Triadimenol 150 C Flowable Fungicide/Insecticide

Hazard Alert Code: MODERATE

Chemwatch Material Safety Data Sheet

Issue Date: 22-Sep-2009

CHEMWATCH 21-1254

XC9317SC

Version No:2.0

CD 2011/1 Page 3 of 8

Section 4 - FIRST AID MEASURES

dichlorophenoxyacetic acid (2,4-D) and its derivatives

Gastric lavage if there are no signs of impending convulsions.

Section 5 - FIRE FIGHTING MEASURES

EXTINGUISHING MEDIA

Water spray or fog.

Foam.

Dry chemical

powder.

BCF (where regulations permit).

FIRE FIGHTING

Alert Fire Brigade and tell

them location and nature of hazard.

Wear full

body protective clothing with breathing apparatus.

Prevent, by any means available, spillage from entering drains or water course.

Use water delivered as a fine spray to control fire and cool

adjacent area.

FIRE/EXPLOSION HAZARD

Combustible.

Slight fire hazard when exposed to heat or flame.

Heating may cause expansion or decomposition leading to violent rupture of containers.

On combustion, may emit toxic fumes of carbon monoxide (CO).

Combustion products include: carbon dioxide (CO2), hydrogen chloride, phosgene, nitrogen oxides (NOx), other pyrolysis products

typical

of burning organic material.

May emit poisonous fumes.

May emit corrosive fumes.

FIRE INCOMPATIBILITY

Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool

chlorine etc. as ignition may

result.

HAZCHEM

None

Personal Protective Equipment

Breathing apparatus.

Chemical splash suit.

Section 6 - ACCIDENTAL RELEASE MEASURES

MINOR SPILLS

Remove all

ignition sources.

Clean up all

spills immediately.

Avoid breathing vapours and contact with skin and eyes.

Control personal contact by using protective equipment.

MAJOR SPILLS

■ Moderate hazard.

Clear area of personnel and move upwind.

Alert Fire Brigade and tell

them location and nature of hazard.

Wear breathing apparatus plus protective gloves.

Prevent, by any means available, spillage from entering drains or water course.

Personal Protective Equipment advice is contained in Section 8 of the MSDS.

continued...

4Farmers Triadimenol 150 C Flowable Fungicide/Insecticide

Hazard Alert Code: MODERATE

Chemwatch Material Safety Data Sheet

Issue Date: 22-Sep-2009

CHEMWATCH 21-1254

XC9317SC

Version No:2.0

CD 2011/1 Page 4 of 8

Section 7 - HANDLING AND STORAGE

PROCEDURE FOR HANDLING

DO NOT allow clothing wet with material to stay in contact with skin.

Avoid all personal contact, including inhalation.

Wear protective clothing when risk of exposure occurs.

Use in a well-ventilated area.

Prevent concentration in hollows and sumps.

SUITABLE CONTAINER

Metal can or drum

Packaging as recommended by manufacturer.

Check all containers are clearly labelled and free from leaks.

STORAGE INCOMPATIBILITY

■ High nitrogen compounds are often unstable or explosive; the tendency is exaggerated by attachment of azide or diazonium groups,

or a high-nitrogen heterocyclic nucleus.

High-nitrogen chemical families include

azides

diazoazoles

diazonium salts

hydrazinium salts.

Avoid reaction with oxidising agents.

STORAGE REQUIREMENTS

Store in original containers.

Keep containers securely sealed.

No smoking, naked lights or ignition sources.

Store in a cool, dry, well-ventilated area.

Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION

EXPOSURE CONTROLS

Source

Material

TWA ppm TWA

STEL

STEL

Peak

Peak

Notes

mg/m³

mg/m³

mg/m³

F/CC

___________

___________

_______

_______

_______

_______

_______

_______

_______

_______

Australia

4Farmers

Exposure

Triadimenol

150 C

Standards

Flowable

Fungicide/Insecti

cide (Pyrethrum)

Australia

glycerol

(see

Exposure

(Glycerin mist

Chapter

Standards

(a))

The following materials had no OELs on our records

triadimenol:

CAS:55219- 65- 3 CAS:89482- 17- 7 CAS:82200- 72- 4

water:

CAS:7732- 18- 5

PERSONAL PROTECTION

RESPIRATOR

type a-p filter of sufficient capacity.

continued...

4Farmers Triadimenol 150 C Flowable Fungicide/Insecticide

Hazard Alert Code: MODERATE

Chemwatch Material Safety Data Sheet

Issue Date: 22-Sep-2009

CHEMWATCH 21-1254

XC9317SC

Version No:2.0

CD 2011/1 Page 5 of 8

Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION

EYE

Safety glasses with side shields.

Chemical goggles.

Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document,

describing the wearing of lens or restrictions on use, should be created for each workplace or task. This should include a

review of lens absorption and adsorption for the class of chemicals in use and an account of injury experience. Medical

first-aid personnel should be trained in their removal and suitable equipment should be readily available. In the event of

chemical

exposure, begin eye irrigation immediately and remove contact lens as soon as practicable. Lens should be removed at

the first signs of eye redness or irritation - lens should be removed in a clean environment only after workers have washed

hands thoroughly. [CDC NIOSH Current Intelligence Bulletin 59].

HANDS/FEET

Wear chemical

protective gloves, eg. PVC.

Wear safety footwear or safety gumboots, eg. Rubber.

Suitability and durability of glove type is dependent on usage. Important factors in the selection of gloves include: such as:

frequency and duration of contact,

chemical

resistance of glove material,

glove thickness and

dexterity.

OTHER

Overalls.

P.V.C. apron.

Barrier cream.

Skin cleansing cream.

ENGINEERING CONTROLS

■ Local

exhaust ventilation usually required. If risk of overexposure exists, wear approved respirator.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

APPEARANCE

Dark blue, viscous liquid with slight odour; mixes with water.

PHYSICAL PROPERTIES

Liquid.

Mixes with water.

State

Liquid

Molecular Weight

Not Applicable

Melting Range (°C)

<0

Viscosity

Not Available

Boiling Range (°C)

100 approx

Solubility in water (g/L)

Miscible

Flash Point (°C)

Not Available

pH (1% solution)

Not Available

Decomposition Temp (°C)

Not Available

pH (as supplied)

Autoignition Temp (°C)

Not Available

Vapour Pressure (kPa)

Not Available

Upper Explosive Limit (%)

Not Available

Specific Gravity (water=1)

1.2 approx

Lower Explosive Limit (%)

Not Available

Relative Vapour Density

Not Available

(air=1)

Volatile Component (%vol)

Not Available

Evaporation Rate

Not Available

glycerol

log Kow (Sangster 1997):

- 1.76

Section 10 - STABILITY AND REACTIVITY

CONDITIONS CONTRIBUTING TO INSTABILITY

Presence of incompatible materials.

Product is considered stable.

Hazardous polymerisation will not occur.

For incompatible materials - refer to Section 7 - Handling and Storage.

continued...

4Farmers Triadimenol 150 C Flowable Fungicide/Insecticide

Hazard Alert Code: MODERATE

Chemwatch Material Safety Data Sheet

Issue Date: 22-Sep-2009

CHEMWATCH 21-1254

XC9317SC

Version No:2.0

CD 2011/1 Page 6 of 8

Section 11 - TOXICOLOGICAL INFORMATION

POTENTIAL HEALTH EFFECTS

ACUTE HEALTH EFFECTS

CHRONIC HEALTH EFFECTS

■ Irritating to eyes, respiratory system and skin.

■ Limited evidence of a carcinogenic

effect.

■ Inhalation, skin contact and/or ingestion may produce

■ May possibly affect fertility*.

health damage*.

■ * (limited evidence).

■ May possibly be harmful to the foetus/

embryo*.

■ Cumulative effects may result following

exposure*.

■ Possible risk of harm to breastfed

babies*.

■ * (limited evidence).

TOXICITY AND IRRITATION

■ For chlorophenoxy pesticides:.

WARNING: This substance has been classified by the IARC as Group 2B: Possibly Carcinogenic to Humans.

Side-reactions during manufacture of the parent compound may result in the production of trace amounts of polyhalogenated

aromatic hydrocarbon(s). Halogenated phenols, and especially their alkali

salts, can condense above 300 deg.

Polyhalogenated aromatic hydrocarbons (PHAHs) comprise two major groups. The first group represented by the halogenated

derivatives of dibenzodioxins (the chlorinated form is PCDD), dibenzofurans (PCDF) and biphenyls (PCB) exert their toxic effect

(as hepatoxicants, reproductive toxicants, immunotoxicants and procarcinogens) by interaction with a cytostolic protein known as

the Ah receptor.

Section 12 - ECOLOGICAL INFORMATION

Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Avoid release to the environment.

Refer to special instructions/ safety data sheets.

Ecotoxicity

Ingredient

Persistence:

Persistence: Air

Bioaccumulation

Mobility

Water/Soil

4Farmers Triadimenol

150 C

No Data

No Data

Flowable Fungicide/Insecticide

Available

Available

triadimenol

HIGH

No Data

Available

cypermethrin

HIGH

No Data

Available

glycerol

No Data

HIGH

Available

Section 13 - DISPOSAL CONSIDERATIONS

Containers may still present a chemical hazard/ danger when empty.

Return to supplier for reuse/ recycling if possible.

Otherwise:

If container can not be cleaned sufficiently well to ensure that residuals do not remain or if the container cannot be used to

store the same product, then puncture containers, to prevent re-use, and bury at an authorised landfill.

Where possible retain label warnings and MSDS and observe all notices pertaining to the product.

Legislation addressing waste disposal requirements may differ by country, state and/ or territory. Each user must refer to laws

operating in their area.

A Hierarchy of Controls seems to be common - the user should investigate:

Reduction.

DO NOT allow wash water from cleaning or process equipment to enter drains.

It may be necessary to collect all wash water for treatment before disposal.

continued...

4Farmers Triadimenol 150 C Flowable Fungicide/Insecticide

Hazard Alert Code: MODERATE

Chemwatch Material Safety Data Sheet

Issue Date: 22-Sep-2009

CHEMWATCH 21-1254

XC9317SC

Version No:2.0

CD 2011/1 Page 7 of 8

Section 13 - DISPOSAL CONSIDERATIONS

In all cases disposal to sewer may be subject to local laws and regulations and these should be considered first.

Where in doubt contact the responsible authority.

Recycle wherever possible or consult manufacturer for recycling options.

Consult State Land Waste Authority for disposal.

Bury or incinerate residue at an approved site.

Recycle containers if possible, or dispose of in an authorised landfill.

Section 14 - TRANSPORTATION INFORMATION

HAZCHEM:

None

(ADG7)

NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS: UN, IATA, IMDG

Section 15 - REGULATORY INFORMATION

POISONS SCHEDULE None

REGULATIONS

Regulations for ingredients

triadimenol (CAS: 55219-65-3,89482-17-7,82200-72-4) is found on the following regulatory lists;

"Australia ADI list - Acceptable daily intakes for agricultural and veterinary chemicals","Australia Inventory of Chemical

Substances (AICS)","Australia New Zealand Food Standards Code - Maximum Residue Limits (Australia only) - Schedule 1","OECD

Representative List of High Production Volume (HPV) Chemicals"

cypermethrin (CAS: 52315-07-8,69865-47-0,86752-99-0,86753-92-6,88161-75-5,97955-44-7,137497-61-

1,139203-31-9,142443-95-6,146909-55-9,186554-45-0,67375-30-8,65731-84-2,71697-59-1) is found

on the following regulatory lists;

"Australia ADI list - Acceptable daily intakes for agricultural and veterinary chemicals","Australia Hazardous Substances",

"Australia Inventory of Chemical Substances (AICS)","Australia New Zealand Food Standards Code - Maximum Residue Limits

(Australia only) - Schedule 1","Australia New Zealand Food Standards Code - Maximum Residue Limits (Australia only) - Schedule 3 -

Chemical Groups","Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 6","OSPAR Substances

removed from the List of Substances of Possible Concern","WHO Guidelines for Drinking-water Quality - Chemicals excluded from

guideline value derivation"

glycerol (CAS: 56-81-5) is found on the following regulatory lists;

"Australia Exposure Standards","Australia High Volume Industrial Chemical List (HVICL)","Australia Inventory of Chemical

Substances (AICS)","Australia Therapeutic Goods Administration (TGA) Substances that may be used as active ingredients in Listed

medicines","CODEX General Standard for Food Additives (GSFA) - Additives Permitted for Use in Food in General, Unless Otherwise

Specified, in Accordance with GMP","GESAMP/EHS Composite List - GESAMP Hazard Profiles","IMO IBC Code Chapter 18: List of

products to which the Code does not apply","IMO MARPOL 73/78 (Annex II) - List of Other Liquid Substances","International Council

of Chemical Associations (ICCA) - High Production Volume List","International Fragrance Association (IFRA) Survey: Transparency

List","OECD Representative List of High Production Volume (HPV) Chemicals"

water (CAS: 7732-18-5) is found on the following regulatory lists;

"Australia Inventory of Chemical Substances (AICS)","IMO IBC Code Chapter 18: List of products to which the Code does not apply",

"International Fragrance Association (IFRA) Survey: Transparency List","OECD Representative List of High Production Volume (HPV)

Chemicals"

No data for 4Farmers Triadimenol 150 C Flowable Fungicide/Insecticide (CW: 21-1254)

continued...

4Farmers Triadimenol 150 C Flowable Fungicide/Insecticide

Hazard Alert Code: MODERATE

Chemwatch Material Safety Data Sheet

Issue Date: 22-Sep-2009

CHEMWATCH 21-1254

XC9317SC

Version No:2.0

CD 2011/1 Page 8 of 8

Section 16 - OTHER INFORMATION

Denmark Advisory list for selfclassification of dangerous substances

Substance

Suggested codes

triadimenol

55219- 65- 3

N; R51/53

cypermethrin

65731- 84- 2

Mut3; R68 N;

R50/53

INGREDIENTS WITH MULTIPLE CAS NUMBERS

Ingredient Name

triadimenol

55219-65-3,

89482-17-7,

82200-72-4

cypermethrin

52315-07-8,

69865-47-0,

86752-99-0,

86753-92-6,

88161-75-5,

97955-44-7,

137497-61-1,

139203-31-9,

142443-

95-6,

146909-55-9,

186554-45-0,

67375-30-8,

65731-84-2,

71697-59-1

■ Classification of the preparation and its individual components has drawn on official and authoritative sources as well as

independent review by the Chemwatch Classification committee using available literature references.

A list of reference resources used to assist the committee may be found at:

www.chemwatch.net/references.

■ The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether

the reported Hazards are Risks in the workplace or other settings.

This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or

criticism, as permitted under the Copyright Act, no part may be reproduced by any process without written

permission from CHEMWATCH. TEL (+61 3) 9572 4700.

Issue Date: 22-Sep-2009

Print Date: 31-May-2011

This is the end of the MSDS.

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