4FARMERS TRIADIMEFON 500 FUNGICIDE W.P.

Australia - English - APVMA (Australian Pesticides and Veterinary Medicines Authority)

Active ingredient:
TRIADIMEFON
Available from:
4 FARMERS AUSTRALIA PTY LTD
Class:
AgChem
Therapeutic group:
BARLEY | WHEAT
Therapeutic area:
FUNGICIDE
Therapeutic indications:
LEAF RUST | POWDERY MILDEW | SEPTORIA TRITICI BLOTCH | STRIPE RUST | TAKE-ALL OF WHEAT | PUCCINIA RECONDITA F.SP. TRITI | PUCCINIA TRITICINA | SEPTORIA TRITICI | TAKE-ALL OF WHEAT - SUPPRESSIO | WHEAT LEAF RUST | YELLOW RUST
Authorization status:
Registered
Authorization number:
50160
Authorization date:
2000-10-17

Material Safety Data Sheet

Triadimefon 500 WP

1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER

Producttrade name: 4Farmers Triadimefon 500 WPFungicide.

Other names:

Recommended use: Agriculturalfungicide for controlof diseases incereals and other crops.

Companyname& address: 4Farmers Pty. Ltd.

A.C.N 067 443 485

70 McDowellSt, Welshpool, Western Australia, 6106.

Ph:(08) 9356 3445 Fax (08) 9356 3447

2. HAZARDS IDENTIFICATION

Hazard classification: Hazardousaccording to the criteria of NOHSC. Non-dangerous goods.

Risk phrases: R20 Harmfulbyinhalation.

R22Harmful if swallowed.

R36Irritatingtoeyes.

R37Irritatingtorespiratory system.

Safetyphrases: S20/21 When using do noteator drink/smoke

S24/25 Avoid contactwithskin/eyes

S29/35 Do notemptyintodrains/Dispose of materialand container ina safe way

SUSDP Classification: S6

ADG Classification: Nota dangerous good

UN Number: None allocated

3. COMPOSITION

Substance CAS Number % content

Triadimefon43121-43-350

Surfactants 5

Calciumcarbonate 471-34-1 To 100.

4. FIRST AID MEASURES

Skincontact: Remove contaminated clothing. Wash contaminated skinwithsoapy water. If

skinirritation develops, getmedicalattention. Wash clothing thoroughlybefore re-use.

Eye contact: Rinse eye(s) withclean running water for 15 mins. Getmedicalattention.

Ingestion: Rinse mouth. Give water todrink ifpatientisconscious. DO NOT induce

vomiting. If vomiting occurs ensure patientcan breathe, then give water todrink. Getmedicalattention.

Advice todoctor: No specific antidote isknown. Treatsymptomatically.

5. FIRE FIGHTING MEASURES

Suitable extinguishing media:Carbon dioxide, drychemical, foam, water fog, water stream.

Unsuitable extinguishing media:

Special hazards in fire: Product is not flammable. Will burn if heated by combustion of other

compounds. Combustion mayrelease carbon dioxide,nitrogen oxides, and/or chlorine compounds.

Required specialprotective equipmentfor fire-fighters: Wear selfcontained breathing apparatus ifin

enclosed space.

Hazchemcode:

6. ACCIDENTAL RELEASE MEASURES

Emergencyprocedures: Wear protective equipment to prevent skin and eyes being affected.

Evacuate unprotected and unnecessarypersonnel fromarea of spill.

If material is spilling froma container, stop the spillage onlyif this can be done safely.

Prevent spillage enteringdrains orwatercourse.

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Material Safety Data Sheet

Triadimefon 500 WP

Methods for containment & cleanup: Spilt powder may need to be dampenedto settle dust. Mixing with damp

soil will helpif this is practicable.

Soil can be used to formbunds to contain spillage.

Contaminated soil should be collectedfor disposal at a suitable landfill.

Contaminated area and tools should be washed downwith hypochlorite bleach.

Personalprotective equipmentand clothingshould be washed withsoapywater.

7. HANDLING AND STORAGE

Handling: Keep awayfromfood, drink, and animalfeedstuff.

KEEP OUT OF REACH OF CHILDREN.

Wear suitable Personalprotective equipmentwhen handling and spraying.

Storage: Store inthe original container ina dry, cool, ventilated,LOCKED area.

DO NOT store inprolonged sunlight.

DO NOT store withfood, seed, or animalfeedstuff.

8. EXPOSURE CONTROLS

Nationalexposure standards:The ADI for Triadimefon issetat0.03mg/kg/day. The corresponding NOEL is

setat2.5mg/kg/day. No exposure limitshave been set.

Engineering measures: Use assisted ventilation in enclosed spaces if needed,especially storage areas.

Personalprotection equipment:

Eye/face protection: Goggles orglasses to AS 1366, AS/NZS1337

Hand/skin protection: Overalls, PVC gloves and apron, face shield

Respiratory protection: Shouldnot be necessary under normal conditions. If spray mist may be

encountered, a particulate filterto AS/NZS 1715 should be worn.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance: White, micro-fine powder insoluble bags.

Odour: Alkaline, irritating limestone.

pH: Very alkaline reactionwhenmixedwithwater.

Vapour pressure: Triadimefon – 0.02 mPa @ 20 o C.

Vapour density:

Boiling point/range:

Melting/freezing point: Triadimefon melts at 82 o C. If it does, it will be absorbedbythe CaCO

filler.

Solubility: Fully dispersible. Active will be insoluble micro-particles.

Specific gravity- density: Bulkdensityof productisapprox 0.8.

Flashpoint:N/A

Explosive limits (air): N/A

Ignition temperature: N/A

10. STABILITY AND REACTIVITY

Chemical stability: Normally stable.Active may degrade in strong UV light.

Conditions toavoid: Veryhigh or low temperatures.

Materials toavoid: Strong oxidising agents.

Hazardous decomposition products: Oxides of nitrogen and chlorine. Burning with limited oxygen may

produce carbon monoxide.

Hazardous reactions: Not known. Does not polymerise.

11. TOXICOLOGICAL INFORMATION

Acute toxicity: Triadimefon:LD

rats1000 mg/kg.

Chronic toxicity: Triadimefon:NOEL 300 mg/kg dietfor ratsover 2 years.

Possible routes of exposure: Inhalation of productdustand/or spraymistare the mostlikelycauses of

exposure.

Range of effects. Excessive exposure mayaffecthuman healthas follows:

Skincontact: Irritant, especially the CaCO

.

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Material Safety Data Sheet

Triadimefon 500 WP

Eye contact: Irritant, especially the CaCO

.

Inhalation/ingestion: Irritant, especially the CaCO

.

Dose/conc./conditions likelytocause injury:10-20g.

Delayed effects if any:

Relevantnegative data:

12. ECOLOGICAL INFORMATION

Ecotoxicity:

Aquaticorganisms: Relativelynon-toxic.

Flora: Relativelynon-toxic.

Fauna : Relativelynon-toxic.

Soilorganisms: Relativelynon-toxic.

Bees: Non-toxic.

Long term: Unknown butprobablylow.

Ozone effects: None recorded.

Mobility: Low.

Bioaccumulative potential: Unknown but probably low.

13. DISPOSAL CONSIDERATIONS

Product: Whenever possible, productshould be used for itsintended purpose, even if

reclaimed fromspillage (reclaimedproduct must be uncontaminated).

Containers: Whenever possible, follow directions given on container.

If notavailable, tripleor pressure rinse plasticor metalcontainers before disposal. Recycle containers if

possible (replace cap and return cleancontainers to recycler or designated collection point). Treat

rinsings as for productabove.

If not recycling, break, crush or puncture and bury empty containers in a localauthority landfill. If no

landfill is available, bury the containers below 500 mmin a disposal pit specifically marked and set up

for thispurpose clear of waterways, desirable vegetation and tree roots. Emptycontainers and product

should notbe burnt.

Sewage: Do notdispose of productor rinsings intosewage systems or septictanks.

14. TRANSPORT INFORMATION

Nota dangerous good, so has no UN Number, UN proper shipping name, ADG Class, or ADG Packing Group.

Special precautions: Do not store with foodstuffs.

4Farmers does not anticipate that this product will be shipped by air or sea, nor beexported. Extra precautions

mayapplyifsuch transportisundertaken.

15. REGULATORY INFORMATION

AICS:Allof the significantingredients inthisformulation are tobe found inthe publicAICSDatabase.

Thisproductisan AgriculturalChemicalregistered bythe AgriculturalPesticides and VeterinaryMedicines

Authority.

16. OTHER INFORMATION

TLV –Threshold limitvalue.

TWA – Timeweighted average.

ThisMSDS prepared February2008.

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