4FARMERS TRIADIMEFON 125 FUNGICIDE SPRAY

Australia - English - APVMA (Australian Pesticides and Veterinary Medicines Authority)

Active ingredient:
TRIADIMEFON
Available from:
4 FARMERS AUSTRALIA PTY LTD
INN (International Name):
triadimefon(125g/L)
Pharmaceutical form:
EMULSIFIABLE CONCENTRATE
Composition:
TRIADIMEFON TRIAZOLE Active 125.0 g/L
Units in package:
1000L; 100L; 10L; 200L; 20L
Class:
A - Agricultural
Manufactured by:
4 FARMERS
Therapeutic group:
AZALEA | BARLEY | CUCURBIT | GRAPEVINE | PEA | SUGAR CANE | WHEAT | CANTALOUPE | CHOKO | CUCUMBER | GHERKIN | HONEYDEW MELON | I
Therapeutic area:
FUNGICIDE
Therapeutic indications:
BARLEY LEAF SCALD | LEAF RUST | PETAL BLIGHT | PINEAPPLE DISEASE | POWDERY MILDEW | SPECKLED LEAF BLOTCH | STRIPE RUST | AZALEA | BARLEY SCALD | CERATOCYSTIS PARADOXA | PUCCINIA RECONDITA F.SP. TRITI | PUCCINIA TRITICINA | WHEAT LEAF RUST | YELLOW RUST
Product summary:
Poison schedule: 5; Withholding period: WHP: Barley Wheat: DO NOT HARVEST FOR 28 DAYS AFTER APPLICATION. Barley Whe at: DO NOT GRAZE OR CUT FOR STOCK FOOD FOR 28 DAYS AFTER APPLICATION. Grapes Peas: DO NOT HARVEST FOR 14 DAYS AFTER APPLIOCATION. Cucurbits: DO NOT HARVES T FOR 1 DAY AFTER APPLICATION.; Host/pest details: AZALEA: [PETAL BLIGHT]; BARLEY: [BARLEY LEAF SCALD, POWDERY MILDEW]; CUCURBIT: [POWDERY MILDEW]; GRAPEVINE: [POWDERY MILDEW]; PEA: [POWDERY MILDEW]; SUGAR CANE: [PINEAPPLE DISEASE]; WHEAT: [LEAF RUST, POWDERY MILDEW, SPECKLED LEAF BLOTCH, STRIPE RUST]; Poison schedule: 5; Withholding period: ; Host/pest details: AZALEA: [PETAL BLIGHT]; BARLEY: [BARLEY LEAF SCALD, POWDERY MILDEW]; CUCURBIT: [POWDERY MILDEW]; GRAPEVINE: [POWDERY MILDEW]; PEA: [POWDERY MILDEW]; SUGAR CANE: [PINEAPPLE DISEASE]; WHEAT: [LEAF RUST, POWDERY MILDEW, SPECKLED LEAF BLOTCH, STRIPE RUST]; For control of: stripe rust and speckled leaf blotch of wheat; powdery mildew and leaf scald of barley; powdery mildew of peas, grapevines and cucurbits; pineapple disease of sugar cane.See RESTRAINTS on label
Authorization status:
Registered
Authorization number:
51248
Authorization date:
2019-07-01

WHEAT: For control of leaf and stripe rusts; septoria tritici blotch and powdery mildew

BARLEY: For control of scald and powdery mildew

PEAS, GRAPEVINES, CUCURBITS: For control of powdery mildew

SUGAR CANE: For control of pineapple disease

Contents: 10 Litres

4FARMERS PTY. LTD.

A.C.N. 067 443 485

643 MURRAY STREET, WEST PERTH,

WESTERN AUSTRALIA 6005

PH (08) 9356 3445 FAX: (08) 9356 3447

TRIADIMEFON 125

FUNGICIDE SPRAY

ACTIVE CONSTITUENT: 125g/L TRIADIMEFON

SOLVENT: 689g/L HYDROCARBON LIQUID

100g/L N-METHYL-2-PYRROLIDONE

POISON

KEEP OUT OF REACH OF CHILDREN

READ SAFETY DIRECTIONS BEFORE OPENING OR USING

IMPORTANT: READ THE ATTACHED LEAFLET THOROUGHLY BEFORE USE

FUNGICIDE RESISTANCE WARNING

Triadimefon is a member of the D.M.I group of fungicides. For

fungicide resistance management, 4Farmers Triadimefon 125 is a

Group C fungicide.

Some naturally occurring

individual fungi resistant to 4Farmers Triadimefon 125 and other

Group C fungicides may exist through normal genetic variability in

any fungal population. The resistant individuals can eventually

dominate the fungi population if these fungicides are used

repeatedly. These resistant fungi will not be controlled by 4Farmers

Triadimefon 125 and other Group C fungicides, thus resulting in

efficacy and possible yield loss.

Since the occurrence of resistant fungi is difficult to detect prior to

use, 4Farmers Pty Ltd accepts no liability for any losses that may

result from the failure of 4Farmers Triadimefon 125 to control

resistant fungi.

PROTECTION OF WILDLIFE, FISH,

CRUSTACEA AND ENVIRONMENT

Harmful to fish.

DO NOT contaminate streams, rivers or waterways with the

chemical or used containers.

STORAGE AND DISPOSAL:

Store in the closed, original container in a dry, well-ventilated area,

as cool as possible. DO NOT store for prolonged periods in direct

sunlight. Store in a locked room or place away from children,

animals, food, feedstuffs, seed and fertilisers. Triple or preferably

pressure rinse containers before disposal. Add rinsings to spray

tank. Do not dispose of undiluted chemicals on site. Break, crush

or puncture and bury empty containers in a local landfill. If no

landfill is available, bury the containers below 500mm in a disposal

pit specifically marked and set up for this purpose clear of

waterways, desirable vegetation and roots. Empty containers and

product should not be burnt.

SAFETY DIRECTIONS:

Poisonous if swallowed. Avoid contact with eyes and skin and do

not inhale spray mist. When preparing spray wear PVC or rubber

apron, elbow-length PVC gloves and face shield. When using the

prepared spray wear face shield. If product on skin immediately

wash area with soap and water. After use and before eating,

drinking or smoking, wash hands, arms and face thoroughly with

soap and water. After each day’s use wash gloves, face shield and

contaminated clothing.

FIRST AID:

If poisoning occurs, contact a doctor or Poisons Information Centre

on 131126.

If swallowed, and if more than 15 minutes from a hospital, induce

vomiting, preferably using Ipecac Syrup APF.

MATERIAL SAFETY DATA SHEET:

For further information see Material Safety Data Sheet which can

be obtained from the supplier.

CONDITIONS OF SALE:

The use of 4 Farmers Triadimefon 125 Fungicide Spray, being

beyond the control of the manufacturer, no warranty expressed or

implied is given by 4 Farmers Pty. Ltd. regarding its suitability,

fitness or efficacy for any purpose for which it is used by the buyer,

whether in accordance with the directions or not and 4 Farmers Pty.

Ltd. accepts no responsibility for any consequences whatsoever

resulting from the use of this product

IN AN EMERGENCY, CONTACT:

ACOHS

AUSTRALIAN CENTRE FOR OCCUPATIONAL

HEALTH AND SAFETY

1800 638 556 (24 HOURS)

Police and Fire Brigade DIAL 000

National Poisons Information Centre:

DIAL 13 11 26 (from anywhere in Australia)

APVMA Approval Number: 51248/10L/0505

Batch Number:

Date of Manufacture:

GROUP

C

FUNGICIDE

GROUP

C

FUNGICIDE

Info

pest

Verified

DIRECTIONS FOR USE:

RESTRAINT:

DO NOT apply if rain is expected within 2 hours.

DO NOT apply as a mix with any herbicide that might cause crop injury if

used with wetters or spray oils, as this product has some of the properties

of those adjuvants.

GROUP C FUNGICIDE

WHEAT: For control of leaf and stripe rusts; septoria tritici blotch and

powdery mildew

BARLEY: For control of scald and powdery mildew

PEAS, GRAPEVINES, CUCURBITS: For control of powdery mildew

SUGAR CANE: For control of pineapple disease

4FARMERS PTY. LTD.

A.C.N. 067 443 485

643 MURRAY STREET, WEST PERTH,

WESTERN AUSTRALIA 6005

PH (08) 9356 3445 FAX: (08) 9356 3447

TRIADIMEFON 125

FUNGICIDE SPRAY

ACTIVE CONSTITUENT: 125g/L TRIADIMEFON

SOLVENT: 689g/L HYDROCARBON LIQUID

100g/L N-METHYL-2-PYRROLIDONE

POISON

KEEP OUT OF REACH OF CHILDREN

READ SAFETY DIRECTIONS BEFORE OPENING OR USING

APVMA Approval No.:

51248/0505

GENERAL INSTRUCTIONS:

CONTROL OF WHEAT RUSTS

4Farmers Triadimefon 125EC Fungicide may be applied by aircraft or ground spraying

equipment.

SPRAY TIMINGS FOR STRIPE RUST CONTROL:

Determine the susceptibility of the wheat variety from local Department of Agriculture

data then follow spray programme below.

Seedling Infections:

When approximately 20% of the leaves show signs of infection during tillering or jointing,

spray within a week.

Adult Infections:

Susceptible Varieties: Spray within one week if approximately 10% of leaves show

infection. Do not delay.

Moderately Susceptible Varieties: Spray within one week if approximately 15-20% of

leaves show infection. Do not delay.

Moderately Resistant and Resistant Varieties: Spray within one week if rust appears

and spreads.

MIXING

Half fill the spray tank with clean filtered water. With agitator running, add the required

quantity of 4Farmers Triadimefon and top up the tank with clean filtered water.

Agitate prior to and during spraying.

DO NOT begin adding 4Farmers Triadimefon before tank is half full.

DO NOT mix more than can be used for the day’s spraying.

DO NOT tank mix with trace elements or other chemicals without first checking

compatibility.

GRAPEVINES

Dilute Spraying: Use a sprayer designed to apply high volumes of water up to the point

of run-off and matched to the crop being sprayed. Set up and operate the sprayer to

achieve even coverage throughout the crop canopy. Apply sufficient water to cover the

crop to the point of run-off. Avoid excessive run-off. The required water volume may be

determined by applying different test volumes, using different settings on the sprayer,

from industry guidelines or expert advice. Add the amount of product specified in the

Directions for Use table for each 100L of water. Spray to the point of run-off. The

required dilute spray volume will change and the spray set up and operation also may

need to be changed, as the crop grows.

Concentrate Spraying: Use a sprayer designed and set up for concentrate spraying

(that is a sprayer which applies water volumes less than those required to reach the

point of run-off) and matched to the crop being sprayed. Set up and operate the sprayer

to achieve even coverage throughout the crop canopy using your chosen water volume.

Determine and appropriate dilute spray volume (See Dilute Spraying above) for the crop

canopy, this is needed to calculate the concentrate mixing rate. The mixing rate for

concentrate spraying can then be calculated in the following way:

Example only:

Dilute spray volume as determined above (for example 1500L/ha)

Your chosen concentrate spray volume: (for example 500L/ha)

The concentration factor in this example is 3x (ie: 1500L ÷ 500L = 3)

If the dilute label rate is 10mL/100L, then the concentrate rate becomes 3 x 10,

that is 30mL/100L of concentrate spray.

The chosen spray volume, amount of product per 100mL water, and the sprayer set

up and operation may need to be changed as the crop grows. For further information

on concentrate spraying users are advised to consult relevant industry guidelines,

undertake appropriate competency training and follow Industry Best Practices.

SPRAYING

Ground Rig: Use a convenient amount of water, eg. 50-100 L water/Ha.

Aircraft: Apply at not less than 10 L/Ha; preferably in a cross wind of greater than 5

knots. If this is not possible, increase the volume to 30L/Ha and increase the droplet

size. Spray in the morning and reduce the swathe width. Booms, with fan nozzles set

forward at 45º forward to the airstream and Micronairs with blade settings of 30-50º are

equally satisfactory. Use proper measures (eg smoke generators) for gauging wind

speed, direction and variability of the wind.

DIRECTION FOR USE TABLE

Crop

Disease/

State (s)

Rate

WHP

Critical

Pest

days

Comments

Barley

Wheat

Peas

Grapevines

Sugar

Cane

Cucurbits

Eg melon,

pumpkin,

cucumber

Azaleas

Scald

Powdery

mildew

Leaf rust

Stripe rust

Powdery

mildew

Septoria

tritici

blotch

Powdery

mildew

Pineapple

disease

Powdery

mildew

Petal blight

NSW, VIC,

TAS, SA,

WA ONLY

STATES

NSW, VIC,

TAS ONLY

NSW, VIC,

WA, SA

ONLY

Qld, NSW

only

NSW, WA

ONLY

STATES

1L/ha

500mL

to 1L/ha

1L/ha

500mL

to 1L/ha

1L/ha

500mL

20mL/

100L

100mL in

100L

40mL

/100L or

400mL

200mL/

100L

Where this disease frequently

affects the flag leaf, apply at or

near mid-tillering.

Monitor crops sown without seed

or fertiliser applied ungicide from

mid tillering. Apply at the first signs

of disease. For later infections

apply just before head emergence

if middle canopy leaves are

infected.

Respraying may be required as

reinfection can occur. Monitor at-

risk crops from 3 weeks after

application to assess if

reapplication is required.

Normally use 500 mL/ha.

Only use 1L/ha where the yield is

expected to be greater than

2 tonnes/ha or if a longer residual

is required.

Monitor crops sown without seed

or fertiliser applied fungicide from

mid tillering. Apply at the first signs

of disease. For later infections

apply just before head emergence

if middle canopy leaves are

infected.

Where this disease commonly

affects the Flag leaf, apply to

susceptible varieties at the

5-6 tiller stage. Reinfection can

occur if moist conditions prevail.

Apply a preventative spray at

flowering at the first sign of

disease, or if disease is imminent.

Apply a second spray 14 days

later (flat pod stage).

This rate for grapevines is for

dilute spraying. For concentrate

spraying refer to the

Mixing/Application Section. Apply

the same total amount of

4Farmers Triadimefon 125 EC

Fungicide whether applying by

dilute or concentrate spraying

methods. Apply thoroughly at the

following 5 growth stages:-

When shoots are 10 cm in

length

Immediately before flowering

Mid flowering

After fruit set

Prior to bunches close.

Fully immerse, dip or spray cut

ends. Ensure thorough wetting for

up to 3 minutes.

Apply thoroughly at the first sign

of disease. Repeat at 5-10 day

intervals. Use short spray intervals

when disease pressure is high or

plants are rapidly growing.

Results are dependent on good

coverage.

Apply thoroughly every 2-3 weeks

from expanded bud stage until

end of flowering.

NOT TO BE USED FOR ANY PURPOSE, OR IN ANY MANNER,

CONTRARY TO THIS LABEL UNLESS AUTHORISED UNDER

APPROPRIATE LEGISLATION.

WITHHOLDING PERIOD:

Barley, Wheat:

DO NOT HARVEST FOR 28 DAYS AFTER APPLICATION.

Barley, Wheat:

DO NOT GRAZE OR CUT FOR STOCK FOOD FOR 28

DAYS AFTER APPLICATION.

Grapes, Peas:

DO NOT HARVEST FOR 14 DAYS AFTER APPLICATION.

Cucurbits:

DO NOT HARVEST FOR 1 DAY AFTER APPLICATION.

FUNGICIDE RESISTANCE WARNING

Triadimefon is a member of the D.M.I group

of fungicides. For fungicide resistance management, 4Farmers Triadimefon 125 is a

Group C fungicide.

Some naturally occurring individual fungi resistant to 4Farmers Triadimefon 125 and

other Group C fungicides may exist through normal genetic variability in any fungal

population. The resistant individuals can eventually dominate the fungi population if

these fungicides are used repeatedly. These resistant fungi will not be controlled by

4Farmers Triadimefon 125 and other Group C fungicides, thus resulting in efficacy and

possible yield loss.

Since the occurrence of resistant fungi is difficult to detect prior to use, 4Farmers Pty Ltd

accepts no liability for any losses that may result from the failure of 4Farmers

Triadimefon 125 to control resistant fungi.

PROTECTION OF WILDLIFE, FISH, CRUSTACEA AND ENVIRONMENT

Harmful to fish.

DO NOT contaminate streams, rivers or waterways with the chemical or used containers.

STORAGE AND DISPOSAL

Store in the closed, original container in a dry, well-ventilated area, as cool as possible.

DO NOT store for prolonged periods in direct sunlight. Store in a locked room or place

away from children, animals, food, feedstuffs, seed and fertilisers. Triple or preferably

pressure rinse containers before disposal. Add rinsings to spray tank. Do not dispose of

undiluted chemicals on site. Break, crush or puncture and bury empty containers in a

local landfill. If no landfill is available, bury the containers below 500mm in a disposal pit

specifically marked and set up for this purpose clear of waterways, desirable vegetation

and roots. Empty containers and product should not be burnt.

SAFETY DIRECTIONS

Poisonous if swallowed. Avoid contact with eyes and skin and do not inhale spray mist.

When preparing spray wear PVC or rubber apron, elbow-length PVC gloves and face

shield. When using the prepared spray wear face shield. If product on skin immediately

wash area with soap and water. After use and before eating, drinking or smoking, wash

hands, arms and face thoroughly with soap and water. After each day’s use wash gloves,

face shield and contaminated clothing.

FIRST AID

If poisoning occurs, contact a doctor or Poisons Information Centre on 131126.

If swallowed, and if more than 15 minutes from a hospital, induce vomiting, preferably

using Ipecac Syrup APF.

MATERIAL SAFETY DATA SHEET:

For further information see Material Safety Data Sheet which can be obtained from the

supplier.

CONDITIONS OF SALE

The use of 4 Farmers Triadimefon 125 Fungicide Spray, being beyond the control of the

manufacturer, no warranty expressed or implied is given by 4 Farmers Pty. Ltd. regarding

its suitability, fitness or efficacy for any purpose for which it is used by the buyer,

whether in accordance with the directions or not and 4 Farmers Pty. Ltd. accepts no

responsibility for any consequences whatsoever resulting from the use of this product

Police and Fire Brigade Dial 000

National Poisons Information Centre:

Dial 13 11 26 (from anywhere in Australia)

In an emergency, contact:

ACOHS

Australian Centre for Occupational Health and Safety

1800 638 556 (24 hours)

NOT TO BE USED FOR ANY PURPOSE, OR IN ANY MANNER,

CONTRARY TO THIS LABEL UNLESS AUTHORISED UNDER

APPROPRIATE LEGISLATION.

WITHHOLDING PERIOD:

Barley, Wheat:

DO NOT HARVEST FOR 28 DAYS AFTER APPLICATION.

Barley, Wheat:

DO NOT GRAZE OR CUT FOR STOCK FOOD FOR 28

DAYS AFTER APPLICATION.

Grapes, Peas:

DO NOT HARVEST FOR 14 DAYS AFTER APPLICATION.

Cucurbits:

DO NOT HARVEST FOR 1 DAY AFTER APPLICATION.

APPLIED TO FERTILISER FOR IN-FURROW APPLICATION

Crop

Disease/

State (s)

Rate

WHP

Critical

Pest

days

Comments

Wheat

Wheat Leaf

NSW, VIC,

800mL/ha

Apply product evenly onto the

Rust

SA and WA

fertiliser. Do not use on DAP or

(Puccinia

only

similar granulated product as

recondite)

use will cause the fertiliser to be

too wet. If adding to a particularly

dusty, dry fertiliser granule, dilute

with minimum water (up to a

maximum of 8Litres) ensuring

constant mixing of the suspension

by using a “granny pot” or similar

device.

Calculation of the rate

required/tonne fertiliser is below:

1000 ÷ (Fertiliser rate/ha)

x rate of fungicide (L)

Eg: Using 100kg fertiliser/ha

and requiring 800mL/ha fungicide:

1000÷100 x 0.8 = 8L/tonne

GROUP C FUNGICIDE

4Farmers Triadimefon 125 EC Fungicide

Hazard Alert Code: HIGH

Chemwatch Material Safety Data Sheet

Issue Date: 22-Jul-2009

CHEMWATCH 3723135

XC9317SC

Version No:2.0

CD 2011/1 Page 1 of 8

Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME

4Farmers Triadimefon 125 EC Fungicide

PRODUCT USE

Fungicide for control of leaf diseases in cereals and other crops.

SUPPLIER

Company: 4Farmers

Address:

1/70 McDowell Street

Welshpool, 6106

Australia

Telephone: +61 8 9356 3445

Fax: +61 8 9356 3447

Email: admin@4farmers.com.au

Website: http://www.4farmers.com.au/msds/

Section 2 - HAZARDS IDENTIFICATION

STATEMENT OF HAZARDOUS NATURE

HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS. According to NOHSC Criteria, and ADG Code.

COMBUSTIBLE LIQUID, regulated under AS1940 for Bulk Storage purposes only.

CHEMWATCH HAZARD RATINGS

Flammability

Toxicity

Body Contact

Reactivity

Chronic

SCALE:

Min/Nil=0

Low=1

Moderate=2

High=3

Extreme=4

RISK

SAFETY

■ Irritating to eyes and skin.

Keep locked up.

■ Limited evidence of a carcinogenic effect.

Do not breathe gas/fumes/vapour/spray.

■ May cause SENSITISATION by skin contact.

In case of insufficient ventilation, wear

suitable respiratory equipment.

■ Toxic to aquatic organisms, may cause long-

Use only in well

ventilated areas.

term adverse effects in the aquatic

environment.

■ May cause harm to the unborn child.

Keep container in a well

ventilated place.

■ HARMFUL- May cause lung damage if swallowed.

Avoid exposure - obtain special instructions

before use.

■ Repeated exposure may cause skin dryness and

To clean the floor and all

objects contaminated

cracking.

by this material, use water.

■ Vapours may cause drowsiness and dizziness.

Keep container tightly closed.

This material

and its container must be disposed

of in a safe way.

Keep away from food, drink and animal

feeding

stuffs.

continued...

4Farmers Triadimefon 125 EC Fungicide

Hazard Alert Code: HIGH

Chemwatch Material Safety Data Sheet

Issue Date: 22-Jul-2009

CHEMWATCH 3723135

XC9317SC

Version No:2.0

CD 2011/1 Page 2 of 8

Section 2 - HAZARDS IDENTIFICATION

In case of contact with eyes, rinse with plenty

of water and contact Doctor or Poisons Information

Centre.

Use appropriate container to avoid environmental

contamination.

Avoid release to the environment. Refer to

special instructions/Safety data sheets.

Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS

NAME

CAS RN

triadimefon

43121-43-3

12.5

solvent naphtha petroleum, heavy aromatic

64742-94-5

N- methyl- 2- pyrrolidone

872-50-4

dispersing/wetting agents

<8

Section 4 - FIRST AID MEASURES

SWALLOWED

If swallowed do NOT induce vomiting.

If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and

prevent aspiration.

Observe the patient carefully.

Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious.

Avoid giving milk or oils.

Avoid giving alcohol.

If spontaneous vomiting appears imminent or occurs, hold patient's head down, lower than their hips to help avoid possible

aspiration of vomitus.

EYE

■ If this product comes in contact with the eyes:

Wash out immediately with fresh running water.

Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting

the upper and lower lids.

Seek medical attention without delay; if pain persists or recurs seek medical attention.

Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.

SKIN

■ If skin contact occurs:

Immediately remove all contaminated clothing, including footwear.

Flush skin and hair with running water (and soap if available).

Seek medical attention in event of irritation.

INHALED

If fumes or combustion products are inhaled remove from contaminated area.

Lay patient down. Keep warm and rested.

Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid

procedures.

Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket

mask as trained. Perform CPR if necessary.

NOTES TO PHYSICIAN

■ Any material

aspirated during vomiting may produce lung injury. Therefore emesis should not be induced mechanically or

pharmacologically.

For acute or short term repeated exposures to petroleum distillates or related hydrocarbons:

Primary threat to life, from pure petroleum distillate ingestion and/or inhalation, is respiratory failure.

Patients should be quickly evaluated for signs of respiratory distress (e.g. cyanosis, tachypnoea, intercostal retraction,

obtundation) and given oxygen. Patients with inadequate tidal

volumes or poor arterial blood gases (pO2 50 mm Hg) should be

intubated.

Arrhythmias complicate some hydrocarbon ingestion and/or inhalation and electrocardiographic evidence of myocardial injury has

been reported; intravenous lines and cardiac monitors should be established in obviously symptomatic patients. The lungs

excrete inhaled solvents, so that hyperventilation improves clearance.

continued...

4Farmers Triadimefon 125 EC Fungicide

Hazard Alert Code: HIGH

Chemwatch Material Safety Data Sheet

Issue Date: 22-Jul-2009

CHEMWATCH 3723135

XC9317SC

Version No:2.0

CD 2011/1 Page 3 of 8

Section 4 - FIRST AID MEASURES

A chest x-ray should be taken immediately after stabilisation of breathing and circulation to document aspiration and detect

the presence of pneumothorax.

Following exposures to chlorophenoxy compounds:

Acute toxic reactions are rare. The by-product of production, dioxin, may be implicated in subacute features such as hepatic

enlargement, chloracne, neuromuscular symptoms and deranged porphyrin metabolism.

Large intentional

overdoses result in coma, metabolic acidosis, myalgias, muscle weakness, elevated serum creatine kinase,

myoglobinuria, irritation of the skin, eyes, respiratory tract and gut and mild renal and hepatic dysfunction.

Several cases of sensorimotor peripheral neuropathies have been associated with chronic dermal exposure to 2,4-D. For acute

exposures the usual methods of gut and skin contamination (lavage, charcoal, cathartic) are recommended in the first several

hours. Alkalisation of the urine and generous fluid replacement have the added benefit of treating any myoglobinuria present.

Monitor metabolic acidosis, hyperthermia, hyperkalaemia, myoglobinuria and hepatic/renal dysfunction. for 2,4-

dichlorophenoxyacetic acid (2,4-D) and its derivatives

Gastric lavage if there are no signs of impending convulsions.

Section 5 - FIRE FIGHTING MEASURES

EXTINGUISHING MEDIA

Water spray or fog.

Foam.

Dry chemical

powder.

BCF (where regulations permit).

FIRE FIGHTING

Alert Fire Brigade and tell

them location and nature of hazard.

Wear full

body protective clothing with breathing apparatus.

Prevent, by any means available, spillage from entering drains or water course.

Use water delivered as a fine spray to control fire and cool

adjacent area.

FIRE/EXPLOSION HAZARD

Combustible.

Slight fire hazard when exposed to heat or flame.

Heating may cause expansion or decomposition leading to violent rupture of containers.

On combustion, may emit toxic fumes of carbon monoxide (CO).

Combustion products include: carbon dioxide (CO2), hydrogen chloride, phosgene, nitrogen oxides (NOx), other pyrolysis products

typical

of burning organic material.

May emit poisonous fumes.

May emit corrosive fumes.

FIRE INCOMPATIBILITY

Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool

chlorine etc. as ignition may

result.

HAZCHEM

None

Personal Protective Equipment

Breathing apparatus.

Gas tight chemical resistant suit.

Limit exposure duration to 1 BA set 30 mins.

Section 6 - ACCIDENTAL RELEASE MEASURES

MINOR SPILLS

Remove all

ignition sources.

Clean up all

spills immediately.

Avoid breathing vapours and contact with skin and eyes.

Control personal contact by using protective equipment.

MAJOR SPILLS

■ Moderate hazard.

Clear area of personnel and move upwind.

Alert Fire Brigade and tell

them location and nature of hazard.

continued...

4Farmers Triadimefon 125 EC Fungicide

Hazard Alert Code: HIGH

Chemwatch Material Safety Data Sheet

Issue Date: 22-Jul-2009

CHEMWATCH 3723135

XC9317SC

Version No:2.0

CD 2011/1 Page 4 of 8

Section 6 - ACCIDENTAL RELEASE MEASURES

Wear breathing apparatus plus protective gloves.

Prevent, by any means available, spillage from entering drains or water course.

Personal Protective Equipment advice is contained in Section 8 of the MSDS.

Section 7 - HANDLING AND STORAGE

PROCEDURE FOR HANDLING

Containers, even those that have been emptied, may contain explosive vapours.

Do NOT cut, drill, grind, weld or perform similar operations on or near containers.

DO NOT allow clothing wet with material to stay in contact with skin.

Electrostatic discharge may be generated during pumping - this may result in fire.

Ensure electrical continuity by bonding and grounding (earthing) all equipment.

Restrict line velocity during pumping in order to avoid generation of electrostatic discharge (<=1 m/sec until fill pipe

submerged to twice its diameter, then <= 7 m/sec).

Avoid splash filling.

Avoid all personal contact, including inhalation.

Wear protective clothing when risk of exposure occurs.

Use in a well-ventilated area.

Prevent concentration in hollows and sumps.

SUITABLE CONTAINER

Metal can or drum

Packaging as recommended by manufacturer.

Check all containers are clearly labelled and free from leaks.

STORAGE INCOMPATIBILITY

■ High nitrogen compounds are often unstable or explosive; the tendency is exaggerated by attachment of azide or diazonium groups,

or a high-nitrogen heterocyclic nucleus.

High-nitrogen chemical families include

azides

diazoazoles

diazonium salts

hydrazinium salts.

Avoid reaction with oxidising agents.

STORAGE REQUIREMENTS

Store in original containers.

Keep containers securely sealed.

No smoking, naked lights or ignition sources.

Store in a cool, dry, well-ventilated area.

Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION

EXPOSURE CONTROLS

Source

Material

TWA ppm TWA

STEL

STEL

Peak

Peak

Notes

mg/m³

mg/m³

mg/m³

F/CC

___________

___________

_______

_______

_______

_______

_______

_______

_______

_______

Australia

4Farmers

(see

Exposure

Triadimefon 125

Chapter

Standards

EC Fungicide

(Petrol

(gasoline))

Australia

N- methyl- 2-

Exposure

pyrrolidone (1-

Standards

Methyl- 2-

pyrrolidone)

The following materials had no OELs on our records

triadimefon:

CAS:43121- 43- 3

continued...

4Farmers Triadimefon 125 EC Fungicide

Hazard Alert Code: HIGH

Chemwatch Material Safety Data Sheet

Issue Date: 22-Jul-2009

CHEMWATCH 3723135

XC9317SC

Version No:2.0

CD 2011/1 Page 5 of 8

Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION

PERSONAL PROTECTION

RESPIRATOR

type ak-p filter of sufficient capacity.

EYE

Safety glasses with side shields.

Chemical goggles.

Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document,

describing the wearing of lens or restrictions on use, should be created for each workplace or task. This should include a

review of lens absorption and adsorption for the class of chemicals in use and an account of injury experience. Medical

first-aid personnel should be trained in their removal and suitable equipment should be readily available. In the event of

chemical

exposure, begin eye irrigation immediately and remove contact lens as soon as practicable. Lens should be removed at

the first signs of eye redness or irritation - lens should be removed in a clean environment only after workers have washed

hands thoroughly. [CDC NIOSH Current Intelligence Bulletin 59].

HANDS/FEET

Wear chemical

protective gloves, eg. PVC.

Wear safety footwear or safety gumboots, eg. Rubber.

NOTE:

The material

may produce skin sensitisation in predisposed individuals. Care must be taken, when removing gloves and other

protective equipment, to avoid all

possible skin contact.

Contaminated leather items, such as shoes, belts and watch-bands should be removed and destroyed.

Suitability and durability of glove type is dependent on usage. Important factors in the selection of gloves include: such as:

frequency and duration of contact,

chemical

resistance of glove material,

glove thickness and

dexterity.

OTHER

Overalls.

P.V.C. apron.

Barrier cream.

Skin cleansing cream.

ENGINEERING CONTROLS

■ Local

exhaust ventilation usually required. If risk of overexposure exists, wear approved respirator.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

APPEARANCE

Clear, pale brown liquid with strong petroleum odour; mixes with water.

PHYSICAL PROPERTIES

Liquid.

Mixes with water.

State

Liquid

Molecular Weight

Not Applicable

Melting Range (°C)

- 13 (solvent)

Viscosity

Not Available

Boiling Range (°C)

220- 290 (solvent)

Solubility in water (g/L)

Miscible

Flash Point (°C)

95 (PMCC)

pH (1% solution)

Not Available

Decomposition Temp (°C)

Not Available

pH (as supplied)

Not Available

Autoignition Temp (°C)

>450 (solvent)

Vapour Pressure (kPa)

0.006 @ 20C

(solvent)

Upper Explosive Limit (%)

7 (solvent)

Specific Gravity (water=1)

1.023

Lower Explosive Limit (%)

0.6 (solvent)

Relative Vapour Density

>1 (solvent)

(air=1)

continued...

4Farmers Triadimefon 125 EC Fungicide

Hazard Alert Code: HIGH

Chemwatch Material Safety Data Sheet

Issue Date: 22-Jul-2009

CHEMWATCH 3723135

XC9317SC

Version No:2.0

CD 2011/1 Page 6 of 8

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Volatile Component (%vol)

Not Available

Evaporation Rate

Not Available

Section 10 - STABILITY AND REACTIVITY

CONDITIONS CONTRIBUTING TO INSTABILITY

Presence of incompatible materials.

Product is considered stable.

Hazardous polymerisation will not occur.

For incompatible materials - refer to Section 7 - Handling and Storage.

Section 11 - TOXICOLOGICAL INFORMATION

POTENTIAL HEALTH EFFECTS

ACUTE HEALTH EFFECTS

CHRONIC HEALTH EFFECTS

■ HARMFUL- May cause lung damage if swallowed.

■ May cause SENSITISATION by skin contact.

■ Irritating to eyes and skin.

■ Limited evidence of a carcinogenic

effect.

■ Vapours may cause dizziness or suffocation.

■ May cause harm to the unborn child.

■ Vapours may cause drowsiness and dizziness.

■ Repeated exposure may cause skin dryness

and cracking.

■ May produce discomfort of the respiratory system*.

■ May possibly affect fertility*.

■ Inhalation, skin contact and/or ingestion may

■ Cumulative effects may result following

produce health damage*.

exposure*.

■ * (limited evidence).

■ * (limited evidence).

TOXICITY AND IRRITATION

■ Contact allergies quickly manifest themselves as contact eczema, more rarely as urticaria or Quincke's oedema. The pathogenesis

of contact eczema involves a cell-mediated (T lymphocytes) immune reaction of the delayed type.

For chlorophenoxy pesticides:.

WARNING: This substance has been classified by the IARC as Group 2B: Possibly Carcinogenic to Humans.

Side-reactions during manufacture of the parent compound may result in the production of trace amounts of polyhalogenated

aromatic hydrocarbon(s). Halogenated phenols, and especially their alkali

salts, can condense above 300 deg.

Polyhalogenated aromatic hydrocarbons (PHAHs) comprise two major groups. The first group represented by the halogenated

derivatives of dibenzodioxins (the chlorinated form is PCDD), dibenzofurans (PCDF) and biphenyls (PCB) exert their toxic effect

(as hepatoxicants, reproductive toxicants, immunotoxicants and procarcinogens) by interaction with a cytostolic protein known as

the Ah receptor.

for petroleum:

This product contains benzene which is known to cause acute myeloid leukaemia and n-hexane which has been shown to metabolize to

compounds which are neuropathic.

This product contains toluene.

This product contains ethyl

benzene and naphthalene from which there is evidence of tumours in rodents

Carcinogenicity: Inhalation exposure to mice causes liver tumours, which are not considered relevant to humans.

Section 12 - ECOLOGICAL INFORMATION

Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Avoid release to the environment.

Refer to special instructions/ safety data sheets.

Ecotoxicity

Ingredient

Persistence:

Persistence: Air

Bioaccumulation

Mobility

Water/Soil

4Farmers Triadimefon 125 EC

No Data

No Data

Fungicide

Available

Available

triadimefon

HIGH

No Data

Available

continued...

4Farmers Triadimefon 125 EC Fungicide

Hazard Alert Code: HIGH

Chemwatch Material Safety Data Sheet

Issue Date: 22-Jul-2009

CHEMWATCH 3723135

XC9317SC

Version No:2.0

CD 2011/1 Page 7 of 8

Section 12 - ECOLOGICAL INFORMATION

solvent naphtha petroleum, heavy

No Data

No Data

aromatic

Available

Available

N- methyl- 2- pyrrolidone

No Data

HIGH

Available

Section 13 - DISPOSAL CONSIDERATIONS

Containers may still present a chemical hazard/ danger when empty.

Return to supplier for reuse/ recycling if possible.

Otherwise:

If container can not be cleaned sufficiently well to ensure that residuals do not remain or if the container cannot be used to

store the same product, then puncture containers, to prevent re-use, and bury at an authorised landfill.

Where possible retain label warnings and MSDS and observe all notices pertaining to the product.

Legislation addressing waste disposal requirements may differ by country, state and/ or territory. Each user must refer to laws

operating in their area.

A Hierarchy of Controls seems to be common - the user should investigate:

Reduction.

DO NOT allow wash water from cleaning or process equipment to enter drains.

It may be necessary to collect all wash water for treatment before disposal.

In all cases disposal to sewer may be subject to local laws and regulations and these should be considered first.

Where in doubt contact the responsible authority.

Recycle wherever possible or consult manufacturer for recycling options.

Consult State Land Waste Authority for disposal.

Bury or incinerate residue at an approved site.

Recycle containers if possible, or dispose of in an authorised landfill.

Section 14 - TRANSPORTATION INFORMATION

Labels Required: COMBUSTIBLE LIQUID, regulated under AS1940 for Bulk Storage purposes only.

HAZCHEM:

None

(ADG7)

NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS: UN, IATA, IMDG

Section 15 - REGULATORY INFORMATION

POISONS SCHEDULE None

REGULATIONS

Regulations for ingredients

triadimefon (CAS: 43121-43-3) is found on the following regulatory lists;

"Australia - Australian Capital Territory - Environment Protection Regulation: Ambient environmental standards (Domestic water

supply - pesticides)","Australia - Australian Capital Territory Environment Protection Regulation Pollutants entering waterways -

Domestic water quality","Australia ADI list - Acceptable daily intakes for agricultural and veterinary chemicals","Australia

Hazardous Substances","Australia Inventory of Chemical Substances (AICS)","Australia New Zealand Food Standards Code - Maximum

Residue Limits (Australia only) - Schedule 1","Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) -

Schedule 5","Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 6","International Maritime

Dangerous Goods Requirements (IMDG Code) - Substance Index","OECD Representative List of High Production Volume (HPV) Chemicals"

continued...

4Farmers Triadimefon 125 EC Fungicide

Hazard Alert Code: HIGH

Chemwatch Material Safety Data Sheet

Issue Date: 22-Jul-2009

CHEMWATCH 3723135

XC9317SC

Version No:2.0

CD 2011/1 Page 8 of 8

Section 15 - REGULATORY INFORMATION

solvent naphtha petroleum, heavy aromatic (CAS: 64742-94-5) is found on the following

regulatory lists;

"Australia Hazardous Substances","Australia High Volume Industrial Chemical List (HVICL)","Australia Inventory of Chemical

Substances (AICS)","International Council of Chemical Associations (ICCA) - High Production Volume List","OECD Representative

List of High Production Volume (HPV) Chemicals"

N-methyl-2-pyrrolidone (CAS: 872-50-4,26138-58-9) is found on the following regulatory lists;

"Australia Exposure Standards","Australia Hazardous Substances","Australia Inventory of Chemical Substances (AICS)","Australia

Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix E (Part 2)","Australia Standard for the Uniform

Scheduling of Medicines and Poisons (SUSMP) - Schedule 5","Australia Standard for the Uniform Scheduling of Medicines and Poisons

(SUSMP) - Schedule 6","GESAMP/EHS Composite List - GESAMP Hazard Profiles","IMO IBC Code Chapter 17: Summary of minimum

requirements","IMO MARPOL 73/78 (Annex II) - List of Noxious Liquid Substances Carried in Bulk","International Council of

Chemical Associations (ICCA) - High Production Volume List","OECD Representative List of High Production Volume (HPV) Chemicals"

No data for 4Farmers Triadimefon 125 EC Fungicide (CW: 3723135)

Section 16 - OTHER INFORMATION

INGREDIENTS WITH MULTIPLE CAS NUMBERS

Ingredient Name

N-methyl-2-pyrrolidone

872-50-4,

26138-58-9

■ Classification of the preparation and its individual components has drawn on official and authoritative sources as well as

independent review by the Chemwatch Classification committee using available literature references.

A list of reference resources used to assist the committee may be found at:

www.chemwatch.net/references.

■ The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether

the reported Hazards are Risks in the workplace or other settings.

This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or

criticism, as permitted under the Copyright Act, no part may be reproduced by any process without written

permission from CHEMWATCH. TEL (+61 3) 9572 4700.

Issue Date: 22-Jul-2009

Print Date: 23-May-2011

This is the end of the MSDS.

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