Vibrance Gold

Primær information

  • Handelsnavn:
  • Vibrance Gold Flydende bejdse
  • Lægemiddelform:
  • Flydende bejdse
  • Sammensætning:
  • 25 g/l difenoconazol; 25 g/l fludioxonil; 50 g/l sedaxane
  • Brugt til:
  • Planter
  • Medicin typen:
  • agrokemiske

Dokumenter

  • for den brede offentlighed:
  • Oplysningerne indlægssedlen for dette produkt er i øjeblikket ikke tilgængelig, kan du sende en anmodning til vores kundeservice, og vi vil give dig besked, så snart vi er i stand til at opnå det.


    Anmode informationsbrochure for offentligheden.

Lokation

  • Fås i:
  • Vibrance Gold Flydende bejdse
    Danmark
  • Sprog:
  • dansk

Andre oplysninger

Status

  • Kilde:
  • SEGES Landbrug & Fødevarer
  • Autorisation status:
  • Afprøvet i Landsforsøg
  • Sidste ændring:
  • 26-02-2018

Produktresumé

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

VIBRANCE GOLD

Version

Revision Date:

20.02.2017

SDS Number:

S1464594542

This version replaces all previous

versions.

1 / 22

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

Trade name

VIBRANCE GOLD

Design code

A16283D

1.2 Relevant identified uses of the substance or mixture and uses advised against

Use of the

Substance/Mixture

Fungicide, Seed treatment

1.3 Details of the supplier of the safety data sheet

Company

Syngenta Crop Protection AG

Postfach

CH-4002 Basel

Switzerland

+41 61 323 11 11

Telefax

+41 61 323 12 12

E-mail address

sds.ch@syngenta.com

1.4 Emergency telephone number

Emergency telephone

number

+44 1484 538444

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Classification (REGULATION (EC) No 1272/2008)

Acute aquatic toxicity, Category 1

H400: Very toxic to aquatic life.

Chronic aquatic toxicity, Category 1

H410: Very toxic to aquatic life with long lasting

effects.

2.2 Label elements

Labelling (REGULATION (EC) No 1272/2008)

Hazard pictograms

Signal word

Warning

Hazard statements

H410

Very toxic to aquatic life with long lasting effects.

Supplemental Hazard

Statements

EUH208

Contains 1,2-benzisothiazol-3-one. May

produce an allergic reaction.

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

VIBRANCE GOLD

Version

Revision Date:

20.02.2017

SDS Number:

S1464594542

This version replaces all previous

versions.

2 / 22

EUH401

To avoid risks to human health and the

environment, comply with the instructions for use.

Precautionary statements

Response:

P391

Collect spillage.

Disposal:

P501

Dispose of contents/ container to an approved waste

disposal plant.

2.3 Other hazards

This substance/mixture contains no components considered to be either persistent,

bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of

0.1% or higher.

SECTION 3: Composition/information on ingredients

3.2 Mixtures

Hazardous components

Chemical name

CAS-No.

EC-No.

Registration number

Classification

Concentration

(% w/w)

poly(oxy-1,2-ethanediyl), alpha-9-

octadecenyl-omega-hydroxy-,(Z)-

9004-98-2

500-016-2

Acute Tox. 4; H302

Eye Dam. 1; H318

>= 3 - < 10

sedaxane

874967-67-6

Aquatic Acute 1;

H400

Aquatic Chronic 2;

H411

>= 2.5 - < 10

difenoconazole

119446-68-3

Acute Tox. 4; H302

Eye Irrit. 2; H319

Aquatic Acute 1;

H400

Aquatic Chronic 1;

H410

>= 1 - < 2.5

fludioxonil

131341-86-1

Aquatic Acute 1;

H400

Aquatic Chronic 1;

H410

>= 1 - < 2.5

poly(oxy-1,2-ethanediyl), alpha-

sulfo-omega-[tris(1-

phenylethyl)phenoxy]-,

ammonium salt

119432-41-6

Aquatic Chronic 3;

H412

>= 1 - < 2.5

1,2-benzisothiazol-3(2H)-one

2634-33-5

220-120-9

Acute Tox. 4; H302

Skin Irrit. 2; H315

Eye Dam. 1; H318

Skin Sens. 1; H317

Aquatic Acute 1;

H400

>= 0.025 - <

0.05

bronopol (INN)

52-51-7

200-143-0

Acute Tox. 4; H302

Acute Tox. 4; H312

Skin Irrit. 2; H315

>= 0.025 - <

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

VIBRANCE GOLD

Version

Revision Date:

20.02.2017

SDS Number:

S1464594542

This version replaces all previous

versions.

3 / 22

Eye Dam. 1; H318

STOT SE 3; H335

Aquatic Acute 1;

H400

Aquatic Chronic 1;

H410

For explanation of abbreviations see section 16.

SECTION 4: First aid measures

4.1 Description of first aid measures

General advice

Have the product container, label or Safety Data Sheet with

you when calling the emergency number, a poison control

center or physician, or going for treatment.

If inhaled

Move the victim to fresh air.

If breathing is irregular or stopped, administer artificial

respiration.

Keep patient warm and at rest.

Call a physician or poison control centre immediately.

In case of skin contact

Take off all contaminated clothing immediately.

Wash off immediately with plenty of water.

If skin irritation persists, call a physician.

Wash contaminated clothing before re-use.

In case of eye contact

Rinse immediately with plenty of water, also under the eyelids,

for at least 15 minutes.

Remove contact lenses.

Immediate medical attention is required.

If swallowed

If swallowed, seek medical advice immediately and show this

container or label.

Do NOT induce vomiting.

4.2 Most important symptoms and effects, both acute and delayed

Symptoms

No information available.

4.3 Indication of any immediate medical attention and special treatment needed

Treatment

There is no specific antidote available.

Treat symptomatically.

SECTION 5: Firefighting measures

5.1 Extinguishing media

Suitable extinguishing media

Extinguishing media - small fires

Use water spray, alcohol-resistant foam, dry chemical or

carbon dioxide.

Extinguishing media - large fires

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

VIBRANCE GOLD

Version

Revision Date:

20.02.2017

SDS Number:

S1464594542

This version replaces all previous

versions.

4 / 22

Alcohol-resistant foam

Water spray

Unsuitable extinguishing

media

Do not use a solid water stream as it may scatter and spread

fire.

5.2 Special hazards arising from the substance or mixture

Specific hazards during

firefighting

As the product contains combustible organic components, fire

will produce dense black smoke containing hazardous

products of combustion (see section 10).

Exposure to decomposition products may be a hazard to

health.

5.3 Advice for firefighters

Special protective equipment

for firefighters

Wear full protective clothing and self-contained breathing

apparatus.

Further information

Do not allow run-off from fire fighting to enter drains or water

courses.

Cool closed containers exposed to fire with water spray.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Personal precautions

Refer to protective measures listed in sections 7 and 8.

6.2 Environmental precautions

Environmental precautions

Prevent further leakage or spillage if safe to do so.

Do not flush into surface water or sanitary sewer system.

If the product contaminates rivers and lakes or drains inform

respective authorities.

6.3 Methods and material for containment and cleaning up

Methods for cleaning up

Contain spillage, and then collect with non-combustible

absorbent material, (e.g. sand, earth, diatomaceous earth,

vermiculite) and place in container for disposal according to

local / national regulations (see section 13).

6.4 Reference to other sections

For disposal considerations see section 13., Refer to protective measures listed in sections 7 and 8.

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Advice on safe handling

No special protective measures against fire required.

Avoid contact with skin and eyes.

When using do not eat, drink or smoke.

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

VIBRANCE GOLD

Version

Revision Date:

20.02.2017

SDS Number:

S1464594542

This version replaces all previous

versions.

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For personal protection see section 8.

7.2 Conditions for safe storage, including any incompatibilities

Requirements for storage

areas and containers

No special storage conditions required. Keep containers

tightly closed in a dry, cool and well-ventilated place. Keep out

of the reach of children. Keep away from food, drink and

animal feedingstuffs.

7.3 Specific end use(s)

Specific use(s)

For proper and safe use of this product, please refer to the

approval conditions laid down on the product label.

SECTION 8: Exposure controls/personal protection

8.1 Control parameters

Occupational Exposure Limits

Components

CAS-No.

Value type (Form

of exposure)

Control parameters

Basis

sedaxane

874967-67-

2 mg/m3

Syngenta

difenoconazole

119446-68-

5 mg/m3

Syngenta

fludioxonil

131341-86-

5 mg/m3

Syngenta

8.2 Exposure controls

Engineering measures

Containment and/or segregation is the most reliable technical protection measure if exposure

cannot be eliminated.

The extent of these protection measures depends on the actual risks in use.

Maintain air concentrations below occupational exposure standards.

Where necessary, seek additional occupational hygiene advice.

Personal protective equipment

Eye protection

No special protective equipment required.

Hand protection

Remarks

No special protective equipment required.

Skin and body protection

No special protective equipment required.

Select skin and body protection based on the physical job

requirements.

Respiratory protection

No personal respiratory protective equipment normally

required.

When workers are facing concentrations above the exposure

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

VIBRANCE GOLD

Version

Revision Date:

20.02.2017

SDS Number:

S1464594542

This version replaces all previous

versions.

6 / 22

limit they must use appropriate certified respirators.

Protective measures

The use of technical measures should always have priority

over the use of personal protective equipment.

When selecting personal protective equipment, seek

appropriate professional advice.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Appearance

suspension

Colour

light red to dark red

Odour

sweetish, chalky

5 - 9

Concentration: 1 % w/v

Flash point

> 100 °C(991.0 hPa)

Method: Pensky-Martens closed cup

Density

1.079 g/cm3 (20 °C)

Auto-ignition temperature

465 °C

Viscosity

Viscosity, dynamic

133 - 474 mPa.s (40 °C)

71 - 357 mPa.s (20 °C)

Explosive properties

Not explosive

Oxidizing properties

The substance or mixture is not classified as oxidizing.

9.2 Other information

Surface tension

35.0 mN/m, 20 °C

SECTION 10: Stability and reactivity

10.1 Reactivity

See section 10.3 "Possibility of hazardous reactions".

10.2 Chemical stability

Stable under normal conditions.

10.3 Possibility of hazardous reactions

Hazardous reactions

No dangerous reaction known under conditions of normal use.

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

VIBRANCE GOLD

Version

Revision Date:

20.02.2017

SDS Number:

S1464594542

This version replaces all previous

versions.

7 / 22

10.4 Conditions to avoid

Conditions to avoid

No decomposition if used as directed.

10.5 Incompatible materials

Materials to avoid

None known.

10.6 Hazardous decomposition products

Combustion or thermal decomposition will evolve toxic and irritant vapours.

SECTION 11: Toxicological information

11.1 Information on toxicological effects

Acute toxicity

Product:

Acute oral toxicity

LD50 (Rat, female): > 2,000 mg/kg

Assessment: The substance or mixture has no acute oral

toxicity

Acute inhalation toxicity

LC50 (Rat, male and female): 5.11 mg/l

Exposure time: 4 h

Test atmosphere: dust/mist

Acute dermal toxicity

LD50 (Rat, male and female): > 2,000 mg/kg

Assessment: The substance or mixture has no acute dermal

toxicity

Components:

poly(oxy-1,2-ethanediyl), alpha-9-octadecenyl-omega-hydroxy-,(Z)-:

Acute oral toxicity

LD50 (Rat): 500 - 2,000 mg/kg

sedaxane:

Acute oral toxicity

LD50 (Rat, female): 5,000 mg/kg

Acute inhalation toxicity

LC50 (Rat, male and female): > 5.244 mg/l

Exposure time: 4 h

Test atmosphere: dust/mist

Assessment: The substance or mixture has no acute

inhalation toxicity

Acute dermal toxicity

LD50 (Rat, male and female): > 5,000 mg/kg

difenoconazole:

Acute oral toxicity

LD50 (Rat, male and female): 1,453 mg/kg

Assessment: The component/mixture is moderately toxic after

single ingestion.

Acute inhalation toxicity

LC50 (Rat, male and female): > 3,300 mg/m3

Exposure time: 4 h

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

VIBRANCE GOLD

Version

Revision Date:

20.02.2017

SDS Number:

S1464594542

This version replaces all previous

versions.

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Test atmosphere: dust/mist

Assessment: The substance or mixture has no acute

inhalation toxicity

Acute dermal toxicity

LD50 (Rabbit, male and female): > 2,010 mg/kg

Assessment: The substance or mixture has no acute dermal

toxicity

fludioxonil:

Acute oral toxicity

LD50 (Rat, male and female): > 5,000 mg/kg

Acute inhalation toxicity

LC50 (Rat, male and female): > 2.6 mg/l

Exposure time: 4 h

Test atmosphere: dust/mist

Assessment: The substance or mixture has no acute

inhalation toxicity

Acute dermal toxicity

LD50 (Rat, male and female): > 2,000 mg/kg

Assessment: The substance or mixture has no acute dermal

toxicity

1,2-benzisothiazol-3(2H)-one:

Acute oral toxicity

Assessment: The component/mixture is moderately toxic after

single ingestion.

bronopol (INN):

Acute oral toxicity

Assessment: The component/mixture is moderately toxic after

single ingestion.

Acute toxicity estimate: 500 mg/kg

Method: Converted acute toxicity point estimate

Acute dermal toxicity

Assessment: The component/mixture is moderately toxic after

single contact with skin.

Acute toxicity estimate: 1,100 mg/kg

Method: Converted acute toxicity point estimate

Skin corrosion/irritation

Product:

Species: Rabbit

Result: No skin irritation

Components:

poly(oxy-1,2-ethanediyl), alpha-9-octadecenyl-omega-hydroxy-,(Z)-:

Species: Rabbit

Result: No skin irritation

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

VIBRANCE GOLD

Version

Revision Date:

20.02.2017

SDS Number:

S1464594542

This version replaces all previous

versions.

9 / 22

sedaxane:

Species: Rabbit

Result: No skin irritation

difenoconazole:

Species: Rabbit

Result: No skin irritation

fludioxonil:

Species: Rabbit

Result: No skin irritation

1,2-benzisothiazol-3(2H)-one:

Result: Irritating to skin.

bronopol (INN):

Result: Irritating to skin.

Serious eye damage/eye irritation

Product:

Species: Rabbit

Result: No eye irritation

Components:

poly(oxy-1,2-ethanediyl), alpha-9-octadecenyl-omega-hydroxy-,(Z)-:

Species: Rabbit

Result: Irreversible effects on the eye

sedaxane:

Species: Rabbit

Result: No eye irritation

difenoconazole:

Species: Rabbit

Result: Irritation to eyes, reversing within 7 days

fludioxonil:

Species: Rabbit

Result: No eye irritation

1,2-benzisothiazol-3(2H)-one:

Result: Risk of serious damage to eyes.

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

VIBRANCE GOLD

Version

Revision Date:

20.02.2017

SDS Number:

S1464594542

This version replaces all previous

versions.

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bronopol (INN):

Result: Risk of serious damage to eyes.

Respiratory or skin sensitisation

Product:

Test Type: Buehler Test

Species: Guinea pig

Result: Did not cause sensitisation on laboratory animals.

Components:

sedaxane:

Result: Did not cause sensitisation on laboratory animals.

difenoconazole:

Species: Guinea pig

Result: Did not cause sensitisation on laboratory animals.

fludioxonil:

Species: Guinea pig

Result: Did not cause sensitisation on laboratory animals.

1,2-benzisothiazol-3(2H)-one:

Result: Probability or evidence of skin sensitisation in humans

Germ cell mutagenicity

Components:

sedaxane:

Germ cell mutagenicity-

Assessment

Animal testing did not show any mutagenic effects.

difenoconazole:

Germ cell mutagenicity-

Assessment

Animal testing did not show any mutagenic effects.

fludioxonil:

Germ cell mutagenicity-

Assessment

Animal testing did not show any mutagenic effects.

Carcinogenicity

Components:

sedaxane:

Carcinogenicity -

Assessment

Weight of evidence does not support classification as a

carcinogen, At extremely high doses, numerically higher

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

VIBRANCE GOLD

Version

Revision Date:

20.02.2017

SDS Number:

S1464594542

This version replaces all previous

versions.

11 / 22

incidences of uterine, thyroid and liver tumors (male and/or

female rats) and liver tumors (male mice) were within the

range of normal background variation and thus considered

unrelated to treatment. Some Regulatory Authorities have

taken a more conservative position that these high-dose

findings are treatment-related in rats and mice. The dose

levels where these findings occur are not relevant to human

exposure levels.

difenoconazole:

Carcinogenicity -

Assessment

Weight of evidence does not support classification as a

carcinogen, In a two-year feeding study of mice, an oncogenic

effect was seen in the livers of males and females., The

observed tumors do not appear to be relevant for men.

fludioxonil:

Carcinogenicity -

Assessment

No evidence of carcinogenicity in animal studies.

Reproductive toxicity

Components:

sedaxane:

Reproductive toxicity -

Assessment

No toxicity to reproduction

difenoconazole:

Reproductive toxicity -

Assessment

No toxicity to reproduction

fludioxonil:

Reproductive toxicity -

Assessment

No toxicity to reproduction

STOT - single exposure

Components:

bronopol (INN):

Assessment: The substance or mixture is classified as specific target organ toxicant, single

exposure, category 3 with respiratory tract irritation.

Repeated dose toxicity

Components:

sedaxane:

Remarks: No adverse effect has been observed in chronic toxicity tests.

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

VIBRANCE GOLD

Version

Revision Date:

20.02.2017

SDS Number:

S1464594542

This version replaces all previous

versions.

12 / 22

difenoconazole:

Remarks: No adverse effect has been observed in chronic toxicity tests.

fludioxonil:

Remarks: No adverse effect has been observed in chronic toxicity tests.

SECTION 12: Ecological information

12.1 Toxicity

Product:

Ecotoxicology Assessment

Acute aquatic toxicity

Very toxic to aquatic life., Classification of the product is

based on the summation of the concentrations of classified

components.

Chronic aquatic toxicity

Very toxic to aquatic life with long lasting effects.,

Classification of the product is based on the summation of the

concentrations of classified components.

Components:

poly(oxy-1,2-ethanediyl), alpha-9-octadecenyl-omega-hydroxy-,(Z)-:

Toxicity to fish

LC50 (Danio rerio (zebra fish)): 1 - 10 mg/l

Exposure time: 96 h

Ecotoxicology Assessment

Acute aquatic toxicity

This product has no known ecotoxicological effects.

Chronic aquatic toxicity

This product has no known ecotoxicological effects.

sedaxane:

Toxicity to fish

LC50 (Cyprinus carpio (Carp)): 0.62 mg/l

Exposure time: 96 h

LC50 (Pimephales promelas (fathead minnow)): 0.98 mg/l

Exposure time: 96 h

Toxicity to daphnia and other

aquatic invertebrates

EC50 (Daphnia magna (Water flea)): 6.10 mg/l

Exposure time: 48 h

Toxicity to algae

ErC50 (Pseudokirchneriella subcapitata (green algae)): 3 mg/l

Exposure time: 96 h

NOEC (Pseudokirchneriella subcapitata (green algae)): 1 mg/l

End point: Growth rate

Exposure time: 96 h

ErC50 (Lemna gibba (gibbous duckweed)): 6.5 mg/l

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

VIBRANCE GOLD

Version

Revision Date:

20.02.2017

SDS Number:

S1464594542

This version replaces all previous

versions.

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Exposure time: 7 d

NOEC (Lemna gibba (gibbous duckweed)): 0.59 mg/l

End point: Growth rate

Exposure time: 7 d

M-Factor (Acute aquatic

toxicity)

Toxicity to fish (Chronic

toxicity)

NOEC: 0.165 mg/l

Exposure time: 33 d

Species: Pimephales promelas (fathead minnow)

Toxicity to daphnia and other

aquatic invertebrates

(Chronic toxicity)

NOEC: 0.82 mg/l

Exposure time: 21 d

Species: Daphnia magna (Water flea)

difenoconazole:

Toxicity to fish

LC50 (Oncorhynchus mykiss (rainbow trout)): 1.1 mg/l

Exposure time: 96 h

Toxicity to daphnia and other

aquatic invertebrates

EC50 (Daphnia magna (Water flea)): 0.77 mg/l

Exposure time: 48 h

EC50 (Americamysis bahia (Mysid shrimp)): 0.15 mg/l

Exposure time: 96 h

Toxicity to algae

EC50 (Navicula pelliculosa (Freshwater diatom)): 0.091 mg/l

Exposure time: 72 h

NOEC (Navicula pelliculosa (Freshwater diatom)): 0.053 mg/l

Exposure time: 72 h

NOEC (Desmodesmus subspicatus (green algae)): 0.0086

mg/l

Exposure time: 72 h

M-Factor (Acute aquatic

toxicity)

Toxicity to microorganisms

EC50 (activated sludge): > 100 mg/l

Exposure time: 3 h

Toxicity to fish (Chronic

toxicity)

NOEC: 0.0076 mg/l

Exposure time: 34 d

Species: Pimephales promelas (fathead minnow)

Toxicity to daphnia and other

aquatic invertebrates

(Chronic toxicity)

NOEC: 0.0056 mg/l

Exposure time: 21 d

Species: Daphnia magna (Water flea)

NOEC: 0.0046 mg/l

Exposure time: 28 d

Species: Americamysis

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

VIBRANCE GOLD

Version

Revision Date:

20.02.2017

SDS Number:

S1464594542

This version replaces all previous

versions.

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M-Factor (Chronic aquatic

toxicity)

fludioxonil:

Toxicity to fish

LC50 (Oncorhynchus mykiss (rainbow trout)): 0.23 mg/l

Exposure time: 96 h

Toxicity to daphnia and other

aquatic invertebrates

EC50 (Daphnia magna (Water flea)): 0.4 mg/l

Exposure time: 48 h

Toxicity to algae

ErC50 (Pseudokirchneriella subcapitata (green algae)): > 0.44

mg/l

Exposure time: 96 h

NOEC (Pseudokirchneriella subcapitata (green algae)): 0.132

mg/l

Exposure time: 96 h

ErC50 (Skeletonema costatum (marine diatom)): 0.43 mg/l

Exposure time: 96 h

NOEC (Skeletonema costatum (marine diatom)): 0.14 mg/l

End point: Growth rate

Exposure time: 96 h

M-Factor (Acute aquatic

toxicity)

Toxicity to microorganisms

EC50 (activated sludge): > 100 mg/l

Exposure time: 3 h

Toxicity to fish (Chronic

toxicity)

NOEC: 0.04 mg/l

Exposure time: 28 d

Species: Oncorhynchus mykiss (rainbow trout)

Toxicity to daphnia and other

aquatic invertebrates

(Chronic toxicity)

NOEC: 0.035 mg/l

Exposure time: 21 d

Species: Daphnia magna (Water flea)

M-Factor (Chronic aquatic

toxicity)

poly(oxy-1,2-ethanediyl), alpha-sulfo-omega-[tris(1-phenylethyl)phenoxy]-, ammonium salt:

Toxicity to fish

LC50 (Oncorhynchus mykiss (rainbow trout)): 33 mg/l

Exposure time: 96 h

Toxicity to daphnia and other

aquatic invertebrates

EC50 (Daphnia magna (Water flea)): 24 mg/l

Exposure time: 48 h

Ecotoxicology Assessment

Acute aquatic toxicity

This product has no known ecotoxicological effects.

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

VIBRANCE GOLD

Version

Revision Date:

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SDS Number:

S1464594542

This version replaces all previous

versions.

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Chronic aquatic toxicity

Harmful to aquatic life with long lasting effects.

1,2-benzisothiazol-3(2H)-one:

Ecotoxicology Assessment

Acute aquatic toxicity

Very toxic to aquatic life.

bronopol (INN):

Toxicity to algae

NOEC (algae): 0.0025 mg/l

Exposure time: 72 h

M-Factor (Acute aquatic

toxicity)

M-Factor (Chronic aquatic

toxicity)

Ecotoxicology Assessment

Acute aquatic toxicity

Very toxic to aquatic life.

12.2 Persistence and degradability

Components:

poly(oxy-1,2-ethanediyl), alpha-9-octadecenyl-omega-hydroxy-,(Z)-:

Biodegradability

Result: Readily biodegradable.

sedaxane:

Biodegradability

Result: Not readily biodegradable.

Stability in water

Degradation half life: > 1 y

Remarks: Persistent in water.

difenoconazole:

Biodegradability

Result: Not readily biodegradable.

Stability in water

Degradation half life: 1 d

Remarks: Product is not persistent.

fludioxonil:

Biodegradability

Result: Not readily biodegradable.

bronopol (INN):

Biodegradability

Result: Readily biodegradable.

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

VIBRANCE GOLD

Version

Revision Date:

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SDS Number:

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12.3 Bioaccumulative potential

Components:

sedaxane:

Bioaccumulation

Remarks: Does not bioaccumulate.

Partition coefficient: n-

octanol/water

log Pow: 3.3 (25 °C)

difenoconazole:

Bioaccumulation

Remarks: High bioaccumulation potential.

Partition coefficient: n-

octanol/water

log Pow: 4.4 (25 °C)

fludioxonil:

Bioaccumulation

Remarks: Does not bioaccumulate.

Partition coefficient: n-

octanol/water

log Pow: 4.12 (25 °C)

12.4 Mobility in soil

Components:

sedaxane:

Distribution among

environmental compartments

Remarks: Low to medium mobility in soil.

Stability in soil

Percentage dissipation: 50 % (DT50: 83 d)

Remarks: Product is not persistent.

difenoconazole:

Distribution among

environmental compartments

Remarks: Low mobility in soil.

Stability in soil

Percentage dissipation: 50 % (DT50: 149 - 187 d)

Remarks: Product is not persistent.

fludioxonil:

Distribution among

environmental compartments

Remarks: immobile

Stability in soil

Percentage dissipation: 50 % (DT50: 14 d)

Remarks: Product is not persistent.

12.5 Results of PBT and vPvB assessment

Product:

Assessment

This substance/mixture contains no components considered

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to be either persistent, bioaccumulative and toxic (PBT), or

very persistent and very bioaccumulative (vPvB) at levels of

0.1% or higher..

Components:

sedaxane:

Assessment

This substance is not considered to be persistent,

bioaccumulating and toxic (PBT).. This substance is not

considered to be very persistent and very bioaccumulating

(vPvB)..

difenoconazole:

Assessment

This substance is not considered to be persistent,

bioaccumulating and toxic (PBT).. This substance is not

considered to be very persistent and very bioaccumulating

(vPvB)..

fludioxonil:

Assessment

This substance is not considered to be persistent,

bioaccumulating and toxic (PBT).. This substance is not

considered to be very persistent and very bioaccumulating

(vPvB)..

12.6 Other adverse effects

Components:

poly(oxy-1,2-ethanediyl), alpha-9-octadecenyl-omega-hydroxy-,(Z)-:

Additional ecological

information

No data available

sedaxane:

Additional ecological

information

No data available

difenoconazole:

Additional ecological

information

No data available

fludioxonil:

Additional ecological

information

No data available

poly(oxy-1,2-ethanediyl), alpha-sulfo-omega-[tris(1-phenylethyl)phenoxy]-, ammonium salt:

Additional ecological

information

No data available

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1,2-benzisothiazol-3(2H)-one:

Additional ecological

information

No data available

bronopol (INN):

Additional ecological

information

No data available

SECTION 13: Disposal considerations

13.1 Waste treatment methods

Product

Do not contaminate ponds, waterways or ditches with

chemical or used container.

Do not dispose of waste into sewer.

Where possible recycling is preferred to disposal or

incineration.

If recycling is not practicable, dispose of in compliance with

local regulations.

Contaminated packaging

Empty remaining contents.

Triple rinse containers.

Empty containers should be taken to an approved waste

handling site for recycling or disposal.

Do not re-use empty containers.

SECTION 14: Transport information

14.1 UN number

ADN

UN 3082

ADR

UN 3082

RID

UN 3082

IMDG

UN 3082

IATA

UN 3082

14.2 UN proper shipping name

ADN

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,

N.O.S.

(DIFENOCONAZOLE AND FLUDIOXONIL)

ADR

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,

N.O.S.

(DIFENOCONAZOLE AND FLUDIOXONIL)

RID

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,

N.O.S.

(DIFENOCONAZOLE AND FLUDIOXONIL)

IMDG

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,

N.O.S.

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(DIFENOCONAZOLE AND FLUDIOXONIL)

IATA

Environmentally hazardous substance, liquid, n.o.s.

(DIFENOCONAZOLE AND FLUDIOXONIL)

14.3 Transport hazard class(es)

ADN

ADR

RID

IMDG

IATA

14.4 Packing group

ADN

Packing group

Classification Code

Hazard Identification Number

Labels

ADR

Packing group

Classification Code

Hazard Identification Number

Labels

Tunnel restriction code

RID

Packing group

Classification Code

Hazard Identification Number

Labels

IMDG

Packing group

Labels

EmS Code

F-A, S-F

IATA (Cargo)

Packing instruction (cargo

aircraft)

Packing instruction (LQ)

Y964

Packing group

Labels

Miscellaneous

IATA (Passenger)

Packing instruction

(passenger aircraft)

Packing instruction (LQ)

Y964

Packing group

Labels

Miscellaneous

14.5 Environmental hazards

ADN

Environmentally hazardous

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ADR

Environmentally hazardous

RID

Environmentally hazardous

IMDG

Marine pollutant

IATA (Passenger)

Marine pollutant

IATA (Cargo)

Marine pollutant

14.6 Special precautions for user

Not applicable

14.7 Transport in bulk according to Annex II of Marpol and the IBC Code

Not applicable for product as supplied.

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or

mixture

Regulation (EC) No 649/2012 of the European

Parliament and the Council concerning the export and

import of dangerous chemicals

Not applicable

REACH - Candidate List of Substances of Very High

Concern for Authorisation (Article 59).

Not applicable

Regulation (EC) No 1005/2009 on substances that

deplete the ozone layer

Not applicable

Regulation (EC) No 850/2004 on persistent organic

pollutants

Not applicable

Seveso III: Directive 2012/18/EU of the European Parliament and of the Council on the control of

major-accident hazards involving dangerous substances.

Quantity 1

Quantity 2

ENVIRONMENTAL

HAZARDS

100 t

200 t

Other regulations

Take note of Directive 98/24/EC on the protection of the

health and safety of workers from the risks related to chemical

agents at work.

15.2 Chemical safety assessment

A Chemical Safety Assessment is not required for this substance when it is used in the specified

applications.

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SECTION 16: Other information

Full text of H-Statements

H302

Harmful if swallowed.

H312

Harmful in contact with skin.

H315

Causes skin irritation.

H317

May cause an allergic skin reaction.

H318

Causes serious eye damage.

H319

Causes serious eye irritation.

H335

May cause respiratory irritation.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

H411

Toxic to aquatic life with long lasting effects.

H412

Harmful to aquatic life with long lasting effects.

Full text of other abbreviations

Acute Tox.

Acute toxicity

Aquatic Acute

Acute aquatic toxicity

Aquatic Chronic

Chronic aquatic toxicity

Eye Dam.

Serious eye damage

Eye Irrit.

Eye irritation

Skin Irrit.

Skin irritation

Skin Sens.

Skin sensitisation

STOT SE

Specific target organ toxicity - single exposure

ADN - European Agreement concerning the International Carriage of Dangerous Goods by Inland

Waterways; ADR - European Agreement concerning the International Carriage of Dangerous

Goods by Road; AICS - Australian Inventory of Chemical Substances; ASTM - American Society

Testing

Materials;

Body

weight;

Classification

Labelling

Packaging

Regulation;

Regulation

(EC)

1272/2008;

Carcinogen,

Mutagen

Reproductive

Toxicant; DIN - Standard of the German Institute for Standardisation; DSL - Domestic Substances

List

(Canada);

ECHA

European

Chemicals

Agency;

EC-Number

European

Community

number; ECx - Concentration associated with x% response; ELx - Loading rate associated with

x% response; EmS - Emergency Schedule; ENCS - Existing and New Chemical Substances

(Japan); ErCx - Concentration associated with x% growth rate response; GHS - Globally

Harmonized System; GLP - Good Laboratory Practice; IARC - International Agency for Research

on Cancer; IATA - International Air Transport Association; IBC - International Code for the

Construction and Equipment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half maximal

inhibitory concentration; ICAO - International Civil Aviation Organization; IECSC - Inventory of

Existing Chemical Substances in China; IMDG - International Maritime Dangerous Goods; IMO -

International Maritime Organization; ISHL - Industrial Safety and Health Law (Japan); ISO -

International Organisation for Standardization; KECI - Korea Existing Chemicals Inventory; LC50

- Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to 50% of a test

population (Median Lethal Dose); MARPOL - International Convention for the Prevention of

Pollution from Ships; n.o.s. - Not Otherwise Specified; NO(A)EC - No Observed (Adverse) Effect

Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No Observable Effect

Loading Rate; NZIoC - New Zealand Inventory of Chemicals; OECD - Organization for Economic

Co-operation and Development; OPPTS - Office of Chemical Safety and Pollution Prevention;

PBT - Persistent, Bioaccumulative and Toxic substance; PICCS - Philippines Inventory of

Chemicals and Chemical Substances; (Q)SAR - (Quantitative) Structure Activity Relationship;

REACH - Regulation (EC) No 1907/2006 of the European Parliament and of the Council

concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals; RID -

Regulations concerning the International Carriage of Dangerous Goods by Rail; SADT - Self-

Accelerating Decomposition Temperature; SDS - Safety Data Sheet; TCSI - Taiwan Chemical

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

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SDS Number:

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Substance Inventory; TSCA - Toxic Substances Control Act (United States); UN - United Nations;

UNRTDG - United Nations Recommendations on the Transport of Dangerous Goods; vPvB -

Very Persistent and Very Bioaccumulative

Further information

The information provided in this Safety Data Sheet is correct to the best of our knowledge,

information and belief at the date of its publication. The information given is designed only as a

guidance for safe handling, use, processing, storage, transportation, disposal and release and is

not to be considered a warranty or quality specification. The information relates only to the

specific material designated and may not be valid for such material used in combination with any

other materials or in any process, unless specified in the text.

CH / EN

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