Tricera

Primær information

  • Handelsnavn:
  • Tricera Emulsionskoncentrat
  • Lægemiddelform:
  • Emulsionskoncentrat
  • Sammensætning:
  • 30 g/l clopyralid; 75 g/l fluroxypyr; 375 g/l 2,4-D
  • Brugt til:
  • Planter
  • Medicin typen:
  • agrokemiske

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Lokation

  • Fås i:
  • Tricera Emulsionskoncentrat
    Danmark
  • Sprog:
  • dansk

Andre oplysninger

Status

  • Kilde:
  • SEGES Landbrug & Fødevarer
  • Autorisation status:
  • Afprøvet i Landsforsøg
  • Sidste ændring:
  • 07-02-2018

Produktresumé

2,4-d/Fluroxypyr/Clopyralid 480 EC

SAFETY DATA SHEET

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH) Annex II

Revision Date 11-Nov-2015

Version

Product No HRB00991

Publish Date 11-Nov-2015

H-221-SO-RAII AG-CDF1-480 EC

Section 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE

COMPANY/UNDERTAKING

1.1. Product identifier

2,4-d/Fluroxypyr/Clopyralid 480 EC

Pure substance/mixture

Mixture

1.2. Relevant identified uses of the substance or mixture and uses advised against

Recommended Use

Herbicide

Uses advised against

No information available

1.3. Details of the supplier of the safety data sheet

Supplier Address

ADAMA Agan Ltd

P.O.B. 262

ASHDOD Israel

For further information, please contact

Email address

SDS@ADAMA.COM

1.4. Emergency telephone number

Emergency Telephone

+972-03-6106666 Subscription no. 36789 (ADAMA Makhteshim Ltd.)

Section 2: HAZARDS IDENTIFICATION

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No. 1272/2008 [CLP]

Acute toxicity - Oral

Category 4 - (H302)

Serious eye damage/eye irritation

Category 1 - (H318)

_____________________________________________________________________________________________

Skin sensitization

Category 1 - (H317)

Hazardous to the Aquatic

Environment - Chronic Hazard

Category 2 - (H411)

2.2. Label elements

Page 1 / 9

Labeling according to Regulation (EC) No. 1272/2008 [CLP]

_____________________________________________________________________________________________

2,4-d/Fluroxypyr/Clopyralid 480 EC - HRB00991

Revision Date 11-Nov-2015

Hazard pictograms

Signal word

Danger

Hazard Statements

H302 - Harmful if swallowed

H317 - May cause an allergic skin reaction

H318 - Causes serious eye damage

H411 - Toxic to aquatic life with long lasting effects

Precautionary Statements

P102 - Keep out of reach of children

P270 - Do not eat, drink or smoke when using this product

P280 - Wear protective gloves/protective clothing/eye protection/face protection

P302 + P352 - IF ON SKIN: Wash with plenty of soap and water

P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes.

Remove contact lenses, if present and easy to do. Continue rinsing

P501 - Dispose of contents/ container to an approved waste disposal plant

EU Specific Hazard Statements

EUH401 - To avoid risks to human health and the environment, comply with the instructions

for use

Additional phrases for PPP

SP1 - Do not contaminate water with the product or its container (Do not clean application

equipment near surface water/Avoid contamination via drains from farmyards and roads).

2.3. Other hazards

No information available

Section 3: COMPOSITION/INFORMATION ON INGREDIENTS

3.2 Mixture

Chemical Name

Weight-%

CAS No

EC No

Index No

Classification according to

Regulation (EC) No.

1272/2008 [CLP]

M-Factor

REACH

Registration

Number

2,4-D ester

52-58

1928-43-4

217-673-3

607-308-00-X

Acute Tox. 4 (H302)

Skin Sens. 1 (H317)

Aquatic Acute 1 (H400)

Aquatic Chronic 1 (H410)

Fluroxypyr-meptyl

8-12

81406-37-3

279-752-9

607-272-00-5

Aquatic Acute 1 (H400)

Aquatic Chronic 1 (H410)

Clopyralid (ISO)

1702-17-6

216-935-4

607-231-00-1

Eye Dam. 1 (H318)

2-Ethylhexanol

104-76-7

203-234-3

STOT SE 3 (H335)

Skin Irrit. 2 (H315)

Eye Irrit. 2 (H319)

Acute Tox. 4 (H332)

01-211948728

9-20

Benzenesulfonic acid,

C10-13-alkyl derivs.,

calcium salt

90194-26-6

Skin Irrit. 2 (H315)

Eye Dam. 1 (H318)

Aquatic Chronic 3 (H412)

01-211956059

2-37

_____________________________________________________________________________________________

Full text of H- and EUH-phrases: see section 16

Section 4: FIRST AID MEASURES

Page 2 / 9

_____________________________________________________________________________________________

2,4-d/Fluroxypyr/Clopyralid 480 EC - HRB00991

Revision Date 11-Nov-2015

4.1. Description of first aid measures

General advice

In case of accident or unwellness, seek medical advice immediately (show directions for

use or safety data sheet if possible). First aider: Pay attention to self-protection!.

Inhalation

Remove to fresh air. If breathing is irregular or stopped, administer artificial respiration. Call

a physician.

Skin Contact

Wash off immediately with soap and plenty of water while removing all contaminated

clothes and shoes. Consult a physician if necessary.

Eye contact

Immediately flush with plenty of water. After initial flushing, remove any contact lenses and

continue flushing for at least 15 minutes. Keep eye wide open while rinsing. Immediate

medical attention is required.

Ingestion

Rinse mouth. Drink plenty of water. Call a physician or poison control center immediately.

Self-protection of the first aider

Use personal protective equipment as required.

4.2. Most important symptoms and effects, both acute and delayed

Symptoms

None known

4.3. Indication of any immediate medical attention and special treatment needed

Note to physicians

Treat symptomatically.

Section 5: FIRE-FIGHTING MEASURES

5.1. Extinguishing media

Suitable Extinguishing Media

Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Unsuitable Extinguishing Media

No information available.

5.2. Special hazards arising from the substance or mixture

No specific hazard known.

5.3. Advice for firefighters

In the event of fire, wear self-contained breathing apparatus

In the event of fire and/or explosion do not breathe fumes.

Section 6: ACCIDENTAL RELEASE MEASURES

_____________________________________________________________________________________________

6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions

Avoid contact with skin, eyes or clothing. Use personal protective equipment as required. Evacuate personnel to safe areas. Keep

people away from and upwind of spill/leak.

For emergency responders

Use personal protection recommended in Section 8.

Page 3 / 9

6.2. Environmental precautions

_____________________________________________________________________________________________

2,4-d/Fluroxypyr/Clopyralid 480 EC - HRB00991

Revision Date 11-Nov-2015

Prevent entry into waterways, sewers, basements or confined areas. Do not flush into surface water or sanitary sewer system.

Prevent further leakage or spillage if safe to do so. Prevent product from entering drains.

6.3. Methods and material for containment and cleaning up

Methods for cleaning up

Take up mechanically, placing in appropriate containers for disposal.

6.4. Reference to other sections

Other Information

See also section 8,13

Section 7: HANDLING AND STORAGE

7.1. Precautions for safe handling

Advice on safe handling

Avoid contact with skin, eyes or clothing. Wash contaminated clothing before reuse. Do not eat, drink or smoke when using this

product. Use personal protective equipment as required. Do not breathe dust/fume/gas/mist/vapors/spray. Use with local exhaust

ventilation.

General Hygiene Considerations

When using do not eat, drink or smoke. Wash contaminated clothing before reuse. Regular cleaning of equipment, work area and

clothing is recommended.

7.2. Conditions for safe storage, including any incompatibilities

Storage Conditions

Keep container tightly closed in a dry and well-ventilated place. Keep out of the reach of children. Keep containers tightly closed in

a cool, well-ventilated place. Keep in properly labeled containers.

7.3. Specific end use(s)

Risk Management Methods (RMM)

The information required is contained in this Material Safety Data Sheet.

Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1. Control parameters

Chemical Name

European Union

France

Spain

Germany

2,4-D ester

1928-43-4

TWA: 1 mg/m

Ceiling / Peak: 8

mg/m

Skin

2-Ethylhexanol

104-76-7

TWA: 10 ppm

TWA: 54 mg/m

Ceiling / Peak: 10 ppm

Ceiling / Peak: 54

mg/m

TWA: 20 ppm

TWA: 110 mg/m

Chemical Name

Austria

Switzerland

Poland

Norway

Ireland

2,4-D ester

1928-43-4

Skin

STEL 4 mg/m

TWA: 1 mg/m

_____________________________________________________________________________________________

Skin

STEL: 8 mg/m

TWA: 1 mg/m

2-Ethylhexanol

104-76-7

Skin

STEL 100 ppm

STEL 540 mg/m

TWA: 50 ppm

TWA: 270 mg/m

STEL: 20 ppm

STEL: 110 mg/m

TWA: 20 ppm

TWA: 110 mg/m

STEL: 320 mg/m

TWA: 160 mg/m

Page 4 / 9

_____________________________________________________________________________________________

2,4-d/Fluroxypyr/Clopyralid 480 EC - HRB00991

Revision Date 11-Nov-2015

8.2. Exposure controls

Engineering Controls

Ensure adequate ventilation, especially in confined areas.

Personal protective equipment

Eye/face protection

Tight sealing safety goggles.

Hand Protection

Gloves made of plastic or rubber.

Body Protection

Suitable protective clothing, Apron, Gloves made of plastic or rubber.

General Hygiene Considerations

When using do not eat, drink or smoke. Wash contaminated clothing before reuse. Regular

cleaning of equipment, work area and clothing is recommended.

Environmental exposure controls

Do not allow into any sewer, on the ground or into any body of water.

Section 9: PHYSICAL AND CHEMICAL PROPERTIES

9.1. Information on basic physical and chemical properties

9.2. Other information

Section 10: STABILITY AND REACTIVITY

10.1. Reactivity

No data available.

10.2. Chemical stability

Stable under normal conditions.

10.3. Possibility of hazardous reactions

Property

Values

Method

Remarks

Appearance

Physical state

:

Liquid

Color

:

amber

Odor

:

Aromatic

Odor threshold

:

No data available

pH

:

2.3 - 3.3

CIPAC MT 75.3

Melting point/freezing point °C

:

----

Not Applicable

Boiling point/boiling range °C

:

----

Not Applicable

Flash point °C

:

111.2

ASTM D7094

Evaporation rate

:

Not Applicable

Flammability (solid, gas)

:

Not applicable for liquids

Upper/lower flammability or

explosive limits

:

No data available

Vapor pressure kPa

:

----

Not Applicable

Vapor density

:

No data available

Relative density

:

1.045 - 1.145

CIPAC MT 3.1

Solubility(ies) mg/l

:

----

Not Applicable

Partition Coefficient

(n-octanol/water) Log Pow

:

See Section 12 for more

information

Autoignition temperature °C

:

----

No data available

Decomposition temperature °C

:

No data available

Kinematic viscosity mm2/s 40 °C

:

OECD 114

Explosive properties

:

Not an explosive

EEC A.14

Oxidizing properties

:

Not oxidizing

EEC A.21

_____________________________________________________________________________________________

Bulk density g/ml

:

Surface tension mN/m

:

29.6

Page 5 / 9

EEC A.5

25 °C

_____________________________________________________________________________________________

2,4-d/Fluroxypyr/Clopyralid 480 EC - HRB00991

Revision Date 11-Nov-2015

None under normal processing.

10.4. Conditions to avoid

Heat, flames and sparks.

10.5. Incompatible materials

No information available

10.6. Hazardous decomposition products

None under normal use conditions.

Section 11: TOXICOLOGY INFORMATION

11.1. Information on toxicological effects

Acute toxicity

Chronic toxicity

Germ cell mutagenicity

Chemical Name

2,4-D ester

:

Not classified

Fluroxypyr-meptyl

:

Not classified

Clopyralid (ISO)

:

Not classified

Carcinogenicity

Chemical Name

2,4-D ester

:

Not Carcinogenic

Fluroxypyr-meptyl

:

Not Carcinogenic

Clopyralid (ISO)

:

Not Carcinogenic

Reproductive toxicity .

Chemical Name

2,4-D ester

:

Not toxic for the reproductive system

Fluroxypyr-meptyl

:

Not toxic for the reproductive system

Clopyralid (ISO)

:

Not toxic for the reproductive system

STOT - single exposure

Chemical Name

2,4-D ester

:

Not available

Fluroxypyr-meptyl

:

Not available

Clopyralid (ISO)

:

No data available

STOT - repeated exposure

Chemical Name

2,4-D ester

:

Not available

Fluroxypyr-meptyl

:

Not available

Clopyralid (ISO)

:

No data available

Aspiration hazard

Values

Species

Method

Remarks

Oral LD50 mg/kg

:

OECD 423

Dermal LD50 mg/kg

:

> 2000

OECD 402

Inhalation LC50 mg/l/4h

:

5.08

OECD 403

Skin corrosion/irritation

:

Non-irritating to the skin

Rabbit

OECD 404

Serious eye damage/eye irritation

:

Severely irritating to eyes

Rabbit

OECD 405

Respiratory/skin sensitization

:

Skin sensitizer

_____________________________________________________________________________________________

Guinea pig

OECD 429

Page 6 / 9

_____________________________________________________________________________________________

2,4-d/Fluroxypyr/Clopyralid 480 EC - HRB00991

Revision Date 11-Nov-2015

Chemical Name

2,4-D ester

:

Not available

Fluroxypyr-meptyl

:

Not available

Clopyralid (ISO)

:

Section 12: ECOLOGICAL INFORMATION

12.1. Toxicity

Aquatic toxicity

Terrestrial Toxicity

Birds Oral LD50 mg/kg

Chemical Name

2,4-D ester

:

> 633

Japanese quail

Fluroxypyr-meptyl

:

> 2000

Bobwhite quail

Clopyralid (ISO)

:

1465

Mallard duck

Bees Oral LD50 μg/bee

Chemical Name

2,4-D ester

:

Fluroxypyr-meptyl

:

> 100

Clopyralid (ISO)

:

> 100

12.2. Persistence and degradability

Water DT50 days

Chemical Name

2,4-D ester

:

OECD 308

Fluroxypyr-meptyl

:

38.1

Clopyralid (ISO)

:

No data available

Soil DT50 days

Chemical Name

2,4-D ester

:

OECD 307

Fluroxypyr-meptyl

:

Clopyralid (ISO)

:

14 - 56

Biodegradation

Chemical Name

2,4-D ester

:

Not available

Fluroxypyr-meptyl

:

No data available

Clopyralid (ISO)

:

Readily biodegradable

readly biodegradable

12.3. Bioaccumulative potential

Chemical Name

2,4-D ester

:

5.78

OECD 121

25° C

Fluroxypyr-meptyl

:

5.04

pH 7

Clopyralid (ISO)

:

- 2.63

pH 7

Acute toxicity

Values

Species

Method

Remarks

Fish 96-hour LC50 mg/l

:

> 100

Oncorhynchus

mykiss

OECD 203

Crustacea 48-hour EC50 mg/l

:

> 100

Daphnia magna

OECD 202

Algae 72-hour EC50 mg/l

:

> 100

P. subcapitata

OECD 201

Other plants EC50 mg/l

:

82.1

Lemna gibba

OECD 221

_____________________________________________________________________________________________

Abiotic Degradation

Values

Method

Remarks

Partition Coefficient

(n-octanol/water) Log Pow

Values

Page 7 / 9

Method

Remarks

_____________________________________________________________________________________________

2,4-d/Fluroxypyr/Clopyralid 480 EC - HRB00991

Revision Date 11-Nov-2015

Bioconcentration factor (BCF)

Chemical Name

2,4-D ester

:

Not available

Fluroxypyr-meptyl

:

Clopyralid (ISO)

:

12.4. Mobility in soil

Chemical Name

2,4-D ester

:

84540

OECD 121

Fluroxypyr-meptyl

:

19550

Clopyralid (ISO)

:

4.64

12.5. Results of PBT and vPvB assessment

The components in this formulation do not meet the criteria for classification as PBT or vPvB

12.6. Other adverse effects

No information available.

Section 13: DISPOSAL CONSIDERATIONS

13.1. Waste treatment methods

Waste from residues/unused

products

Disposal should be in accordance with applicable regional, national and local laws and

regulations.

Contaminated packaging

Improper disposal or reuse of this container may be dangerous and illegal.

Other Information

Waste codes should be assigned by the user based on the application for which the product

was used.

Section 14: TRANSPORTATION INFORMATION

IMDG/IMO

14.1 UN/ID No

3082

14.2 Proper shipping name

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. ( 2,4-D ester

Fluroxypyr-meptyl )

14.3 Hazard Class

14.4 Packing Group

14.5 Marine pollutant

14.6 Special precautions for user

RID/ADR

14.1 UN/ID No

3082

14.2 Proper shipping name

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. ( 2,4-D ester

Fluroxypyr-meptyl )

14.3 Hazard Class

14.4 Packing Group

14.5 Environmental hazard

14.6 Special precautions for user

ICAO/IATA

14.1 UN/ID No

3082

14.2 Proper shipping name

_____________________________________________________________________________________________

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. ( 2,4-D ester

Fluroxypyr-meptyl )

14.3 Hazard Class

14.4 Packing Group

Adsorption/Desorption

Values

Page 8 / 9

Method

Remarks

_____________________________________________________________________________________________

2,4-d/Fluroxypyr/Clopyralid 480 EC - HRB00991

Revision Date 11-Nov-2015

14.5 Environmental hazard

14.6 Special precautions for user

14.7 Transport in bulk according to

Annex II of MARPOL 73/78 and the

IBC Code

Not Applicable

Section 15: REGULATORY INFORMATION

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

15.2. Chemical safety assessment

A chemical safety assessment according to regulation (EC) No. 1907/2006 is not required. A risk assessment was performed

according to directive (EC) No. 91/414 or according to regulation (EC) No. 1107/2009.

Section 16: OTHER INFORMATION

Full text of H-Statements referred to under sections 2 and 3

H302 - Harmful if swallowed

H315 - Causes skin irritation

H317 - May cause an allergic skin reaction

H318 - Causes serious eye damage

H319 - Causes serious eye irritation

H332 - Harmful if inhaled

H335 - May cause respiratory irritation

H400 - Very toxic to aquatic life

H410 - Very toxic to aquatic life with long lasting effects

H412 - Harmful to aquatic life with long lasting effects

_____________________________________________________________________________________________

Revision Note

*** - Change from previous version.

This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006

Disclaimer

The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief

at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing,

storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The

information relates only to the specific material designated and may not be valid for such material used in combination

with any other materials or in any process, unless specified in the text.

Page 9 / 9

End of Safety Data Sheet

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