Proman

Primær information

  • Handelsnavn:
  • Proman Suspensionskoncentrat
  • Lægemiddelform:
  • Suspensionskoncentrat
  • Sammensætning:
  • 500 g/l metobromuron
  • Brugt til:
  • Planter
  • Medicin typen:
  • agrokemiske

Dokumenter

  • for den brede offentlighed:
  • Oplysningerne indlægssedlen for dette produkt er i øjeblikket ikke tilgængelig, kan du sende en anmodning til vores kundeservice, og vi vil give dig besked, så snart vi er i stand til at opnå det.


    Anmode informationsbrochure for offentligheden.

Lokation

  • Fås i:
  • Proman Suspensionskoncentrat
    Danmark
  • Sprog:
  • dansk

Andre oplysninger

Status

  • Kilde:
  • SEGES Landbrug & Fødevarer
  • Autorisation status:
  • Afprøvet i Landsforsøg
  • Sidste ændring:
  • 07-02-2018

Produktresumé

Proman

Safety Data Sheet

according to Regulation (EU) 2015/830

Date of issue: 2016/01/27

Revision date:

Supersedes: 2015/06/16

Version: 1.0

2016/01/27

EN (English)

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1.

Product identifier

Product form

Mixture

Trade name

Proman

Product code

BCP222H

Product group

Blend

1.2.

Relevant identified uses of the substance or mixture and uses advised against

1.2.1.

Relevant identified uses

Main use category

Professional use

Use of the substance/mixture

Herbicide

1.2.2.

Uses advised against

No additional information available

1.3.

Details of the supplier of the safety data sheet

Belchim Crop Protection NV/SA

Technologielaan 7

1840 Londerzeel - Belgium

T +32 (0)52 30 09 06 - F +32 (0)52 30 11 35

info@belchim.com - www.belchim.com

1.4.

Emergency telephone number

Emergency number

+32(0)14584545

24 H/7 days

Country

Organisation/Company

Address

Emergency number

Comment

Belgium

Centre Anti-

Poisons/Antigifcentrum

c/o Hôpital Central de la Base - Reine

Astrid

Rue Bruyn 1

1120 Bruxelles/Brussel

+32 70 245 245

SECTION 2: Hazards identification

2.1.

Classification of the substance or mixture

Classification according to Regulation (EC) No. 1272/2008 [CLP]Mixture/Substance: SDS EU 2015: According to Regulation (EU) 2015/830

(REACH Annex II)

Carcinogenicity, Category 2

H351

Specific target organ toxicity — Repeated exposure, Category 2

H373

Hazardous to the aquatic environment — Acute Hazard, Category 1

H400

Hazardous to the aquatic environment — Chronic Hazard, Category 1

H410

Full text of hazard classes and H-statements : see section 16

Adverse physicochemical, human health and environmental effects

No additional information available

2.2.

Label elements

Labelling according to Regulation (EC) No. 1272/2008 [CLP]

Hazard pictograms (CLP)

GHS08

GHS09

Signal word (CLP)

Warning

Hazard statements (CLP)

H351 - Suspected of causing cancer

H373 - May cause damage to organs through prolonged or repeated exposure

H410 - Very toxic to aquatic life with long lasting effects

Precautionary statements (CLP)

P201 - Obtain special instructions before use

P273 - Avoid release to the environment

P280 - Wear protective gloves, protective clothing

Proman

Safety Data Sheet

according to Regulation (EU) 2015/830

2016/01/27

EN (English)

P301+P312 - IF SWALLOWED: Call a POISON CENTER or doctor if you feel unwell

P308+P313 - IF exposed or concerned: Get medical advice/attention

P391 - Collect spillage

P501 - Dispose of contents/container to hazardous or special waste collection point, in

accordance with local, regional, national and/or international regulation

EUH-statements

EUH208 - Contains Metobromuron . May produce an allergic reaction

EUH401 - To avoid risks to human health and the environment, comply with the instructions for

Extra phrases

SP1: Do not contaminate water with the product or its container (Do not clean application

equipment near surface water/Avoid contamination via drains from farmyards and roads)

Spe3: To protect aquatic organisms/non-target plants/non-target arthropods/insects respect an

unsprayed buffer zone of (distance to be specified) to non-agricultural land/surface water

bodies

2.3.

Other hazards

No additional information available

SECTION 3: Composition/information on ingredients

3.1.

Substance

Not applicable

3.2.

Mixture

Name

Product identifier

%

Classification according to

Regulation (EC) No.

1272/2008 [CLP]

Metobromuron Technical

(CAS No)

3060-89-7

(EC no)

221-301-5

<= 50

Acute Tox. 4 (Oral), H302

Skin Sens. 1, H317

Carc. 2, H351

STOT RE 2, H373

Aquatic Acute 1, H400

Aquatic Chronic 1, H410

Sulfonated aromatic polymer, sodium salt

<= 5

Eye Irrit. 2, H319

Full text of H-statements: see section 16

SECTION 4: First aid measures

4.1.

Description of first aid measures

First-aid measures general

IF exposed or concerned: Get medical advice/attention.

First-aid measures after inhalation

Remove person to fresh air and keep comfortable for breathing.

First-aid measures after skin contact

Wash skin with plenty of water.

First-aid measures after eye contact

Rinse eyes with water as a precaution.

First-aid measures after ingestion

Call a poison center or a doctor if you feel unwell.

4.2.

Most important symptoms and effects, both acute and delayed

Symptoms/injuries

Methaemoglobin formation.

4.3.

Indication of any immediate medical attention and special treatment needed

Treat symptomatically.

SECTION 5: Firefighting measures

5.1.

Extinguishing media

Suitable extinguishing media

Water spray. Dry powder. Foam. Carbon dioxide.

5.2.

Special hazards arising from the substance or mixture

Hazardous decomposition products in case of

fire

Toxic fumes may be released.

5.3.

Advice for firefighters

Protection during firefighting

Do not attempt to take action without suitable protective equipment. Self-contained breathing

apparatus. Complete protective clothing.

SECTION 6: Accidental release measures

6.1.

Personal precautions, protective equipment and emergency procedures

6.1.1.

For non-emergency personnel

Emergency procedures

Ventilate spillage area. Do not breathe dust/fume/gas/mist/vapours/spray.

Proman

Safety Data Sheet

according to Regulation (EU) 2015/830

2016/01/27

EN (English)

6.1.2.

For emergency responders

Protective equipment

Do not attempt to take action without suitable protective equipment. For further information

refer to section 8: "Exposure controls/personal protection".

6.2.

Environmental precautions

Avoid release to the environment.

6.3.

Methods and material for containment and cleaning up

For containment

Collect spillage.

Methods for cleaning up

Take up liquid spill into absorbent material. Notify authorities if product enters sewers or public

waters.

Other information

Dispose of materials or solid residues at an authorized site.

6.4.

Reference to other sections

For further information refer to section 13.

SECTION 7: Handling and storage

7.1.

Precautions for safe handling

Precautions for safe handling

Ensure good ventilation of the work station. Obtain special instructions before use. Do not

handle until all safety precautions have been read and understood. Wear personal protective

equipment. Do not breathe dust/fume/gas/mist/vapours/spray.

Hygiene measures

Do not eat, drink or smoke when using this product. Always wash hands after handling the

product.

7.2.

Conditions for safe storage, including any incompatibilities

Storage conditions

Store locked up. Store in a well-ventilated place. Store at room temperature

Storage temperature

< 30 °C

7.3.

Specific end use(s)

No additional information available

SECTION 8: Exposure controls/personal protection

8.1.

Control parameters

No additional information available

8.2.

Exposure controls

Appropriate engineering controls

Ensure good ventilation of the work station.

Personal protective equipment

Gloves. Protective clothing.

Hand protection

Protective gloves

Eye protection

Safety glasses

Skin and body protection

Wear suitable protective clothing

Respiratory protection

In case of insufficient ventilation, wear suitable respiratory equipment

Environmental exposure controls

Avoid release to the environment.

SECTION 9: Physical and chemical properties

9.1.

Information on basic physical and chemical properties

Physical state

Liquid

Colour

White to off-white.

Odour

Faint aromatic.

Odour threshold

No data available

7,9 (21°C)

Relative evaporation rate (butyl acetate=1)

No data available

Melting point

No data available

Freezing point

No data available

Boiling point

No data available

Proman

Safety Data Sheet

according to Regulation (EU) 2015/830

2016/01/27

EN (English)

Flash point

> 100 °C

Auto-ignition temperature

> 800 °C

Decomposition temperature

No data available

Flammability (solid, gas)

Not flammable

Vapour pressure

No data available

Relative vapour density at 20 °C

No data available

Relative density

No data available

Density

1,219 g/cm³ (20°C)

Solubility

Dispersible.

Log Pow

No data available

Viscosity, kinematic

No data available

Viscosity, dynamic

111 - 315 mPa.s (100/s - 10/s)

Explosive properties

None.

Oxidising properties

None.

Explosive limits

No data available

9.2.

Other information

No additional information available

SECTION 10: Stability and reactivity

10.1.

Reactivity

The product is non-reactive under normal conditions of use, storage and transport.

10.2.

Chemical stability

Stable under normal conditions.

10.3.

Possibility of hazardous reactions

No dangerous reactions known under normal conditions of use.

10.4.

Conditions to avoid

None under recommended storage and handling conditions (see section 7).

10.5.

Incompatible materials

No additional information available

10.6.

Hazardous decomposition products

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

SECTION 11: Toxicological information

11.1.

Information on toxicological effects

Acute toxicity

Not classified

Proman

LD50 oral rat

> 2000 mg/kg

LD50 oral

> 2000 ml/kg

Metobromuron Technical (3060-89-7)

LD50 oral rat

1000 - 2150 mg/kg

LD50 dermal rat

> 3000 mg/kg

LC50 inhalation rat (Dust/Mist - mg/l/4h)

> 1,6 mg/l/4h

Skin corrosion/irritation

Not classified

pH: 7,9 (21°C)

Serious eye damage/irritation

Not classified

pH: 7,9 (21°C)

Respiratory or skin sensitisation

Not classified

Germ cell mutagenicity

Not classified

Carcinogenicity

Suspected of causing cancer.

Reproductive toxicity

Not classified

Specific target organ toxicity (single exposure)

Not classified

Specific target organ toxicity (repeated

exposure)

May cause damage to organs through prolonged or repeated exposure.

Aspiration hazard

Not classified

Proman

Safety Data Sheet

according to Regulation (EU) 2015/830

2016/01/27

EN (English)

SECTION 12: Ecological information

12.1.

Toxicity

Proman

LC50 fish 1

≥ 100 mg/l

EC50 Daphnia 1

≥ 100 mg/l

ErC50 (algae)

1,39 mg/l (72 h)

ErC50 (other aquatic plants)

0,73 mg/l (7 d)

12.2.

Persistence and degradability

No additional information available

12.3.

Bioaccumulative potential

No additional information available

12.4.

Mobility in soil

No additional information available

12.5.

Results of PBT and vPvB assessment

Component

Metobromuron Technical (3060-89-7)

This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII

This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII

12.6.

Other adverse effects

No additional information available

SECTION 13: Disposal considerations

13.1.

Waste treatment methods

Waste treatment methods

Dispose of contents/container in accordance with licensed collector’s sorting instructions.

SECTION 14: Transport information

In accordance with ADR / RID / IMDG / IATA / ADN

ADR

IMDG

IATA

ADN

RID

14.1.

UN number

3082

3082

3082

3082

3082

14.2.

UN proper shipping name

ENVIRONMENTALLY

HAZARDOUS

SUBSTANCE, LIQUID,

N.O.S.

ENVIRONMENTALLY

HAZARDOUS

SUBSTANCE, LIQUID,

N.O.S.

Environmentally

hazardous substance,

liquid, n.o.s.

ENVIRONMENTALLY

HAZARDOUS

SUBSTANCE, LIQUID,

N.O.S.

ENVIRONMENTALLY

HAZARDOUS

SUBSTANCE, LIQUID,

N.O.S.

Transport document description

UN 3082

ENVIRONMENTALLY

HAZARDOUS

SUBSTANCE, LIQUID,

N.O.S. (Metobromuron), 9,

III, (E)

UN 3082

ENVIRONMENTALLY

HAZARDOUS

SUBSTANCE, LIQUID,

N.O.S., 9, III, MARINE

POLLUTANT/ENVIRONM

ENTALLY HAZARDOUS

UN 3082 Environmentally

hazardous substance,

liquid, n.o.s., 9, III,

ENVIRONMENTALLY

HAZARDOUS

UN 3082

ENVIRONMENTALLY

HAZARDOUS

SUBSTANCE, LIQUID,

N.O.S., 9, III,

ENVIRONMENTALLY

HAZARDOUS

UN 3082

ENVIRONMENTALLY

HAZARDOUS

SUBSTANCE, LIQUID,

N.O.S., 9, III,

ENVIRONMENTALLY

HAZARDOUS

14.3.

Transport hazard class(es)

14.4.

Packing group

14.5.

Environmental hazards

Dangerous for the

environment : Yes

Dangerous for the

environment : Yes

Marine pollutant : Yes

Dangerous for the

environment : Yes

Dangerous for the

environment : Yes

Dangerous for the

environment : Yes

No supplementary information available

Proman

Safety Data Sheet

according to Regulation (EU) 2015/830

2016/01/27

EN (English)

14.6.

Special precautions for user

- Overland transport

Orange plates

- Transport by sea

No data available

- Air transport

No data available

- Inland waterway transport

Classification code (ADN)

Number of blue cones/lights (ADN)

- Rail transport

No data available

14.7.

Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

Not applicable

SECTION 15: Regulatory information

15.1.

Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1.

EU-Regulations

Contains no REACH substances with Annex XVII restrictions

Contains no substance on the REACH candidate list

Contains no REACH Annex XIV substances

15.1.2.

National regulations

No additional information available

15.2.

Chemical safety assessment

No chemical safety assessment has been carried out

SECTION 16: Other information

Full text of H- and EUH-statements:

Acute Tox. 4 (Oral)

Acute toxicity (oral), Category 4

Aquatic Acute 1

Hazardous to the aquatic environment — Acute Hazard, Category 1

Aquatic Chronic 1

Hazardous to the aquatic environment — Chronic Hazard, Category 1

Carc. 2

Carcinogenicity, Category 2

Eye Irrit. 2

Serious eye damage/eye irritation, Category 2

Skin Sens. 1

Sensitisation — Skin, Category 1

STOT RE 2

Specific target organ toxicity — Repeated exposure, Category 2

H302

Harmful if swallowed

H317

May cause an allergic skin reaction

H319

Causes serious eye irritation

H351

Suspected of causing cancer

H373

May cause damage to organs through prolonged or repeated exposure

H400

Very toxic to aquatic life

H410

Very toxic to aquatic life with long lasting effects

EUH208

Contains . May produce an allergic reaction

EUH401

To avoid risks to human health and the environment, comply with the instructions for use

SDS EU BCP (REACH Annex II) 2015-11-25

This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be

construed as guaranteeing any specific property of the product

  • Oplysningerne indlægssedlen for dette produkt er i øjeblikket ikke tilgængelig, kan du sende en anmodning til vores kundeservice, og vi vil give dig besked, så snart vi er i stand til at opnå det.

    Anmode informationsbrochure for offentligheden.



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