DIRECTIONS FOR USE
A-Z Product Guide
Your last 5 products
No products viewed
1. IDENTIFICATION OF THE
SUBSTANCE/PREPARATION AND OF THE
COMPANY OR UNDERTAKING
Identification of the substance or preparation
2. COMPOSITION/INFORMATION ON
For the full text of the R phrases mentioned in this Section, see Section 16.
3. HAZARDS IDENTIFICATION
Health Hazards: Irritating to skin and eyes.
Environmental hazard in case of accident (Spillage/Leakage): Toxic to aquatic organisms, may cause long-term
adverse effects in the aquatic environment.
4. FIRST AID MEASURES
Design Code A12303C
Syngenta Crop Protection UK Ltd
Whittlesford, CAMBRIDGE, CB2 4QT
Emergency Phone +44 (0)1484 538444 (24h)
20 - 40
solvent naphtha (petroleum), highly arom
40 - 60
51/53, 65, 66
1 - 5
General Advice: Have the product container, label or Material Safety Data Sheet with you when calling the Syngenta
01-10-2007 Side 1 af 4
5. FIRE FIGHTING MEASURES
6. ACCIDENTAL RELEASE MEASURES
Personal precautions: Refer to protective measures listed in Sections 7 and 8.
Environmental precautions: Prevent further leakage or spillage if safe to do so. Do not flush into surface water or
sanitary sewer system.
Methods for cleaning up: Contain and collect spillage with non-combustible absorbent material, (e.g., sand, earth,
diatomaceous earth, vermiculite) and place in container for disposal according to local/national regulations (see
Additional advice: If the product contaminates rivers and lakes or drains inform respective authorities.
7. HANDLING AND STORAGE
8. EXPOSURE CONTROLS / PERSONAL
Components with workplace control parameters
Containment and/or segregation is the most reliable technical protection measure if exposure cannot be eliminated.
The extent of these protection measures depends on the actual risks in use. If airborne mists or vapours are
generated, use local exhaust ventilation controls. Assess exposure and use any additional measures to keep airborne
levels below any relevant exposure limit. Where necessary, seek additional occupational hygiene advice.
PERSONAL PROTECTIVE EQUIPMENT
Protective measures: The use of technical measures should always have priority over the use of personal protective
equipment. When selecting personal protective equipment, seek appropriate professional advice. Personal
protectrive equipment should be certified to appropriate standards.
Respiratory protection: No personal respiratory protective equipment normally required. A particulate filter
respirator may be necessary until effective technical measures are installed.
Hand protection: Chemical resistant gloves should be used. Gloves should be certified to an appropriate standard.
Gloves should have a minimum breakthrough time that is appropriate to the duration of exposure. The breakthrough
time of gloves varies according to the thickness, material and manufacturer. Gloves should be changed when
breakthrough is suspected. Suitable material: nitrile rubber.
Eye protection: If eye contact is possible, use tight-fitting chemical safey goggles.
Skin and body protection: Assess the exposure and select chemical resistant clothing based on the potential for
contact and the permeation/penetration characteristics of the clothing material. Wash with soap and water after
removing protective clothing. Decontaminate clothing before re-use, or use disposable equipment (suits, aprons,
sleeves, boots, etc).
Wear as appropriate: Impervious protective suit.
emergency number, a poison centre or physician, or going for treatment.
Inhalation: Move to fresh air. If breathing is irregular or stopped, administer artificial respiration. Keep patient warm and at rest.
Call a physician or Poison Control Centre immediately.
Skin Contact: Take off all contaminated clothing immediately. Wash off immediately with plenty of water. If skin irritation
persists, call a physician. Wash contaminated clothing before re-use.
Eye Contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses.
Immediate medical attention is required.
Ingestion: If swallowed, seek medical advice immediately and show this container or label. Do not induce vomiting: contains
petroleum distillates and/or aromatic solvents.
Medical advice: There is no specific antidote available. Treat symptomatically. Do not induce vomiting: contains petroleum
distillates and/or aromatic solvents.
Suitable Extinguishing Media
- small fires: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Extinguishing media - large fires: Use alcohol-resistant foam or water spray.
Extinguishing media which must not be used for safety reasons: Do not use a solid water stream as it may scatter and
Special Hazards during fire fighting: As the product contains combustible organic components, fire will produce dense black
smoke containing hazardous products of combustion (see Section 10). Exposure to decomposition products may be a hazard
Special protective equipment for fire fighters: In the event of fire, wear self-contained breathing apparatus.
Further information: Do not allow run-off from fire fighting to enter drains or water courses. Cool closed containers exposed to
fire with water spray.
Advice on safe handling: No special technical protective measures required. No special handling advice required. Avoid
contact with skin and eyes. When using, do not eat, drink or smoke. For personal protection see Section 8.
Requirements for storage areas and containers: No special storage conditions required. Keep containers tightly closed in a
dry, cool and well-ventilated place. Keep out of the reach of children. Keep away from food, drink and animal feeding stuffs.
Other data: Physically of chemically stable for at least 2 years when stored in the original unopened sales container at ambient
8 h TWA
solvent naphtha (petroleum), highly arom.
15 ppm, 100 mg/m
8 h TWA
01-10-2007 Side 2 af 4
9. PHYSICAL AND CHEMICAL PROPERTIES
10. STABILITY AND REACTIVITY
11. TOXICOLOGICAL INFORMATION
12. ECOLOGICAL INFORMATION
ELIMINATION INFORMATION (PERSISTENCE AND DEGRADABILITY)
Bioaccumulation: Cloquintocet-mexyl does not bioaccumulate. Pinoxaden has low potential for bioaccumulation.
Stability in water: Cloquintocet-mexyl is not persistent in water. Pinoxaden is not persistent in water.
Stability in soil: Cloquintocet-mexyl is not persistent in soil. Pinoxaden is not persistent in soil.
Mobility: Cloquintocet-mexyl is immobile in soil. Pinoxaden has medium mobility in soil.
13. DISPOSAL CONSIDERATIONS
Product: Do not contaminate ponds, waterways or ditches with chemical or used containers. Do not dispose of waste
into sewer. Where possible recycling is preferred to disposal or incineration. If recycling is not practicable, dispose of
in compliance with local regulations.
Contaminated packaging: Empty remaining contents. Triple rinse containers. Empty containers should be taken for
local recycling or waste disposal. Do not re-use empty containers.
14. TRANSPORT INFORMATION
Yellow to orange
79°C (751 mmHg)
Explosive Properties: Not explosive
1.03 g/ml (20°C)
36.6 mN/m (undiluted; 25°C)
8.34 mPa.s (20°C)
4.41 mPa.s (40°C)
Combustion or thermal decomposition will evolve toxic and irritant vapours.
None known. Hazardous polymerization does not occur. Stable under normal
Acute Oral Toxicity, female Rat LD
Acute Dermal Toxicity, male and female
Acute Inhalation Toxicity, rat; 4 h LC
Moderately Irritating (rabbit)
Moderately Irritating (rabbit)
Not sensitising (guinea pig)
Long term toxicity:
Did not show carcinogenic, teratogenic or mutagenic effects in animal
Acute Toxicity to Fish LC
5.6 mg/l (Oncorhynchus mykiss, (Rainbow trout), 96 h.
Growth Inhibition, Algae EbC
4.6 mg/l (Pseudokirchneriella subcapitata (green algae), 72 h.
Growth Inhibition, Algae ErC
9.7 mg/l (Pseudokirchneriella subcapitata (green algae), 72 h.
Toxicity to Aquatic Invertebrates EC
3.2 mg/l (Daphnia magna (water flea), 48 h.
Proper Shipping Name
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.,
01-10-2007 Side 3 af 4
15. REGULATORY INFORMATION
16. OTHER INFORMATION
Always read the label. Use pesticides safely.
Based upon SDS issue date 02/02/2006, version 3. DPD compliant. Update: Reformatting & changes
throughout Sections 4, 5, 6, 7, 8 and 11. Addition of poly(oxy-1,2-ethanediyl), alphaphenyl-omegahydroxy-,
styrenated in Section 2. Addition of R37 in Section 16. Addition of Elimination information in Section 12.
Product Registration Number: MAPP 12521.
Text of R phrases mentioned in Section 2:
The information contained herein is based on the present state of our knowledge as is intended to describe
our products from the point of view of safety requirements. It should not therefore be construed as
guaranteeing specific properties.
DANGEROUS FOR THE ENVIRONMENT
Risk phrases (R)
Irritating to eyes and skin.
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
Keep out of the reach of children.
Keep away from food, drink and animal feeding stuffs.
When using do not eat, drink or smoke.
This material and its container must be disposed of in a safe way.
36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
Use appropriate containment to avoid environmental contamination.
To avoid risks to man and the environment, comply with the instructions for use.
Harmful by inhalation.
R36/37 Irritating to eyes and respiratory system.
May cause sensitisation by skin contact.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Harmful: may cause lung damage if swallowed.
Repeated exposure may cause skin dryness or cracking.
01-10-2007 Side 4 af 4