Adexar

Primær information

  • Handelsnavn:
  • Adexar Emulsionskoncentrat
  • Lægemiddelform:
  • Emulsionskoncentrat
  • Sammensætning:
  • 62,5 g/l epoxiconazol; 62,5 g/l fluxapyroxad
  • Brugt til:
  • Planter
  • Medicin typen:
  • agrokemiske

Dokumenter

  • for den brede offentlighed:
  • Oplysningerne indlægssedlen for dette produkt er i øjeblikket ikke tilgængelig, kan du sende en anmodning til vores kundeservice, og vi vil give dig besked, så snart vi er i stand til at opnå det.


    Anmode informationsbrochure for offentligheden.

Lokation

  • Fås i:
  • Adexar Emulsionskoncentrat
    Danmark
  • Sprog:
  • dansk

Andre oplysninger

Status

  • Kilde:
  • SEGES Landbrug & Fødevarer
  • Autorisation status:
  • Afprøvet i Landsforsøg
  • Sidste ændring:
  • 08-02-2018

Produktresumé

Safety data sheet

Page: 1/20

BASF Safety data sheet according to Regulation (EC) No. 1907/2006

Date / Revised: 21.11.2013

Version: 2.0

Product: ADEXAR

(ID no. 30519170/SDS_CPA_GB/EN)

Date of print 23.11.2013

SECTION 1: Identification of the substance/mixture and of the

company/undertaking

1.1. Product identifier

ADEXAR

1.2. Relevant identified uses of the substance or mixture and uses advised against

Relevant identified uses: crop protection product, fungicide

1.3. Details of the supplier of the safety data sheet

Company:

BASF SE

67056 Ludwigshafen

GERMANY

Contact address:

BASF plc

PO Box 4, Earl Road, Cheadle Hulme,

Cheadle, Cheshire

SK8 6QG, UNITED KINGDOM

Telephone: +44 161 485-6222

E-mail address: product-safety-north@basf.com

1.4. Emergency telephone number

International emergency number:

Telephone: +49 180 2273-112

SECTION 2: Hazards Identification

2.1. Classification of the substance or mixture

According to Regulation (EC) No 1272/2008 [CLP]

Acute Tox. 4 (oral)

Eye Dam./Irrit. 2

Skin Sens. 1

Carc. 2

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BASF Safety data sheet according to Regulation (EC) No. 1907/2006

Date / Revised: 21.11.2013

Version: 2.0

Product: ADEXAR

(ID no. 30519170/SDS_CPA_GB/EN)

Date of print 23.11.2013

Repr. 2 (fertility)

Repr. 2 (unborn child)

Aquatic Acute 1

Aquatic Chronic 1

According to Directive 67/548/EEC or 1999/45/EC

Carc. Cat. 3

Repr. Cat. 3

Possible Hazards:

Harmful if swallowed.

Irritating to eyes.

Limited evidence of a carcinogenic effect.

May cause sensitization by skin contact.

Possible risk of impaired fertility.

Possible risk of harm to the unborn child.

Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

For the classifications not written out in full in this section the full text can be found in section 16.

2.2. Label elements

Globally Harmonized System (GHS) in accordance with UK regulations.

Pictogram:

Signal Word:

Warning

Hazard Statement:

H319

Causes serious eye irritation.

H302

Harmful if swallowed.

H317

May cause an allergic skin reaction.

H351

Suspected of causing cancer.

H361fd

Suspected of damaging fertility. Suspected of damaging the unborn

child.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

EUH401

To avoid risks to human health and the environment, comply with the

instructions for use.

Precautionary Statements (Prevention):

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BASF Safety data sheet according to Regulation (EC) No. 1907/2006

Date / Revised: 21.11.2013

Version: 2.0

Product: ADEXAR

(ID no. 30519170/SDS_CPA_GB/EN)

Date of print 23.11.2013

P201

Obtain special instructions before use.

P261d

Avoid breathing vapours.

P264

Wash with plenty of water and soap thoroughly after handling.

P270

Do not eat, drink or smoke when using this product.

P272

Contaminated work clothing should not be allowed out of the workplace.

P280f

Wear protective gloves and eye/face protection.

Precautionary Statements (Response):

P301 + P312

IF SWALLOWED: Call a POISON CENTER or doctor/physician if you

feel unwell.

P302 + P352

IF ON SKIN: Wash with plenty of soap and water.

P305 + P351 + P338

IF IN EYES: Rinse cautiously with water for several minutes. Remove

contact lenses, if present and easy to do. Continue rinsing.

P308 + P313

IF exposed or concerned: Get medical advice/attention.

P330

Rinse mouth.

P333 + P313

If skin irritation or rash occurs: Get medical advice/attention.

P363

Wash contaminated clothing before reuse.

P391

Collect spillage.

Precautionary Statements (Storage):

P405

Store locked up.

Precautionary Statements (Disposal):

P501.1

Dispose of contents/container in accordance with local regulations.

According to Regulation (EC) No 1272/2008 [CLP]

Hazard determining component(s) for labelling: EPOXICONAZOLE, FLUXAPYROXAD,

BENZYLALCOHOL, (2S)-2-HYDROXY-PROPANOIC ACID 2-ETHYLHEXYL ESTER

According to Directive 67/548/EEC or 1999/45/EC

Classification/labelling in accordance with UK regulations.

Hazard symbol(s)

Harmful.

Dangerous for the environment.

R-phrase(s)

Harmful if swallowed.

Irritating to eyes.

Limited evidence of a carcinogenic effect.

May cause sensitization by skin contact.

Possible risk of impaired fertility.

Possible risk of harm to the unborn child.

R50/53

Very toxic to aquatic organisms, may cause long-term adverse effects

in the aquatic environment.

S-phrase(s)

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BASF Safety data sheet according to Regulation (EC) No. 1907/2006

Date / Revised: 21.11.2013

Version: 2.0

Product: ADEXAR

(ID no. 30519170/SDS_CPA_GB/EN)

Date of print 23.11.2013

Keep out of the reach of children.

Keep away from food, drink and animal feeding stuffs.

S20/21

When using do not eat, drink or smoke.

S23.1

Do not breathe spray.

S24/25

Avoid contact with skin and eyes.

In case of contact with eyes, rinse immediately with plenty of water and

seek medical advice.

Do not empty into drains.

This material and its container must be disposed of in a safe way.

S36/37/39

Wear suitable protective clothing, gloves and eye/face protection.

If swallowed, seek medical advice immediately and show this container

or label.

Use appropriate container to avoid environmental contamination.

Hazard determining component(s) for labelling: EPOXICONAZOLE, FLUXAPYROXAD,

BENZYLALCOHOL, (2S)-2-HYDROXY-PROPANOIC ACID 2-ETHYLHEXYL ESTER

2.3. Other hazards

According to Regulation (EC) No 1272/2008 [CLP]

See section 12 - Results of PBT and vPvB assessment.

If applicable information is provided in this section on other hazards which do not result in

classification but which may contribute to the overall hazards of the substance or mixture.

SECTION 3: Composition/Information on Ingredients

3.1. Substances

Not applicable

3.2. Mixtures

Chemical nature

crop protection product, fungicide, Emulsifiable concentrate (EC)

Hazardous ingredients (GHS)

according to Regulation (EC) No. 1272/2008

Page: 5/20

BASF Safety data sheet according to Regulation (EC) No. 1907/2006

Date / Revised: 21.11.2013

Version: 2.0

Product: ADEXAR

(ID no. 30519170/SDS_CPA_GB/EN)

Date of print 23.11.2013

Epoxiconazole; (2RS,3SR)-3-(2-chlorophenyl)-2-(4-fluorophenyl)-[(1H-1,2,4-triazol-1-

yl)methyl]oxirane

Content (W/W): 6 %

CAS Number: 133855-98-8

EC-Number: 406-850-2

REACH registration number: 01-

0000015634-70

INDEX-Number: 613-175-00-9

Carc. 2

Repr. 2 (fertility)

Repr. 2 (unborn child)

Aquatic Chronic 2

H411, H351, H361fd

1H-Pyrazole-4-carboxamide, 3-(difluoromethyl)-1-methyl-N-(3',4',5'-trifluoro[1,1'-biphenyl]-2-yl)-

Content (W/W): 6 %

CAS Number: 907204-31-3

Carc. 2

Aquatic Acute 1

Aquatic Chronic 1

H351, H400, H410

2-Ethylhexyl-S-lactate

Content (W/W): < 50 %

CAS Number: 186817-80-1

EC-Number: 228-503-2

Skin Corr./Irrit. 2

Eye Dam./Irrit. 2

Skin Sens. 1

H319, H315, H317

benzyl alcohol

Content (W/W): < 25 %

CAS Number: 100-51-6

EC-Number: 202-859-9

REACH registration number: 01-

2119492630-38

INDEX-Number: 603-057-00-5

Acute Tox. 4 (oral)

Acute Tox. 4 (Inhalation - mist)

H332, H302

Solvent naphtha (petroleum), heavy arom.; Kerosine - unspecified

Content (W/W): < 9 %

CAS Number: 64742-94-5

EC-Number: 265-198-5

REACH registration number: 01-

2119451097-39

INDEX-Number: 649-424-00-3

Asp. Tox. 1

STOT SE 3 (drowsiness and dizziness)

Aquatic Chronic 2

H411, H304, H336

Polyarylphenol ethoxylate

Content (W/W): < 8 %

CAS Number: 99734-09-5

Aquatic Chronic 3

Aquatic Acute 3

H402, H412

calcium bis(tetrapropylenebenzenesulphonate)

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BASF Safety data sheet according to Regulation (EC) No. 1907/2006

Date / Revised: 21.11.2013

Version: 2.0

Product: ADEXAR

(ID no. 30519170/SDS_CPA_GB/EN)

Date of print 23.11.2013

Content (W/W): < 5 %

CAS Number: 11117-11-6

Acute Tox. 4 (dermal)

Skin Corr./Irrit. 2

Eye Dam./Irrit. 1

Aquatic Chronic 3

H318, H315, H312, H412

Fatty alcohol polyglycolether

Content (W/W): < 5 %

Acute Tox. 4 (oral)

Eye Dam./Irrit. 1

Aquatic Chronic 2

H318, H302, H411

naphthalene

Content (W/W): < 0.05 %

CAS Number: 91-20-3

EC-Number: 202-049-5

INDEX-Number: 601-052-00-2

Acute Tox. 4 (oral)

Carc. 2

Aquatic Acute 1

Aquatic Chronic 1

M-factor acute: 1

M-factor chronic: 1

H302, H351, H400, H410

Dimethyl sulfoxide

Content (W/W): < 10 %

CAS Number: 67-68-5

EC-Number: 200-664-3

REACH registration number: 01-

2119431362-50

Hazardous ingredients

according to Directive 1999/45/EC

Epoxiconazole; (2RS,3SR)-3-(2-chlorophenyl)-2-(4-fluorophenyl)-[(1H-1,2,4-triazol-1-

yl)methyl]oxirane

Content (W/W): 6 %

CAS Number: 133855-98-8

EC-Number: 406-850-2

REACH registration number: 01-0000015634-70

INDEX-Number: 613-175-00-9

Hazard symbol(s): Xn, N

R-phrase(s): 40, 62, 63, 51/53

Carc. Cat. 3

Repr. Cat. 3

1H-Pyrazole-4-carboxamide, 3-(difluoromethyl)-1-methyl-N-(3',4',5'-trifluoro[1,1'-biphenyl]-2-yl)-

Content (W/W): 6 %

CAS Number: 907204-31-3

Hazard symbol(s): Xn, N

R-phrase(s): 40, 50/53

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BASF Safety data sheet according to Regulation (EC) No. 1907/2006

Date / Revised: 21.11.2013

Version: 2.0

Product: ADEXAR

(ID no. 30519170/SDS_CPA_GB/EN)

Date of print 23.11.2013

Carc. Cat. 3

2-Ethylhexyl-S-lactate

Content (W/W): < 50 %

CAS Number: 186817-80-1

EC-Number: 228-503-2

Hazard symbol(s): Xi

R-phrase(s): 36/38, 43

benzyl alcohol

Content (W/W): < 25 %

CAS Number: 100-51-6

EC-Number: 202-859-9

REACH registration number: 01-2119492630-38

INDEX-Number: 603-057-00-5

Hazard symbol(s): Xn

R-phrase(s): 20/22

Solvent naphtha (petroleum), heavy arom.; Kerosine - unspecified

Content (W/W): < 9 %

CAS Number: 64742-94-5

EC-Number: 265-198-5

REACH registration number: 01-2119451097-39

INDEX-Number: 649-424-00-3

Hazard symbol(s): Xn, N

R-phrase(s): 65, 66, 67, 51/53

Polyarylphenol ethoxylate

Content (W/W): < 8 %

CAS Number: 99734-09-5

R-phrase(s): 52/53

calcium bis(tetrapropylenebenzenesulphonate)

Content (W/W): < 5 %

CAS Number: 11117-11-6

Hazard symbol(s): Xn

R-phrase(s): 21, 38, 41, 52/53

Fatty alcohol polyglycolether

Content (W/W): < 5 %

Hazard symbol(s): Xn, N

R-phrase(s): 22, 41, 51/53

naphthalene

Content (W/W): < 0.05 %

CAS Number: 91-20-3

EC-Number: 202-049-5

INDEX-Number: 601-052-00-2

Hazard symbol(s): Xn, N

R-phrase(s): 22, 40, 50/53

Carc. Cat. 3

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BASF Safety data sheet according to Regulation (EC) No. 1907/2006

Date / Revised: 21.11.2013

Version: 2.0

Product: ADEXAR

(ID no. 30519170/SDS_CPA_GB/EN)

Date of print 23.11.2013

Dimethyl sulfoxide

Content (W/W): < 10 %

CAS Number: 67-68-5

EC-Number: 200-664-3

REACH registration number: 01-2119431362-50

For the classifications not written out in full in this section, including the indication of danger, the

hazard symbols, the R phrases, and the hazard statements, the full text is listed in section 16.

SECTION 4: First-Aid Measures

4.1. Description of first aid measures

Show container, label and/or safety data sheet to physician.

If inhaled:

Keep patient calm, remove to fresh air, seek medical attention.

On skin contact:

Wash thoroughly with soap and water.

On contact with eyes:

Wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an

eye specialist.

On ingestion:

Immediately rinse mouth and then drink 200-300 ml of water, seek medical attention.

4.2. Most important symptoms and effects, both acute and delayed

Symptoms: The most important known symptoms and effects are described in the labelling (see

section 2) and/or in section 11., Further important symptoms and effects are so far not known.

4.3. Indication of any immediate medical attention and special treatment needed

Treatment: Treat according to symptoms (decontamination, vital functions), no known specific

antidote.

SECTION 5: Fire-Fighting Measures

5.1. Extinguishing media

Suitable extinguishing media:

water spray, carbon dioxide, foam, dry powder

5.2. Special hazards arising from the substance or mixture

carbon monoxide, Carbon dioxide, hydrogen chloride, hydrogen fluoride, nitrogen oxides,

organochloric compounds

The substances/groups of substances mentioned can be released in case of fire.

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BASF Safety data sheet according to Regulation (EC) No. 1907/2006

Date / Revised: 21.11.2013

Version: 2.0

Product: ADEXAR

(ID no. 30519170/SDS_CPA_GB/EN)

Date of print 23.11.2013

5.3. Advice for fire-fighters

Special protective equipment:

Wear self-contained breathing apparatus and chemical-protective clothing.

Further information:

In case of fire and/or explosion do not breathe fumes. Keep containers cool by spraying with water if

exposed to fire. Collect contaminated extinguishing water separately, do not allow to reach sewage

or effluent systems. Dispose of fire debris and contaminated extinguishing water in accordance with

official regulations.

SECTION 6: Accidental Release Measures

6.1. Personal precautions, protective equipment and emergency procedures

Do not breathe vapour/spray. Use personal protective clothing. Avoid contact with the skin, eyes and

clothing.

6.2. Environmental precautions

Do not discharge into the subsoil/soil. Do not discharge into drains/surface waters/groundwater.

Do not allow contamination of public drains or surface or ground waters. Inform local water plc if

spillage enters drains and the Environment Agency (England & Wales), the Scottish Environmental

Protection Agency (Scotland), or the Environment and Heritage Service (Northern Ireland) if it enters

surface or ground waters. Keep people and animals away.

6.3. Methods and material for containment and cleaning up

For small amounts: Pick up with suitable absorbent material (e.g. sand, sawdust, general-purpose

binder, kieselguhr).

For large amounts: Dike spillage. Pump off product.

Dispose of absorbed material in accordance with regulations. Collect waste in suitable containers,

which can be labeled and sealed. Clean contaminated floors and objects thoroughly with water and

detergents, observing environmental regulations.

6.4. Reference to other sections

Information regarding exposure controls/personal protection and disposal considerations can be

found in section 8 and 13.

SECTION 7: Handling and Storage

7.1. Precautions for safe handling

No special measures necessary if stored and handled correctly. Ensure thorough ventilation of

stores and work areas. When using do not eat, drink or smoke. Hands and/or face should be washed

before breaks and at the end of the shift.

Protection against fire and explosion:

Vapours may form ignitable mixture with air. Prevent electrostatic charge - sources of ignition should

be kept well clear - fire extinguishers should be kept handy.

7.2. Conditions for safe storage, including any incompatibilities

Page: 10/20

BASF Safety data sheet according to Regulation (EC) No. 1907/2006

Date / Revised: 21.11.2013

Version: 2.0

Product: ADEXAR

(ID no. 30519170/SDS_CPA_GB/EN)

Date of print 23.11.2013

Segregate from foods and animal feeds.

Further information on storage conditions: Keep away from heat. Protect from direct sunlight.

Protect from temperatures below: -10 °C

Changes in the properties of the product may occur if substance/product is stored below indicated

temperature for extended periods of time.

Protect from temperatures above: 40 °C

Changes in the properties of the product may occur if substance/product is stored above indicated

temperature for extended periods of time.

7.3. Specific end use(s)

For the relevant identified use(s) listed in Section 1 the advice mentioned in this section 7 is to be

observed.

SECTION 8: Exposure Controls/Personal Protection

8.1. Control parameters

Components with occupational exposure limits

Refer to the current edition of HSE Guidance Note EH40 Occupational Exposure Limits (United

Kingdom). For normal use and handling refer to the product label/leaflet. In all other cases the

following apply.

8.2. Exposure controls

Personal protective equipment

Respiratory protection:

Suitable respiratory protection for higher concentrations or long-term effect: Combination filter for

gases/vapours of organic, inorganic, acid inorganic and alkaline compounds (e.g. EN 14387 Type

ABEK).

Hand protection:

Suitable chemical resistant safety gloves (EN 374) also with prolonged, direct contact

(Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to

EN 374): E.g. nitrile rubber (0.4 mm), chloroprene rubber (0.5 mm), butyl rubber (0.7 mm) and other

Eye protection:

Safety glasses with side-shields (frame goggles) (e.g. EN 166)

Body protection:

Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting

boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case

of dust).

General safety and hygiene measures

The statements on personal protective equipment in the instructions for use apply when handling

crop-protection agents in final-consumer packing. Wearing of closed work clothing is recommended.

Store work clothing separately. Keep away from food, drink and animal feeding stuffs.

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BASF Safety data sheet according to Regulation (EC) No. 1907/2006

Date / Revised: 21.11.2013

Version: 2.0

Product: ADEXAR

(ID no. 30519170/SDS_CPA_GB/EN)

Date of print 23.11.2013

SECTION 9: Physical and Chemical Properties

9.1. Information on basic physical and chemical properties

Form:

liquid

Colour:

red-brown

Odour:

moderate odour, aromatic

Odour threshold:

Not determined due to potential

health hazard by inhalation.

pH value:

approx. 4 - 6

(water, 1 %(m), approx. 20 °C)

(pH Meter)

crystallization temperature:

< -20 °C

Boiling point:

approx. 205 °C

(1,013 hPa)

Information applies to the solvent.

Flash point:

approx. 102.5 °C

(Directive 92/69/EEC, A.9)

Evaporation rate:

not applicable

Flammability:

not highly flammable

Lower explosion limit:

As a result of our experience with this

product and our knowledge of its

composition we do not expect any

hazard as long as the product is used

appropriately and in accordance with

the intended use.

Upper explosion limit:

As a result of our experience with this

product and our knowledge of its

composition we do not expect any

hazard as long as the product is used

appropriately and in accordance with

the intended use.

Ignition temperature:

approx. 282 °C

(Directive 92/69/EEC, A.15)

Vapour pressure:

approx. 0.13 hPa

(25 °C)

Information applies to the solvent.

Relative density:

approx. 1.04

(20 °C)

(calculated)

Relative vapour density (air):

not determined

Solubility in water:

emulsifiable

Partitioning coefficient n-octanol/water (log Kow):

not applicable

Thermal decomposition:

170 °C, 10 kJ/kg (DSC (OECD 113))

240 °C, 70 kJ/kg (DSC (OECD 113))

405 °C, > 100 kJ/kg (DSC (OECD 113))

Viscosity, dynamic:

approx. 9.1 mPa.s

(40 °C, 100 1/s)

(OECD 114)

Page: 12/20

BASF Safety data sheet according to Regulation (EC) No. 1907/2006

Date / Revised: 21.11.2013

Version: 2.0

Product: ADEXAR

(ID no. 30519170/SDS_CPA_GB/EN)

Date of print 23.11.2013

Explosion hazard:

not explosive

(Directive 92/69/EEC, A.14)

Fire promoting properties:

not fire-propagating

(Directive 2004/73/EC, A.21)

9.2. Other information

Other Information:

If necessary, information on other physical and chemical parameters is indicated in this section.

SECTION 10: Stability and Reactivity

10.1. Reactivity

No hazardous reactions if stored and handled as prescribed/indicated.

10.2. Chemical stability

The product is stable if stored and handled as prescribed/indicated.

10.3. Possibility of hazardous reactions

No hazardous reactions if stored and handled as prescribed/indicated.

10.4. Conditions to avoid

See MSDS section 7 - Handling and storage.

10.5. Incompatible materials

Substances to avoid:

strong acids, strong bases, strong oxidizing agents

10.6. Hazardous decomposition products

Hazardous decomposition products:

No hazardous decomposition products if stored and handled as prescribed/indicated.

SECTION 11: Toxicological Information

11.1. Information on toxicological effects

Acute toxicity

Assessment of acute toxicity:

Of moderate toxicity after single ingestion. Virtually nontoxic after a single skin contact. Virtually

nontoxic by inhalation.

Experimental/calculated data:

LD50 rat (oral): > 500 - < 2,000 mg/kg (OECD Guideline 423)

LC50 rat (by inhalation): 6.18 mg/l 4 h (OECD Guideline 403)

An aerosol was tested.

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BASF Safety data sheet according to Regulation (EC) No. 1907/2006

Date / Revised: 21.11.2013

Version: 2.0

Product: ADEXAR

(ID no. 30519170/SDS_CPA_GB/EN)

Date of print 23.11.2013

LD50 rat (dermal): > 5,000 mg/kg (OECD Guideline 402)

Irritation

Assessment of irritating effects:

Not irritating to the skin. Eye contact causes irritation.

Experimental/calculated data:

Skin corrosion/irritation rabbit: non-irritant (OECD Guideline 404)

Serious eye damage/irritation rabbit: Irritant. (OECD Guideline 405)

Respiratory/Skin sensitization

Assessment of sensitization:

Sensitization after skin contact possible.

Experimental/calculated data:

Mouse Local Lymph Node Assay (LLNA) mouse: Caused skin sensitization in animal studies.

(OECD Guideline 429)

Germ cell mutagenicity

Assessment of mutagenicity:

The product has not been tested. The statement has been derived from the properties of the

individual components. Mutagenicity tests revealed no genotoxic potential.

Carcinogenicity

Assessment of carcinogenicity:

The product has not been tested. The statement has been derived from the properties of the

individual components.

Information on: Epoxiconazole; (2RS,3SR)-3-(2-chlorophenyl)-2-(4-fluorophenyl)-[(1H-1,2,4-triazol-1-

yl)methyl]oxirane

Assessment of carcinogenicity:

Indication of possible carcinogenic effect in animal tests.

Information on: 1H-Pyrazole-4-carboxamide, 3-(difluoromethyl)-1-methyl-N-(3',4',5'-trifluoro[1,1'-

biphenyl]-2-yl)-

Assessment of carcinogenicity:

Indication of possible carcinogenic effect in animal tests.

----------------------------------

Reproductive toxicity

Assessment of reproduction toxicity:

The product has not been tested. The statement has been derived from the properties of the

individual components.

Page: 14/20

BASF Safety data sheet according to Regulation (EC) No. 1907/2006

Date / Revised: 21.11.2013

Version: 2.0

Product: ADEXAR

(ID no. 30519170/SDS_CPA_GB/EN)

Date of print 23.11.2013

Information on: Epoxiconazole; (2RS,3SR)-3-(2-chlorophenyl)-2-(4-fluorophenyl)-[(1H-1,2,4-triazol-1-

yl)methyl]oxirane

Assessment of reproduction toxicity:

The results of animal studies suggest a fertility impairing effect.

----------------------------------

Developmental toxicity

Assessment of teratogenicity:

The product has not been tested. The statement has been derived from the properties of the

individual components.

Information on: Epoxiconazole; (2RS,3SR)-3-(2-chlorophenyl)-2-(4-fluorophenyl)-[(1H-1,2,4-triazol-1-

yl)methyl]oxirane

Assessment of teratogenicity:

Indications of possible developmental toxicity/teratogenicity were seen in animal studies.

----------------------------------

Repeated dose toxicity and Specific target organ toxicity (repeated exposure)

Assessment of repeated dose toxicity:

The product has not been tested. The statement has been derived from the properties of the

individual components.

Information on: Epoxiconazole; (2RS,3SR)-3-(2-chlorophenyl)-2-(4-fluorophenyl)-[(1H-1,2,4-triazol-1-

yl)methyl]oxirane

Assessment of repeated dose toxicity:

Repeated exposure to large quantities may affect certain organs.

----------------------------------

Other relevant toxicity information

Misuse can be harmful to health.

SECTION 12: Ecological Information

12.1. Toxicity

Assessment of aquatic toxicity:

Very toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment.

Toxicity to fish:

LC50 (96 h) 10.6 mg/l, Oncorhynchus mykiss (OECD Guideline 203)

Aquatic invertebrates:

EC50 (48 h) 28.9 mg/l, Daphnia magna (OECD Guideline 202, part 1, static)

Aquatic plants:

EC50 (72 h) 5.38 mg/l (growth rate), Pseudokirchneriella subcapitata (OECD Guideline 201)

EC50 (7 d) 0.265 mg/l (growth rate), Lemna gibba (OECD guideline 221, static)

Page: 15/20

BASF Safety data sheet according to Regulation (EC) No. 1907/2006

Date / Revised: 21.11.2013

Version: 2.0

Product: ADEXAR

(ID no. 30519170/SDS_CPA_GB/EN)

Date of print 23.11.2013

12.2. Persistence and degradability

Assessment biodegradation and elimination (H2O):

The product has not been tested. The statement has been derived from the properties of the

individual components.

Information on: Epoxiconazole; (2RS,3SR)-3-(2-chlorophenyl)-2-(4-fluorophenyl)-[(1H-1,2,4-triazol-1-

yl)methyl]oxirane

Assessment biodegradation and elimination (H2O):

Not readily biodegradable (by OECD criteria).

Information on: 1H-Pyrazole-4-carboxamide, 3-(difluoromethyl)-1-methyl-N-(3',4',5'-trifluoro[1,1'-

biphenyl]-2-yl)-

Assessment biodegradation and elimination (H2O):

Not readily biodegradable (by OECD criteria).

----------------------------------

12.3. Bioaccumulative potential

Assessment bioaccumulation potential:

The product has not been tested. The statement has been derived from the properties of the

individual components.

Information on: Epoxiconazole; (2RS,3SR)-3-(2-chlorophenyl)-2-(4-fluorophenyl)-[(1H-1,2,4-triazol-1-

yl)methyl]oxirane

Bioaccumulation potential:

Bioconcentration factor: 59 - 70, Oncorhynchus mykiss (OECD-Guideline 305)

Does not accumulate in organisms.

Information on: 1H-Pyrazole-4-carboxamide, 3-(difluoromethyl)-1-methyl-N-(3',4',5'-trifluoro[1,1'-

biphenyl]-2-yl)-

Bioaccumulation potential:

Bioconcentration factor: 36 - 37 (28 d), Lepomis macrochirus (OECD-Guideline 305)

Does not accumulate in organisms.

----------------------------------

12.4. Mobility in soil

Assessment transport between environmental compartments:

The product has not been tested. The statement has been derived from the properties of the

individual components.

Information on: Epoxiconazole; (2RS,3SR)-3-(2-chlorophenyl)-2-(4-fluorophenyl)-[(1H-1,2,4-triazol-1-

yl)methyl]oxirane

Assessment transport between environmental compartments:

Following exposure to soil, adsorption to solid soil particles is probable, therefore contamination of

groundwater is not expected.

Information on: 1H-Pyrazole-4-carboxamide, 3-(difluoromethyl)-1-methyl-N-(3',4',5'-trifluoro[1,1'-

biphenyl]-2-yl)-

Assessment transport between environmental compartments:

Page: 16/20

BASF Safety data sheet according to Regulation (EC) No. 1907/2006

Date / Revised: 21.11.2013

Version: 2.0

Product: ADEXAR

(ID no. 30519170/SDS_CPA_GB/EN)

Date of print 23.11.2013

Following exposure to soil, adsorption to solid soil particles is probable, therefore contamination of

groundwater is not expected.

----------------------------------

12.5. Results of PBT and vPvB assessment

The product does not contain a substance fulfilling the PBT (persistent/bioaccumulative/toxic) criteria

or the vPvB (very persistent/very bioaccumulative) criteria.

12.6. Other adverse effects

The product does not contain substances that are listed in Regulation (EC) 1005/2009 on

substances that deplete the ozone layer.

12.7. Additional information

Other ecotoxicological advice:

Do not discharge product into the environment without control.

SECTION 13: Disposal Considerations

13.1. Waste treatment methods

Must be sent to a suitable incineration plant, observing local regulations.

The UK Environmental Protection (Duty of Care) Regulations (EP) and amendments should be noted

(United Kingdom).

This product and any uncleaned containers must be disposed of as hazardous waste in accordance

with the 2005 Hazardous Waste Regulations and amendments (United Kingdom)

Contaminated packaging:

Contaminated packaging should be emptied as far as possible and disposed of in the same manner

as the substance/product.

SECTION 14: Transport Information

Land transport

ADR

UN number

UN3082

UN proper shipping name:

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,

N.O.S. (contains EPOXICONAZOLE, FLUXAPYROXAD)

Transport hazard class(es):

9, EHSM

Packing group:

Environmental hazards:

Special precautions for

Tunnel code: E

Page: 17/20

BASF Safety data sheet according to Regulation (EC) No. 1907/2006

Date / Revised: 21.11.2013

Version: 2.0

Product: ADEXAR

(ID no. 30519170/SDS_CPA_GB/EN)

Date of print 23.11.2013

user:

RID

UN number

UN3082

UN proper shipping name:

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,

N.O.S. (contains EPOXICONAZOLE, FLUXAPYROXAD)

Transport hazard class(es):

9, EHSM

Packing group:

Environmental hazards:

Special precautions for

user:

None known

Inland waterway transport

ADN

UN number

UN3082

UN proper shipping name:

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,

N.O.S. (contains EPOXICONAZOLE, FLUXAPYROXAD)

Transport hazard class(es):

9, EHSM

Packing group:

Environmental hazards:

Special precautions for

user:

None known

Transport in inland

waterway vessel:

Not evaluated

Sea transport

IMDG

UN number:

UN 3082

UN proper shipping name:

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,

N.O.S. (contains EPOXICONAZOLE, FLUXAPYROXAD)

Transport hazard class(es):

9, EHSM

Packing group:

Environmental hazards:

Marine pollutant: YES

Special precautions for

user:

None known

Air transport

IATA/ICAO

UN number:

UN 3082

UN proper shipping name:

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,

N.O.S. (contains EPOXICONAZOLE, FLUXAPYROXAD)

Transport hazard class(es):

9, EHSM

Page: 18/20

BASF Safety data sheet according to Regulation (EC) No. 1907/2006

Date / Revised: 21.11.2013

Version: 2.0

Product: ADEXAR

(ID no. 30519170/SDS_CPA_GB/EN)

Date of print 23.11.2013

Packing group:

Environmental hazards:

Special precautions for

user:

None known

14.1. UN number

See corresponding entries for “UN number” for the respective regulations in the tables above.

14.2. UN proper shipping name

See corresponding entries for “UN proper shipping name” for the respective regulations in the tables

above.

14.3. Transport hazard class(es)

See corresponding entries for “Transport hazard class(es)” for the respective regulations in the

tables above.

14.4. Packing group

See corresponding entries for “Packing group” for the respective regulations in the tables above.

14.5. Environmental hazards

See corresponding entries for “Environmental hazards” for the respective regulations in the tables

above.

14.6. Special precautions for user

See corresponding entries for “Special precautions for user” for the respective regulations in the

tables above.

14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code

Regulation:

Not evaluated

Shipment approved:

Not evaluated

Pollution name:

Not evaluated

Pollution category:

Not evaluated

Ship Type:

Not evaluated

Further information

This product is subject to the most recent edition of "The Carriage of Dangerous Goods and Use of

Transportable Pressure Equipment Regulations" and their amendments (United Kingdom).

SECTION 15: Regulatory Information

15.1. Safety, health and environmental regulations/legislation specific for the

substance or mixture

For the user of this plant-protective product applies: 'To avoid risks to man and the environment,

comply with the instructions for use.' (Directive 1999/45/EC, Article 10, No. 1.2)

Page: 19/20

BASF Safety data sheet according to Regulation (EC) No. 1907/2006

Date / Revised: 21.11.2013

Version: 2.0

Product: ADEXAR

(ID no. 30519170/SDS_CPA_GB/EN)

Date of print 23.11.2013

The data should be considered when making any assessment under the Control of Substances

Hazardous to Health Regulations (COSHH), and related guidance, for example, 'COSHH Essentials'

(United Kingdom).

This product is classified under the Chemicals (Hazard Information and Packaging) Regulations,

(CHIP) (United Kingdom).

This product may be subject to the Control of Major Accident Hazards Regulations (COMAH), and

amendments if specific threshold tonnages are exceeded (United Kingdom).

15.2. Chemical Safety Assessment

Advice on product handling can be found in sections 7 and 8 of this safety data sheet.

SECTION 16: Other Information

For proper and safe use of this product, please refer to the approval conditions laid down on the

product label.

Full text of the classifications, including the indication of danger, the hazard symbols, the R phrases,

and the hazard statements, if mentioned in section 2 or 3:

Harmful.

Dangerous for the environment.

Irritant.

Limited evidence of a carcinogenic effect.

Possible risk of impaired fertility.

Possible risk of harm to the unborn child.

51/53

Toxic to aquatic organisms, may cause long-term adverse effects in the

aquatic environment.

50/53

Very toxic to aquatic organisms, may cause long-term adverse effects in

the aquatic environment.

36/38

Irritating to eyes and skin.

May cause sensitization by skin contact.

20/22

Harmful by inhalation and if swallowed.

Harmful: may cause lung damage if swallowed.

Repeated exposure may cause skin dryness or cracking.

Vapours may cause drowsiness and dizziness.

52/53

Harmful to aquatic organisms, may cause long-term adverse effects in

the aquatic environment.

Harmful in contact with skin.

Irritating to skin.

Risk of serious damage to eyes.

Harmful if swallowed.

Acute Tox.

Acute toxicity

Eye Dam./Irrit.

Serious eye damage/eye irritation

Skin Sens.

Skin sensitization

Carc.

Carcinogenicity

Repr.

Reproductive toxicity

Aquatic Acute

Hazardous to the aquatic environment - acute

Aquatic Chronic

Hazardous to the aquatic environment - chronic

Skin Corr./Irrit.

Skin corrosion/irritation

Asp. Tox.

Aspiration hazard

Page: 20/20

BASF Safety data sheet according to Regulation (EC) No. 1907/2006

Date / Revised: 21.11.2013

Version: 2.0

Product: ADEXAR

(ID no. 30519170/SDS_CPA_GB/EN)

Date of print 23.11.2013

STOT SE

Specific target organ toxicity — single exposure

Carc. Cat. 3

Carcinogenic substances Category 3: Substances which cause concern

for man owing to possible carcinogenic effects.

Repr. Cat. 3

Reprotoxic substances (fertility or development) Category 3: Substances

which cause concern for humans owing to possible developmental toxic

effects or substances which cause concern for human fertility.

H411

Toxic to aquatic life with long lasting effects.

H351

Suspected of causing cancer.

H361fd

Suspected of damaging fertility. Suspected of damaging the unborn child.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

H319

Causes serious eye irritation.

H315

Causes skin irritation.

H317

May cause an allergic skin reaction.

H332

Harmful if inhaled.

H302

Harmful if swallowed.

H304

May be fatal if swallowed and enters airways.

H336

May cause drowsiness or dizziness.

H402

Harmful to aquatic life.

H412

Harmful to aquatic life with long lasting effects.

H318

Causes serious eye damage.

H312

Harmful in contact with skin.

If you have any queries relating to this MSDS, it's contents or any other product safety related questions,

please write to the following e-mail address: product-safety-north@basf.com

The data contained in this safety data sheet are based on our current knowledge and experience and

describe the product only with regard to safety requirements. The data do not describe the product's

properties (product specification). Neither should any agreed property nor the suitability of the product for

any specific purpose be deduced from the data contained in the safety data sheet. It is the responsibility

of the recipient of the product to ensure any proprietary rights and existing laws and legislation are

observed.

Vertical lines in the left hand margin indicate an amendment from the previous version.

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