DIP IT LIQUID

Primær information

  • Handelsnavn:
  • DIP IT LIQUID
  • Brugt til:
  • Mennesker
  • Medicin typen:
  • Medicinsk udstyr

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  • for den brede offentlighed:
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Lokation

  • Fås i:
  • DIP IT LIQUID
    Irland
  • Sprog:
  • engelsk

Status

  • Kilde:
  • Ecolab
  • Autorisationsnummer:
  • 110723E
  • Sidste ændring:
  • 12-03-2018

Produktresumé: dosering, interaktioner, bivirkninger

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

Dip-it Liquid

110723E

1 / 14

Section: 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE

COMPANY/UNDERTAKING

1.1 Product identifier

Product name

Dip-it Liquid

Product code

110723E

Use of the

Substance/Mixture

Presoak

Substance type:

Mixture

For professional users only.

Product dilution information

No dilution information provided.

1.2 Relevant identified uses of the substance or mixture and uses advised against

Identified uses

Dishwash product. Manual process

Recommended restrictions

on use

Reserved for industrial and professional use.

1.3 Details of the supplier of the safety data sheet

Company

Ecolab Ltd.

PO Box 11; Winnington Avenue

Northwich, Cheshire, United Kingdom CW8 4DX

+353 (0)1 276 3500

ccs@ecolab.com

1.4 Emergency telephone number

Emergency telephone

number

+353 (0)1 276 3500

Poison Information Centre

telephone number

For medical professionals only:

+353 (0)1 837 9964 (8am-10pm)

Date of Compilation/Revision

13.04.2017

Version

Section: 2. HAZARDS IDENTIFICATION

2.1 Classification of the substance or mixture

Classification (REGULATION (EC) No 1272/2008)

Corrosive to metals, Category 1

H290

Skin corrosion, Category 1A

H314

Serious eye damage, Category 1

H318

Acute aquatic toxicity, Category 1

H400

Chronic aquatic toxicity, Category 2

H411

SAFETY DATA SHEET

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2.2 Label elements

Labelling (REGULATION (EC) No 1272/2008)

Hazard pictograms

Signal Word

Danger

Hazard Statements

H290

May be corrosive to metals.

H314

Causes severe skin burns and eye damage.

H400

Very toxic to aquatic life.

H411

Toxic to aquatic life with long lasting effects.

Supplemental Hazard

Statements

EUH031

Contact with acids liberates toxic gas.

Precautionary Statements

Prevention:

P273

Avoid release to the environment.

P280

Wear protective gloves/ eye protection/ face

protection.

Response:

P303 + P361 + P353

IF ON SKIN (or hair): Take off immediately

all contaminated clothing. Rinse skin with

water/shower.

P305 + P351 + P338

IF IN EYES: Rinse cautiously with water

for several minutes. Remove contact lenses, if

present and easy to do. Continue rinsing.

P310

Immediately call a POISON CENTER/doctor.

Hazardous components which must be listed on the label:

potassium hydroxide

sodium hypochlorite

2.3 Other hazards

Mixing this product with acid or ammonia releases chlorine gas.

Section: 3. COMPOSITION/INFORMATION ON INGREDIENTS

3.2 Mixtures

Hazardous components

Chemical Name

CAS-No.

EC-No.

REACH No.

ClassificationREGULATION (EC) No

1272/2008

Concentration:

potassium hydroxide

1310-58-3

215-181-3

01-2119487136-33

Acute toxicity Category 4; H302

Skin corrosion Category 1A; H314

Corrosive to metals Category 1; H290

>= 10 - < 20

sodium hypochlorite

7681-52-9

231-668-3

01-2119488154-34

Nota B Skin corrosion Category 1B;

H314

Acute aquatic toxicity Category 1; H400

Chronic aquatic toxicity Category 1;

>= 2.5 - < 5

SAFETY DATA SHEET

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H410

Substances with a workplace exposure limit :

sodium hydroxide

1310-73-2

215-185-5

01-2119457892-27

Skin corrosion Category 1A; H314

Corrosive to metals Category 1; H290

>= 0.1 - < 0.25

For the full text of the H-Statements mentioned in this Section, see Section 16.

Section: 4. FIRST AID MEASURES

4.1 Description of first aid measures

In case of eye contact

Rinse immediately with plenty of water, also under the eyelids, for

at least 15 minutes. Remove contact lenses, if present and easy

to do. Continue rinsing. Get medical attention immediately.

In case of skin contact

Wash off immediately with plenty of water for at least 15 minutes.

Use a mild soap if available. Wash clothing before reuse.

Thoroughly clean shoes before reuse. Get medical attention

immediately.

If swallowed

Rinse mouth with water. Do NOT induce vomiting. Never give

anything by mouth to an unconscious person. Get medical

attention immediately.

If inhaled

Remove to fresh air. Treat symptomatically. Get medical attention

if symptoms occur.

4.2 Most important symptoms and effects, both acute and delayed

See Section 11 for more detailed information on health effects and symptoms.

4.3 Indication of immediate medical attention and special treatment needed

Treatment

Treat symptomatically.

Section: 5. FIREFIGHTING MEASURES

5.1 Extinguishing media

Suitable extinguishing media

Use extinguishing measures that are appropriate to local

circumstances and the surrounding environment.

Unsuitable extinguishing

media

None known.

5.2 Special hazards arising from the substance or mixture

Specific hazards during

firefighting

Exposure to decomposition products may be a hazard to health.

Hazardous combustion

products

Decomposition products may include the following materials:

Carbon oxides

nitrogen oxides (NOx)

Sulphur oxides

Oxides of phosphorus

5.3 Advice for firefighters

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

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Special protective equipment

for firefighters

: Use personal protective equipment.

Further information

: Collect contaminated fire extinguishing water separately. This

must not be discharged into drains. Fire residues and

contaminated fire extinguishing water must be disposed of in

accordance with local regulations. In the event of fire and/or

explosion do not breathe fumes.

Section: 6. ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures

Advice for non-emergency

personnel

Ensure adequate ventilation. Keep people away from and upwind

of spill/leak. Avoid inhalation, ingestion and contact with skin and

eyes. When workers are facing concentrations above the

exposure limit they must use appropriate certified respirators.

Ensure clean-up is conducted by trained personnel only. Refer to

protective measures listed in sections 7 and 8.

Advice for emergency

responders

If specialised clothing is required to deal with the spillage, take

note of any information in Section 8 on suitable and unsuitable

materials.

6.2 Environmental precautions

Environmental precautions

Do not allow contact with soil, surface or ground water.

6.3 Methods and materials for containment and cleaning up

Methods for cleaning up

Stop leak if safe to do so. Contain spillage, and then collect with

non-combustible absorbent material, (e.g. sand, earth,

diatomaceous earth, vermiculite) and place in container for

disposal according to local / national regulations (see section 13).

Flush away traces with water. For large spills, dike spilled material

or otherwise contain material to ensure runoff does not reach a

waterway.

6.4 Reference to other sections

See Section 1 for emergency contact information.

For personal protection see section 8.

See Section 13 for additional waste treatment information.

Section: 7. HANDLING AND STORAGE

7.1 Precautions for safe handling

Advice on safe handling

Do not ingest. Do not get in eyes, on skin, or on clothing. Do not

breathe dust/fume/gas/mist/vapours/spray. Use only with

adequate ventilation. Wash hands thoroughly after handling.

Mixing this product with acid or ammonia releases chlorine gas.

Hygiene measures

Handle in accordance with good industrial hygiene and safety

practice. Remove and wash contaminated clothing before re-use.

Wash face, hands and any exposed skin thoroughly after

handling. Provide suitable facilities for quick drenching or flushing

of the eyes and body in case of contact or splash hazard.

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

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7.2 Conditions for safe storage, including any incompatibilities

Requirements for storage

areas and containers

Do not store near acids. Keep out of reach of children. Keep

container tightly closed. Store in suitable labeled containers.

Storage temperature

0 °C to 35 °C

7.3 Specific end uses

Specific use(s)

Dishwash product. Manual process

Section: 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 Control parameters

Occupational Exposure Limits

Components

CAS-No.

Value type (Form

of exposure)

Control parameters

Basis

potassium hydroxide

1310-58-3

OELV - 15 min

(STEL)

2 mg/m3

IR_OEL

sodium hydroxide

1310-73-2

OELV - 15 min

(STEL)

2 mg/m3

IR_OEL

DNEL

potassium hydroxide

End Use: Workers

Exposure routes: Inhalation

Value: 1 mg/m3

End Use: Consumers

Exposure routes: Inhalation

Value: 1 mg/m3

sodium hydroxide

End Use: Workers

Exposure routes: Inhalation

Potential health effects: Long-term local effects

Value: 1 mg/m3

End Use: Consumers

Exposure routes: Inhalation

Potential health effects: Long-term local effects

Value: 1 mg/m3

8.2 Exposure controls

Appropriate engineering controls

Engineering measures

Effective exhaust ventilation system. Maintain air concentrations

below occupational exposure standards.

Individual protection measures

Hygiene measures

Handle in accordance with good industrial hygiene and safety

practice. Remove and wash contaminated clothing before re-use.

Wash face, hands and any exposed skin thoroughly after

handling. Provide suitable facilities for quick drenching or flushing

of the eyes and body in case of contact or splash hazard.

SAFETY DATA SHEET

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Eye/face protection (EN 166)

Safety goggles

Face-shield

Hand protection (EN 374)

Recommended preventive skin protection

Gloves

Nitrile rubber

butyl-rubber

Breakthrough time: 1 – 4 hours

Minimum thickness for butyl-rubber 0.7 mm for nitrile rubber 0.4

mm or equivalent (please refer to the gloves

manufacturer/distributor for advise).

Gloves should be discarded and replaced if there is any indication

of degradation or chemical breakthrough.

Skin and body protection

(EN 14605)

Personal protective equipment comprising: suitable protective

gloves, safety goggles and protective clothing

Respiratory protection (EN

143, 14387)

None required if airborne concentrations are maintained below the

exposure limit listed in Exposure Limit Information. Use certified

respiratory protection equipment meeting EU

requirements(89/656/EEC, 89/686/EEC ), or equivalent, when

respiratory risks cannot be avoided or sufficiently limited by

technical means of collective protection or by measures, methods

or procedures of work organization.

Environmental exposure controls

General advice

: Consider the provision of containment around storage vessels.

Section: 9. PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on basic physical and chemical properties

Appearance

: liquid

Colour

: light yellow

Odour

: Chlorine

13.5 - 14.0, 100 %

Flash point

Not applicable.

Odour Threshold

Not applicable and/or not determined for the mixture

Melting point/freezing point

Not applicable and/or not determined for the mixture

Initial boiling point and

boiling range

Not applicable and/or not determined for the mixture

Evaporation rate

Not applicable and/or not determined for the mixture

Flammability (solid, gas)

Not applicable and/or not determined for the mixture

Upper explosion limit

Not applicable and/or not determined for the mixture

Lower explosion limit

Not applicable and/or not determined for the mixture

Vapour pressure

Not applicable and/or not determined for the mixture

Relative vapour density

Not applicable and/or not determined for the mixture

Relative density

1.3 - 1.35

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Water solubility

soluble

Solubility in other solvents

Not applicable and/or not determined for the mixture

Partition coefficient: n-

octanol/water

Not applicable and/or not determined for the mixture

Auto-ignition temperature

Not applicable and/or not determined for the mixture

Thermal decomposition

Not applicable and/or not determined for the mixture

Viscosity, kinematic

Not applicable and/or not determined for the mixture

Explosive properties

Not applicable and/or not determined for the mixture

Oxidizing properties

9.2 Other information

Not applicable and/or not determined for the mixture

Section: 10. STABILITY AND REACTIVITY

10.1 Reactivity

No dangerous reaction known under conditions of normal use.

10.2 Chemical stability

Stable under normal conditions.

10.3 Possibility of hazardous reactions

Mixing this product with acid or ammonia releases chlorine gas.

10.4 Conditions to avoid

None known.

10.5 Incompatible materials

Acids

10.6 Hazardous decomposition products

Decomposition products may include the following materials:

Carbon oxides

nitrogen oxides (NOx)

Sulphur oxides

Oxides of phosphorus

Section: 11. TOXICOLOGICAL INFORMATION

11.1 Information on toxicological effects

Information on likely routes of

exposure

Inhalation, Eye contact, Skin contact

Product

SAFETY DATA SHEET

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Acute oral toxicity

: Acute toxicity estimate : > 2,000 mg/kg

Acute inhalation toxicity

: There is no data available for this product.

Acute dermal toxicity

: There is no data available for this product.

Skin corrosion/irritation

: There is no data available for this product.

Serious eye damage/eye

irritation

: There is no data available for this product.

Respiratory or skin

sensitization

: There is no data available for this product.

Carcinogenicity

: There is no data available for this product.

Reproductive effects

: There is no data available for this product.

Germ cell mutagenicity

: There is no data available for this product.

Teratogenicity

: There is no data available for this product.

STOT - single exposure

: There is no data available for this product.

STOT - repeated exposure

: There is no data available for this product.

Aspiration toxicity

: There is no data available for this product.

Components

Acute oral toxicity

: potassium hydroxide

LD50 rat: 333 mg/kg

sodium hypochlorite

LD50 rat: 5,230 mg/kg

Components

Acute inhalation toxicity

: sodium hypochlorite

4 h LC50 rat: 5.25 mg/l

Components

Acute dermal toxicity

: sodium hypochlorite

LD50 rabbit: 10,000 mg/kg

Potential Health Effects

Eyes

Causes serious eye damage.

Skin

Causes severe skin burns.

Ingestion

Causes digestive tract burns.

Inhalation

May cause nose, throat, and lung irritation.

Chronic Exposure

Health injuries are not known or expected under normal use.

Experience with human exposure

SAFETY DATA SHEET

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Eye contact

Redness, Pain, Corrosion

Skin contact

Redness, Pain, Corrosion

Ingestion

Corrosion, Abdominal pain

Inhalation

Respiratory irritation, Cough

Section: 12. ECOLOGICAL INFORMATION

12.1 Ecotoxicity

Environmental Effects

Very toxic to aquatic life. Toxic to aquatic life with long lasting

effects.

Product

Toxicity to fish

: no data available

Toxicity to daphnia and other

aquatic invertebrates

: no data available

Toxicity to algae

: no data available

Components

Toxicity to daphnia and other

aquatic invertebrates

: sodium hypochlorite

48 h EC50: 0.071 mg/l

sodium hydroxide

48 h EC50: 40 mg/l

12.2 Persistence and degradability

Product

Biodegradability

: The surfactants contained in the product are biodegradable

according to the requirements of the detergent regulation

648/2004/EC

Components

Biodegradability

potassium hydroxide

Result: Not applicable - inorganic

sodium hypochlorite

Result: Not applicable - inorganic

sodium hydroxide

Result: Not applicable - inorganic

12.3 Bioaccumulative potential

no data available

12.4 Mobility in soil

no data available

SAFETY DATA SHEET

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12.5 Results of PBT and vPvB assessment

Product

Assessment

This substance/mixture contains no components considered to be

either persistent, bioaccumulative and toxic (PBT), or very

persistent and very bioaccumulative (vPvB) at levels of 0.1% or

higher.

12.6 Other adverse effects

no data available

Section: 13. DISPOSAL CONSIDERATIONS

Dispose of in accordance with the European Directives on waste and hazardous waste.Waste

codes should be assigned by the user, preferably in discussion with the waste disposal authorities.

13.1 Waste treatment methods

Product

: The product should not be allowed to enter drains, water courses

or the soil. Where possible recycling is preferred to disposal or

incineration. If recycling is not practicable, dispose of in

compliance with local regulations. Dispose of wastes in an

approved waste disposal facility.

Contaminated packaging

: Dispose of as unused product. Empty containers should be taken

to an approved waste handling site for recycling or disposal. Do

not re-use empty containers. Dispose of in accordance with local,

state, and federal regulations.

Guidance for Waste Code

selection

: Inorganic wastes containing dangerous substances. If this product

is used in any further processes, the final user must redefine and

assign the most appropriate European Waste Catalogue Code. It

is the responsibility of the waste generator to determine the

toxicity and physical properties of the material generated to

determine the proper waste identification and disposal methods in

compliance with applicable European (EU Directive 2008/98/EC)

and local regulations.

Section: 14. TRANSPORT INFORMATION

The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are

in compliance with the selected mode of transport.

Land transport (ADR/ADN/RID)

14.1 UN number

3266

14.2 UN proper shipping

name

CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S.

(Potassium hydroxide, sodium hypochlorite)

14.3 Transport hazard

class(es)

14.4 Packing group

14.5 Environmental hazards

14.6 Special precautions for

user

None

SAFETY DATA SHEET

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Air transport (IATA)

14.1 UN number

3266

14.2 UN proper shipping

name

Corrosive liquid, basic, inorganic, n.o.s.

(Potassium hydroxide, sodium hypochlorite)

14.3 Transport hazard

class(es)

14.4 Packing group

14.5 Environmental hazards

14.6 Special precautions for

user

None

Sea transport (IMDG/IMO)

14.1 UN number

3266

14.2 UN proper shipping

name

CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S.

(Potassium hydroxide, sodium hypochlorite)

14.3 Transport hazard

class(es)

14.4 Packing group

14.5 Environmental hazards

14.6 Special precautions for

user

None

14.7 Transport in bulk

according to Annex II of

MARPOL 73/78 and the IBC

Code

Not applicable.

Section: 15. REGULATORY INFORMATION

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

according to Detergents

Regulation EC 648/2004

5 % or over but less than 15 %: Phosphates

less than 5 %: Chlorine-based bleaching agents

National Regulations

Take note of Dir 94/33/EC on the protection of young people at work.

Other regulations

Safety, Health and Welfare at Work Act, 2005

European Communities (Classification, Packaging, Labelling and

Notification of Dangerous Preparations) Regulations 1995. (S.I.

272 of 1995) as amended

15.2 Chemical Safety Assessment

This product contains substances for which Chemical Safety Assessments are still required.

Section: 16. OTHER INFORMATION

Procedure used to derive the classification according to REGULATION (EC) No 1272/2008

Classification

Justification

SAFETY DATA SHEET

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Corrosive to metals 1, H290

Calculation method

Skin corrosion 1A, H314

Based on product data or assessment

Serious eye damage 1, H318

Based on product data or assessment

Acute aquatic toxicity 1, H400

Calculation method

Chronic aquatic toxicity 2, H411

Calculation method

Full text of H-Statements

H290

May be corrosive to metals.

H302

Harmful if swallowed.

H314

Causes severe skin burns and eye damage.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Full text of other abbreviations

ADN – European Agreement concerning the International Carriage of Dangerous Goods by

Inland Waterways; ADR – European Agreement concerning the International Carriage of

Dangerous Goods by Road; AICS – Australian Inventory of Chemical Substances; ASTM –

American Society for the Testing of Materials; bw – Body weight; CLP – Classification Labelling

Packaging Regulation; Regulation (EC) No 1272/2008; CMR – Carcinogen, Mutagen or

Reproductive Toxicant; DIN – Standard of the German Institute for Standardisation; DSL –

Domestic Substances List (Canada); ECHA – European Chemicals Agency; EC-Number –

European Community number; ECx – Concentration associated with x% response; ELx – Loading

rate associated with x% response; EmS – Emergency Schedule; ENCS – Existing and New

Chemical Substances (Japan); ErCx – Concentration associated with x% growth rate response;

GHS – Globally Harmonized System; GLP – Good Laboratory Practice; IARC – International

Agency for Research on Cancer; IATA – International Air Transport Association; IBC –

International Code for the Construction and Equipment of Ships carrying Dangerous Chemicals in

Bulk; IC50 – Half maximal inhibitory concentration; ICAO – International Civil Aviation

Organization; IECSC – Inventory of Existing Chemical Substances in China; IMDG – International

Maritime Dangerous Goods; IMO – International Maritime Organization; ISHL – Industrial Safety

and Health Law (Japan); ISO – International Organisation for Standardization; KECI – Korea

Existing Chemicals Inventory; LC50 – Lethal Concentration to 50 % of a test population; LD50 –

Lethal Dose to 50% of a test population (Median Lethal Dose); MARPOL – International

Convention for the Prevention of Pollution from Ships; n.o.s. – Not Otherwise Specified; NO(A)EC

– No Observed (Adverse) Effect Concentration; NO(A)EL – No Observed (Adverse) Effect Level;

NOELR – No Observable Effect Loading Rate; NZIoC – New Zealand Inventory of Chemicals;

OECD – Organization for Economic Co-operation and Development; OPPTS – Office of Chemical

Safety and Pollution Prevention; PBT – Persistent, Bioaccumulative and Toxic substance; PICCS

– Philippines Inventory of Chemicals and Chemical Substances; (Q)SAR – (Quantitative)

Structure Activity Relationship; REACH – Regulation (EC) No 1907/2006 of the European

Parliament and of the Council concerning the Registration, Evaluation, Authorisation and

Restriction of Chemicals; RID – Regulations concerning the International Carriage of Dangerous

Goods by Rail; SADT – Self-Accelerating Decomposition Temperature; SDS – Safety Data Sheet;

TCSI – Taiwan Chemical Substance Inventory; TRGS – Technical Rule for Hazardous

Substances; TSCA – Toxic Substances Control Act (United States); UN – United Nations; vPvB –

Very Persistent and Very Bioaccumulative

Prepared by

Regulatory Affairs

Numbers quoted in the MSDS are given in the format: 1,000,000 = 1 million and 1,000 = 1

thousand. 0.1 = 1 tenth and 0.001 = 1 thousandth

REVISED INFORMATION: Significant changes to regulatory or health information for this revision

is indicated by a bar in the left-hand margin of the SDS.

SAFETY DATA SHEET

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The information provided in this Safety Data Sheet is correct to the best of our knowledge,

information and belief at the date of its publication. The information given is designed only as a

guidance for safe handling, use, processing, storage, transportation, disposal and release and is

not to be considered a warranty or quality specification. The information relates only to the specific

material designated and may not be valid for such material used in combination with any other

materials or in any process, unless specified in the text.

ANNEX: EXPOSURE SCENARIOS

DPD+ Substances:

The following substances are the lead substances that contribute to the mixture Exposure

Scenario according to the DPD+ Rule:

Route

Substance

CAS-No.

EINECS-No.

Ingestion

potassium hydroxide

1310-58-3

215-181-3

Inhalation

potassium hydroxide

1310-58-3

215-181-3

Dermal

potassium hydroxide

1310-58-3

215-181-3

Eyes

potassium hydroxide

1310-58-3

215-181-3

aquatic environment

sodium hypochlorite

7681-52-9

231-668-3

Physical properties DPD+ Substances:

Substance

Vapour pressure

Water solubility

Pow

Molar Mass

potassium hydroxide

1,120 g/l

56.11 g/mol

sodium hypochlorite

25 hPa

1,000 g/l

To calculate if your downstream Operating Conditions and Risk management Measures are

safe, please calculate your risk factor at the website below:

www.ecetoc.org/tra

Short title of Exposure

Scenario

Dishwash product. Manual process

Use descriptors

Main User Groups

Professional uses: Public domain (administration, education,

entertainment, services, craftsmen)

Sectors of end-use

SU22: Professional uses: Public domain (administration,

education, entertainment, services, craftsmen)

Process categories

PROC10: Roller application or brushing

PROC8a: Transfer of substance or preparation (charging/

discharging) from/ to vessels/ large containers at non-dedicated

facilities

Product categories

PC35: Washing and cleaning products (including solvent based

SAFETY DATA SHEET

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products)

Environmental Release

Categories

ERC8a: Wide dispersive indoor use of processing aids in open

systems

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