KAY WATERLESS URINAL TOILET CLEANER

Основна информация

  • Търговско наименование:
  • KAY WATERLESS URINAL TOILET CLEANER
  • Използвай за:
  • Хората
  • Вид на лекарството:
  • Медицински устройство

Документи

Локализация

  • Предлага се в:
  • KAY WATERLESS URINAL TOILET CLEANER
    Ирландия
  • Език:
  • английски

Състояние

  • Източник:
  • Ecolab
  • Номер на разрешението:
  • 114354E
  • Последна актуализация:
  • 12-03-2018

кратка характеристика на продукта: дозировка, взаимодействия, странични ефекти.

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

KAY WATERLESS URINAL & TOILET CLEANER

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Section: 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE

COMPANY/UNDERTAKING

1.1 Product identifier

Product name

KAY WATERLESS URINAL & TOILET CLEANER

Product code

114354E

Use of the

Substance/Mixture

Cleaning product

Substance type:

Mixture

For professional users only.

Product dilution information

Product is sold ready to use.

1.2 Relevant identified uses of the substance or mixture and uses advised against

Identified uses

Sanitary cleaner. Spray and wipe manual process

Recommended restrictions

on use

Reserved for industrial and professional use.

1.3 Details of the supplier of the safety data sheet

Company

KAY BVBA

Havenlaan 4, Ravenshout Bed. 4 210

B-3980 Tessenderlo, Belgium +32 13 67 06 91 (Belgium)

BE_KAY_CS@ecolab.com

1.4 Emergency telephone number

Emergency telephone

number

+32 13 67 06 91 (Belgium)

Poison Information Centre

telephone number

For medical professionals only:

+353 (0)1 837 9964 (8am-10pm)

Date of Compilation/Revision

23.06.2015

version

Section: 2. HAZARDS IDENTIFICATION

2.1 Classification of the substance or mixture

Classification (REGULATION (EC) No 1272/2008)

Eye irritation, Category 2

H319

Classification (67/548/EEC, 1999/45/EC)

Xi; IRRITANT

For the full text of the R-phrases mentioned in this Section, see Section 16.

For the full text of the H-Statements mentioned in this Section, see Section 16.

2.2 Label elements

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

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Labelling (REGULATION (EC) No 1272/2008)

Hazard pictograms

Signal Word

Warning

Hazard Statements

H319

Causes serious eye irritation.

Precautionary Statements

Prevention:

P280

Wear protective gloves.

Additional Labelling:

Special labelling of certain

mixtures

Contains: 1,2-benzisothiazol-3(2H)-one May produce an allergic

reaction.

2.3 Other hazards

None known.

Section: 3. COMPOSITION/INFORMATION ON INGREDIENTS

3.2 Mixtures

Hazardous components

Chemical Name

CAS-No.

EC-No.

REACH No.

Classification

(67/548/EEC)

Classification

(REGULATION (EC) No

1272/2008)

Concentration:

Fattyalcohol

ethoxylates > 5EO

68439-45-2

Xi; R38-R41

Serious eye damage/eye

irritation Category 1; H318

Skin corrosion/irritation

Category 2; H315

>= 1 - < 2.5

sodium

dodecylbenzene

sulfonate

25155-30-0

246-680-4

Xn; R22-R41-

Acute toxicity Category 4;

H302

Skin irritation Category 2;

H315

Serious eye damage

Category 1; H318

>= 1 - < 2.5

WEL substance :

Propylene glycol

57-55-6

200-338-0

01-2119456809-23

>= 1 - < 2.5

For the full text of the R-phrases mentioned in this Section, see Section 16.

For the full text of the H-Statements mentioned in this Section, see Section 16.

Section: 4. FIRST AID MEASURES

4.1 Description of first aid measures

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

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In case of eye contact

Rinse immediately with plenty of water, also under the eyelids, for

at least 15 minutes. Remove contact lenses, if present and easy

to do. Continue rinsing. Get medical attention.

In case of skin contact

Rinse with plenty of water.

If swallowed

Rinse mouth. Get medical attention if symptoms occur.

If inhaled

Get medical attention if symptoms occur.

4.2 Most important symptoms and effects, both acute and delayed

See Section 11 for more detailed information on health effects and symptoms.

4.3 Indication of immediate medical attention and special treatment needed

Treatment

Treat symptomatically.

Section: 5. FIREFIGHTING MEASURES

5.1 Extinguishing media

Suitable extinguishing media

Use extinguishing measures that are appropriate to local

circumstances and the surrounding environment.

Unsuitable extinguishing

media

None known.

5.2 Special hazards arising from the substance or mixture

Specific hazards during

firefighting

Not flammable or combustible.

Hazardous combustion

products

Decomposition products may include the following materials:

Carbon oxides

nitrogen oxides (NOx)

Sulphur oxides

Oxides of phosphorus

5.3 Advice for firefighters

Special protective equipment

for firefighters

: Use personal protective equipment.

Further information

: Fire residues and contaminated fire extinguishing water must be

disposed of in accordance with local regulations. In the event of

fire and/or explosion do not breathe fumes.

Section: 6. ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures

Advice for non-emergency

personnel

Ensure clean-up is conducted by trained personnel only. Refer to

protective measures listed in sections 7 and 8.

Advice for emergency

responders

If specialised clothing is required to deal with the spillage, take

note of any information in Section 8 on suitable and unsuitable

SAFETY DATA SHEET

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materials.

6.2 Environmental precautions

Environmental precautions

Do not allow contact with soil, surface or ground water.

6.3 Methods and materials for containment and cleaning up

Methods for cleaning up

Stop leak if safe to do so. Contain spillage, and then collect with

non-combustible absorbent material, (e.g. sand, earth,

diatomaceous earth, vermiculite) and place in container for

disposal according to local / national regulations (see section 13).

Flush away traces with water. For large spills, dike spilled material

or otherwise contain material to ensure runoff does not reach a

waterway.

6.4 Reference to other sections

See Section 1 for emergency contact information.

For personal protection see section 8.

See Section 13 for additional waste treatment information.

Section: 7. HANDLING AND STORAGE

7.1 Precautions for safe handling

Advice on safe handling

Avoid contact with skin and eyes. Use only with adequate

ventilation. Wash hands thoroughly after handling.

Hygiene measures

Handle in accordance with good industrial hygiene and safety

practice. Remove and wash contaminated clothing before re-use.

Wash face, hands and any exposed skin thoroughly after

handling.

7.2 Conditions for safe storage, including any incompatibilities

Requirements for storage

areas and containers

Keep out of reach of children. Keep container tightly closed. Store

in suitable labeled containers.

Storage temperature

5 °C to 45 °C

7.3 Specific end uses

Specific use(s)

Sanitary cleaner. Spray and wipe manual process

Section: 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 Control parameters

Occupational Exposure Limits

CAS-No.

Components

Value type (Form of

exposure)

Control

parameters

Update

Basis

57-55-6

Propylene

glycol

OELV - 8 hrs (TWA)

(particles)

10 mg/m3

2011-12-02

IR_OEL

OELV - 8 hrs (TWA)

(vapour and

150 ppm

470 mg/m3

2011-12-02

IR_OEL

SAFETY DATA SHEET

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particles)

DNEL

Propylene glycol

End Use: Workers

Exposure routes: Inhalation

Potential health effects: Long-term systemic effects

Value: 168 mg/m3

End Use: Workers

Exposure routes: Inhalation

Potential health effects: Long-term local effects

Value: 10 mg/m3

End Use: Consumers

Exposure routes: Inhalation

Potential health effects: Long-term systemic effects

Value: 50 mg/m3

End Use: Consumers

Exposure routes: Inhalation

Potential health effects: Long-term local effects

Value: 10 mg/m3

End Use: Consumers

Exposure routes: Dermal

Potential health effects: Long-term systemic effects

Value: 213 mg/cm2

End Use: Consumers

Exposure routes: Ingestion

Potential health effects: Long-term systemic effects

Value: 85 ppm

PNEC

Propylene glycol

Fresh water

Value: 260 mg/l

Marine water

Value: 26 mg/l

Intermittent use/release

Value: 183 mg/l

Fresh water sediment

Value: 572 mg/kg

Marine sediment

Value: 57.2 mg/kg

Sewage treatment plant

Value: 20000 mg/l

Soil

Value: 50 mg/kg

8.2 Exposure controls

SAFETY DATA SHEET

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Appropriate engineering controls

Engineering measures

Good general ventilation should be sufficient to control worker

exposure to airborne contaminants.

Individual protection measures

Hygiene measures

Handle in accordance with good industrial hygiene and safety

practice. Remove and wash contaminated clothing before re-use.

Wash face, hands and any exposed skin thoroughly after

handling.

Eye/face protection (EN 166)

No special protective equipment required.

Hand protection (EN 374)

Wear the following personal protective equipment:

Nitrile rubber

butyl-rubber

Impervious gloves

Gloves should be discarded and replaced if there is any indication

of degradation or chemical breakthrough.

Skin and body protection (EN

14605)

No special protective equipment required.

Respiratory protection (EN

143, 14387)

None required if airborne concentrations are maintained below the

exposure limit listed in Exposure Limit Information. Use certified

respiratory protection equipment meeting EU

requirements(89/656/EEC, 89/686/EEC ), or equivalent, when

respiratory risks cannot be avoided or sufficiently limited by

technical means of collective protection or by measures, methods

or procedures of work organization.

Environmental exposure controls

General advice

: Consider the provision of containment around storage vessels.

Section: 9. PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on basic physical and chemical properties

Appearance

: liquid

Colour

: opaque, white

Odour

: citrus

7.0 - 9.0, 100 %

Flash point

Not applicable., Does not sustain combustion.

Odour Threshold

Not applicable and/or not determined for the mixture

Melting point/freezing point

Not applicable and/or not determined for the mixture

Initial boiling point and

boiling range

> 100 °C

Evaporation rate

Not applicable and/or not determined for the mixture

Flammability (solid, gas)

Not applicable and/or not determined for the mixture

Upper explosion limit

Not applicable and/or not determined for the mixture

Lower explosion limit

Not applicable and/or not determined for the mixture

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Vapour pressure

Not applicable and/or not determined for the mixture

Relative vapour density

Not applicable and/or not determined for the mixture

Relative density

1.0 - 1.01

Water solubility

soluble

Solubility in other solvents

Not applicable and/or not determined for the mixture

Partition coefficient: n-

octanol/water

Not applicable and/or not determined for the mixture

Auto-ignition temperature

Not applicable and/or not determined for the mixture

Thermal decomposition

Not applicable and/or not determined for the mixture

Viscosity, kinematic

Not applicable and/or not determined for the mixture

Explosive properties

Not applicable and/or not determined for the mixture

Oxidizing properties

The substance or mixture is not classified as oxidizing.

9.2 Other information

Not applicable and/or not determined for the mixture

Section: 10. STABILITY AND REACTIVITY

10.1 Reactivity

No dangerous reaction known under conditions of normal use.

10.2 Chemical stability

Stable under normal conditions.

10.3 Possibility of hazardous reactions

No dangerous reaction known under conditions of normal use.

10.4 Conditions to avoid

None known.

10.5 Incompatible materials

Metals

10.6 Hazardous decomposition products

Decomposition products may include the following materials:

Carbon oxides

nitrogen oxides (NOx)

Sulphur oxides

Oxides of phosphorus

Section: 11. TOXICOLOGICAL INFORMATION

11.1 Information on toxicological effects

Information on likely routes of

exposure

Inhalation, Eye contact, Skin contact

SAFETY DATA SHEET

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Toxicity

Acute oral toxicity

: Acute toxicity estimate : > 2,000 mg/kg

Acute inhalation toxicity

: There is no data available for this product.

Acute dermal toxicity

: There is no data available for this product.

Skin corrosion/irritation

: There is no data available for this product.

Serious eye damage/eye

irritation

: Mild eye irritation

Respiratory or skin

sensitization

: There is no data available for this product.

Carcinogenicity

: There is no data available for this product.

Reproductive effects

: There is no data available for this product.

Germ cell mutagenicity

: There is no data available for this product.

Teratogenicity

: There is no data available for this product.

STOT - single exposure

: There is no data available for this product.

STOT - repeated exposure

: There is no data available for this product.

Aspiration toxicity

: There is no data available for this product.

Components

Acute oral toxicity

: Fattyalcohol ethoxylates > 5EO

LD50 rat: 7,000 mg/kg

sodium dodecylbenzene sulfonate

LD50 rat: 1,086 mg/kg

Propylene glycol

LD50 rat: 22,000 mg/kg

Components

Acute inhalation toxicity

: Propylene glycol

4 h LC50 rat: > 158.5 mg/l

Components

Acute dermal toxicity

: Fattyalcohol ethoxylates > 5EO

LD50 rabbit: > 2,000 mg/kg

Potential Health Effects

Eyes

Causes serious eye irritation.

Skin

Health injuries are not known or expected under normal use.

Ingestion

Health injuries are not known or expected under normal use.

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

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Inhalation

Health injuries are not known or expected under normal use.

Chronic Exposure

Health injuries are not known or expected under normal use.

Experience with human exposure

Eye contact

Redness, Pain, Irritation

Skin contact

No symptoms known or expected.

Ingestion

No symptoms known or expected.

Inhalation

No symptoms known or expected.

Section: 12. ECOLOGICAL INFORMATION

12.1 Ecotoxicity

Environmental Effects

This product has no known ecotoxicological effects.

Product

Toxicity to fish

: no data available

Toxicity to daphnia and other

aquatic invertebrates

: no data available

Toxicity to algae

: no data available

Components

Toxicity to fish

: Fattyalcohol ethoxylates > 5EO

96 h LC50 Fish: 1.5 mg/l

sodium dodecylbenzene sulfonate

96 h LC50: 3.2 mg/l

Propylene glycol

96 h LC50: > 10,000 mg/l

Components

Toxicity to daphnia and other

aquatic invertebrates

: Propylene glycol

48 h EC50: 18,340 mg/l

Components

Toxicity to algae

: Propylene glycol

96 h EC50: 19,000 mg/l

12.2 Persistence and degradability

Product

Biodegradability

: The surfactants contained in the product are biodegradable

according to the requirements of the detergent regulation

648/2004/EC

Components

Biodegradability

Fattyalcohol ethoxylates > 5EO

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Result: Readily biodegradable.

sodium dodecylbenzene sulfonate

Result: Readily biodegradable.

Propylene glycol

Result: Readily biodegradable.

12.3 Bioaccumulative potential

no data available

12.4 Mobility in soil

no data available

12.5 Results of PBT and vPvB assessment

Product

Assessment

This substance/mixture contains no components considered to be

either persistent, bioaccumulative and toxic (PBT), or very

persistent and very bioaccumulative (vPvB) at levels of 0.1% or

higher.

12.6 Other adverse effects

no data available

Section: 13. DISPOSAL CONSIDERATIONS

Dispose of in accordance with the European Directives on waste and hazardous waste.Waste

codes should be assigned by the user, preferably in discussion with the waste disposal authorities.

13.1 Waste treatment methods

Product

: Where possible recycling is preferred to disposal or incineration. If

recycling is not practicable, dispose of in compliance with local

regulations. Dispose of wastes in an approved waste disposal

facility.

Contaminated packaging

: Dispose of as unused product. Empty containers should be taken

to an approved waste handling site for recycling or disposal. Do

not re-use empty containers. Dispose of in accordance with local,

state, and federal regulations.

European Waste Catalogue

: 200129* - detergents containing dangerous substances

Section: 14. TRANSPORT INFORMATION

The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are

in compliance with the selected mode of transport.

Land transport (ADR/ADN/RID)

14.1 UN number

Not dangerous goods

14.2 UN proper shipping

name

Not dangerous goods

SAFETY DATA SHEET

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14.3 Transport hazard

class(es)

Not dangerous goods

14.4 Packing group

Not dangerous goods

14.5 Environmental hazards

Not dangerous goods

14.6 Special precautions for

user

Not dangerous goods

Air transport (IATA)

14.1 UN number

Not dangerous goods

14.2 UN proper shipping

name

Not dangerous goods

14.3 Transport hazard

class(es)

Not dangerous goods

14.4 Packing group

Not dangerous goods

14.5 Environmental hazards

Not dangerous goods

14.6 Special precautions for

user

Not dangerous goods

Sea transport (IMDG/IMO)

14.1 UN number

Not dangerous goods

14.2 UN proper shipping

name

Not dangerous goods

14.3 Transport hazard

class(es)

Not dangerous goods

14.4 Packing group

Not dangerous goods

14.5 Environmental hazards

Not dangerous goods

14.6 Special precautions for

user

Not dangerous goods

14.7 Transport in bulk

according to Annex II of

MARPOL 73/78 and the IBC

Code

Not dangerous goods

Section: 15. REGULATORY INFORMATION

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

according to Detergents

Regulation EC 648/2004

less than 5 %: Anionic surfactants, Non-ionic surfactants, EDTA

and salts thereof

Preservation agents:

1,2-benzisothiazol-3(2H)-one

Allergens:

d-Limonene

Linalool

Cinnamal

Citronellol

Geraniol

Citral

Eugenol

National Regulations

Take note of Dir 94/33/EC on the protection of young people at work.

SAFETY DATA SHEET

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Other regulations

Safety, Health and Welfare at Work Act, 2005

European Communities (Classification, Packaging, Labelling and

Notification of Dangerous Preparations) Regulations 1995. (S.I.

272 of 1995) as amended

15.2 Chemical Safety Assessment

This product contains substances for which Chemical Safety Assessments are still required.

Section: 16. OTHER INFORMATION

Full text of R-Phrases

Harmful if swallowed.

Irritating to skin.

Risk of serious damage to eyes.

Full text of H-Statements

H302

Harmful if swallowed.

H315

Causes skin irritation.

H318

Causes serious eye damage.

Full text of other abbreviations

Prepared by

Regulatory Affairs

Numbers quoted in the MSDS are given in the format: 1,000,000 = 1 million and 1,000 = 1

thousand. 0.1 = 1 tenth and 0.001 = 1 thousandth

REVISED INFORMATION: Significant changes to regulatory or health information for this revision

is indicated by a bar in the left-hand margin of the SDS.

The information provided in this Safety Data Sheet is correct to the best of our knowledge,

information and belief at the date of its publication. The information given is designed only as a

guidance for safe handling, use, processing, storage, transportation, disposal and release and is

not to be considered a warranty or quality specification. The information relates only to the specific

material designated and may not be valid for such material used in combination with any other

materials or in any process, unless specified in the text.

ANNEX: EXPOSURE SCENARIOS

DPD+ Substances:

The following substances are the lead substances that contribute to the mixture Exposure

Scenario according to the DPD+ Rule:

Route

Substance

CAS-No.

EINECS-No.

Ingestion

sodium dodecylbenzene sulfonate

25155-30-0

246-680-4

Inhalation

No lead substance

Dermal

Fattyalcohol ethoxylates > 5EO

68439-45-2

Eyes

Fattyalcohol ethoxylates > 5EO

68439-45-2

aquatic environment

No lead substance

Physical properties DPD+ Substances:

SAFETY DATA SHEET

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Substance

Vapour pressure

Water solubility

Pow

Molar Mass

sodium dodecylbenzene

sulfonate

< 0.0000001 hPa

0.1 g/l

2,089.3

348.48 g/mol

To calculate if your downstream Operating Conditions and Risk management Measures are

safe, please calculate your risk factor at the website below:

www.ecetoc.org/tra

Short title of Exposure

Scenario

Sanitary cleaner. Spray and wipe manual process

Use descriptors

Main User Groups

Professional uses: Public domain (administration, education,

entertainment, services, craftsmen)

Sectors of end-use

SU22: Professional uses: Public domain (administration,

education, entertainment, services, craftsmen)

Process categories

PROC10: Roller application or brushing

PROC11: Non industrial spraying

PROC8a: Transfer of substance or preparation (charging/

discharging) from/ to vessels/ large containers at non-dedicated

facilities

Product categories

PC35: Washing and cleaning products (including solvent based

products)

Environmental Release

Categories

ERC8a: Wide dispersive indoor use of processing aids in open

systems