Dazo Fluorescent Marking Gel

Основна информация

  • Търговско наименование:
  • Dazo Fluorescent Marking Gel
  • Използвай за:
  • Хората
  • Вид на лекарството:
  • Медицински устройство

Документи

Локализация

  • Предлага се в:
  • Dazo Fluorescent Marking Gel
    Ирландия
  • Език:
  • английски

Състояние

  • Източник:
  • Ecolab
  • Номер на разрешението:
  • 115403E
  • Последна актуализация:
  • 12-03-2018

кратка характеристика на продукта: дозировка, взаимодействия, странични ефекти.

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

Dazo Fluorescent Marking Gel

115403E

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Section: 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE

COMPANY/UNDERTAKING

1.1 Product identifier

Product name

Dazo Fluorescent Marking Gel

Product code

115403E

Use of the

Substance/Mixture

Maintenance Product

Substance type:

Mixture

For professional users only.

Product dilution information

No dilution information provided.

1.2 Relevant identified uses of the substance or mixture and uses advised against

Identified uses

General purpose cleaner. Manual process

Recommended restrictions

on use

Reserved for industrial and professional use.

1.3 Details of the supplier of the safety data sheet

Company

Ecolab Ltd.

PO Box 11; Winnington Avenue

Northwich, Cheshire, United Kingdom CW8 4DX

+353 (0)1 276 3500

ccs@ecolab.com

1.4 Emergency telephone number

Emergency telephone

number

+353 (0)1 276 3500

Poison Information Centre

telephone number

For medical professionals only:

+353 (0)1 837 9964 (8am-10pm)

Date of Compilation/Revision

29.06.2016

version

Section: 2. HAZARDS IDENTIFICATION

2.1 Classification of the substance or mixture

Classification (REGULATION (EC) No 1272/2008)

Eye irritation, Category 2

H319

The classification of this product is based on toxicological assessment.

Classification (67/548/EEC, 1999/45/EC)

Xi; IRRITANT

SAFETY DATA SHEET

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The classification of this product is based on toxicological

assessment.

2.2 Label elements

Labelling (REGULATION (EC) No 1272/2008)

Hazard pictograms

Signal Word

Warning

Hazard Statements

H319

Causes serious eye irritation.

Precautionary Statements

Prevention:

P280e

Wear eye protection/face protection.

Hazardous components which must be listed on the label:

Amphoteric surfactants

2.3 Other hazards

None known.

Section: 3. COMPOSITION/INFORMATION ON INGREDIENTS

3.2 Mixtures

Hazardous components

Chemical Name

CAS-No.

EC-No.

REACH No.

ClassificationREGULATION (EC) No

1272/2008

Concentration:

propan-2-ol

67-63-0

200-661-7

01-2119457558-25

Flammable liquids Category 2; H225

Eye irritation Category 2; H319

Specific target organ toxicity - single

exposure Category 3; H336

>= 3 - < 5

Alcohols, C9-11,

ethoxylated

68439-46-3

Acute toxicity Category 4; H302

Skin irritation Category 2; H315

Serious eye damage Category 1; H318

>= 3 - < 5

Cationic surfactants

61791-10-4

Acute toxicity Category 4; H302

Eye irritation Category 2; H319

Chronic aquatic toxicity Category 2;

H411

>= 1 - < 2.5

2-phenoxyethanol

122-99-6

204-589-7

01-2119488943-21

Acute toxicity Category 4; H302

Eye irritation Category 2; H319

>= 1 - < 2.5

poly(oxy-1,2-ethanediyl),

a-(2-propylheptyl)-w-

hydroxy-

160875-66-1

Serious eye damage Category 1; H318

>= 1 - < 2.5

For the full text of the H-Statements mentioned in this Section, see Section 16.

Section: 4. FIRST AID MEASURES

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

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4.1 Description of first aid measures

In case of eye contact

Rinse immediately with plenty of water, also under the eyelids, for

at least 15 minutes. Remove contact lenses, if present and easy

to do. Continue rinsing. Get medical attention.

In case of skin contact

Rinse with plenty of water.

If swallowed

Rinse mouth. Get medical attention if symptoms occur.

If inhaled

Get medical attention if symptoms occur.

4.2 Most important symptoms and effects, both acute and delayed

See Section 11 for more detailed information on health effects and symptoms.

4.3 Indication of immediate medical attention and special treatment needed

Treatment

Treat symptomatically.

Section: 5. FIREFIGHTING MEASURES

5.1 Extinguishing media

Suitable extinguishing media

Use extinguishing measures that are appropriate to local

circumstances and the surrounding environment.

Unsuitable extinguishing

media

None known.

5.2 Special hazards arising from the substance or mixture

Specific hazards during

firefighting

Not flammable or combustible.

Hazardous combustion

products

Decomposition products may include the following materials:

Carbon oxides

nitrogen oxides (NOx)

Sulphur oxides

Oxides of phosphorus

5.3 Advice for firefighters

Special protective equipment

for firefighters

: Use personal protective equipment.

Further information

: Fire residues and contaminated fire extinguishing water must be

disposed of in accordance with local regulations. In the event of

fire and/or explosion do not breathe fumes.

Section: 6. ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures

Advice for non-emergency

personnel

Ensure clean-up is conducted by trained personnel only. Refer to

protective measures listed in sections 7 and 8.

SAFETY DATA SHEET

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Advice for emergency

responders

If specialised clothing is required to deal with the spillage, take

note of any information in Section 8 on suitable and unsuitable

materials.

6.2 Environmental precautions

Environmental precautions

Do not allow contact with soil, surface or ground water.

6.3 Methods and materials for containment and cleaning up

Methods for cleaning up

Stop leak if safe to do so. Contain spillage, and then collect with

non-combustible absorbent material, (e.g. sand, earth,

diatomaceous earth, vermiculite) and place in container for

disposal according to local / national regulations (see section 13).

Flush away traces with water. For large spills, dike spilled material

or otherwise contain material to ensure runoff does not reach a

waterway.

6.4 Reference to other sections

See Section 1 for emergency contact information.

For personal protection see section 8.

See Section 13 for additional waste treatment information.

Section: 7. HANDLING AND STORAGE

7.1 Precautions for safe handling

Advice on safe handling

Avoid contact with skin and eyes. Use only with adequate

ventilation. Wash hands thoroughly after handling.

Hygiene measures

Handle in accordance with good industrial hygiene and safety

practice. Remove and wash contaminated clothing before re-use.

Wash face, hands and any exposed skin thoroughly after

handling.

7.2 Conditions for safe storage, including any incompatibilities

Requirements for storage

areas and containers

Keep out of reach of children. Keep container tightly closed. Store

in suitable labeled containers.

Storage temperature

0 °C to 40 °C

7.3 Specific end uses

Specific use(s)

General purpose cleaner. Manual process

Section: 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 Control parameters

Occupational Exposure Limits

Components

CAS-No.

Value type (Form

of exposure)

Control parameters

Basis

propan-2-ol

67-63-0

OELV - 8 hrs

(TWA)

200 ppm

IR_OEL

Further information

Substances which have the capacity to penetrate intact skin when they come

in contact with it, and be absorbed into the body

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OELV - 15 min

(STEL)

400 ppm

IR_OEL

Further information

Substances which have the capacity to penetrate intact skin when they come

in contact with it, and be absorbed into the body

DNEL

propan-2-ol

End Use: Workers

Exposure routes: Dermal

Potential health effects: Long-term systemic effects

Value: 888 mg/cm2

End Use: Workers

Exposure routes: Inhalation

Potential health effects: Long-term systemic effects

Value: 500 mg/m3

End Use: Consumers

Exposure routes: Dermal

Potential health effects: Long-term systemic effects

Value: 319 mg/cm2

End Use: Consumers

Exposure routes: Inhalation

Potential health effects: Long-term systemic effects

Value: 89 mg/m3

End Use: Consumers

Exposure routes: Ingestion

Potential health effects: Long-term systemic effects

Value: 26 ppm

PNEC

propan-2-ol

Fresh water

Value: 140.9 mg/l

Marine water

Value: 140.9 mg/l

Intermittent use/release

Value: 140.9 mg/l

Fresh water

Value: 552 mg/kg

Marine sediment

Value: 552 mg/kg

Soil

Value: 28 mg/kg

Sewage treatment plant

Value: 2251 mg/l

Oral

Value: 160 mg/kg

8.2 Exposure controls

SAFETY DATA SHEET

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Appropriate engineering controls

Engineering measures

Good general ventilation should be sufficient to control worker

exposure to airborne contaminants.

Individual protection measures

Hygiene measures

Handle in accordance with good industrial hygiene and safety

practice. Remove and wash contaminated clothing before re-use.

Wash face, hands and any exposed skin thoroughly after

handling.

Eye/face protection (EN 166)

Safety glasses with side-shields

Hand protection (EN 374)

No special protective equipment required.

Skin and body protection

(EN 14605)

No special protective equipment required.

Respiratory protection (EN

143, 14387)

None required if airborne concentrations are maintained below the

exposure limit listed in Exposure Limit Information. Use certified

respiratory protection equipment meeting EU

requirements(89/656/EEC, 89/686/EEC ), or equivalent, when

respiratory risks cannot be avoided or sufficiently limited by

technical means of collective protection or by measures, methods

or procedures of work organization.

Environmental exposure controls

General advice

: Consider the provision of containment around storage vessels.

Section: 9. PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on basic physical and chemical properties

Appearance

: liquid

Colour

: clear, yellow

Odour

: alcohol-like

5.0 - 9.0, 100 %

Flash point

Not applicable., Does not sustain combustion.

Odour Threshold

Not applicable and/or not determined for the mixture

Melting point/freezing point

Not applicable and/or not determined for the mixture

Initial boiling point and

boiling range

> 100 °C

Evaporation rate

Not applicable and/or not determined for the mixture

Flammability (solid, gas)

Not applicable and/or not determined for the mixture

Upper explosion limit

Not applicable and/or not determined for the mixture

Lower explosion limit

Not applicable and/or not determined for the mixture

Vapour pressure

Not applicable and/or not determined for the mixture

SAFETY DATA SHEET

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Relative vapour density

Not applicable and/or not determined for the mixture

Relative density

1.01 - 1.018

Water solubility

soluble

Solubility in other solvents

Not applicable and/or not determined for the mixture

Partition coefficient: n-

octanol/water

Not applicable and/or not determined for the mixture

Auto-ignition temperature

Not applicable and/or not determined for the mixture

Thermal decomposition

Not applicable and/or not determined for the mixture

Viscosity, kinematic

3457.890 mm2/s (40 °C)

Explosive properties

Not applicable and/or not determined for the mixture

Oxidizing properties

The substance or mixture is not classified as oxidizing.

9.2 Other information

Not applicable and/or not determined for the mixture

Section: 10. STABILITY AND REACTIVITY

10.1 Reactivity

No dangerous reaction known under conditions of normal use.

10.2 Chemical stability

Stable under normal conditions.

10.3 Possibility of hazardous reactions

No dangerous reaction known under conditions of normal use.

10.4 Conditions to avoid

None known.

10.5 Incompatible materials

None known.

10.6 Hazardous decomposition products

Decomposition products may include the following materials:

Carbon oxides

nitrogen oxides (NOx)

Sulphur oxides

Oxides of phosphorus

Section: 11. TOXICOLOGICAL INFORMATION

11.1 Information on toxicological effects

Information on likely routes of

exposure

Inhalation, Eye contact, Skin contact

SAFETY DATA SHEET

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Product

Acute oral toxicity

: Acute toxicity estimate : > 2,000 mg/kg

Acute inhalation toxicity

: There is no data available for this product.

Acute dermal toxicity

: There is no data available for this product.

Skin corrosion/irritation

: There is no data available for this product.

Serious eye damage/eye

irritation

: Causes serious eye irritation.

Method: OECD Test Guideline 437

Test substance: Product

Respiratory or skin

sensitization

: There is no data available for this product.

Carcinogenicity

: There is no data available for this product.

Reproductive effects

: There is no data available for this product.

Germ cell mutagenicity

: There is no data available for this product.

Teratogenicity

: There is no data available for this product.

STOT - single exposure

: There is no data available for this product.

STOT - repeated exposure

: There is no data available for this product.

Aspiration toxicity

: There is no data available for this product.

Components

Acute oral toxicity

: propan-2-ol

LD50 rat: 5,840 mg/kg

Alcohols, C9-11, ethoxylated

LD50 rat: 1,400 mg/kg

Cationic surfactants

LD50 rat: 580 mg/kg

2-phenoxyethanol

LD50 rat: 2,000 mg/kg

poly(oxy-1,2-ethanediyl), a-(2-propylheptyl)-w-hydroxy-

LD50 rat: > 2,000 mg/kg

Components

Acute inhalation toxicity

: propan-2-ol

4 h LC50 rat: > 30 mg/l

Components

Acute dermal toxicity

: propan-2-ol

LD50 rabbit: 12,870 mg/kg

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

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Alcohols, C9-11, ethoxylated

LD50 rat: > 5,000 mg/kg

2-phenoxyethanol

LD50 rabbit: 2,250 mg/kg

Potential Health Effects

Eyes

Causes serious eye irritation.

Skin

Health injuries are not known or expected under normal use.

Ingestion

Health injuries are not known or expected under normal use.

Inhalation

Health injuries are not known or expected under normal use.

Chronic Exposure

Health injuries are not known or expected under normal use.

Experience with human exposure

Eye contact

Redness, Pain, Irritation

Skin contact

No symptoms known or expected.

Ingestion

No symptoms known or expected.

Inhalation

No symptoms known or expected.

Section: 12. ECOLOGICAL INFORMATION

12.1 Ecotoxicity

Environmental Effects

This product has no known ecotoxicological effects.

Product

Toxicity to fish

: no data available

Toxicity to daphnia and other

aquatic invertebrates

: no data available

Toxicity to algae

: no data available

Components

Toxicity to fish

: propan-2-ol

96 h LC50 Pimephales promelas (fathead minnow): 9,640 mg/l

Alcohols, C9-11, ethoxylated

96 h LC50 Fish: 8.5 mg/l

2-phenoxyethanol

96 h LC50 Fish: > 220 mg/l

Components

Toxicity to daphnia and other

aquatic invertebrates

: propan-2-ol

LC50 Daphnia magna (Water flea): > 10,000 mg/l

Alcohols, C9-11, ethoxylated

48 h EC50 Daphnia magna (Water flea): 5.3 mg/l

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

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poly(oxy-1,2-ethanediyl), a-(2-propylheptyl)-w-hydroxy-

48 h EC50 Daphnia: 10 mg/l

12.2 Persistence and degradability

Product

Biodegradability

: The surfactants contained in the product are biodegradable

according to the requirements of the detergent regulation

648/2004/EC

Components

Biodegradability

propan-2-ol

Result: Readily biodegradable.

Alcohols, C9-11, ethoxylated

Result: Readily biodegradable.

Cationic surfactants

Result: Poorly biodegradable

2-phenoxyethanol

Result: Readily biodegradable.

poly(oxy-1,2-ethanediyl), a-(2-propylheptyl)-w-hydroxy-

Result: Readily biodegradable.

12.3 Bioaccumulative potential

no data available

12.4 Mobility in soil

no data available

12.5 Results of PBT and vPvB assessment

Product

Assessment

This substance/mixture contains no components considered to be

either persistent, bioaccumulative and toxic (PBT), or very

persistent and very bioaccumulative (vPvB) at levels of 0.1% or

higher.

12.6 Other adverse effects

no data available

Section: 13. DISPOSAL CONSIDERATIONS

Dispose of in accordance with the European Directives on waste and hazardous waste.Waste

codes should be assigned by the user, preferably in discussion with the waste disposal authorities.

13.1 Waste treatment methods

Product

: Where possible recycling is preferred to disposal or incineration. If

recycling is not practicable, dispose of in compliance with local

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

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regulations. Dispose of wastes in an approved waste disposal

facility.

Contaminated packaging

: Dispose of as unused product. Empty containers should be taken

to an approved waste handling site for recycling or disposal. Do

not re-use empty containers. Dispose of in accordance with local,

state, and federal regulations.

Guidance for Waste Code

selection

: Organic wastes containing dangerous substances. If this product

is used in any further processes, the final user must redefine and

assign the most appropriate European Waste Catalogue Code. It

is the responsibility of the waste generator to determine the

toxicity and physical properties of the material generated to

determine the proper waste identification and disposal methods in

compliance with applicable European (EU Directive 2008/98/EC)

and local regulations.

Section: 14. TRANSPORT INFORMATION

The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are

in compliance with the selected mode of transport.

Land transport (ADR/ADN/RID)

14.1 UN number

Not dangerous goods

14.2 UN proper shipping

name

Not dangerous goods

14.3 Transport hazard

class(es)

Not dangerous goods

14.4 Packing group

Not dangerous goods

14.5 Environmental hazards

Not dangerous goods

14.6 Special precautions for

user

Not dangerous goods

Air transport (IATA)

14.1 UN number

Not dangerous goods

14.2 UN proper shipping

name

Not dangerous goods

14.3 Transport hazard

class(es)

Not dangerous goods

14.4 Packing group

Not dangerous goods

14.5 Environmental hazards

Not dangerous goods

14.6 Special precautions for

user

Not dangerous goods

Sea transport (IMDG/IMO)

14.1 UN number

Not dangerous goods

14.2 UN proper shipping

name

Not dangerous goods

14.3 Transport hazard

class(es)

Not dangerous goods

14.4 Packing group

Not dangerous goods

14.5 Environmental hazards

Not dangerous goods

14.6 Special precautions for

user

Not dangerous goods

SAFETY DATA SHEET

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14.7 Transport in bulk

according to Annex II of

MARPOL 73/78 and the IBC

Code

Not dangerous goods

Section: 15. REGULATORY INFORMATION

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

according to Detergents

Regulation EC 648/2004

5 % or over but less than 15 %: Amphoteric surfactants, Non-ionic

surfactants

less than 5 %: Cationic surfactants

Preservation agents:

2-phenoxyethanol

National Regulations

Take note of Dir 94/33/EC on the protection of young people at work.

Other regulations

Safety, Health and Welfare at Work Act, 2005

European Communities (Classification, Packaging, Labelling and

Notification of Dangerous Preparations) Regulations 1995. (S.I.

272 of 1995) as amended

15.2 Chemical Safety Assessment

This product contains substances for which Chemical Safety Assessments are still required.

Section: 16. OTHER INFORMATION

Full text of H-Statements

H225

Highly flammable liquid and vapour.

H302

Harmful if swallowed.

H315

Causes skin irritation.

H318

Causes serious eye damage.

H319

Causes serious eye irritation.

H336

May cause drowsiness or dizziness.

H411

Toxic to aquatic life with long lasting effects.

Full text of other abbreviations

ADN - European Agreement concerning the International Carriage of Dangerous Goods by Inland

Waterways; ADR - European Agreement concerning the International Carriage of Dangerous

Goods by Road; AICS - Australian Inventory of Chemical Substances; ASTM - American Society

Testing

Materials;

Body

weight;

Classification

Labelling

Packaging

Regulation;

Regulation

(EC)

1272/2008;

Carcinogen,

Mutagen

Reproductive

Toxicant; DIN - Standard of the German Institute for Standardisation; DSL - Domestic Substances

List

(Canada);

ECHA

European

Chemicals

Agency;

EC-Number

European

Community

number; ECx - Concentration associated with x% response; ELx - Loading rate associated with

x% response; EmS - Emergency Schedule; ENCS - Existing and New Chemical Substances

(Japan);

ErCx

- Concentration associated

with x% growth rate response;

- Globally

Harmonized System; GLP - Good Laboratory Practice; IARC - International Agency for Research

on Cancer; IATA - International Air Transport Association; IBC - International Code for the

SAFETY DATA SHEET

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Construction and Equipment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half maximal

inhibitory concentration; ICAO - International Civil Aviation Organization; IECSC - Inventory of

Existing Chemical Substances in China; IMDG - International Maritime Dangerous Goods; IMO -

International Maritime Organization; ISHL - Industrial Safety and Health Law (Japan); ISO -

International Organisation for Standardization; KECI - Korea Existing Chemicals Inventory; LC50 -

Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to 50% of a test population

(Median Lethal Dose); MARPOL - International Convention for the Prevention of Pollution from

Ships; n.o.s. - Not Otherwise Specified; NO(A)EC - No Observed (Adverse) Effect Concentration;

NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No Observable Effect Loading Rate;

NZIoC - New Zealand Inventory of Chemicals; OECD - Organization for Economic Co-operation

and Development; OPPTS - Office of Chemical Safety and Pollution Prevention; PBT - Persistent,

Bioaccumulative and Toxic substance; PICCS - Philippines Inventory of Chemicals and Chemical

Substances; (Q)SAR - (Quantitative) Structure Activity Relationship; REACH - Regulation (EC)

No 1907/2006 of the European Parliament and of the Council concerning the Registration,

Evaluation,

Authorisation

Restriction

Chemicals;

Regulations

concerning

International Carriage of Dangerous Goods by Rail; SADT - Self-Accelerating Decomposition

Temperature; SDS - Safety Data Sheet; TCSI - Taiwan Chemical Substance Inventory; TRGS -

Technical Rule for Hazardous Substances; TSCA - Toxic Substances Control Act (United States);

UN - United Nations; vPvB - Very Persistent and Very Bioaccumulative

Prepared by

Regulatory Affairs

Numbers quoted in the MSDS are given in the format: 1,000,000 = 1 million and 1,000 = 1

thousand. 0.1 = 1 tenth and 0.001 = 1 thousandth

REVISED INFORMATION: Significant changes to regulatory or health information for this revision

is indicated by a bar in the left-hand margin of the SDS.

The information provided in this Safety Data Sheet is correct to the best of our knowledge,

information and belief at the date of its publication. The information given is designed only as a

guidance for safe handling, use, processing, storage, transportation, disposal and release and is

not to be considered a warranty or quality specification. The information relates only to the specific

material designated and may not be valid for such material used in combination with any other

materials or in any process, unless specified in the text.

ANNEX: EXPOSURE SCENARIOS

DPD+ Substances:

The following substances are the lead substances that contribute to the mixture Exposure

Scenario according to the DPD+ Rule:

Route

Substance

CAS-No.

EINECS-No.

Ingestion

Alcohols, C9-11, ethoxylated

68439-46-3

Inhalation

propan-2-ol

67-63-0

200-661-7

Dermal

Alcohols, C9-11, ethoxylated

68439-46-3

Eyes

Alcohols, C9-11, ethoxylated

68439-46-3

aquatic environment

No lead substance

Physical properties DPD+ Substances:

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

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Substance

Vapour pressure

Water solubility

Pow

Molar Mass

Alcohols, C9-11,

ethoxylated

2.17 Pa

94.58 mg/l

1,995.26

propan-2-ol

6,020 Pa

60.10 g/mol

To calculate if your downstream Operating Conditions and Risk management Measures are

safe, please calculate your risk factor at the website below:

www.ecetoc.org/tra

Short title of Exposure

Scenario

General purpose cleaner. Manual process

Use descriptors

Main User Groups

Professional uses: Public domain (administration, education,

entertainment, services, craftsmen)

Sectors of end-use

SU22: Professional uses: Public domain (administration,

education, entertainment, services, craftsmen)

Process categories

PROC10: Roller application or brushing

PROC8a: Transfer of substance or preparation (charging/

discharging) from/ to vessels/ large containers at non-dedicated

facilities

Product categories

PC35: Washing and cleaning products (including solvent based

products)

Environmental Release

Categories

ERC8a: Wide dispersive indoor use of processing aids in open

systems